Capillary Flow Guided Assembly of Microbeads for Quasiperiodic

Transcription

Capillary Flow Guided Assembly of Microbeads for Quasiperiodic
National Science Foundation & Nebraska Center for Energy Science Research
Capillary Flow Guided Assembly of Microbeads for Quasiperiodic Stacking
Ziguang Chen1, Ming Zhang2, You Zhou3, Timothy Patten2, Gang-yu Liu2, and Li Tan1* (ltan4@unl.edu)
1Department
of Engineering Mechanics and Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE, 68588
2Department of Chemistry, University of California, Davis, CA, 95616 3Center for Biotechnology, University of Nebraska, Lincoln, NE, 68588
Quasiperiodic Features
Periodic tiling
Quasiperiodic tiling
Objectives
Develop a simple process to manufacture
rarely seen but powerful quasiperiodic stacking;
Understand the stacking mechanism;
Reveal properties resulting from a quasiperiodic stacking.
Hierarchical Stacking
Moiré feature-like optical contrast observed;
Fast Fourier Transformation show relative
o
rotations at 10, 20 and 30 , respectively.
Dynamic Growth
Confocal microscopy reveals detailed stacking.
(0.97, 1.00)D
(0.94, 0.97)D
(0.91, 0.94)D
(0.88, 0.91)D
(0.85, 0.88)D
(0.81, 0.85)D
Manufacturing Process
Sequential growth in real-time.
Dodecagonally packed features plotted
based on height;
Extensive hierarchy revealed.
Conclusions
Monolayer growth limited by buckling.
Experimental setup and sequenced growth of a
dual-layer stacking by regulating a capillary flow;
Quasiperiodic pattern forms due to the coexistence of viscous force and gravity.
Manufacturing defects get self-repaired.
Quasiperiodic stacking of microbeads
obtained without using any templates;
Dynamic stacking driven by gravity and
capillary flow induced viscous force;
Confocal microscopy and modeling suggest
extensive hierarchy in dodecagonal packed
structures.

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