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Water quality assessment : Akumal case Dra. Laura M. Hernández Terrones Foto Laura Hernández Objectives… ¤ Evaluate water quality in the area and determine the aquatic ecosystems condition ¤ Provide science based information in order to facilitate water resource management Climate change and water Impacts Society Change Ecosystem Tropical storm and hurricanes (frecuency and intensity) Temperature increase Health Services interruption Diseases Food Damage to agriculture, livestock and fisheries Security Socioeconomic Coastal zone protection Tourism Energy production Order and law Floods damage Sea level increase Floods (coast and contient) Coral bleaching Coastal zone protection Damage to infraestructure and properties Ocean acidification, salt water Intrusion, drought…. Source: GEO-4 2007 History ¤ 2006-2009 ¤ Water quality monitoring in Akumal ¤ 2011-2013 ¤ Monitoring network design and instrumentation for water quality evaluation in Tulum municipality 2006-2009 Yal Ku Foto Laura Hernández Yal Ku: Salinity ¤ Summer 2007 ¤ Spring 2008 Yal Ku: temperature ¤ Winter: 25-27 ºC ¤ Summer: 28-30 ºC Chemical composition Na 60 40 70 30 80 90 Yal Kú 10 Lagartos 100 Cl 0 20 0 10 20 30 40 Ca Fecha 2500 2250 Oct-2008 2750 Sep-2008 Jul-2008 Jun-2008 Apr-2008 Feb-2008 Jan-2008 Nov-2007 Sep-2007 Aug-2007 Jun-2007 Escherichia coli (NMP/100 ml) Yal Ku: coliform bacteria 3000 Huracán "Dean" YK 1 YK2 YK3 YK5 YK6 YK7 YK8 1500 1250 1000 750 500 250 0 Yal Ku: Nutrients ¤ Nitrate concentrations in Yal Ku lagoon were between 28.71μM and 55.97μM ¤ Values are higher than threshold limits established by Mexican environment legislation for aquatic life protection in marine waters (water quality ecological criteria CE-CCA-001/89) (<0.645 μM NO3) ¤ Significantly higher than values reported by Mutchler et al. (2007) at the same location (26.9 μM n=2). 160 y = 0.8212x - 5.3156 140 R2 = 0.8992 n=84 YK04 N-NO 3 ( µ M) 120 YK05 100 YK06 80 YK07 YK03 60 YK02 YK01 40 20 0 0 20 40 60 80 100 E. coli (NMP/100 ml) 120 140 160 Lagartos lagoon Foto Laura Hernández Lagartos lagoon: nutrients L01 L02 L03 L04 180.0 160.0 120.0 100.0 80.0 60.0 40.0 Date Sept-08 Aug-08 Jul-08 Jun-08 May-08 Apr-08 Mar-08 Feb-08 Jan-08 Nov-07 0.0 Oct-07 20.0 Sept-07 NO3- (µM) 140.0 Bays Fecha Oct-2008 Sep-2008 4000 Fecha 3000 2000 1000 0 500 Huracán "Dean" Oct-2008 750 Sep-2008 Jul-2008 Jun-2008 Apr-2008 Feb-2008 Jan-2008 Nov-2007 Sep-2007 9000 Jul-2008 10000 Aug-2007 12000 Jun-2008 8000 Jun-2007 Bays Apr-2008 Feb-2008 Jan-2008 Nov-2007 11000 Sep-2007 Aug-2007 Jun-2007 Escherichia coli (NMP/100 ml) 1250 1000 PAS PJS PJN BMLS BMLN BAS BAN 250 0 Bays: Nutrients 180" SGD+1" SGD+2S" SGD+3S" MC+1" MC+2" SGD+4S" SGD+2N" 160" N"NO3%(uM)% 140" 120" 100" 80" 60" 40" 20" 0" Sep+07" Oct+07" Nov+07" Jan+08" Feb+08" Mar+08" Apr+08" Date% May+08" Jun+08" Jul+08" Aug+08" Sep+08" 4000 SGD, MC 3500 3000 [SO4] mg/L 2500 YAL KU LAGOON 2000 1500 1000 500 LAGARTOS LAGOON 0 0 20 40 60 80 100 [Si-SiO2] umol/L 120 140 160 180 Fecha 6000 4000 10-Sep-07 5-Sep-07 31-Aug-07 26-Aug-07 21-Aug-07 16-Aug-07 11-Aug-07 6-Aug-07 1-Aug-07 E. coli (NMP/100 ml) Other… 16000 14000 8000 CA1 CA2 CA3 SR1 SR2 2000 0 2011-2013 ¤ Water quality network monitoring design for Tulum (CCT) ¤ Phase I. Sites selection and water sampling effort ¤ Phase II. Water sampling, sites instrumentation, and validation process Profile: Uxuxubi November 2012 January 2013 11 /2 8/ 11 12# /3 0/ 1 12 2# /2 /1 12 2# /4 /1 12 2# /6 /1 12 2# /8 / 12 12# /1 0/ 12 12# /1 2/ 12 12# /1 4/ 12 12# /1 6/ 12 12# /1 8/ 12 12# /2 0/ 12 12# /2 2/ 12 12# /2 4/ 12 12# /2 6/ 12 12# /2 8/ 12 12# /3 0/ 12 1/ # 1/ 13 1/ # 3/ 13 1/ # 5/ 13 1/ # 7/ 13 1/ # 9/ 1 1/ 3# 11 /1 1/ 3# 13 /1 1/ 3# 15 /1 1/ 3# 17 /1 1/ 3# 19 /1 1/ 3# 21 /1 3# Columna)de)Agua)(cm)) CA#(cm)# 26# 25# 25# 20# 24# 15# 23# FECHA) Temperatura)(°C)) 35# 28# Temperatura#(°C)# 27# 30# Nitrates in Akumal selected sites Concentraciones+Nitratos+(mg/L)+ Agosto&2012& Noviembre&2012& Enero&2013& 16.533& 14.63& 14.341& 12.091& 10.58& 9.40& 7.835& 5.743& 3.138& 3.893& 3.139& 1.814& 1.246& 0.84& Cenote&A& 3.61& 3.283& Cenote&B& Cenote&C& YKC& SGD1& 1.74& 0.748& SGD2& Constructed wetlands CW1 CW2 CW3 site CW4 E. coli Removal efficiency(%) 2007 2008 CW1 67-99 85-99 CW2 64-99 79-99 CW3 33-97 40-99 Conclusions ¤ The rising groundwater contamination will increase the stress on available water resources and valuable ecosystems, especially the adjacent coral reef. ¤ The results of this monitoring will provide valuable data to propose and/or improve protection, conservation measures ¤ The next phases will give useful information and help us to estimate ¤ Mixing conditions, ¤ Contaminants transport, ¤ We can not stop the natural processes, but we can to diminish their impact, with a responsible and informed approach ¤ “The hope is to create at the same time strategies to address climate change and to impulse the sustainable development” ¤ Mohan Munasinghe, 2007 ¤ IPCC ¤ Water quality impacts the development, and the development patterns will affect the water quality now and in a near future. Centro Ecológico Akumal MC Paul Sánchez-Navarro R. MC Iván Penié R. MC Edith Sosa B. Centro de Investigación Científica de Yucatán, A.C Quím. Daniela Ortega C. Biol. Viridiana Nava R. MCM. Fanny de Gante Ayora Special recognition must be given to the national and international students Gracias !! laurah@cicy.mx Thank you!!