INTERLABORATORY STUDY NAPHTHA iis06N01 2006

INTERLABORATORY STUDY NAPHTHA iis06N01
2006
Report form A for analysis results sample 0620
Report to: R.J. Starink/ E. van der Burg before April 28, 2006
fax. + 31 181 69 45 43
Determination
Unit
Preferred
method
(**)
Colour (Saybolt)
D156
Copper Corrosion 3hrs@50°C
D130
Unrounded
Actual
result 0620
method
used (**)
Density at 15 °C
Kg/L
Distillation
Automated or Manual ?
*
i.b.p.
°C
D86
*
50% recovered
°C
D86
*
f.b.p.
°C
D86
mg/kg
D3227
Sulphur
mg/kg
*) please circle correct option
D2622
Mercaptans
result 0620
rounded cfr.
used standard
D4052
A / M *)
**) See Instructions
Name of laboratory:
date of sample receipt:
Country:
Name of responsible manager:
date of report:
INTERLABORATORY STUDY
NAPHTHA iis06N01
2006
Report form B for analysis results of sample 0621
Report to: R.J. Starink/ E. van der Burg before April 28, 2006
fax. + 31 181 69 45 43
Determination
Unit
Preferred
method
(**)
Organic chlorides as Cl
mg/kg
D5808
Methanol
mg/kg
MTBE
mg/kg
Unrounded
Actual
result 0621
method
used (**)
result 0621
rounded cfr.
used standard
PONA / PIONA / PNA
n-paraffines
vol%
D5443
i-paraffines
vol%
D5443
olefines
vol%
naphthenes
vol%
D5443
aromatics
vol%
D5443
C4 and lighter hydrocarbons
vol%
D5443
Compounds with bp >200°C vol%
n-paraffines
Wt% D5443
i-paraffines
Wt% D5443
Olefines
Wt%
Naphthenes
Wt% D5443
aromatics
Wt% D5443
C4 and lighter hydrocarbons
Wt% D5443
Compounds with bp >200°C
Wt%
Metals
Lead content as Pb
µg/kg
IP224
=== LOW Mercury content (0 – 15 µg/kg)
Mercury content as Hg
µg/kg
(**) See Instructions
Name of laboratory:
date of sample receipt:
Country:
Name of responsible manager:
date of report:
INTERLABORATORY STUDY
NAPHTHA iis06N01
2006
Report form C for analysis results of sample 0622 and 0623
ONLY for MERCURY as Hg
Report to: R.J. Starink/ E. van der Burg before April 28, 2006
fax. + 31 181 69 45 43
Determination
Mercury Determination
Unit
µg/kg
Determination
unit
* Mercury as Hg
(**) see instructions
Unrounded
Actual
result 0622
method
used (**)
result 0622
rounded cfr.
used standard
= = = = Medium content (15 – 150 µg/kg) = = = =
* Mercury as Hg
Mercury Determination
Preferred
method
(**)
Preferred
method
(**)
Unrounded
Actual
result 0623
method
used (**)
result 0623
rounded cfr.
used standard
= = = = High content (150 – 500 µg/kg) = = = =
µg/kg
Short description of the method used:
(how much sample used, sample treatments, destruction, etc.):
How was the mercury detected and quantified (Hydride, ICP, other):
What calibration was used (e.g. external standard, internal standard):
Were analytical results corrected for recovery (Yes/No):
Remarks:
Name of laboratory:
date of sample receipt:
Country:
Name of responsible manager:
date of report:
Instructions to participants for the interlaboratory study Naphtha iis06N01
*
Please confirm samples receipt as soon as you have received this package, preferably using the fax form that
you receive together with this package. Please complete the form and fax it to I.I.S (faxno. ++ 31 181 69 45
43)
If bottles have been broken please do not accept the package from the courier. New samples are on account of
the courier. When the bottles have been leaking please report this on the fax form.
*
This interlaboratory study concerns 4 different samples of Naphtha (500 mL of sample 0620, 500 mL of
sample 0621, 100 ml of sample 0622 and 100 ml of sample 0623). Please treat the samples as if they were
routine samples. On 3 samples Mercury (Hg) is requested #0621 = low, #0622 = medium, #0623 = high
content.
*
Each laboratory is requested to analyse the sample(s) in the way it would normally do in day-to-day
circumstances. Furthermore, each laboratory is advised to perform only those analyses you routinely do
(but you are allowed to do all analysis if you like). It might be wise to start with those tests which are most
important to your laboratory, especially if the supplied sample amount seems to be critical for you lab.
*
Report the analytical results using the indicated units on the report form. Report in the last column the
analytical results, rounded in accordance with the standard method that was used. Report in the first result
column the same analytical results but less rounded (we suggest to report one extra significant figure) in order
to give more meaningful statistical calculations. For example, when you use ASTM D4052 for the
determination of Density and you found a result of 0.75285 kg/L, we request you to report 0.7529 kg/l in
accordance with ASTM D4052 and 0.75285 kg/L as ‘unrounded’ result.
*
On report form A, B and C an extra column is added on request of several participants. This column is
named: ”preferred method”. In this column the method is mentioned, which the Institute for Interlaboratory
Studies will use for calculating the z-scores. It is of utmost importance to know that the method, which is
mentioned, is NOT mandatory. So when you normally use in day-to-day circumstances an other method
than the method prescribed in the ”preferred method” column, please use your method and note the actual
used method in the ”actual method used” column
*
Report also the method used on the report form. If no Standard method is used, report 'in house' method or
report the official method on which it is based with the remark 'mod' (modified).
*
Return the completed report form(s) to the Institute for Interlaboratory Studies at Spijkenisse, The
Netherlands, preferably one week after sample receipt, but in any case before the indicated closing date:
April 28, 2006 (preferably by fax).
*
If you have any remarks/questions please contact:
ing. R.J. Starink/ E. van der Burg, Institute for Interlaboratory Studies
p.o. box 200, NL-3200 AE Spijkenisse, The Netherlands
tel.no. ++ 31 181 69 45 41
faxno. ++ 31 181 69 45 43
email: iisnl@sgs.com