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The Use of Glass Bricks in Architecture in the 19th and 20th Centuries: A Case Study Kristel De Vis,1 * Patric Jacobs,2 Joost Caen,1 and Koen Janssens3 kristel.devis@artesis.be Conservation Studies Artesis University College of Antwerp Antwerp, Belgium 1 Department of Geology and Soil Science Ghent University Ghent, Belgium 2 Abstract Nineteenth- and 20th-century glass was used in buildings in a variety of surprising and innovative ways. Engineers (e.g., Gustave Falconnier), architects, and designers (e.g., Frank Lloyd Wright) applied known theories of light refraction to guarantee maximum light while guarding privacy in an environment in which growing cities required radical solutions to the problem of lighting storefronts and sidewalks. The idea of using light refraction was translated into the use of glass prisms and glass bricks, which refract light into previously unlightable spaces, particularly those in deep courts and wells or on narrow streets bordered by tall buildings. The light refracted through the application of these glass elements brings natural light into factories, homes, and offices. These glass elements are now over a century old, and they are disappearing evidence of a time in which these architectural glass elements were more often used and more varied than similar elements are today. The diversity of materials applied (e.g., concrete, mortar, cast iron, and blown and semi-industrial glasses) will present future conservators with a serious dilemma. 194 MiTAC Department of Chemistry University of Antwerp Wilrijk, Belgium 3 This paper focuses on a case in which semi-industrial glass bricks were applied in an old paper factory in Huy, Belgium. Patent history, material, and initial analysis results will be discussed. Keywords: glass bricks, Falconnier, Papeterie Godin, degradation Introduction At the dawn of the Industrial Revolution, the distribution of light into previously unlightable spaces such as deep courts and wells, narrow streets bordered by tall buildings, and factories was a primary issue. The basic concept of light refraction to introduce more light in an inferior (or interior) space, using various forms of glass, had already resulted in a patent for E. Wyndus (GB no. 232, Glass and Lamps for Ships, Mines &c.) in 1684, as it did later in more extended—but Wyndus-based— projects such as those by R. Cole (GB no. 372, Forming Glass into Conical Figures and Lamps, 1704), A. Pellatt (GB no. 3,058, Lighting in the Interior of Ships, Buildings, etc., 1807), and G. Preston (GB no. 4,222, Deck Glass Rim, Safety Grate for Ships, 1818). These inventions were primarily intended to improve 17th-century street lighting Figure 1 Falconnier briques are sealed with a pastille of molten glass. (Photo: K. De Vis) in London and other cities, and they eventually developed into deck lights that were used on ships to illuminate deeper spaces. In the 19th century, the basements of commercial buildings often extended into the space beneath the sidewalk and occasionally even under the street. To make this possible, heavy cast-iron columns supported the sidewalk and the roof of the vault. Allowing daylight into the cellars or vaults required imaginative engineering because lighting with gas or kerosene presented hazards in these enclosed spaces, where ventilation was limited and the possibility of fire was ever present. The ingenious invention of the “vault light” allowed natural light to be filtered through the sidewalk into the basement while providing a surface rigid enough to support pedestrian traffic (Gayle, Waite, and Look 1998, p. 51). Theodore Hyatt’s patent (U.S. no. 4,266, Illuminating Vault Cover, 1845) is a variation of E. Rockwell’s patented vault light (U.S. no. 8,058X, 1834), which was extensively described in the 1834 Mechanic’s Magazine: “Every citizen is aware that the common vault light[s], or grating, which may be seen on our sidewalks at every few steps, are not only unsightly to the eye, but often positively dangerous. Very frequently they are found loose, often broken, with a bar or two out and in winter so slippery as to render it hazardous to step upon them” (Knight 1834). This confirms the presence and common knowledge of vault lights in pavements. The new vault lights of Hyatt and Rockwell were implemented with convex glass in the center to afford light that entered and radiated on all sides (ibid.). Some of the applications introduced by these two inventors are still visible on streets in New York City (Stuart 2003). Prism glass was further developed by James G. Pennycuick, a British inventor, who filed a U.S. patent application (no. 312,290, Window Glass) in 1882. This became the basis of the Radiation Light Company of Chicago (1896) and, one year later, the Luxfer Company (Neumann 1995a).1 Hollow glass blocks, invented as an alternative means of providing light, have been used in ceilings, walls, and floor panels. Unlike prism glass, they are still employed in architectural applications. In this paper, the initial results of a case study on Falconnier blocks will be discussed. The study focuses on the glass block and dalle de verre technology that is found in western European architecture. A Western European Application: Brique de verre (Glass Block/Brick) When Gustave Falconnier (1845–1913) of Nyon, Switzerland, presented his briques en verre soufflé at the meeting of French civil engineers in Paris in 1895 (Anon. 1895, pp. 573–574), he could not have anticipated the im pact of his invention on 20th- and 21st-century architecture. His glass blocks were produced by mold blowing. The glassblowers, who perspired freely and thus drank considerable quantities of water, breathed out a moistureladen air that ultimately condensed. This detracted from the appearance of the blocks, which were sealed with a marked pastille of molten glass (Fig. 1). The sides of the bricks were recessed to take mortar, and the bricks were laid up like masonry bricks, with or without an embedded metal reinforcement. The construction of these glass 1. Glass prisms are a type of architectural glass element designed to bring more daylight into the dark interiors of factories and densely built urban centers. The Luxfer Company was studied by Dietrich Neumann of Brown University, and the results of his research can be found in Neumann 1995a and 1995b. 195 Figure 2 Glass bricks at the entrance to a private building (Villa Andreae, Kollum, the Netherlands). (Photo: L. A. E. Lutz) blocks, as well as the formation of complete walls or even conservatories (Fig. 2), is well described and illustrated in patents dating from 1886 to 1907. Describing the improved technology of his glass bricks in his second patent (CH no. 212, Briques en verre soufflé avec cachets de verre fermant l’ouverture ayant servi à la soufflure, 1888), Falconnier compared his first bricks (FR no. 179595, title unknown, 1886) with “les bouteilles ordinaires.” These were bricks that were open on one side, and they were closed on-site, during the assembly of the wall, with paper, cloth, mastic, or ciment de bois. Despite careful construction and frequent maintenance, it was not possible to prevent all intrusions into the glass block because of the effects of condensation. It is not clear whether this kind of glass brick can still be found on-site. After 1888, Falconnier presented bricks that were closed with a pastille of molten glass and marked with the trademark and/ or license number. He also introduced several variations on his basic patents, such as briquetage légers et écono miques (lightweight and economical bricks) with a less complicated construction method (CH no. 48, 1888) and 196 De Vis AND others briques de verre pour réflecteurs (bricks that could be used as reflectors; CH no. 7754, 1893). These bricks, with bigger glass surfaces, were coated with a metallic layer and covered with a preserving varnish. When light rays fell upon the glass brick, they penetrated into the brick and were radiated by the several coated surfaces so that the reflected light was of a higher intensity. Falconnier’s two last improvements of the glass brick were patented in 1904 (CH no. 28315, Construction perfectionnée en briques creuses en verre) and 1907 (CH no. 41374, Construction en briques soufflées en verre). Several European companies were allowed to make the patented Falconnier bricks, including Adlerhütten G. Mayer & Co. in Penzig, Germany (Sommer 2003, p. 156); Glashütte Gerresheim in Düsseldorf, Germany; and the Haywards Company in London (Winterton 1953, p. 9; Hermans 2009). In addition, these bricks were quite popular with architects such as Hector Guimard, Auguste Perret, Le Corbusier (Charles-Edouard Jeanneret-Gris) (Schittich, Debord, and Drey 2001, p. 11), Eduard Cuypers, and Hendrik Petrus Berlage (Stokroos 1994, p. 37). A Case Study: The Old Paper Factory Godin Frères in Huy, Belgium Papeterie Godin is located in the French-speaking part of Belgium, near Liège, between Marchin and Huy. Between 1840 and 1967, the Godin family produced all kinds of paper. The company had various technical installations, including a pulverizer, a continuous-feed paper machine, gluing units, and washing and bleaching quarters. On several occasions, especially during the 19th century, the company was praised as a model organization for its technological advancement from windmill-powered energy to hydraulic wheels driven by steam, and for its ability to offer employment to 1,500 skilled workers (Didot 1854, p. 115; Scheler 1865, p. 186). After the com pany closed in 1967, the site was abandoned. In 2005, when the village of Marchin decided to build a new commercial area there, the original semi-industrial Falconnier bricks were discovered. Fortunately, developers were able to save the bricks in the summer of 2009, before the razing of the original building, which was thought to have been contaminated. These bricks are the only known patented Falconnier bricks that survive in Belgium. General Description of the Assembly In the summer of 2009, only the washing and bleaching quarters of the Godin factory remained to be demolished (Fig. 3). The windows on the upper floors were decorated with translucent bricks of various colors, while only transparent bricks were found on the floors below. Each window consisting of translucent glass had one glass brick colored amber, green, or red. All of the bricks were colored throughout, except for the red ones, which were made by flashing (red on white). The technique of flashing glass is well known in the manufacture of vessel glass as well as sheet glass. In both processes, a semimolten bubble of colorless glass is dipped into a pot of red glass, with the colored glass forming a thin coating on the surface. Afterward, the flashed bubble could be formed into a sheet of glass (by the cylindrical or spinning method) or pressed in a mold to form bottles or a Falconnier brick (Wigginton 2004, p. 26). The glass bricks were laid up like masonry bricks, with a layer of mortar 0.8–1.2 centimeters thick. Although the windows had been constructed more than 80 years earlier, they were stable and would have been able to last much longer. The bricks were removed from the window openings with a hammer and chisel. Unfortunately, during this process, some of the bricks were broken. The damaged bricks were numbered, cleaned, rejoined with tape, and stored in plastic bags. One of the red bricks was examined with a microscope. It was cracked from the bottom to the top, which permitted observers to study the construction and thickness of the glass layers and the glass seal, and to form a better idea of the internal degradation of the brick. Primary analysis of the glass composition was accomplished using SEMEDS. General Description of the Red Falconnier Brick Only a few types of Falconnier bricks are known: square (no. 6), watch with band (no. 8), squashed hexagon (no. 9), and four regular hexagons (nos. 7, 7½, 10, and 11). All Figure 3 The old Godin paper factory in Huy, Belgium, June 2009. (Photo: K. De Vis) the use of glass bricks in architecture in the 19th and 20th centuries: a case study 197 Figure 4 Falconnier bricks nos. 6, 7, 8, and 9 (patent scans). of these bricks are rare today, but no. 8 is the most common kind, and it was found at the Huy site (Fig. 4). The brick made in flashed red glass was sealed with a pastille of molten glass marked with the inscription “Falconnier [ ] 774 D.R.P.,” which probably refers to patent number 41774 of 1887 as a German patent (Deutsches Reich Patent). Unlike the brick, the pastille was made of transparent glass. The side of the brick, to the left of the pastille, is embossed with “Falconnier,” and the poorly preserved embossing on the right side reads “[ ] France [ ] ique + [ ],” which may refer to the inscription “FALCONNIER / DEP FRANCE BELGIQUE + nnn / FRANCE” that can be found on a similar brick in the Museum of Modern Art in New York City (2308.2001.1-3). In the inscription, “nnn” refers to the style number, which is most often 8. In addition to the complete brick, half- and quarter-size bricks for squaring up the window were found on the site. The red brick measures 13.9 by 19.7 centimeters, and it weighs 0.82 kilograms (Fig. 5). In modern glass bricks, which are produced by pressing two halves together at 600°–700°C, redeposits of evap orated alkali oxides can be found on the interior front surfaces. These surfaces can react with H2O and CO2 from the residual brick atmosphere, leading to the formation of an alkali-rich silicate hydrate layer; this layer, in turn, can produce corrosion where NaHCO3 crystals finally grow (De Moraes and others 2008). Preliminary traces of corrosion can be seen on the inside of the Falconnier brick, which are indicated by the iridescence of the glass layer. The surface shows a rainbowlike effect without flaking or any other form of active degradation, but on a microscopic scale a progressive breakdown of the siliceous layer may already have occurred (Newton and Davison 1997, 198 De Vis AND others p. 157). The interior surface of the brick, which remains pristine from its formation in the mold and its sealing with the glass pastille, may react with the residual gas mixture enclosed in the brick. These bricks are thought to enclose air that is more or less rarefied because, as was noted earlier, the glassblower, who was obliged to drink water, exhaled a moisture-laden air that ultimately condensed into the brick (McGrath and Frost 1961, p. 64). Because the Falconnier patents provide no information on the composition of the glass, SEM-EDS measurements were performed on the red brick, using a JEOL 6300 scanning electron microscope equipped with an energy-dispersive X-ray detector (Reed 2005, p. 76). The spectra were collected for 100 seconds by using a 2 nA electron beam current, an accelerating voltage of 20 kV, Figure 5 Red Falconnier brick no. 8. (Photo: K. De Vis) Huy - Red Glass Brick 100000 White Glass Layer Red Glass Layer Si 10000 Pb Na Ca 1000 K Ca Pb 100 10 1 0.1 0 2 4 6 8 10 12 14 16 18 20 keV Figure 6 XRF spectrum of the bulk layer and the red surface layer. and a magnification of 500X. These parameters were found to be suitable for quantitative analysis of glass without significant diffusion of sodium during the irra diation (Schalm 2000, pp. 45–71). The net intensities were calculated with the AXIL (Analysis of X-Rays by Iterative Least Squares) program and were quantified by means of a standardless ZAF program (Schalm and Janssens 2003). The red and white/transparent layers were measured and quantified. The basic composition of the transparent layer of the brick corresponds to that of a multicomponent soda-lime-silica glass, which was the most common type of glass in the 20th century. It contains about 75.5% SiO2, but it has a reduced amount of Na2O (10.6%; 12%–18% is usual). The amount of K2O (6.5%) is within the normal standards of 5%–12%. The red layer is also a soda-lime glass, but its levels of SiO2 and Na2O decrease significantly, to 57.9% and 1.4% respectively; its K2O level (8.0%) remains within the standard range. Meanwhile, a new material was added to the batch. A quantity of 30.5% PbO makes the glass relatively soft, and it produces a brilliant refractive index. This optical character may be the reason for applying the lead glass on the exterior of the brick: so as to achieve a wider range of diffraction (Fig. 6). Because of the limits of SEM-EDS, the coloring agent for the red glass could not be detected. A study of the coloring agent will be part of further research. Conclusion The glass bricks of the old Godin paper factory shed new light on the history of early modern architecture and the development of its glass elements. The complex general conditions of architectural production have received far less attention than they deserve. Although patents can be discovered and studied, it is important to determine how the materials were invented, promoted, and eventually incorporated into the architecture of that time. The bricks from Huy are the only ones known in Belgium that confirm the descriptions in the patents. The fact that the glass contains various batch materials with different amounts of metal oxides will lead to more extensive analytical research on both the physical and the chemical properties of the glass. the use of glass bricks in architecture in the 19th and 20th centuries: a case study 199 Acknowledgments This research is part of Kristel De Vis’s Ph.D. dissertation “The Application of Tiles, Bricks, and Blocks of Glass in an Architectural Context Applied in the 19th and 20th Centuries: Materials, Degradation Phenomena, and First Conservation/Restoration Approach” at Artesis University College of Antwerp, the University of Antwerp, and Ghent University, Belgium. References Anon. 1895 Mémoires et compte rendu des travaux de la Société des Ingénieurs Civils de France, fondée le 4 mars 1848, v. 2, Paris, 1895. Neumann 1995a Dietrich Neumann, “‘The Century’s Triumph in Lighting’: The Luxfer Prism Companies and Their Contribution to Early Modern Architecture,” Journal of the Society of Architectural Historians, v. 54, no. 1, March 1995, pp. 24–53. Neumann 1995b Dietrich Neumann, “Prismatic Glass,” in 20th-Century Building Materials, ed. Thomas C. Jester, Washington, D.C.: National Park Service, 1995, pp. 188–199. Newton and Davison 1997 Roy Newton and Sandra Davison, Conservation of Glass, London: Butterworth-Heinemann, 1997. De Moraes and others 2008 Flavia de Moraes and others, “Corrosion and Crystallization at the Inner Surfaces of Glass Bricks,” Journal of Non-Crystalline Solids, no. 354, 2008, pp. 284–289. Reed 2005 S. J. B. Reed, Electron Microprobe Analysis and Scanning Electron Microscopy in Geology, 2nd ed., Cambridge: Cambridge University Press, 2005. Didot 1854 Ambroise Firmin Didot, L’Imprimerie: La Librairie et la papeterie à l’exposition universelle de 1851. Rapport du XVII e jury, Paris: Imprimerie Impériale, 1854. Schalm 2000 O. Schalm, “Characterization of Paint Layers in Stained Glass Windows,” Ph.D. diss., University of Antwerp, 2000. Gayle, Waite, and Look 1998 Margot Gayle, John G. Waite, and David W. Look, Metals in America’s Historic Buildings, New York and London: Norton & Company, 1998. Hermans 2009 T. Hermans, adviser, Rijksdienst voor het cultureel Erf goed, the Netherlands, conversation with Kristel De Vis on Falconnier brick producers, February 22, 2009. Knight 1834 J. Knight, ed., “Rockwell’s Patent Vault Light,” Mechanic’s Magazine, Register of Inventions and Improvements, v. 4, July–December 1834, pp. 91–92. McGrath and Frost 1961 Raymond McGrath and A. C. Frost, Glass in Architecture and Decoration, London: Architectural Press, 1961. 200 De Vis AND others Schalm and Janssens 2003 O. Schalm and K. Janssens, “A Flexible and Accurate Quantification Algorithm for Electron Probe X-Ray Microanalysis Based on Thin-Film Element Yields,” Spectrochimica Acta, Part B, 58, 2003, pp. 669–680. Scheler 1865 Aug. Scheler, Annuaire statistique et historique belge, Brussels: Brussels Imprimerie, 1865. Schittich, Debord, and Drey 2001 Christian Schittich, Didier Debord, and Sabine Drey, Construire en verre, Paris: Presses Polytechniques, 2001. Sommer 2003 Siegfried Sommer, “Glasbauten,” in Technik-Wissen, 1900–1915.14, ed. Reinhard Welz, Mannheim: Vermitt ler Verlag e.K., 2003. Stokroos 1994 Meindert Stokroos, Bouwglas in Nederland: Het gebruik van glas in de bouwnijverheid tot 1940, Amsterdam: Stadsdrukkerij Amsterdam, 1994. Stuart 2003 Diana Stuart, Designs Underfoot: The Art of Manhole Covers in New York City, Sharon, Connecticut: Lyons Press, 2003. Wigginton 2004 Michael Wigginton, Glass in Architecture, London: Phaidon Press, 2004. Winterton 1953 L. C. Winterton, Years of Reflection, 1783–1953: The Story of Haywards of the Borough, London: Harley Publishing Co. Ltd., 1953. the use of glass bricks in architecture in the 19th and 20th centuries: a case study 201 Glass and Ceramics Conservation 2010 Interim Meeting of the ICOM-CC Working Group October 3–6, 2010 Corning, New York, U.S.A. Hannelore Roemich, Editorial Coordinator ICOM Committee for Conservation in association with The Corning Museum of Glass © 2010 International Council of Museums ICOM-CC Glass and Ceramics Working Group Committee: Gerhard Eggert Coordinator Hannelore Roemich Editorial Coordinator Review Panel for Papers Renske Dooijes, Leiden, The Netherlands Gerhard Eggert, Stuttgart, Germany Agnès Gall-Ortlik, Barcelona, Spain Isabelle Garachon, Amsterdam, The Netherlands Stephen P. Koob, Corning, New York, U.S.A. Laurianne Robinet, Gif-sur-Yvette, France Kate van Lookeren Campagne, Amsterdam, The Netherlands For The Corning Museum of Glass: Editor: Richard W. Price Design and Typography: Jacolyn S. Saunders Editorial Adviser: David Whitehouse Proofreader: Monica S. Rumsey Reference Librarian: Gail P. Bardhan ISBN: 978-0-87290-182-7 Library of Congress Control Number: 2010931220 All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted in any form or by any means, whether electronic or mechanical, including photocopying, recording, or otherwise, without the prior permission in writing of the publisher. Cover Image: Cire perdue figure made by Frederick Carder in the 1930s or 1940s, with a repair in which the epoxy is badly yellowed. The Corning Museum of Glass (59.4.426).