materials
Transcription
materials
SUMMARY EDITORIAL............................................................3 HIGHLIGHTS OF 2011 ............................................. 5 ACTIVITIES ...........................................................6 RESEARCH & DEVELOPMENT ....................................8 MATERIALS ............................................................ 9 ENVIRONMENT ....................................................... 14 PROCESSES............................................................. 18 SERVICES TO COMPANIES .........................................23 STUDIES AND TESTS ......................................................... 26 WE PARTICIPATE IN ................................................35 WE ARE STAKEHOLDERS IN .......................................38 MEETINGS AND COUNCILS........................................39 PUBLICATIONS, CONFERENCES AND FAIRS ....................44 KEY FIGURES .........................................................54 1 2 Environment and Materials Research Association EDITORIAL EMRA brings together the expertise of six Environmental, Materials and Process Research Centres in order to provide a sustainable development reponse to major economic and societal challenges. These six research centres in the province of Hainaut - Certech (CEntre de Ressources Techologiques en CHimie, in Seneffe), CRIBC (Centre de Recherche de l'Industrie Belge de la Céramique, in Mons), CTP (Centre Terre & Pierre, in Tournai), INISMa (INstitut Interuniversitaire des Silicates, sols et Matériaux, in Mons), INS (Institut National des Silicates, in Mons) and Materia Nova (in Mons) chose to form an association under the name of "EMRA" at the end of 2011, by ratifying a charter of mutual commitment. For INS, CRIBC and INISMa, founded under the impetus of the ceramics sector in 1938, 1948 and 1973, respectively, this was not a new initiative. They had already been putting their synergy and expertise in the field of materials (ceramics, glass, and so on), soils and the environment to good use within the BCRC (Belgian Ceramic Research Centre) for many years. In 2009, the CTP and BCRC decided to work together and thus laid the foundations of the strong EMRA partnership. After a three-year "engagement" for these original partners, Certech and Materia Nova came to add the finishing touches to EMRA's expertise in November 2011. Created in 1996, also as the result of an industrial initiative (Ateliers Louis Carton, in Tournai), the Centre Terre & Pierre was initially dedicated exclusively to mineral processing before it diversified its activities. CTP now has extensive expertise in the environmental field, particularly in the recycling and valorisation of "materials". Certech, centre of chemical expertise and applied research, was also created in 1996, by UCL. For the last 15 years, the centre has offered research and service contracts to small and large companies directly or indirectly involved with chemical sector technology, such as automotive, construction, packaging, food, pharmaceutical, medical, cosmetic, energy, environment, and so on. Originally founded by the Polytechnic Faculty of Mons (FPMs) and the University of Mons-Hainaut (UMH) as part of Objective 1 in Hainaut, Materia Nova has been functioning as an independent organisation (asbl - non-profit) since 2001. In July 2008, it merged with NATISS to form a single accredited centre. Materia Nova specialises in material surfaces and interfaces (metals, glass, polymers, etc.) as well as polymers (especially nano-composites and bioplastics). 3 Environment and Materials Research Association Benefitting from its location in the heart of Europe and the combined resources now at its disposal, EMRA offers quality services at both the local and international level in analysis, testing, consultancy, expert reports, certifications, product/process development, research and innovation. As proof of the partners' commitment and determination to offer even greater efficiency for customers, it was agreed — and is now the case — that only two of the six centres, which enjoy a special reputation in the field and which have the greatest level of expertise, would respond to enquiries. Like its partners, EMRA operates as an SME. The managerial autonomy left to each member ensures the flexibility and rapidity of response characteristic of small organisations, while at the same time offering to the industry a wider range of services. Having already operated for a long time according to the ISO 9001 quality management system and to some of the ISO 14001 environmental management system, part of EMRA's testing activities is under ISO 17025 accreditation. By way of its members, EMRA is also recognised as an expert on the CEN, ISO and AFNOR standardisation committees and is also an approved Research Centre in Wallonia, at Belgian Federal level as well as in Flanders, which therefore makes it also an eligible research partner in the EU Research Framework Programme. Governance of EMRA is entrusted to an Executive Committee whose role is defined by internal rules and regulations (ROI). It is made up of a management representative from each approved Research Centre. This Committee makes the necessary decisions for the smooth running of the strong partnership. Each partner is then responsible for relaying necessary information to its respective management bodies. A member of the Executive Committee is appointed as coordinator, according to a rotation system. In addition to representing EMRA, the coordinator's role is to lead the Executive Committee and its working parties. In order to be even more efficient, dynamic working parties are created as and when the need arises within EMRA. These working parties bring specialist(s) from each partner organisation together over a specific topic. The members of the working parties get to know each other, share their "best practice" experience and, ultimately, make proposals for joint efforts and improvements to the overall working of the Centres. It's the definition of a "win-win" situation. Stéphane Neirynck EMRA Coordinator 4 Environment and Materials Research Association HIGHLIGHTS OF 2011 JANUARY JUNE NOVEMBER 27 - Lab'Insigth (Mons) 7 to 9 – Environord – (Lille, FR) 8 to 10 - Intersolar fair – (Munich, DE)* 19 - ECERS Conference (Stockholm, SE) Prix Stuijts Lecture 4 – Signature of the EMRA charter 1 to 30 Commissioning of SPS equipment (Mons) 9 and 10 - Emissions from Odours from Materials 9th edition 23 - Hainolase Day (Mons) 29 to 2/12 - Pollutec 2011 (Paris, FR)* 29 SFGP (Lille, FR) FEBRUARY 7 - Annual BCerS Day (Leuven) 16 - MITECH Cluster Reception (Mons) JULY MARCH 1 - "Innov'action Emballage" fair (Villers-le-Bouillet) 10 -14– PAC RIM 9–(Cairns, AUS) DECEMBER SEPTEMBER APRIL 13 to 16 – AETOC (Mons) 29 - Inauguration of experimental centre (Seneffe site) MAY 3 and 4 - SINAL fair (Châlons-enChampagne, FR) 21 - Open day: international chemistry year (Mons) 24 to 27 – TMB – waste to resources (Hanover, DE) 25 - JTECH " Bioplastics: reactive compounding and applications" (Ghislenghien) 25-27Poudres et Matériaux Frittés (Saint Etienne, FR) 23 – Open day (Tournai site) st st 26 – 1 Defence of the 1 First Doca thesis (Louvain-la-Neuve) SPS 28 – Eurofinish (Ghent) 7 - 9 Rencontres Internationales sur la Projection Thermique (Limoges, FR) 9 - Commissioning of SOLINDUS equipment (Châtelet) 9 - RF Convergence portfolio science day (Mons) OCTOBER 12 and 13 - Les RDV Carnot – (Lyon, FR)* 13 - JTECH "Protection de la Pierre" 20 - JTECH "electronics organic" (Mons) 25 - Open day: high schools (all EMRA sites) * supported by 5 Environment and Materials Research Association ACTIVITIES (Bio)polymers Reactive extrusion Ceramics Sintering of inorganic materials Electrolytic depositions Intensification of chemical processes Geopolymers Mineral processing Refractory materials Inorganic materials processing Nanomaterials Rapid prototyping Nanocomposites Laser technology Cement phases Thermal treatments Inorganic and hybrid coatings Organic and hybrid coatings Rocks and minerals Glass 6 Environment and Materials Research Association Air Biotechnology Energy conversion "Cradle to Cradle" Energy saving Energy efficient processes Quality labelling Energy recovery Recycling inorganic materials Recycling organic materials Soil Biomass valorisation Waste valorisation 7 Environment and Materials Research Association RESEARCH & DEVELOPMENT The driving force of EMRA's research policy is to meet the main expectations of the industrial world. These expectations are centred on remaining competitive, the deployment and/or redeployment of activities, adaption to technological change and product and process diversification initiatives. Through their research and technology watch activities, and by becoming part of international networks, EMRA members have become the leaders in their respective technological fields. They have all the appropriate facilities and equipment for these assignments. In 2011, EMRA teams had nearly 70 R&D projects on the go. These projects are, more often than not, partially supported by public funds and allow the research teams to expand their expertise in the Environmental, Process and Materials fields. The results of their research work will subsequently be developed within the companies. Main sources of funding : Alongside these projects which help expand the expertise of EMRA members, many businesses innovation work has been backed by EMRA in the form of either Technical Support or Industrial Research. The partners guide 8 companies in the setting up of projects, collaborate on research, and provide technological transfers. In 2011, some 130 companies received support for their innovation work thanks to EMRA's expertise. Environment and Materials Research Association MATERIALS FROM SYNTHESIS TO FINISHED PRODUCT FROM THE ORIGIN OF RAW MATERIALS TO THEIR SECOND LIFE In 2011, EMRA teams carried out 31 research projects, with the support of public funds. The aim was to develop sustainable materials with appropriate properties and performances for market needs: from ceramics to plastics to hydraulic bonding agents. EMRA's expertise in materials covers a number of areas: CERAMICS (baked clay products, technical ceramics, refractory ceramics, etc.) — formulation, processes, studies of physical and chemical properties, analysis of natural or synthetic raw materials. GLASS (hollow and flat glass): optical, chemical and mechanical characterisations, analysis of flaws, development of glass compositions. which enable primary or secondary materials to be incorporated, with the aim of developing alternative materials for the construction and public works industry (BTP). FORMULATION OF HYDRAULIC BINDING AGENTS THE DEVELOPMENT OF ORGANIC, INORGANIC OR HYBRID that can be applied to every type of substrate or material, with the aim of improving their current performance or providing new, innovative uses. COATINGS AGRO-SOURCED PLASTICS (whether filled fibres/nanoparticles or not) in order to improve their performance and extend the scope of their use. 9 Environment and Materials Research Association Our R&D projects PROJECT MICROPACK Development of a micro-structured composite material with high barrier properties for food preservation using existing machines PARTNERS Certech, Celabor, Carah PIMI- REMANOS A micro-system integration platform fit for industrial use and capable of solving the majority of problems linked to packaging RF - EVERWALL Production of barrier layers for applications related to food UMONS, Materia Nova, ULB RF - SMARTFILM A Development of optically active organic components UMONS, Materia Nova, ULB RF - SURFACE A Station for profilometry and surface analysis of thin films. UMONS, , Materia Nova SINOPLISS POLYTISS Development of thermoplastics, thermosetting products and composites of renewable origin FUNDING Ulg, SIRRIS, CEWAC, Materia Nova Convergence Materia Nova, Ulg, UMONS, FUSAGx Polymer technology, implementation, formulation, characterisation and recycling Certech, Materia Nova, CTP T-REX-MORECAR Modelling rheological properties of refractory concretes INISMa, CSTC, ULg- LTAS SOLAPACK Use of sorption layers on cellulose packaging materials in order to prevent the migration of critical substances Certech, Celabor, PTS (G), ZUT(PL), COBRO (PL), Polish Chamber of Packaging Cornet PCtoTEM Development of new "track-etched" polycarbonate membranes for medical and diagnostic use Certech, manufacturer CWALity HYCOLASE Laser deposition of high-performance ceramic-metal composites intended for the surface hardening of wearresistant parts TECHNOPOLY CRIBC, UMons, BAM(DE), VTT(FIN) First Doca INTERMES Mesoporous structures obtained from interconnected networks Certech, UMons HARCANA The High Aspect Ratio CArbon-based NAnocomposites Materia Nova + 15 international partners FP7 - 7th framework programme Certech, UCL-BSMA, UlgCERM, FUNDP-LPS Greenomat mobilisation programme CLEANOPTIC Nano-composite coatings with self-cleaning, anti-icing, non-reflective properties, applied by a completely green process on glass panels used in the capture of solar energy PRISTIMATMEDIMAT HAP and TCP-based materials for medical use SIRRIS, CRITT-MDTS, UPJV, UVHC - LMCPA, CRIBC PRISTIMATTRANSMAT Materials for transport (functional surface modification, gradient materials and on-board intelligence systems) UVHC – LMCPA, CRITTMDTS, SIRRIS, UPJV, UVHC-DOAE, CRIBC Research and development of thin layer sol-gel type coatings for the protection of metallic surfaces and treatment of stone Certech, CRITT-MDTS, GEGENA2 HYBRIPROTECH 10 INTERREG IV Environment and Materials Research Association NANOparticles for the production of high performance biodegradable polyLACtic acid-based materials Materia Nova, ENSAIT, ENSCL NAnocomposites aimed at the VAlorisation and counting of REcycled plastic materials Materia Nova, CREPIM, ARMINES POLYCHANVRE Cross-border development of polymer-hemp composite materials Certech, Ulg, Gembloux Agro-BIOTECH,CRITTMDTS, INRA, VALBIOM,CHANVRECO RECY-POLYMER The recycling and valorisation of thermoplastics from a cross-border perspective Certech, VKC, CREPIM COMPONAT Development of natural vegetable oil-based composites Certech, UCL-BSMA, CSTC + industrial partnership BIOWALL Production of bioplastics like polylactides from agricultural raw materials Materia Nova, UMONS + industrial partnership CARMAT Development of new types of construction materials obtained by carbonation, using industrial fumes and steel slag fractions that are hard to recycle CTP, CRR, CSTC, ISSeP, UCL + industrial partnership FRENSIS Super-insulating window, including ultra-thin vacuumsealed double glazing in a very high performance thermal frame Materia Nova, UMONS, UCL + industrial partnership WAL-AID Promoting competition and durability for the Walloon food industry by creating an interdisciplinary platform of different skills to encourage interaction. CELABOR, CRA-W, FUNDP, Gx AB, Materia Nova, UCL, ULg + industrial partnership CEMCALC Ternary cements with high calcium and low slag content CSTC, CRIC, CTP, ULg MODICELL Development of food packaging materials combining a cellulose matrix with a biodegradable polymer to improve water and oxygen barrier properties Certech, Materia Nova, Celabor NANOFORM Hydrothermal synthesis of oxide nanopowders with a controlled morphology for multipurpose coatings CTP, CoRI, INISMa PRIBREF I & II Standardised procedures to help control the workability and setting of hydraulic setting refractory concretes GEL DEGEL Critical analysis and optimisation of the European methodology for assessing the behaviour of bricks and masonry in freezing conditions II NANOLAC NAVARE • • INTERREG IV Marshall Plan* Collective research CRIBC (Pribref I) CRIBC , CRIC (Pribref II) SPFEconomie/NBN CSTC, CRIBC Centres : MECATECH, GreenWin, WAGRALIM, BIOWIN Clusters : Val+, MITECH 11 Environment and Materials Research Association Key projects TECHNOPOLY The TECHNOLOPOLY portfolio draws on the complementarity and proximity of the three EMRA member research centres. The section of the TECHNOLOPOLY portfolio relating to exceptional equipment concerns the acquisition of remarkable, entirely modular reactive extrusion equipment which allows work to be carried out on small quantities of products. It aims to combine two separate disciplines; namely chemistry and the implementation of polymers in a single "one batch" process, and moreover, to continuously develop and perfect high performance polymer materials in economically attractive conditions (for the industrial sector). Reactive extrusion opens up numerous possibilities — such as use as a chemical reactor and/or mixing tool, mass polymerisation, chemical grafting, rheological modification, blend recording, dynamic vulcanisation, recycling, or continuous production of semi-finished products — and enables these numerous factors to be adapted and combined. The recycling project of the TechnoPoly portfolio aims to put plastic waste selectively collected from container stocks to good use in two main ways: mechanical recycling and catalytic cracking (recovery and valorisation of carbon and energy content in the form of fuel). In order to execute the project effectively, various tasks were carried out, such as monitoring the state-of-the-art, characterising collected plastic waste, physical and chemical processing aimed at separating the various types of plastics, and formulating, implementing and assessing the properties of recycled products. The promotion section of the portfolio aims to ensure the effective linkage of technological transfers between the research centres and the companies. The promotion and development of research results are achieved through various communication, technology watch and awareness-raising activities in companies, especially SMEs. These activities are carried out in close collaboration with existing development organisations such as the Agence de Stimulation Technologique (AST). Also worth mentioning is the contact with industrial members of the Val+ and Plastiwin clusters, as well as joint visits and participation in various trade shows and conferences. 12 Environment and Materials Research Association NANOLAC As part of the NANOLAC project, EMRA research teams are developing high performance PLA-based (polylactic acid) materials in partnership with other Centres. PLA is filled with nanoparticles which endow the PLA matrix with various properties, such as semi-conductivity, fire-resistance, and improved shock resistance. These nanostructured plastics can be melt spun, and the spun product has beneficial anti-bacterial properties which could be of interest in medicine. FRENSIS, THE PARTNERSHIP BETWEEN A LARGE MANUFACTURER AND AN SME The FRENSIS project is supported by AGC and Pierret-System, and combines the skills of a large manufacturer with the expertise of an SME. "Pierret-System", explains Philippe DELVAUX, head of technical approvals at Pierret-System, "has been producing doors and windows in PVC, aluminium, wood and wood-aluminium for nearly 60 years now. Our policy, in terms of research and development, has been focussed, for several years now, on the design of more energy-efficient products. On the Frensis project, we formed a partnership with AGC to design a super-insulating window. AGC deals with the design of the super-insulating window, and PierretSystem deals with the design of a super-insulating window profile system. The end product must be twice as effective as anything currently on the market". This is an ambitious target, which could not be carried out without the help of partners such as EMRA and UMONS' members. 13 Environment and Materials Research Association ENVIRONMENT FOR SUSTAINABLE DEVELOPMENT HELPING TO MAKE THE ENVIRONMENT A HEALTHIER, SAFER PLACE Available technologies, combined with the multidisciplinary experience of researchers and technicians, have made it possible to become involved in R&D projects such as the following, which hold considerable implications for the environment. AIR AND SOIL POLLUTION/REMEDIATION (bio-remediation, valorisation of greenhouse gases, smoke purification, or even the development of monitoring tools, to name a few). EMRA develops projects related to the testing and purification of atmospheric pollution, exposure in the workplace, analysis of ambient air, as well as emissions from materials. ENERGY SAVING, whether through the energy efficiency of processes, energy conservation, energy recovery, the development of insulation materials, or the design of less energy-consuming materials. THE PRODUCT/MATERIALS LIFE CYCLE, by either valorisation or "cradle to cradle" processes. EMRA is involved in the separation and processing of renewable solid materials into "materials" or energy, and also provides assistance in relation to the environmental impact of alternative materials, regardless of their formulation or characterisation. 14 Environment and Materials Research Association Our R&D projects PROJECT NORMACAT Use of REFIOM Materials REFIOMPurification Development of new AFNOR XP B44-13- compliant materials with photocatalytic activity for air purification Use of materials for REFIOM (Résidus d'Épuration des Fumées d'Incinérateur d'Ordures Ménagères - Residues from domestic waste incineration fume purification) Establishment of perennial valorisation channels for REFIOM PARTNERS FUNDING Certech Certified by the AXELERA Cluster CTP, ULB, CRIBC CTP, ULB Convergence VALSOLINDUS Validation and valorisation of integrated and sustainable solutions for sediments and similar materials ISSeP, Carah, CTP, UMons SOLINDUS Integrated sustainable solutions for sediments and similar materials CTP, ISSeP, INISMa, (DG02) PLACAREF Conversion of both pure methane and carbon dioxide, and of their mixtures, into monomers and hydrogen by microwave plasma / heterogeneous catalysis coupling Materia Nova, UMons, UCL, Universidad de Cordoba (Spain) First Doca NOSENS Automobile pollution and atmospheric pollutant detection and measurement UMons, Materia Nova, UCL Greenomat mobilisation programme GEDSET Sustainable management of cross-border sediment ARMINES, BRGM, INERIS, CTP, ISSeP INTERREG IV SENSOPLAST Methodology for the control of mechanisms for the appearance of sensory defects generated by plastic products Certech, Armines Douai MINERVE Characterisation and optimisation of the mineralisation process of buried wastes within engineered landfill sites and uncontrolled dumps, with the aim of reducing the ecological footprint by the valorisation of associated renewable energy (biogas) and residual materials. CTP, UCL, ULg + industrial partnership COLAMIN Simultaneous management of asbestos and other industrial waste based on the development of a mobile crossneutralisation unit CTP, INISMa-CRIBC + industrial partnership GAZTON Transformation of CO2 content in fumes from industrial ovens to a lean gas able to be recycled as fuel for use in the same ovens, through the use of plasma technology powered with green electricity Materia Nova + industrial partnership • • Marshall Plan* Centres : MECATECH, GreenWin, WAGRALIM, BIOWIN Clusters : Val+, MITECH 15 Environment and Materials Research Association HUMIBATI Treatment of rising humidity in buildings. Development of solvent-free products and assessment of their impact on the environment Certech, CSTC PARAGGLO Improvement of filtration systems by agglomeration of fine particles Certech, CRM, CENAERO RECYMELT Valorisation of solid residues from fusion or refining ovens CRM, CTP, CRIBC, GeMMe, ISSeP REVADEC II Optimal valorisation of material flows resulting from the reenabling of old dumps CTP, Certech, CERISIC PICOM Key Collective research Comparative study of testing methods for measuring the photocatalytic activity of construction materials for the removal of NOx and VOCs. The project is part of the establishment of European standard CEN TC 386. BRRC,Certech, Centexbel Normative research Open innovation project aimed at developing a new generation of fuel cells Certech, UCL-EMIC, UlgCIOR, Ulg-LASSC, IT4IP, Nanocyl Marshall Plan projects REFIOM ESTABLISHMENT OF PERENNIAL RENEWAL CHANNELS FOR RESIDUES FROM DOMESTIC WASTE INCINERATION FUME PURIFICATION This research portfolio explores several processes for the valorisation of residues from domestic waste incineration fume purification in the construction materials or hydraulic binding agent sectors. The preliminary stage of cleansing the residues aims to remove pollutant elements or compounds harmful to its intended use. The research therefore also extends to the purification of the water emanating from these cleansing operations. The technology watch and tests carried out have enabled researchers to identify several promising routes for the reuse of these residues, which will allow the tonnage of final waste from incinerators to be significantly reduced. 16 Environment and Materials Research Association NOSENS DEVELOPMENT AND MEASUREMENT OF AUTOMOBILE POLLUTION AND ATMOSPHERIC POLLUTANTS EMRA's partner centres also have expertise in the field of indoor air quality measurement and in the development of specific miniature sensors for NO2, O3 and CO emissions. - - In the field of indoor air quality, specific sampling techniques as well as state-of-the-art chemical and sensory analyses are used to measure emissions from plastic materials, solvents, synthetic products or natural materials involved in construction (floor and wall coverings, paint, varnish, coatings, glue, insulation material, furniture, and so on) as well as transport (seats, dashboards, roof lining, and so on). Miniature sensors developed within EMRA (metallic oxide-based semi-conductors) are selective, highly sensitive, compact, and easily electronically integrated (they have now been upgraded for NO2, CO and O3 detection). With the Nosens project, the EMRA teams are diversifying air quality measurement tools. This project aims to develop a quasi-distributed fibre-optic sensor for detecting nitrogen oxide NO2 in closed environments (tunnels, covered car parks, and so on). This sensor should be able to measure at least ten points on the same fibre and detect concentrations ranging from 0 to 3 mg/m (0 to 1.5 ppm). 17 Environment and Materials Research Association PROCESSES FROM LAB SCALE TO PRE-INDUSTRIALISATION MASTERING THE PROCESSES OF TODAY TO DEVELOP THE MATERIALS OF TOMORROW EMRA's research teams handle many processes and are working on the development of innovative, sustainable technologies in accordance with "materials" and environmental standards. MINERAL PROCESSING TECHNIQUES enable ore and mineral processing patterns to be developed and can also be useful environmentally for valorising secondary raw materials. These techniques, using either dry or wet methods, enable material flows to be prepared for valorisation (crushing, grinding, sorting, sieving, granulometric separation, gravimetric analysis, etc.) REACTIVE EXTRUSION enables plastic materials to be functionalised, grafted and chemically modified, and active fillers or functional additives inserted to create new materials and improve their performance. PROCESS INTENSIFICATION (the use of extreme reaction conditions - very high temperatures and pressures, short reaction time, continuous processes), is a relatively new approach in the chemical industry which reduces the environmental impact of these processes. EMRA carries out research in this domain in order to open up new prospects for companies 18 and enable them to adopt these effective technologies in their chemical and physical operations. PROCESSING OF INORGANIC MATERIALS: EMRA teams handle the various stages of powder, suspension or paste formulation, whether for traditional, technical or refractory ceramics or for glass (including optimisation of the concentration of binding agents, additives, stabilisers and the capacity factor according to the desired properties). These materials are processed by casting, pressing in moulds, extrusion or rapid prototyping. The densification of inorganic materials is carried out either by fusion, traditional sintering or by Spark Plasma Sintering (SPS). COLD PLASMA TECHNOLOGIES: the vacuum deposition of thin films is currently a key technology for use in many industrial operations. Although its industrial use was mainly centred on the development of thin films on glass for many years, there are now various other uses that may be of interest to small and medium-sized enterprises. LASER TECHNOLOGIES make two types of processes possible. A distinction can be made between socalled "additive" processes (by material addition) andso-called "subtractive" processes (by material subtraction). These processes have very varied usages, ranging from decorative or traceability marking to the production of functional layers (wear-resistant, electro-conductive, etc.) including the development of components by additive construction or selective machining. These techniques may be applied to a wide range of materials of various types (metals, ceramics, glass, organic polymers, or composites). Environment and Materials Research Association Our R&D projects PROJECT HOPE4PD Development of new treatments for Parkinson's Disease PARTNERS FUNDING Certech, FUNDP, ULB, Euroscreen, UCB Marshall Plan CoRi, CRM,UMons, INISMa-CRIBC, ULB, Materia Nova RF - CLEARZINC Development of a new anticorrosion process to replace galvanising RF - HAINOLASE Hainaut-based platform dedicated to laser surface treatments CRIBC, UMons, Improving the wear properties of materials by laser treatment CRIBC, UMons, RF-LASESURF SINOPLISSBIOTISS Implementation of innovative processes for biomass valorisation and high added value molecule production. SINOPLISS EXTRUDISS Reactive extrusion: an environmentally compliant process for biomaterial production Materia Nova T-REX-CERAPIDE Industrial validation of an innovative technology for rapid densification by sintering high added value ceramics and cermet products under a pulsed electrical field. CRIBC , CTP, UMons, SIRRIS, T-REX-EQUIDER Spark Plasma Sintering Rapid Densification Equipment CRIBC ECOPOR Environmentally-friendly manufacturing process for ceramic structures of oriented porosity UMons, CRIBC, UVHC (FR), ICV (ESP) Materia Nova, ULB, FUSAGx First Doca SENSCOAT Deposition of thin films of structured metallic oxides by conventional and highly ionised plasma magnetron. Application to chemical microsensors Materia Nova, UMons, Université Rovira i Virgili (ESP) SIMUGLASS Development of a synergistic computational tool for material modelling, process simulation and optimization of optical glass moulding CGCRI, CRIBC, IIT Madras, IIT Delhi, TU lasi / EU contracted DTA, Fraunhofer IPT, industrial partners EDILCO SMARTSPRAY CATARR Electrodeposition in ionic liquid environment for connectors Manufacture of low cost electrochrome windows by ultrasonic pyrolyse spray Use of a catalyser for moderating conditions of molecule production Convergence ULB, Materia Nova FUNDP, INISMa, ULg Materia Nova, UMONS, USTL FP7 - 7th framework programme Greenomat mobilisation programme INTERREG IV 19 Environment and Materials Research Association BARCELONE PHOSBIOL2 PHOENIX RECYSTERIL Complete, new valorisation of wheat bran by fragmentation of the components of an agricultural by-product Production of a second generation of bioethanol from renewable or recycled material by an innovative technology Conversion of carbon grinding residues for metallurgy; Energy valorisation of complex final waste Study into the separation and valorisation of previously decontaminated hospital waste TECHFLAX Development of the non-edible co-products generated by the fractionation of flaxseed HM+ The smarter aircraft: Health Monitoring and Predictive Maintenance OPTI2MAT Developing original new technology for surface treatment and ensuring its conversion to industrial use METEORIT Processing of a powder spraying process for the development of new galvanised products STEELFSW Using the innovative friction stir process in steel welding • • FUNDP, ULg -Gx ABT, CTP, Materia Nova+ industrial partnership Certech, Ulg, GxABT + industrial partner Certech, CRM + industrial partner Marshall Plan* CTP, RECYWALL + industrial partnership Materia Nova, CoRI, CVG, Université de Rouen, Université de Reims + industrial partner CRIBC + industrial partner UMons , Materia Nova RW excellence programme CRM, Materia Nova, CRIBC Collective research CEWAC, CRIBC, IBS, CENAERO Centres : MECATECH, GreenWin, WAGRALIM, BIOWIN Clusters : Val+, MITECH Key projects RF-CLEARZINC The main objective of the Clearzinc project is the development of a new anticorrosion treatment system for steel without applying a zinc coating to it. It plans to find a way to provide durable protection for steel by combining a protective oxide-based surface treatment with corrosion inhibitor reservoirs, incorporated both into the treatment and into a highly reticulated organic coating. The incorporation of reservoirs in the protective layers is completely innovative and enables corrosion inhibitors to be available in places where their presence is essential, particularly when it comes to scratches and gouges, where the exposed metal can therefore be protected. EMRA participates in the development, deposition and characterisation of oxide-based barrier layers: sol-gel coating for manufactured parts and the development of corrosion inhibitor reservoirs. 20 Environment and Materials Research Association T-REX, EQUIDER The EQUIDER (Rapid DEnsification EQUIpment for Spark Plasma Sintering) project is part of the T-REX portfolio. It aims to equip the Mons site with the latest generation of SPS rapid sintering equipment. This is a special uniaxial pressing technique in which stoking is performed by Joule effect after the firing of a high intensity current (several thousand amps for just ten volts) into the pistons and the matrix, but also into the powder to be densified (if it is electrically conductive). This equipment, which is ultimately intended to be used for the benefit of industrial development, consolidates expertise in sintering densification processes and extend the range of services offered to Walloon industries in the ceramics and powder metallurgy sectors. This exceptional equipment was installed in Mons, accepted, and finally put into service successfully at the end of 2011. It is now available to respond to the needs of these industries, who have shown great interest in it. This equipment enables a large number of materials to be sintered up to 2,200°C at speeds of as much as 400°C/min. The equipment consists of two units, the first of which enables samples of a diameter of 20 to 40 mm to be densified under a maximum charge of 100 kN, while the largest unit, which benefits from a hybrid firing system (SPS and resistive heating), enables samples of 80 to 150 mm in diameter to be densified under a maximum charge of 1,250 kN. SINOPLISS-BIOTISS Nowadays, Innovation must include Sustainable Development. Optimising the valorisation of agricultural coproducts and the modernisation of processes are key. Reconciling these aspects with societal and economic challenges is a major issue for the future. The chemical industry has understood this and is increasingly focusing its developments in this direction. It is clear that Plant-based Chemistry occupies a predominant place in this sustainable chemistry (use of renewable resources in order to produce chemical derivatives). One of the major tools of this plant-based chemistry is industrial biotechnology (fermentation and biocatalysis). Intensified processes are another technology which enables high added value molecules to be obtained from biomass. These technologies are complementary to the development of selective processes with low energy requirements. Biomass can be converted into energy, materials or high added value molecules. Over the last few decades, industrial research has been mainly focussed on the conversion of biomass into biodeisel and biofuel. The need for innovation is still considerable, and there is a need to widen and expand the supply of accessible bio-based products in order to meet the needs of the chemical industry in various synthons (organic, aromatic and amino acids and chiral molecules, for example). 21 Environment and Materials Research Association RF-LASESURF As part of the FEDER "Functional Coatings" portfolio, the LASESURF project is centred on the improvement of the wear properties of materials by surface laser treatment. It comprises two sections, the first of which focuses on the study of the deposition of hybrid micro-textured cladding for wear-resistant purposes, while the second section investigates uses of the selective laser sintering technique to obtain functional coatings and/or "Net Shape" ceramic components (without mechanical machining). The LASESURF project thus uses equipment from the HAINOLASE section as part of research aimed at developing the materials and surfaces of the future. PHOENIX ThePhoenixproject, supported by the Walloon Region's Marshall Plan, will enable final grinding waste conversion to liquid hydrocarbons and carbon useful in iron and steel production to become industrialised. Grinding residue contains material as diverse as heterogeneous plastics, rubber, textiles, wood, and foam, to name a few. This process not only avoids putting this type of waste in landfills, but also aims to effectively exploit a new energy source. The end purpose of the project is actually to directly inject these fuels into cogeneration engines for the simultaneous production of electricity and heat. Research work in 2011 has enabled hydrocarbons to be purified by physical and chemical treatment in order to obtain clean fuels which comply with both the mechanical constraints of engines and, at the same time, environmental constraints on atmospheric emissions. In addition to hydrocarbons, the catalytic cracking process also produces a dry, friable solid carbon residue, in which the metals have not been trapped and can be recycled. The valorisation of carbon residue has been studied by the CRM for use in the iron and steel industry, such as for the direct reduction of iron oxides resulting from the treatment of grinding residue. The installation of an experimental unit is a significant step forward in the development of this project. If successful, it should enable an industrial unit capable of valorising 70,000 tons of grinding residue per hour to be put into service in Wallonia, which would produce enough electricity to power 30,000 homes. It should also create about sixty direct jobs. 22 Environment and Materials Research Association SERVICES TO COMPANIES In keeping with their goal to create innovation in business, EMRA teams are tuned in to the industrial world and put their expertise, know-how and technical platforms to work for companies. These services to companies are supported by guidance projects funded by the Walloon region and through SPF-Economie (Standards Department). Its goal, for companies who are in need of scientific or technical expertise, is to set up services which consist of technological audits of process or product-related problems and advice directed towards technological expertise. Guidance is supported by a technology watch, which involves enabling experts to stay continually up-to-date on scientific and technical progress (both in Belgium and abroad) within their fields of expertise that have a high potential for industrial innovation. In 2011, 13 business assistance projects (apart from daily assistance to companies and valorisation) were supported by public funds in order to offer a better service. These projects cover EMRA's three areas of activity (Environment, Processes and Materials) In 2011, 602 companies were supported by EMRA members, half of which are VSEs or SMEs. 12% of companies were supported by at least two EMRA partner centres. Distribution of requests 47 % Materials 36 % Environment 17 % Processes The approved research centres are the preferred point of contact for companies wishing to improve their processes or develop a new product. The business assistance and valorisation projects, subsidised by the Walloon Region, FEDER and SPFEconomie, promote the transfer of skills to companies by providing a technology watch in the relevant field, by supporting the companies in their choices, and by helping them solving technical problems which involve the use of particular technologies. 23 Environment and Materials Research Association PROJECT AIRPOLMA Identification and treatment of pollutants emitted by materials in confined spaces BARRIERE Guidance in the development of barrier materials for use in food and medical packaging Certech, Celabor INORganic materials: CERamics, glass, concrete, minerals CRIBC, INISMa, CTP CERVINOR IMMUNOHELP GUIDEMB Immunochemical guidance service focussing on the production of polyclonal antibodies, the characterisation and the purification of antibodies and ELISA kit Provision of expertise in the food packaging sector, covering aspects of barrier materials, implementation and transformation processes, and methods for improving foodstuff preservation MATSOLID Treatment of primary and secondary SOLID MATerials POLYMERE Development and formulation of special polymer materials REVETACT Guidance on active coatings VALODECH Valorisation of industrial waste SOLERO WALLREACH PRISTIMAT Technical support for the integrated management of environmental impacts (SOIL, AIR, WATER) Guidance on REACH regulations Technology watch and promotion concerning materials for uses in medicine and transport (roadmap and coordination actions) Certech, CER Certech, Celabor CTP Walloon Region Certech CRM, CoRI, Materia Nova RECYWALL, CRR, CTP CEBEDEAU, CTP, INISMa-CRIBC, CEWAC, CELABOR, Certech CER, Certech, Materia Nova CEBEDEAU INISMa, CRITTMDTS, SIRRIS, UPJV, UVHC - LMCPA Establishment of continual valorisation systems for residues from domestic waste incineration fume purification (REFIOM) SOLINDUS (valorisation) Integrated and sustainable solutions for sediments and similar materials (valorisation section) CTP, ISSeP, INISMa, (DG02) T-REX PROM Promotion of technological services available as part of the T REX and Functional Coatings portfolios INISMa, CRIBC Promoting and raising awareness of standards and technical rules. FUNDING Certech REFIOM (valorisation) Standards Department 2011 24 PARTNERS Interreg IV CTP, CRIBC CRIBC RF - VALOMAT To reinforce the integrated and structuring effect of the FUNCTIONAL COATINGS project portfolio Materia Nova SINOPLISS VALORISS To reinforce the integrated and structuring effect of the SINOPLISS project portfolio Materia Nova Convergence NBN Environment and Materials Research Association Technology cheques Available since 1st January 2009, the Technology Cheque is a financial assistance tool for SMEs seeking technological expertise on a specific topic. This assistance may be in relation to any of the following: preliminary testing, calculations and analysis, carrying out all or part of the design and/or adaptation of products, processes or services, or the resolution of technical problems related to the quality and compliance of newly-developed products, processes and services. In 2011, for EMRA... 421 technology cheques 38 companies involved Tax credit Research TECHNOLOGY CHEQUES GOOD TO KNOW: Who can benefit from them? Any SME who is established as a trading company and has its headquarters in Wallonia. Who needs to pay what? Each Technology Cheque has a face value of 500€ (up to a maximum of 20,000€ per year). The company only has to pay 25% of its value, and the other 75% is covered by the RW and FEDER. What can the cheques be used for? The technology cheques can be used on services provided by accredited Research Centres in partnership with a Belgian higher education institute from the French-speaking community. Who organises it all? The AST (Agence de Stimulation Technologique) via a web interface: www.innovons.be tax credit (France) In the European era, the EMRA members cannot allow their activities to be limited to just Belgian territory. It is in this spirit that they requested and obtained French research tax credit approval for all of their activities. 25 Environment and Materials Research Association STUDIES & TESTS Labels/Standardisation The expertise of EMRA members is acknowledged by standardisation offices and for conducting product trials/tests as part of certification processes. Expertise: - Development of European "Air Quality" Standard EN13725 - "Measurement of odour concentration using dynamic olfactometry" - ISO 16000 "Indoor Air" standards. EMRA is currently involved on various committees. - Development of quality labels related to agrosourced products (via AIB-Vinçotte). And more... - EMRA has a role as a "Standards Department for Ceramics and Glass", awarded and funded by SPF-Economie in order to raise awareness of standards in SMEs in the ceramics, nanotechnology and glass sectors. - - - The Centre is also involved in various standards committees (CEN & ISO) relating to these sectors. In 2011, EMRA started procedures for obtaining approval from the Walloon Region for waste analysis. EMRA is VCA certified for those of its building site activities that require it. Benor "Compliance label" for construction products in Belgium. Vinçotte EMRA is approved by AIB-Vinçotte for OK-compost quality labelling http://www.okcompost.be BQA: Belgian Quality Association System and environment certification body accredited by BELAC. EMRA provided this association with the sector's leading auditors for carrying out quality (ISO 9000) and environmental (ISO 14001 and EMAS) audits. http://www.bqa.be ICG : International Commission on Glass International association bringing together companies with scientific and technological activities in the glass sector. EMRA is the Belgian representative for this association and actively participates on technical committees 2 and 10 (Chemistry and Optical). IMPC: International Mineral Processing Congress The aim of the IMPC is the regular organisation of world mineral processing conferences. EMRA is the Belgian representative on the Advisory Committee. www.impc2010.org 26 Environment and Materials Research Association CEN : European Committee for Standardisation Through these services, it provides a platform for the development of European standards and other technical specifications. EMRA is present and active on TC129, 187 & 352. www.cen.eu ISO (The International Organization for Standardization) is the world's largest developer of voluntary international standards. EMRA is participating in work on TC206. www.iso.org CE: The "CE" mark indicates a product's conformity with European Community requirements for manufacturers. The "Glass and Components" department is the recognised body for marking (Id.No.1174) according to article 18 of the Construction Products Directive CPD 89/106/EEC AMECA : Automotive Manufacturers Equipment Compliance Agency Inc. (USA) The "Glass and Components" department is an AMECA accreditation laboratory for car windscreen approval tests. The "Glass and Components" department is a sub-contracted laboratory for AIB Vinçotte International for the car windscreen sector. Belgian Union for Technical Approval of Construction: The UBA is the technical approvals institution for construction materials, products, and systems and for installers in Belgium. The "Glass and Components" department is a sub-contracted laboratory for UBAtc for the windows for buildings sector. 27 Environment and Materials Research Association Fields of expertise You have an idea, and you want to carry out feasibility studies? Do you have to carry out tests and measurements? Whatever it may be, our experts are here for you. EMRA carries out tests, analysis and expert reports on work in various fields, using experienced teams with state-of-the-art laboratories and a stock of high-performance equipment. Efficient coordination of the various departments enables them to maintain and develop an essential asset for their work in industry: the capacity to offer a comprehensive solution to their needs or isolated problems. Particular attention is also paid to the timescale for the carrying out of services, the quality of which is objectified and guaranteed by ISO 9001 certification, as well as ISO 17025 accreditation for their ever-expanding range of tests. MATERIALS Physical and Chemical Analysis Services are designed to respond to requests for analysis, characterisation and tests on the various EMRA sites, and also to deal entirely objectively with scientific and technical expertise assignments. Our organisation affords us a high degree of reactivity and the true ability to adapt to any given problem. The wide range of analysis and chemical characterisation technologies available to the laboratories (such as induced plasma spectrometry (ICP), X-ray fluorescence (XRF), scanning electron microscopy coupled with EDS and WDS, UV-Visible spectrophotometry, mercury analysis, ionic chromatography, TEM, XPS, etc.) enables us to fulfil analysis needs for all types of inorganic, mineral and polymer materials. Part of the chemical analysis is ISO 17025 accredited. Our laboratories also offer a wide range of physical characterisations of materials and matter, including: STRUCTURAL AND TEXTURAL CHARACTERISATION: micrography (SEM), granulometry (sedigraphy, laser, optical morphology analysis), porosimetry, rugosimetry, permeability measuring (Blaine), zeta potential measuring. MECHANICAL AND THERMOMECHANICAL CHARACTERISATION: flexion, compression and traction, elasticity module, wear, hardness and creep measurement. THERMIC CHARACTERISATION: dilatometry, conductivity, resistance, thermogravimetry, diffusivity, calorimetry, thermal shock, drying monitoring, etc. MINERALOGICAL CHARACTERISATION: petrography via polarising optical microscope, stereo-microscopy, DRX (including high temperature scanning), sample preparation technique including a thin slide grinding machine. 28 CHARACTERISATION OF RHEOLOGICAL BEHAVIOUR: electrophoretic mobility, suspension rheometry (viscosity, creep, fatigue according to frequency), ceramic pastes and concretes, measurement of concrete consistency and monitoring of setting times (VICAT needle, exothermic profile, ultrasound), electrical conductivity, capillary rheometry for ceramic pastes, turbidimetry, rheometry and high temperature viscosity measurement (melted materials). Environment and Materials Research Association WINDOWS AND COMPONENTS A specialist team at the Mons site carries out specific tests on glass products, such as approval and certification tests on windows for buildings (including their various components — mastics and desicants), initial tests for CE marking, production follow-up, approval of car windscreens and motorcycle helmet visors, climatic and UV ageing, railway equipment, analysis of the nature and quality of gas for filling double glazing, the identification of bubbles in glass, and optical characterisation of glass (colour, refraction indices, etc.). OPTICAL CHARACTERISATION: UV-Visible transmission and reflection, refraction and emissivity index measurement, colour measurement. INSPECTION OF MATERIAL ODOURS EMRA has the expertise to measure the emission of odours from materials, and also to propose solutions to mitigate these emissions. CHARACTERISATION OF SURFACES Equipped with an exceptional technological platform (XPS, TOF-SIMs, SEM-EDX, etc.) for the analysis and profilometry of thin films, EMRA teams support companies in the development of new formulations or assist them with the detection of trace elements (pollutants, drugs), measurements of light elements (C, O, N), quantitatively, differentiating several states of oxidation of the same element, analysis of insulation (glass, polymers, ceramics), and detecting surface flaws or surface contaminations. THE DURABILITY OF SURFACE TREATMENTS MECHANICAL AND TRIBOLOGICAL CHARACTERISATION of coatings (micro and nano scratch test, nano hardness, wear, etc.) The teams assess the corrosion-resistance of metallic materials with or without protective coatings (temporary or permanent), simulate industrial or urban environments by means of an artificial atmosphere containing sulphur dioxide, carry out condensation resistance tests on uncoated metallic materials (for resistance to corrosion) or in the presence of an organic coating (for resistance to blistering, etc.), or even simulate the weathering of materials exposed to sunlight (Xenotest). These studies are coupled with electrochemical techniques in order to understand the alteration mechanisms of surface treatments. CONSTRUCTION EMRA has two "Construction" departments; one in Mons, and the other in Bertrix. These two entities carry out a number of specialist tests in the laboratory and on site for the building and road materials sector, such as ballast, hydrocarbons, earthenware materials (bricks and tiles), concrete, slates, and so on. THE COMPOSITION OF PLASTIC MATERIALS Equipped with their high-performance analytical tools, the teams have an in-depth knowledge of materials and are active in the deformulation of plastic materials, such as the determination of the chemical composition of resins and polymers, additives and the identification of fillers. 29 Environment and Materials Research Association Expertise Our experts offer their assistance on subjects as diverse as: manufacturing defects, usage problems, the origin of premature ageing, interactions between materials and the environment, the identification of defects of mechanical and chemical origin, or aesthetic problems, and have extended their range of services to include the simulation of materials behaviour. Our expertise is particularly centred on: Faults in bricks, tiles or ceramic tiles (efflorescence, marks, abnormal wear, lustre, etc.) The choice of refractory materials and analysis of behaviour during operation, as well as research in to the causes of malfunction. Analysis of defects in glass products, identification of their origin (inclusions, stones, threads, bubbles, etc.) and breakage diagnosis. Identification of the origin of glass fragments recovered in the case of accidental contamination of commercial products (food production, pharmaceuticals, etc.) Problems raised by engineering offices concerning soil stability in view of the construction of buildings or civil engineering structures or for developing refractory linings Inspection of breaks in materials (ceramics, glass, metals, etc.) The highlighting of the use of accelerants in "deliberate" fires The examination of corrosion phenomena in piping and other metallic parts The presence and identification of asbestos in materials Assistance with the design of parts, parametric design optimisation from a thermo-mechanical point of view through use of a template, and reverse engineering of parts by the establishment of a sintering template, and so on. Inspection of thermic treatment tools (oven, drier, casting ladle, etc.) by infra-red camera ENVIRONMENT Valorisation of solid matter Some solid materials, such as mineral waste or industrial by-products, are rarely valorisable as they occur at the location where they are produced. EMRA's partner centres (with the support of RECYWALL – www.recywall.be) have a large stock of equipment which enables them to offer integrated solutions for the valorisation of these materials towards materials and energy. The technologies and expertise developed by our teams produce reliable, environmentally and economically viable solutions. Physical or chemical characterisation of byproducts and waste Separation of solids into valorisable parts Treatment of solids Transformation to materials or energy 30 In 2011, EMRA started procedures for obtaining approval from the Walloon Region for waste analysis. Environment and Materials Research Association Soil analysis EMRA's experts carry out sampling, analysis and consultancy for industry related to the remediation of contaminated land. The experts continually monitor Walloon, Belgian or international regulations. This activity is extended to water and air as part of a guidance project through a partnership of several centres. As part of their participation in ACENIS, 38 sites were drilled for environmental samples in 2011. Activities relating to soil surveys also involve geotechnical surveys. In 2011, the Mons and Bertrix sites also managed 438 geotechnical dossiers from the construction and civil engineering sectors. Several sites were surveyed for the private sector (architects, individuals, contractors, engineering and design offices, etc.) and for the public sector (authorities, local councils, etc.). Air analysis EMRA takes samples and measurements and makes analyses on-line (for noise, odours, gas discharge). The environmental impact is assessed by means of atmospheric dispersal simulations and assessment of the immediate neighbourhood. Assessment of performance of purification units and advice on processes are also offered. Customers have come from various industrial sectors, such as cement, glassmaking, incineration, chemical industries, and so on. Supported by a guidance project, EMRA services also include the analysis and treatment of pollutants emitted by materials in confined spaces. SOLINDUS platform Semi-industrial experimental centre for the treatment of sediments As part of the SOLINDUS (Integrated and sustainable solutions for sediments and similar materials) project portfolio, EMRA and partner ISSeP aim to apply a mineral processing approach to the treatment of dredging products and similar materials. This approach has already been used and proven in several countries for environmental uses, such as the decontamination of sediments. In this context, contaminated sediments are similar to a low value ore from which adverse elements must be removed. The mineral processing approach is beneficial, as these processes are generally based on relatively simple physical and/or physico-chemical principles. In general, these methods are among the least expensive to employ (compared to thermal or chemical extraction or destruction). Besides their simplicity and their moderate operating costs, these technologies do not lead to the formation of new, potentially toxic or dangerous by-products, and therefore are of great interest environmentally. 31 Environment and Materials Research Association From a scientific standpoint, the activities in the SOLINDUS project portfolio may be divided into four parts: 1. Characterisation (physico-chemical) of input and output materials and flows, 2. Selection of the most suitable equipment for the intended Walloon guidelines for the mineral processing treatment of sediment, with optimisation of operating conditions, 3. Validation of each treatment stage on the minipilot scale (100 kg/h of dry material) and its extrapolation on the scale of the experimental platform (1 t/h of dry material), 4. Research and assessment of inerting and/or valorisation paths for each of the output flows, according to their characteristics and volume. A pilot scale experimental platform capable of dealing with 1.0 to 1.5 m³/h is in its initial phase. This platform is situated in Châtelet, on land provided by the DGO2 - Direction des Recherches Hydrauliques, in a building with an area of 700 m². This exceptional equipment aims to validate the hypothesis of mineralurgical processing of sedimentary material derived from dredging operations on a semi-industrial scale. The dimensioning was carried out on the basis of experimental results obtained on the Tournai site, at the laboratory scale and then at the pilot scale over the last three years. PROCESSES Food barrier/packaging properties With experimental equipment for drying, mixing, granulation, extrusion, co-extrusion and injection moulding, the EMRA teams, in partnership with other agronomic research centres, are helping companies with the development of food packaging. Highly flexible equipment has been designed to simulate industrial transformation processes, such as the composition and co-extrusion of films. They are also used for the extrusion of tubes, insulation of wire, injection moulding and the preparation of nanocomposites. Output ranges are available from 5g to a few hundred kg of processed material. Surface treatments EMRA has expertise in the development of active coatings, whether by wet process, electrodeposition by dry process (plasma), or by laser. These active coatings are applied to any type of 32 surface (plastic, glass or metal). EMRA teams work from laboratory scale to pilot scale. These coatings, in the form of colloidal suspensions or sol-gel, are applied by dip-coating, spin-coating, spray, serigraphy or printing (inkjet). Environment and Materials Research Association Pilot halls MINERAL PROCESSING The pilot hall (over 5,000 m²) has brought together numerous pieces of equipment at laboratory and pilot scale, enabling matter to be mineralurgically treated and packaged, and materials to be processed. Highly sophisticated consolidation techniques such as hot pressing (uniaxial and isostatic) and SPS as well as various cold processing techniques (uniaxial and isostatic pressing, extruding, casting, etc.) are also provided on the Mons site. On the Tournai site, mineralurgical equipment enabling granulometric, gravimetric, electrostatic, Foucault current, physico-chemical (flotation), mechanical process or solid/liquid separations, is available to companies for their process development studies as well as a wide range of shredders, crushers, granulators (including spraydryers) and grinders including an autogenous crusher which enables a grinding-drying processing loop to be achieved at pilot scale. Various ovens and kilns (muffle furnace, rotary kiln.) are available for thermal treatment. POLYMERS On 2 May 2011, EMRA opened a new pilot hall on its Seneffe site. Various equipment for the development of plastic materials and catalytic pyrolysis units enable industrial simulations to be carried out in recycling, waste processing, and the use of renewable materials. Laser technology "Engrave a name on a base the size of a hair or carve a ceramic tooth in a few minutes: these are the types of tasks that Hainolase, a research centre established in Mons, can accomplish. The possibilities of offering laser cutting in the 'new materials' sector are being explored. The goal is to be able to offer the results of this research to companies in Wallonia, and thus develop a new and innovative way to do business.” TéléMB 22/11/2011 The Hainolase technological platform enables: 3D (5 axes) machining, laser microtexturation, laser marking/deposition, multi-material and multilayer ink-jet printing, cutting/drilling, laser cladding, rapid prototyping by selective laser 3D sintering/melting (SLS-SLM) for micromechanics usage, biomedicine, electronics, decoration, and more. 33 Environment and Materials Research Association Semi-industrial scale extrusion EMRA teams have a technological platform dedicated to extrusion, ranging from mini to semiindustrial scale. The entire stock of machines is made up of extruders capable not only of developing plastic materials, but also of carrying out reactive extrusion. Thermal processing EMRA is equipped with thermal processing tools developed over a variety of products ranging from granulated to powdery. Our expertise in thermal processing is focussed around a thermogravimetric measurement device (ATG-DTA) coupled with a gas analyser, stoves and muffle furnaces, a melting furncace, and pilot and laboratory-sized direct and indirect heat rotary ovens. It also covers thermal desorption tests as well as tests on calcination, decarbonation, alteration of chemical composition, intra crystalline phase change as a function of thermal processing, or quite simply drying to order. 34 Environment and Materials Research Association WE PARTICIPATE IN Accord-Wallonie asbl R&D forces in Wallonia http://www.accord-wallonie.be BCerS asbl – ECerS – JECS Trust The Belgian Ceramic Society (BCerS): Belgian society of scientists and manufacturers of the ceramics sector. http://www.bcers.be BElgian Solid Waste Association http://www.beswa.be Centre of competitive excellence: Creation development eco-friendly enterprises http://www.cd2e.com/panel_accueil MITECH cluster Micro-Technology cluster for Intelligent Manufacturing & Products http://clusters.wallonie.be/mitech/fr/contact.html Val+ cluster (solid waste) The VAL+ cluster brings together active players in the treatment of waste http://clusters.wallonie.be/dechetssolides/fr/ The European Federation of Chemical Engineering www.efce.info Le Groupement d'Intérêt Scientifique Sites, Sols et Sédiments Pollués www.gis3sp.fr Groupement Belge de l'Énergie Explosive This group brings together all players involved in the use of explosives. www.gbee.be Société de l'industrie minérale (Sim) The promotion and dissemination of scientific and technical knowledge on mineral matter. www.lasim.org 35 Environment and Materials Research Association UCRC Union des Centres de Recherche Collective http://www.centexbel.be/ucrc/ Vlaamse Overkoepelende Organisatie van Technologieverstrekkers This non-profit organisation supports the organisational collaboration of 18 scientific and technological innovation centres and contributes to give substance, in the field, to the government's innovation policy. http://www.vloot.be Union Wallonne des Entreprises www.uwe.be Plastiwin Walloon cluster bringing together active players in the plastics processing sector http://clusters.wallonie.be/plastiwin/fr TWEED cluster Walloon energy technology - Environment and sustainable development http://clusters.wallonie.be/tweed/fr GFES French Carbon Research Group http://www.gfec.net/ GFP French Polymer Group http://www.gfp.asso.fr/ VOM Belgian surface treatments association http://www.vom.be/ GIS- Surface Scientific interest grouping in the surface treatments sector http://www.gis-surfaces.be/ TEAM centre French centre ("Technologies de l’environnement appliquées aux matériaux" - Environmental technologies applied to materials) dedicated to waste valorisation. UP-TEX Centre French centre of collective excellence bringing together textile players http://www.up-tex.fr/ 36 Environment and Materials Research Association IAR centre French centre of competitive excellence, partnership of industries and agro-resources http://www.iar-pole.com MECATECH centre Walloon centre of competitive excellence in mechanical engineering http://www.polemecatech.be Greenwin centre Walloon centre of competitive excellence: accelerator of innovation in environmental technology http://www.greenwin.be/ BioWin centre Walloon centre of competitive excellence in health http://www.biowin.org/biowin/fr/5408-home.html Wagralim centre Walloon centre of competitive excellence in agro-industry http://www.wagralim.be/ French centre of competitive excellence in plastics processing http://www.plastipolis.fr/ European technology platform for Sustainable Chemistry http://www.suschem.org/ Belgian Royal Society of Chemistry http://www.src.be/ Belgian Polymer Group http://www.belgianpolymergroup.be/ GN-MEBA National scanning electron microscope and microanalysis group http://mr.gnmeba.free.fr/index.htm 37 Environment and Materials Research Association WE ARE STAKEHOLDERS IN ACENIS SCRL Sole point of contact for meeting needs related to the characterisation of soil and subsoil contamination (including underground water) and the remediation to be applied. http://www.acenis.be LABOMOSAN SA Labomosan carries out the majority of tests, either in the laboratory and on site, needed before, during and after production to ensure that all building, civil engineering structures and road construction projects are carried out properly or under its supervision. Labotour SA The specialist in characterisation of road and construction products http://www.labotour.com/ Lasedesign SA Specialist in enamel laser sintering for the purpose of marking, personalising or functionalising objects and substrates of any kind. http://www.lase-design.be/ Mineral X Real estate company with a view to expanding the CTP's real estate. NaNo4 Company working in the synthesis of organic nanocomposites to order VALORE Company working in the production and marketing of formulated speciality products. RECYWALL Economic interest group (registered office: Mons site). The group brings together 8 research centres created by the following industrial sectors: Wood (CTIB), Ceramics and Glass (CRIBC-INISMa), Construction (CSTC), Roads (CRR), Metal manufacture (SIRRIS), Organic coatings (CoRI), Textiles (Centexbel). The purpose of this group, both in Belgium and abroad, is to carry out any operation relating to the research, study and execution of projects in the field of waste, recycling and recovery, as well as the use of matter or materials, without limits as to the technologies used. 38 Environment and Materials Research Association MEETINGS AND COUNCILS UMons FIB Services NGK Ceramics Europe Lebailly Fedicer/Wienerberger PPConsulting Guests Conti Di Loreto Wauters De Bruycker Willain Patte Eeckman Cambier Calogero Osvaldo André Daniel Bernard Pierre Jean-Pierre Francis Vice-Chairman Chairman Board of Directors General Meeting INS Honorary Chairman Managing Director Ceramag Keramo Steinzeug Megaceram NCA Technologies Neoceram Pottelberg Tuileries du Hainaut (TDH) CRIBC Council Guests Wienerberger Bricks NGK Ceramics Europe Service Public de Wallonie DGO6 Belref Lebailly SA Keramo Steinzeug FGTB Pottelberg IWT - Vlaams Gewest FIB Services - PPC CSC Mons-La Louvière Vesuvius Belgium nv Wienerberger Bricks NGK Ceramics Europe Wauters De Nooze Di Loreto André Alain Osvaldo Collette Lemaire Willain Cambier Eeckman Chambart Dewitte Renaud Michel Bernard Francis Jean-Pierre Hilde Carine Gillin Humblet Jonniaux Jorissen Lootens Maertens Otte Patte Urbain Van Belle Van der Biest Veys Alain Florence Henri Chris Paul Michael Dirk Pierre Jean-Marc Rony Johan Jean-Noël Chairman Manufacturers x Permanent committee NGK Ceramics Europe FGTB FIB Services SPF Economie, SME, Classes Moyennes Neoceram Tuileries du Hainaut (TDH) x x x Managing Director Honorary Chairman x x x x x x x x x INISMa 39 Environment and Materials Research Association 40 De Haan Wauters Conti Deridder Di Loreto Escarmelle Lazzaroni Lemaire Patte Rennotte Snyders Van de Neste Willain André André Calogero Roland Osvaldo Jean-François Roberto Michel Pierre Jacques Rony Marc Bernard Chairman Vice-Chairman Gillin Alain Observer Cambier Damman De Nooze Delaunois Dubois Lybaert Sakas Francis Pascal Alain Fabienne Philippe Paul Achille Managing Director x Co-opted x x x x Co-opted x x Board of Directors General Meeting Manufacturers UMons-FPMs NGK Ceramics Europe/INS UMons FIV FIB Services/INS IDEA UMons Neoceram PPConsulting/INS Yara/IDEA UMons AGC Glass Europe Tuileries du Hainaut (TDH)/INS Service Public de Wallonie DGO6 Guest UMons FGTB /IDEA UMons-FPMs UMons UMons-FPMs IDEA Environment and Materials Research Association CTP UCL IDETA UMONS ULB Guest Service Public de Wallonie - DGO6 General Meeting UCL IDETA ALC UMONS ULB Pierre Daniel Jean-François Michel Michel Jean-Pierre Laurent Philippe Pierre Serge Marc Stéphane Villers Pierre Duquesne Laduron Lucion Thimus Mercier Dumortier Delbar Luyten Seynhaeve Vandewattyne Begin Busquin Calozet Bodson Polet Boucher Roggeman Xavier Dominique Christian Jean-François Daniel Armel Gonzague Philippe Frédéric Pierre Alain Philippe Michel Michel Jean-Pierre Serge Yves Manufacturers x Chairman Secretary/Treasurer Vice-Chairman x x x x x Board of Directors ALC Germain Mercier Thimus Bodson Lerat Polet Dupont Luyten Vandewattyne Boucher Degrez Neirynck Managing Director Observer Chairman Vice-Chairman Secretary/Treasurer 41 Environment and Materials Research Association MATERIA NOVA Manufacturers ESE Vandeputte Oleochemicals AFTA Descy Vandeputte Clavareau* Galactic Bogaert General Meeting IMBC Politique Scientifique Fédérale ULB ArcelorMittal Cosucra Groupe Warcoing AGC Flat Glass Europe Total Petrochemicals Guest Service Public de Wallonie DGO6 ULB Idea Igretec Hoccinvest UMons UMons Ideta Mettens Philippe Di Stefano Beguin Crahay Van de Neste Maziers Langer Patrick Michel Jean Marc Eric Luc Villers Pierre Roggeman Escarmelle Debois Pattyn Delaunois Olivier Vandewattyne Yves Jean-François Marc Dominique Fabienne Marjorie Pierre x x x x Chairman Board of Directors UMons Conti Lybaert Dubois Vince Belle Gilbert Luc Guy JeanChristophe Calogero Paul Philippe Dany Jean-Sebastien Vice-Chairman x x x x Observer * Since the creation of Materia Nova, a close and continual collaboration was established with Mr Guy Clavareau. On 8 June 2006, he joined the Board of Directors. On 2 October 2011, he died after a long illness. We will not forget the support he gave us over the years. 42 Environment and Materials Research Association CERTECH Manufacturers Bourgmestre Seneffe Total Umicore Veolia Nanocyl Arcelor Mittal MacTac Grando François Benoit Christian Thomas Eric Yves-Jacques Nathalie Philippe Guy Egbert David Francis Michel Carine Yves May Henry Randoux Thierry Villers Pierre Durieux Philippe Guests Service Public de Wallonie DGO6 Sopartec Chairman Board of Directors General Meeting UCL Blondel Macq Bailly Pardoen Gaigneaux Schneider Burteau Busquin Debras Lox Benanou Massin Beguin Lefevre Charlier x x x x x x x Managing Director of Certech until 29 February 2012 Managing Director of Certech since 1st March 2012 Observer 43 Environment and Materials Research Association PUBLICATIONS • "La photocatalyse: dépollution de l’eau ou de l’air et matériaux autonettoyants" [Guillard Ch, Kartheuser B, Lacombe S] ; Techniques de l’Ingénieur; Ref J1270, 10 November 2011 • "Hygiène industrielle, bien-être au travail: les chèques technologiques au service des PME", [Moro S and Pacary T.]PMEKMO 300, page 62 (2011) • "Limites de rejets et d’exposition des composés organiques volatils", [Collignon F., MoroS.,. Lalande D., Kartheuser B. and Pacary T.] ; Monthly gazette of the Belgian association of metal surface treatments, June, pages 8-12 (2011) • "Chitosan physico–chemical properties modulate defense responses and resistance in tobacco plants against the oomycete Phytophthora nicotianae", [Falcón-Rodríguez A.B., Costales D., Cabrera J.C., Martínez-Téllez M.A.]; Pesticide Biochemistry and Physiology; 100: 221–228, 2011 • "The removal of organic matter and heavy metals of fine dredging sludge fractions by froth flotation", [Descamps Ph., Chantry G. , Grymonprez B., Lucion Ch. ], International Symposium on Sediment Management, p. 289-296 (2011) • "Déchets ménagers, déchets verts et boues de STEP" (in part), [Dupont L. and Lucion Ch.], Le Recyclage, vol. 2, Société de l'Industrie Minérale, 53-77 (2011). • "Sédiments portuaires et de canaux – Projets de recherche du C.T.P. sur les sédiments des canaux" (partie d'ouvrage), [Lucion Ch. and Laboudigue A.], Le Recyclage, vol. 2, Société de l'Industrie Minérale 270-277 (2011). • "Technologie de revalidation d'anciennes décharges", [Chantry G., Koller E., Hubaux P., Lucion Ch., Lalande D. ], Recyclage & Valorisation n° 32, 38-47 (2011) • "La Préparation des Matériaux Mous", [Jadin A.] ; Préparation des Echantillons pour MEB et Microanalyses , EDP-Sciences, 187-196 Paris (2011) • "Estimation de l’efficacité et de la durabilité par vieillissement naturel des produits protecteurs de la pierre: le programme HYBRIPROTECH", [Eyssautier-Chuine S. , Fronteau G., Gommeaux M., Thomachotschneider C. and Michaud G.] ; Matériaux & Techniques, 99 5 547-553, (2011) • "Laser frequency combs and ultracold neutrons to probe braneworlds through stimulated matter swapping between branes", [Sarrazin M., Petit F.]; Physical Review D 83, 035009 (2011) • "Preliminary study on suspension plasma sprayed ZrO2+8wt% Y2O3 coatings", [Kozerski S., Latka L., Pawlowski L., Cernuschi F., Petit F., Pierlot C., Podlesak H.]; Journal of the European Ceramic Society 31 2089–2098, (2011) • "Photooxidation of polylactide/calcium sulfate composites", [Gardette M., Therias S., Gardette J.L., Murariu M., Dubois Ph.], Polym. Degrad. Stab., 96, 616-623, (2011) • "Thermal degradation of poly(L-lactide): accelerating effect of residual DBU-based organic catalysts", [Raquez J.M., Barone D.T.-J., Luklinska Z., Persenaire O., Belayew A., Eyckmans J., Schrooten J., Dubois Ph.], Biomacromolecules, 12, 692-700, (2011) • "Universality and percolation in biodegradable poly(epsilo-caprolactone)/multi-wall carbon nanotube nanocomposites from broadband AC and DC conductivity at various temperatures", [Lerari D., Peeterbroeck S., Benali S., Benaboura A., Dubois Ph.], L. Appl. Polym. Sci., 121, 1355-1364, (2011) • "Organocatalytic synthesis and post-polymerisation functionalization of allyl-functional poly(carbonates)", [Bello A., Laredo E., Marval J., Grimau M., Arnal M.L., Muller A.J., Ruelle B., Dubois Ph.]; Macromolecules, 44, 2819-2828, (2011) 44 Environment and Materials Research Association • "High performance polylactide/ZnO nanocomposites designed for films and fibers with special end-use properties", [Murariu M., Doumbia A., Bonnaud L., Dechief A-L., Paint Y., Ferreira M., Campagne C., Devaux E., Dubois Ph.], Biomacromolecules, 12, 1761-1771, (2011) • "Surface and fouling release properties of silicone/organomodified montmorillonite coatings" [Beigbeder A., Labruyere C. Viville P., Pettit M. E., Callow M. E., Callow J. A., Bonnaud L., Lazzaroni R., Dubois Ph., J. Adhes.]; Sci. Tech., 25, 1689-1700, (2011) • "Study of the effect of nanoclay incorporation on the rheological properties and corrosion protection by a silane layer", [Olivier M.-G., Fedel M., Sciamanna V., Vandermiers C., Motte C., Poelman M., Deflorian F. ]; Progress in Organic Coatings 72, 15-20, (2011) • "Electrochemical study of the corrosion behaviour at the edges of electrocoated steel", [Poelman M., Recloux I. , Cornil N., Blandin N., Deronne L., LeDisert Y., Olivier M.-G. ]; Progress in Organic Coatings, in press • "Improvement of corrosion protection offered to galvanized steel by incorporation of lanthanide modified nanoclays in silane layer", [Motte , C. Poelman M. , Roobroeck A., Fedel M., Deflorian F., Olivier M.-G.]; Progress in Organic Coatings, in press • "Mild steel corrosion in chloride environment: effect of surface preparation and influence of inorganic inhibitors", [Atmani F., Lahem D., Poelman M., Buess-Herman C., Olivier M.-G.] Corrosion Engineering Science and Technology • "Synergistic improvement of the inhibitive activity of dicarboxylates in preventing mild steel corrosion in neutral aqueous solution" [D. Lahem, M. Poelman, F. Atmani, M.-G. Olivier]; Corrosion Engineering Science and Technology • " Les plastiques biodégradables dans l’emballage alimentaire, Food Science and Law", [Talon O.]; pages 6, 7-11 (2011) • " Biocomposites based on flax short fibres and linseed oil, Industrial Crops and Products » [Lazko J, Dupré B., Dheilly R-M., Quéneudec M] ; 33: 317–324 (2011) • "Fire Retardancy of Multiphase Polymer Systems, Handbook of Multiphase Polymer Systems", [Ferriol M., Laoutid F., Lopez-Cuesta J-M; Eds A. Boudenne, L. Ibos, Y. Candau and Sabu Thomas] Publisher Wiley – Blackwell : 843–864 (2011) • "Récupération par cyanuration des métaux précieux contenus dans les cartes électroniques de téléphones portables", [de la Torre E., Espinoza S., Guevara A., Lucion Ch.], Recyclage et Valorisation n°34, 56-60 (2011) • "Quelques techniques minéralurgiques applicables au traitement des sédiments", [Koller M-M., Pereira F., Lucion Ch.] ; Mines & carrières, n° 181 Hors-série, 38-44 (mai 2011) • "Recyclage, par voie pyrométallurgique, de l'aluminium contenu dans divers déchets industriels et électroniques", [de la Torre E., Espinoza S., Guevara A., Lucion Ch. ], Recyclage et Valorisation n°34, 48-55 (2011) • "Traitement automatique des DEEE par séparations minéralurgiques", [Lucion Ch. , Hubaux P., Touzé S. , Save M. ], Recyclage et Valorisation n°34, 42-47 (2011) • "MSWI boiler fly ashes : magnetic separation for material recovery", [De Boom A., Degrez M., Hubaux P., Lucion Ch.], Waste Management n°31, 1505-1513 (2011) • "Prélèvements d'échantillons" (partie d'ouvrage), [Lucion Ch. ], Le Recyclage, vol. 2, Société de l'Industrie Minérale, 35-50 (2011) 45 Environment and Materials Research Association • "A new way to improve thermal capacities of lubricants for manufacturing flint glass perfume bottles Part A : How to combine thermal analysis and physicochemical observations at glass/punch interface" [Moreau P, Lochegnies D, Kermel C, Carpentier J.-M., Vivier H.] ; New Journal of Glass and Ceramics, 1, 7991 (2011) • "A new way to improve thermal capacities of lubricants for manufacturing flint glass perfume bottles Part A : Thermal analysis and physicochemical observations for different lubrications at the glass/punch interface" [Moreau P, Lochegnies D, Kermel C, Carpentier J.-M., Vivier H] ; New Journal of Glass and Ceramics, 1, 92-104 (2011) • "Spray-drying : an alternative synthesis method for polycationic oxide compounds" [Rivas-Murias B., Fagnard J.-F., Vanderbemden Ph., Traianidis M., Henrist C., Cloots R., Vertruyen B.]; J. Phys. Chem. Solids, 72, 152 (2011) • "Use of Electrochemical Impedance Spectroscopy (EIS) for the Evaluation of Electrocoatings Performances" [Olivier M.-G., Poelman M.] "Recent Researches in Corrosion Evaluation and Protection" [Ed. Reza Shoja Razavi] InTech, January 2012. • "Surface treatment of carbon nanotubes via plasma technology" [Ruelle B., Bittencourt C., Dubois Ph.] "Polymer Carbon Nanotube Composites: Synthesis, Properties and Applications" [Eds. T. McNally, P. Pöschke]; Woodhead Publishing Ltd, Chapter 2, 25-54 (2011) • "Method for rapid control of bacterial PHA production through thermogravimetric analysis" [Talon O, Berezina N]; J Chem Technol Biotechnol; 86: 1195–1197 (2011) • "In situ compatibilization of thermoplastic starch and poly(butylene adipate-co-terephalate) by reactive melt blending in presence of maleic anhydride" [Frédérix C, Talon O, Lewillion Ph.]; Chemical Engineering Transaction; 24: 865-870, (2011) • "Lipase-catalyzed synthesis of L -cysteine glucosyl esters in organic media" [Valepyn E, Nys J., Richel A., Laurent P, Berezina N, Talon O., Paquot M] Biocatalysis and Biotransformation; 29(1): 25–30, (2011) • "Combining cone calorimeter and PCFC to determine the mode of action of flame retardant additives" [Sonnier R., Ferry L., Longuet C., Laoutid F., Friederich B., Laachachi A., Lopez-Cuesta J-M.], Polym. Adv. Technol., 22: 1091-1099 (2011) CONFERENCES • " Stir Bar Sorptive Extraction ", presentation at the technical meeting organised by VEOLIA, Maison de la chimie, [Henneuse C.], " Analyse des odeurs et des composés organiques volatils (COV) émis par des matériaux polymères – Résolution de problèmes par la technique SBSE ", 20 January 2011, Paris (FR) • "Laser sintering of ceramic green bodies", [Juste E], poster at the Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) • "Slurry Spray Modelling by Discrete Element for optimized selective laser sintering (SLS)" [Martic G., Petit F., Lardot V., Cambier F.]; poster at the Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) • "Modification of alumina surface properties by laser treatment", [Martic G., Van Overschelde O., Petit F., Lardot V., Cambier F.], poster at the Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) • "Densification of alumina by FAST and conventional hot pressing: Comparative study", [Demuynck M], oral presentation, Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) 46 Environment and Materials Research Association • "Predictive model applicable to water debinding of Complex shape parts injection molded using commercial feedstocks" [Dupont V., Delmotte C., Erauw J-P., Cambier F., Boulanger T., Emmerechts C., Guerra B., Beeckman E.], oral presentation, Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) • “Time-resolved study of oxidation of carbon refractory materials and debinding of ceramic green bodies using a high temperature cell in FTIR equipment” [Hocquet S., Dupont V., Cambier F., poster presentation, Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) • "Development of a piezoelectric actuator for cryogenic applications " [Martic G., Traianidis M., Petit F., Poortemann-M.,–Lardot V., Cambier F.], poster presentation at the Annual Meeting of the Belgian Ceramic Society, 07 February 2011, Mons (BE) • “Micro-machining of ceramics with lasers”. [Petit F.] oral presentation, Technifutur seminar: uses of laser machining, 24 February 2011, Liège (BE) • "Performant nanocomposites based on poly (epsilon-caprolactone) grafted CNTs (PCL-g-CNTs)" [Peeterbroeck S., Ruelle B., Godfroid T., Snyders R., Bittencourt C., Dubois Ph.], poster presentation, training school cost action MP0701, , 28 February and 1st March 2011, Naples (IT) • " Amélioration des propriétés barrières aux gaz et aux arômes de feuilles en polypropylène destinées au thermoformage" [ Damsir H.] ; Oral Presentation, Innovaction packaging, 1st March 2011, Villers-le Bouillet (BE) • "Effect of alumina nanoparticles on the morphology and thermal stability of immiscible polymer blends", [Laoutid F., Francois D., Bonnaud L., Dubois Ph.], poster presentation, Sixth “Matinée des chercheurs”, 22 March 2011, Mons (BE) • "A la recherche de nouveaux matériaux d'électrolyte et de cathode pour SOFC: weberite et cobaltite" [Preux N.] Oral presentation at the GFC Annual Meetings of 21 to 23 March 2011, Limoges (FR) • "Consolidation d’alumine par frittage sélectif " [Juste E., Petit F., Cambier F.], Oral presentation at the GFC annual meeting of 21 to 23 March 2011, Limoges (FR) • "The "green" challenge: PLA (nano)composites for "durable" applications ?" [Murariu M., Bonnaud L., Berlier K., Dechief A.L., Paint Y., Dubois Ph.] poster presentation, Matinée des Chercheurs 2011, 22 March 2011, Mons (BE) • "Effect of alumina nanoparticles on the morphology and thermal stability of immiscible polymer blends" [Laoutid F., Francois D., Bonnaud L., Dubois Ph.] presentation at the 6th "Matinée des chercheurs", 22 March 2011, Mons (BE) • " La corrosion: les défis du futur : Le sol-gel au service des nouveaux matériaux ", [Collignon F.], presentation at HYBRIPROTECH themed day, 24 March 2011, Charlevilles-Mézière (FR). • "Determination of most efficient valerate enhancers in PHBV production by C. necator through experimental design approach" [Berezina N]; IPTB 2011, March, Milan(IT) • "Evaluation of valerate enhancers in PHBV production by C. necator through experimental design approach" [Berezina N.]; IBIO 2011, April, Dalian(CHIN) • "Using Electrochemical Impedance Spectroscopy (EIS) for the evaluation in short term of coatings performances: advantages and limitations" [ Poelman M], presentation at the AETOC (Application of Electrochemical Techniques to Organic Coatings) workshop, April 2011 in Mons (BE). • "Lanthanide modified nanoclays as reservoirs for doping silane sol-gel layers applied on galvanized steel" [Motte C., Poelman M., Roobroeck A., Fedel M., Deflorian F., Olivier M.G.], AETOC (Application of Electrochemical Techniques to Organic Coatings) workshop, April 2011 in Mons (BE). 47 Environment and Materials Research Association • "In situ compatibilization of TPPS and PBAT by reactivemelt blending with addition of MA", [Frédérix C]; ICHEAP-10, 2011, May, Florence (IT) • "Revêtements sol-gel pour application anti-corrosion" [Aubry P.], oral presentaiton, Pristimat conference: Les nouveautés en traitement de surface des matériaux – apport du sol-gel., 23 May 2011, Maubeuge (FR) • "Synthesis process of polylactide by reactive extrusion, Bioplastics Technical Conference" [ Cayuela J.]; May, Ghislenghien (BE) • "Valorisation des co-produits de lin et de chanvre" [ Lazko J.] Siñal 2011, May, Chalons-en-Champagne (FR) • "Comparison of the sintering behaviour of alumina processed by FAST and HP" [Cambier F, Demuynck M, Erauw J.-P., Van der Biest O.,Delannay F] oral Advanced Research Workshop Engineering Ceramics, , 8-12 May 2011, Smolenice (SK) • "Les applications des plastiques végétaux aujourd’hui et demain", (Dropsit S.), Current and Future Uses workshop presentation; May 2011, Arras (FR) • "Synthesis of new modified oils based thermosetting polyurethanes", [ Poussard L., Landercy N., Talon O., Rossit S., Deherripon C.]; BPG, 12-13 May, Houffalize (BE) • "Effect of alumina nanoparticles on the morphology and thermal stability of immiscible polymer blends" [Laoutid F., Francois D., Bonnaud L., Dubois Ph.], poster presentation, Annual Meeting of the Belgian Polymer Group, , 12-13 May 2011, Houffalize (BE) • "High density polyethylene (HDPE) nanocomposites with improved mechanical and electrical properties: use of masterbatches (MB) to confine and improve carbon nanotube dispersion" [Bonnaud L., Murariu O., Dubois Ph.], poster presentation, Annual Meeting of the Belgian Polymer Group, , 12-13 May 2011, Houffalize (BE) • "Effect of alumina nanoparticles on the morphology and thermal stability of immiscible polymer blends" [Laoutid F., Francois D., Bonnaud L., Dubois Ph.] presentation Annual Meeting of the Belgian Polymer Group 12-13 May 2011, Houffalize (BE) • "PLA (nano)composites for engineering applications" [Murariu M., Dechief A.L., Peeterbroeck S., Bonnaud L., Dubois Ph.] poster presentation, poster presentation, Annual Meeting of the Belgian Polymer Group, , 12-13 May 2011, Houffalize (BE) • "Dispersion of CNTs in Rubbers: Role of polymer-to-filler grafting in" [Verge P., Peeterbroeck S., Bonnaud L, Dubois Ph.], poster presentation, Annual Meeting of the Belgian Polymer Group, , 12-13 May 2011, Houffalize (BE) • "Effect of alumina nanoparticles on the morphology and thermal stability of immiscible polymer blends" [Laoutid F., Francois D., Bonnaud L., Dubois Ph.], poster presentation, EPF 5th summer school, 15-20 May 2011, Gargnano (IT) • "Effect of alumina nanoparticles on the morphology and thermal stability of immiscible polymer blends", [Laoutid F., Francois D., Bonnaud L., Dubois Ph.] presentation, EPF 5th summer school, 15-20 May 2011, , Gargnano (IT) • "Monitoring of refractory mortar hydration by several techniques" [Abdelouhab S., Flament P., Cambier M., Tirlocq J., Erauw J.-P., Cambier F.] poster presentation, 12th Conference of the ECerS, 19-24 June 2011, Stockholm (SE) • "Bio-sourced raw materials for coatings and paints" [.Hillairet C.], ATIPIC, , 20th June 2011, Brussels (BE) • "Laser cladding of metal/ceramic composites for wear applications" [Deschuyteneer D., Petit F., Gonon M., Holmberg K., Wäsche R., Cambier F] poster presentation, 12th Conference of the ECerS, 19-24 June 2011, Stockholm (SE) 48 Environment and Materials Research Association • "Laser micro-machining of ceramics" [Petit F., Cambier F.] key note lecture, 12th Conference of the ECerS, 19-24 June 2011, Stockholm (SE) • "Ceramics: Black Magic or exact science?" [Cambier F.]; (guest, Stuijts Lecture) 12th Conference of the ECerS, 19-24 June 2011, Stockholm (SE) • "Selective Nd/YVO4-laser consolidation of alumina in presence of an absorption promoter" [Juste E., Petit F., Lardot V., Cambier F]; Oral presentation, 12th Conference of the ECerS, 19-24 June 2011, Stockholm (SE) • “Development of ceramic coatings on metallic substrates for mechanical applications”[Lardot V., Outirite M., Chebaidi S., Nivot C., Tricotaux A., Courtois C., Champagne P.], poster presentation 12th Conference of the ECerS, 19-24 June 2011, Stockholm (SE) • "Application of the Master Sintering Curve Method to Spark Plasma Sintering of alumina" [Cambier F., Demuynck M., VanMeensel K., Van der Biest O., Erauw JP.] oral presentation, PacRim 9, July 2011, Cairns (AUS) • "Role of polymer-to-filler grafting in dispersion of CNTs in Rubbers" [Verge P., Peeterbroeck S., Bonnaud L, Dubois Ph.], poster presentation, European Polymer Congress, 26 June to 1st July 2011, Granada (SP) • "New way of dry incorporation of cellulose nano whiskers in poly (lactic acid)" [Sénéchal T., Huguet MH., Talon O.]; Biopol, August 2011, Strasbourg (FR) • "Flax by-products valorization in starch-based biocomposites", [Lazko J., Huguet MH., Paternostre L.]; Biopol, August 2011, Strasbourg (FR) • "Improving functional properties of flax biocomposites", [Lazko J., Goullieux A., Dheilly RM., Quéneudec M.] Biopol, August 2011, Strasbourg (FR) • "The Ninth IWA Symposium on Off-Flavours in the Aquatic Environment; Odour and emissions from plastic materials" [Henneuse C.] Key Note Invited Speaker, RGU, 14-18 August 2011, Aberdeen (UK). • "Apparent activation energy for densification of alumina-based composites by FAST (Field Assisted Sintering)" [Erauw JP., Demuynck M., Cambier F., oral presentation , Sintering 2011, 28 August – 1 September 2011, Jeju (KOR) • "Synthesis and characterization of new vegetable modified oils based thermosetting polyurethanes", [ Poussard L., Landercy N., Mariage J., Talon O., Rossit S., Deherripon C.]; Biopol, August 2011, Strasbourg (FR) • "Protecting mild steel against corrosion in neutral aqueous solution using combined inhibitors: a classical and local electrochemical approach" [Poelman M., Lahem D., Atmani F., Recloux I.,Olivier M.], poster presentation Eurocorr, September 2011 , Stockholm (SE). • "PLA-graphite nanocomposites as promising new materials for engineering applications", [Murariu M., Dechief A.L., Paint Y., Bonnaud L., Raquez J.M., Dubois Ph.], poster presentation, 19th BEPS annual meeting, , 28-30 September 2011, Vienna (AU) • "Préserver la pierre: aractéristiques et emploi des produits protecteurs " ", [Eyssautier S., Pleck J.], HYBRIPROTECH themed day " les sols-gels comme produits protecteurs " , 13 October 2011, Reims (FR) • "REFIOM: les contraintes liées à leur valorisation", [Bouillot F., Marquis S., Trobbiani S., Tirlocq J., Pilate P., Leleu P., André S.], Salon BEST oral presentation, 14 October 2011, Liège (BE). • "SOLINDUS (SOLutions INtégrées et Durables pour Sédiments et matières assimilées): du laboratoire à la plateforme expérimentale industrielle", [Brequel H.], oral presentation Salon BEST, 14 October 2011, Liège (BE). . • " Impact de la mise en forme de polylactide sur l’émission de COVs " [Piroëlle A., Rusu D., Lacrampe M.F., Krawczak P.,Henneuse C., Ducruet V.]; 39th Polymers Study Day (JEPO 39), 16 to 21 October 2011, Val Joly, Eppe-Sauvage (FR) Talon O., 49 Environment and Materials Research Association • "Time-dependent simulation of temperature field in SPS by the use of a PID temperature controller in a coupled thermoelectric finite element model" [Vanherck T., Lobry J., Demuynck M., Cambier F.], poster presentation International Workshop on SPS, 20-21 October 2011, Cap Breton (FR) • "Matériaux et impact environnemental, focus sur les peintures et polymères "; [Luciani A.] ; Innovaction Rénovation durable ; 17 November 2011, Gembloux (BE) • "The work of ISO TC146 for the standardisation of sensory tests – a support for the accreditation in material odour testing" [Noiset O.], Workshop on sensory science for food contact materials safety, 29 November 2011, Ispra (IT) • "L’analyse objective de l’impact environnemental d’un projet de recherche est-elle possible ? " [Talon O.] ; Atelier "Que pouvons-nous faire pour que notre R&D soutienne mieux nos régions face aux profondes mutations économiques et sociétales ? " November 2011; Ghislenghien (BE) • "Porous ceramics by ice templating: freezing characteristics and microstructure properties" [Hautcoeur D., Leriche A., Moreno R., Nieto M.I., Baudin C.,.Gonon M., Sciamana V., Lardot V., Cambier F.] poster presentation IV Congresso Luso-Espanhol de Ceramica & Vidro 16-18 November 2011, Aveiro (P), • "Porous ceramics by ice templating: freezing characteristics and microstructure properties", [Hautcoeur D., Leriche A., Moreno R., Nieto M.I., Baudin C.,.Gonon M., Sciamana V., Lardot V., Cambier F.], "Students' meeting :processing and applications of ceramics", oral presentation, 16-18 November 2011 Novi Sad (SRB) • "PLA-graphite nanocomposites as new materials for engineering applications", [Murariu M., Dechief A.L., Paint Y., Bonnaud L., Raquez J.M., Dubois Ph.], poster presentation, IAP FS2 6/27 annual network meeting, 21 November 2011, Louvain (BE) • "Etude expérimentale et modélisation d'un matériau à gradients " [Ferguen N., Outirite M., Pelegris C., Cogne C., Courtois C., Rigo O., Hocquet S., Lardot V., Cambier F., Leriche A.]; Proc. 13th Congress of the st French Society of Process Engineering (SFGP) – 29 November to 1 December 2011, Lille Grand Palais (FR) • "Biodégradation – oxodégradation « entre gris clair et gris foncé" [Berthé V.] ; Symposium on the industrialisation of natural fibre composites, November 2011, Dijon (FR) • "Laser machining of ceramics" [Cambier.F., Petit.F.] guest oral presentation, 4 IPSCCG, 16-18 November 2011, Aveiro (P) • "Synthesis of new modified oils based thermosetting polyurethanes" [Poussard L., Landercy N., Talon O., Rossit S., Deherripon C.]; GFP, November 2011, Pau (FR) • "Laser cladding of metal/ceramic composites for wear applications" [Deschuyteneer D., Petit F., Gonon M., Holenberg K., Wäsche R., Cambier F.], oral presentation, Students' meeting "processing and applications of ceramics", 16-18 November 2011 Novi Sad (SRB) • "Additive manufacturing of bone substitute " [Clarinval AM., Boilet L., Descamps M., Leriche A., Soyeur Q., th Sforza T., Monnoye D., Hocquet S., Lardot V., Cambier F., poster presentation, 10 National Day on Biomedical Engineering and Annual Symposium of the IEEE EMBS Benelux Chapter 1 & 2, December 2011, Louvain (BE) • "First step and two steps laser cladding of zirconia and remelting" [Preux N., Petit F., Lardot V., Cambier F., poster presentation, Fifth international meeting on Thermal Projection, 7 to 9 December 2011, Limoges (FR) • "Improving Performances of Agromaterials for Building Applications " [Lazko J.] Workshop presentation "Agromaterials, Technical Fibers and Ecocomposites" , December 2011, Saint-Quentin (FR) • "Revêtement hybride organique-inorganique sur acier doux " [Aubry P., Nivot C., Delmotte C., Lardot V., Cambier F.]; Poster presentation. 13th Congress of the French Society of Process Engineering (SFGP) – 29 st November to 1 December 2011, Lille Grand Palais (FR) 50 th Environment and Materials Research Association • "Les procédés de traitement par cyanuration y compris les méthodes de destruction de cyanure résiduel– Exemples de schémas de traitement d'installations équatoriennes", [Lucion Ch.], Kayenn Mining Symposium, Oral presentation December 2011, OrKiDé de Guyane, Cayenne, Guyana (FR). • "Role of odour perception and olfactory testing in product evaluation" [Noiset O.], 9th Edition Emissions and odours from materials, 9th & 10th 2011, Brussels (BE) • "Scratch test mechanical properties of suspension plasma sprayed TiO2 coatings " [Leszek L., Pawlowski L., Petit F., Kozerski S.] ; poster presentation ITSC conference, , 27-29 September 2011, Hamburg (DE) COURSES • "Les bioplastiques sont-ils des plastiques verts ? " [Talon O.] ; INSA, Rouen (FR) January 2011 • "Minéralurgie au service de l'environnement - Recyclage et valorisation des déchets" [Lucion Ch.], 16 February; 9, 17 and 23 March 2011, UVHC Valenciennes (FR). • "Biotechnologie blanche" [Berezina N]; ENSCMu, , November 2011, Mulhouse (FR) • "Etat de l’art des agroressources", [Lazko J.]; Université Picardie Jules Verne, , December 2011, Amiens (FR) FAIRS AND SHOWS: STANDS • Innovaction Emballage, 1st March 2011, Villers le Bouillet (BE) • 7 SPE "Additives & Colors" C ference, 16-17 March 2011, Köningswinter Bonn (DE) • SINAL, Convention Non-Alimentaire Valorisant les Agro-ressources, 3-4 April, Châlons en Champagne (FR) • Journée Bioplastiques, 25 May, Ghislenghien (BE) • Environord, 7-9 June , Lille (FR) • GEDSET plenary day, 28 and 29 June 2011, Douai (FR) • Intersolar, June 2011, Munich (DE) • XVIIème Journées Groupement Français de Spectroscopie Vibrationelle 2011, 8-10 June, Limoges (FR) • Les RDV Carnots , 12 and 13 October 2011, Lyon (FR) • Best, 10ème Salon Européen de l’Environnement, de l’Energie et des Technologies Propres, 13-14 October 2011, Liège (BE) • Innovaction Rénovation Durable, 17 November 2011, Gembloux (BE) • Pollutec 2011, 22 November – 2 December, Paris (FR) th on CONFERENCES, FAIRS AND SHOWS: VISITOR • "GBEE (Groupement Belge de l’Energie Explosive) – La qualité du tir", 28/01/2011, Mons (BE) • "Bioplastics componding & processing", 29-30 March 2011, Miami (USA) • "7th International Conference on Polymer and Textile Biotechnology", IPTB 2011, 2 to 4 March 2011, Milan (IT) • "Journée Cluster Eurométropole" 15 March 2011, Tournai (BE) • "Formation Sim –flottation", 22 March 2011, Paris (FR) • "JEC Composites", 29-31 March, Paris (FR) • "Formation sites et sols pollués (aspects législatifs et gestion)", 5 and 6 April 2011, Paris (FR) 51 Environment and Materials Research Association • "The 11th International PVC Conference", 12-14 April, Brighton (UK) • "2nd slag symposium", 18 to 20 April, Louvain (BE) • "4th World Congress of Industrial Biotechnology", IBIO 2011, 25 to 30 April 2011, Dalian (China) • Icheap10, 8 to 11 May 2011, Florence (IT) • "Hydrophobe IV International Conference on Water Repellent Treatment of Building Materials", 11-15 May , Rome (IT) • "Application des plastiques végétaux aujourd’hui et demain", 12 May 2011 , Arras (FR) • "Fundamentals and developments in polymer processing science and technology", EPF Summer School, 15-20 May 2011, Gargnano (IT) • "Les gîtes sous-marins profonds" (SIM Technical Day), 16 May 2011, Paris (FR) • "8th International Conference of the European Industrial Hemp Association (EIHA)", 18-19 May 2011, Rheinforum (DE) • "Waste-to-resources 2011", 23 to 28 May 2011, Hanover (DE) • Cinbios – RRB 7 (1st day), 08 June 2011, Bruges (BE) • "The 3 European Process Intensification Conference", 20-23 June 2011, Manchester (UK) • "The 7 International Symposium on Modern Principles for Air Monitoring and Biomonitoring" Airmon, 20-24 June 2011, Loen (NOR) • "Journée sédiments", 27 June 2011, Liège (BE) • "Biopol 3rd International Conference on Biodegradable and Biobased Polymers", 29-31 August 2011, Strasbourg (FR) • "Plant Based Chemistry for 2020", 5-7 September 2011, Paris (FR) • 3ème Colloque "Fibres naturelles et polymères", 15 September , Troyes (FR) • "The 19th Annual Meeting of the BioEnvironmental Society", BEPS 2011, 27 to 30 September 2011, Vienna (AU) • "Groupement Belge de la Société de l’Industrie Minérale", 4 October 2011, Liège (BE) • "Sol-gel: une très vielle technologie pour les applications du futur!", 19 October Bracquegny (BE) • "International Event on Renewable Plastics, Textiles and composite", 27 October 2011, Elewijt (BE) • "2 European Symposium on Photocatalysis", JEP 2011, 29-30 October 2011, Bordeaux (FR) • "L’Analyse du cycle de vie au service de la pensée stratégique", 3-4 November 2011, Lille (FR) • "L'industrialisation des composites fibres naturelles", 17-18 November 2011, Dijon (FR) • "European Bioplastic Association (EBA) n°6", 23 November 2011, Berlin (DE) • "Safety of Manufactured Nanomaterials: from Design to Safe Production", 13 December 2011, Namur (BE) rd th 2011, Strépy- nd PATENTS Inventors: Yahia Lemmouchi, Olivier Persenaire, Robert Quintana, Leïla Bonnaud and Philippe Dubois Patent application number: 1105420.2 Celulose Acetate and plasticizer blends British American Tobacco (Investments) Limited Ref: SVH/62550GB1 Inventors: Yahia Lemmouchi, Olivier Persenaire, Robert Quintana, Leïla Bonnaud and Philippe Dubois Patent application number: 1105455.8 52 Environment and Materials Research Association Blends of a Polylactic Acid and a Water-Soluble Polymer British American Tobacco (Investments) Limited Ref: SVH/62550GB1 Inventors: Nantet Locabennes – G. Nantet, P. Hubaux. WO 2011/027255 A1 Procedure for the installation and recycling of plaster waste products Inventors: Yahia Lemmouchi, Olivier Persenaire, Robert Quintana, Leïla Bonnaud and Philippe Dubois UK Patent Application No. 1112402.1 CA and Water-Soluble Material Blend British American Tobacco (Investments) Limited Ref: SVH/63680GB1 Inventors: Philippe Dubois, Valérie Lison, Emmanuel Duquesne, Olivier Talon, Julien Cayuela, Laurent Paternostre, WO2011 144625(A1), Process for nucleating and accelerating the crystallization of polylactide Futerro SA 53 Environment and Materials Research Association KEY FIGURES (K€) Income 2010 2011 Customer invoicing 9,996 11,895 Operating grants 8,525 9,419 182 213 1,412 1,578 20,115 23,105 Purchases and Services 4,485 5,435 Payroll 14,898 15,468 Depreciation of Share Capital and provisions 484 839 Other charges 71 197 19,938 21,939 408 1,166 4,432 3,115 Subscriptions Other products TOTAL Charges TOTAL Results Investments Investment grants (equipment and buildings) 271 partners 4000 industrial contracts per year More than 1000 clients 0,9% Breakdown of revenue 6,8% 40,8% 51,5% Industrial contracts Public contracts Subscriptions Other 54