Safety Data Sheet

Transcription

Safety Data Sheet

according to Regulation (EC) No. 1907/2006
(amended by Regulation (EU) 2015/830)
SAFETY DATA SHEET
Collano RS 8500 component A
1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product code
None.
Synonyms
None.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture
High quality, elastic 2 compound adhesive
1.3. Details of the supplier of the safety data sheet
Company/Undertaking Identification
Collano Adhesives AG
Eichenstrasse 12
CH-6203 Sempach Station
Tel. +41 41 469 92 75
Fax +41 41 469 91 12
www.collano.com
sdb@collano.com
1.4. Emergency telephone number
+41 41 469 92 75 (Mo - Fr 8:00 - 17:00 MEZ/CET)
(+41 44 251 51 51 Tox Center)
Issuing date
11.07.2016
Version
4 (Previous versions: 3)
2. Hazards identification
2.1. Classification of the substance or mixture
Classification according to
Regulation (EC) No. 1272/2008
Serious eye damage/eye irritation, Cat. 2, H319
Skin Sensitisation, Cat. 1, H317
The product is classified and labelled according to Regulation (EC) No. 1272/2008.
Additional information
For the full text of the phrases mentioned in this Section, see
Section 16.
2.2. Label elements
X
Signal Word
Warning
Collano RS 8500 component A+B
Version 4
Print Date 04.08.2016
1 / 15
Hazard Statements
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
Precautionary statements
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264: Wash skin thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of
the workplace.
P280: Wear protective gloves/ protective clothing/ eye protection/
face protection.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P333 + P313: If skin irritation or rash occurs: Get medical advice/
attention.
P337 + P313: If eye irritation persists: Get medical advice/
attention.
P362 + P364: Take off contaminated clothing and wash it before
reuse.
P501: Dispose of contents/ container to an approved waste
disposal plant.
Supplemental information
None.
Product identifier
2,4,6-Tris(dimethylaminomethyl)phenol, CAS-No. 90-72-2, EC-No.
202-013-9
2.3. Other hazards
No information available.
3. Composition/information on ingredients
Chemical characterization
Silanized poly ether.
Components
CLP Classification
Product identifier
Trimethoxyvinylsilan
< 2%
Acute Tox. 4 H332, Flam. Liq. 3
H226
2,4,6-Tris(dimethylaminomethyl)phenol
< 5%
Acute Tox. 4 H302, Eye Irrit. 2
H319, Skin Irrit. 2 H315
CAS-No.: 2768-02-7
EC-No.: 220-449-8
CAS-No.: 90-72-2
EC-No.: 202-013-9
Index-No: 603-069-00-0
1,8-Diazabicyclo[5.4.0]undec-7-en
< 1%
Acute Tox. 3 H301, Skin Corr. 1B
H314, Aquatic Chronic 3 H412,
Met. Corr. 1 H290
CAS-No.: 6674-22-2
EC-No.: 229-713-7
For the full text of the phrases mentioned in this Section, see Section 16.
Hazardous impurities
None known.
4. First aid measures
4.1. Description of first aid measures
Inhalation
Move to fresh air in case of accidental inhalation of vapours or
decomposition products.
Skin contact
Wash off with soap and plenty of water.
Eye contact
If easy to do, remove contact lens, if worn. Keep eye wide open while
rinsing. If eye irritation persists, consult a specialist.
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Ingestion
Do not induce vomiting. Never give anything by mouth to an unconscious
person. Consult a physician for severe cases.
4.2. Most important symptoms and
effects, both acute and delayed
None known.
4.3. Indication of any immediate
medical attention and special
treatment needed
None known.
5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray. Foam. Dry powder. Dry sand. Carbon dioxide (CO2).
Extinguishing media which must not
be used for safety reasons
None.
5.2. Special hazards arising from the
substance or mixture
None.
5.3. Advice for firefighters
Special protective equipment for
firefighters
Not required.
Specific methods
No special measures required.
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
Advice for emergency responders
Handle in accordance with good industrial hygiene and safety practice.
6.2. Environmental precautions
No special environmental precautions required. Do not flush into surface
water or sanitary sewer system.
6.3. Methods and material for
containment and cleaning up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder,
universal binder, sawdust).
7. Handling and storage
7.1. Precautions for safe handling
No special handling advice required.
7.2. Conditions for safe storage,
including any incompatibilities
Do not freeze.
7.3. Specific end use(s)
8. Exposure controls/personal protection
8.1. Control parameters
Exposure limit(s)
No data is available on the product itself.
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8.2. Exposure controls
Occupational exposure controls
Avoid contact with skin. General industrial hygiene practice. When using do
not eat or drink.
Personal protection equipment
Respiratory protection
In case of good ventilation no personal respiratory protective equipment
required.
Hand protection
Impervious gloves. Butylrubber. Nitrile rubber. Natural rubber. Pay attention
to the indications of the gloves producers on penetration and breakthrough
time.
Eye protection
Avoid contact with eyes. Safety glasses with side-shields.
Skin and body protection
Thermal hazards
Environmental exposure controls
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Form
Colour
Odour
Odour Threshold
pH:
Melting point/range:
Boiling point/range:
Flash point:
Strongly viscous. Paste.
White.
Amine-like.
not applicable
No data available.
~86°C
Evaporation Rate:
Flammability:
Explosion limits:
Vapour pressure:
Vapor density:
Relative density:
Water solubility:
Partition coefficient (noctanol/water):
Autoignition temperature:
Decomposition temperature:
Viscosity:
Combustion/explosion hazards:
Oxidizing properties:
~1.1 g/ml
insoluble
Not applicable.
Strongly viscous.
not hazardous
None
9.2. Other information
10. Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
No decomposition if stored and applied as directed.
10.3. Possibility of hazardous
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reactions
10.4. Conditions to avoid
Not required.
10.5. Incompatible materials
None.
10.6. Hazardous decomposition
products
None reasonably foreseeable.
11. Toxicological information
11.1. Information on toxicological effects
Acute toxicity
Trimethoxyvinylsilan (CAS 2768-02-7)
Oral LD50 Rat = 7340 µL/kg (NLM_CIP)
2,4,6-Tris(dimethylaminomethyl)phenol (CAS 90-72-2)
Dermal LD50 Rat = 1280 mg/kg (NLM_CIP)
Oral LD50 Rat = 1200 mg/kg (NLM_CIP)
Skin corrosion/irritation
No data available.
Serious eye damage/eye irritation
No data available.
Respiratory / Skin Sensitisation
No data available.
Carcinogenicity
No data available.
Germ cell mutagenicity
No data available.
Reproductive toxicity
No data available.
Specific target organ toxicity (single
exposure)
No data available.
Specific target organ toxicity
(repeated exposure)
No data available.
Aspiration hazard
No data available.
Human experience
No data available.
12. Ecological information
12.1. Toxicity
Ecological injuries are not known or expected under normal use.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB
assessment
12.6. Other adverse effects
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13. Disposal considerations
13.1. Waste treatment methods
Waste from residues / unused
products
In accordance with local and national regulations. Should not be released
into the environment. According to the European Waste Catalogue, Waste
Codes are not product specific, but application specific.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste
disposal.
14. Transport information
ADR/RID
Not required.
IMDG
Not required.
IATA
Not required.
Further Information
Not classified as dangerous in the meaning of transport regulations.
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulatory Information
The product is classified and labelled according to Regulation (EC) No.
1272/2008.
class of danger according to VbF lll.
Water contaminating class (WGK Germany) = 1.
Merkblatt BG Chemie:
M004 Reizende Stoffe/Ätzende Stoffe
Trimethoxyvinylsilan (CAS 2768-02-7)
EU - REACH (1907/2006) - List of
Present
Registered Substances
Germany - Water Classification
ID Number 1769, hazard class 1 - low hazard to waters
(VwVwS) - Annex 2 - Water Hazard
Classes
2,4,6-Tris(dimethylaminomethyl)phenol (CAS 90-72-2)
Present
ID Number 6702, hazard class 1 - low hazard to waters (footnote 46)
Classes
1,8-Diazabicyclo[5.4.0]undec-7-en (CAS 6674-22-2)
Present
15.2. Chemical safety assessment
Not required.
16. Other information
Revision Note
Safety datasheet sections which have been updated: 1,2,3,9,15,16.
Key or legend to abbreviations and
acronyms
CLP: Classification according to Regulation (EC) No. 1272/2008 (GHS)
Full text of phrases referred to under
sections 2 and 3
H226: Flammable liquid and vapour.
H290: May be corrosive to metals.
H301: Toxic if swallowed.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
Version 4
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H315: Causes skin irritation.
H332: Harmful if inhaled.
H412: Harmful to aquatic life with long lasting effects.
Instructions for use
Restricted to professional users.
Disclaimer
It is not to be considered a warranty or quality specification. The
information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The
information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be
considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless
specified in the text.
Version 4
7 / 15
according to Regulation (EC) No. 1907/2006
(amended by Regulation (EU) 2015/830)
SAFETY DATA SHEET
Collano RS 8500 component B
1. Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Product code
None.
Synonyms
None.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the Substance/Mixture
Hardener, industrial adhesive
1.3. Details of the supplier of the safety data sheet
Company/Undertaking Identification
Collano Adhesives AG
Eichenstrasse 12
CH-6203 Sempach Station
Tel. +41 41 469 92 75
Fax +41 41 469 91 12
www.collano.com
sdb@collano.com
1.4. Emergency telephone number
+41 41 469 92 75 (Mo - Fr 8:00 - 17:00 MEZ/CET)
(+41 44 251 51 51 Tox Center)
Issuing date
11.07.2016
Version
4 (Previous versions: 3)
2. Hazards identification
2.1. Classification of the substance or mixture
Classification according to
Regulation (EC) No. 1272/2008
Skin corrosion/irritation, Cat. 2, H315
Serious eye damage/eye irritation, Cat. 2, H319
Skin Sensitisation, Cat. 1, H317
Hazardous to the aquatic environment, chronic, Cat. 2, H411
The product is classified and labelled according to Regulation (EC) No. 1272/2008.
Additional information
For the full text of the phrases mentioned in this Section, see
Section 16.
2.2. Label elements
X
Signal Word
Warning
Version 4
8 / 15
Hazard Statements
H411: Toxic to aquatic life with long lasting effects.
Precautionary statements
P261: Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.
P264: Wash skin thoroughly after handling.
P272: Contaminated work clothing should not be allowed out of
the workplace.
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/
face protection.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for
several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P333 + P313: If skin irritation or rash occurs: Get medical advice/
attention.
P362 + P364: Take off contaminated clothing and wash it before
reuse.
P501: Dispose of contents/ container to an approved waste
disposal plant.
Supplemental information
Contains epoxy constituents. May produce an allergic reaction.
Product identifier
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin
(number average molecular weight ≤ 700), CAS-No. 25068-38-6,
EC-No. 500-033-5
p-tert.-Butylphenylglycidether, CAS-No. 3101-60-8, EC-No. 221453-2
Trimethylolpropane triglycidyl ether, CAS-No. 30499-70-8
2.3. Other hazards
3. Composition/information on ingredients
Chemical characterization
Epoxi resins
Components
CLP Classification
reaction product: bisphenol-A(epichlorhydrin) epoxy resin (number
average molecular weight ≤ 700)
< 75%
p-tert.-Butylphenylglycidether
< 25%
Trimethylolpropane triglycidyl ether
< 0.5%
Eye Irrit. 2 H319, Skin Irrit. 2
H315, Skin Sens. 1 H317, Aquatic
Chronic 2 H411
[CEy2: C ≥ 5 % ¦ CSk2: C ≥ 5 %]
Eye Irrit. 2 H319, Skin Irrit. 2
H315, Skin Sens. 1 H317, Aquatic
Chronic 2 H411
Skin Irrit. 2 H315, Skin Sens. 1
H317, Eye Irrit. 2 H319, Aquatic
Chronic 3 H412
Product identifier
CAS-No.: 25068-38-6
EC-No.: 500-033-5
Index-No: 603-074-00-8
CAS-No.: 3101-60-8
EC-No.: 221-453-2
CAS-No.: 30499-70-8
For the full text of the phrases mentioned in this Section, see Section 16.
Hazardous impurities
None known.
Version 4
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4. First aid measures
4.1. Description of first aid measures
Inhalation
Move to fresh air in case of accidental inhalation of vapours or
decomposition products. In the case of inhalation of aerosol/mist consult a
physician if necessary.
Skin contact
Wash off with soap and plenty of water. If skin irritation persists, call a
physician.
Eye contact
If easy to do, remove contact lens, if worn. Keep eye wide open while
rinsing. If eye irritation persists, consult a specialist.
Ingestion
Immediately give plenty of water (if possible charcoal slurry). Do not induce
vomiting. Consult a physician for severe cases. If a person vomits when
lying on his back, place him in the recovery position.
4.2. Most important symptoms and
effects, both acute and delayed
None known.
4.3. Indication of any immediate
medical attention and special
treatment needed
None known.
5. Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media
Water spray. Foam. Dry powder. Carbon dioxide (CO2).
Extinguishing media which must not
be used for safety reasons
High volume water jet.
5.2. Special hazards arising from the
substance or mixture
Fire may cause COx to evolve. In the event of fire the following can be
released: irritant and toxic fumes.
5.3. Advice for firefighters
Special protective equipment for
firefighters
In the event of fire, wear self-contained breathing apparatus. Complete suit
protecting against chemicals.
Specific methods
6. Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Advice for non-emergency personnel
Advice for emergency responders
6.2. Environmental precautions
Prevent product from entering drains. Do not contaminate surface water.
Avoid subsoil penetration.
6.3. Methods and material for
containment and cleaning up
Use mechanical handling equipment. Soak up with inert absorbent material
and dispose of as hazardous waste.
Version 4
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7. Handling and storage
7.1. Precautions for safe handling
Provide sufficient air exchange and/or exhaust in work rooms. Handle and
open container with care. Keep away from heat and sources of ignition.
7.2. Conditions for safe storage,
including any incompatibilities
Do not store together with . Keep at temperatures between 10 and 40 °C.
Keep container tightly closed.
7.3. Specific end use(s)
8. Exposure controls/personal protection
8.1. Control parameters
Exposure limit(s)
8.2. Exposure controls
Occupational exposure controls
Avoid contact with skin, eyes and clothing. Do not smoke. Ensure adequate
ventilation, especially in confined areas.
Personal protection equipment
Respiratory protection
In case of good ventilation no personal respiratory protective equipment
required.
Hand protection
Impervious gloves. Butylrubber. Nitrile rubber. Natural rubber. Pay attention
to the indications of the gloves producers on penetration and breakthrough
time.
Eye protection
Avoid contact with eyes. Safety glasses with side-shields.
Skin and body protection
Lightweight protective clothing.
Thermal hazards
Environmental exposure controls
9. Physical and chemical properties
9.1. Information on basic physical and chemical properties
Form
Colour
Odour
Odour Threshold
pH:
Melting point/range:
Boiling point/range:
Flash point:
Strongly viscous. Paste.
Dark grey.
Characteristic.
not applicable
No data available.
~200°C
Evaporation Rate:
Flammability:
Explosion limits:
Vapour pressure:
Vapor density:
Relative density:
Water solubility:
~1.04 g/ml
reacts with water
Version 4
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Partition coefficient (noctanol/water):
Autoignition temperature:
Decomposition temperature:
Viscosity:
Combustion/explosion hazards:
Oxidizing properties:
Not applicable.
<100°C
10'000 mPas
not hazardous
None
9.2. Other information
General Product Characteristics
Total solids content 100 Weight %
10. Stability and reactivity
10.1. Reactivity
10.2. Chemical stability
No decomposition if stored and applied as directed.
10.3. Possibility of hazardous
reactions
10.4. Conditions to avoid
Burning produces obnoxious and toxic fumes.
10.5. Incompatible materials
Strong acids and strong bases. Strong oxidizing agents.
10.6. Hazardous decomposition
products
Carbon oxides.
11. Toxicological information
11.1. Information on toxicological effects
Acute toxicity
No data is available on the product itself. LD50/oral/rat >= 2000 mg/kg.
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number
average molecular weight ≤ 700) (CAS 25068-38-6)
Oral LD50 Rat = 11400 mg/kg (NLM_CIP)
Skin corrosion/irritation
No data available.
Serious eye damage/eye irritation
No data available.
Respiratory / Skin Sensitisation
May cause sensitization of susceptible persons by skin contact.
Carcinogenicity
No data available.
Germ cell mutagenicity
No data available.
Reproductive toxicity
No data available.
Specific target organ toxicity (single
exposure)
No data available.
Specific target organ toxicity
(repeated exposure)
No data available.
Aspiration hazard
No data available.
Human experience
No data available.
Version 4
12 / 15
12. Ecological information
12.1. Toxicity
May cause long-term adverse effects in the aquatic environment.
12.2. Persistence and degradability
No data available.
12.3. Bioaccumulative potential
No data available.
12.4. Mobility in soil
No data available.
12.5. Results of PBT and vPvB
assessment
12.6. Other adverse effects
13. Disposal considerations
13.1. Waste treatment methods
Waste from residues / unused
products
Should not be released into the environment. Dispose of as special waste
in compliance with local and national regulations. According to the
European Waste Catalogue, Waste Codes are not product specific, but
application specific.
Contaminated packaging
Empty containers should be taken for local recycling, recovery or waste
disposal.
14. Transport information
ADR/RID
UN 3082.
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (reaction product: bisphenol-A-(epichlorhydrin) epoxy resin
(number average molecular weight ≤ 700)).
Class 9.
Packing group III.
ADR/RID-Labels 9+ENV.
Environmentally hazardous: Yes
Classification code M6.
Hazard identification no. 90.
Limited quantity 5 L.
Excepted quantity E1.
Tunnel restriction code E
IMDG
UN 3082.
Class 9.
Packing group III.
IMDG-Labels 9+ENV.
EmS F-A, S-F.
Marine pollutant: Yes.
Version 4
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IATA
UN 3082.
Proper shipping name: Environmentally hazardous substance, liquid, n.o.s.
(reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number
average molecular weight ≤ 700)).
Class 9.
Packing group III.
IATA label 9+ENV.
Packing instruction (passenger aircraft): 964 (450 L).
Packing instruction (LQ): Y964 (30 kg G).
Packing instruction (cargo aircraft): 964 (450 L).
Inland navigation ADN
UN 3082.
Class 9.
Packing group III.
ADN labels 9+ENV.
Classification code M6.
None.
Further Information
15. Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulatory Information
Contains epoxy constituents. See information supplied by the
manufacturer.
GISCODE (D): RE1
Water contaminating class (WGK Germany) = 2.
Merkblatt BG Chemie:
M004 Reizende Stoffe/Ätzende Stoffe
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ≤ 700) (CAS
25068-38-6)
EU - No-Longer Polymers List
NLP No. 500-033-5
(67/548/EEC)
Present
ID Number 2007, hazard class 2 - hazard to waters (molecular weight
<700, content of free epichlorohydrin <20 ppm, not classified as R40 or
Classes
R45)
p-tert.-Butylphenylglycidether (CAS 3101-60-8)
Present
Trimethylolpropane triglycidyl ether (CAS 30499-70-8)
Present
15.2. Chemical safety assessment
Not required.
16. Other information
Revision Note
Safety datasheet sections which have been updated: 1,2,3,16.
Key or legend to abbreviations and
acronyms
CLP: Classification according to Regulation (EC) No. 1272/2008 (GHS)
Full text of phrases referred to under
sections 2 and 3
H411: Toxic to aquatic life with long lasting effects.
H412: Harmful to aquatic life with long lasting effects.
Version 4
14 / 15
Instructions for use
Restricted to professional users.
Disclaimer
It is not to be considered a warranty or quality specification. The
information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The
information given is designed only as a guidance for safe handling, use,
processing, storage, transportation, disposal and release and is not to be
considered a warranty or quality specification. The information relates only
to the specific material designated and may not be valid for such material
used in combination with any other materials or in any process, unless
specified in the text.
Version 4
15 / 15

Safety Data Sheet

Transcription

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