R o y a
Transcription
R o y a
Royal-treatment – scientific background and practical application Presentation at COST E22 Conference in Reinbek, November 2001 A. Treu*, H. Militz* and S. Breyne** * University Göttingen, Institute of Wood Biology and Wood Technology ** Dr. Wolman GmbH I. Introduction The presented work was part of a project of the Institute of Wood Biology and Wood Technology (University Göttingen) in cooperation with Dr. WOLMAN Company Beginning: April 2001, Duration: 3 years Durability of our native wood species is limited and especially for most of our important economic timber it is moderate or bad. Pine wood (Pinus sylvestris) and especially pine sapwood has moderate or low durability. In order to build long lasting garden furniture, panelling, etc. for hazard-class 3 (and 4) pine wood has to be impregnated with wood preservatives. Durability of a product is influenced by different factors not only by effectiveness of biocides or natural durability of wood but furthermore by factors like crack behaviour, UV-stability and water behaviour of wood. Today wood preservatives with different compounds are used. A critical discussion about some preservative compounds is becoming increasingly important. It is known that the addition of water repellents, like oil, to wood has a positive influence on product performance. The philosophy of wood preservation industry to produce “fit for purpose”-products, having good durability, good esthetical properties and not negative environmental impact is growing. In our project a copper based chromium-free wood-preservative is used in combination with modified linseed oil. This combined treatment, called ROYAL-treatment, is going to be optimised and therefore the process parameters are investigated. The treated products are analysed referring to their amount of preservative- and oil-uptake and different characteristics like leaching, durability against weathering, stability of dimension and aesthetics of surfaces are investigated. 1 II. Oil and wood Oil is well known in use of different applications. In combination with wood it is often used for surface treatment, dipping, vacuum-pressure-application and drying. Because of its ability to transport heat oil can be used for drying processes (SIMMONS, 1989 “Preparation of chemically dried cellulosic fuel”; HÄGER,1982 Royal-process) and wood modifications (MENZ, 1999 heat treatment of wood). %- reduction of water uptake compared to reference 60 78,8 76,9 78,6 65,9 67,4 80 82,5 83,1 81,9 71,8 66,1 95,1 95,5 96,2 91,2 89,8 100 PS 542 PS 600 30 min 6,9 0 -20 soya-oil walnut-oil 16,8 20 orange-oil rape-oil 40 32,6 reduction % A student project about the use of natural oils in wood preservation was performed at the Institute of Wood Biology and Wood Technology of the University Göttingen (DÜSING, LANGEN, NÖLLENHEIDT, 2001). Different oils (orange-, soya-, rape-, walnut-, and two tall-oils) were tested and their reduction of water uptake in comparison to a reference described. The positive water repellent effect can be seen in figure 1. 24 hours 2 weeks time For the period of three years SAILER Fig. 1: screening of different oils (2001) investigated hemp-oil- and linseed-oil-impregnated wood samples (with a high oil uptake) in an outside weathering test. Referenced untreated pine wood samples have considerable changing of moisture content. It is quite evident that oil impregnated wood samples have a small fluctuation or moisture content during the outside weathering. Another process were oil is used in a very different manner is the Menz-process. In this oil-heat-treatment wood is completely covered with hot modified linseed oil. Oiltemperatures are between 180 – 220 oC. In terms of heat-treatment different versions are described. Therefore different statements about biological efficacy were made. Fig 2: outside weathering test of hempoil and linseed oil impregnated wood samples Oil, waxes, resins and water repellent additives can improve the hydrophobity of surfaces of wood. Therefore it has a positive effect against leaching of preservative compounds (COOPER, 1997). Oil, especially linseed oil, is often used as basic component for varnishes and paint. It has good autoxidativ properties and can harden without modification or addition of siccatives. Responsible for the curing properties of linseed oil are the linoleic and linolenic fatty acids, which can also be found in other plant oils like hempoil or rapeoil. A non-drying oil does not possess the power to take up oxygen from the air and to loose its liquid characteristics (MORELL, 1925). Linseed oil cannot act as a cell wall bulking agent. Its base molecule is too large and hydrophobic to enter the cell wall in a short time impregnation process. However, during the 2 impregnation process linseed oil fids cavities such as the tracheid lumina, the rays and any cracks in wood structure (OLSSON,1999). It is known that linseed- or rapeoil-treatments have no effect on protection against fungi (SAILER et al., 1998, VAN ACKER et al., 1999). Linseed oil is also not light stable. In case of light exposure constituents of oil can change (JANDER, 1932). From that reason a combined process (wood preservatives – oil) is researched. 3 III. Process characteristics The ROYAL-treatment, developed by Bror Olof Häger (GB 2088422A, US 4305978, DE 3008263A1) is a combined process. A copper-salt-impregnation (in our case WOLMANIT CX-8) is followed by an oil-impregnation (modified Linseed oil). This process is yet used in Europe since some years, but further details of many process parameters are still not investigated. In Europe only a few companies use the royal-process as a production-process (see table 1) Tab. 1: Application of the Royal-process in Europe Country Company Product amount Norway NYE MÖRE TRÄ AS paneling, nois-proof Ca. 8000 m³/year walls Norway MARNA BRUK paneling, nois-proof Ca. 4000 m³/year walls Denmark FREJLEV TRAE windows and doors Ca.1000 m³/year Germany: WERTH-HOLZ garden furniture, fences, playgrounds Ca. 5000 m³/year Significant for the royal-process are two steps and therefore two different vessels are used. For testings and investigations of this combined process a new pilot plant was developed in cooperation with the plant-manufacturer (SHARF-Bassum, GERMANY). Picture 1 shows the pilot plant at University Göttingen. 1. LOWRY-process The LOWRY-process (LOWRY, 1906) is a simplified procedure that is used for impregnation of waterborne wood preservatives. Mainly two steps are significant for the LOWRY-process: a pressure phase (>9 bar, 1 hour) and a high vacuum at the end of the process (20 min). The uptake of preservative is for pine wood 4 kg/m³ (at 4 per cent solution) Fig 3: Pilot-plant of Univerity Göttingen 2. Oil-impregnation The oil-impregnation is a treatment of wood with hot oil in a vacuum. Aim is to dry the oil from nearly wet state to a wood moisture content of between 12-18 % and to hydrophobize the surface in order to prevent leaching of preservatives. Therefore a vacuum is set (about 200 mbar) for several hours and the linseed oil is heated up to 80° C. This is done in order to reduce the steam pressure of water and to boil water out of wood. 4 The steam-pressure of water depends on temperature and pressure. A high vacuum needs only a low temperature for boiling of water. The boiled out water (steam) is cooled in a condensate-reservoir and can be absorbed and its quantity can be assessed. The wood samples can be dried to a certain moisture content in regard of the condensate. Tab. 2: Boiling point subject to temperature and pressure The process is finished when requested moisture content is reached. Different dimensions of wood samples and moisture contents need different duration of an oil-impregnation-process (between 2 and 12 hours). IV. Results and Foresight It can be stated yet that variation of moisture content during an outside exposure of Royalimpregnated wood in comparison to CX-8 impregnated and untreated pine wood is less. In an outside weathering test of 20 month with linseed-oil impregnated wood samples (Lap-joints, ENV 12037) wood moisture content was below 20 % (SAILER et al., 1999). EDLUND (1994) carried out comparative studies with horizontal installed royal-, CCA- and unimpregnated wood samples for the period of 65 month. The measured wood moisture content can be seen in figure 4. Weathering test Royal-treated 100 pine untreated moisture content [%] spruce untreated CCA-treated 80 60 40 TREU, 2001 20 0 0 5 10 13 23 month 51 65 EDLUND, 1994 Fig. 4: Changing of moisture content during an outside weathering test 5 Figure 5 shows the moisture content during an accelerated weathering test. An outside weathering test can be simulated in a accelerated weathering machine (QUV). Three different steps within a weathering-cycle can be chosen: Condensation water system, UV-light system and spray water system. moisture content of wood samples during the weathering test (QUV) 40 Royal cx-8 moisture content [%] 35 untreated 30 25 20 15 10 Step 1 /24 Step 3/1-26 Step 4/2-27 Step 1 /163 Step 4/1-166 Time Step 3/2-168 Step 4/2-171 TREU, 2001 Fig. 5: moisture content during an accelerated weathering test (QUV-tester) The change of colour is also an important factor to evaluate wood samples and products. Because of its missing UV-protection royal-impregnated wood samples are becoming grey after some month. Figure 6 shows a wood sample in an outside weathering test. The pictures were taken after 1, 3 and 6 month. May 2001 August 2001 October 2001 Fig. 6: changing of colour after several month 6 The project deals with the Process-development- and optimizing with regard to end product, moisture content, efficacy and uptake optimization. Wood properties are investigated especially water-repellancy, UV- stability, esthetical properties, shrinkage/swelling, crack behaviour, and leaching of wood preservative and oil. Further research within the next 3 years will focus on the following items: ♦ ♦ ♦ ♦ ♦ ♦ ♦ Migration of wood preservatives to oil during impregnation process Emission of oil and wood preservatives during exposure to weathering Long term water repellency Optimization of the process V. References Bearce, H. 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Rosenqvist, Marie: The distribution of introduced acetyl groups and a linseed oil model substance in wood examined by microautoradiography and ESEM, Sailer, Michael: Anwendung von Pflanzenölimprägnierung zum Schutz von Holz im Außenbereich, Hamburg, Dissertation, 2001, Als Manuskript gedruckt. Schneider, Marc H.: Model for moisture diffusion through wood containing linseed oil, In: Wood science, Jg. 1980, H. Vol. 12, No. 4, S. 207-213. Schneider, Marc H.: Wood - linseed oil interactions, New York, Dissertation, 1978, State University of New York College of environmental science and forestry Als Manuskript gedruckt. Schneider, M. H.: Scanning electron microscope study of a coating component deposited from solution into wood, In: Journal of the oil and colour chemists' association, 1979. Jg. (1979), H. 62, S. 441-444. Schneider, M. H.; Sharp, A. R.: A model for the uptake of linseed oil by wood, In: Journal of coatings technology, H. 54 / 693, S. 91-96. 8