SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION COMMON NAME:

ABS Pipe and Fittings
Date updated: 1/14/14
SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION
COMMON NAME:
ABS Pipe and Fittings
CHEMICAL NAME:
Not Applicable. Formulation, see section 3.
FORMULA:
Mixture
PRODUCT CAS NO.:
Mixture, see section 3.
Recommended Use:
Drain Waste and Vent Pipe and Fittings
SUPPLIER:
Charlotte Pipe and Foundry Company (Plastics Division)
ADDRESS:
4210 Old Charlotte Highway
CITY, STATE, ZIP:
Monroe, NC 28110
PHONE:
+1-704-372-3650
EMERGENCY PHONE: +1-704-372-3650
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic and irritating gases and fumes may be given off during burning or thermal decomposition. Avoid generating
dust. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential
dust explosion hazard.
GHS Status
This material is hazardous in accordance with the hazard communication standard, 29 CFR
1910.1200
Classification of the
substance or mixture
Skin irritation – Category 2
GHS label pictogram
Signal word
Hazard statements
Eye irritation – Category 2 B
Carcinogenicity – Category 2
Health hazard.
Warning
Causes eye irritation.
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SAFETY DATA SHEET
Causes skin irritation.
Suspected of causing cancer if inhaled.
Precautionary statements
Prevention
Response
Storage
Disposal
Hazards not otherwise
classified
Relevant routes of
exposure
Inhalation
Skin contact
Eye contact
Ingestion
Obtain special instructions before use. Do not handle until all safety precautions have been
read and understood. Wear protective breathing gear, such as an N95 or P95 respirator.
Wash skin thoroughly after handling.
If on skin: wash with plenty of water. If in eyes. Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention. Take off contaminated clothing and wash before
reuse.
Keep away from intense heat, flames. Store locked up.
Dispose of in accordance with local regulations.
None known.
Skin, eyes, inhalation.
Melted product is flammable and produces intense heat and dense smoke during
burning. Irritating gases and fumes may be given off during burning or thermal
decomposition.
May cause allergic reaction.
No data available.
No data available.
3. HAZARDOUS INGREDIENTS: COMPOSITION/INFORMATION
INGREDIENT
%
WEIGHT
NIOSH REL
PEL-OSHA
TLV-ACGIH
95 - 100
None established for ABS
Particulates not otherwise
classified: 15 mg/m3
None established
Corn oil
CAS 8001-30-7
0-3
Carbon black
CAS 1333-86-4
0-2
Vegetable oil:
5 mg/m3 (PEL, respirable
fraction)
15 mg/m3 (PEL, total
dust)
3.5 mg/m3 (TWA)
None
Established for
ABS
Particulates not
otherwise
classified: 10
mg/m3 (inhalable
fraction)
10 mg/m3 (8hour TWA)
3.0 mg/m3
(TWA)
3.5 mg/m3 (TWA)
Acrylonitrile Butadiene Styrene
CAS 9003-56-9
Vegetable oil mist:
10 mg/m3 (total
TWA)
4. FIRST AID MEASURES
EYE CONTACT: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes.
SKIN CONTACT: Rinse with water. Remove contaminated clothing and shoes. In the event of any complaints or symptoms,
avoid further exposure. Wash clothing before reuse. Clean shoes before reuse.
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INHALATION: If vapors from excessive heating, burning or decomposition products are inhaled: remove victim to fresh air and
keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular, or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-tomouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing, such as collar, tie, belt, or waistband. In case of inhalation of decomposition
products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance.
INGESTION: Wash out mouth with water. Remove dentures, if any. Remove victim to fresh air and keep at rest in a position
comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water
to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so
by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical
attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical
attention immediately. Loosen tight clothing, such as collar, tie, belt, or waistband.
Notes to physician: In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under surveillance for 48 hours
Specific treatments: None known
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: 388-400°C (730-752°F)
FLAMMABLE LIMITS:
Decomposition products may be combustible.
LEL: No Data
UEL: No data
EXTINGUISHING MEDIA: Use media appropriate for surrounding fire.
FIRE AND EXPLOSION HAZARDS: Thermal decomposition may produce carbon dioxide, carbon monoxide, nitrogen
oxides, sulfur oxides, halogenated compounds, and metal oxide/oxides.
PROTECTIVE MEASURES FOR FIRE FIGHTERS: Firefighters must wear a NIOSH-approved, full-face piece self-contained
breathing apparatus (SCBA) operated in positive pressure mode and full turnout or bunker gear with additional chemical
protective clothing as necessary to protect against thermal decomposition products.
SPECIAL PROTECTIVE ACTIONS FOR FIRE FIGHTERS: If there is a fire, promptly isolate the scene by removing all
persons from the vicinity of the incident. No action shall be taken involving any personal risk or without suitable training.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment, and emergency measures
For non-emergency personnel
No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel
from entering. Do not touch or walk through spilled material. Provide adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Put on
appropriate personal protective equipment.
For emergency responders
If specialized clothing is required to deal with decomposition products or fumes
from burning or excessive heating, take note of information in Section 8 on
suitable and unsuitable materials. See also information in “for non-emergency
personnel.”
Environmental precautions
Avoid dispersal of spilled material and runoff and contact with soil, waterways,
drains, and sewers. Inform the relevant authorities if the product has caused
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environmental pollution (sewers, waterways, soil, or air).
Methods and materials for containment and clean-up
Small spill
Avoid dust generation. Vacuum dust with equipment fitted with a HEPA filter
and place in a closed, labeled waste container. See Section 1 for emergency
contact information.
Large spill
Move containers from spill area. Approach release from upwind. Prevent entry
into sewers, waterways, basements, and confined areas. Avoid dust
generation. Vacuum dust with equipment fitted with a HEPA filter and place in a
closed, labeled waste container. See Section 1 for emergency contact
information.
7. HANDLING AND STORAGE
Conditions for safe storage, including
any incompatibilities
Precautions for safe handling
Protective measures
Advice on general occupational
hygiene
Store in a dry place away from direct sunlight, heat, and incompatible
materials. Avoid intense heat and flames.
Put on appropriate personal protective equipment (see Section 8). Do not
handle until all safety precautions have been read and understood. Do not get
particles, vapors or fumes in eyes, on skin, or on clothing. Do not ingest. If
during normal use, the material presents a respiratory hazard, use only with
adequate ventilation or wear appropriate respirator.
Employees must wash hands and face before eating, drinking, or smoking.
Remove contaminated clothing and protective equipment before entering eating
areas. See also section 8 for additional information on hygiene measures.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROLS: If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local
exhaust ventilation, or other engineering controls to keep worker exposure to airborne contaminants below recommended
and statutory limits.
RESPIRATORY PROTECTION: Cutting or sanding this product can generate dust. Used a properly fitted particulate filter
respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product, and the safe working limits of the respirator. A
NIOSH-approved N95 single use or P95 multiple use respirator will protect the employee from at least 95% of airborne
particles. Follow the respirator manufacture’s instructions for proper use. If adhesives or other substances are used with this
product, refer to the product manufacturer’s safety data sheet for applicable respiratory protective measures.
SKIN PROTECTION: Chemical-resistant, impervious gloves complying with an approved standard should be worn when
handling this or any chemical product, if a risk assessment indicates this is necessary. Considering the parameters specified
by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted
that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of
mixtures containing several substances, the protection time of the gloves cannot be accurately estimated. If adhesives or
other substances are used with this product, refer to the product manufacturer’s safety data sheet for applicable skin
protective measures.
BODY PROTECTION: Personal protective equipment for the body should be selected on the task being performed and the
risks involved, and should be approved by a specialist before handling this product. If adhesives or other substances are
used with this product, refer to the product manufacturer’s safety data sheet for applicable skin protective measures.
EYE/FACE PROTECTION: Safety eyewear complying with an approved standard must be used when a risk assessment
indicates this is necessary to avoid exposure to dust. Particulates and dust can be formed when cutting, grinding or sanding
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SAFETY DATA SHEET
this product. If contact with dust or particulates is possible, the following should be worn unless the assessment indicates a
higher degree of protection: safety glasses with side shields. If adhesives or other substances are used with this product,
refer to the product manufacturer’s safety data sheet for applicable eye and face protective measures.
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE:
Solid. Black.
ODOR:
Slight, sweet, aromatic.
ODOR THRESHOLD:
Not available
BOILING POINT:
Not available
FLASH POINT:
388-400°C (730-752°F)
FLAMMABILITY:
Melted product is flammable.
AUTOIGNITION TEMPERATURE:
495-510°C (923-950°F)
DECOMPOSITION TEMPERATURE:
Approximately 260°C (500°F)
LOWER/UPPER EXPLOSION LIMITS:
Not available
VAPOR PRESSURE:
Not available
LIQUID DENSITY:
Not available
SPECIFIC GRAVITY:
Approximately 1.05
MELTING POINT:
Not available
pH:
Not available
SOLUBILITY:
Insoluble
% VOLATILE:
Not available
VISCOSITY:
Not available
10. STABILITY AND REACTIVITY
Stability:
Stable at normal temperatures and pressures.
Reactivity:
Stable at normal temperatures and pressures.
Conditions to avoid:
Heat, flames, sparks and other sources of ignition.
Incompatible materials/conditions:
Consult the Charlotte Pipe and Foundry chemical resistance guide.
Hazardous decomposition products:
Hydrogen chloride, carbon oxides, small amounts of benzene and aromatic and
aliphatic hydrocarbons, phosgene.
Not available.
Hazardous polymerization:
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY:
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No toxicological data is available for the finished product.
SENSITIZATION: No data available.
MUTAGENICITY: No data available.
DEVELEPMENTAL: No data available.
Fertility: No data available.
CARCINOGENICITY: This product contains Carbon Black, which is classified by the International Agency for Research on
Cancer as 2B: possibly carcinogenic to humans. Not listed on the National Toxicology Program Report on Carcinogens or
OSHA Subpart Z.
REPRODUCTIVE TOXICITY: Not available
TERATOGENICITY: Not available
SPECIFIC TARGET ORGANS – SINGLE EXPOSURE: Not available
SPECIFIC TARGET ORGANS – REPEATED EXPOSURE: Not available
ASPIRATION HAZARD: Not available
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
Potential acute health effects
Eye contact
Inhalation
Skin contact
Ingestion
No known significant effects or critical hazards. Dust can cause eye irritation.
Exposure to decomposition products may cause a health hazard. Serious effects
may be delayed following exposure.
Skin irritant.
No known significant effects or critical hazards.
Symptoms related to the physical, chemical, and toxicological characteristics
Eye contact
No data available.
Inhalation
No data available
Skin contact
Adverse symptoms may include irritation.
Ingestion
No data available
Immediate, delayed and chronic effects from short term exposure
Short term exposure
Potential immediate effects
Potential delayed effects
No data available.
No data available
Long term exposure
Potential immediate effects
Potential delayed effects
No data available.
No data available
Potential chronic effects
General
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No data available.
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SAFETY DATA SHEET
Carcinogenicity
May cause cancer. Risk of cancer depends on duration and level of exposure.
12. ECOLOGICAL INFORMATION
Numerical measures of toxicity
No data available
Persistence and degradability
Does not biodegrade over time.
Bioaccumulative potential
No data available
Mobility in soil
No data available.
Other adverse effects: No known significant or critical hazards.
13. DISPOSAL CONSIDERATIONS
The generation of waste should be avoided or minimized wherever possible. Disposal of this product, and by-products should
at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local
authority requirements. Waste should not be disposed of to the sewer unless fully compliant with the requirements of all
authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when
recycling is not feasible. This material must be disposed of in a safe way.
14. TRANSPORT INFORMATION
PROPER SHIPPING NAME:
Not Regulated
HAZARD CLASS:
Not Regulated
IDENTIFICATION NUMBER:
Not Regulated
SHIPPING LABEL:
Not Regulated
PACKING GROUP:
Not Regulated
United States
15. REGULATORY INFORMATION
TSCA 8(b):
All ingredients are listed on the U.S. Toxic Substances Control Act
inventory.
Airborne unbound particles of carbon black of respirable size are listed as
being carcinogenic per California Proposition 65.
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SAFETY DATA SHEET
16. OTHER INFORMATION
Date of Preparation:
6 December 2013
Key To Acronyms:
CAS:
CFR:
HEPA
IARC:
LD50
LC50
LEL:
mg/l
NIOSH:
NTP:
OSHA:
PEL:
TSCA
TLV:
TWA:
UEL:
3
ug/ m
Chemical Abstracts Service
Code of Federal Regulations
High-Efficiency Particulate Air (filter)
International Agency for Research on Cancer
Lethal dose to 50% of exposed laboratory animals
Lethal concentration to 50% of exposed laboratory animals
Lower Explosive Limit
Milligrams per liter
National Institute for Occupational Safety and Health (US)
National Toxicology Program
Occupational Safety and Health Administration (US)
Permissible Exposure Limit
Toxic Substances Control Act
Threshold Limit Value – American Conference of Governmental Industrial Hygienists (ACGIH)
Time Weighted Average
Upper Explosive Limit
Micrograms per cubic meter
DISCLAIMER
NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR
WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESS OR IMPLIED, IS MADE REGARDING
PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE FOR THE ABS MATERIALS AS
REPRESENTED IN THIS MSDS SHEET. Charlotte Pipe and Foundry assumes no liability whatsoever for the
use of or reliance upon this information. The information and data contained in this MSDS has been compiled
from information believed to be accurate and is offered for your consideration, investigation and verification.
Buyer assumes all risk of use, storage, handling and disposal of the product in compliance with applicable
federal, state, and local laws and regulations.
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