Overview of Pyrolysis Experience in Canada
Transcription
Overview of Pyrolysis Experience in Canada
Overview of Pyrolysis Experience in Canada Fernando Preto CanmetENERGY Natural Resources Canada IEA Task 34, Espoo, Finland June, 2010 Industry/Government study has concluded that bioenergy and bioproduct opportunities are stronger economically and socially when integrated within the traditional industry’s operations rather than on a stand-alone basis. Pyrolysis (and gasification) generally ranked at the top of the bioenergy opportunities. 1 Companies with G/P Experience* Gasification Enerkem Norampac Nexterra Plasco Pyrolysis ABRI Tech Agritherm Alterna Dynamotive Ensyn Pyrovac RTI Titan *Listed alphabetically ABRI Tech Single Auger Fast Pyrolysis Modular Portable Units •Joint venture between Advanced Biorefinery Inc (Peter Fransham) and Forespect (Namure, Quebec) fabricators. •1 tpd portable “farm” & “research” units built: CanmetENERGY; Saskatchewan Research Council; AES BioEnergy, New Zealand; US Forest Service 5 tpd Mobile Pyrolysis Plant •50 tpd units built for Ontario and Iowa (commissioing not completed) 2 ABRI Tech 50 tpd Portable Unit (Iowa) Grinder / Drier Reactor Condenser 4 tpd 3 4 Agri-therm Units: 1 - 10 tpd unit used for R&D 1 - 10 tpd unit shipped to Mexico 1 - 10 tpd unit being built as mobile laboratory Maximizing Charcoal Yield Alterna Biochar, Prince George, BC 5 Alterna Biochar W Operated pilot “box” pyrolyzer ( = 5 – 10 min) Successfully produced briquettes Future efforts: Scale-up Char pellets Char gasification Other char uses Dynamotive Fluid bed fast pyrolysis “Biotherm” projects include a 15TPD Pilot Plant, a 130TPD Plant in West Lorne, and a 200TPD Plant in Guelph Orenda 6 7 8 9 10 Ensyn “Utilization” Initiatives: - Slow Diesel Testing (Manitoba Hydro) - Commercial Burner Development (BMA & CanmetENERGY) - Potential for District Heating CanmetENERGY Complex (3 MWth) 11 PyroVac Christian Roy, founder of PyroVac has since co-founded Vaperma Inc, and is co-inventor of Siftek™ polymer membrane technology. He is contemplating a return to the pyrolysis field including application of membranes to separate water from light soluble organics 12 RTI – Resource Transforms Int. Ltd Principal Contact: Jan Piskorz R&D and Consulting Optimize pyrolysis (WFPP) for maximum liquid yields Pathways for selective formation of market-oriented specific chemicals: glycoaldehyde, hydroxyacetaldehyde “Bio-char mixes” Titan Clean Energy (SK) Organic Power (BC) Slow Pyrolysis for Biochar… 13 Government & Academia Agriculture and Agri-Food Canada CanmetENERGY (Natural Resources Canada) National Research Council Saskatchewan Research Council Ecole Polytechnique de Montréal University of Toronto University of Western Ontario University of British Columbia and University of Saskatchewan [Gasification of Bio-oil] Principal Contact: Carlos M. Monreal Agriculture and Agri-Food Canada 14 15 16 CanmetENERGY (Natural Resources Canada) Principal Contacts: Fernando Preto (Research Side) Ed Hogan (Program Side) Nozzle and Burner Development Pyrolysis Process Development 20 kg Batch Pyrolysis Unit Catalytic Conversion and Emulsification Financial and Technical Support for Industry Pyrolysis Process Development Feedstock and Product Characterization 17 CanmetENERGY Bio-Oil Nozzle: External mix air assist atomiser. Fuel is injected through a central pipe with a slight contraction at the tip allowing for a slight pressure build-up to aid atomisation – Firing into tunnel furnace ~100 kg/h Tote #1 Comb Air T = 46 C Tote #1 Comb Air T = 117 C Tote #2 - Plugged Tote #2 –Modified Nozzle 18 19 Saskatchewan Research Council: Installing ABRI Tech 1 tpd Unit Principal Contact: Darren Anweiler Focus on Ag residues: Wheat & Flax Straw, Poultry Litter Ecole Polytechnique de Montréal Principal Contact: Jamal Chaouki Microwave Pyrolysis of biomass and wastes Problems associated with chloride Focus on “fluff” due to problems associated with chloride and high metals content 6 PhD and 2 post-docs 20 University of Toronto Principal Contact: Murray Thompson Burner development (Swirl & Atomization) Combustion of 80/20 bio-oil/ethanol mixtures CFD Combustion model Bio-oil upgrading 4 Grad students + 2 in Fall 10 kW Burner University of Western Ontario Principal Contact: Franco Berrutti 5 pyrolysis pilot plants ( 1-2 kg/h) Valorization of different feedstocks Primary “cheap” upgrading Co-processing with fossil fuels Catalytic pyrolysis Gasification of pyrolysis oils >10 students and pdfs Principals in Agri-Therm Research Instutute: ICFAR 21 Thank You! Fernando Preto preto@nrcan.gc.ca Tel: +1-613-996-5589 http://canmetenergy.nrcan.gc.ca/ 22
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