Manufacturing Tools
Transcription
Manufacturing Tools
24 MANUFACTURING TOOLS TOM RITZDORF Commercial electroplating began almost two centuries ago. The manufacturing technology for a long time consisted of what we consider the minimum elements needed to deposit metal: open tanks, simple solutions for cleaning, rinsing, and electrodeposition, soluble or insoluble anodes, and a power source. There was virtually no ventilation or proper waste disposal. The entire operation was manual. Electroplating quality depended greatly on the experience and skill of the operator. Certain physical properties of deposits were improved after plating by heat treating or buffing [1]. Over the years the industry grew as an art. Improved processes and techniques were discovered along the way and many were kept secret until others heard about them or stumbled on the technology themselves. Eventually platers began filing patents to protect their rights to discoveries. About the same time entrepreneurs emerged to make a business of developing and selling new ideas for better plating solutions, techniques, and machinery. Following Edison’s success with his research laboratory, many industrial companies established their own research and development laboratories, which included electroplating sections supporting manufacturing operations. Electroplating manufacturing technology was developed as needed: (1) to solve production problems, (2) to reduce cost, (3) to increase production rates, (4) to improve quality of the product, and (5) to meet new standards set by product designers and waste disposal regulations. Modern electroplating technologies developed for manufacturing include solutions with the best chemistry available, machines that automatically transport the product through all stages of processing, computerized monitoring, and control systems that also store and process data, online and offline inspection facility, rapid chemical analysis systems, and an efficient waste treatment system. Many developments have resulted from attempts to reduce manufacturing costs, such as increasing production rates with the same equipment, utilizing cheaper materials, or eliminating unnecessary process steps or equipment. Also new technologies originally developed in non-electroplating industries have been adopted for use in advanced electroplating. Software for machine automation, data logging, and data processing are good examples. Equipment designed specifically for electroplating semiconductor wafers and related microelectronic components have brought together all of the advanced control concepts and have led to great improvements in understanding the nature of the electroplating chemistries and processes that have been utilized in these applications. Fully automatic electroplating equipment can be justified only when large volumes of the same or similar product are processed. Modern automatic tools can be operated with fewer operators, but these people often must be more skilled and knowledgeable about instrumentation, sensors, and computers as well as electroplating. 24.1 ELECTROPLATING EQUIPMENT Automated plating machines were invented to do more costeffective plating through increased worker productivity, improved quality and reproducibility, and higher plating speeds. Equipment design and development improved as time progressed. Better materials, especially special plastics, minimized solution contamination from the machine. Stronger and more corrosion-resistant construction materials extended machine life while allowing operation at higher Modern Electroplating, Fifth Edition Edited by Mordechay Schlesinger and Milan Paunovic Copyright Ó 2010 John Wiley & Sons, Inc. 513 514 MANUFACTURING TOOLS production rates. Modern electronics and sensor technology have made possible more fully automatic plating machines. Equipment for electroplating should be designed with the plating processes in mind. In this regard, care should be taken to provide mass transfer through solution (or part) agitation, replenishment of the plating chemistry, and appropriate distribution of the current density among the parts to be plated. Additionally, the temperature of the chemistry and parts and the solution concentrations should be well controlled to provide repeatable results. This may mean paying close attention to solution drag-in and drag-out, depending on the type of equipment being considered. It is also important to pay close attention to how electrical contact is made to the parts to be processed in order to ensure reliable and repeatable performance. Much of the development that has gone into providing efficient automated electroplating of various parts has been to increase the deposition speed of the electrolytic processes to improve equipment throughput. This is important in order to get the best return on the money spent to buy the automated processing equipment. Since the maximum deposition rate that is reasonable in a manufacturing process is usually related to the limiting current density, this effort essentially consists of boosting the limiting current density for a particular process. Of course, increasing the limiting current density usually involves one or more of the following three changes to the process: 1. Increase the metal concentration in the bath 2. Increase the deposition temperature 3. Increase the agitation rate at the workpiece (decrease the diffusion boundary layer thickness) While the metal concentration depends more on the chemistry than the hardware, the equipment may need to be adapted in order to deal with the high metal concentration by reducing salt crystal formation or to be compatible with modified base electrolyte chemistry. An increase in deposition temperature may also require equipment changes to minimize evaporation or control hazardous fumes or to handle increased corrosive effects of the plating chemistry. Typically, increasing the agitation rate near the cathode in a plating process involves increasing solution flow rates and/or adding agitation through mechanical means or gas bubblers. While the cathode surface is usually the focus in order to increase the flux of metal ions to the surface to enable faster plating rates, the anodic reactions and adequate supply of reactants and removal of reaction products may also be important to avoid limiting the deposition rate due to anode polarization. Modern electroplating manufacturing technology is concerned with mass production, automation, quality, and flexibility. Mass production is important for low-cost manufacturing. It requires machines that will process parts at a high rate while meeting all the specified requirements [2]. Automation helps to minimize labor costs and produce a uniform product. Quality is required to meet market acceptability and product life. Flexibility provides the ability of plating machines to process a variety of parts without extensive machine modification. It can significantly reduce the capital cost of accommodating multiple part types. It is important, at the same time, to consider the type of parts being plated and their particular requirements in order to use equipment that is optimally designed for those parts. Plating machine types include barrel, vibratory, rack, edge board, strip and wire platers, and wafer platers. 24.2 BARREL PLATERS Barrel plating began in the post–Civil War years. Barrels were the first plating device to dramatically increase productivity [3]. There is no racking and unracking of parts, and the operation corresponds well with other bulk treatment operations such as barrel polishing, burnishing, deburring, phosphating, and oxide coating. Barrel plating machines usually require less space, and they are easily automated, minimizing operator attention. Plating barrels come in many sizes and designs, but there are two basic types: horizontal and oblique. Horizontal barrels are usually hexagonal with perforated cylinder walls and have a removable panel through which parts are loaded and unloaded (Fig. 24.1). They may be partially or entirely immersed and rotated via plastic gears. Oblique, or 45 , barrels may have solid walls, open at the top, and contain plating solution, anodes, and the parts being plated or they may have perforated walls and be partially or totally immersed in a tank with outside anodes. A cross section of an automatic barrel plating machine is shown in Figure 24.2. FIGURE 24.1 Rotating plating barrel fixture. RACK PLATERS 515 FIGURE 24.3 Vibratory plating unit where all processing is done in one place moving solutions in and out using different anodes. FIGURE 24.2 Cross section of automated barrel plating machine. Considerable work has gone into plating barrel design and evaluation of construction materials [3]. Construction of a typical barrel plating machine is concerned with (1) the barrel which is rotated so that parts inside are tumbled to expose different areas to plating, (2) a tank that holds the plating solution, anodes, support for the barrel assembly, and means for connecting the barrel to a current source, (3) a gearing system to transfer motor power to barrel rotation, and (4) a means of making electrical contact to parts with flexible probes called danglers fed in through the rotating bearings or with metal studs fastened to the inside barrel walls. To achieve the optimum in barrel plating performance in plating speed and deposit distribution, careful consideration must be given to part size, weight, shape, and type of plating to be applied [4]. Deposit thickness is made more uniform by the following processes: 1. 2. 3. 4. Decreasing the deposit thickness Increasing the plating time Increasing the rotation speed of the barrel Increasing the amount of barrel periphery open to plating solution 5. Decreasing the size of the load 6. Decreasing the size of the barrel Plating current densities are usually low-l0 to 20 mA cm2 [or 1–2 amperes per square foot (ASF)]. Since the number of piece parts plated in a barrel is very large, the productivity of plating is high even though the plating rate is slow. Barrel plating machines are automated using lift arm or elevator-type barrel carriers. They are operated by indexing or stop-and-go movement. In more recent developments of automatic barrels, the cylinder and superstructure assembly is mounted in a carriage, permitting up-and-down movement and a motor drive to rotate and elevate the cylinder. The carriage moves from tank to tank along rails either overhead or on the tanks. 24.3 VIBRATORY PLATERS Vibratory plating is one of the newer developments in plating machines. It is used to plate small parts in bulklike barrel plating, but instead of rotating, it relies on vibrational energy applied to the bottom of the processing cell to move parts about [5]. More uniform deposits are claimed for the vibratory plater compared to barrel plating. The technique is able to handle fragile parts without distortion or damage. At present there are two types of vibratory platers: (1) where all processing is done in one place with solutions moved in an out for the plating sequence (Fig. 24.3) and (2) where the processing moves a basket with a vibrator attached from tank to tank in a sequence like a conventional barrel line [6, 7]. Both vibration frequency and amplitude are adjustable. This is necessary to compensate for process solution viscosity differences to achieve optimum agitation conditions. 24.4 RACK PLATERS Rack plating consists of attaching parts to an insulated frame and either manually or automatically moving the racks of parts through all plating and rinsing steps [8]. Figure 24.4 is a cross section of a typical rack plating hoist assembly for printed circuit boards. Good rack design and construction are important to successful rack plating. The following factors must be considered: 1. Size and shape of parts to be plated 2. Size and shape of rack based on tank size and other equipment 516 MANUFACTURING TOOLS FIGURE 24.4 Cross section of a typical rack plating hoist assembly for printed circuit boards. 3. Method of supporting and making electrical contact to parts 4. Insulation of metal parts of rack other than contacts 5. Dielectric shielding to control plating distribution on parts Rack plating machines are of two types: straight line or return. Straight-line machines may be loaded at one end and unloaded at the other, or the process controller can be programmed to bring the rack carrier to the starting point where the same operator can unload and reload the carrier. Return machines are designed to have the carriers always move in the same direction and the tanks are laid out so that racks circle back and the unload station is next to, or the same as, the load position. Rack carrier movement through the machine can be stepand-repeat or continuous. Step-and-repeat machines move carriers a fixed distance on a preset time cycle. When racks are moved from one tank to another, they are raised before carrier movement, then lowered. If racks are in a long plating tank, they are not raised until they reach the end of the tank. Plating thickness is determined by cathode current density and dwell time in the tank. Machines with continuous rack movement automatically raise and lower racks to move from tank to tank. As with step and repeat, dwell time at each process step is controlled by line speed. Electroplating equipment is designed to deposit metal uniformly on the parts to be plated. Current distribution within plating tanks is usually controlled by incorporating dielectric baffles as current shields and by proper design of anode size and placement within the tank. In some cases, bipolar electrodes may be used to improve current distribution. Solution agitation in rack plating equipment may be accomplished in one or more of several methods. The most common methods of solution agitation include mechanical agitators, bubble agitation (usually air), or forced-solution eductors (jet pumps) that mix the solution and direct the flow within the tank across the cathodes to be plated. Ultrasonic agitation has also been used in some cases to provide agitation at the electrode surfaces. Electroless plating is typically a slow deposition process but can deposit uniform films and can deposit on nonconductive substrates. Electroless plating solutions rely on a reducing agent to supply the electrons. The choice of pH, temperature, reducing agent, metal ion, and their concentrations determines the electroless deposition rate. The slow plating rate can be compensated by plating many parts at one time. Plating equipment for electroless plating is similar to that for electroplating but different in several important respects. There is no power supply. This provides advantages in that the equipment is simpler, with no electrical connections. The operating cost may be increased due to higher bath temperatures, though. Dwell time in the plating tank is usually long, often 24 hours for a “full build” of copper on printed circuit boards (PCBs). Continuous solution filtration is essential to remove particulates that could cause spontaneous metal deposition which depletes metal ions from solution and potentially “crashes” the bath. Also, an additional tank containing an acidic stripping solution may be necessary for periodic removal of metal that has plated out on the equipment. The manufacture of PCBs using fully electroless copper is a viable technology to produce fine-line conductors and high-aspect-ratio through holes [9]. Other electroless processes that are in industrial use include nickel for decorative coating of plastics or wear-resistant coatings and electroless nickel/immersion gold (ENIG) for pad finishing of microelectronic components. Many of the pad finishing processes that have historically been used also contained palladium as a barrier between the nickel and gold, and increasingly only nickel and gold are being used. 24.5 STRIP PLATERS Most strip platers can be divided into two groups: (1) electrotinning and electrogalvanizing mill steel platers and (2) STRIP PLATERS strip platers for electronic parts. Both types of strip platers are usually operated reel to reel continuously with splicing “on the fly.” 24.5.1 Electrotinning Prior to 1937 all commercial tin plate was manufactured by the hot-dipping process. Electrolytic tin plate on steel became more economical than the hot-dipping process when continuous cold reduction mills came into operation in the early 1930s [10, 11]. By 1935 small experimental plating machines were designed and built that were capable of electroplating tin on steel strip at high speeds. Electrolytic tin plate became a commercial item in 1937. Electrotinning could produce a thinner, more uniform tin coating than the hot-dipping process [12–14]. Three plating processes were developed: (1) alkaline stannate, (2) ferrostan [registered trademark of US Steel] (polysulfonate), and (3) Halogen (fluoride and chloride). Plating baths for electrotinning are designed for very high speed tin deposition. Most commercial tin plating lines in the world use the ferrostan process, which is based on a sulfonic acid electrolyte. Figure 24.5 shows schematic arrangements of three types of handling and processing machines. These are big machines designed for high-speed strip travel at over 11 m s1 (2000 ft min1). The entry end “pays off” strip into a looping tower that stores a large amount of strip. When the payoff strip approaches its end, it is stopped and quickly spliced by welding to a new roll of strip. While the payoff speed is below normal line speed, strip in the looping tower keeps it going until the payoff strip catches up and restores FIGURE 24.5 517 the volume of strip in the looping tower. A steady tension is put on the strip after the looping tower. Figure 24.6 shows the entry end of an electrolytic tinning line. The steel is cleaned and acid pickled before entering the plating section. Tin anodes need to be replaced often. The procedure is illustrated in Figure 24.7. Note the size of the bus bars that carry current to the cathode contact cylinders. Highspeed strip travel requires very high currents to deposit the required tin. The typical electrical power capacity for a ferrostan line is 100,000 A at 24 V. Solution drag-out control is important since it can amount to 30 gal h1. After rinsing, the tin-plated strip passes a reflow tower that heats the strip above the melting point of tin. This gives the tin a brilliant luster typical of hot dipping. The fused and quenched tin is given a chemical treatment, rinsed, and dried. Finally, a lubricant oil film such as dioctyl sebacate is applied to improve its handling properties in succeeding operations. This is usually an electrostatic process using a high potential between the strip and a fixed electrode while a mist of the oil is produced in between the surfaces. The strip next enters the unit which supplies traction power to pull it through the machine. A tachometer generator is attached to the drive motor which produces the signals to regulate the plating and melting currents in relation to strip speed. 24.5.2 Electrogalvanizing Electrogalvanizing strip plating machines were developed after electrotinning machines [10]. They are similar in design, as shown in the schematic arrangement of a line at Schematic arrangement of handling and processing units of three types of electrotinning lines. 518 MANUFACTURING TOOLS FIGURE 24.6 Entry end of electrotinning line with one coil being paid off and another in reserve position—splice by wleding. FIGURE 24.7 Tin anodes being placed in tank. Note the size of the bus barscarrying current to cells. United States Steel (Fig. 24.8). A looping unit is employed at both ends to enable splicing while the machine is running at full speed. Machines for plating on both sides use vertical cells like those used for electrotinning with either soluble or insoluble anodes and a zinc sulfate electrolyte. FIGURE 24.8 The auto industry requires one-sided zinc-coated steel. United States Steel developed the radial cell system for single-side zinc deposition illustrated in Figure 24.9. The design achieves efficient plating power usage by reducing the distance between anodes and strip. The conductor rolls are 2.4 m (8 ft) in diameter. The total plating pass length is about 67 m (220 ft) for all 18 cells. The zinc for electrolytic replenishment is provided from cast zinc anodes supported on conducting bridges. The anodes are moved across the bridges at a rate determined by the line control computer. Approximately one-half of the anode is consumed as it moves across the bridge. It is then removed and remelted for casting into new anodes. The plating current at each cell is 28,000 A for the 18 cells. The maximum plating voltage is 12 V. Strip widths on the line range from 91.4 to166.4 cm (36 to 65.5 in.). Line speed is computer controlled to maximize production with the available current. Maximum line speed is 183 m min1 (600 ft min1). After leaving the plating section, the strip is rinsed, dried, and moved to the main pulling station. An X-ray coating gauge continuously monitors the coating thickness and provides a feedback signal to the computer for line speed adjustments to maintain the specified zinc thickness. Electrogalvanizing one side of strip up to 6 ft in width at 600 ft min1 is a commercial process. Machines for doing this generally operate 24 h a day seven days a week and stop only for maintenance. Splices are made by welding “on the fly,” and the plating thickness is continuously monitored by X ray with the output signal fed to a plating current controller to Schematic arrangement of one-sided electrogalvanizing line. STRIP PLATERS FIGURE 24.9 519 Schematic arrangement of conductor roll and plating unit CAROSEL for one-sided electrogalvanizing. FIGURE 24.10 Schematic of belt cell for one-sided electrogalvanizing steel strip: (1) metal belt, (2) rubber bonded to top of metal belt, (3) continuous moving steel strip, (4) electrical contact to metal belt, (5) insoluble anode, (6) solution into cell, and (7) solution exit. maintain a constant deposit thickness. The large expense of these machines can only be justified if there is a large volume of product to be plated over several years. Another commercial electrogalvanizing plating cell design developed for depositing zinc on only one side of sheet steel is shown schematically in Figure 24.10 [11, 15]. The “belt cell” uses solution flow between an insoluble anode and a cathode 6 mm apart at 4 m s1 to achieve turbulent flow. Steel strip moves through the cell in the opposite direction to solution flow at speeds up to 200 m 1. Dense, coherent zinc deposits are obtained from sulfate solutions at high current densities up to 350 ASD [16, 17]. Cathode efficiencies are as high as 95%, which is attributed to the high solution flow rate. 24.5.3 Strip Plating for Electronics The explosive growth of the electronics industry began about 40 years ago, and it continues today. It led to a tremendous demand for contacts, lead frames, wire leads, chip carriers, and many other components requiring electroplating of tin, solder, nickel, silver, gold, palladium, or palladium–nickel. The huge number of components required makes it necessary to develop electroplating technology capable of high speed and sometimes selective processing. Loose parts such as pins can be plated in high volume in barrels and vibratory machines. Gold and other precious metals often must be deposited selectively for economic reasons and strip platers are best suited to the job. These are usually reel-to-reel plating machines designed to process one or more part shapes. Modern technology has provided strip plating machine designers with a vast array of chemically stable materials, electrical and electronic devices, and subsystems. High-speed reel-to-reel platers can be divided into four segments: (1) strip transport system, (2) a table with small plating cells and larger solution reservoirs, (3) electrical power sources and controls, and (4) a display of plating conditions. An example of such a machine is shown in Figure 24.11. The machine was designed to electropolish, nickel plate, and gold plate telephone modular cord plug blades. All cells and reservoir tanks were covered to minimize contamination from the environment and make fume exhaust more efficient. It has four separate plating lines each 520 MANUFACTURING TOOLS FIGURE 24.11 Four-line automatic strip plater for telephone modular cord blade plugs. running at 12 ft min1. Figure 24.12 is a schematic of the strip plater. Since the blade being processed in the equipment shown in Figure 24.11 was formed by punching, the contact area had a shear/break surface and needed considerable electropolishing. Dwell time in the electropolishing cells required electropolishing selectively at a current density of about 4000 A ft2 to achieve the desired finish. A high current to a strip can lead to several problems: (1) electrical arcing at the contacts can eventually cause a poor contact, (2) excessive heating of the strip, and (3) excessive heating of the solution. The arcing problem was solved by using tungsten/silver alloy contacting material. Electropolishing quality degrades with solution heating. Strip heating is minimized by keeping the cell short and electrically contacting strip at both ends to minimize resistive heating. Solution heating is also controlled by keeping anode–cathode spacing as close as possible and cooling the phosphoric acid electropolishing solution in the tank. Another problem occurs when electropolishing copper alloy strip. The solution becomes saturated with copper and even- tually starts depositing a powder at the cathode. The copper powder bridges the cell, causing an electrical short so electropolishing stops. The powder is easily removed manually, but an automatic method is more economical. Two methods can be used: (1) a rotating cylindrical cathode with a scraper to remove the powder or (2) periodically vacuuming off the solution with powder next to the cathode. The solution is returned to the tank after the powder is separated out. Good rinsing between chemical and electrochemical steps is very important in all electroplating systems. Spray rinsing is very effective. Nickel plating cells use small titanium baskets with bags and nickel pellets inside. The entire strip receives a gold strike followed by a selective hard gold plate just at the contact edge. Sensors detect when a payoff reel empties or a take-up reel becomes full. That particular line automatically stops until the operator changes reels and restarts the line. Narrow strip platers are used mainly to process parts for electronic applications. These are reel-to-reel platers and often deposit metal selectively. Considerable development has gone into these machines in recent years [18]. They are highly automated, plate at high speeds, and deposit metal with excellent precision. Typical applications are connector terminals and semiconductor lead frames. Gold was often used in these applications, but recently palladium and palladium–nickel alloy with a gold flash has replaced most of the gold [18]. Specially designed selective plating systems have been developed to minimize the usage of precious metals [19]. Strip may be punched or unpunched. Plating unpunched strip is referred to as stripe on strip, with punching done afterward. Most connector terminal plating is done on punched strip with terminals held together with tie bars which are removed during connector assembly. Development of high-speed strip platers began just at the time small low-cost microprocessors became available for machine control. This led to programmable logic controllers (PLCs) being used for overall process and machine control of strip platers. More recently, small computers such as PCs FIGURE 24.12 Schematic of strip plating facility. Each cell is a miniature chemical processing tank. STRIP PLATERS have been used but not in direct machine control. PCs are very good for operator interface and reporting functions. PLCs are better for direct control [20, 21]. Often both electronic devices are used in combination for plating machine monitoring and control [22]. A main plant computer can be programmed to watch over plating operations and alert engineers of problems as they occur. The machine shown in Figure 24.12 utilizes a PLC for process monitoring and control with an interface PC for data logging and analysis. Customers often request data on the processes used to electroplate their product and will pay extra for the information. A central console and process display panel (Fig. 24.13) allows the operator to quickly see the status of machine operation. Each process segment of the machine is designed to run in either the manual or automatic mode. This is desirable when a segment may not be functioning properly in the automatic mode. Another type of strip plater is used in the printed circuit board industry to electroform a thin continuous sheet of copper which is bonded to a plastic dielectric. Copper is plated on the outside of a large rotating polished stainless steel drum. The drum is treated so the copper is removed easily in a continuous sheet. The outside surface of the sheet is purposely plated with a slightly rough copper surface to improve adhesion when it is bonded to a plastic dielectric. This is called vendor copper and may be applied to one or both sides of a flexible or rigid dielectric. FIGURE 24.13 Central console and process display panel. 521 A third type of strip plater manufactures flexible printed circuits. All chemical and electrochemical processing is done on wide roll-to-roll strip plating machines. A thin copper sheet is bonded to one or both sides of a flexible dielectric material such as mylar. A plating mask is applied to one or both sides. Rolls of strip, or web as it is called, then are passed through the plating machine to produce a printed circuit copper much thicker than the initial copper. Tin–lead solder may be plated over the copper for solderability and/or as an etching mask for definition of electrical circuits after the plating mask is removed. The web moves over wide rollers on top and down into each tank in the processing line. The end of each roll is spliced to the next, so the machine sees a continuous web. Bandoleer Plating Bandoleer plating involves attaching individual parts such as connector terminals to a carrier belt that moves through all processing steps like a strip plater. Parts that otherwise would be plated all over in a barrel or vibratory plater can be selectively plated on a bandoleer machine. A vibrator parts handler orients and moves the parts to the carrier belt where they are attached. At the end of the line, parts are detached and the belt circles back to the front of the machine. Edge Board Platers Edge board or tab platers are designed to plate precious metal contacts on printed circuit boards. These are relatively new machines in the plating industry and were developed to serve a specific need for rapid selective plating of gold on contact fingers. Boards are loaded automatically into the continuous motion transport system by indexing the board carrier at the proper time so that moving belts can grasp the board and start it through all processing steps similar to plating nickel and gold on connector contacts in a strip plater. Rubber belts also serve as plating masks for selective plating to eliminate taping. Transport and plating belts are specially designed to firmly contact boards with compliant rubber that will not wear excessively and not stretch. These properties can only be achieved with a compound belt made up of several layers. The belt may also incorporate metal inserts for electrical contact to the contact fingers. Good solution agitation around the cathode is essential for high-speed plating which is necessary for rapid movement of boards through the machine. Plating cell length is another factor that can determine machine speed. If line speed is limited by plating rate in a particular cell, any increase in that cell length can increase line speed. Improving solution agitation around the cathode area may also allow higher line speeds. Good rinsing between chemical treatments is important. Belts also must be rinsed thoroughly before the belts return and contact new boards coming into the plating line. 522 MANUFACTURING TOOLS Drying is done with a blast of hot air directed at the wet areas. Unloading is automatic with boards pushed into board carriers that are indexed to receive each board as it comes off the plating line. Most edge board platers are single lines to avoid being too complicated, especially when belt transport and masking are used. Some tab platers do not use belts. Masking is done with tape that can be done by machine, but this operation is more costly. In such machines contact to the fingers is made via a tie bar around the outer edge of the board which is cut off later. Electric current is brought to the tie bar at either the side or top. Board transport is by moving belts or an overhead trolley with fasteners holding boards. 24.5.4 Wire Platers Wire platers were the first high-speed platers, with plating current densities up to 2000 ASF [10]. These high current densities are made possible by moving the wire at high speeds through plating solution causing rapid wire motion relative to solution, not only parallel to the pull direction but also perpendicular as the result of wire vibration as it travels through the plating cell. Wire is an ideal cathode, usually being round in cross section and continuously uniform in shape throughout the plating operation. Wire also lends itself to multiple line platers, which is important in achieving highvolume production of plated wire needed in a variety of applications. Tin and tin–lead alloys are plated on copper for electrical wire. Gold or palladium–gold is plated on copper wire for connector jacks, copper on steel wire for communication systems, and zinc on steel for fencing and other outdoor applications. Classification of various cell designs is done on the basis of the direction of forced fluid flow which may be axial, normal/radial, or tangential. These are modified somewhat in practical cells [23–25]. Conditions which produce turbulent flow are favored for high-speed plating. 24.6 DECORATIVE AND ENGINEERING PLATING At one time a thin bright chromium deposit over bright nickel plating was used extensively on automobile and appliance parts. In recent times, a combination of product styling changes and increased cost of the Ni–Cr finish due to tougher environmental regulations has reduced its use mainly to just trim. A significant improvement in the cost of hexavalent chromium disposal or recovery would help bring greater use of the attractive bright Ni–Cr electroplated finish. Engineering electroplating technology generally involves improving mechanical wear or corrosion protection by applying metal with special physical properties on very small or very large objects [26]. Outdoor objects such as statues and building domes are usually made decorative by plating but the process of doing the plating involves many engineering factors. The technique of brush plating is used extensively for applications where the part to be plated is too large or in a fixed position away from a plating shop. Special plating fixtures and solutions for substrate cleaning and depositing a variety of metals have been developed [27]. The technique is also used to repair worn or poorly machined parts. Electroforming of metal shapes can be another type of engineering plating [28]. Complicated forms impossible to machine are examples of ideal applications of electroforming. These can be very large objects or extremely tiny forms such as inertial elements in MEMS (microelectromechanical systems) gyroscopes and acceleration sensors or the copper coils and magnetic yokes used in computer memory disk drive and tape read–write heads [29, 30]. Another example is the manufacture of compact discs (CDs) where electroplated nickel stampers are electroformed with the precise image of the master audio or video recording [31]. Where these small devices are plated on silicon wafers or similar substrates, the equipment used will be wafer plating equipment, as described in the next section. 24.7 WAFER PLATING EQUIPMENT Electroplating of wafers used in semiconductor or microelectronic manufacturing has matured dramatically over the last two decades [32–34]. As electroplating has moved from the thin-film recording head and GaAs semiconductor device manufacturing areas to mainstream silicon semiconductors and the manufacturing of numerous MEMS devices, the understanding of the chemistry, process, and equipment interactions has grown dramatically. In addition to advances in chemistry formulations specifically designed to provide superconformal deposition profiles (>100% step coverage) or relatively high deposition rates, several advances have been made to electroplating equipment that is used in the microelectronics industry. These advances include such things as current shielding and virtual anode designs [35, 36], multiple anodes for current distribution control, independently controlled current thieving, and membrane solution separation systems. Many advances have also been made in automated analysis and replenishment systems that are integrated into or support the plating equipment, as will be described in the next chapter. The considerations that are usually the most important in microelectronics plating include process robustness and repeatability. Plating processes usually occur late in the manufacture of microelectronics components, where their value is greatest, and the batch processing nature of microelectronics manufacturing means that between hundreds and hundreds of thousands of devices may be at risk on a single wafer if it is misprocessed. Wafer-to-wafer repeatability is very important in order to ensure uniform product WAFER PLATING EQUIPMENT characteristics, and within-die or within-feature thickness or alloy composition uniformity may also be critical factors. Some of these considerations mean that the microscale pattern density of the substrate may be important in terms of determining the results on the wafer or substrate [37–39]. Generally, semiconductor wafers and similar microelectronic substrates are plated in machines that are automated. The automation required in a manufacturing environment for leading-edge semiconductor devices typically involves completely automatic unloading of the wafers from the holder (cassette or FOUP—front opening unified pod), automatic transfer and processing of the wafers through each of the process steps, and loading the wafers back into the correct holder after they are rinsed and dried. Complete data logging of all the process parameters and response data is also typical, as well as sending these data files to a host computer system over a network connection automatically to facilitate data archiving. Most of these aspects are accomplished according to industry standard specifications for equipment automation, ergonomics, data handling, and general semiconductor equipment guidelines [40–44]. There are also special regulations that apply to equipment that will be used in the European Union [45]. All of these special requirements and specifications, coupled with the understanding that the value of the product being processed may be much more than the equipment itself, results in processing equipment that is relatively complex and costs multiple millions of dollars to purchase (see Fig. 24.13). Also, wafer plating systems have sophisticated error recovery schemes in order to minimize the chance of scrapping wafers when a processing fault occurs. Sometimes semiautomated versions of the equipment are used for research and development or for troubleshooting process and integration problems in a manufacturing line. In these cases, an evaluation of which of the standard semiconductor equipment guidelines must be met should be completed prior to manufacturing of the equipment. Laboratory facilities are also important to help solve production problems when the plating process does not perform as expected. Experimental runs on a small scale can be set up to determine the cause of a problem and also how it may be corrected on the production line. Laboratories are also set up to do routine chemical analysis and plating tests such as the Hull cell or the hydrodynamically controlled Hull cell, which can provide insight to manufacturing problems [46]. Microelectronic plating is done in several types of plating chamber designs. Cell designs based on paddle agitation were some of the first configurations used in microelectronic plating processes. Most often, a fountain plating cell is used for semiconductor plating applications. Rack plating systems can also be configured to handle microelectronic substrates. These plating cells may be configured with the wafer oriented vertically or horizontally, with different 523 advantages and disadvantages for each particular design and configuration. 24.7.1 Paddle Cells Electroplating manufacturing technologies are often developed first in a laboratory. An example is the reciprocating paddle plating cell which was developed by IBM for uniform and rapid deposition of NiFe, Cu, and Au on micrometerscale features for electronic and magnetic devices [47–49]. These cells were designed to provide cathode agitation and reproducible alloy composition uniformity on substrates that could not easily be rotated during the deposition of magnetic films deposited in the presence of an aligning magnetic field. Cells based on this original design have been used in the magnetic recording head industry for the last 30–40 years (see Fig. 24.14). More recently, the reciprocating paddle design has been updated to provide more uniform agitation at the cathode surface along with better control of the current distribution across the face of the substrate and compatibility with automated microelectronic processing systems, as described above [50, 51]. 24.7.2 Fountain Cells Most electrochemical deposition on semiconductor wafers or similar substrates occurs in fountain electroplating cells. These are cells, or electrochemical reactors, where the solution flow is generally from the bottom to the top of the chamber and where the solution exits the main processing area by flowing over a weir near the edge of the wafer. Figure 24.15 shows two examples of common fountain plating cells used in semiconductor processing. Fountain FIGURE 24.14 Deposition cell designed to provide cathode agitation. 524 MANUFACTURING TOOLS FIGURE 24.15 Two examples of common fountain plating cells used in semiconductor processing. plating cells have the advantage of having a characteristically uniform diffusion layer thickness from center to edge when used for plating blanket films on a spinning substrate. Since automated fountain plating systems were first introduced in the early 1990s, many improvements have been made to these electroplating cells to adapt them to the specialized needs of microelectronics plating. Most of these modifications have allowed more efficient utilization with less maintenance, lower cost of operation, or improved process performance and stability. Features such as quick-change anodes and process kits to support different wafer sizes have helped to eliminate expensive down-time associated with these maintenance activities. Incorporation of ion-selective membrane systems have increased bath life, decreased addi- tive consumption, and improved chemical stability. Multiple electrode systems have improved current density control across the wafer and have helped automated plating systems respond to variations in incoming material. It is also becoming more common for microelectronic plating systems to incorporate automated rinsing capability as part of the plating cell, itself, which minimizes the chance of corrosion and minimizes dragout of plating chemicals. 24.7.3 Rack Platers Semiconductor and other microelectronic substrates may also be plated in rack platers. These have already been described above, in Section 24.4, and function in much the REFERENCES same way when used for microelectronic manufacturing. Substrates may be loaded automatically into racks, or fixtures, by the processing equipment or the substrate may be loaded into the rack by operators and loaded into the machine for automatic transport and processing. The racks may be transported and processed in a vertical position or in a horizontal position. Mechanical agitators and eductors provide the most common forms of solution agitation for processing microelectronic components. When using rack plating equipment, it is always critically important to make sure to rinse thoroughly to minimize carry-in of chemicals from upstream processes. These systems typically exhibit greater solution dragout than other types of wafer plating equipment. 24.7.4 controllers and sensors to increase the level of automation in the industry. Technology exists to fully automate most plating machines. The utilization of this technology depends on its cost effectiveness and the ability of plating engineers and operators to handle advanced technology such as computers with complex control software. Plating processes continue to improve with better understanding and knowledge about the processes and the deposits produced for various applications. ACKNOWLEDGMENTS Figures 24.2 and 24.4 were supplied by NAPCO, Inc. Figures 24.6–24.10 are reprinted with permission from The Making, Shaping and Treating of Steel, 10th ed., AISE, 1996. Ancillary Chambers Automated wafer processing systems will contain chambers other than electrochemical deposition (ECD) chambers to accomplish such tasks as wafer alignment (using flats or notches), prewetting, surface activation, intermediate rinses, back-side contamination cleans, final rinse and dry, thickness measurement, and anneals. In fact, they may even include chambers to strip photoresist or to etch metal seed and barrier layers after plating and photoresist stripping. Some of these chamber types are straightforward to include in a plating system, while others may require special considerations with respect to segregation of chemicals and air handling. The configuration, or layout, of a wafer plating tool with multiple chamber types can be fairly complicated, especially if the process times can vary within a particular process chamber, as in parts with different plated thickness requirements. Multiple chambers can be used in parallel to accommodate longer processes. While more process chambers may be added to overcome bottlenecks in the process sequence, complex scheduling software is usually required to allow efficient use of all the chambers, especially when a mix of product types must be accommodated. This scheduling software may also take into account delays between process steps, which may need to be minimized in order to minimize surface oxidation between steps and maintain product quality. These scheduling algorithms may be incorporated into equipment simulators that are used to predict the equipment throughput in order to configure the tools that will best meet the expected needs with respect to product mix and fab capacity requirements [52]. 24.8 525 SUMMARY A wide variety of plating machines have been invented and developed to serve specific needs for electroplating parts with increased productivity and better deposit properties and at a lower manufacturing cost. There is greater use of electronic REFERENCES 1. H. J. Hawkins, The Polishing and Plating of Metals, Lindsay Publishing, Ormond Beach, FL (1987). Originally published in 1902. 2. M. J. Moll and L. J. Durney, Electroplating Engineering Handbook, 4th ed., L. J. Durney, Ed., Van Nostrand Reinhold, New York, 1984, p. 606. 3. W. H. Jackson, A. K. Graham, and R. K. Asher, Electroplating Engineering Handbook, 4th ed., L. J. Durney, Ed., Van Nostrand Reinhold, New York, 1984, p. 573. 4. S. E. Craig, Jr. and R. E. Harr, Plating, 60, 617 (1973); 61, 1101 (1974). 5. M. R. Kalantary, S. A. Amadi, and D. R. Gabe, Electrochemical Engineering, Inst. Chern. Symp. Ser. No. 112, Hemisphere, New York, 1989, pp. 199–206. 6. J. A. Lochet, company publication on vibratory plating, Vanguard Research Assoc., San Diego, CA. 7. P. A. Schopfer, company publication on vibratory plating, MECO, Bradenton, FL. 8. H. Tilton, Electroplating Engineering Handbook, 4th ed., L. J. Durney, Ed., Van Nostrand Reinhold, New York, 1984, p. 559. 9. H. Nakahara, Printed Circuit Handbook, C. F. Coombs, Ed., McGraw-Hill, New York, 1995, Ch. 20. 10. The Making, Shaping and Treating of Steel, 10th ed., W. Lankford Ed., Association of Iron and Steel Engineers, Pittsburgh, PA, 1996. 11. R. Winand, Belgium Patent No. 879,696 (Feb. 15, 1980). 12. E. Morgan, Tin Plate and Modern Canmaking Technology, Pergamon, Oxford, 1985. 13. W. E. Hoare, E. S. Hedges, and B. T. K. Barry, The Technology of Tinplate, Edward Arnold, London, 1965. 14. T.A. Turner, Canmaking: The Technology of Metal Protection and Decoration, Springer, New York, 1998. 15. R. Winard, Oberfiache-Surf, 25 (11) (1984). 16. A. Weymeersch, R. Winand, and L. Renard, Plating Surf Finish., 68 (4), 56–59 (1981). 526 MANUFACTURING TOOLS 17. A. Weymeersch, R. Winand, and L. Renard, Plating Surf Finish., 68 (5), 70 (1981). 18. D. R. Turner, Prod. Finish., 66 (2) (1987). 19. D. R. Turner, Met. Finish., 76 (10), 19 (1978). 20. B. W. Niebel, A. B. Draper, and R. A. Wysk, Modern Manufacturing Process Engineering, McGraw-Hill, New York, 1989, p. 805. 21. R. Mackiewicz, Process/Industrial Instruments and Controls Handbook, 4th ed., McGraw-Hill, New York, 1993, Sec. 3.32. 22. M. Baab, Control Eng., 40 (4), 46 (1993). 23. A. Tvarusko, Plating, 58, 983 (1971). 24. R. C. Alkire and A. Tvarusko, J. Electrochem. Soc., 119, 340 (1972). 25. A. Tvarusko, J. Electrochem. Soc., 120, 87 (1973). 26. G. F. Bidmead, Trans. Inst. Metal Finish., 59, 129 (1981). 27. J. C. Norris, in Metal Finishing Guidebook, M. Murphy, Ed., Elsevier, Amsterdam, 1992, pp. 301–320. 28. J. W. Dini and H. R. Johnson, Plating Surf. Finish., 64 (8), 44 (1977). 29. D. A. Thompson and L. T. Romankiw, IBM Disk Storage Tech., 2, 3–5 (1980). 30. L. T. Romankiw and T. A. Palumbo, “Electrodep. Tech., Theory and Practice,” Electrochem. Soc. Proc., 17, 13 (1987). 31. H. V. Reynolds, Plating Surf. Finish., 82 (5), 80 (1995). 32. T. Ritzdorf, “Challenges and Opportunities for Electrochemical Processing in Microelectronics,” ECS Trans., 6 (8), 1 (2007). 33. M. Datta, “Electrochemical Processing Technologies in Chip Fabrication: Challenges and Opportunities,” Electrochim. Acta, 48, 2975–2985 (2003). 34. T. Ritzdorf, J. Klocke, B. Kim, B. Batz, R. Baskaran, D. Erickson, and E. Young, “Electrochemical Processing for Microelectronic Applications,” in Proceedings of the AIChE Annual Meeting, Symposium on Metallization Processes in Semiconductor Device Fabrication, American Institute of Chemical Engineers, San Francisco, 2003, Paper 192d. 35. T. Ritzdorf and D. Fulton, “Electrochemical Deposition Equipment,” in New Trends in Electrochemical Technology, Vol. 3, Microelectronic Packaging, M. Datta, T. Osaka, J.W. Schultze (Eds.), CRC, Boca Raton, FL, 2005, pp. 495–509. 36. J. Klocke, P. McHugh, G. Wilson, K. Ritari, M. Roberts, and T. Ritzdorf, “Overcoming Terminal Effects During Electrochemical Deposition of Copper Films for 300 mm Damascene Interconnect Applications,” in Proceedings of the Advanced Metallization Conference (AMC) 2002, B. M. Melnick, T. S. Cale, S. Zaima, and T. Ohta, Eds., Materials Research Society, Warrendale, PA, 2003, pp. 373–377. 37. S. Mehdizadeh, J. O. Dukovic, P. C. Andricacos, L. T. Romankiw, and H. Y. Cheh, “The Influence of Lithographic Patterning on 38. 39. 40. 41. 42. 43. 44. 45. 46. 47. 48. 49. 50. 51. 52. Current Distribution: A Model for Microfabrication by Electrodeposition,” J. ECS, 139 (1), 78–91 (1992). S. Mehdizadeh, J. Dukovic, P. C. Andricacos, L. T. Romankiw, and H. Y. Cheh, “The Influence of Lithographic Patterning on Current Distribution in Electrodeposition: Experimental Study and Mass-Transfer Effects,” J. ECS, 140 (12), 3497–3505 (1993). B. DeBecker and A. C. West, “Workpiece, Pattern, and Feature Scale Current Distributions,” J. Electrochem. Soc., 143, (2), 486–492 (1996). SEMI E15, Specifications for Tool Load Port, Semiconductor Equipment and Materials International, San Jose, CA, 2003. SEMI E19, Standard Mechanical Interface (SMIF), Semiconductor Equipment and Materials International, San Jose, CA, 2002. SEMI E64, Specification for 300mm Cart to SEMI E15.1 Docking Interface Port, Semiconductor Equipment and Materials International, San Jose, CA, 2000. SEMI S8, Safety Guidelines for Ergonomics Engineering of Semiconductor Manufacturing Equipment, Semiconductor Equipment and Materials International, San Jose, CA, 2003. SEMI S2, Environmental, Health, and Safety Guidelines for Semiconductor Manufacturing Equipment, Semiconductor Equipment and Materials International, San Jose, CA, 2003. Directive 98/37/EC of the European Parliament and of the Council of June 22, 1998, on the approximation of the laws of the Member States relating to machinery, available: http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri¼ CONSLEG:1998L0037:19980812:EN:PDF. I. Kadija, J. A. Abys, V. Chinchankar, and H. K. Straschil, Plating Surf Finish., 78 (7), 60 (1991). J. V. Powers and L. T. Romankiw,U.S. Patent 3,652,442, (1972). D. E. Rice, D. Sundstrum, M. F. McEachern, L. A. Klumb, and J. B. Talbot, J. Electrochem. Soc., 135, 2777 (1988). L. T. Romankiw, J. V. Powers, and R. Acosta, “Paddle Electroplating Tool—Early Development Studies and Evolution,” in Peaks in Plating, Semitool, Kalispell, MT, 2006. G. J. Wilson and P. R. McHugh, “Unsteady Numerical Simulation of the Mass Transfer within a Reciprocating Paddle Electroplating Cell,” J. Electrochem. Soc., 152, C356 (2005). P. R. McHugh, G. Wilson, D. Erickson, and D. Woodruff, “Design of a Multiple-Electrode Magnetic-Alloy Plating Cell Using Numerical Modeling,” ECS Trans. 16 (45), 283 (2009). T. L. Ritzdorf, G. J. Wilson, P. R. McHugh, D. J. Woodruff, K. M. Hanson, and D. Fulton, “Design and Modeling of Equipment used in Electrochemical Processes for Microelectronics,” IBM J. Res. Dev., 49 (1), 65–77 (Jan. 2005).