The influence of physico-chemical material properties on erosion
Transcription
The influence of physico-chemical material properties on erosion
Geomorphology 81 (2006) 235 – 251 www.elsevier.com/locate/geomorph The influence of physico-chemical material properties on erosion processes in the badlands of Basilicata, Southern Italy Marco Piccarreta a , Hazel Faulkner b,⁎, Mario Bentivenga c , Domenico Capolongo a a c Dipartimento di Geologia e Geofisica, Università degli Studi di Bari, Via F. Orabona, 4, 70125 Bari, Italy b Flood Hazard Research Centre, Middlesex University, Enfield EN34SA, Middlesex, UK Dipartimento di Scienze Geologiche, Università della Basilicata, Contrada Macchia Romana, Potenza, Italy Received 16 June 2005; received in revised form 3 February 2006; accepted 14 April 2006 Available online 12 July 2006 Abstract Piping (tunnelling) appears to be one of the more significant methods of erosion in the badlands in the Plio-Pleistocene marinesourced clays of the Basilicata area in Southern Italy. A detailed field investigation of the pedological, textural, mineralogical and geochemical properties of the clay-rich terrains widely outcropping in two selected badland field sites (the Fossa Bradanica area and the Bacino di Sant'Arcangelo) was undertaken to further elucidate process variability across the complex site. Paralleling findings from other piped badlands, certain physico-chemical properties of the clays were found to influence the different erosional processes in fundamental ways. The very dispersive nature of the materials enhances pipe enlargement so that subsurface flow rapidly becomes the dominant process, causing pipe enlargement by a process of positive feedback. The paper speculates on the progressive role of surface and subsurface processes in the genesis of all evolutional badland forms (calanchi, calanchi mammellonari and biancane). In an early stage, the calanchi mammellonari are produced, as slope mounds become increasingly separated by a dense network of small inclined pipes in the intermediate part of the slopes, a site which is presumed to favour elevated subsurface flow. When the overburden collapses, many cones are isolated in these portions of the slope. A second stage follows in which overland flow dominates, with the water canalizing into small gullies generated by the collapsed crust. At the base of many slopes, this same mechanism produces biancane as residual cones. Because of the structural weakness of piped materials, mass movements cannot be ruled out. In a few locations, landsliding may be involved, especially in the formation of calanchi mammellonari. In this case the intersection of the vertical pipes with the impermeable substratum focuses subsurface flow, and collapse of the surface along this failure plane. Subsequent remodelling occurs by surface processes, since the ‘catchment volume’ for large pipes no longer exists. This interpretation differs from that of others who have argued that in other locations the biancane formation is linked to the development of large vertical pipes along tectonic joints. © 2006 Elsevier B.V. All rights reserved. Keywords: Biancane; Calanchi; Piping; Tunnelling; Dispersivity; Gully; Badland 1. Introduction ⁎ Corresponding author. Tel.: +44 2084115531; fax: +44 2084115403. E-mail address: h.p.faulkner@mdx.ac.uk (H. Faulkner). 0169-555X/$ - see front matter © 2006 Elsevier B.V. All rights reserved. doi:10.1016/j.geomorph.2006.04.010 Badland landscapes are very widespread in the PlioPleistocene marine clays of the Basilicata region of Southern Italy. The badland morphology is dominated by the classic calanchi, calanchi mammellonari and 236 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 biancane1 forms that have been described extensively elsewhere in Italy by Alexander (1982) and Farifteh and Soeters (1999). Calanchi are large degraded landscapes that are present in the form of single morphological units with steep, bare slopes and channels which rapidly incise and extend headwards (Alexander, 1982). However, biancane are dome-shaped forms dominated by rills and micropipes developed in bedrock and surrounded by a basal micropediment (Torri and Bryan, 1997) and have been interpreted by some authors as the end-product of calanchi erosion (Alexander, 1982; Del Prete et al., 1994). Calanchi mammellonari are arguably transitional between calanchi and biancane, due to their intermediate morphological and physico-chemical characteristics (Castelvecchi and Vittorini, 1967; Vittorini, 1977; Alexander, 1980; Sdao et al., 1984; Pinna and Vittorini, 1989). Despite some recent investigations which focus on surface erosion rates (Clarke and Rendell, 2005) we argue here, as have many other geomorphologists, that these landforms cannot be fully interpreted without considering their highly dispersive nature and the tendency for extensive pipe development. In the current investigation, the extensive literature on these badland slope forms is further developed by assessing the success of new material diagnosis tools to further elucidate the manner in which material properties, geomorphological connectivity and developmental stage interplay to explain the differences between the various slope forms. The results are used to develop an explanatory geomorphological model that includes both the geomorphological and geochemical autostabilisation potential of the site as part of the story. It has long been recognised that the local Mediterranean climate, tectonics and human impact interact to determine the gross morphology and surface conditions of this landscape. Revisiting early interpretations by Alexander (1982), attention has recently been given to the explanatory role of lithology, in particular sediment size and clay mineralogy, in explaining the badland forms. For instance, on biancane sites, Battaglia et al. (2002) found clay fractions to be over 65%, significantly higher than on the calanchi sites; whereas the latter were coarser with sand fractions between 6% and 18%. Both sites have been reported to possess clay minerals in the smectitic group, double-layer clays that are dispersive. This study would suggest that material properties can be morphologically diagnostic. Early work in badland areas has always affirmed that physico-chemical properties of the materials play an important role in 1 Torri (personal communication) suggests these terms were devised originally by Gausparri (1978). both rill initiation (Hodges and Bryan, 1982; Imeson et al., 1982; Gerits et al., 1987; Imeson and Verstraten, 1988) and surface crust development (Bryan et al., 1978; Torri and Bryan, 1997). Smectitic (2:1:1 clays) will swell on wetting, sometimes sealing the surface, encouraging overland flow and rill erosion. Additionally, for these clay minerals, high exchangeable sodium on the exchange complex promotes dispersion (deflocculation) of the clays. The exchangeable sodium percentage (ESP), sodium adsorption ratio (SAR), sodium percentage (PS) and total dissolved salts (TDS) are commonly used to measure the dispersive state. Sediment containing deflocculated clay can be entrained at much lower stream powers than normal (Sherard et al., 1976; Torri et al., 1994), so these geochemical properties strongly affect physical erosion rates and patterns (Faulkner, 2006). However, if suitable macropores are available within the material for enlargement, dispersion can encourage the rapid enlargement of subsurface pipes (Benito et al., 1993; Gutierrez et al., 1997), a process sometimes referred to as piping or tunnelling. It has been argued that the threshold values for deflocculation are ESP = 12% and SAR > 15. However, although Battaglia et al. (2002) found the SAR to be significantly higher in biancane than in calanchi forms, the difference alone did not seem to be able to distinguish the two features. To predict the tendency of materials to pipe, Faulkner et al. (2000, 2003, 2004) explored the effectiveness of the relationship between electrical conductivity (EC) and SAR, originally used by Rengasamy et al. (1984). Whilst this improves diagnosis over the use of ESP or SAR values alone, it seems that this analysis is also insufficient in itself to distinguish between badland surfaces in terms of their morphology. It was found that the percentage presence of the swelling clays in the overall material mass is very important. Where clay percentages are high, the material mass is rendered impermeable on swelling, encouraging surface wash erosion and reducing infiltration. Where clay percentages are low, the deflocculation of the clay fraction merely destructures a material already lacking in other sources of cohesion, encouraging subsurface erosion. Given the presence of a suitable hydraulic gradient through a site, this distinction will separate materials that are dispersive but which do not develop large pipes from those that do. Therefore, the relationship between sediment size and SAR was demonstrated to play an additional role in diagnosing the development of a non-dispersive crust at a single badland site. M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Robinson and Phillips (2001) found that high organic matter (OM), iron and aluminum oxides can promote aggregate stabilization in the top horizons. The effective organic buffering content of surfaces in their study areas was found to be present when OM contents > 20 g·kg− 1, this value being sufficient to stabilize aggregates. Data from another badland site near Vera in SE Spain (Faulkner et al., 2003) demonstrated that through time, buffering of site geochemistry of several sorts can be involved in local surface stabilization. In some cases, crusts may lose sodium over time, probably because of the buffering by calcium during leaching or by hydrogen on the cation exchange sites under a vegetation cover or in 237 the presence of algae (for example, see Alexander et al., 1994). The relationship between pH and SAR can be used to indicate the extent of material buffering as dispersivity changes. Paralleling similar findings by Robinson and Phillips (2001), Faulkner et al. (2004) found in SE Spain that the latter condition may present morphologically as a stable (buffered) crust and a dispersive subsurface horizon into which shallow subsurface pipes preferentially locate. When the non-dispersive crusts collapse into the pipe, rills and gullies form (“pipe-origin” rills and gullies). Provided no change to basal connectivity occurs through time, the reduction of SAR in surface materials may progress to the point where a Fig. 1. Location of the two study areas in SE Italy. 238 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Alexander, 1982). Pipe enlargement, surface geomorphology and evolution style depend on all these issues, not just the material's dispersive signature. 2. Aims This paper uses these previous findings in relation to badland material diagnosis (Faulkner et al., 2000; Battaglia et al., 2002) and material autostabilisation (Torri and Bryan, 1997; Robinson and Phillips, 2001; Faulkner et al., 2003, 2004) as tools with which to reinterpret two new slope sites in the Basilicata badland areas. Specific objectives are to ➢ assess the efficacy of the ‘three signature’ diagnostic plots as tools to interpret the sites; ➢ explore whether downslope patterns of autostabilisation found in other similar badland areas are present; ➢ use findings to explore the link between physicochemical properties of the clays and pipe frequency and slope morphology; ➢ use further local geomorphological factors to speculate as to how the erosional processes then operate through time to explain the evolution of the various badland forms (calanchi, calanchi mammellonari and biancane). 3. Regional setting Fig. 2. Block diagram suggesting the manner in which lithology and fracture patterns have affected the development of the monoclinal landscape and Aliano. geochemical autostabilisation occurs at some depth, as in the Tabernas badlands (Faulkner et al., 2003). Even these three ‘site signatures’ (SAR/EC; particle size/SAR; pH/SAR) are in themselves not sufficient to explain the morphological variety found in badland areas because the topographic setting of the exposed materials, and changes to that topographic setting through time, are also crucial. At any point within a dispersive, infiltrating landscape where there is a sufficiently large ‘up-net’ catchment volume of water (which depends on the availability of a considerable infiltrating surface ‘up-net’, which is topographically determined at any one point in time), then significant pipe flow volumes can be generated ‘down-net’. In the presence of good hydraulic gradients through the site, pipes can reach colossal sizes when all these conditions are met (Heede, 1971; The investigated area in the Fossa Bradanica is located at Serra Pizzuta, near Pisticci, while the other study area is at Masseria Mastrosimone, Aliano, within Bacino di Sant'Arcangelo, a part of the middle Agri basin that has been mapped as having some of the most environmentally sensitive2 landscapes in southern Italy (Basso et al., 2000) (Fig. 1). The Masseria Mastrosimone area is dominated by silty and marly PlioPleistocene marine-sourced clays and rare beds of sands, with a total thickness estimated at 900 m. The Serra Pizzuta site, south-west slope of the Pisticci hill, is dominated by silty clays interspersed with rare sandier units and capped discordantly by polygenetic conglomerates. In both study areas, the topography has a gentle dip and morphology is expressed as a typical monoclinal landscape. However, the causes for the Basso et al. (2000) define an environmentally sensitive area as “… a specific and delimited entity in which environmental and socioeconomic factors are not balanced, or are not sustainable for that particular environment”. 2 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 239 Fig. 3. Block diagram suggesting the manner in which landslide features have produced a topography at Pisticci which has a superficial similarity to that at Aliano. monoclinal topography differ in the two regions. The Aliano (Fig. 2) site has been interpreted as a simple monoclinal system, whereas at the Pisticci site, landslides are particularly widespread on the SE-facing hillslopes (Guerricchio and Melidoro, 1982). Whereas the gentle dip slopes around Masseria Mastrosimone near Aliano, when not resculpted by land-levelling, retain a fairly good vegetation cover and in places are used for agriculture, the scarp slopes are devoid of cover and are back-wearing by a mixture of surface wash, piping and mass movements. Near Pisticci the surficial pattern is repeated, although the direction of (and reasons for) the failure planes that separate the monoclinals is interpreted differently (Fig. 3), and the slopes are generally somewhat steeper. In both settings, the rapidity of the geomorphic processes on the relatively steeper scarp slopes generally prohibits vegetation from securing a stable function. On vertical imagery, this monoclinal topography displays a stripy appearance, the paler linear elements (the bare surfaces of the badlands) are formed in every case on the scarp in the monoclinal field. Although the monoclinal morphology has differing origins in the two areas, in both settings, the existing primary and secondary network of fractures and joints appears to influence the genesis and development of surface drainage (Del Prete et al., 1994). Farifteh and Soeters (1999) argue that at the large scale, the initiation, development, spatial distribution and intensity of the pipe systems in the area are influenced by the geostructural lineated characteristics of the area. At a more detailed scale, it is the secondary failure and joint features in both settings that appear to influence the nature and direction of the smaller scale evolution of scarp slope forms (Boenzi et al., 1976). At Aliano, down-valley structural features have been focussed around the weaker parts of the structural sequence of marine Fig. 4. Aspects of the slope morphology suggestive of pipe activity in the Plio-Pleistocene sediments. 240 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Fig. 5. Images of the two study slopes: (a) the Masseria Mastrosimone site at Aliano; (b) the Serra Pizzuta slope at Pisticci. clays, although in the case of Pisticci, since these are failure planes not lithological features, these lineaments are more discontinuous in their down-valley pattern as might be imagined. Certainly these fractures and joints would appear to give a rectilinear look to some of the resulting morphology around Aliano. Farifteh and Soeters (1999) conclude that the joints in the clay bedrock provide macropore foci for pipe enlargement. Several authors (Alexander, 1982; Phillips, 1998; Clarke and Rendell, 2000) have demonstrated that abundant montmorillonite and mean ESP values between 36% and 45% characterize the extensively piped clays of this area, so pipe development is very commonly found along these features (Fig. 4). Given that larger pipes will collapse to produce a sort of surface drainage feature (or gully), the overall progression of the morphology by predominantly piping and then subsequent pipe roof collapse has underlying structural control. At a smaller scale still, dissection cracks in the clay will further focus the development of micropipes; however, these may follow the hydraulic gradients produced by the development of secondary morphology, rather than the original structural patterns, a view supported by the field research of Torri et al. (1994). 4. Data and methods After a detailed field study of the widely outcropping Plio-Pleistocene clay terrain at both sites, pedological, textural, mineralogical and geochemical investigation was undertaken within each of the two study sites. Sets of soil samples were collected at top, middle and base of two characteristic badland slopes, one in each area (Fig. 5). Two sampling procedures were followed. The first sampling, from the crust to the bedrock (found to a maximum depth of about 50 cm at Masseria Mastrosimone and 90 cm at Serra Pizzuta), was aimed to reconstruct the pedologic profile and to define OM, pH, EC3 in order to evaluate the soil aggregate stability. To reassure ourselves that the sampling on the basis of visual identification of soil profile features was not biased, a second sampling was made at a regular centimetre scale, moving from crust to bedrock. The analysis of mineralogy was determined in greater detail from this sampling. X-ray diffraction was used for total and clay fraction samples using a Siemens D5000 diffractometer. Chemical elements of bulk rock were determined by X-ray fluorescence using a Philips PW 1480/10 spectrometer with Cr radiation. The chemical characterisation also includes pH, SAR = (Na+/[(Ca2++ Mg 2+ )/2] 1/2 ), PS = ([Na + /(Na + + K + + Ca 2+ + Mg 2+ )] ⁎ 100); and TDS (total dissolved salts, used here as a substitute for electrical conductivity in the signature plots adopted by Faulkner et al., 2000). Whilst the SAR ,TDS and pH would allow an interpretation of the first and third signatures used for material diagnosis by Faulkner et al. (2001), to obtain particle size for signature 2, the samples were prepared for granulometric, mineralogical and chemical characterisation at IMAA (Istituto di Metodologie di Analisi Ambientale, Italian CNR, Potenza). A detailed grain size analysis (Shepard, 1954) was carried out for the samples adopting a laser diffraction method; the separation of the granulometric fractions was made using the fractionated sedimentation technique. Since mean sediment sizes were all so convergent, a decision was made to use the clay % in the sample 3 In the event, TDS was used as a surrogate parameter for EC due to analytic difficulties with the sample. This does not affect the sense of this signature analysis because of the strong correlation between TDS and EC. M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 241 Table 1 Data related to the preliminary set of material analyses Location Horizon Depth (cm) Masseria Mastrosimone (Aliano) Top C1 0–24 R 24–54+ Middle C1 0–24 R 24–54+ Base C1a 0–6 C1b 6–12 C1c 12–18 R 18–42+ Pisticci Top A 0–15 BC 15–30 CB 30–50 CR 50–90+ R 90+ Middle C1 0–12 R 12–34+ Base C1 0–12 R 12–34+ pH Organic Matter (g/kg)a Total CaCO3 (g/kg) Electrical conductivity (μ S/cm) SAR 18.21 8.48 9.75 8.48 9.75 8.55 9.38 9.97 9.23 6.13 5.16 6.13 5.16 8.43 8.79 7.80 6.80 143.08 138.28 143.08 138.28 127.44 150.73 138.42 145.89 2850 1879 2850 1879 5230 5180 1038 1422 8.55 8.21 8.38 8.56 10.02 4.01 3.67 4.02 6.80 5.11 6.78 5.11 6.78 155.60 171.57 163.59 171.57 145.89 91.42 158.03 91.42 158.03 140.6 2060 2400 1889 1422 4830 4360 4830 4360 8.44 9.06 8.44 9.06 rather than the mean particle size for use when plotting signature 2. 5. Results and interpretation The results relating to the first set of samples show that all the aggregates have OM contents below the critical threshold of 20 g/kg and SAR values exceeding the threshold of 15 (Table 1). As a consequence they suffer physico-chemical breakdown on contact with water. The pH values range from 8.29 18.02 8.12 17.94 15.84 13.69 15.30 4.54 27.44 30.41 50.56 26.65 37.97 to 8.85 at Masseria Mastrosimone, and from 8.22 to 9.19 at Serra Pizzuta. In both cases, pH values increase towards the base of the examined profiles. The EC values show the same pattern with depth as pH. Signature 1, the relationship between EC and SAR plotted in relation to the Rengasamy et al. (1984) domains shows that all the samples have a dispersive character (Fig. 6). The sampling on the basis of horizons did not appear to be sufficient to differentiate the samples so that they can be inspected for process changes with depth. Fig. 6. The first sample survey data plotted for the Aliano and Pisticci slopes in relation to the Rengasamy domains of dispersivity (Rengasamy et al., 1984). 242 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 90%; (b) more than 50% of particles are smaller than 8 μm; (c) the clay fraction <2 μm represents about the 20% of the total. Further inspection of Table 2 demonstrates that in relation to the top and immediate subcrust data, a coarse crust is often underlain by inwashing of finer particles in the layer beneath, whereas the subsoil increases in coarseness once again. On Fig. 8a and b, the parameters influencing dispersivity at both the Masseria Mastrosimone (Aliano) and Serra Pizzuta (Pisticci) sites, calculated from the first survey data, are plotted as profiles (data listed in Table 1) for top, middle and slope base positions. The values of pH show the same general increase with depth down the profiles of both investigated slopes, whereas SAR demonstrates very different behaviour between the two sites. At the top and at the base sites of Serra Pizzuta slope (Fig. 8b), SAR increases up to a depth of 20–25 cm, and then slightly The more detailed second set of samples was analysed for textural, mineralogical and chemical characteristics in the same way as before. Mineralogical analyses demonstrated that phyllosilicates dominate both the sites, followed in order of abundance by quartz, calcite, feldspars and dolomite. Traces of gypsum and hematite are present only in some samples. Clay mineralogy is dominated by illite and kaolinite, followed by chlorite and expandable clays. These data do not agree with previous literature, which has suggested that montmorillonite is the main clay mineral. In both the investigated slopes, there are no significant mineralogical differences from the top to the base site of the slopes. The textural data in Table 2 and Fig. 7 demonstrate that the samples of both investigated sites are clayey silts with a sandy fraction <3%. The analysis shows that (a) the percentage of the fraction smaller than 32 μm is about Table 2 Data related to the second set of material analyses Sample Na+ K+ Masseria Mastrosimone (Aliano) TA1 9.23 0.58 TA2 21.99 0.80 TA3 13.75 0.56 TA4 10.56 0.01 MA1 8.79 0.67 MA2 15.39 0.60 MA3 11.21 1.03 MA4 6.82 1.23 BA1 11.87 0.91 BA2 8.14 0.65 BA3 5.50 0.91 BA4 6.38 0.65 BA5 7.04 0.65 Pisticci TP1 TP2 TP3 TP4 TP5 MP1 MP2 MP3 MP4 MP5 MP6 BP1 BP2 BP3 BP4 BP5 BP6 BP7 0.63 6.52 13.27 17.83 19.57 21.97 33.06 23.05 18.49 16.53 19.36 15.01 26.10 15.66 23.27 16.09 13.05 16.09 0.55 0.45 0.58 0.36 0.46 0.56 0.69 0.55 0.58 0.43 0.54 0.69 0.66 0.52 0.69 0.51 0.49 0.69 Ca2+ Mg2+ TDS (meq/l) PS SAR (meq/l) pH Clay % 1.56 2.78 0.51 0.68 1.49 0.63 0.81 0.95 2.59 1.14 0.88 0.95 0.76 0.94 2.50 0.58 1.14 0.67 0.58 1.14 1.87 0.71 1.77 1.35 1.46 1.25 12.32 28.07 15.39 13.39 11.62 17.20 14.20 10.86 16.07 11.68 8.64 9.43 9.69 74.98 78.36 89.32 78.83 75.69 89.49 78.98 62.75 73.88 69.63 63.64 67.66 72.63 8.26 13.55 18.64 11.05 8.48 19.76 11.35 5.74 9.25 6.75 5.20 5.82 7.03 8.29 8.43 8.44 8.64 8.40 8.68 8.85 8.67 8.60 8.70 8.68 8.70 8.79 28.70 33.70 32.30 32.00 31.00 31.00 32.30 34.30 33.30 31.70 32.00 33.70 31.30 0.40 5.55 11.35 0.50 0.94 4.12 6.74 0.75 0.30 0.15 0.17 3.12 3.06 0.17 0.44 0.22 0.20 0.50 0.66 1.13 1.75 0.21 0.51 0.41 0.62 0.25 0.33 0.25 0.29 1.54 0.82 0.45 0.82 0.29 0.33 0.82 2.24 13.66 26.94 18.90 21.48 27.06 41.10 24.60 19.69 17.36 20.36 20.36 30.64 16.81 25.22 17.12 14.06 18.11 28.18 47.78 49.24 94.38 91.11 81.18 80.43 93.72 93.89 95.21 95.09 73.71 85.17 93.15 92.27 94.02 92.79 88.89 0.87 3.57 5.18 30.04 22.99 14.60 17.24 32.68 32.98 37.12 40.24 9.83 18.74 27.96 29.32 31.79 25.38 19.80 8.22 8.40 8.63 9.01 8.97 8.59 8.98 9.19 9.00 8.85 8.93 8.41 8.74 8.78 8.91 8.79 8.75 8.82 41.70 40.00 42.30 40.00 36.70 35.30 36.70 34.00 38.70 37.70 36.00 37.00 35.00 35.00 36.00 35.00 34.00 36.50 The sample code’s first symbol refers to the position on the slope , i.e.T, M, and B refer to top, middle and base slope samples. The second code symbol refers to locations at Pisticci and Aliano, respectively. Final code numbers suggest depth of sample. M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 243 Fig. 7. Grain size plots in which materials for the two sites are distinguished on the basis of sediment class: (a) Aliano; (b) Pisticci. decreases towards the bedrock, whereas it continuously increases in the middle-slope profile. At Masseria Mastrosimone (Fig. 8a), SAR shows the same behaviour as at Serra Pizzuta at the top of the slope, whereas SAR decreases or remains constant at the middle and base slope positions. The data in both Fig. 8a and b indicate an increase in dispersivity favouring piping at depths and geochemical autostabilisation at the surface. The effect is more pronounced in the case of the Pisticci data. The saturated paste composition of the second set of samples is given in Table 2, together with the calculated SAR, PS and TDS parameters. The monovalent cations appear mainly represented by sodium, and potassium is only present in small concentrations. Calcium and magnesium are always dissolved in pore water in significant amounts, with Ca2+ often dominating over Mg2+ at the surface, whereas Mg2+ prevails at depth. From Fig. 6, all the samples of Masseria Mastrosimone and those of the middle and base sites of slope of Serra Pizzuta are dispersive, according to the Rengasamy et al. (1984) criteria. However, Sherard et al. (1976) explored SAR, TDS and PS as a function of clay dispersivity, and this plot was attempted as Fig. 9. On this diagram, clays plotting in zone A have a high tendency for spontaneous dispersion and can be distinguished from the sediments of zone C (potentially dispersive or nondispersive) and those of zone B (ordinarily erosion-resistant). In Fig. 9, the samples from the top site of Serra Pizzuta slope are differently interpreted: the surficial (crust) sample PT1 shows a non-dispersive tendency; the dispersive status of the middle samples PT2 and PT3 is ambiguous, and the deepest samples PT4 and PT5 are dispersive. These data again reflect the tendency, clearer for Serra Pizzuta site, towards the geochemical autostabilisation, starting at the top of the slope. The full set of site signatures is displayed for the second, fuller survey in Fig. 10. Firstly, we consider the Serra Pizzuta (Pisticci) signatures. The SAR/TDS signature suggests that the slope is stabilising from the top–down, and since pH was found to be always lower in the crust than in the substratum, the idea that a more acidic (buffered) surface develops through time can be inferred. This is confirmed by the strong positive correlation between pH and SAR at the top of the Pisticci slope, reinforcing the view that autostabilisation of the crust at Pisticci is occurring by a buffering mechanism. These findings match our Spanish results from Vera (Faulkner et al., 2003). At Masseria Mastrosimone (Aliano), however, the least dispersive sites are found at the slope base. Since the slope top is host to a considerable cover of Pistacia lentiscus and Lygeum spartum, these results were surprising. Apart from the sporadic presence of L. spartum, the erosional slopes are normally bare at Serra Pizzuta. It appears that stabilisation of the materials at Aliano by organic buffering has not proceeded very far, if at all. However, Table 1 shows that despite the absence of current vegetation, the top of the Pisticci slope has the highest organic content of all samples analysed (10 g/ kg). Although lower than the threshold for aggregate formation noted by Robinson and Phillips (2001) in similar materials, this difference may hold a key to the contrasting pattern of signatures described above. 244 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Fig. 8. (a) Surface-to-depth plots of cations, SAR and pH for the top, middle and slope base sites, Aliano. (b) Surface-to-depth plots of cations, SAR and pH for the top, middle and slope base sites, Pisticci. M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Fig. 8 (continued). 245 246 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Fig. 9. Sherard's suggested diagnosis shows that from our first survey, site PT1 is not dispersive, PT2 and PT3 are intermediate, and all others are dispersive. Sites labelled PT = Pisticci top. Piccarreta et al. (2006) argue that semi-natural vegetation may have been present at the Pisticci site at the beginning of the 20th century, and that cultivation may have been intense from this period onwards. We argue here that this explains this disparity, and that the unexpected differences found can be possibly attributed to the buffering exchange between hydrogen and sodium ions at this site due to the availability of organic acids during at an earlier period when the cultivation of the site started. None of the relationships between particle size and SAR (not shown) were significant, probably owing to the generally similar mean sediment sizes, which failed to effectively spread the SAR values. As a result, the second site signature (SAR/particle size) was replaced by SAR/clay % of the sample (Fig. 10) for both sites. In this figure, the value r is the Pearson's product moment correlation for the best fit lines, which are plotted where the relationship is significant (p > 0.01). The expected inverse nature of the second signature, as found at Mocatan, SE Spain (Faulkner et al., 2000) and which proved to vary downslope as geochemical autostabilisation progressed in Vera, SE Spain (Faulkner et al., 2003), was picked up again in the case of the Serra Pizzuta (Pisticci) sites, although this effect was not noticeable in the Masseria Mastrosimone (Aliano) data set. All the slope top sites have finer material than the slope bases. 6. Geomorphological implications Our results suggest that Alexander's (1982) view of the Basilicata badland landforms as an evolutionary sequence is correct, and that Battaglia's differences are explicable in terms of geochemical site stabilisation, i.e., geochemical changes of the same material as calanchi geostabilised into biancane features. The results obtained for these samples from relatively short rectilinear slopes on the two badland sites show clearly that Basilicata clays are highly dispersive and prone to piping and tunnelling in the middle and basal part of the slopes, and that, especially at Pisticci, they show a tendency to autostabilisation at the surface, paralleling findings elsewhere. The results provide tentative support for the use of the site signature approach in characterising these effects. Also, as observed by several authors (Alexander, 1982; Sdao et al., 1984; Farifteh and Soeters, 1999), subsurface flow is frequently focussed along macropores associated with cracks, bedding planes or failure planes at both sites. It can be inferred that the geochemical changes cause a deflection of the subsurface flows at the interface with unweathered subsurfaces, so that on progressive degradation and pipe collapse a hummocky degraded state progressively evolves (calanchi mammellonari). It is also not surprising that the forms evolve in midslope and are degraded finally into biancane, which dominate at the base of the evolving escarpment because the upslope pipes will be relatively larger, collapse and degrade earlier. Therefore, the pattern is progressive with distance downslope, because up-slope catchment ‘volume’ for pipe flow during any one event is distancedependent. Both tectonic and/or failure features dictate the gross form of the mounds. It is also possible to hypothesize that calanchi mammellonari are produced in M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Fig. 10. The three site signatures for Aliano (above) and Pisticci (below). 247 248 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 Fig. 11. Schematic diagrams and plates illustrating the manner in which cones or mounds become isolated by surface processes through time (b and c); and small pipe development suggested for the Aliano site (d and e). the Serra Pizzuta (Pisticci) case by the remodelling of the small landslides bodies (Fig. 3), although how the interplay between pipe enlargement and landslide generation works requires further investigation. For instance, it is possible that local infilling of joints and failure planes provides a site for vegetation to settle which can have a locally important role in increasing or decreasing erosion and the pH of subsurface flow. At Aliano, field surveys showed that in the intermediate part of the slopes, the calanchi mammellonari are M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 separated by a dense network of small inclined pipes, which favour elevated subsurface flow (Fig. 11). When the crusts collapse, many cones are isolated in these portions of the slope. However, once some erosion has occurred, the new slopes develop minor pipe forms (of much smaller size and relatively shallow because of a very restricted catchment at this stage), these will be inclined along new, local hydraulic gradients. Together with desiccation cracks which can develop at the contact between cracked surface and impermeable substratum, they produce a highly ramified or reticulated network of subsurface horizontal pipes and micropipes. At the base of many slopes, this same mechanism produces biancane as residuals cones, the surface of which appear to become relatively fossilised with a relative preponderance of overland flow, with the water canalizing into small rills generated by the crust's collapse. Thus, alongside the important physico-chemical predispositions of the sites, the geomorphology of each site, and the progressive hydraulic conditions as erosion proceeds (and their distance-dependency) gives rise to the calanchi/calanchi mammellonari/biancane sequence down the scarp slopes. 7. Conclusions Paralleling findings from other piped badlands, this research has demonstrated that certain physico-chemical properties of the local sodic Plio-Pleistocene clays 249 influence the different erosional processes in the two study slopes at Basilicata in fundamental ways. The physico-chemical properties of the two monitored badland sites show an important tendency (clearer around Pisticci) to geochemical autostabilisation on the top of the slope. Clay materials in the middle and base of slopes retain a dispersive character. Piping plays a main role in badland morphology, especially in the intermediate and basal part of the slope, favouring the formation and development of calanchi mammellonari and biancane. The very dispersive nature of the materials enhances pipe enlargement along planes of weakness, so that subsurface flow rapidly becomes the dominant process, causing pipe enlargement by a process of positive feedback. The pH/SAR relationship shows the tendency of the crust to autostabilise, confirming it is really an effective site signature. This paper has also speculated on the progressive role of surface and subsurface in the evolution of badland forms (calanchi, calanchi mammellonari and biancane) at both sites. Our interpretation is as follows: at Aliano, an early stage following the exploitation of local planes of weakness (joints, bedding plans at Aliano), calanchi mammellonari are produced as slope mounds are increasingly separated by a dense network of little inclined pipes in the intermediate part of the slopes, a site which is presumed to favour elevated subsurface flow (Fig. 11). When the overburden collapses, many cones are isolated in these portions of the slope. A Fig. 12. Schematic diagram and plate illustrating the development of calanchi mammellonari and biancane forms on the slipped surfaces at Pisticci. 250 M. Piccarreta et al. / Geomorphology 81 (2006) 235–251 second stage follows in which overland flow dominates, with the water canalizing into small gullies generated by the collapsed crust. At the base of many slopes, this same mechanism produces biancane as residual cones. Because of failure planes at Pisticci, by contrast, the macropore development is controlled by failure planes. In a few locations in both areas, a secondary (post-pipe development) role for mass movements cannot be ruled out, especially in the formation of calanchi mammellonari at Pisticci (Fig. 12). In this case the intersection of the vertical pipes with the impermeable substratum focuses subsurface flow and collapse of the surface along this failure plane. Subsequent remodelling occurs by surface processes, since the ‘catchment volume’ for large pipes no longer exists. This interpretation differs from that of others who have argued that in most locations biancane formation is linked to the development of large vertical pipes along tectonic joints. Geochemical stabilisation signals at both locations support these interpretations and suggest that ‘top– down’ geochemical slope stabilisation is occurring as calanchi evolve into biancane. 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