Document 6526467
Transcription
Document 6526467
CAP-XX (Australia) Pty Ltd ABN 28 077 060 872 ACN 077 060 872 Unit 9, 12 Mars Rd Lane Cove, NSW 2066 Australia Tel: +61 2 9420 0690 Fax: +61 2 9420 0692 Web: www.cap-xx.com GB130 & GB230 SUPERCAPACITORS Datasheet Rev 1.0 Features High capacitance; High energy density Low ESR; High pulse power support High peak current Thin, prismatic form factor Typical Applications Pulse power support for LED flash, RF modems, GPS, thermal printers, etc. Secure power backup for handheld PDAs, POS terminals, Location trackers, SSDs, and M2M wireless networks Ride-through power during interruptions Efficient energy storage device for ambient energy harvesters such as solar, vibration/kinetic, thermo-electric and RF scavenging Peak power support for improved audio performance Specifications Table 1: Nominal Characteristics Device GB130F GB130G GB230F GB230G 1 Nominal 1 Capacitance 700mF 700mF 350mF 350mF Nominal 2 ESR 30m 30m 60m 60m Nominal Voltage 2.3V 2.3V 4.5V 4.5V Body Size 3 20.5 x 18.5mm 20.5 x 18.5mm 20.5 x 18.5mm 20.5 x 18.5mm 2 Thickness 1.5mm 1.6mm 3.1mm 3.2mm 3 +/-20% at 23ºC DC. +/- 20% at 23ºC, measured using a 0.5A step in current. Refer to Section 14. Table 2: Absolute Maximum Ratings Parameter Terminal Voltage/cell Temperature Name Conditions Min Vc T -40 Max Units 2.75 V +70 °C Table 3: Electrical Characteristics Parameter Terminal Voltage/cell Leakage 4 Current RMS 5 Current Peak 6 Current 4 5 Name Conditions Min Vc 23°C 0.0 IL 23°C, 2.25V for 72hrs 0.0 IRMS IP Max Units 2.3 V 2.0 µA 23°C 7.0 A 23°C >20 A Refer to Section 10. Refer to Section 8. 6 Typical 1.0 Single pulse, non-repetitive current. CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd 3 GB130 / GB230 Datasheet v1.0 1. ESR and Capacitance In its simplest form, the Equivalent Series Resistance (ESR) of a supercapacitor is the real part of its complex impedance. In the time domain it can be found by applying a step discharge current to a charged capacitor as shown in Figure 1. The ESR is found by dividing the instantaneous voltage step (∆V) by the current (I). The effective capacitance (Ce) for a given discharge time is found by dividing the total charge removed from the capacitor (∆Qn) by the voltage lost by the capacitor (∆Vn). Note that ∆V, the IR drop, is not included in this calculation because very little charge is removed from the capacitor during this time. Ce(t) shows the time response of the capacitor, and it is useful for predicting circuit behavior in pulsed applications. For GB230, as shown in Figure 1, V = 4.491V – 4.420V = 0.071V, and I = 1.011A, so ESR = 0.071V / 1.011A = 70.2mΩ Similarly, for a pulse width of 20ms: Vn = 4.420V – 4.325 V = 0.095V, tn = 0.02s, and I = 1.011A, so Ce (20ms) = 1.011A X 0.02s/0.095V = 213mF Note that Ce(10s) DC capacitance ESR 4.5 Voltage 1.8 Current t n 1.6 4.4 1.4 Vn 1.2 4.3 1 t Ci I v 4.2 0.8 0.6 Q n t Ce I n Vn Vn I 4.1 0.4 SUpercapacitor Load Current (A) Supercapacitor Voltage (V) V 2 V I 0.2 4 -0.01 0 0 0.01 Time(s) 0.02 0.03 0.04 Figure 1: Definitions for ESR, Instantaneous Capacitance and Effective Capacitance Page 2 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 2. Measuring DC Capacitance CAP-XX measures DC capacitance by recording the time taken for the supercapacitor voltage to decline from ~2/3 of Vnom to ~1/3 of Vnom after a current step is applied. The supercapacitor is charged to its nominal voltage, disconnected from the source, and a constant current discharge of 100mA applied. C = I x Δt / ΔV. For GB230, as shown in Figure 2, with I = 0.100A, and taking ΔV as 3.0V – 1.0V = 2V, the corresponding Δt is 11.83s – 5.108s = 6.722s, so C = 0.100 x 6.722 / 2.0 = 336mF. 0.2 5 4.5 0.16 Current (A) 4 0.14 Voltage (V) 3.5 0.12 3 0.1 2.5 0.08 2 0.06 1.5 0.04 1 0.02 0.5 0 Supercapacitor Voltage (V) Supercapacitor Current (A) 0.18 0 -5 0 5 10 15 20 Time (S) Figure 2: Measuring DC capacitance 3. Measuring ESR CAP-XX measures ESR by recording the voltage drop across the supercapacitor 50µs after a current step is applied. The supercapacitor is charged to its nominal voltage, disconnected from the source, and a current step applied. The 50µs delay ensures that the current step has settled. For GB230, as shown in Figure 3, ΔV = 4.49V – 4.38V = 80mV, and ΔI = 1.03A (load pulse), so ESR = ΔV / ΔI = 0.080 / 1.03 = 49.5mΩ. 4. Effective Capacitance Figure 4 shows the effective capacitance for a GB230 @ 23⁰C. The GB230 was charged to nominal voltage (4.5V) and held there until the charge current dropped to < 100µA. The supercapacitor was then disconnected from the source and discharged with a constant current, i. The voltage drop, excluding the ESR drop (as per the example of Fig 1) was then measured for various times from the start of the discharge. This enables Ce(t) to be calculated as i x t/Vdrop(t). Fig 4 shows Ce(t), where Ce is shown as a % of DC capacitance. Page 3 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 V I = ILOAD Figure 3: Measuring ESR Figure 4: Effective Capacitance as a function of Pulse Width Page 4 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 5. Frequency Response Figure 5 shows that the GB230 behaves as an ideal capacitor until ~3Hz, at which point the magnitude no longer rolls off proportionally to 1/frequency, and the phase crosses -45⁰. The performance of supercapacitors with frequency is complex, and the best predictor of performance is Figure 4, which shows effective capacitance as a function of pulse width. GB230 Frequency Response 100.00 100 Magnitude 80 Phase 60 10.00 20 1.00 0 -20 -40 Phase (Degrees) Magnitude (Ohms) 40 0.10 -60 -80 0.01 1.E-02 1.E+00 1.E+02 Frequency (Hz) 1.E+04 -100 1.E+06 Figure 5: Frequency Response of Impedance (biased at 4.5V with a 50mV test signal) GA230 ESR, Capacitance and Inductance vs. Freqency 1000 Inductance 100 1.0 ESR Capacitance 10 0.1 0.0 1.E-02 1.E+00 1.E+02 1.E+04 Inductance (nH) ESR(Ohms)/Capacitance(F) 10.0 1 1.E+06 Frequency (Hz) Figure 6: Frequency Response of ESR, Capacitance and Inductance Page 5 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 Inductance becomes significant above 10kHz, where it becomes >70nH (Figure 6). The GB230 is self-resonant in the 5kHz range. 6. Pulse Response Figure 7 shows the voltage ripple for a class 10 GPRS pulse with a GB230 providing the 1.8A load pulse for 1.15ms on a 25% duty cycle, with the source current limited to 600mA. The low ESR and high effective capacitance of the GB230 limits the voltage ripple seen by the load to 110mV. The supercapacitor supplies the difference between the 1.8A load current and the 0.6A source current. 4.5 1.8 4.45 1.6 4.4 Load Current (A) Load Current (A) 1.4 1.2 4.35 4.3 Limited Source Current 1 4.25 Capacitor Voltage 0.8 4.2 0.6 4.15 0.4 4.1 0.2 4.05 0 Capacitor Voltage (V) 2 4 -1.0 1.0 3.0 Time (mS) 5.0 7.0 Figure 7: Supercapacitor voltage ripple for GPRS class 10 pulse with 1.8A peak load current Page 6 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 7. Effect of Temperature on Capacitance and ESR DC capacitance does not vary over the operating temperature range Normalised C vs Temp 120% C normalised to value @ 25 deg C 115% 110% 105% 100% 95% 90% 85% 80% -40 -20 0 20 40 60 80 Temperature (deg C) . Figure 8: Capacitance change with temperature ESR increases at low temperatures: At -40⁰C, ESR is ~350% of nominal (at 23⁰C). Normalised ESR vs Temp 180% ESR normalised to value @ 25 deg C 160% 140% 120% 100% 80% 60% 40% 20% 0% -40 -20 0 20 40 60 80 Temperature deg C Figure 9: ESR change with temperature Page 7 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 8. RMS Current Continuous current flow into/out of the supercapacitor will cause self-heating. This limits the maximum continuous current the supercapacitor can handle. Self-heating is measured by applying a current square wave with a 50% duty cycle, charging the supercapacitor to its nominal voltage, then discharging it to 0.5V at a constant current. For a square wave, the RMS current is the same as the current amplitude. Figure 10 shows the increase in temperature in the body of the supercapacitor as a function of RMS current, and an empirically derived formula to estimate the temperature rise for any given RMS current. For example, if the ambient temperature is 40⁰C, and the maximum desired temperature for the supercapacitor is 70⁰C, the allowable temperature increase = 30⁰C. Reading from Figure 10, the maximum sustainable RMS current to remain within this temperature limit is 4A. GB230 5 min Temp Rise vs Irms Current (Part mounted on 1.6mm FR4 circuit board, Temp after 5 Min) 60 Temp Increase (Deg C) 50 40 30 20 10 0 0 1 2 3 Current (A) 4 5 6 Figure 10: Temperature increase as a function of RMS current 8. SPICE Models Please refer to the CAP-XX website (www.cap-xx.com) for SPICE models of our supercapacitors. Note that the SPICE model predicts the frequency and pulse response of a supercapacitor, but not its leakage current over the first ~120hrs (see Leakage Current section). Page 8 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 9. Leakage Current The capacitance in a supercapacitor is distributed throughout the electrode material, so the device will continue to draw some charge current long after it has reached terminal voltage. This diffusion current will gradually decay until the underlying leakage current of the device is revealed. The leakage current of the GB130 and GB230 supercapacitors is ~1uA at 23⁰C. As shown in Figure 11, the leakage current after 24hrs is ~2A. After 72hrs, it has decayed to less than 1A. Leakage current increases with temperature. The leakage current at 50⁰C will be approximately double that at 23⁰C. 14 Leakage Current (µA) 12 10 8 6 4 2 0 0.00 20.00 40.00 60.00 Time (Hours) 80.00 Figure 11: Leakage current of GB230 @ 23⁰C and 4.5V Page 9 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd 100.00 GB130 / GB230 Datasheet v1.0 10. Minimum Charge Current The minimum charge current for the GB130 and GB230 is < 20A. Supercapacitors do not follow the function V = I x t / C during charging from 0V at very low charge currents. The minimum charge current at which charging follows V = I x t / C is ~100A. Figure 12: Charging behavior of a GB130 supercapacitor at 23C Charge Current 2.5 200u Voltage (V) 2.0 100uA 50u 20uA 1.5 1.0 0.5 0.0 0.00 5.00 10.00 15.00 20.00 Time (hrs) 25.00 30.00 35.00 Figure 12: Charging behavior of a GB130 supercapacitor at 23C Page 10 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 11. Soldering CAP-XX recommends a maximum soldering time of 5 seconds when using an iron at 400⁰C in an ambient temperature of 23⁰C. Capacitor Internal Temperature when Soldering Capacitor Internal Temperature (°C) 55 50 Iron at 400°C 45 Iron at 300°C 40 35 30 25 20 0 1 2 3 4 5 6 7 8 9 10 Time (s) Figure 13: Supercapacitor temperature during soldering 12. Shock and Vibration Shock (half-sine pulse) Tested to IEC68-2-27 Amplitude 30g±20% Duration 18ms±5% No. of Shocks 3 in each direction (18 in total) No. of Axis 3 orthogonal Results No electrical or mechanical degradation (adhesive not required) Vibration (sinusoidal pulse): Tested to IEC68-2-6 Frequency 55Hz-500Hz Amplitude 0.35mm±3dB (55Hz to 59.55Hz) 5g±3dB (59.55Hz to 500Hz) Sweep Rate 1 Oct/min No. of Cycles 10 (55Hz-500Hz-50Hz) No. of Axis 3 orthogonal Results No electrical or mechanical degradation (adhesive not required) Page 11 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 13. Mechanical drawings GB230 dual cell supercapacitor module Page 12 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd GB130 / GB230 Datasheet v1.0 GB130 single cell supercapacitor Page 13 of 13 CAP-XX reserves the right to change the specification of its products and any data without notice. CAP-XX products are not authorized for use in life support systems. © 2012 CAP-XX (Australia) Pty Ltd