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Estimating Salt Budgets to Predict Chloride Threats to Municipal Wells From Salt Institute Presented at Minnesota Water Conference 2015 October 13, 2015 John Jansen, P.G., Ph.D. The Good: In Pre-Modern Times: • Salt was once a limited strategic resource • Trade routes of thousands of miles existed for centuries to move salt around the Middle East • Salt production is the weapon Gandhi used to challenge the English occupation in India • The word “Salary” has its origins in Romans paying soldiers in salt • Being worth your salt was a literal concern In Modern Times: • Mined salt has made salt cheap and plentiful • Deicing with road salt has made winter travel faster and safer • U of Marquette study found road salt cuts accidents by 88% “Snow fighters may save more people the fire fighters” • Going back to ice covered roads is impractical unimaginable to most people Environmental and Health Risks of Road Salt Contamination Area of Impact Human health Infrastructure Examples of Impacts • • • Hypertension from excess sodium in drinking water Ferrocyanide, added to chloride salts to prevent clumping, can release 25% cyanide ions in presence of sunlight Corrosion of concrete reinforcing rods in road, bridges, parking structures, etc. • • • Vegetation • • • Soil • • Corrosion costs estimated at $3.5 to $7 billion per year in the U.S. Corrosion protection practices increase the cost of auto manufacturing by nearly $4 billion/year Corrosion protection costs estimated at $8.3 billion/year for highway bridges, and $109 billion for epoxy coating; Osmotic imbalance in plants, inhibiting water absorption and reducing root growth Inhibition of seed germination and root growth for grasses and wildflowers (for NaCl as low as 100 ppm in soil) Competition to native species from salt-tolerant invasive species Inhibition of soil bacteria (for NaCl concentrations as low as 90 ppm), compromising soil structure and increasing erosion Accumulation of salt, particularly sodium, in soil over time, reduces soil fertility and affects soil chemistry Groundwater • Remediation of salt contamination in drinking water estimated at $10 million nationally Wildlife • Compromised health in birds ingesting salt at 266 mg/kg; median lethal dose in birds and mammals is 3,000 mg/kg Aquatic life • Decreased dissolved oxygen and increased nutrient loading, promotingeutrophication Release of toxic metals from sediment into the water column • • • • Reduction of number and diversity of macroinvertebrates Critical tolerance values in 10% of aquatic species exceeded for prolonged exposure to chloride concentrations >220 mg/L Median lethal dose (7 days exposure to salt) for 17 species of fish, amphibians, crustaceans ranges from 1,440 – 6,031 mg/L (mean value of 3,345 mg/L) From City of Madison Salt Report 2006 • Secondary Drinking water MCL for Cl 250 ppm (based on taste issues) • USEPA drinking water equivalency guideline for Na 20 ppm (based on sensitivity of people with hypertension) • USEPA Cl Surface water standards; Acute 860 ppm and Chronic 230 ppm (based on toxicity for fish) • IEPA Surface water standards; Acute 500 ppm Fingerprinting Source of Chloride with Halide Ratios • Chloride/Bromide ratios diagnostic of chloride source • Road salt and septic effluent/waste water occupy same range • Other indicators can be used to identify septic effluent and waste water • Trace ferrocyanide (anti-caking agent) can be used as road salt indicator • Road Salt is usually the biggest culprit in the northern states • Road salt is typically 60 to 90% of the loading • Other sources like water softeners and sewage treatment plants are secondary Application Rates of Road Salt are Still Going Up source: Madison and Dane County Road Salt Report, 2012 https://illinois.edu/blog/dialogFileSec/2095.JPG Data from Salt Institute, 2011 • US road salt use over 20 million tons by 2010 • National application rates have tripled since 1980 despite aggressive reduction efforts Chloride levels Are Rising in Most Surface water Bodies From City of Madison Salt Report 2013 • Chloride levels are three to five times higher in Madison’s lakes over the last 50 years 37 lakes, streams & wetlands on DRAFT 303(d) list for chloride in the TCMA (roughly 10% assessed) – 2 Chloride TMDLs completed 41 waters determined to be “High Risk” in TCMA Defined as having values within 10% of the standard or at least one exceedance of the standard Groundwater levels of chloride in the TCMA are increasing 30% of wells above the standard Impact on baseflow levels of chloride is important USGS groundwater data also shows Significant increase in chloride since 1996 in Upper Mississippi River Basin Metropolitan trend analysis for the Mississippi, Minnesota and St. Croix Rivers in TCMA all show increases in chloride (compared to the 10 year average) Source: Brooke Asleson, Minnesota Pollution Control Agency Chloride Levels in Minnesota’s Sand and Gravel Aquifers From Kroening 2014 (MPCA) • Wells with elevated Chloride are clustered near cities • Highest levels in Twin Cities area but other areas having problems • University of Minnesota study found that 78% of the chloride used is being retained in the TCMA Discrete Sources Can Generate Spatially Limited Plumes Locally Grown Salt Water Intrusion for the Landlocked Downward flow from density flow and/or vertical gradient A Question of Balance: Developing a Salt Budget for a Wellfield • What salt loading can the groundwater system handle? • Is the safe level enough to keep the roads clear? • Can be done for a well, stream, or basin • Loading limits depend on soil type, recharge rate and Groundwater Flow Pattern • Level of effort can be matched to the need for accuracy – start simple and increase level of effort if needed • Target values can be fit to sensitive receptors South Well Field City of Marshfield, WI • Oldest well field still in use by City • Currently 5 active wells, 2 abandoned • 4 wells several decades old • Located in an area with a state highway, an airport, and many parking lots • Capture zone delineated by two previous studies South Well Field Chloride Trends • • • • Cl levels doubled to tripled from 1985 to 2011 Apparent declining trend in 2 of 5 wells from 2011 to 2013 Data sparse so trends from 1985 to 2011 are speculative Sodium levels exceed 30 ppm in wellfield (58 ppm in 1998) Salt Loading in Capture Zone • Salt load calculated using lane miles and average salt loading rate from WDOT and City Road Department • Lower application rates used for parking lots and runways (may actually be much higher) • Used capture zone from both wellhead studies • Estimated loading rate 926 to 1575 tons/yr Calculating Maximum Groundwater Chloride Concentrations • Using estimated range of recharge rates (3 to 7 in/yr) average Chloride levels could exceed 2,500 ppm if all the water was recharged – NOT REALITY • Using an estimated percentage of infiltration of about 25%, the average chloride concentrations of recharge would be 360 ppm (not implausible given concentrations in other wells) • Using a lower level infiltration estimate (10%) predicts average chloride concentration of recharge of about 130 ppm (similar to recent values in wells) • Capture zone for the well field indicates that the bulk of the water in the aquifer is probably less than 5 or 10 years old • Chloride levels have reached equilibrium for current application rates • No large increases likely if loading rate does not rise • Any reductions in loading will result in improvements within a few years • City is currently reducing salt loading and rerouting parking lot runoff to continue decreasing trends • Well fields with more critical problems may require monitoring wells, transport models, extraction wells, and more aggressive follow up work • Budget approach is inexpensive screening tool Sodium and Chloride Concentrations at Production Well AVY-1 Ashland, New Hampshire Production Well AVY-1 Ashland, New Hampshire 160 Chloride Sodium 140 Production Well AVY-1 Linear (Chloride) Linear (Sodium) Concentration (mg/l) 120 100 80 60 40 Wellhead Protection Area (WHPA) Date Dec-08 Dec-07 Dec-06 Dec-05 Dec-04 Dec-03 Dec-02 Dec-01 Dec-00 Dec-99 Dec-98 Dec-97 Dec-96 Dec-95 Dec-94 20 Screen Elevations and Average Chloride Concentrations PW AVY-1 D Upwelling toward well Scavenger Well in plume??? Density driven downward migration from source area Green Storm Water Management May Be Making Groundwater Problems Worse •Several states and local governments are adopting infiltration basins as a “green” solution to storm water •Most rules are surface water driven, do not account for groundwater quality •Other chemicals also a threat (fertilizers, pesticides, VOCs, metals…) •Time lag of years to decades may make solving the problem by source reduction too little and too late •Are we trading a 2 week problem in surface water for a multi-decade problem in groundwater? Mitigation • Reduce loading to groundwater • Divert snow melt away from recharge basins • Keep snow stockpiles out of capture zones and on impervious surfaces that drain to surface water • Identify salt hot spots in soils and aquifer and remove or dilute • Managed aquifer recharge with low salt water to dilute salt concentrations and flush out of aquifer • Use scavenger wells or barrier wells? • Locate new wells in low salt load areas and protect those areas Treatment • Blending with low salt water • Requires suitable water source and piping to blending point • Reverse osmosis • High energy requirements • Brine disposal issues • High cost To be avoided if at all possible End of the Road For Me Note: not caused by road salt JENNY JASPERSON, MPCA/UMD FLOOD EFFECTS ON SW-GW INTERACTIONS KAREN GRAN, UMD JOE MAGNER, EAST BRANCH AMITY CREEK UMN JOHN SWENSON, UMD OUTLINE Scope Study Area Data Collection Background/Broader Results SW/GW Response to the Flood PROJECT SCOPE Examine GW-SW interaction and water budget characterization at watershed and reach scales in a coldwater stream with a healthy and stable brook trout population. Identify locations of GW-SW exchange, upwelling zones, storage zones Look at SW/GW levels and composition; and seasonal variation Evaluate change in these relationships as result of a major flood WHY EAST BRANCH AMITY CREEK? Native Brook Trout Population BKT densities 95 th Percentile in greater Arrowhead Region Supports all age classes No stocking of BKT since 1993 Suspected GW inputs Good/Excellent Thermal Conditions (Primary Growth Range = 96%, 2011) >60% flow contribution to lower gage during low to mid-range flows MPCA’s WRAPS Schedule (Lake Superior South – 2011 start) STUDY AREA STUDY AREA Lake Superior South Major watershed Main tributary to Amity Creek. Geology: Bedrock, Till, Alluvium Distinct Features EAST BRANCH AMITY CREEK Entrenched Stream Valley Lateral movement of stream in clay walls Till/alluvium mix Remnant channels & inactive beaver dams DATA COLLECTION DATA COLLECTION Water Level Data Stable Isotopes of O & H 1-Flow/level gage 9-monitoring wells Timeframe 2010-2014 Data Complete Years: 20112012 DATA COLLECTION P V C w i t h b o t t o m s c re e n Depth Range: 2.33 – 3.67 feet below surface HOBO loggers Soils: Mix of sand, gravel, and clay 250 feet ISOTOPE SAMPLE LOCATIONS Precipitation SW GW Snowmelt Rain event Baseflow 2012 WEATHER • Mild Winter with lower than average snowpack • 3-inch rain event in May • Major flood event: June 19th -20th • Extreme Drought declared in September BROADER STUDY DEFINING FLOODPLAIN STORAGE Near Bank Storage: Stream water moves into the banks during periods of high flow and typically returns to the stream channel within day(s) or weeks. Depressional Storage: Precipitation or above bankfull stream water is captured in depressions, infiltrating through the soil profile. Depending on the system, water returns to the stream may take weeks, months, or years. WATER LEVEL COMPARISON Depth-to-water Duration Curves Continuous Levels, 2011 Depressional vs Near Bank ISOTOPE HYDROGEOLOGY Isotopes of an element have similar charge, but different masses. Diagram source: http://www.ces.fau.edu/nasa/module-3/how-is-temperature-measured/isotopes.php The amount of 18 O compared to using Del Notation: 16 O (or 2 H to H) is expressed δ18O ‰ = (18O/16O)sample – (18O/16O)standard x 1000 ‰ VSMOW (18O/16O)standard Parts per thousand enrichment or depletion relativ e to the standard VSMOW is the standard (Vienna Standard Mean Ocean Water) ISOTOPE DATA δD = 8.37 δ18O + 15.47 R2 = 0.9823 Craig, 1961. Linear Relationship δD = 8δ18O + 10 , water that has not been evaporated. SW-GW RESPONSE TO FLOOD June 19 th -20 th , 2012 DULUTH FLOOD, 2012 - 500 Year Storm - 7.5-8.5 inches - <24-hr Duration STREAM FLOW (CFS) RESPONSE 800 East Branch Amity Creek, Duluth MN - H02037005 600 400 200 0 4/10/11 2000 7/19/11 10/27/11 2/4/12 5/14/12 8/22/12 Amity Creek at Occidental Blvd, Duluth MN - H02038001 1500 1000 500 0 04/07/11 07/16/11 10/24/11 02/01/12 *HECRAS model used to Model Ungauged High Flows 05/11/12 08/19/12 STREAM FLOW RESPONSE Photo: MPCA 5/24/12 – 3-inch event http://content.govdelivery.com/accounts/MNPCA/bulletins/c97fd0 Photo: www.lakesuperiorstreams.org June 20th, 2012 – falling limb of flood event VALLEY WAS INUNDATED JULY 21st – TWO DAYS AFTER PEAK FLOWS Debris in trees, 3 - 4’ above ground in floodplain Bank erosion where channel abutted steep valley walls Areas of channel aggradation and incision. One well was damaged & all well covers were removed by water One well was filled in with sand. Remnant channel was scoured. GEOMORPHIC RESPONSE INCISION & AGGRADATION Slope Break Slope Break Slope break at old (2010) beaver dam = Response control Lateral Movement at bends Upstream side of Break • Alluvial fill Downstream side of Break • In-channel incision • Debris caught on banks flow REMNANT CHANNEL Post-Flood Pre-Flood 15+00 13+00 13+00 Channel Incision and loss of organics, exposing gravel alluvium. FLOOD EFFECTS DATA • CHANGE IN GW LEVELS • CHANGE IN GW COMPOSITIONS DROP IN GROUNDWATER LEVELS D RY W E L L S = F I RS T CL U E Slope break GROUNDWATER LEVELS I N CI S ION I N MA I N CH A N N E L & RE MN A N T Near Bank Depressional /Remnant mw12+00 2012: -0.84’ 2013: -0.60’ mw13+00 2012: -1.43’ 2013: -1.02’ Elevation (ft) 1019.5 1017.5 mw12+00 mw13+00 1015.5 1013.5 3/15/10 9/15/10 3/18/11 9/18/11 3/20/12 9/20/12 3/23/13 9/23/13 GROUNDWATER LEVELS A RE A S O F N O N O T I CE A BL E I N CI S ION Near Bank mw4+00 2012: -0.11’ 2013: +0.17’ Elevation (ft) 1028 1026 mw4+00 1024 1022 03/15/10 09/15/10 03/18/11 09/18/11 03/20/12 09/20/12 03/23/13 09/23/13 REDUCED DRY SEASON GROUNDWATER LEVELS 8+00, not installed 2013 D R Y D R Y • Drop in GW levels in remnant channel and East Branch Amity-below slope break. • Slight rebound in 2013 D R Y D R Y TEMPORARY CHANGE IN STREAM BASEFLOW COMPOSITION Post-Flood 2012 Baseflow 2014 Baseflow 2012 – 3-inch Pre-flood Rain Event 2012 Snowmelt 2010 Baseflow NEAR BANK EXCHANGE • Near Bank GW ≈ stream water → frequent interaction • During small rain event, inside bend well had more SW signal • No obvious changes in relationships due to the flood. DEPRESSIONAL GW ISOTOPIC SIGNATURE • Depressional GW is stable. Disconnected from precipitation, stream flow, & remnant SW. • Water in remnant channel is less affected by precipitation & runoff than the stream. DEPRESSIONAL GW ISOTOPIC SIGNATURE • Sept 2012: • Depressional GW has changed, now having a heavier signal. • No barrier between SW & GW in the remnant channel. • Stream has a slightly different signal. • 2013: • Depressional & outside bend Near-bank GW are approaching “Original water” signal DEPRESSIONAL GW ISOTOPIC SIGNATURE Ideas & Interpretations: • Depressional GW changed, having a heavier signal. • Floodwaters replaced or mixed into the shallow GW table. • No barrier between SW & GW in the remnant channel. • Incision flushed out organics and reduced the barrier OR • All water in the system had been replaced or re-mixed. • Sept 2012: Stream has a slightly different signal than remnant & wells. • Strong influence from upstream site SW13?? Assuming different composition at SW13. • Depressional GW & outside bend Near-bank GW are approaching “Original water” signal by July 2013. • 2013 was a more typical climate year, including more snowmelt contributions. • GW is re-establishing the pre-flood composition SUMMARY Floodplain Storage behaves differently than Bank Storage. Differences in depth-to-water, rainfall response time, & exchange with SW. Evaporative Losses differ throughout watershed. Strong GW signal entering watershed 1.5 upstream of study reach In areas of flood-induced incision, the GW table dropped. Groundwater was replaced or re-mixed during flood event. Groundwater signal was trending back toward the “original water” or a more negative signal one year later. Groundwater levels remained at lowered levels with a slight rebound one year later. A SPECIAL THANKS TO: MPCA & MPCA Staff Pat Carey Suzanne Hanson Andrew Streitz Pete Knutson Andrew Swanson, former MPCA Brittany Story Jeff Jasperson Mike Kennedy Tom Schaub Tom Estabrooks Zach Moore, MN DNR (former MPCA) University of Minnesota Duluth & Twin Cities Rich Axler, NRRI Howard Mooers, UMD Jerry Henneck, NRRI Keith Anderson & TSA3 Tim Beaster, SSLSWCD Molly Wick, former UMD Grant Neitzel, former UMD Megan Kelly, MN DNR QUESTIONS Jenny Jasperson Watershed Unit MPCA Duluth office 218-302-6634 jenny.jasperson@state.mn.us 2012 MIXING MODELS BASEFLOW SEPARATION May 2012 3-inch Rain Event Post-flood 2012 Baseflow Snowmelt 2012 Non-flood year Baseflow (2010 & 2014) Initial Township Testing 2013-2014 Results for Nitrate in Private Wells The Minnesota Department of Agriculture’s Township Testing Program Kimberly Kaiser Hydrologist Nikol Ross Hydrologist Fertilizer Management Unit Contributing Staff Hydrologists • • • • • • • • • • • Nikol Ross Jeff Paddock Brennon Schaefer Bill VanRyswk-Supervisor Marie Juenemann Katie Rassmussen Adam McCullough Ryan Meyer Alicia O’Hare Jaime Nielsen Dylan Timm Managers/Supervisors/ Program Administrators • Bruce Montgomery • Larry Gunderson • Annie Felix-Girth-NFMP • Heather Johnson • Margaret Wagner Minnesota Agriculture • Corn and soybeans are Minnesota’s top producing crops • Nationally, Minnesota ranks 4th for corn production and 3rd for soybean production • The agriculture and food industry is the 2nd largest employer in Minnesota http://www.nass.usda.gov/Quick_Stats/Ag_Overview/stateOverview.php?state=MINNESOTA Minnesota Drinking Water • 8 community water supply systems treat for nitrate • 105 non-community system’s had water sources with nitrate at or above the maximum contaminant level (MCL) of 10 milligrams per liter (mg/L). 50,000 people Up from 6 systems in 2008 (Minnesota Drinking Water Annual Report 2014, MDH) The Minnesota Department of Agriculture is the state agency responsible for nitrate in groundwater, relating to nitrogen fertilizer Minnesota’s Nitrogen Fertilizer Management Plan (NFMP) • The state’s blueprint for minimizing groundwater impacts from the use of nitrogen fertilizer. • 2015 revision- guided by an advisory committee • The plan calls for an assessment of current nitrate conditions in private wells in order to determine nitrate exceedances in drinking water at a township scale. NFMP Phased Approach to Regulation Criteria Prevention Level One Level Two 1. Nitrate Concentration <5% 2. BMP Use/Adoption Unknown Unknown Acceptable Regulatory Status Voluntary Voluntary Voluntary Level Three 5% >= 10 mg/L or 10% >= 10 mg/L 10% >= 10 mg/L 10% >= 7 mg/L Voluntary Level Four 15% >= 10 mg/L Not acceptable Not acceptable Regulatory Regulatory Regulatory Township Testing Program (2-step assessment) This survey approach was developed with input from the advisory committee and from years of experience with nitrate clinics and volunteer private well networks Step 1. • Initial homeowner collected sample – Offer all well owners in the township a free nitrate test kit. Step 2. • Offer follow-up sample for high (≥5 mg/L) nitrate wells – Collected by trained staff (with homeowner permission) *http://www.mda.state.mn.us/protecting/cleanwaterfund/gwdwprotection Except that: At the direction of the Minnesota Legislature ( HF1183 Article 2, Sec. 3, part b), Cite: Minn. Stat.; 2013 Minn. Laws Chap. 137 Art. 2 Sec. 3(b) additional funds were appropriated: “monitoring for pesticides when nitrate is detected” • The MDA began sampling in September of 2014 for common detection pesticides as a pilot project in Dakota County. • MDA List 1 Pesticides, which is comprised of 22 pesticide-related compounds and includes the five groundwater common detection parent compounds. Township Testing Program (2-step assessment) This survey approach was developed with input from the advisory committee and from years of MDA experience with nitrate clinics and volunteer private well networks Step 1. • Initial homeowner collected sample – all well owners in the township are offered a free nitrate test kit. Step 2. • Offer pesticide sample and follow-up nitrate sample for wells with detectable nitrate • Collected by trained staff (with homeowner permission) *http://www.mda.state.mn.us/protecting/cleanwaterfund/gwdwprotection Where do we start? • Areas with a history of high nitrate results • Significant row crop production and vulnerable groundwater • Local staff knowledge and input Step 1. Initial Sample (Homeowner Collected) • Work with local partner (SWCDs or County environmental services) to offer free nitrate test kits to homeowners in vulnerable townships • The local partner responsibilities • Develops the mailing list of private well owners • Public service announcements/outreach/homeowner questions • Coordinates with a certified lab to send well owners a nitrate test kit. What’s in the Nitrate Kit? Well owners receive in the mail: • Invitation letter • Sample bottle • Sampling instructions • Prepaid mailer • Survey about their well (construction type, depth, age and potential nitrate sources) Homeowners receive their results from the lab with a brochure discussing the results. Cost: < $30 per well for Administration/supplies/analysis /data entry Initial Data Analysis of Homeowner Collected Samples 1. Summarize results by township 2. Summarize well surveys • • • • • 3. Type of well construction Well depth Well age well Land use Potential nitrogen sources – septic distances/feedlots/fertilizer storage Summarize all relevant groundwater information • County geologic atlas or regional aquifer assessments/nitrate probability maps • County well index well profile 4. Results by aquifer (if unique ID is provided and a well log is available) Preliminary Results of Homeowner Collected Samples 2013-2014 Approximate % ≥ 10 Number of Number of mg/L Townships Wells* < 5% 14 1351 5- 9.9% 17 2334 >=10 % 29 3657 Total 60 7342 * Does not include wells of known hand dug construction or wells with unclear locations. Total Samples Collected by Township • Average response rate is 30% Total Samples Collected by Township Step 2. Follow-Up Sampling Offer all well owners with detectable nitrate a free pesticide sample and follow-up nitrate sample 1. Blue tag Document well information • • • • Unique well Identification number Well type Well diameter Obvious well construction problems Damaged casing Poor seal Hand Dug Well photo credit: MDH/SE Network well coordinator training slides Step 2. Follow-Up Sampling 2. Collect nitrate and pesticide samples (MDA staff) 3. Inventory possible nitrate sources close to the well. • Septic sources – appropriate isolation distances? • Animal sources – animal or poultry building/feedlot/manure storage? • Other sources – fertilizer storage Data Analysis for Follow-up Sampling 1. Have results changed significantly since initial homeowner sample? 2. Does the survey information accurately reflect the well site visit and well log information? 3. Aquifer designation and nitrate results Prior to Making a NFMP Level Determination Data Must be Reviewed and Screened 1. Well Information for high nitrate wells • Obvious well construction problems (cracked casing/ no grout/ poor seal) 2. Screen out wells with likely point sources • Septic sources – appropriate isolation distances? • Animal sources – animal or poultry building/feedlot/manure storage? • Other sources – fertilizer storage In Summary: • Local partners and private well owners are the cornerstone of this program. • By the year 2019, between 250350 Townships will be assessed for nitrate conditions in private wells. • Approximately 30,000 homeowners will have tested their well for nitrate. Questions? http://www.mda.state.mn.us/en/protecting/cleanwaterfund/gwdwprotection/township testing.aspx http://www.mda.state.mn.us/chemicals/fertilizers/nutrient-mgmt/nitrogenplan.aspx Kimberly Kaiser Hydrologist Fertilizer Management Unit Minnesota Department of Agriculture 651-201-6280 Kimberly.kaiser@state.mn.us