Hydraulic seals for water and water-based fluids
Transcription
Hydraulic seals for water and water-based fluids
2012 Dutch Fluid Power Conference Hydraulic seals for water and water-based fluids Nick A. Peppiatt BSc, PhD, CEng, MIMechE Hallite Seals International Ltd at Hampton United Kingdom 123 2012 Dutch Fluid Power Conference Contents Hydraulic seals for water and water-based fluids Page Abstract 125 1. Introduction – the reciprocating seal system125 2. Use of water and water-based fluids 126 3. HFA fluids127 4. Applications of HFA fluids – longwall roof supports127 5. Typical seals and bearings for HFA fluids131 5.1. Piston seals131 5.2. Rod seals132 5.3. Bearings132 6. Reciprocating seal testing132 7. Effects of corrosion133 8. Seal material compatibility135 9. Use of HFCs135 10. Conclusions136 124 Nick A. Peppiatt Hydraulic seals for water and water-based fluids 2012 Dutch Fluid Power Conference Abstract The use of water as a hydraulic fluid is discussed and some examples of successful applications of water-based fluids, particularly longwall mining roof supports, are described. Examples of seal designs used in these applications are shown, and the effects of seal material/fluid media compatibility considered. 1. Introduction – the reciprocating seal system Keywords: Seal system HFA Corrosion Compatibility HFC The reciprocating seal system consists of the following elements: 1. Housings: • Surface finishes – static and dynamic, • Dimensions and • Assembly details - chamfers. 2. Bearings: • Metal or plastic. 3. Fluid: • Compatibility and • Lubricity. 4. Soft Parts: • Rod seal, wiper, piston seal and static seals. 5. Operating conditions: • Pressure, • Temperature, • Speed, • Stroke and • External environment. Obviously many factors can affect the performance of the soft parts and clearly one of major importance for the hydraulic sealing system is the fluid. Its influence on the sealing system needs to be considered carefully. This paper examines the effects of the use of water and water-based fluids on the sealing system. Nick A. Peppiatt Hydraulic seals for water and water-based fluids 125 2012 Dutch Fluid Power Conference 2. Use of water and water-based fluids The limitations of water as a hydraulic fluid include the following: 1. The temperature range is limited to +5 to +50 °C (refer to, for example, ISO 7745 [1]). The low temperature limit is to prevent the water from freezing; the upper limit is because of the high vapour pressure of water, which can lead to cavitation problems. 2. Water can encourage the growth of bacteria and fungi. This is an important consideration in this health and safety conscious age, with the associated necessity for risk assessments. 3. Plain water is a very poor lubricant. 4. Water is a major factor in causing corrosion of metal components. Of course, all these limitations can be overcome by the use of oil-based fluids. The earliest hydraulic systems, developed by Bramah and dating from the 1790s, used plain water and the seals used in the cylinders were leather cups. Maximum pressures used were around 550 bar. (McNeil [2]). In the late 1800s hydraulic ring mains, using water, were set up in many cities, a notable one being run by the London Hydraulic Power Company, which operated for about one hundred years. The fluid, at a pressure of around 50 bar, operated cranes, lifts, presses and capstans. Burrows [3] has noted that as early as the 1860s additives to improve the performance of water as a hydraulic fluid were being proposed. The hydraulic ring mains were eventually superseded by electricity. In the author’s experience, hydraulic systems using plain water are now rare. The British Fluid Power Association (BFPA) did have a Water Hydraulics Committee, which produced a technical guide in 1999 [4], but this committee has since been disbanded. On the other hand, water-based hydraulic fluids are successfully and widely used in systems where fireresistance is required and examples are given later. ISO 6743-4 [5] describes three basic water-based hydraulic fluids. These are: 1. HFA – oil in water emulsions or chemical solutions in water with typically more than 80% mass fraction of water (in most cases this is 95% or greater), 2. HFB - water in oil emulsions and 3. HFC - water polymer solutions with typically more than 35% mass fraction of water. HFB fluids are rarely used and will not be considered further in this paper. 126 Nick A. Peppiatt Hydraulic seals for water and water-based fluids 2012 Dutch Fluid Power Conference 3. HFA fluids Typical HFA fluids have a water content of 95% or greater. Like water, they have a low viscosity of around 1 cSt, but the additive, which makes the fluid alkaline with a pH value of around 9 to 9.5, has three functions: 1. It is a biocide, 2. It prevents corrosion enabling carbon steel components to be used and 3. The soapiness of the fluid provides improved lubricity over plain water. The low viscosity HFA fluids are of two types, HFAE, which are oil-in-water emulsions and the later HFAS, which are chemical solutions in water. Scums can build up in the HFAE types, which can cause clogging of valves and filters, but this does give them generally a better lubricity than the cleaner HFAS type. Higher viscosity HFAE fluids with a water content of greater than 80% have also been developed. 4. Applications of HFA fluids – longwall roof supports Low viscosity HFA fluids have been used very successfully for many years in selfadvancing hydraulic roof supports for the longwall mining of minerals such as coal and potash. The author has many years’ experience in developing and specifying reciprocating seals for use in such fluids ([6], [7] and [8]). As the equipment is used underground and, thus, hidden away, there is very little awareness of these large hydraulic machines outside the mineral extraction industry. Some examples of the largest and latest roof supports, or shields are shown in figures 1 and 2 on the next page. The coal face consists of a line of around 150 of these supports, which support the roof of the mine whilst the shearer cuts the coal along a face length of around 300 m. The operation of such a modern longwall face is now highly automated. The leg cylinders, which keep the roof of the mine from the floor whilst the coal is being cut, can be clearly seen in figures 1 and 2. A cutaway drawing of a typical constant yield double telescopic leg is shown in figure 3. The outer stage bores of the leg cylinders shown in figures 1 and 2 are 480 mm and 500 mm respectively. These main hydraulic leg cylinders are connected to a yield valve on the full bore side, which controls the release of fluid from the leg when the pressure exerted by the roof exceeds a pressure of around 450 bar. Pressure is trapped in the inner cylinder, so that the inner cylinder pressure is the yield pressure multiplied by the area ratio of the cylinder bores, which is often a factor of two. Nick A. Peppiatt Hydraulic seals for water and water-based fluids 127 2012 Dutch Fluid Power Conference Figure 1. 1750 tonne roof support with 480mm bore leg cylinders – note the bronze plated rods Figure 2. Roof supports for 7 m face with 500 mm bore leg cylinders 128 Nick A. Peppiatt Hydraulic seals for water and water-based fluids 2012 Dutch Fluid Power Conference Figure 3. Cutaway drawing of typical constant yield double telescopic (CYDT) roof support leg cylinder showing the seals and bearings The roof support also has a number of other cylinders including: 1. The advancing ram which pushes the armoured face conveyor forward and to drag the support forward (to make the face self-advance), 2. The base lift ram to lift the front of the support while it is being advanced, 3. The stabilising ram to control the support linkage, 4. The side shield rams to close the space between supports and 5. The sprag rams or flipper rams to control the sprags or flippers at the front of the support. Some of these cylinders can be seen particularly in figure 2. The maximum pump pressure operating these cylinders is around 315 bar. In contrast, a typical UK home market leg from over thirty years ago is shown in figure 4. This is again a double telescopic leg, but with an outer stage bore of 108 mm (4.250 in). This leg has an extended length of just over one metre. This increase in maximum leg diameter over the last thirty years is shown in figure 5. This doubling of diameter has increased the load capability of roof support shields fourfold and has enabled deeper cuts to be made in the coal seams (seven metres in the case of the shield with the 500mm bore leg) increasing mine productivity enormously. At the current time, with the maximum roof support width of 2 m, for transportation reasons, 500mm bore cylinders appear close to the practical maximum limit. Nick A. Peppiatt Hydraulic seals for water and water-based fluids 129 2012 Dutch Fluid Power Conference Figure 4. UK home market 108 mm (4.25 in) bore leg cylinder (from 1970s) in convergence test rig The use of HFA fluids enables standard carbon steels to be used in the construction of the cylinders, although the glands often have to be given special treatment to avoid the problems of excessive corrosion. Figure 5. Graph showing largest mining leg cylinder bore diameter against approximate year of introduction 130 Nick A. Peppiatt Hydraulic seals for water and water-based fluids 2012 Dutch Fluid Power Conference It should be pointed out that the longwall face advances intermittently, the frequency being governed by the time the shearer takes to make a cut along the whole face. This gives plenty of time for the seal and fluid to cool down between working strokes. The shearer also uses hydraulic cylinders, but as these are used continuously, the operating fluid here is generally mineral oil based. The volume of fluid in the shearer is very much smaller than that required for the roof support system. 5. Typical seals and bearings for HFA fluids 5.1. Piston seals The typical piston seal construction used in longwall roof support cylinders is shown in figure 6. This has a polyester elastomer wear face, which is energised by a nitrile (NBR) element, which seals between the piston and the face, and there are generally two hard plastic anti-extrusion rings. This design has now become widely used in mining roof support cylinders for two main reasons: Figure 6. Polyester faced piston seal – 3-d model (left), cross section shown installed on a piston (right) 1. It can run on a wide variety of surface finish values from skived and roller burnished to honed tube bores of varying initial roughness and 2. It also works satisfactorily both in the older emulsion type fluids (HFAE) and the newer micro-emulsions (HFAE) and synthetic fluids (HFAS), which were introduced in the late 1980s and early 1990s to reduce the problems of soapy scums blocking valves and filters [7]. Additionally this seal design can be readily fitted to one piece housings as the energising rubber seal component and the polyester face can be stretched over the piston and the hard plastic backup rings are split. The design has also proved adaptable to the growth in the diameter of hydraulic leg cylinders from 250 mm to 500 mm over the last thirty years as shown in figure 5. As a result of the high inner stage pressures the seal is often fitted with additional support rings to give the seal construction greater extrusion resistance. Nick A. Peppiatt Hydraulic seals for water and water-based fluids 131 2012 Dutch Fluid Power Conference 5.2. Rod seals Polyurethanes are well proven as extremely wear resistant materials in hydraulic applications using mineral oil. Unfortunately, some formulations are very susceptible to hydrolysis, or attack by water. The development of hydrolysis resistant grades with good resistance to permanent set has enabled polyurethane rod seal designs to be used successfully in HFA water based fluids since the early 1990s. A typical design is shown in figure 7. In this example, the polyurethane shell is energised by a nitrile (NBR) O-ring and the seal also has a hard plastic anti-extrusion ring. Figure 7. Rod seal with hydrolysis polyurethane shell – 3d (left), cross-section shown installed in a gland (right) 5.3. Bearings As is shown in the leg cylinder drawing, figure 3, plastic bearing strips are preferred for guiding the piston through the bore and the rod through the gland. Such plastic bearings have been used on piston heads for many years, but pick-up problems occurring between cast iron glands and chromed rods as a result of the poor lubricity of HFA led to their introduction for the glands as well. The bearing materials are typically acetal (POM) or fabric reinforced polyester. The use of glass filled nylon (GFN) bearings is not recommended as nylon (PA) is dimensionally unstable in the presence of water. 6. Reciprocating seal testing The initial development of the polyester faced piston seals, which took place in the 1980s, was carried out by the convergence testing of mining leg cylinders in the Hallite mining leg cylinder test rig shown in figure 4. A full description of this testing was reported by Peppiatt [6]. In addition, Hallite have carried out a considerable amount of wear testing in a standard reciprocating rod seal test arrangement, as shown in figure 8. The test pressure used was 345 bar, which was constant as the rod was reciprocated. The rod speed was 0.2 m/s and the maximum temperature allowed was 50 °C. The temperature was controlled by the 132 Nick A. Peppiatt Hydraulic seals for water and water-based fluids 2012 Dutch Fluid Power Conference dwell time at the end of each stroke. The number of cycles was 20,000. The tests clearly showed that for the polyurethane rod seal material and the polyester elastomer piston face material the wear over 20,000 cycles in HFA fluids is considerably less than in tap water. Of course, if a test using otherwise similar conditions was run using mineral oil, a duration of at least ten times greater would be expected. Test seal grooves ► ► ► Test pressure Figure 8. Cross-section through a reciprocating rod seal test pod. The rod is reciprocated by an external drive cylinder 7. Effects of corrosion It is essential that the condition of a water based fluid system is monitored and the fluid correctly maintained. The consequences of not doing this can be very expensive. Figure 9 shows the effects of using untreated mine-water in a roof support advancing ram where the highly stressed surface of a skived and roller burnished cylinder tube has been attacked and converted it from a benign surface for a seal to run on to one that is highly abrasive and rough enough to rapidly destroy the piston seal and bearing. Corrosion of the cylinder rods is much less of a problem because the rods are generally hard chrome plated, often over a layer of bronze plate, which provides an impermeable layer over the steel. In certain mine conditions, bronze plating only is used on the rods of the leg cylinders. The leg cylinders of the roof support shield shown in figure 1 are an example of this. Nick A. Peppiatt Hydraulic seals for water and water-based fluids 133 2012 Dutch Fluid Power Conference Figure 9. Example of corroded cylinder bore (above) and resulting damaged piston seal and bearing (below) 134 Nick A. Peppiatt Hydraulic seals for water and water-based fluids 2012 Dutch Fluid Power Conference 8. Seal material compatibility A factor which must not be taken for granted is the chemical compatibility of fluids with seal materials. ISO 6072 (9) gives details of suitable compatibility test conditions and table 1 gives the results of such immersion tests for the polyester elastomer face material and the polyurethane rod seal material in several water-based fluids, in comparison with the ISO 6072 guidelines for allowable change. Note that these guidelines, which were in the 2002 edition of ISO 6072, have now been removed from the 2011 edition. However, they are retained in BS ISO 6072 as a National Annex. From table 1 it can be seen that, although there are changes in properties of the materials in distilled water and the HFAE fluids, these changes are not major, and the fluid/seal material compatibility is acceptable. This agrees with experience, as these materials have been used in these fluid types for many years without compatibility problems. On the other hand major and unacceptable changes of material property have occurred with the thickened HFA and the HFC water glycol. This again agrees with application experience. Fluid Distilled water Immersion time and temperature Material Change in hardness Volume change (%) Loss in tensile strength (%) Increase in elongation (%) HFAE HFAE Thickened microHFA emulsion (20/80) 56 days at 70 °C HFC (water glycol) ISO 6072 guideline 42 days at 70 °C A B A B A B A B A B -2 0 -1 0 -2 0 -4 -1 -2 0 +10/-10 1 1 7 2 5 4 18 12 5 3 -5/+20 13 14 3 12 27 4 54 84 77 100 50 12 15 41 59 20 21 41 -98 -28 -100 -50 A = Hydrolysis resistant polyurethane (used in rod seals) B = Hydrolysis stabilised polyester elastomer (used in piston seal faces) Table 1. Compatibility results for hydrolysis resistant polyurethane and polyester seal materials in various water based fluids 9. Use of HFCs HFC fluids are polymer solutions (generally glycol based) of between 35 and 80 % water. They can have viscosities similar to mineral based hydraulic oils and the anti-freeze properties of the additive allow them to work down to -20 °C. The upper temperature is still limited by the high vapour pressure of water. They are commonly used where a fire resistant fluid is working harder and needs to provide a better lubricity than HFA. They are commonly used in applications such as hydraulic systems for steel works. There is Nick A. Peppiatt Hydraulic seals for water and water-based fluids 135 2012 Dutch Fluid Power Conference a common misconception that, because they are fire-resistant fluids, they are also fluids which can operate at higher temperatures. This is clearly not desirable because of the low vapour pressure of water and seal material compatibility concerns. It can be seen from table 1 that the seals developed for longwall mining applications may not be successful when used in HFC fluids, because of the problems of long-term chemical attack. In general, nitrile rubber seals are to be preferred [8]. 10. Conclusions Going back to the nineteenth century, the original hydraulic fluid was plain water. Now, only a very small proportion of hydraulic systems use plain water as a fluid. This is because water on its own has a number of major disadvantages. A number of these can be overcome by the addition of a low percentage of additives (HFA), and these do not reduce the fire resistance of the media compared with plain water. Such fluids have been used successfully for many years in underground hydraulic equipment to extract minerals – an application where fire resistance is paramount. Seals have been successfully developed for this application to enable the output of such equipment to increase many times. The importance of maintaining the condition of such fluids to achieve the successful operation of this mining equipment cannot be overemphasised. There are several different water based fluid types and seals that are suitable well proven for one type may not be suitable for another. References [1] SO 7745 Hydraulic fluid power – Fire-resistant (FR) fluids – Requirements and guidelines for use, 2010. [2] I. McNeil ‘Hydraulic power transmission- the first 350 years’. I.Mech.E. The Newcomen Society lecture 26th November 1975. [3] C.R. Burrows ‘Fluid power systems design – Bramah’s legacy’. Proceedings of I.Mech.E. 13th December 1995. [4] ‘Water Hydraulics – a Technical Guide’ BFPA P82, 1999. [5] ISO 6743-4, Lubricants, industrial oils and related products (class L) – Classification – Part 4: Family H (Hydraulic systems), 1999. [6] N.A.Peppiatt ‘New developments in hydraulic sealing for longwall roof supports’. Paper presented at 11th International Conference on Fluid Sealing, Cannes, 8th -10th April 1987. [7] N.A.Peppiatt ‘Reciprocating Hydraulic Seals for Water-Based Fluids’. Paper presented at NFPA 47th Conference on Fluid Power, 23rd-25th April 1996. [8] N.A. Peppiatt. ‘Sealing water-based fluids’ Paper presented at 21st International Conference on Fluid Sealing, Milton Keynes, 30th Nov-1st Dec 2011. [9] ISO 6072 Rubber – Compatibility between hydraulic fluids and standard elastomeric materials, 2011. 136 Nick A. Peppiatt Hydraulic seals for water and water-based fluids