APTCO, LLC

Transcription

APTCO, LLC

APTCO, LLC
Premium Grape Boxes
Contact:
Jim Banuelos
Phone 661-792-2107
FAX: 661-792-2387
Mail Address:
1998 Road 152
Delano, CA 93215
Shipping Address:
31381 Pond Road Building 2
McFarland, CA 93250
Title Page
APTCO, LLC
Introduction to APTCO’s Expandable Polystyrene Box
What is EPS (Expandable Polystyrene)?
Expandable Polystyrene is a rigid cellular plastic that was developed for food
containers and general packaging applications. The raw material can be expanded to
a desired density for the specific application required. The designed advantages of
EPS are: EPS is inert, EPS is safe for food contact, EPS does not support bacterial
growth, EPS is resistant to moisture, EPS is recyclable, EPS has excellent insulation
properties, EPS can be processed to be strong enough to do the job and therefore
there can be a considerable weight savings over alternatives. There are many types
of EPS that are available because of the great range of applications for EPS. APTCO
is committed to select the best material for this application and to work with our
suppliers to improve the material for a better quality final product.
How is EPS expanded?
EPS arrives at APTCO as small beads in 2,205 lb containers. When controlled heat is
applied to the beads they expand to the required density. How much and how long
heat is applied determines the final density of the expanded beads. APTCO takes
special care in this part of the process to try and make every bead the same density
by controlling the process and minimizing variation in the process. If this is not done
properly heavy boxes and light boxes will result from the same mold. APTCO knows
that its customers count on every box to be capable to handle full load of three
pallets of grapes, so we precisely control the weight of the box .
Does APTCO make a heavy density box?
All APTCO boxes are made with the same density material. This material is formulated and expanded to make a box strong enough for three pallet high configuration
in cold storage for the 7L and ME boxes. Our boxes have a successful proven history
for three high configuration in cold storage. Therefore compare our standard box to
our competitors heavy density box for pricing purposes. We do not have a light density box.
How is EPS molded?
After EPS is expanded it is dried and stabilized in silos. APTCO also takes care to
control this process to minimize variation and deliver a consistently aged bead to
the molding machine. The molding process has four parts, filling the mold with
expanded beads, heating and fusing the beads into one solid mass, cooling the mass
into a rigid part and ejecting the part. APTCO has all single cavity molds to produce
the most consistent part. Multi cavity molds produce more parts but sacrifice
consistency. A multi cavity mold does not fill the same amount in each cavity, the
steam cooking process can not be identical for each cavity, and the cooling of the
mold will be slightly different for each cavity. All APTCO molds are the same and all
molding machines are the identical. The result of minimizing variation throughout
the process is a consistent part from mold to mold, cycle to cycle, day to day and
month to month.
Introduction Page 1
APTCO, LLC
What are the advantages of APTCO’s box design?
When you remove the APTCO lid, push in slightly on the bottom under the lid lock
and lift the lid off. The lid lock will keep the lid on in transit and during movement
around your cold storage. The step on the side helps lock the lid on but does not
overstress the lid lock during lid removal. The high step on the inside of the bottom
of the box prevents crushing of grapes in the seam when the lid is installed.
High lip inside
Stepped side panel to help lock lid.
Positive lid lock
Why is an APTCO box less expensive to use?
Every part of the molding process has been designed to make a consistently strong
box. APTCO’s customer’s report less wastage in the field from mishandling damage.
The new APTCO lid design is stronger, easier to use and does not damage grapes
when the lid is put on. The box was designed to stack 10 layers per pallet, three
pallets high in cold storage. This reduces your cold storage needs. The consistent
product results in straight vertical columns in cold storage that have more safety
factor than competitor’s boxes.
What are the special considerations regarding the storing and use of EPS
boxes?
EPS is highly flammable and will produce thick black smoke when burned. It is
difficult to extinguish while burning because of its cellular nature entraping oxygen.
Please review MSDS sheet enclosed for more information regarding EPS.
Precautions that are listed in the APTCO manual must be followed or catastrophic
failure of the box may result. The box is designed to be used in cold storage up to
three pallets high but damage to the box or improper stacking could cause failure
of the box resulting in a pallet column toppling. APTCO will stand behind our box
but not if it is used improperly.
Does APTCO recycle EPS?
APTCO has the equipment to recycle the scrap from APTCO and our competitors.
This scrap is recycled and does not go to the dump. Any EPS can be recycled. However construction grade EPS material should not be recycled at APTCO because the
flame retardant additive is incompatible with food packaging applications.
Introduction Page 2
APTCO, LLC
Three Pallet High Stacking in Cold Storage
What are some considerations in the pallet design for stacking three high?
The pallet must be made of utility grade or better of fir, pine or spruce wood.
The pallet must have sufficient stringers in the proper location to support the walls
of the foam box.
The pallet must transfer the load properly to the layer of boxes below the pallet.
The 7L pallet in this manual must be laid out as shown. If the boxes are laid out
backwards the stringers will not match the walls of the box.
Never cross stack boxes. Always register stack boxes to keep the load on the walls
of the box.
Immediately repair damage to pallets and boxes caused by forklift accidents.
The pallet designs in this manual have a proven successfull history stacking three
pallets high in cold storage.
Introduction Page 3
APTCO, LLC
EPS Storage in the Field
EPS boxes should not remain in the sun for more than a few days.
APTCO stores the boxes in blocks wrapped in ultraviolet protecting
black plastic to prevent sun damage, dirt contamination and wind
damage
The size of the blocks may vary due to location size. The layout of
the blocks is designed to limit the risk of fire loss. There will be
fire breaks to allow fire truck access to blocks.
There is a code painted on the block, it consists of five lines. The
first line is when the block is started which is also the day the box
is produced. The box should be at least ten days old before it is
used in cold storage. The second line is when the block is finished.
The third line is when the block is wrapped. The box is wet when
it is produced and we wrap it after the moisture has evaporated.
The fourth line is the owner of the box and the type of box. The
last line is the number of bundles in the block and the block number at this location.
Started March 30,2000
Finished March 31,2000
Wrapped March 31,2000
Sunview A7L
576 Bundles, Block 15
Introduction Page 4
APTCO, LLC
Similarity
APTCO 7L is similar to:
Styrotek STH
Agri-cel DL
APTCO ME is similar to:
Styrotek SB
Agri-cel LM
However, boxes will vary dimensionally between competitors
resulting in similar but not equivalent boxes. Mixing of boxes
within a pallet will result in uneven loading on boxes with
unpredictable results.
Do not mix APTCO and competitors’ boxes on a pallet.
Do not use a box that has aged less than 10 days since
manufactured.
Introduction Page 5
APTCO, LLC
5F
5 Boxes per layer
14 Layers to red line
70 Boxes per pallet
External Dimensions
(centimeters)
24.00
61.0
x
x
16.00
40.6
x
x
6.50
16.5
Inches
cm
Internal Dimensions
(centimeters)
22.07
56.1
x
x
14.07
35.7
x
x
5.63
14.3
Inches
cm
External Volume
2496
1.444
0.0409
IN^3
FT^3
M^3
Internal Volume
1748
1.012
0.0286
IN^3
FT^3
M^3
1.16
525
± POUNDS
± GRAMS
Weight
5 Layer Page 1
APTCO, LLC
5F Pallet Layout
There are five 5F boxes per layer.
See next page for pallet dimensions.
5 Layer Page 2
APTCO, LLC
5 Layer Page 3
APTCO, LLC
5F Cold Storage Stacking
Total Height
Boxes Per
Layers
With Pallet
Pallet
11
76.5
55
12
83.0
60
13
89.5
65
14
96.0
70
1. Stack in this manner to expose one end of each box for labeling.
2. Do not cross-stack rows. (Boxes need vertical walls to carry the weight)
Register stack all rows.
3. Add corner boards and band horizontally.
4. 14 layers 5F will be 96” in height including pallet.
5 Layer Page 4
APTCO, LLC
5F Warranty
Seller warrants that its boxes shall be of a quality suitable for
packing and shipping table grapes to market, and shall have
sufficient strength to hold 19 pounds of grapes per box, stack
boxes 14 layers high per pallet, and stack three pallets high if
stacking is performed strictly in accordance with written
instructions provided by Seller. If any box fails to perform as
specified during the calendar year in which it was delivered to
Buyer, Seller will replace that box with a box of similar
configuration and said replacement shall constitute Buyer’s sole
and exclusive remedy for breach of any representation or
warranty made by Seller. In order for Buyer to be entitled to
receive said replacement boxes, Buyer must notify Seller
immediately upon discovery of any failure, so that Seller may
inspect the failed box in the position in which failure occurred.
This warranty is in lieu of all other warranties, express or implied,
including but not limited to any implied warranty of
merchantability or fitness for any particular use. This warranty
shall not apply with respect to any failure resulting from any
misuse or abuse of boxes, including but not limited to any failure
to use and store boxes in manner specified by Seller. In no event
shall Seller be responsible for incidental or consequential
damages, or any loss or injury to persons or products, arising
from or in connection with the use of these boxes.
5 Layer Page 5
APTCO, LLC
5G
5 Boxes per layer
15 Layers to red line
75 Boxes per pallet
External Dimensions
(centimeters)
24.00
61.0
x
x
16.00
40.6
x
x
6.06
15.4
Inches
cm
Internal Dimensions
(centimeters)
22.07
56.1
x
x
14.07
35.7
x
x
5.19
13.2
Inches
cm
External Volume
2327
1.347
0.0381
IN^3
FT^3
M^3
Internal Volume
1612
0.933
0.0264
IN^3
FT^3
M^3
1.10
501
± POUNDS
± GRAMS
Weight
5 Layer Page 6
APTCO, LLC
5G Pallet Layout
There are five 5G boxes per layer.
5 Layer Page 7
APTCO, LLC
5 Layer Page 8
APTCO, LLC
5G Cold Storage Stacking
Total Height
Boxes Per
Layers
With Pallet
Pallet
12
77.7
60
13
83.8
65
14
89.8
70
15
95.9
75
3. Add corner boards and band horizontally. Corner boards should be fastened to the pallet.
4. 15 layers 5G will be 96” in height including pallet.
5 Layer Page 9
APTCO, LLC
5G Warranty
This warranty is in lieu of all other warranties, express or implied,
including but not limited to any implied warranty of
misuse or abuse of boxes, including but not limited to any failure
to use and store boxes in manner specified by Seller. In no event
shall Seller be responsible for incidental or consequential
damages, or any loss or injury to persons or products, arising
from or in connection with the use of these boxes.
5 Layer Page 10
APTCO, LLC
5S
24x16
External Dimensions
(centimeters)
24.00
61.0
x
x
16.00
40.6
x
x
5.69
14.4
Inches
cm
Internal Dimensions
21.07
x
14.07
x
4.81
Inches
(centimeters)
53.5
x
35.7
x
12.2
cm
External Volume
2184
1.264
0.0358
IN^3
FT^3
M^3
Internal Volume
1426
0.825
0.0234
IN^3
FT^3
M^3
1.07
485
± POUNDS
± GRAMS
Weight
5 Layer Page 11
APTCO, LLC
5S Pallet Layout
There are five 24x16 boxes per layer.
5 Layer Page 12
APTCO, LLC
5 Layer Page 13
APTCO, LLC
5S Cold Storage Stacking
Total Height Boxes Per
Layers With Pallet
Pallet
13
78.9
65
14
84.6
70
15
90.3
75
16
96.0
80
4. This configuration is 96” high.
5 Layer Page 14
APTCO, LLC
5S Warranty
This warranty is in lieu of all other warranties, express or
implied, including but not limited to any implied warranty of
misuse or abuse of boxes, including but not limited to any
failure to use and store boxes in manner specified by Seller. In
no event shall Seller be responsible for incidental or
consequential damages, or any loss or injury to persons or
products, arising from or in connection with the use of these
boxes.
5 Layer Page 15
APTCO, LLC
ME
20x16
External Dimensions
(centimeters)
20.00
50.8
x
x
16.00
40.6
x
x
6.75
17.1
Inches
cm
Internal Dimensions
(centimeters)
18.13
46.0
x
x
14.19
36.0
x
x
5.75
14.6
Inches
cm
External Volume
2160
1.250
0.0354
IN^3
FT^3
M^3
Internal Volume
1479
0.856
IN^3
FT^3
0.0242
M^3
1.05
478
± POUNDS
± GRAMS
Weight
6 Layer Page 1
APTCO, LLC
ME Pallet Layout
There are six ME boxes per layer.
6 Layer Page 2
APTCO, LLC
6 Layer Page 3
APTCO, LLC
ME Pallet Stack
There are 72 ME boxes per pallet;
6 boxes per layer, 12 layers per pallet.
Total Height
Boxes Per
Layers
With Pallet
Pallet
10
72.5
60
11
79.3
66
12
86.0
72
13
92.8
78
6 Layer Page 4
APTCO, LLC
ME Warranty
configuration and said replacement shall constitute Buyer’s
sole and exclusive remedy for breach of any representation or
boxes.
6 Layer Page 5
APTCO, LLC
6N
6 Boxes per layer
14 layers per pallet
2 Pallets high
External Dimensions
(centimeters)
20.00
50.8
x
x
16.00
40.6
x
x
6.44
16.4
Inches
cm
Internal Dimensions
(centimeters)
18.13
46.1
x
x
14.56
37.0
x
x
5.50
14.0
Inches
cm
External Volume
2061
1.193
0.0338
IN^3
FT^3
M^3
Internal Volume
1452
0.840
0.0238
IN^3
FT^3
M^3
0.94
428
± POUNDS
± GRAMS
Weight
6 Layer Page 6
APTCO, LLC
6N Pallet Layout
There are six 6N boxes per layer.
6 Layer Page 7
APTCO, LLC
6 Layer Page 8
APTCO, LLC
6N Pallet Stack
6 Boxes per layer
14 layers per pallet
2 Pallets high limit
Total Height
Boxes Per
Layers
With Pallet
Pallet
11
75.8
66
12
82.3
72
13
88.7
78
14
95.2
84
4. This is not a three pallet high box
6 Layer Page 9
APTCO, LLC
6N Warranty
boxes 14 layers high per pallet, and stack two pallets high if
sole and exclusive remedy for breach of any representation or
boxes.
6 Layer Page 10
APTCO, LLC
7L
20x13.25
7 boxes per layer
External Dimensions
(centimeters)
20.00
50.8
x
x
13.25
33.7
x
x
7.75
19.7
Inches
cm
Internal Dimensions
(centimeters)
17.75
45.1
x
x
11.50
29.2
x
x
6.75
17.1
Inches
cm
External Volume
2054
1.189
0.0337
IN^3
FT^3
M^3
Internal Volume
1378
0.797
0.0226
IN^3
FT^3
M^3
1.01
459
± POUNDS
± GRAMS
Weight
7 Layer Page 1
APTCO, LLC
7L Pallet Layout
There are seven 7L boxes per layer.
7 Layer Page 2
APTCO, LLC
7 Layer Page 3
APTCO, LLC
7L Pallet Stack
There are 70 7L boxes per pallet;
7 per layer, 10 layers high.
Total Height
Boxes Per
Layers
With Pallet
Pallet
9
74.8
63
10
82.5
70
11
90.3
77
12
98.0
84
4. This configuration is 82½” high.
7 Layer Page 4
APTCO, LLC
7L Warranty
specified during the calendar year in which it was delivered
to Buyer, Seller will replace that box with a box of similar
sole and exclusive remedy for breach of any representation
or warranty made by Seller. In order for Buyer to be entitled
to receive said replacement boxes, Buyer must notify Seller
inspect the failed box in the position in which failure
occurred.
merchantability or fitness for any particular use. This
warranty shall not apply with respect to any failure resulting
from any misuse or abuse of boxes, including but not limited
to any failure to use and store boxes in manner specified by
Seller. In no event shall Seller be responsible for incidental or
boxes.
7 Layer Page 5
APTCO, LLC
B7
20.5x13.6
7 boxes per layer
External Dimensions
(centimeters)
20.50
52.1
x
x
13.63
34.6
x
x
7.75
19.7
Inches
cm
Internal Dimensions
(centimeters)
18.19
46.2
x
x
11.70
29.7
x
x
6.75
17.1
Inches
cm
External Volume
2165
1.253
0.0355
IN^3
FT^3
M^3
Internal Volume
1437
0.831
0.0235
IN^3
FT^3
M^3
1.09
495
± POUNDS
± GRAMS
Weight
7 Layer Page 6
APTCO, LLC
B7 Pallet Layout
There are seven B7 boxes per layer.
7 Layer Page 7
APTCO, LLC
7 Layer Page 8
APTCO, LLC
B7 Pallet Stack
There are 70 B7 boxes per pallet;
Total Height
Boxes Per
Layers
With Pallet
Pallet
9
74.8
63
10
82.5
70
11
90.3
77
12
98.0
84
4. This configuration is 82½” high.
7 Layer Page 9
APTCO, LLC
B7 Warranty
occurred.
boxes.
7 Layer Page 10
APTCO, LLC
C7
20.5x13.625
7 boxes per layer
12 Layers per pallet
External Dimensions
(centimeters)
20.50
52.1
x
x
13.63
34.6
x
x
7.56
19.2
Inches
cm
Internal Dimensions
(centimeters)
18.25
46.4
x
x
11.69
29.7
x
x
6.56
16.7
Inches
cm
External Volume
2112
1.222
0.0346
IN^3
FT^3
M^3
Internal Volume
1400
0.810
0.0229
IN^3
FT^3
M^3
1.04
471
± POUNDS
± GRAMS
Weight
7 Layer Page 11
APTCO, LLC
C7 Pallet Layout
There are seven C7 boxes per layer.
7 Layer Page 12
APTCO, LLC
7 Layer Page 13
APTCO, LLC
C7 Pallet Stack
20.5x13.625
7 boxes per layer
Total Height
Boxes Per
Layers
With Pallet
Pallet
9
73.0
63
10
80.6
70
11
88.2
77
12
95.7
84
4. This configuration is 95 3/4” high.
7 Layer Page 14
APTCO, LLC
C7 Warranty
occurred.
boxes.
7 Layer Page 15
APTCO, LLC
7N
20.5 x 13.625
7 boxes per layer
External Dimensions
(centimeters)
20.50
52.1
x
x
13.63
34.6
x
x
7.50
19.1
Inches
cm
Internal Dimensions
(centimeters)
18.64
47.3
x
x
12.12
30.8
x
x
6.63
16.8
Inches
cm
External Volume
2096
1.213
0.0343
IN^3
FT^3
M^3
Internal Volume
1498
0.867
0.0245
IN^3
FT^3
M^3
0.89
403
± POUNDS
± GRAMS
Weight
7 Layer Page 16
APTCO, LLC
7N Pallet Layout
There are seven 7N boxes per layer.
7 Layer Page 17
APTCO, LLC
7 Layer Page 18
APTCO, LLC
7N Pallet Stack
20.5 x 13.625
7 boxes per layer
Total Height
Boxes Per
Layers
With Pallet
Pallet
9
72.5
63
10
80.0
70
11
87.5
77
12
95.0
84
4. This configuration is 95” high.
7 Layer Page 19
APTCO, LLC
7N Warranty
boxes 11 layers high per pallet, and stack two pallets high if
occurred.
boxes.
7 Layer Page 20
APTCO, LLC
8L
20x12
8 boxes per layer
External Dimensions
19.88
x
11.88
x
8.50
Inches
(centimeters)
50.5
x
30.2
x
21.6
cm
Internal Dimensions
17.95
x
10.07
x
7.63
Inches
(centimeters)
45.6
x
25.6
x
19.4
cm
External Volume
2006
1.161
IN^3
FT^3
0.0329
M^3
1378
0.798
0.0226
IN^3
FT^3
M^3
0.95
429
± POUNDS
± GRAMS
Internal Volume
Weight
8 Layer Page 1
APTCO, LLC
8L Pallet Layout
There are eight 8L boxes per layer.
8 Layer Page 2
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APTCO, LLC
8L Pallet Stack
There are 80 8L boxes per pallet;
Total Height Boxes Per
Layers
With Pallet
Pallet
8
73.0
64
9
81.5
72
10
90.0
80
11
98.5
88
8 Layer Page 4
APTCO, LLC
8L Warranty
occurred.
boxes.
8 Layer Page 5
APTCO, LLC
5K
16x12
External Dimensions
(centimeters)
15.75
40.0
x
x
11.88
30.2
x
x
6.88
17.5
Inches
cm
Internal Dimensions
(centimeters)
14.13
35.9
x
x
10.25
26.0
x
x
5.75
14.6
Inches
cm
External Volume
1287
0.745
0.0211
IN^3
FT^3
M^3
Internal Volume
832
0.482
0.0136
IN^3
FT^3
M^3
0.67
306
± POUNDS
± GRAMS
Weight
10 Layer Page 1
APTCO, LLC
5K Pallet Layout
There are ten 5K boxes per layer.
10 Layer Page 2
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5 6#
*
(
788
% 0
3 '
% 3
-
APTCO, LLC
5K Pallet Stack
Ten 5K boxes per layer, up to ten layers per pallet.
Total Height
Boxes Per
Layers
With Pallet
Pallet
10
73.8
100
11
80.7
110
12
87.6
120
13
94.4
130
1. Do not cross-stack rows. (Boxes need vertical walls to carry the
weight) Register stack all rows.
10 Layer Page 4
APTCO, LLC
5K Warranty
Seller warrants that its boxes shall be of a quality
suitable for packing and shipping table grapes to
market, and shall have sufficient strength to hold 11
pounds of grapes per box, stack boxes 10 layers high
per pallet, and stack three pallets high if stacking is
performed strictly in accordance with written
instructions provided by Seller. If any box fails to
perform as specified during the calendar year in which
it was delivered to Buyer, Seller will replace that box
with a box of similar configuration and said
replacement shall constitute Buyer’s sole and exclusive
remedy for breach of any representation or warranty
made by Seller. In order for Buyer to be entitled to
receive said replacement boxes, Buyer must notify
Seller immediately upon discovery of any failure, so
that Seller may inspect the failed box in the position in
which failure occurred.
This warranty is in lieu of all other warranties, express
or implied, including but not limited to any implied
warranty of merchantability or fitness for any particular
use. This warranty shall not apply with respect to any
failure resulting from any misuse or abuse of boxes,
including but not limited to any failure to use and store
boxes in manner specified by Seller. In no event shall
Seller be responsible for incidental or consequential
damages, or any loss or injury to persons or products,
arising from or in connection with the use of these
boxes.
10 Layer Page 5
APTCO
1998 Rd 152
Delano, CA 93215
ATTN: Jim Banulos
March 16, 2006
RE: - Huntsman EPS Products Grades 55 and 71
FDA Compliance Title 21 CFR Section 177.1640,
And Title 21 CFR 174.5 and 21 CFR 106 and 107
Dear Mr. Banulos,
Thank you for your interest in Huntsman EPS packaging materials. This letter is in response to
your request regarding compliance to FDA guidelines.
In reference to FDA regulations 21 CFR 177.1640 "Polystyrene and rubber-modified
polystyrene" and 21 CFR 174.5 and 21 CFR 106 and 107. Huntsman guarantees that each
shipment of our EPS resin products, grades 55 and 71, complies with all applicable
requirements of intended use set forth in Federal Food Drug and Cosmetic Act, as amended, and
all applicable food additive regulations, provided they are used for the intended purpose under
the conditions of Good Manufacturing Practice (GMP). As such, these Huntsman EPS grades
may be used in the manufacture of shipping boxes to hold aqueous foods (such as grapes) and ice
coolers for household use and other such items. It is important to note that this guarantee
applies only to these specified grades of our EPS resin products. Other grades may not
conform to FDA regulations.
Records relating to the manufacture of these materials will be maintained by Huntsman for at
least 3 years in the event that a FDA review is required.
If I can provide any additional information or assistance, please call me at 757-546-7767, or
contact me via e-mail at: Joe_Casassa@Huntsman.com
Regards,
Joseph F Casassa
Huntsman Expandable Polystyrene Company, LC.
Customer and Sales Support / Code and Regulatory Compliance
CC: Steve Hockman - Huntsman
HUNTSMAN EXPANDABLE POLYMERS COMPANY, LC.
900 Baydon Lane • Chesapeake, Virginia 23322 • 757-546-7767 • Fax 757-546-8369
NOVA Chemicals Corporation
6711 Mississauga Rd., Suite 200
Mississauga, Ontario, Canada L5N 2W3
Telephone: (905) 542-6992
Fax: (905) 542-8075
Toll Free: 1-800-268-2507
August 6, 2003
By E-Mail: jarvies@novachem.com
Aptco, LLC.
1998 Road 152
Delano, CA 93215
File: 2150-10-1
To Whom It May Concern:
Re: Regulatory Compliance of NOVA Chemicals Inc. Expandable Polystyrene Resins
(EPS) R330B, D240B and D175B
This letter is in response to your request regarding the above grades of NOVA Chemicals EPS
Resins to our Mr. Shawn Jarvie.
NOVA Chemicals has a letter from its legal counsel giving the opinion that the subject resins
comply with the United States Federal Food, Drug and Cosmetic Act and all applicable Food
and Drug Administration (FDA) regulations. The resins comply with Title 21 of the US Code of
Federal Regulations, Section 177.1640 "Polystyrene and rubber-modified polystyrene" as it is in
effect on the date of this letter. The resins may be used in the manufacture of shipping boxes to
hold aqueous foods (such as grapes) and ice coolers for household use.
As noted below, we cannot however be held responsible for any processing which may occur to
produce finished articles, packaging materials, or their component(s).
This information is believed to be correct as of the date of this letter. However, since regulations
are subject to change we recommend that you contact us in one year's time to confirm the
regulatory status.
I trust this information will be sufficient for your needs. If you require further information, please
contact the undersigned at (905) 542-6992, by fax at (905) 542-8075, or by e-mail at
santrylj@novachem.com.
Yours sincerely,
Linda J. Santry, Ph.D.
Senior Advisor, Product Regulatory Compliance
Product Integrity
cc: J. Quinlan - email
Although the above information is provided in good faith, NOVA Chemicals cannot be held responsible for any processing or compounding
which may occur to produce finished articles, packaging materials or their components. Further NOVA CHEMICALS MAKES NO
WARRANTY OR REPRESENTATION OF ANY KIND, REGARDING THE INFORMATION GIVEN OR THE PRODUCTS DESCRIBED, AND
EXPRESSLY DISCLAIMS ALL IMPLIED WARRANTIES, REPRESENTATIONS AND CONDITIONS, INCLUDING WITHOUT LIMITATION
ALL WARRANTIES AND CONDITIONS OF QUALITY, MERCHANTABILITY AND SUITABILITY OR FITNESS FOR A PARTICULAR
PURPOSE. Responsibility for use, storage, handling and disposal of the products described herein is that of the purchaser or end user.
Aptco LLC EPS FDA status .doc
MATERIAL SAFETY DATA SHEET
READ AND UNDERSTAND MATERIAL SAFETY DATA SHEET BEFORE HANDLING OR DISPOSING
OF PRODUCT
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
EXPANDABLE POLYSTYRENE (EPS)
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
MATERIAL IDENTITY
MSDS CODE AND NAME
GRADE 71NS
GRADE71
1
B
Chemical Name and/or Family or Description:
Chemical Name: Polystyrene thermoplastic polymer
Synonym(s): EPS
Molecular Formula: (C8H8)X
COMPANY INFORMATION
Huntsman Corporation
P.O. Box 4980
The Woodlands, TX 77387-4980
TELEPHONE NUMBERS
Transportation Emergency
Company:
(800) 328-8501
CHEMTREC: (800) 424-9300
Medical Emergency: (409) 722-9673 (24 Hour)
General MSDS Assistance: (281) 719-6432
Technical Information:
(800) 972-1010
2. COMPOSITION AND INFORMATION ON INGREDIENTS
THE CRITERIA FOR LISTING COMPONENTS IN THE COMPOSITION SECTION ARE AS FOLLOWS: CARCINOGENS ARE LISTED WHEN
PRESENT AT 0.1 % OR GREATER; COMPONENTS WHICH ARE OTHERWISE HAZARDOUS ACCORDING TO OSHA ARE LISTED WHEN
PRESENT AT 1.0 % OR GREATER; NON-HAZARDOUS COMPONENTS ARE LISTED AT 3.0 % OR GREATER. THIS IS NOT INTENDED
TO BE COMPLETE COMPOSITIONAL DISCLOSURE. REFER TO SECTION 14 FOR APPLICABLE STATES' RIGHT TO KNOW AND
OTHER REGULATORY INFORMATION.
Product and/or Component(s) Carcinogenic According to:
OSHA____
IARC____
NTP____
OTHER____
NONE__X__
Composition:
Chemical Name
CAS Number
Benzene, ethenyl-, homopolymer (Common name:
Polystyrene)
Pentane
9003-53-6
Exposure Limits
600 ppm TWA ACGIH
1000 ppm TWA OSHA
750 ppm STEL OSHA
120 ppm TWA (Canada)
350 mg/m3 TWA (Canada)
109-66-0
* May contain trace amounts of styrene. See Section 11 for additional information.
1
Range in %
>92.6
< 7.0
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Solid, white beads
Odor:
Slight hydrocarbon odor
WARNING STATEMENT
EXTREMELY FLAMMABLE VAPOR
VAPOR MAY CAUSE FLASH FIRE
VAPOR MAY CAUSE DIZZINESS AND DROWSINESS
VAPOR MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT
DANGER!
Hazardous Material
Information System
(United States)
Health
1
Fire
3
0
Reactivity
National Fire Protection
Association NFPA
(United States)
3
Health
1
Personal protection
Flammability
0
Reactivity
Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye__X__
Skin__X__
Inhalation__X__
Ingestion____
Effects of Overexposure
Acute:
Eyes:
Skin:
Inhalation:
Ingestion:
Sensitization Properties:
Vapor may cause irritation, experienced as discomfort, with excess tear production and
blinking, and seen as excess redness of the eye. Product may contain residual amounts of
dust or small particulates which may cause eye irritation or abrasion experienced as mild
discomfort and slight excess redness of the eye.
Product may contain residual amounts of dust or small particulates that may cause skin
irritation or abrasion experienced as local redness with possible mild discomfort.
Vapors or mist may cause irritation of the nose and throat. Inhalation may cause dizziness,
drowsiness, euphoria, loss of coordination, disorientation, headache, nausea, and vomiting.
In poorly ventilated areas or confined spaces, unconsciousness and asphyxiation may result.
Prolonged or repeated overexposure may result in the absorption of potentially harmful
amounts of material.
Dust may cause irritation of the nose and throat. Overexposure to high concentrations of
dust may cause respiratory irritation, experienced as coughing and difficulty breathing.
If more than several mouthfuls are swallowed, abdominal discomfort, nausea, and diarrhea
may occur.
Unknown
Chronic:
Prolonged or repeated inhalation of dust or particulates may impair lung function or cause lung damage.
Medical Conditions Aggravated by Exposure:
Overexposure to vapor, dust or mist may aggravate existing respiratory conditions, such as asthma, bronchitis, and
inflammatory or fibrotic respiratory disease.
2
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
Other Remarks:
None
4. FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for several minutes. Remove larger particulates from the eye as one would any foreign object.
Get medical attention if eye irritation persists or particulates are difficult to remove from the eye.
Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if skin irritation develops or persists.
Ingestion:
If more than several mouthfuls of this material are swallowed, give two glasses of water (16 oz.). Get medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, clear person's airway and give artificial respiration. If breathing is difficult,
qualified medical personnel may administer oxygen. Get medical attention immediately.
Other Instructions:
None.
5. FIRE-FIGHTING MEASURES
Ignition Temperature - AIT (degrees C):
260
471
(500 F) for Pentane
(880 F) by ASTM D-1929 Expanded polystyrene
Flash Point (degrees C):
-40
(-40 F) CC for Pentane
Flammable Limits % (Lower-Upper):
Lower: 1.5 for Pentane
Upper: 7.8 for Pentane
Recommended Fire Extinguishing Agents And Special Procedures:
Water may be ineffective on flames but should be used to cool fire-exposed containers and provide protection for persons
attempting to stop the leak. Use water spray, dry chemical, foam or carbon dioxide to extinguish flames.
Unusual or Explosive Hazards:
Danger! Extremely flammable materials may release vapors that travel long distances, ignite, and flash back. Containers may
explode in a fire. Do not expose to heat, sparks, flame, static, or other sources of ignition. When handling, use non-sparking
tool, ground and bond all containers.
Explosive air-vapor mixtures may form. Fire gives off dense black smoke and acid gasses. Electrostatic discharge can be a
source of ignition due to accumulated pentane vapors exceeding the L.E.L. (lower explosive limit) of 1.5% (15,000 ppm).
Pentane vapors may be emitted from newly opened containers or when the product is heated. If ignited, there could be a very
high rate of flame propagation.
"NO SMOKING - NO MATCHES - NO LIGHTERS - NO WELDING" rules should be enforced.
Special Protective Equipment for Firefighters:
Wear full protective clothing and positive pressure breathing apparatus.
3
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills: CHEMTREC (800)424-9300)
Procedures in Case of Accidental Release, Breakage or Leakage:
Avoid the generation of dust clouds. Place in appropriate containers for disposal or recycle. Avoid breathing dust. Pressure
demand air supplied respirators should always be worn when the airborne concentration of the contaminant or oxygen is
unknown. Otherwise, wear respiratory protection and other personal protective equipment as appropriate for the potential
exposure hazard. Wear gloves, goggles, and protective clothing to avoid contact with eyes, skin, or clothing. Use vacuuming
or sweeping compound for clean-up. Do not dry sweep or use methods which increase dusting. Prevent entry into sewers and
waterways.
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Use spark-proof tools. Material may be at elevated temperatures and/or pressures. Exercise care when opening bleeders
and sampling ports.
Storage:
Ground and bond shipping container, transfer line, and receiving container. Keep away from heat, sparks, flame, and other
sources of ignition.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Avoid eye contact. Chemical type goggles should be worn. Do not wear contact lenses.
Skin Protection:
Workers should wash exposed skin several times daily with soap and water. Soiled work clothing should be laundered or
dry-cleaned.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or dust is generated and the occupational
exposure limit of the product, or any component of the product, is exceeded, use appropriate NIOSH or MSHA approved air
purifying or air supplied respirator after determining the airborne concentration of the contaminant. Air supplied respirators
should always be worn when airborne concentration of the contaminant or oxygen content is unknown.
Ventilation:
Use explosion-proof equipment to maintain adequate ventilation to meet occupational exposure limits, if applicable (see
below), prevent accumulation of explosive air-gas mixtures, and avoid significant oxygen displacement. Oxygen levels should
be at least 19.5% in confined spaces or other work areas (OSHA value).
Exposure Limit for the Total Product:
None established for product; refer to Section 2 for component exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance:
Solid, white beads
Odor:
4
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
Boiling Point (degrees C):
Not applicable
Melting/Freezing Point (degrees C):
Softens and expands at 93.3-101.7 C (200-215 F)
Specific Gravity (water=1):
Depending on bulk density of the product, the material may float on the top of water.
pH:
Not applicable.
Vapor Pressure:
Negligible
Viscosity:
Not applicable
VOC Content:
Not determined.
Vapor Density (Air=1):
>1
Solubility in Water (%):
< 0.1
Other:
None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
Air____
Water____
Heat__X__
Strong Oxidizers__X__
Others____
None of these____
Comments:
None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones.
Hazardous Polymerizations:
DO NOT OCCUR
11. TOXICOLOGICAL INFORMATION
TOXICOLOGICAL INFORMATION (ANIMAL TOXICITY DATA)
Oral:
LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Not determined.
Dermal:
LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic
IRRITATION INDEX, ESTIMATION OF IRRITATION (SPECIES)
5
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
Skin:
(Draize) Believed to be > .50 - 3.00 /8.0 (rabbit) slightly irritating
Eyes:
(Draize) Believed to be > 15.00 - 25.00 /110 (rabbit) slightly irritating
Sensitization:
Not determined.
Other:
Product may contain dust or particulates that may cause eye irritation or abrasion.
This product may contain residual styrene. Typical concentrations are less than 0.1%. Please refer to product-specific
purchasing specifications for information on residual styrene content of this product.
Chronic (lifetime) exposure to styrene resulted in bronchoalveolar (lung) tumors in mice, but not in rats. The relevance of these
cell-type specific mouse lung tumors to humans is not known. Nasal effects were also observed in these rats and mice
exposed to styrene. In subchronic exposure studies, repeated exposures of female mice to styrene resulted in liver toxicity,
however, this effect was not observed in rats.
12. DISPOSAL CONSIDERATIONS:
Waste Disposal Methods:
This material should be disposed of in accordance with local, state and federal regulations.
Remarks:
Do not allow to enter drains or sewers.
13. TRANSPORT INFORMATION
Transportation
DOT:
Proper Shipping Name:
Polymeric beads, expandable
Hazard Class:
9
Identification Number:
UN 2211
Packing Group:
III
Label Required:
Class 9
IMDG
Hazard Class
9
Identification Number
UN 2211
Packing Group
III
6
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
Label Required
Class 9 (See Section 16 for additional information)
ICAO
Hazard Class
9
Identification Number
UN 2211
Packing Group
III
Label Required
Class 9 (See Section 16 for additional information)
TDG
Hazard Class:
9
Identification Number:
UN 2211
Label Required:
Class 9 (per UN recommendations, black vertical stripes)
14. REGULATORY INFORMATION
Federal Regulations:
SARA Title III:
Section 302/304 Extremely Hazardous Substances
Chemical Name
CAS Number
Range in %
TPQ
RQ
None.
Section 311 Hazardous Categorization:
Acute__X__
Chronic__X__
Fire__X__
Pressure____
Reactive____
N/A____
Section 313 Toxic Chemical
Chemical Name
CAS Number
Concentration
None.
CERCLA 102(a)/DOT Hazardous Substances:
Chemical Name
CAS Number
Range in %
RQ
None.
States Right-to-Know Regulations:
Chemical Name
State Right-to-know
Pentane
FL, MA, MN, NJ, PA, RI
California Prop. 65:
The following detectable components of this product are substances, or belong to classes of substances, known to the State of
California to cause cancer and/or reproductive toxicity.
7
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
Chemical Name
CAS Number
None.
INTERNATIONAL REGULATIONS:
TSCA Inventory Status:
This product, or its components, are listed on, or are exempt from the Toxic Substance Control Act (TSCA) Chemical Substance
Inventory.
WHMIS Classification:
Not determined.
Canadian Inventory Status:
This product, or its components, are listed on or are exempt from the Canadian Domestic Substance List (DSL).
EINECS Inventory Status:
This product, or its components, are listed on or are exempt from the European Inventory of Existing Chemical Substances
(EINECS) or the European List of Notified Chemical Substances (ELINCS).
Australian Inventory Status:
This product, or its components, are listed on or are exempt from the Australian Inventory of Chemical Substances (AICS).
Japan Inventory Status:
This product, or its components, are listed on or are exempt from the Japanese Ministry of International Trade and Industry (MITI)
inventory.
15. ENVIRONMENTAL INFORMATION
Aquatic Toxicity:
Not applicable.
Mobility:
Not applicable.
Persistence and Biodegradability:
This product is expected to persist in the environment.
Potential to Bioaccumulate:
Not applicable.
Remarks:
Sewer/waterways obstruction; fish may eat beads and obstruct their digestive tract.
16. OTHER INFORMATION 9/20/2005
European, ADR regulations require additional marking (see item 2912) "Keep Away From Any Source of Ignition." Vessel carriers request
marking warning "No Smoking or Open Flame" on box doors.
Supercedes: 3/31/2003
The following sections have been revised: 2, 11
Date Issued: 9/20/2005.
8
MSDS CODE AND NAME
DATE ISSUED
DATE PRINTED
COMPANY
:
:
:
:
GRADE 71NS
9/20/2005
9/20/2005
HUNTSMAN
THE INFORMATION IN THIS DATA SHEET IS PROVIDED INDEPENDENTLY OF ANY SALE OF THE PRODUCT. IT IS PROVIDED
FOR THE PURPOSE OF HAZARD COMMUNICATION AS PART OF HUNTSMAN’S PRODUCT SAFETY PROGRAM. IT IS
INTENDED ONLY AS A GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE PRODUCT BY A PROPERLY
TRAINED PERSON. YOU ARE ENCOURAGED AND REQUESTED TO ADVISE THOSE WHO MAY COME IN CONTACT WITH
SUCH PRODUCTS OF THE INFORMATION CONTAINED HEREIN. THE DATA RELATES ONLY TO THE SPECIFIC PRODUCT
DESIGNATED, AND DOES NOT RELATE TO USE OF THE PRODUCT IN COMBINATION WITH ANY OTHER MATERIAL OR USE
OF THE PRODUCT IN ANY PROCESS. THE DATA IS NOT INTENDED TO CONSTITUTE PERFORMANCE INFORMATION
CONCERNING THE PRODUCT. NO EXPRESS WARRANTY, OR IMPLIED WARRANTY OF MERCHANTABILITY FOR FITNESS
FOR A PARTICULAR PURPOSE IS MADE WITH RESPECT TO THE PRODUCT, ITS COMPOSITION, ITS SAFETY OR THE
INFORMATION CONTAINED IN THIS DATA SHEET.
TO DETERMINE THE APPLICABILITY OR THE EFFECTS OF ANY LAW OR REGULATION WITH RESPECT TO THE PRODUCT,
THE USER SHOULD CONSULT A LEGAL ADVISOR OR THE APPROPRIATE GOVERNMENT AGENCY. HUNTSMAN DOES NOT
UNDERTAKE TO FURNISH ADVICE ON SUCH MATTERS.
CURRENT DATA SHEETS ARE AVAILABLE FOR ALL HUNTSMAN PRODUCTS. YOU ARE URGED TO OBTAIN DATA SHEETS
FOR ALL HUNTSMAN PRODUCTS YOU BUY, USE OR DISTRIBUTE BY CALLING (281) 719-6432 OR DIRECTING YOUR
INQUIRIES TO:
HUNTSMAN
MANAGER, PRODUCT SAFETY
P.O. BOX 4980
THE WOODLANDS, TX 77387-4980
NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE OR
MAKE AVAILABLE DATA SHEETS FOR HUNTSMAN PRODUCTS. DATA SHEETS FROM UNAUTHORIZED SOURCES MAY
CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE. NO PART OF THIS DATA SHEET MAY BE
REPRODUCED OR TRANSMITTED IN ANY FORM, OR BY ANY MEANS, WITHOUT PERMISSION IN WRITING FROM
HUNTSMAN. ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE
DIRECTED TO HUNTSMAN, MANAGER, PRODUCT SAFETY AT THE ABOVE ADDRESS.
COPYRIGHT © BY HUNTSMAN CORPORATION. ALL RIGHTS RESERVED.
Material Safety Data Sheet
Material Name: NOVA Chemicals Expandable Polystyrene Regular Grade
MSDS ID: NOVA-0054
Section 1 - Product and Company Identification
Synonyms: Foamable Polystyrene, EPS
Chemical Name: Expandable Polystyrene
Chemical Family: Plastic
Material Use: Petrochemical Industry: Plastics.
Chemical Formula: Mixture
NOVA Chemicals Inc.
1550 Coraopolis Heights Road
Moon Township, PA 15108
In case of Emergency
1-800-561-6682, 1-403-314-8767 (NOVA Chemicals)(24 hours)
1-800-424-9300 (CHEMTREC-USA)
1-613-996-6666 (Canutec-Canada)(24 hours)
Section 2 - Composition / Information on Ingredients
CAS #
9003-53-6
109-66-0
78-78-4
287-92-3
Component
Polystyrene
n-Pentane
Isopentane
Cyclopentane
* All pentanes (normal-, iso-, and cyclo-) combined
Percent by Wt.
92-97
3-8*
0-3*
0-3*
3-8
Additional Information
According to 29 CFR 1910.1200 (Hazard Communication), polystyrene polymer product is not hazardous. The
blowing agent used in the product is considered hazardous.
See Section 8 for applicable exposure limits. See Section 11 for applicable toxicity data.
Section 3 - Hazards Identification
HMIS Ratings: Health: 1 Fire: 3 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
NFPA Ratings: Health: 1 Fire: 3 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
Emergency Overview
DANGER FLAMMABLE Product is a white bead (0.25 - 2.0mm diameter) with a slight hydrocarbon odor. This
product can release a gas that is highly flammable in the presence of open flames, lit cigarettes, sparks, static
electricity discharges, or heat. The blowing agent may be irritating to the eyes, respiratory system and skin. Not
resistant to oxidizing agents, dissolves in organic solvents. When heated to decomposition, product emits acrid
smoke and irritating fumes. Slipping hazard.
Potential Health Effects: Eyes
This product may cause irritation to the eyes.
Potential Health Effects: Skin
This product may cause irritation to the skin from repetitive handling.
Potential Health Effects: Ingestion
This product may be harmful if it is swallowed. Mechanical irritation and blockage of the digestive tract are
possible.
Potential Health Effects: Inhalation
This product may cause irritation to the respiratory system.
____________________________________________________________
Page 1 of 9
Issue Date: 07/17/03
Revision: 2.0000
Print Date: 7/25/2003
MSDS ID: NOVA-0054
Section 4 - First Aid Measures
First Aid: Eyes
Check for and remove any contact lenses. Immediately flush eyes with water for at least 15 minutes, while holding
eyelids open. Seek medical attention at once.
First Aid: Skin
This product may cause irritation to the skin from repetitive handling. Remove contaminated clothing. Wash the
affected skin gently and thoroughly with running water and non-abrasive soap. Seek medical attention.
First Aid: Inhalation
Move person to non-contaminated air. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is
difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It
may be dangerous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is
toxic, infectious or corrosive. Seek medical attention.
First Aid: Ingestion
Not normally expected to present an ingestion hazard. If ingestion occurs, maintain an open airway and seek
medical attention. Watch for an obstruction in the victim's mouth. Remove, if possible, but do not force fingers or a
hard object between victim's teeth.
First Aid: Notes to Physician
Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient.
After adequate first aid, no further treatment is required unless symptoms reappear.
Section 5 - Fire Fighting Measures
Flammability Class:
Upper flammability limit:
Lower flammability limit:
Extremely Flammable (based on pentane)
8.3% (bas ed on blowing agent)
1.4% (based on blowing agent)
Flash Point:
Flash Point Method:
Auto Ignition:
-49ºC (-56ºF) (For Pentane**)
** Closed Cup (Tagliabue)
427ºC (~800.6ºF) (For
Polystyrene)
General Fire Hazards
Dangerous fire and explosion risk. Vigorously supports combustion. When heated to decomposition, product
emits acrid smoke and irritating fumes. Vapors are heavier than air and may travel along the ground to some
distant source of ignition and flash back. Move containers from the fire area if this can be done without risk.
Explosion Hazards
Vapors are heavier than air and may travel along the ground to some distant source of ignition and flash back.
Hazardous Combustion Products
Styrene, oxides of carbon, and other toxic gases at elevated temperatures.
Extinguishing Media
Dry chemical, foam, carbon dioxide, water fog or water spray. Use water to cool fire-exposed containers and to
protect personnel.
Fire Fighting Equipment/Instructions
Wear full set of protective equipment including positive pressure breathing apparatus, chemical goggles and
gloves.
Structural firefighter's protective clothing will only provide limited protection
Move containers from fire area if you can do it without risk. Cool containers with flooding quantities of water until
well after the fire is out. For massive fire, use unmanned hose holders or monitor nozzles; if this is impossible,
withdraw from area and let fire burn. ALWAYS stay away from containers engulfed in fire. Prevent runoff from
entering waterways, drains and sewers.
____________________________________________________________
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Section 6 - Accidental Release Measures
Evacuation Procedures
Isolate area. Keep unnecessary personnel away.
Small Spills
Spilled product may create a dangerous slipping hazard. Eliminate all sources of ignition. Consider isolating the
spill or leak area immediately until ambient air sampling results indicate that the pentane vapor concentration is
below the flammable range. Use appropriate non-sparking tools to put the spilled solid in an appropriate waste
disposal container.
Large Spills
Flammable vapors are released from spills. Use water spray curtain to divert vapor drift. Eliminate all sources of
ignition. Consider evacuating the spill or leak area immediately until ambient air sampling results indicate that the
pentane vapor concentration is below the flammable range. Prevent entry into sewers, basements, or confined
areas; dike if needed.
Special Procedures
Wear appropriate protective equipment and clothing during clean-up. (See Section 8)
Contact local police/emergency services and appropriate emergency telephone numbers provided in Section 1.
Ensure statutory and regulatory reporting requirements in the applicable jurisdiction are met.
Persons not wearing appropriate protective equipment should be excluded from area of spill until clean-up has
been completed.
Damaged or Suspect Damaged Containers
If EPS containers are damaged or suspected to have been damaged during transit, open the truck trailer door
slowly and ventilate for 15 minutes. Never permit smoking. Test the atmosphere to ensure the air is free of
pentane before entering.
Section 7 - Handling and Storage
Handling Procedures
Keep this product from heat, sparks, lit cigarettes, static electricity discharges, or open flame. Ground all
equipment containing material. Do not breathe dusts or vapors from this material. Keep away from incompatibles
such as oxidizing agents, and organic materials. Slipping hazard.
After opening the container in a well ventilated area, allow 15 minutes for the accumulated pentane to dissipate.
Partially opened containers represent a potentially serious hazard because the insides of the container permit a
space for the pentane to accumulate. When partially filled containers have to be used, direct a stream of air into
the container for 15 minutes after opening to ensure no accumulation of pentane in the container.
Maintain sufficient air circulation and ventilation to prevent flammable concentrations from forming, especially in
low-lying areas.
Incompatibility
Not resistant to oxidizing agents, dissolves in organic solvents.
Storage Procedures
Flammable materials should be stored in a separate safety storage cabinet or room. Keep this product from heat,
sparks, lit cigarettes, static electricity discharges, or open flame. Keep the container tightly closed and in a cool,
well-ventilated place. Ground all equipment containing material. A refrigerated room would be preferable for
materials with a flash point lower than 37.8ºC (100ºF).
For additional handing and storage information, refer to the NOVA Chemicals Expandable Polystyrene Storage
and Handling Safety Guide.
____________________________________________________________
Page 3 of 9
Revision: 2.0000
MSDS ID: NOVA-0054
Section 8 - Exposure Controls / Personal Protection
Exposure Guidelines
A: General Material Information
Follow all applicable exposure limits.
B: Component Exposure Limits
ACGIH, OSHA, NIOSH, EPA, TSCA, Alberta, and Ontario exposure limit lists have been checked for those
components with CAS registry numbers. Other exposure limits may apply. Check with authorities.
n-Pentane (109-66-0)
ACGIH:
OSHA:
NIOSH:
Alberta:
Ontario:
600 ppm TWA
600 ppm TWA; 1800 mg/m3 TWA
750 ppm STEL; 2250 mg/m3 STEL
610 ppm Ceiling (15 minute); 1800 mg/m3 Ceiling (15 minute)
1500 ppm IDLH
600 ppm TWAEV; 1770 mg/m3 TWAEV
750 ppm STEV; 2210 mg/m3 STEV
Cyclopentane (287-92-3)
ACGIH:
OSHA:
NIOSH:
Alberta:
Ontario:
600 ppm TWA
600 ppm TWAEV; 1720 mg/m3 TWAEV
Isopentane (78-78-4)
ACGIH:
600 ppm TWA (listed under Pentane, all isomers)
Engineering Controls
Use general ventilation and use local exhaust, where possible, in confined or enclosed spaces. If user operations
generate dusts, mists, or fumes, use appropriate local exhaust ventilation to keep exposures below the
recommended exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: Eyes/Face
Wear chemical goggles.
Personal Protective Equipment: Skin/Hands/Feet
Use impervious gloves. Use of non-static accumulating and fire-resistant protective coveralls and long sleeves is
recommended. Footwear with conductive soles is also recommended.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent buildup of vapor/mist/fume/dust, appropriate NIOSH respiratory
protection must be provided.
Personal Protective Equipment: General
Personal protective equipment (PPE) must not be considered a long term solution to exposure control. PPE must
be accompanied by employer programs to properly select, maintain, clean, fit and use equipment. Consult a
competent industrial hygiene resource to determine hazard potential and/or the PPE manufacturers and
applicable regulations to ensure adequate protection.
Commercial synthetic clothing, unless specifically treated, carries a risk in a fire situation and can generate
dangerous static electricity if donned or doffed in a flammable atmosphere.
____________________________________________________________
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Section 9 - Physical & Chemical Properties
Physical state and appearance:
Odor:
Vapor Pressure:
Dispersion properties:
Solubility (H2O):
Softening Point:
Solid white beads.
Slight hydrocarbon
400 mmHg @ 20ºC
Not dispersed in cold/hot water.
Non-soluble; Soluble in methanol,
methylethylketone, benzene, toluene, or
xylene; Partially soluble in diethyl ether,
n-octanol, acetone.
Approx 50°C - 75°C (122°F - 167°F)
Color:
pH:
Vapor Density (Air=1):
Boiling Point:
Specific Gravity (Water=1):
White
Not applicable
2.5
Not available
Approx. 0.525 to 1.05
Section 10 - Stability & Reactivity Information
Chemical Stability
This is a stable material.
Chemical Stability: Conditions to Avoid
Keep this product from heat, ignition sources, static electricity discharges, and incompatible materials.
Incompatibility
Not resistant to oxidizing agents, dissolves in organic solvents.
Hazardous Polymerization
Will not occur.
Hazardous Decomposition
Styrene, oxides of carbon, and other toxic gases at elevated temperatures.
Section 11 - Toxicological Information
A: Acute Toxicity
This product has not been tested.
Polystyrene homopolymer may be irritating to the eyes. Skin contact with molten or heated material can cause
burns.
The blowing agent used in the product may contain pentane, isopentane, and/or cyclopentane. Components of
the blowing agent can irritate eyes, skin, and respiratory system.
B: Acute Toxicity - LD50/LC50
Inhalation LC50 Rat: 364 gm/m3/4H
LD50 (Intravenous) Mouse: 446 mg/kg
Cyclopentane (287-92-3)
Oral LD50 rat: 11400 mg/kg; Inhalation LC50 rat: 106 gm/m3; Oral LD50 mouse: 12800 mg/kg; Inhalation LC50
mouse: 72 gm/m3
C: Chronic Toxicity
Inhalation of the blowing agent may lead to nervous system effects.
n-Pentane - Exposure can cause nausea and headache. Narcotic in high concentrations. Causes dermatitis.
Chemically damaging to lungs if aspirated.
____________________________________________________________
Page 5 of 9
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MSDS ID: NOVA-0054
D: Chronic Toxicity - Carcinogenic Effects
ACGIH, IARC, OSHA, and NTP carcinogen lists have been checked for those components with CAS registry
numbers.
Polystyrene (9003-53-6)
IARC:
Supplement 7, 1987; Monograph 19, 1979 (Group 3 (not classifiable))
Section 12 - Ecological Information
Ecotoxicity
A: General Material Information
The information below is based on a knowledge of the components and the ecotoxicity of similar products.
Sewer/waterway obstruction; marine life may ingest beads, which may obstruct their digestive tract. Product is
expected to be non-toxic, but small particles may have physical effects on aquatic and terrestrial organisms.
B: Component Analysis - Ecotoxicity - Aquatic/Terrestrial Toxicity
96 Hr LC50 rainbow trout: 9.87 mg/L;96 Hr LC50 fathead minnow: 11.59 mg/L;96 Hr LC50 bluegill: 9.99 mg/L
48 Hr LC50 water flea: 9.7 mg/L
Isopentane (78-78-4)
Air:
When released into the air, isopentane is expected to be readily degraded by reaction with photochemically
produced hydroxyl radicals, with half-life between 1 and 10 days.
Aquatic:
When released into water, isopentane may biodegrade to a moderate extent. When released to water,
isopentane is expected to quickly evaporate. Into the water, isopentane is expected to have a half-life of less than
1 day. Isopentane has an estimated bioconcentration factor (BCF) of less than 100. Isopentane has a log
octanol-water partition coefficient greater than 3.0. Isopentane is not expected to significantly bioaccumulate.
Soil (micro- and macro-organisms): Not Available.
Inhibitory effects on the activity of micro-organisms and impact on sewage treatment plants: Not Available.
Environmental Fate
See information below.
Mobility
Depending on the resin grade's specific gravity, this product may sink or float in freshwater and/or seawater.
Persistence/Degradability
Expected to be inherently non-biodegradable. Integrated environmental half-life expected to be >= 100 days.
Bioaccumulation/Accumulation
Not expected to bioaccumulate significantly.
Physical/Chemical
This product has not been tested.
Section 13 - Disposal Considerations
Component Waste Numbers
No EPA Waste Numbers are applicable for this product's components.
Waste Disposal
Preferred disposal methods are: 1) clean and reuse if possible; 2) contact resin broker; 3) contact plastic recycler;
4) incinerate with waste heat recovery and/or 5) landfill. Reuse, recycling, storing, transportation, and disposal
must be in accordance with applicable federal, state/provincial and local regulation. DO NOT ATTEMPT TO
DISPOSE OF BY UNCONTROLLED IGNITION.
____________________________________________________________
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Revision: 2.0000
MSDS ID: NOVA-0054
Section 14 - Transportation Information
US DOT Information
Shipping Name: Polymeric beads, expandable
UN/NA #: UN2211 Hazard Class: 9 Packing Group: III
Required Label(s): Class 9: Miscellaneous
Canadian TDG Information
UN/NA #: UN2211 Hazard Class: 9 Packing Group: III
International Air Transport Association (IATA) and ICAO Regulations
UN #: UN2211 Hazard Class: 9 Packing Group: III
Required Label(s): Class 9: Miscellaneous
International Maritime Dangerous Goods (IMDG) Regulations
UN #: UN2211 Hazard Class: 9 Packing Group: III
EmS No. 4.1-06
Section 15 - Regulatory Information
A: International Regulations
General Material Information
The monomer is listed by EINECS for polystyrene homopolymer.
Component Analysis - International Inventory Status
Component
Polystyrene
n-Pentane
Cyclopentane
Isopentane
CAS #
9003-53-6
109-66-0
287-92-3
78-78-4
US - TSCA
Yes
Yes
Yes
Yes
CANADA - DSL
Yes
Yes
Yes
Yes
EU - EINECS
No
Yes
Yes
Yes
Canadian Environmental Protection Act (CEPA): All components of this product are on the Domestic Substances
List (DSL), and are acceptable for use under the provisions of CEPA.
B: USA Federal & State Regulations
Other state regulations may apply. Check individual state requirements.
USA OSHA Hazard Communication Class
According to 29 CFR 1910.1200 (Hazard Communication), polystyrene polymer product is not hazardous. The
blowing agent used in the product is considered hazardous.
USA Right-to-Know - Federal
None of this product's components are listed under SARA Section 302 (40 CFR 355 Appendix A), SARA Section
313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).
____________________________________________________________
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Revision: 2.0000
MSDS ID: NOVA-0054
USA Right-to-Know - State
The following components appear on one or more of the following state hazardous substances lists. Some components
(including those present only in trace quantities, and therefore not listed in this document) may be included on the Right
To Know lists of other U.S. states. The reader is therefore cautioned to contact his or her NOVA Chemicals
representative or NOVA Chemicals' Product Integrity group for further U.S. State Right To Know information.
Component
n-Pentane
Cyclopentane
Isopentane
CAS
109-66-0
287-92-3
78-78-4
NJ
Yes
Yes
Yes
PA
Yes
Yes
Yes
C: Canadian Federal WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component
n-Pentane
Cyclopentane
CAS #
109-66-0
287-92-3
Minimum Concentration
1% Item 1243 (1348)
1% Item 477 (610)
WHMIS Classification
Workplace Hazardous Materials Information Systems (WHMIS): This product has been classified in accordance
with the hazard criteria of the Canadian Controlled Product Regulations (CPR), and the MSDS contains all of the
information required by the CPR.
Provincial Regulations
No information available.
Section 16 - Other Information
Label Information
PRECAUTIONS:
DANGER FLAMMABLE Product is a white bead (0.25 - 2.0 mm diameter) with a slight hydrocarbon odor. This
product can release a gas that is highly flammable in the presence of open flames, sparks, static electricity
discharges, or heat. The blowing agent may be irritating to the eyes, respiratory system and skin. Not resistant to
oxidizing agents, dissolves in organic solvents. When heated to decomposition, product emits acrid smoke and
irritating fumes. Slipping hazard.
FIRST AID:
SKIN: This product may cause irritation to the skin from repetitive handling. Remove contaminated clothing. Wash
the affected skin gently and thoroughly with running water and non-abrasive soap. Seek medical attention.
EYES: Check for and remove any contact lenses. Immediately flush eyes with water for at least 15 minutes, while
holding eyelids open. Seek medical attention at once.
INHALATION: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie,
belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. WARNING: It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation
when the inhaled material is toxic, infectious or corrosive. Seek medical attention.
INGESTION: Not normally expected to present an ingestion hazard. If ingestion occurs, maintain an open airway
and seek medical attention. Watch for an obstruction in the victim's mouth. Remove, if possible, but do not force
fingers or a hard object between victim's teeth.
IN CASE OF A SPILL: Eliminate all sources of ignition. Use appropriate non-sparking and grounded tools and
equipment to put the spilled solid in an appropriate waste disposal container. Prevent entry into sewers,
basements, or confined areas; dike if needed.
References
Not available
____________________________________________________________
Page 8 of 9
Revision: 2.0000
MSDS ID: NOVA-0054
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists; BOD = Biochemical Oxygen Demand; CAS = Chemical Abstracts
Service; CERCLA = Comprehensive Environmental Response, Compensation, and Liability Act; CPR = Controlled Products Regulations; DOT
= Department of Transportation; DSL = Domestic Substances List; EINECS = European Inventory of Existing Commercial Substances; EPA =
Environmental Protection Agency; EU = European Union; FDA = Food and Drug Administration; IARC = International Agency for Research on
Cancer; IDL = Ingredient Disclosure List; Kow = Octanol/water partition coefficient; LEL = Lower Explosive Limit; NIOSH = National Institute
for Occupational Safety and Health; NJTSR = New Jersey Trade Secret Registry; NTP = National Toxicology Program; OSHA = Occupational
Safety and Health Administration; RCRA = Resource Conservation and Recovery Act; SARA = Superfund Amendments and Reauthorization
Act; TDG = Transportation of Dangerous Goods; TSCA = Toxic Substances Control Act.
Validated by Business Review Team/Product Integrity Group.
Verified by Product Steward on 07/17/2003
Contact: Product Integrity Group
NOVA Chemicals Corporation
6711 Mississauga Road, Suite 200
Mississauga, Ontario L5N 2W3
Contact Phone: 905-542-6980
Other Information
Notice to Reader
ALTHOUGH THE INFORMATION CONTAINED IN THIS DOCUMENT IS PRESENTED IN GOOD FAITH, BASED ON AVAILABLE
INFORMATION BELIEVED TO BE RELIABLE AT THE TIME OF PREPARATION OF THIS DOCUMENT, NOVA CHEMICALS MAKES NO
WARRANTIES OR REPRESENTATIONS WITH RESPECT TO THE INFORMATION OR THE PRODUCTS DESCRIBED HEREIN, AND
EXPRESSLY DISCLAIMS ALL IMPLIED WARRANTIES AND CONDITIONS (INCLUDING ALL WARRANTIES AND CONDITIONS OF
MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE). THIS INFORMATION IS SUBJECT TO CHANGE WITHOUT
NOTICE. PLEASE CONTACT NOVA CHEMICALS FOR THE MOST CURRENT VERSION OF THIS MSDS. NOVA CHEMICALS DOES
NOT ASSUME RESPONSIBILITY FOR MSDS OBTAINED FROM THIRD PARTY SOURCES.
RESPONSIBILITY FOR USE, STORAGE, HANDLING AND DISPOSAL OF THE PRODUCTS DESCRIBED HEREIN, WHETHER ALONE OR
IN COMBINATION WITH ANY OTHER SUBSTANCE, IS THAT OF THE PURCHASER AND/OR END USER.
is a Registered Trademark of NOVA Brands Ltd.; authorized use
This is the end of MSDS # NOVA-0054
____________________________________________________________
Page 9 of 9
Revision: 2.0000
MATERIAL SAFETY DATA SHEET -- LOYAL
PRODUCT CODE AND NAME
DATE ISSUED
DATE PRINTED
06/01/2004
: EXPANDABLE POLYSTYRENE (EPS)
: 05/01/2004
:
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Material Identity
Product Code and Name -- EXPANDABLE POLYSTYRENE (EPS)
Series
: E, C, B, F, G, R, FD, BL
Chemical Name : Polystyrene thermoplastic polymer
Synonym(s)
: EPS
Molecular Formula : (C8H8)x
COMPANY INFORMATION
LOYAL CHEMICAL INDUSTRIAL CORP.
19F, No. 85, Sec. 1, Chung-Shiao E. Rd.,
Taipei, Taiwan, R. O. C.
Telephone Number: 886-2-23923245
2. COMPOSITION AND INFORMATION ON INGREDIENTS
The criteria for listing components in the composition section are as follows: carcinogens are
listed when present at 0.1% or greater; components which are otherwise hazardous according
to OSHA are listed when present at 1.0% or greater; non-hazardous components are listed at
3.0% or greater. This is not intended to be complete compositional disclosure. Refer to section
14 for international regulatory information.
Product and/or Component(s) Carcinogenic According to:
OSHA_____ IARC____ NTP_____ OTHER _____ NONE
X
Composition:
Chemical Name
CAS Number
Exposure Limits
Benzene, ethenyl-, homopolymer 9003-53-6
(Common name: Polystyrene)
Pentane
109-66-0
600 ppm TWA ACGIH
1000 ppm TWA OSHA
750 ppm STEL OSHA
120 ppm TWA (Canada)
350 mg/m3 TWA (Canada)
Range in %
> 92.6
> 7.0
This product is considered hazardous according to OSHA (1910.1200).
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3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW
Appearance:
Solid, white beads (0.01 to 0.1 inches diameter)
Odor:
WARNING STATEMENT
DANGER! EXTREMELY FLAMMABLE VAPOR
VAPOR MAY CAUSE FLASH FIRE
VAPOR MAY CAUSE DIZZINESS AND DROWSINESS
VAPOR MAY CAUSE IRRITATION TO EYES AND RESPIRATORY TRACT
* Hazardous Material Information System (United States)
Health
Fire
Reactivity
Personal protection
(1)
(3)
(3)
(0)
(0)
(())
* National Fire Protection Association NFPA (United States)
Flammability
3 3
Health
0
1
Reactivity
Specific danger
POTENTIAL HEALTH EFFECTS
Primary Route of Exposure
Eye X
Skin X
Inhalation X
Ingestion
Effects of Overexposure
Acute:
Eyes:
Skin:
Vapor may cause irritation, experienced as discomfort, with
excess tear production and blinking, and seen as excess
redness of the eye. Product may contain residual amounts
of dust or small particulates which may cause eye irritation or
abrasion experienced as mild discomfort and slight excess
redness of the eye.
Product may contain residual amounts of dust or small
particulates that may cause skin irritation or abrasion
experienced as local redness with possible mild discomfort.
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V20040608 AC
Inhalation:Vapors or mist may cause irritation of the nose and throat.
Inhalation may cause dizziness, drowsiness, euphoria, loss
of coordination, disorientation, headache, nausea, and
vomiting. In poorly ventilated areas or confined spaces,
unconsciousness and asphyxiation may result. Prolonged
or repeated overexposure may result in the absorption of
potentially harmful amounts of material.
Dust may cause irritation of the nose and throat.
Overexposure to high concentrations of dust may cause
respiratory irritation, experienced as coughing and difficulty
breathing.
Ingestion:If more than several mouthfuls are swallowed, abdominal
discomfort, nausea, and diarrhea may occur.
Sensitization Properties:Unknown
Chronic:
Prolonged or repeated inhalation of dust or particulates may impair lung
function or cause lung damage.
Medical Conditions Aggravated by Exposure:
Overexposure to vapor, dust or mist may aggravate existing respiratory
conditions, such as asthma, bronchitis, and inflammatory or fibrotic
respiratory disease.
Other Remarks: None
4. FIRST AID MEASURES
Eyes:
Flush eyes with plenty of water for several minutes. Remove larger particulates from
the eye as one would any foreign object. Get medical attention if eye irritation persists
or particulates are difficult to remove from the eye.
Skin:
Wash skin with plenty of soap and water for several minutes. Get medical attention if
skin irritation develops or persists.
Ingestion:
If more than several mouthfuls of this material are swallowed, give two glasses of water
(16 oz.). Get medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, clear person’s airway and give
artificial respiration. If breathing is difficult, qualified medical personnel may
administer oxygen. Get medical attention immediately.
Other Instructions: None.
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5. FIRE-FIGHTING MEASURES
Ignition Temperature – AIT (degrees C):
260 (500 F) for Pentane
471 (880 F) by ASTM D-1929 Expanded polystyrene
Flash Point (degrees C):
-40 (-40 F) CC for Pentane
Flammable Limits % (Lower-Upper):
Lower: 1.5 for Pentane
Upper: 7.8 for Pentane
Recommended Fire Extinguishing Agents And Special Procedures:
Water may be ineffective on flames but should be used to cool fire-exposed
containers and provide protection for persons attempting to stop the leak.
Use water spray, dry chemical, foam or carbon dioxide to extinguish flames.
Unusual or Explosive Hazards:
Danger! Extremely flammable materials may release vapors that travel long
distances, ignite, and flash back, Containers may explode in a fire. Do not
expose to heat, sparks, flame, static, or other sources of ignition. When
handling, use non-sparking tool, ground and bond all containers.
Explosive air-vapor mixtures may form. Fire gives off dense black smoke
and acid gasses. Electrostatic discharge can be a source of ignition due to
accumulated pentane vapors exceeding the L.E.L. (lower explosive limit) of
1.5% (15,000 ppm). Pentane vapors may be emitted from newly opened
containers or when the product is heated. If ignited, there could be a very high
rate of flame propagation.
“NO SMOKING – NO MATCHES – NO LIGHTERS – NO WELDING” rules
should be enforced.
Special Protective Equipment for Firefighters:
Wear full protective clothing and positive pressure breathing apparatus.
6. ACCIDENTAL RELEASE MEASURES (Transportation Spills)
Procedures in Case of Accidental Release, Breakage or Leakage:
Avoid the generation of dust clouds. Place in appropriate containers for disposal or
recycle. Avoid breathing dust. Pressure demand air supplied respirators should
always be worn when the airborne concentration of the contaminant or oxygen is
unknown. Otherwise, wear respiratory protection and other personal protective
equipment as appropriate for the potential exposure hazard. Wear gloves, goggles,
and protective clothing to avoid contact with eyes, skin, or clothing. Use
4
V20040608 AC
vacuuming or sweeping compound for clean-up. Do not dry sweep or use methods
which increase dusting. Prevent entry into sewers and waterways.
7. HANDLING AND STORAGE
Precautions to be Taken in
Handling:
Use spark-proof tools. Materials may be at elevated temperatures and/or pressures.
Exercise care when opening bleeders and sampling ports.
Storage:
Ground and bond shipping container, transfer line, and receiving container. Keep
away from heat, sparks, flame, and other sources of ignition.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Protective Equipment (Type)
Eye/Face Protection:
Avoid eye contact. Chemical type goggles should be worn. Do not wear contact
lenses.
Skin Protection:
Workers should wash exposed skin several times daily with soap and water. Soiled
work clothing should be laundered or dry-cleaned.
Respiratory Protection:
Airborne concentrations should be kept to lowest levels possible. If vapor, mist or
dust is generated and the occupational exposure limit of the product, or any
component of the product, is exceeded, use appropriate NIOSH or MSHA approved
air purifying or air supplied respirator after determining the airborne concentration
of the contaminant. Air supplied respirators should always be worn when airborne
concentration of the contaminant or oxygen content is unknown.
Ventilation:
Use explosion-proof equipment to maintain adequate ventilation to meet
occupational exposure limits, if applicable (see below), prevent accumulation of
explosive air-gas mixtures, and avoid significant oxygen displacement. Oxygen
levels should be at least 19.5% in confined spaces or other work areas (OSHA
value).
Exposure Limit for the Total Product:
5
V20040608 AC
None established for product; refer to Section 2 for component exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Solid, white beads (0.01 to 0.1 inches diameter)
Odor: Slight hydrocarbon odor
Boiling Point (degree C): Not applicable
Melting/Freezing Point (degree C): Softens and expands at 93.3-101.7 C (200-215 F)
Specific Gravity (water=1): 1.14-1.18
pH: Not applicable.
Vapor Pressure: Negligible
Viscosity: Not applicable
VOC Content: Not determined.
Vapor Density (Air=1): > 1
Solubility in Water (%): < 0.1
Other: None
10. STABILITY AND REACTIVITY
This Material Reacts Violently With:
Air__ Water__ Heat X Strong Oxidizers X
Others__ None of these___
Comments: None
Products Evolved When Subjected to Heat or Combustion:
Toxic levels of carbon monoxide, carbon dioxide, irritating aldehydes and ketones.
Hazardous Polymerizations: DO NOT OCCUR
11. TOXICOLOGICAL INFORMATION
Toxicological Information (Animal Toxicity Data)
Oral:
LD50 Believed to be > 5.00 g/kg (rat) practically non-toxic
Inhalation:
Not determined.
Dermal:
LD50 Believed to be > 2.00 g/kg (rabbit) practically non-toxic
Irritation Index, Estimation of Irritation (Species)
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V20040608 AC
Skin: (Draize) Believed to be > .50 – 3.00 /8.0 (rabbit) slightly irritating
Eyes: (Draize) Believed to be > 15.00 – 25.00 /110 (rabbit) slightly irritating
Sensitization: Not determined.
Other:
Product may contain dust or particulates that may cause eye irritation or abrasion.
12. DISPOSAL CONSIDERATION:
Water Disposal Method:
This material should be disposed of in accordance with local, state and federal
regulations.
Remarks:
Do not allow to enter drains or sewers.
13. TRANSPORT INFORMATION
Please refer to the MSDS of Loyal Chemical.
Transportation
DOT
Proper Shipping Name: Polymeric beads, expandable
Hazard Class: 9
Identification Number: UN 2211
Packing Group: III
Label Required: Class 9
IMDG
Hazard Class: 9
Packing Group: III
Label Required: Class 9 (See Section 16 for additional information)
ICAO
Hazard Class: 9
Packing Group: III
Label Required: Class 9 (See Section 16 for additional information)
TDG
Hazard Class: 9
7
V20040608 AC
Packing Group: III
Label Required: Class 9 (per UN recommendations, black vertical stripes)
8
V20040608 AC
APTCO, LLC
Title Page
APTCO, LLC
APTCO, LLC
Agricultural Packaging Technology
Premium Grape Boxes
2006 Product Manual
Title Page
APTCO, LLC
APTCO, LLC
Premium Grape Boxes
2006
Title Page
ACKNOWLEDGEMENT OF REVIEW OF PRODUCT MANUAL
As consideration for the sale of boxes to the undersigned, the undersigned acknowledges
that the undersigned has received, reviewed, and understands the terms and provisions of
the APTCO,LLC Premium Grape Box Product Manual 2006. The undersigned agrees
to utilize all boxes in accordance with the terms and provisions set forth in the
APTCO,LLC Premium Grape Box Product Manual 2006.
THE UNDERSIGNED UNDERSTANDS THAT IF ANY BOX FAILS TO COMPLY
WITH THE STANDARDS SET FORTH IN THE APTCO,LLC Premium Grape Box
Product Manual 2006, A REPLACEMENT BOX WILL BE SUPPLIED AT NO
ADDITIONAL CHARGE. RECEIVING A REPLACEMENT BOX IS THE
UNDERSIGNED’S SOLE AND EXCLUSIVE REMEDY FOR FAILURE OF ANY
BOX TO CONFORM TO PRODUCT SPECIFICATIONS.
For APTCO,LLC: ____________________________ (Printed)
For APTCO,LLC: ____________________________ (Signed)
For: _______________________________________ (Company Name)
Signed By: _________________________________ (Printed)
Signed By: _________________________________ (Signed)
Dated: _____________________________________
Please return to:
APTCO,LLC
1998 Road 152
Delano, CA 93215

APTCO, LLC

Transcription

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