Safety Data Sheet - ICAP-SIRA Chemicals and Polymers S.p.A.

Safety Data Sheet
ICAFINISH IR KS 11
Safety Data Sheet dated 10/5/2015, version 1
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
Mixture identification:
Trade name: ICAFINISH IR KS 11
Trade code: 124943
1.2. Relevant identified uses of the substance or mixture and uses advised against
Industrial user (SU3)
Surface finish agent.
1.3. Details of the supplier of the safety data sheet
Company:
ICAP-SIRA CHEMICALS AND POLYMERS S.P.A.
Via F.Corridoni 19 20015 Parabiago (MI) Italia Tel. +39 0331 496111 fax +39 0331 495005
Competent person responsible for the safety data sheet:
msds@icapsira.com
1.4. Emergency telephone number
Tel. +39 0331 496111 Fax +39 0331 495005 Mobile +39 366/5673002 (Monday to Friday 08.00-12.30 14.0018.00). No numero emergenza sanitaria (No emergency medical services)
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
None.
R Phrases:
R10 Flammable.
R67 Vapours may cause drowsiness and dizziness.
EC regulation criteria 1272/2008 (CLP)
Warning, Flam. Liq. 3, Flammable liquid and vapour.
Warning, STOT SE 3, May cause drowsiness or dizziness.
Adverse physicochemical, human health and environmental effects:
No other hazards
2.2. Label elements
Symbols:
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 1/9
Warning
Hazard statements:
H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
Precautionary statements:
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P241 Use explosion-proof electrical/ventilating/lighting equipment.
P312 Call a POISON CENTER or doctor if you feel unwell.
P370+P378 In case of fire: use dry powder, CO2, foam for extinction.
P501 Dispose of contents/container in accordance with applicable regulations.
Special Provisions:
None
Contents:
1-methoxy-2-propanol; monopropylene glycol methyl ether
Special provisions according to Annex XVII of REACH and subsequent amendments:
None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
If provided, are listed in this section data known about other dangers that do not result in a classification, but
which may contribute to the global dangers of the substance or mixture.
No other hazards
SECTION 3: Composition/information on ingredients
3.1. Substances
N.A.
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related
classification:
>= 70% - < 80% 1-methoxy-2-propanol; monopropylene glycol methyl ether
REACH No.: 01-2119457435-35, Index number: 603-064-00-3, CAS: 107-98-2, EC: 203-539-1
R10-67; substance with a Community workplace exposure limit
2.6/3 Flam. Liq. 3 H226
3.8/3 STOT SE 3 H336
>= 0.1% - < 0.25% 2-methoxypropanol
Index number: 603-106-00-0, CAS: 1589-47-5, EC: 216-455-5
Repr. Cat. 2,Xi; R10-37/38-41-61
2.6/3 Flam. Liq. 3 H226
3.7/1B Repr. 1B H360
3.8/3 STOT SE 3 H335
3.2/2 Skin Irrit. 2 H315
3.3/1 Eye Dam. 1 H318
In case of the REACH registration numbers do not appear, the substance is exempted from registration, does not
reach the threshold of minimum volume for recording or the recording date is not yet forthcoming.
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 2/9
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Wash with plenty of water and soap.
In case of eyes contact:
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
In case of Ingestion:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
4.2. Most important symptoms and effects, both acute and delayed
The symptoms and effects known most relevant, in case of exposure, are described on the label (section 2)
and / or section 11. Other important symptoms and effects are not currently known.
4.3. Indication of any immediate medical attention and special treatment needed
Treatment:
None
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
In case of fire: use dry powder, CO2, foam for extinction. Never use water.
Extinguishing media which must not be used for safety reasons:
Water.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
When heated (decomposition) or in case of fire may liberate carbon oxides, gases and vapors which are
dangerous to health.
5.3. Advice for firefighters
Use suitable breathing apparatus .
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove all sources of ignition.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
6.3. Methods and material for containment and cleaning up
Suitable material for taking up: absorbing material, organic, sand
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13
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SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhaltion of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the
containers.
The maximum temperature permitted for the emptying of containers in plastic material, is 5 ° C below the
flash point (flash point).
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight.
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
See also section 10.
Instructions as regards storage premises:
Cool and adequately ventilated.
Storage class in according to the VCI: 3A (VCI=Verband der Chemischen Industrie).
Flash point: 32 ° C
7.3. Specific end use(s)
Recommendations related to particular uses need to be assessed case by case. Depending on the type of use,
technology and manufacturing cycle.
None in particular
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
1-methoxy-2-propanol; monopropylene glycol methyl ether - CAS: 107-98-2
OEL - LTE(8h): 375 mg/m3, 100 ppm - STE(): 568 mg/m3, 150 ppm - Notes: Pelle-possibilità di un assorbimento
cutaneo significativo
EU - LTE(8h): 375 mg/m3, 100 ppm - STE: 563 mg/m3, 150 ppm - Notes: Bold-type: Indicative Occupational
Exposure Limit Values [2,3] and Limit Values for Occupational Exposure [4] (for references see bibliography)
OEL - LTE(8h): 375 mg/m3, 100 ppm - STE(): 568 mg/m3, 150 ppm - Notes: ITALY - Pelle-possibilità di
assorbimento
ACGIH, 50 ppm, 100 ppm - Notes: A4 - Eye and URT irr
OEL - LTE(8h): 188 mg/m3, 50 ppm - STE(): 375 mg/m3, 100 ppm - Behaviour: Binding - Notes: FRANCE Restrictive statutory limit values
MAK - LTE(8h): 370 mg/m3, 100 ppm - STE(): 740 mg/m3, 200 ppm - Notes: GERMANY
OEL - LTE(8h): 375 mg/m3, 100 ppm - STE(): 568 mg/m3, 150 ppm - Notes: SPAIN
OEL - LTE(8h): 375 mg/m3, 100 ppm - STE: 560 mg/m3, 150 ppm - Notes: UNITED KINGDOM
DNEL Exposure Limit Values
1-methoxy-2-propanol; monopropylene glycol methyl ether - CAS: 107-98-2
Worker Industry: 369 mg/m3 - Worker Professional: 369 mg/m3 - Consumer: 43.9 mg/m3 - Exposure:
Human Inhalation - Frequency: Long Term, systemic effects
Worker Industry: 553.5 mg/m3 - Worker Professional: 553.5 mg/m3 - Exposure: Human Inhalation Frequency: Short Term, local effects
Worker Industry: 50.6 mg/kg - Worker Professional: 50.6 mg/kg - Consumer: 18.1 mg/m3 - Exposure:
Human Dermal - Frequency: Long Term, systemic effects
Consumer: 3.3 mg/m3 - Exposure: Human Oral - Frequency: Long Term, systemic effects
Derived No Effect Level (DNEL), where indicated in SDS, it is a safe level of exposure derived from toxicological
data in accordance with the REACH Regulation. DNEL may differ from an occupational exposure limit (OEL).
The OEL may be recommended by a single company, a organization of state control or expert organization
such as eg. ACGIH. The OEL DNEL are obtained by a different procedure.
PNEC Exposure Limit Values
1-methoxy-2-propanol; monopropylene glycol methyl ether - CAS: 107-98-2
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 4/9
Target:
Target:
Target:
Target:
Target:
Water: intermittent release - Value: 100 mg/l
Freshwater sediments - Value: 41.6 mg/l
Marine water sediments - Value: 4.17 mg/kg
Soil (agricultural) - Value: 2.47 mg/kg
Microorganisms in sewage treatments - Value: 100 mg/l
8.2. Exposure controls
Eye protection:
Not needed for normal use. Anyway, operate according good working practices.
Protection for skin:
Chemical protection clothing.
Protection for hands:
Not needed for normal use.
Respiratory protection:
Use adequate protective respiratory equipment.
Ensure good ventilation to maintain air contaminants below exposure limits. Use respiratory protection filters
for gas / vapor (Type A / AX brown, ref. Standard EN 141) as a function of the levels of occupational exposure
to chemical agents.
Thermal Hazards:
None
Environmental exposure controls:
None
The emissions from ventilation or work process equipment should be checked to ensure compliance with the
directives of the binding legislation on environmental protection. In some cases, to reduce emissions, might be
needed maintenance or technical plant modifications.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance and colour: liquid
Odour: ORGANIC SOLVENTS
Odour threshold: N.D. mg/m3
pH: N.A.
Melting point / freezing point: N.A.
Initial boiling point and boiling range: >100°C
Upper/lower flammability or explosive limits: n.d.
Vapour density: n.d.
Flash point: 32 ° C
Evaporation rate: n.d.
Vapour pressure: N.A.
Relative density: n.d. g/cm3
Solubility in oil: ESTERI E CHETONI
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: <270°C
Decomposition temperature: N.D.
Viscosity: n.d.
Explosive properties: N.A.
Oxidizing properties: N.A.
9.2. Other information
Conductivity: N.D.
Substance Groups relevant properties N.A.
Solids content: 20 1 %
The values do not always conform to the specifications of the product. See the specific technical
documentation for data.
Viscosity data: mPa.s data (instrument Brookfield type RVT); sec data (instrument Ford Cup).
If indicated, in case of a mixture, the data can be refered at one substance in the mixture.
SECTION 10: Stability and reactivity
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 5/9
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
None
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
Avoid contact with combustible materials. The product could catch fire.
10.6. Hazardous decomposition products
None.
When heated (decomposition) or in case of fire may liberate carbon oxides, gases and vapors which are
dangerous to health.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological information of the mixture:
N.A.
Toxicological information of the main substances found in the mixture:
1-methoxy-2-propanol; monopropylene glycol methyl ether - CAS: 107-98-2
a) acute toxicity:
Test: LD50 - Route: Oral - Species: Rat = 5300 mg/kg
Test: LD50 - Route: Skin - Species: Rat > 2000 mg/kg
Test: LC50 - Route: Inhalation - Species: Rat > 7000 Ppm
Test: LD50 - Route: Skin - Species: Rabbit = 13000 mg/kg
d) respiratory or skin sensitisation:
Test: Skin Sensitization - Route: Skin - Species: IC001 Negative
If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered as
N.A.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;
e) germ cell mutagenicity;
f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.
SECTION 12: Ecological information
12.1. Toxicity
Adopt good working practices, so that the product is not released into the environment.
1-methoxy-2-propanol; monopropylene glycol methyl ether - CAS: 107-98-2
a) Aquatic acute toxicity:
Endpoint: EC50 - Species: Fish = 20800 mg/l - Duration h: 96 - Notes: Pimephales promelas
Endpoint: IC50 - Species: Bacteria = 1.0 mg/l - Duration h: 3 - Notes: Fango attivato
Endpoint: LC50 - Species: Fish = 6812 mg/l - Duration h: 96 - Notes: Leuciscus idus
Endpoint: EC50 - Species: Daphnia = 23300 mg/l - Duration h: 48 - Notes: Daphnia magna
Endpoint: EC50 - Species: Algae > 1000 mg/l - Duration h: 168 - Notes: Pseudokirchneriella subcapitata
e) Plant toxicity:
Endpoint: EC50 - Species: Algae = 1.0 mg/l - Duration h: 168 - Notes: Selenastrum capricornutum
12.2. Persistence and degradability
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 6/9
None
Biodegradability: This property is specific for substance and can not be indicated for mixtures.
N.A.
12.3. Bioaccumulative potential
1-methoxy-2-propanol; monopropylene glycol methyl ether - CAS: 107-98-2
Bioaccumulation: Not bioaccumulative - Test: BCF - Bioconcentrantion factor 3.2 - Duration: N.A. - Notes:
Da sds Bitolea rev. 09/10/2013
Bioaccumulation: Not bioaccumulative - Test: Kow - Partition coefficient 0.9 - Duration: N.A. - Notes: <1 da
sds rev. 24/01/2014 Bayer
12.4. Mobility in soil
N.A.
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Recover if possible. In so doing, comply with the local and national regulations currently in force.
For disposal within the EU use its waste number (code), identified in the EU. Obligation to the waste producer,
the identification of the CER code.
SECTION 14: Transport information
14.1. UN number
ADR-UN number: 1866
IATA-Un number: 1866
IMDG-Un number: 1866
14.2. UN proper shipping name
ADR-Shipping Name: RESINA IN SOLUZIONE, INFIAMMABILE
IMDG-Technical name: 1-Metossi-2-propanolo
14.3. Transport hazard class(es)
ADR-Class: 3
ADR-Label: 3
ADR - Hazard identification number: 30
IATA-Class: 3
IATA-Label: 3
IMDG-Class: 3
14.4. Packing group
ADR-Packing Group: III
IATA-Packing group: III
IMDG-Packing group: III
14.5. Environmental hazards
Marine pollutant: NO MARINE POLLUTANT
14.6. Special precautions for user
Transportation, including loading and unloading must be carried out by people who have received the necessary
training required by the modal regulations concerning the transport of dangerous goods.
-Characteristics:
Gives off dangerous fumes.
Flammable liquid.
Hazardous to eyes and air passages. Immiscible or partly miscible with water (less than 10%), lighter than water.
- Hazards:
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 7/9
Heating of container(s) will cause pressure rise with risk of bursting and subsequent explosion. May form explosive
mixture with air. Gives off toxic and irritant fumes when heated or burning. The vapour may be invisible and is
heavier than air. It spreads along the ground and may enter sewers and basements. May be narcotic and cause
unconsciousness.
Rail (RID): 3
Flash point: 32 ° C
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances)
Dir. 99/45/EC (Classification, packaging and labelling of dangerous preparations)
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Dir. 2006/8/EC
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP)
Regulation (EU) n. 453/2010 (Annex I)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 487/2013 (ATP 4 CLP)
Regulation (EU) n. 944/2013 (ATP 5 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC) 1907/2006
(REACH) and subsequent modifications:
Restrictions related to the product:
Restriction 3
Restriction 40
Restrictions related to the substances contained:
Restriction 30
Where applicable, refer to the following regulatory provisions :
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) nr 648/2004 (detergents).
1999/13/EC (VOC directive)
Provisions related to directives 82/501/EC(Seveso), 96/82/EC(Seveso II):
15.2. Chemical safety assessment
No
SECTION 16: Other information
Full text of phrases referred to in Section 3:
R10 Flammable.
R37/38 Irritating to respiratory system and skin.
R41 Risk of serious damage to eyes.
R61 May cause harm to the unborn child.
R67 Vapours may cause drowsiness and dizziness.
H226 Flammable liquid and vapour.
H336 May cause drowsiness or dizziness.
H360 May damage fertility or the unborn child.
H335 May cause respiratory irritation.
H315 Causes skin irritation.
H318 Causes serious eye damage.
This safety data sheet has been completely updated in compliance to Regulation 453/2010/EU.
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ICAFINISH IR KS 11, Safety Data Sheet dated 10/5/2015, version 1 - Pag. 8/9
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the
European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
CCNL - Appendix 1
Insert further consulted bibliography
ICSC - International Chemical Safety Cards (WHO/IPCS/ILO)
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to
the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use
intended.
This MSDS cancels and replaces any preceding release.
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
CLP: Classification, Labeling, Packaging.
DNEL: Derived No Effect Level.
EINECS: European Inventory of Existing Commercial Chemical Substances.
GefStoffVO: Ordinance on Hazardous Substances, Germany.
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
IMDG: International Maritime Code for Dangerous Goods.
INCI: International Nomenclature of Cosmetic Ingredients.
KSt: Explosion coefficient.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
LTE: Long-term exposure.
PNEC: Predicted No Effect Concentration.
STP:
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
STE: Short-term exposure.
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
WGK: German Water Hazard Class.
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