Overview of Pyrolysis Experience in Canada

Transcription

Overview of Pyrolysis Experience in Canada
Overview of Pyrolysis Experience in
Canada
Fernando Preto
CanmetENERGY
Natural Resources Canada
IEA Task 34, Espoo, Finland
June, 2010
Industry/Government study has concluded that bioenergy and bioproduct opportunities are stronger economically and socially when
integrated within the traditional industry’s operations rather than
on a stand-alone basis. Pyrolysis (and gasification) generally
ranked at the top of the bioenergy opportunities.
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Companies with G/P Experience*
ƒ Gasification
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Enerkem
Norampac
Nexterra
Plasco
ƒ Pyrolysis
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ABRI Tech
Agritherm
Alterna
Dynamotive
Ensyn
Pyrovac
RTI
Titan
*Listed alphabetically
ABRI Tech
Single Auger Fast Pyrolysis
Modular Portable Units
•Joint venture between
Advanced Biorefinery Inc
(Peter Fransham) and
Forespect (Namure,
Quebec) fabricators.
•1 tpd portable “farm” &
“research” units built:
CanmetENERGY;
Saskatchewan Research
Council; AES BioEnergy,
New Zealand; US Forest
Service
5 tpd Mobile Pyrolysis Plant
•50 tpd units built for
Ontario and Iowa
(commissioing not
completed)
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ABRI Tech
50 tpd Portable Unit (Iowa)
Grinder / Drier
Reactor
Condenser
4 tpd
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Agri-therm Units:
1 - 10 tpd unit used for R&D
1 - 10 tpd unit shipped to Mexico
1 - 10 tpd unit being built as mobile laboratory
Maximizing Charcoal Yield
Alterna Biochar, Prince George, BC
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Alterna Biochar
W
ƒ Operated pilot “box” pyrolyzer ( = 5 – 10 min)
ƒ Successfully produced briquettes
ƒ Future efforts:
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Scale-up
Char pellets
Char gasification
Other char uses
Dynamotive
Fluid bed fast pyrolysis
“Biotherm” projects
include a 15TPD Pilot
Plant, a 130TPD Plant in
West Lorne, and a
200TPD Plant in Guelph
Orenda
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Ensyn “Utilization” Initiatives:
- Slow Diesel Testing (Manitoba Hydro)
- Commercial Burner Development (BMA & CanmetENERGY)
- Potential for District Heating CanmetENERGY Complex (3 MWth)
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PyroVac
Christian Roy, founder of PyroVac has since co-founded
Vaperma Inc, and is co-inventor of Siftek™ polymer membrane
technology. He is contemplating a return to the pyrolysis field
including application of membranes to separate water from
light soluble organics
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RTI – Resource Transforms Int. Ltd
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Principal Contact: Jan Piskorz
R&D and Consulting
Optimize pyrolysis (WFPP) for maximum liquid yields
Pathways for selective formation of market-oriented
specific chemicals: glycoaldehyde,
hydroxyacetaldehyde
ƒ “Bio-char mixes”
Titan Clean Energy (SK)
Organic Power (BC)
Slow Pyrolysis for Biochar…
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Government & Academia
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Agriculture and Agri-Food Canada
CanmetENERGY (Natural Resources Canada)
National Research Council
Saskatchewan Research Council
ƒ Ecole Polytechnique de Montréal
ƒ University of Toronto
ƒ University of Western Ontario
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University of British Columbia and University of Saskatchewan
[Gasification of Bio-oil]
Principal Contact: Carlos M. Monreal
Agriculture and Agri-Food Canada
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CanmetENERGY (Natural Resources Canada)
ƒ Principal Contacts:
ƒ Fernando Preto (Research Side)
ƒ Ed Hogan (Program Side)
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Nozzle and Burner Development
Pyrolysis Process Development
20 kg Batch Pyrolysis Unit
Catalytic Conversion and Emulsification
Financial and Technical Support for Industry
ƒ Pyrolysis Process Development
ƒ Feedstock and Product Characterization
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CanmetENERGY Bio-Oil Nozzle: External mix air assist atomiser. Fuel is injected
through a central pipe with a slight contraction at the tip allowing for a slight
pressure build-up to aid atomisation – Firing into tunnel furnace ~100 kg/h
Tote #1 Comb Air T = 46 C
Tote #1 Comb Air T = 117 C
Tote #2 - Plugged
Tote #2 –Modified Nozzle
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Saskatchewan Research Council:
Installing ABRI Tech 1 tpd Unit
Principal Contact: Darren Anweiler
Focus on Ag residues: Wheat & Flax Straw, Poultry Litter
Ecole Polytechnique de Montréal
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Principal Contact: Jamal Chaouki
Microwave Pyrolysis of biomass and wastes
Problems associated with chloride
Focus on “fluff” due to problems associated with
chloride and high metals content
ƒ 6 PhD and 2 post-docs
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University of Toronto
ƒ Principal Contact:
Murray Thompson
ƒ Burner development (Swirl &
Atomization)
ƒ Combustion of 80/20
bio-oil/ethanol mixtures
ƒ CFD Combustion model
ƒ Bio-oil upgrading
ƒ 4 Grad students + 2 in Fall
10 kW Burner
University of Western Ontario
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Principal Contact: Franco Berrutti
5 pyrolysis pilot plants ( 1-2 kg/h)
Valorization of different feedstocks
Primary “cheap” upgrading
Co-processing with fossil fuels
Catalytic pyrolysis
Gasification of pyrolysis oils
>10 students and pdfs
Principals in Agri-Therm
Research Instutute: ICFAR
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Thank You!
Fernando Preto
preto@nrcan.gc.ca
Tel: +1-613-996-5589
http://canmetenergy.nrcan.gc.ca/
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