Hydrogeological Study, Lafreniere Subdivision, L`Orignal, Ontario
Transcription
Hydrogeological Study, Lafreniere Subdivision, L`Orignal, Ontario
TESTING 6 INSPECTION CONCRETE ASPHALT GEOTECHNICAL SPECIALISTS STEEL SOILS PILING ROOFING HYDROGEOLOGICAL STUDY LAFRENIERE SUBDIVISION L'ORIGNAL, ONTARIO PREPARED FOR: Neil Levac Engineering Ltd. BY FONDEX LTD TABLE OF CONTENTS PAGE SUMMARY 1. INTRODUCTION 2. TOPOGRAPHY AND REGIONAL GEOLOGY 2.1 Bedrock 2.2 Surficial Deposits 3. REGIONAL HYDROGEOLOGY 4. FIELD WORK 5. GROUNDWATER YIELD OF TEST WELLS 6. GROUNDWATER QUALITY OF TEST WELLS 7. RECOMMENDATIONS 7.1 Well Construction 7.2 Water Quality - Treatment 8. CONCLUSIONS List of Drawinas Drawing 0-A505-1: Test Well Location Appendix Appendix 'A' Appendix 'B' Appendix 'C' - Water Well Records - Chemical and Bacteriological Test Results Appendix 'D' Appendix 'E' - - - Recommended Procedure for the Cementing In-Place Production Line of Casing on Water Wells Treatment Devices for Some Common Water Quality Problems Fondex Report - 1981 SUMMARY Fondex Limited was retained by Neil Levac Engineering Ltd. to undertake a hydrogeological study for a proposed subdivision in the Village of L'Orignal, Ontario. The field work, conducted in December 1989 and January 1990, consisted of three (3) six hour pump tests with water quality sampling. The pump tests revealed adequate groundwater yield in two of the wells (No. 1 and 3) while the third (well No. 2),located in the central and elevated portion of the study site, produced marginal but still acceptable yields as evidenced in a repeat, 18 hour pump test. Water quality is good in general, with some indicators slightly exceeding the MOE guidelines. These values can be reduced by proper well development, filtration, or equivalent systems. Recommendations for such treatments are made in the report. 1. INTRODUCTION Fondex Limited was contracted by Neil Levac Engineering Ltd. to conduct a hydrogeological study for a proposed subdivision in the Village of L'Orignal, Ontario. The work was performed in view of the participation of the Ontario Ministry of the Environment, as part of the Subdivision Review Plan, in the review of all subdivision proposals involving private servicing. The scope of this study was limited to the hydrogeological characterization of the site by conducting: - pump tests to evaluate aquifer yields, and - chemical tests on the groundwater to establish its quality. No terrain analysis was performed in this study. A soil investigation was conducted by Fondex Limited in 1981 to identify the stratigraphy at the site. The site under consideration is located in the Village of L'Orignal, north of Highway 17, East of Ottawa, as shown on Figure 0-A505-1. It is understood that the proposed subdivision will be on part of Lot 4, South of Front St. and will consist of 56 lots. 2. TOPOGRAPHY AND REGIONAL GEOLOGY The North and South extremities of the site (towards Front street and towards the creek, respectively) dip downward, leaving the central portion of the site slightty elevated. The regional topography is flat, with the terrain generally gently sloping northerly in the direction of &heOttawa River. Page 2 2.1 Bedrock Bedrock in the area of L'Orignal appears to be limestone beds of the St. Martin formation, with shales of the Rockliffe formation existng at the eastern border of the village. Depth to bedrock in the region ranges from a few metres below ground surface up to 40 metres. Rock outcrops exist south of the village. 2.2 Surficial De~osits Based on a previous soil investigation (Fondex Limited report 0-5617-S,1981), Appendix 'El the subsoil at the site was found to be predominantly topsoil overlying silt till. Sand or clay may be encountered in some areas above the till; similarly, shallow bedrock exists in some parts of the site. 3. REGIONAL HYDROGEOLOGY Regional groundwater flow occurs generally towards the Ottawa River. Locally, groundwater tends to flow from the higher elevations (such as the rock outcrops south of L'Orignal) towards the river. Based on a study by Environment Canada, the following geochemistry of the groundwater for the area of L'Orignal was found: Page 3 PARAMETER UNITS Total dissolved solids PPm metres metres metres Piezometric surface elevation Range of depth of wells Depth to piezometric surface Groundwater yield Turbidity * IPm JTU Percent sodium % pH Colour Nitrate Hazen U. RANGE PPm Iron PPm PPm Fluoride Chloride Potassium PPm PPm PPm Sulphate Hardness Magnesium Calcium Sodium * JTU = Jackson Turbidity Units Reference: Hydrochemical Study of the lnterstream Area Between Ottawa and St. Lawrence Rivers, Environment Canada, Scientific Series No. 76, 1978 4. FIELD WORK The field work conducted for this project consisted of three (3) 6 hour pump tests to evaluate the groundwater quality and yield. Page 4 The pumping tests were conducted in the wells located as shown in drawing 0-A505-1. The wells were drilled by Maurice Cayer Limited of Casselman, Ontario. The three wells were 158 mm (6.25 in.) in diameter and were steel cased and grouted from ground surface to approximately 7 metres depth. The water well records are given in Appendix 'A'. A standard constant discharge pump test was conducted in each of the three wells, using the procedures recommended by the Ontario Ministry of the Environment. Each test consisted of a 6 hour pumping period during which the drawdown of the well was closely monitored. Once the pumping action stopped, a recovery period was allowed, during which the rise of the water level in the well was recorded. Water samples for chemical and bacteriological analyses were collected near the beginning and end of the pumping test. The test specifications and test data are summarized in the following table. Note that two pump tests were conducted in Well No. 2. The results will be discussed later. Well Number Descriptor 1 Date of test 8-1-90 Depth of well (m) 32 Pumping rate (Igpm) 2-A 2-B 3 5 Pump Setting (m) Hydrostatic W.L. (m) 29,3 1,05 Total Drawdown (m) 1,22 * the initial pumping rate was set at 5 Igpm. However, a rapid drawdown occured during the initial 45 min. of the test such that the rate was reduced to 3 lgpm for the remaining 5 hour and 15 min pumping period ** after 45 min. at 5 Igpm. Drawdown at end of test was 12.90m @ # A based on drawdown at end of test reduced to 3 lgpm after 10.5 hours after 6 hours reduced to 3 lgpm after 10,5 hours Page 5 Because well No. 2 could not sustain a pumping rate of 5 lgpm or 22.7 litreslmin (test A) and therefore problems arose with the interpretation of the data, it was decided to repeat the test in that well (test 0) at a reduced rate of 3.5 lgpm (15.9 litres/min) for 18 hours. The chosen rate was sustained for 10.5 hours; at that time, the drawdown became excessive (well water level too close to pump setting) and the rate was reduced to 3 lgpm (13.6 litreslmin) for the remainder 7.5 hours. Four water samples were taken during this repeat test at 4, 8, 12, and 18 hours from the start of the test, corresponding to samples 2-3, 2-4, 2-5, and 2-6 respectively. Also during this test, measurements of water levels in wells No. 1 and No. 3 were taken; no influence was observed in these wells from the pumping action in well No. 2. 5. GROUNDWATER YIELD OF PUMP TESTS The data from the pump tests were interpreted to obtain parameters such as specific capacity, percent recovery, and transmissivity. The following table presents these results: Descriptor Specific Capacity (Ipm/m) Percent Recover after 60 min. ( O h ) Well Number 1 2-A 2-8 18,6 N\ A o18 18,O 3 Transmissivity (m2/day) drawdown 16,42 N/A 0,5 27,65 recovery 16,42 ole N/A 19,35 @ based on drawdown at end of test Page 6 Wells No. 1 and 3 had no problems providing the 22.3 litres/min (5 Igpm) demanded during the pump tests. For well No. 2, the rate had to be lowered to 13.6 litres/min (3 Igpm) after 45 minutes of pumping because of rapid and excessive drawdown of the water level in the well. The second pump test conducted in well No. 2 (test 2-B) was performed at a rate of 15.9 litres/min (3.5 lgpm) for 10.5 hours before the pumping rate had to be reduced. 6. GROUNDWATER QUALITY OF TEST WELLS Water samples were collected from each well near the beginning and near the end of each pump test (more often during repeat test 2-B as mentioned previously). The samples were sent for chemical and bacteriologicalanalyses. The results, summarized in the table next page, are given in Appendix 'B'. The bacteriological counts in all wells was nil. Among the indicator parameters exceeding MOE guidelines were: i) Health related parameters Sodium Turbidity Note that the measurement of the turbidity was conducted on un-filtered samples and therefore yields apparent values (see Appendix 'B' for details). True turbidity values are given later. ii) Aesthetic parameters Hardness Iron Manganese Colour 0-A505 Page 7 Note that the measurement of colour was conducted using the spectrophotometric method (Standard Methods for the Examination of Water and Waste Water, 1985, 16th Edition, Method 2048, pgae 69). This method usually yields higher colour values. Samples were collected from well No. 2 during the 18 hour pump test 2-8 and in wells 1 and 3 for repeat analysis. The results are as follows: Sample Iron PPm 0,3 MOE Manganese PPm 0,05 Turbidity NTU 1 Colour TCU 5 The above results show acceptable turbidities for wells 2 and 3, somewhat above the MOE objectives for well No. 1. Recommendations to reduce turbidity will be discussed later. o n ~ ,No. 1 and 3 produced With respect to manganese ~ ~ n ~ e n t r a t i wells values slighlty in excess of the MOE objectives; recommendations follow. Page 8 7. RECOMMENDATIONS 7.1 Well Construction Proper well construction is required to maintain, on a long term basis, the quality of the water. Each well should be cased into the bedrock a minimum of 1.5 metres and pressure grouted. Acceptable grouting procedures are described in Appendix 'C'. Grout mixing and setting time should follow the manufacturer's instructions. Each new well should be properly developed until acceptable water quality is achieved. To ensure the water quality of each well, tests for indicators such as iron, colour, turbidity and bacteria should be conducted. Extended pumping periods (10 to 20 hrs) may be required in some wells to achieve the desired water quality as evidenced in well No. 2. Wells for which the bacteriological counts are above the MOE objectives should be shock chlorinated. Chlorination procedures may be found in the Environment Ontario publication "Water Wells and Ground Water Supplies in Ontario". 7.2 Water Qualitv - Treatments Indicators such as sodium, turbidity, hardness, and manganese, were found in excess of MOE objectives in some wells. Following are recommendations on methods to reduce and minimize these parameters. i) Manganese Manganese concentrations in excess of 0.05 mg/l tend to precipitate thus causing stains in pumbling fixtures and laundry. Methods to remove or control this metal include: Page 9 - aeration and settling or filtration - green sand filters - polyphosphates or silica additions - water softeners - chlorination - filtration A description of these methods is given in Appendix 'Dl. ii) Hardness "Hard" water results in the formation of scales in kettles, prevents soap from lathering, and can produce dingy laundry. Water softeners or soluble phosphate additives (Appendix 'Dl) can be used as corrective measures to reduce these problems. iii) Turbidity Turbidity occurs from fine particles (clay, silt, or fine sand) suspensions in the well. Long term pumping usually solves the problem as observed in pump test 2-8. However, if excessive turbidity levels persist, filters such as sand and dolomite can remove the fine- grained particles in the water. 8. CONCLUSIONS A hydrogeological study consisting of three 6 hour pump tests, chemical and bacteriological analyses were conducted at the subject site to evaluate the groundwater yield and quality for a proposed subdivision. A repeat test in well No. 2 (test 2-8) was necessary because the well could not sustain the initial 22.3 litres/min pumping rate used in test 2-A and to verify the quality of the groundwater at that location. Page 10 0-A505 The pump tests indicate an adequate supply from the groundwater, although a marginal yield was observed in well No 2, located in the most elevated section of the site. In general, the water quality is good. Some indicator parameters were however in excess of MOE guidelines. Proper well construction, development, and treatment measures should alleviate these problems. FONDEX LIMITED Guy Felio, Ph.D. Diane Myrand, Hydrogeologist TABLE 1 WATER QUALITY RESULTS PUMPING TESTS HEALTH RELATED PARAMETERS f PARAMETER SODIUM (Na) FLUORIDE (FI) AMMONIA ( N q ) UNITS MOE objectives mg/l 20 mg/l 24 mgll WELL 2 1 2 1 2 1 2 51.4 20.1 26.4 36 24.9 0.1: 0.14 . 0.16 0.17 0.2 0.2 0.5 44.1 0.21 0.3 0.3 ( 0.1 0.7 1.5 < 0.5 (0.5 0.6 (0.5 (0.5 0.5 mg/l 10 NITRITE (NO2) mgll 1 (0.5 TURBIDITY FTU 1 30 50 260 TOTAL COLlFORMS /100ml OTOIO* O 0 0 FAECAL COLlFORMS 1100ml 0 0 0 FAECAL STREPT. 1100ml 0 0 RECOMMENDED < 2 FOR GOOD QlJALITY WELL 3 0.18 NITRATE (NO,) * \ WELL 1 < 0.5 0.1 < 40.5 87 6 0 0 0 0 0 0 0 o o 0 0 18 - WARNING LEVEL FOR PERSONS ON LOW INTAKE SALT DlElS f \ COMMENTS : L \ J TABLE 1 :' Continued ( FONDEX WATER QUALITY RESULTS PUMPING TESTS ESTHETIC PARAMETERS f PARAMETER UNITS MOE objectives CONDUCTIVITY WELL 1 WELL 3 1 2 1 2 1 2 331 334 378 407 402 409 7.3 7.25 6.5-8.5 7.2 PH WELL 2 7.35 7.25 7.1 CALCIUM (Ca) mgll 30.3 26.5 52.7 54.5 43.3 42.7 MAGNESIUM (Mg) mgll 14.2 12.7 9 . 4 21.5 40.2 21.5 CHLORIDE (CI) mg/l 1.9 1.7 250 1.3 1.5 1.2 0.9 213 216 243 241 235 230 197 282 ALKALINITY mgfi Ca CO HARDNESS rngd Ca CO < 200 134 120 226 227 IRON (Fe) mgll 0.3 2.0 0.35 1.92 0.37 2.03 0.46 MARGANESE (Mn) mgll 0.05 0.14 0.1 0.22 0.05 0.23 0.2 SULPHALTE (SOJ mgll 500 25.8 26:1 22.9 23.5 25.8 28.2 NID NID NID N/D NID NID 6 6 2 ODOUR PHENOLS umgll 2 7 4 2 (1.0 (1.0 (1.0 (1.0 (1.0 41.0 180 25 >500 100 450 30 4 TANNINS + LlGNlN mgll COLOUR TCU TOTAL NITROGEN mgll 1.6 1.1 40.2 0.7 40.2 (0.2 POTASSIUM mg/l 8.4 7.7 5.1 3.7 7.8 8.6. 5 ' APPENDICES APPENDIX "A" Water Well Records . . FEE 16 '90 11: 19 RGC HOME CENTER The Ontorio Water Resources Act Ontario WATER W E L ~ RECORD L Environment ....... :, ....,. O eorntnclrr 0 wrmlclrrL 0 rvbr-c rur.Lr 0 caarbub on r m ce*bergonlur 0 "or uses CONTRACTOR'S COPY . . . ., . 3 1 . . ........ . ".. . " .:,., . :.. I . . , 8 . . ,. . ; . . . . . . . , . . . . i .* -. . \ . . . :- ----...'-........ . . . .... ...- ,.. ..... ,..... . . . . . .. .. . . . . . . . . . . 4 . .. . .... ... . . . .. . .. .. . . r .. ' . . ' I . . .I .C . .' .... I. ' , FEB 16 '90 11:20 526 P83, RGC HOME CENTER @ ofthe Ministry The Ontario Water Resources Act WATER WELL RECORD Environment Ontarto WATER RECORD ' .,I,,. = c A,. i u n IqI I V h " . , . . ..".".."..."...., ...- . . , ... .. 7s ..,. ,... ..I 9 0 ..,. 71 ....1 .... ."".#.' 11I1 "ll.q. w O 0 rure .,,AqIC *, ,611 30 brrrle wa111 L L V I ~ "I.. I :I XL.#I LI"LL1 OVRI". 3 6, **" .umrr.r ..'I. .$ 4 a&C.*rl N.l "I', 9 fv. 75- 60 = IN DIACIAM ~ ( L O * SHOW D I I T A N C I S or W I L L ~ R O Y"OAD LID LO1 L I I C I N O I C A I I NORTH ST 11101. rulrlh4 msrortlr I. l,.",,, . 1 "I*.,,, I.I..I,O,~ ,,,, .I I..*# 1111 o cr~ra I .(lOIl~l#OL. L O C A T I O N OF WELL - - ' - --.OU., 0 ~ : ~ O . U D T 6. ! 0 - I "°C' Q ,USE 0 0 OF CONSTRUCTION 0.1'11 0. I.L. ~m.lt.rtom l.o".r.lrL 0 MiTHOD *a*, iCL%QC "-.- 0 U WILL M o r ~ s r ~ c WATER ma11 0.111v.f10m *OLE 0 rrr! .acm-*+ .(- l u r t ~ ~ &.~II# FINAL STATUS n -. .,2 .~.f.C"l.C D o 0 r o o r m e OR am -- - ........ ..- .- - .. ).... .i_ ... C~.OIIIOIIII~ 0 O c f v ~ n l* n * ~ . svrrrr olwtl cambl VOOL lcorrSn1lonA~~ lm.rtmsc$ , . eouurmc~~~ ru~neorri 0 ?vmrlc O WoYm O .or#.r U rm . m r ~ o r r w ~ ot ~ r u r r a c t r mrutrrr ~ 1 I A I m O N k L I WORQuAltlf uwarosnts 0 D D re, vw. bol$~r alr~oeb rllrlme 66767 mor4no oloatr. ...eusl!am co"l.6Clo. 0 orusm 0.1111.1 .I".."* ragrwrr *v*.Cm ,CCM"1SI1" Y CO~JITRACTOR~S I . . ., . ,: . . COPY .... . - . .: . . . . . . .. . . . . . .. . ..., .. .. . . ronw NO C~(II/~FORM . *. "..\ .,,,,-. ' . '.. .' : .. , . ' . i., , :., B . FEB 16 '90 11:20 Ministry Ontario Environment RGC HOME CENTER 526 P04 , The Ontario Woter Resources Act WATER WELL RECORD APPENDIX "6" Chemical and Bacteriological Test Results Laboratoires IASCHEM Inc. 184, chemin Freeman Hull, (Quebec) 582 2B5 Tk1:(819) 778-0020 11 janvier 1990 Rapport de laboratoire Fondex Ltee a/s D. Myrand 123, Jean Proulx Hull (Quebec) (1-0236) Echantillon d'eau (No. 90-0017-1) Point de pr&l&vement: Au debut du puits (#I-I), Orignal Real Estate, Orignal. Prkleveur: Resultats de l'analyse microbioloqique descoliformes totaux fecaux et des streptocoques fecaux d'une eau de puits. (NO. 90-0017-1) Normes de l'eau potable et rksultats Coliformes totaux < 10 UFC1 /I00 m l 0 UFC/100 ml Coliformes fecaux 0 UFC/100 ml 0 UFC/100 ml Streptocoques fbcaux 0 UFC/100 m l 0 UFC/100 ml UFC - unitees formant des colonies (batteries) Apprkciation microbiologique: eau potable. technicien en microbiologie: Magdi G. Yassa, chimiste C. Alvarado Christian Choquet, microbiologiste Laboratoires IASCHEM Inc. 184, chemin Freeman Hull, (Qukbec) J8Z 2B5 T&1:(819) 778-0020 Rapport de laboratoire Fondex Ltbe a/s D. Myrand 123, Jean Proulx Hull (Qukbec) 12 janvier 1990 (1-0236) Echantillon d'eau (No. 90-0017-2). Point de prbli2vement: A la fin du puits ( # I - 2 ) , Orignal Real Estate, Orignal. Prbleveur: Resultats de l'analyse microbioloaique des coliformes totaux et fbcaux, des streptocoques fkcaux d'une eau de puits. (No. 90-0017-2) Normes de l'eau potable Coliformes totaux Coliformes fkcaux Streptocoques fkcaux UFC - unitkes formant des colonies (batteries) Appreciation microbiologique: eau potable. technicien en microbiologie: Magdi G. Yassa, chimiste 6. Alvarado Christian Choquet, microbiologiste Laboratoires IASCHEM Inc. 184, chemin Freeman Hull, (Qukbec 582 2B5 T61: (819) 778-0020 Rapport de laboratoire Fondex Ltke a/s D. Myrand 123, Jean Proulx Hull (Qukbec) 12 janvier 1990 (1-0236) Echantillon d'eau (No. 90-0025-1) Point de prkldvement: Orignal Real Estate (#2-11, Orignal. Prkleveur: R6sultats de l'analyse microbioloqique des coliformes totaux et fOcaux et des streptocoques fecaux d'une eau-de puits. (No. 90-0025-1) Normes de l'eau potable Coliformes totaux Coliformes ft5caux Streptocoques fkcaux 1 UFC - unitbes formant des colonies (batteries) Appr6ciation microbiologique: eau potable. technicien en microbiologie: Magdi G. Yassa, chimiste C. Alvarado Christian Choquet, microbiologiste Laboratoires IASCHEM Inc. 184, chemin Freeman Hull, (Qubbec) 582 2B5 T61: (819) 778-0020 Rapport de laboratoire Fondex Ltke a/s D. Myrand 123, Jean Proulx Hull (Qu6bec) 12 janvier 1990 Echantillon d'eau (No. 90-0025-2) Point de prbl&vement: Orignal Real Estate (#2-2), Orignal. Prkleveur: Rksultats de l'analyse microbiolosique des coliformes totaux et fkcaux et des streptocoques f6caux d'une e-au de puits. (No. 90-0025-2) Normes de l'eau potable resultats Coliformes totaux < 10 UFC1/I00 ml 0 UFC/100 ml Coliformes fkcaux 0 UFC/100 ml 0 UFC/100 ml Streptocoques fbcaux 0 UFC/100 ml 0 1 UFC - UFC/100 ml unitbes formant des colonies (bactkries) Appr6ciation microbiologique: eau potable. technicien en microbiologie: Magdi G. Yassa, chimiste C. Alvarado ~hristianChoquet, microbiologiste Laboratoires IASCHEM Inc. 184, chemin Freeman Hull, (Quebec) 582 2B5 T61:(819) 778-0020 15 janvier 1990 Rapport de laboratoire Fondex Ltbe a/s D. Myrand 123, Jean Proulx Hull (Qubbec) Echantillon d'eau (No. 90-0028-1) Point de prbl&vement: L'Orignal Real Estate (#3-I), Orignal. Preleveur: Rksultats de l'analyse microbioloqique des coliformes totaux et fbcaux et des streptocoques fkcaux d'une eau de puits. (NO. 90-0028-1) Normes de l'eau potable Coliformes totaux Coliformes fbcaux Streptocoques fbcaux Apprbciation microbiologique: eau potable. technicien en microbiologie: Magdi G. Yassa, chimiste C. Alvarado Christian Choquet, microbiologiste I I I I I Laboratoires IASCHEM Inc. 184, chemin Freeman Hull, (Qubbec) 582 2B5 TB1:(819) 778-0020 Rapport de laboratoire Fondex Ltbe a/s D. Myrand 123, Jean Proulx Hull (Qubbec) 15 janvier 1990 (1-0236) Echantillon d'eau (No. 90-0028-2) Point de prbl&vement: L'Orignal Real Estate (#3-21, Orignal. Prkleveur: Rbsultats de l'analyse microbiolosique d-es coliformes totaux et fbcaux et des streptocoques fbcaux d'une eau de puits. (No. 90-0028-2) I Normes de l'eau potable Coliformes totaux < 10 UFC1/lOO m l resultats 0 UFC/100 m l Coliformes fbcaux Streptocoques f6caux I I I 1 UFC - unitees formant des colonies (batteries) Apprbciation microbiologique: eau potable. technicien en microbiologie: Magdi G. Yassa, chimiste C. ~lvarado ~hristianChoquet, microbiologiste I I Madame Diane Myrand Fondex Ltee 123 Jean-Proulx ~ u l lQuebec , ) Suite h votre demande au sujet des methodes d'analyse de notre laboratoire nous vous confirmons que nous utilisons le 'Standard Methods for the Examination of Water and Waste I Water" 1985 16th Edition APHA AWWA WPCE. - 1 I faut remarquer que dans I'analyse des nitrates nous vous donnions les rbsultats en ( N03- et pour les obtenir en N il faut multiplier les resultats par un facteur de 0.226. I I I Pour la couleur c'est la methode spectrophometrique 204 B page 69. Pour la Turbidite c'est la methode Nephelometrique 214 A. Nous esperons que ces renseignements vous seront utiles. Bien a vous, la formagin page 134. Laboratoires Iaschem Inc. 184, chemin Freeman Hull, Qc. 582 2B5 TB1: 778 0020 Rapport de laboratoire 19 fevrier, 1990 Fondex Ltke (1-0236) a/s Diane Myrand 123 Jean-Proulx Hull, Qc. Point du prBlGvement : Orignal, Real Estate Identification de 1'Bchantillon : 900017 RBfbrence: 0-A505 RBsultats Tableau: Analyses chimiques d16chantillons d'eau. (90-0017) ParamGtres d'analyse Mn (mg/L) K (mg/L) Na (mg/L) Alcalinitk (mg/L en CaC03) Azote ammoniacale (mg/L) Azote totale (mg/L) Chlorures (mg/L) Conductivit6 (umhos/cm) Couleur apparente (unitks) Duretk (mg/L) Fluorures (mg/L) Nitrites (mg/L) Nitrates (mg/L) pH Phknols (mg/L) Sulfates (mg/L) Sulfures (mg/L) Turbidit6 (FTU) Ana1ystes:Michel Blais Andree Soucy Dan-iele Prevost RBsultats Laboratoires Iaschem Inc. 184, chemin Freeman . Hull, Qc. 582 2B5 T61: 778 0020 ~ a p p o r tde laboratoire Fondex Ltee (1-0236) a/s Diane Myrand 123 Jean-Proulx Hull, Qc. Point du prelevement : Orignal, Real Estate Identification de l'echantillon : 900025 Reference: 0-A505 Resultats Tableau: Analyses chimiques d'echantillons d'eau. (90-0025) Paramhtres d'analyse (mg/L) (mg/L) (mg/L) (mg/L) K (mg/L) Na (mg/L) Alcalinitk (mg/L en CaC03) Azote ammoniacale (mg/L) Azote totale (mg/L) Chlorures (mg/L) Conductivite (umhos/cm) Couleur apparente (unites) Durete (mg/L) Fluorures (mg/L) Nitrites (mg/L) Nitrates (mg/L) PH Phenols (mg/L) Sulfates (mg/L) Sulfures (mg/L) Turbidite (FTU) Ca Fe Mg Mn Ana1ystes:Michel Blais Andrbe Soucy I Danihle Prkvost Rbsul tats Laboratoires Iaschem Inc. 184, chemin Freeman Hull, Qc. Rapport de laboratoire Fondex Lt6e (1-0236) a/s Diane Myrand 123 Jean-Proulx Hull, Qc. Point du prklPvement : Orignal, Real Estate Identification de 1'6chantillon : 900028 R6ference: 0-A505 Resultats Tableau: Analyses chimiques d'6chantillons d'eau. (90-0028) Param&tres d'analyse Ca (mg/L) Fe (mg/L) Mg (mg/L) Mn (mg/L) K (mg/L) Na (mg/L) Alcalinitk (mg/L en CaC03) Azote ammoniacale (mg/L) Azote totale (mg/L) Chlorures (mg/L) Conductivite (umhos/cm) Couleur apparente (unites) Durete (mg/L) Fluorures (mg/L) Nitrites (mg/L) Nitrates (mg/L) PH Ph6nols (mg/L) I Sulfates (mg/L) Sulfures (mg/L) Turbidit6 (FTU) Ana1ystes:Michel Blais Resultats LAB REPORT NO.: ACC UTEST I 146 Colonnade Rd.. AO-0049 LABORATORIES LTD. Suite 202. Nepean. Onlario K2E 7Y3 (613) 727-5692 REPORT OF ANALYSES 1 Date: A t t n : Diane Project: J a n u a r y 11, 1990 .Iient: I I I1 ( Sample Units Parameter Fe mg/L Mn mg/L Hardness mg/L CaCO, Alkalinity mg/L CaCO, 1 - 1 Sample 1 - 2 Sample 2 - ()-A505 Sample 1 2 - 2 Sample 3 - 1 PH ;onductivity ) I I I I I I I I I FONDEX LTEE umhos mg/L mg/L Na T----------mg/L N-NO2 mg/L N-NH3 mg/L so4 mg/L CL mg/L Phenols mg/L Turbidity NTU Colour Pt/Co Unlts Ca mg/L - ~ g mg/L Tannin & Lignin mg/L Total Nitrogen mg/L K mg/L <1.0 <1.o <1.o - --- ANALYST: <1 .o <1.o LAB REPORT NO.: ACCUTEST I A0-0049 LABOAATOR~ESLTD. 146 Colonnade Rd. Suile 202. Nepean. Ontario K2E 7Y3 (613) 727-5692 REPORT OF ANALYSES I I I I I I I I I I I I I m I I Client: Attn: Diane Sample Sample Units Parameter Fe .Mn Hardness Alkalinity Date: January 11, 1990 Project: 0-A505 Sample Sample Sample 3 - 2 mg/L mg/L mg/L CaCO, mg/L CaCO, PH Conduct~vity - F umhos mg/L mg/L - N-NO3 mg/L N-NO2 mg/L N-NH3 mg/L SO4 mg/L cL mg/L Phenols mg/L Turbidity NTU Colour Pt/Co Units Ca mg/L Mg mg/L Tannin & Lignin mg/L Total Nltrogen mg/L K mg/L -- - -- <1.0 - -- ----- --- - #;r ANALYST: // J LAB REPORT NO.: I I I I ACCUTEST AO-0182 LABORATORIES LTD. 146 Colonnade Rd.. Suite 202. Nepean. Ontario K2E 7Y3 (613) 727-5692 REPORT OF ANALYSES Client: Fondex Ltee Date: Attn: Ms. D i a n e M y r a n d Project: Sample Unlts Parameter 2-3 F e b r u a r y 6, 1990 OA 505 Sample Sample Sample 2-4 2-5 2-6 3-3 Sample Fe mg/L 0.05 <O .05 <0.05 <O .05 0.05 Mn mg/L <O .05 <O .05 <0.05 <0.05 0.21 Hardness mg/L CaCO, Alkalinity mg/L CaCO, PH Conduct~vlty umhos F mg/L Na mg/L N-NO3 mg/L N-NOp mg/L N-NH3 mg/L so4 mg/L CL mg/L Phenols mg/L Turbrdity NTU 26 .O 1.4 2.0 <1.o <1.O Colour Pt/Co Units 2 <2 <2 <2 <2 Ca mg/L Mg mg/L Tannin & Lignin mg/L Total Nltrogen mg/L K mg/L -- -- - - --- - - -- - - ANALYST: LAB REPORTNO.: I ACCUTEST LABORATORIES LTD. 146 Colonnade Rd. Suile 202. Nepean. Onlario K2E 7Y3 I I I Ao-0182 (613) 727-5692 REPORT OF ANALYSES Client: Fondex Ltee Date: February 6 , 1990 Attn: M s . Diane Myrand Project: ) A 505 Sample I 1 I I,, I I I I I I I I Parameter Units Sample Sample Sample Sample 1-3 Fe mg/L (0.05 Mn mg/L 0.10 Hardness mg/L CaCO, Alkal~n~ty mg/L CaC03 PH Conductivity - , umhos mg/L mg/L N-NO3 mg/L N-NO2 mg/L N-NH3 mg/L so4 mg/L CL mg/L Phenols mg/L TUrbldity NTU 1.9 Colour Pt/Co Units 2 Ca mg/L Mg Tannin & Lignln Total N~trogen K - mg/L mg/L mg/L -mg/L- - - - --- ---- - - -- -- ----- ---- - -- - ANALYST: -- APPENDIX "C" Recommended Procedure For the Cementing in-Place of a Production Line Casing on Water Wells RECOMMENDED PROCEDURES FOR THE CEMENTING IN PLACE OF A PRODUCTION LINE OF CASING ON WATER WELLS The annular open space on the outside of a well casing is an area where undesirable surface water and contamination may gain access to a well. One of the most satisfactory ways of eliminating this hazard is to fill this annular space with neat cement grout. To accomplish this it is important to see that: 1. the grout mixture is properly prepared, 2. the grout material is placed in one continuous operation, 3. the grout material is placed upwards from the bottom of the space to be grouted. Neat cement grout should be a mixture of cement and water in the proportion of 100 lbs. of cement to 5 or 6 gallons of clean water. Care should be taken to avoid using excess water as it has a weakening effect on the cement strength. Hydrated lime to the extent of 10% of the volume of cement may be added to make the grout more fluid and thereby more easily pumped. Mixing of cement or cement and hydrated lime with water must be II I thorough. Sand to the extent of not more than two parts (by weight) of sand to one part of cement may be used if the area to be filled is substantial. GROUTING PltOCEDUItE Before starting the operation, all materials should be on hand and assistance should be available, to accomplish grout placement without interruption. It is recommended that the minimum clearance at any point, including couplings, should not be less than 1 1/2 inches (3.81 cm). As the grout moves upward it usually picks up some loose material in the annular space, therefore it is desirable to waste a quantity of the grout which first emerges from a drill hole. In grouting a well there are five general procedures that may be followed: Gravitv Filling Under some conditions, placement by gravity is practical and satisfactory. Gravity installation without the aid of a tremie or grout pipe should not be used unless the interval to be grouted can be seen clearly. In no instance should it be done beyond 30 feet (9.14 m) of depth. Only by visual observation can there be assurance that grout introduced in this way is properly and uniformly distributed and properly tamped in place from surface. 2. Tremie Method Grout material can be placed by tremie pouring after sufficient water or other drilling fluid has been circulated in the annular space to clear obstructions. The tremie method should only be used where there is a minimum annular space of 3 inches (7.62 cm) between the outside of the inside casing and the inside surface of either the outer casing or the bore hole. The minimum size of tremie pipe should be 2 inches (5.08 cm) inside diameter. When making a tremie pour, the tremie pipe should be lowered to the bottom of the zone being grouted, and raised slowly as the grout material is introduced. The tremie pipe should be kept full continuously from start to finish of the grouting procedure, with the discharge end of the tremie pipe being continuously submerged in the grout until the zone to be grouted is completely filled. 3. Pump Placement - Exterior of Casins Method Grout materials can be placed by a pumping method only after sufficient water or other drilling fluid has been circulated in the annular space to clear obstructions. The grout is released in the annular space between the inner and outer casing or the inner casing and the bore hole. The grout pipe should have an inside diameter of at least 1 inch (2.54 cm). Grout should be placed from bottom to top in one continuous I I I I operation. The grout pipe may be slowly raised as the grout is placed but the discharge end of the grout pipe should be submerged in the grout at all times, until grouting is completed. In the event of interruption in the grouting operation, the bottom of the pipe should be raised above the grout level and should not be resubmerged until all air and water have been displaced from the grout pipe and the pipe has been flushed clear with clean water. 4. Pump Placement - Throuah the Casina Method (a) With the casing suspended at least 16 inches (40.6 cm) from the bottom of the hole, grout can be placed by the 2-plug cementing method, after sufficient water and/or drilling fluid has been circulated in the annular space to clear obstructions. The first spacer plug ( 8 inches (20 cm) to 12 inches (30 cm) long), which should be drillable such as a plaster-type material, is inserted in the casing and the casing recapped. A measured volume of grout which should be of sufficient quantity to grout the casing in place is pumped in through the cap. The casing is then uncapped, a second plug is inserted, and the casing recapped. A measured volume of water (slightly less than the volume of the casing) is then pumped into the casing above the top plug pushing it to the bottom of the hole, forcing the grout out the bottom of the casing and up into the annular space. The water in the casing should be maintained for a minimum of 24 hours or until the grout has set. Once the grout has fully set, the plugs are drilled out and drilling resumed. (b) A similar procedure is also used whereby no lower plug is installed. In this case the casing need only be suspended about 8 inches (20 cm) off the bottom . A sufficient quantity of grout is pumped into the casing (filling from the bottom upward) to fill the annular space. A plug is then placed in the casing, the top of the casing capped and a measured volume of water, slightly less than the volume of the casing, is pumped into the casing above the plug pushing it to the bottom, forcing the grout out the bottom of the casing and upward into the annular space. Again, the water in the casing should be maintained until the grout has set, at which time the plug is drilled out and drilling resumed. A third variation to this method is to discharge a small quantity of grout (sufficient to fill the bottom 5 feet (1.5 m) of the hole) with the casing suspended off bottom about 8 inches (20 cm) following which the casing is filled to surface with water leaving the 1 inch (2.54 cm) grout pipe submerged in the grout at the bottom. The top of the casing is then capped and the pumping of grout continued. The water pressure in the casing forces the grout to move out the bottom of the casing and up the annular space to surface. Again the water in the well should be maintained until the grout has set. After the grout has fully set, continuation of drilling can Ccxnmence. (d) Also available to assist with the installation of grout down through the casing are drillable float shoes for attachment to the bottom of a casing (devices fitted with check valves). The grout pipe is threaded into the float shoe and the grout pumped directly through the bottom of the casing and upward though the annular space until it reaches the desired level. Upon completion the grout pipe is unthreaded from the float shoe, removed from the well and flushed clean. After the grout has fully set the float shoe is drilled out and drilling resumed. 5. Grout Dis~lacementMethod The hole is filled with the estimated volume of grout required to fill the annular space. The casing, fitted at the bottom with a drillable plug, is lowered through the grout to the bottom of the hole. Centering guides, welded to the outside of the casing are also recommended to assure proper centering of casing in the hole. If necessary, to maintain the bottom of the casing at the bottom of the hole, the casing should be filled with water. In some cases it may also be necessary to apply additional load inside the casing with drill rods or drill bar (to firmly hold it on bottom and vertical). The load should be maintained until the grout has set, after which the plug in the bottom of the casing is drilled out and drilling continued. This method is only recommended for wells not more than 100 feet (30.5 m) deep. Conclusion It is recommended that grout be allowed 3 to 7 days to set before the well is completed and the pump installed. A waiting period of 24 to 36 hours is required if quick-setting cement is used (this varies with types of cement). II I Whether grouting between two casings or a casing and the bore hole wall, a clearance of at least 1 1/2 inches (3.81 cm) completely surrounding the pipe is recommended. Diagrams of the different methods are attached, I m I I I I I - t n l Attach. 2. TAEMIE METHOD 1. GRAVrrY RUING I *-, TAMRNG PIPE \II GROVT DUMPED IN BY HAND 1 I I v- GROUT I ' TREWE RPE OR URGER DRILLED H a € . DIA. A T LEAST ' 3 URGER THAN WELL CASING AT LEAST 5' U R G E R WELL CASINO -. - IF A CAVING FORMATION IS -ENCOUNTERED AN OUTER wa CASING SHOULD BE INSTALLE 11 (::;!$ . . .. t~--------i ---- NOH-CAVING F ~ + ~ ~ A T I ~ ~ - - - ~ - ~ ~ CASING WEIGHTED WITH WATER OR MU0 FLUID CASING WEIGHTED WIT\ WATER OR MUD FLUD CASING RESTS THE B o n o M - w CEUEN1 GROUT CASING RESTS ON THE B O l 7 0 h The annL.al soace IS cemenlea by OOullnp ~ " o uInrougn l r Dope lorere# 'n Ibe 171u(a1 smce hllstar the ca$,ng Tne woe .s er~seaQurlnp tee 00~1. ho-evet ne o ~ x n a r q eend must @ c u matwars suomer~ea (he annulat soace IS -~JVICO BY mmoonp tnt cement g@out1.e.n surlace and l a m ~ n pQINIV a n D O ~ C Ct t m sur(ace Should onlv M used to cement m 30. or less 01 cavnp 3. PUMP PLACEMENT-EXTERIOR OF CASING METHOD GROUT DRILLED HOLE. DIA. A T LEAST 3" LARGER l h A N W€LL CASING . Y.ELL CASING C \SING WEIGHTED W T H WATER OR MUD FLUID I . - CEMENT GROUT CRILLABLE PLUG The annular soace cemnle4 by lOWled annutar apace ovtrac me c a m p IS m n Q Q f O d WOu@ 1P W m me 4. PUMP PLACEMENT-THROUGH THE CASING METHOD 4.(s) TWO PLUG PROCEDURE GATE VALVE OPEN VALVE CLOSED CEUENT GROW WATER OR MUD F L U 0 tST SEPARATM PLUG 2ND S E W T O R PUKi WATER OR MUD FLUID CEUENT GROVI IST SEPARATOR P L W 4.(b) ONE PLUG PROCEDURE I 1 VALVE CCOSED UNTIL GROW SETS I R U D , SEPARATOR RLG CEMENT OROVT 1ND STEP Ahrt swnvnnt growl ta pwmooa Inlo the lower pa11ot IM crsng r plug 8s m o v e d aorn b y l ~ u d POUUIO m o v e I U C ~ mo c r m n t grout mlo t~ onnutat space 9 I 4. PUMP PtACEMEKT -THROUGH THE CASING METHOD I (~ont'd.) 4 . t ~ ) NO PLUG OPEN END CASING PROCEDURE S T W I N O BOX OA WELL SEAL USED TO PERUIT Llf TIN0 OF GROUT PIPE b 3 L L E O H&E DIA. A 1 LEA f' LARGER T H A N WILL C WELL CASING FLUSHED CLEAN CASING CILLED WITH WATER OR uyg FLUID GROUTING C O U R E T E D .I G*uul 6 tvwtnt*ral @8v,-**,a~~* S I I ~ flu* d l c * u # s ~ .ttm*.I Vlulrr ;lad II@W~ . .11 I*IW I., *.t.,t* ~v,oul1.w ,,I t-~t~,"n .I ~ua,.-k.r UJ, r %n*41 la I~~#IIIUC~IIIIU~",II a)#u,,~ w l * r l : ~ ~ t ~ *10~.8 ~I~*I~&~UI ~,. ' l ~ ~ l >l1lW .I8 Ih' l M l l l l V I l OI lhl. CDSm(1 l $ r e ~ ,r.ul r m l m ~II@IUI.~ ~P.>I F WATER II,.~I APPENDIX "D" Treatment Devices For Some Common Water Quality Problems Extract from "Water Wells and Groundwater Supplies in Ontario" Environment Ontario Publication Second Reprinting, 1989 8. HOME TREATMENT DEVICES FOR SOME COMMON WATER QUALITY PROBLEMS HARDNESS Hardness or "hard water" as it is frequently called is a common characteristic of ground water in most areas of southern Ontario. Ground water as it moves through limestone bedrock or carbonate-rich overburden dissolves calcium and magnesium compounds which cause hardness. High hardness is a nuisance resulting in a scale formation on kettles, it prevents soap from lathering and it can result in a dingy laundry. Two common water-treatment processes exist which can be used as corrective measures; these are water softeners and soluble phosphate additives. Water Softeners In a softening unit (Figure 19), hardness is removed from water by a process called ion exchange. Water flows over an ion exchange resin (synthetic zeolite) that is charged with sodium ions. The calcium and magnesium ions in the water are traded for sodium ions, thus making the water soft. When most of the available sodium ions in the exchange resin have been replaced by calcium and magnesium, the unit must be regenerated with brine (concentrated salt solution). Some of the newer water softeners are fully automatic and regenerate themselves on a predetermined time cycle. Softeners are available in many sizes. Sizing is determined by the amount of water used, the hardness of the water and the frequency of regeneration. Figure 19. Water Softener Greensand Filters Water softeners increase the sodium content of the water up to 46 mg/L sodium for each 100 mglL of hardness removed. Those individuals on a low sodium diet or with high blood pressure (hypertension) or heart disease should consult their physician before drinking softened water on a daily basis. Greensand filters are an effective means for removing iron and manganese concentrations of up to 5-10 mg/L. The greensand media provides oxygen to the water passing through it. This oxidizes these metals resulting in their precipitation and filtration by the greensand. These filters need to be backwashed and have their oxygen supply regenerated on a regular basis in order to ensure their continued effectiveness. This is achieved by flushing with a large volume of water and then rinsing the greensand with a solution of potassium permanganate. Soluble Phosphate Additives Phosphate additives are available for water softening. These softeners are added to hard water to prevent it from reacting with soap or detergent to form a scum. These softeners help keep the carbonates in their dissolved form rather than remove them and thus a scale can still form in kettles, etc. The well water system must be able to provide large volumes of water to backwash the filters. If such volumes cannot be provided it will be necessary to use one of the other treatment methods. The presence of iron or methane organisms in the water can cause a slime buildup on the greensand reducing its effectiveness. It may be necessary to chlorinate the water before it enters the filter to kill the bacteria. IRON AND MANGANESE Ground water frequently contains iron and manganese in a colourless, dissolved form. Concentrations of iron in excess of 0.3 mg/L and manganese in excess of 0.05 mg/L are of concern for aesthetic reasons (see Table 5). When iron and manganese solutions come in contact with air (oxygen), the iron and manganese precipitate. This results in the staining of plumbing fixtures and laundry, and in discoloured or "rusty" water because of the presence of flakes of these metal oxides. Manganese stains are usually a blacker brown than those of iron and may be further distinguished by their ready solubility in mildly acidified hydrogen peroxide. Even a 50-50 mixture of vinegar and drugstore peroxide will remove the stains. Stronger reagents such as those for cleaning water softener resins may be needed for iron stains, particularly if they have been dried, heated or are considerably aged. Polyphosphate or Silicate Additions Polyphosphate is effective in controlling iron and manganese concentrations of up to 2-5 mg/L. A concentrated solution of polyphosphate is added to the water supply by a chemical feeder. The polyphosphate stabilizes the metals, thus preventing them from oxidizing and coming out of solution. There are two limitations to this method; first it will only prevent the metals' ions which have not as yet been oxidized from oxidizing and second, the polyphosphate may break down when the water is heated in a water heater, thus reducing the effectiveness of the polyphosphate. Silicate solution addition works similarly. but requires a simultaneous chlorine treatment to work effectively. Treatment using liquid silicates with a ratio of 3.25 Si O,/Na, 0 can achieve better stablization as is often the case with municipal supplies. Several methods are available which either remove or control these metals - some of these are discussed below. Water Softeners Aeration and Settling or Filtration This method involves aerating the water in order to oxidize the iron and manganese, thus causing them to precipitate. The resulting precipitate is then either allowed to settle in a tank or is removed by filtering. This method is very effective; however, it may require additional chlorination to cope with excess bacteria introduced by aeration effects. J i Water softeners will remove concentrations up to 2 mglL of iron and manganese from the water. it is necessary to maintain the metals in their dissolved forms, by keeping the oxidation to a minimum, otherwise the softener will rapidly become clogged. For this reason, it usually is preferable to remove iron and manganese from the water before it enters the softener. Should resins become filled with these minerals. proprietary formulations containing dithionate and bisulphite chemicals may be obtained for occasional resin bed treatment to restore the operating capacity. should not be used for mixing formula for bottle-fed infants under 6 months. Chlorination-Filtration Units When the concentration of nitrate is high, the source of the problem should be identified and remedial measures taken wherever possible. Remedial measures may involve removing the source of the nitrates, providing better well protection and maintenance or possibly having a well replaced. Chlorine is a strong oxidizing agent and also acts as a disinfectant. The addition of a chlorine solution to the water will oxidize the iron and manganese causing it to precipitate. The water must then be passed through a filter such as sand to remove the metal precipitate. Wherever chlorine tastes and odours need removal, a bed of activated charcoal can be used following iron and manganese removal. Chloride, sulphate and nitrate can be removed from the water supply by various demineralization processes, one of which is reverse-osmosis. CHLORIDE, SULPHATE AND NITRATE Reverse-Osmosis Units Ground waters with chloride and sulphate concentrations in excess of 250 mglL and 500 mg1L respectively, and nitrates in excess of 10 mg/L as nitrogen are not desirable for domestic water supplies. High chloride concentrations are readily identifiable by a salty taste in the water. Drinking water with high chloride concentrations is not harmful to health; however, high chloride concentrations are nearly always accompanied by high sodium concentrations. Individuals on a low sodium diet or with high blood pressure (hypertension), renal, or heart disease should consult their physician before consuming water on a daily basis with sodium concentrations over 20 mglL. In a reverse-osmosis unit, mineralized water is forced through a semipermeable membrane. The membrane passes fresh water the minerals are left behind. These units are generally expensive and will only treat a few litres of water per day, enough for drinking and cooking. If a larger supply of water is needed, it may be necessary to either find a new water source, or else add additional treatment units to the system. High sulphate concentrations in water produce harsh tastes and can have a laxative effect for individuals who are not accustomed to such waters. High nitrate concentrations in water are often indicative of pollution. Nitrate is produced by bacterial action on human and barnyard waste, by fertilizers and by the decomposition of plant matter. The presence of fecal coliform bacteria in the water in addition to nitrate indicates that the source of nitrates is likely septic tanks, or cesspools or barnyard wastes. High nitrate content may cause an oxygen-starved condition in bottle-fed infants under 6 months known as methemoglobinemia. The Ministry of the Environment publication "Ontario Drinking Water Objectives" states that: "Nitrate poisoning from drinking water appears to be restricted to susceptible infants; older children and adults drinking the same water are unaffected. Most water-related cases of methemoglobinemia have been associated with the use of water containing more than 10 mglL nitrate (as N)." Well water with 10 mglL or more of nitrate - BACTERIA, PROTOZOA AND VIRUSES Only a few of the many different kinds of bacteria, protozoa and viruses are pathogenic (diseasetausing). Ground water for the most part does not contain any of these harmful organisms unless it has become polluted by surface water or seepage from sewage facilities. Well contractors are required under Ontario Regulation 612184 to seal the upper portion of wells so that surface water or seepage from septic tanks, privies or cesspools cannot enter the well. Many wells, particularly those that are dug or bored become polluted because the upper portion of the well between the casing and the borehole is not carefully sealed. For additional information on sealing the annulus of wells (see Section 9 and Figures 3a and 3b). The procedure for verifying whether your well water is bacterially safe to drink is discussed under the headings "Microbiological Analyses" (Page 55) and "Interpretation of Microbiological Analyses" (Page 58). If the source of the contamination appears to be septic tank effluent or barnyard wastes, an alternative source of water supply should be found or a commercial water purifier should be installed. The user is cautioned that such waters may also contain high nitrate concentrations. This should be verified especially where there are infants in the household. The equipment used to disinfect drinking water is discussed below. chlorine is usually recommended. Chlorination-filtration units are effective in controlling iron bacteria in the distribution system. Following the installation of a water treatment unit, the water should be retested to ensure that the unit is working properly. Hydrogen sulphide is a gas that can be recognized by its disagreeable "rotten-egg" odor. Water containing hydrogen sulphide is also corrosive and will attack the plumbing system. HYDROGEN SULPHIDE AND SULPHATE-REDUCING BACTERIA Home Water Treatment Devices The Ministry of the Environment has published a guideline entitled "lnformation on the Use of Home Water Treatment Devices" which discusses the integrity of water treatment devices and their claims for removal of health-related contaminants in drinking water. This guideline and a "companion" consumer bulletin sheet entitled "Water Fit to Drink" .are available from your nearest office of the Ministry of the Environment. The bulletin sheet may also be obtained from the Ministry of Consumer and Commercial Relations. IRON BACTERIA lron bacteria occur in ground water. They are non-injurious to health but are nuisance organisms that can cause plugging of water-bearing formations and well screen openings. lron bacteria can be transported on drilling tools from one location to another. Well contractors are required to disinfect all new wells they construct and they should chlorinate any water used in preparing drilling fluids or in other construction purposes associated with the well. lron bacteria produce accumulations of slimy clogging masses and cause the precipitation of iron and manganese. The combined effect of the growth of these organisms and the deposition of iron can completely plug a well screen in a relatively short time. Chlorine is an effective means of controlling iron bacteria. The chlorine kills the bacteria destroying the slime deposits on the well screens and in the surrounding aquifer but at a very slow rate, so prolonged exposure times are required (see Appendix E for instructions on chlorinating an existing well). Unfortunately, iron bacteria are difficult to eradicate permanently and treatment of the well may have to be repeated periodically. To rid a well of iron bacteria, you may have to hire a well contractor who is experienced in handling strong solutions of chlorine. Shock chlorination of the well with at least 500 mglL available Some ground water which contains natural concentrations of sulphate may also contain sulphate-reducing bacteria. These bacteria change the sulphate to corrosion-promoting hydrogen sulphide. Such sulphide may directly create substantial thicknesses of air-corrodable sulphides out of contacted metal surfaces, and may also revert back :o corrosive sulphuric acid at susceptible air-interface surfaces. The formation of hydrogen sulphide and sulphuric acid makes the water more corrosive and speeds up the attack on metals. Sulphate-reducing bacteria favour warmth and require no oxygen to live (anaerobically). Since hot water contains less oxygen than cold water, the bacteria can infest hot water tanks. Their presence can be suspected if a hydrogen sulphide "rotten-egg" odor is noted coming from the hot water taps only. Chlorination-filtration is a satisfactory way of removing hydrogen sulphide from water (see lron and Manganese, Page 62). The chlorine oxidizes the hydrogen sulphide and forms a precipitate of sulphur; it also removes any sulphur bacteria present in the water. The sulphur precipitate is removed by a sediment filter and excess chlorine in drinking water is removed by an activated carbon filter. These bacteria and hydrogen sulphide may also be removed by superchlorination followed by dechlorination with a carbon filter. Bubbling air through the water and splash aeration (running water over baffles while it is exposed to the air) also helps to get rid of the hydrogen sulphide odor. Table 7 from the Water Well Journal (July, 1979) presents advantages and disadvantages of various methods of treating hydrogen sulphide. TABLE 7: CONVENTIONAL HYDROGEN SULPHIDE TREATMENT METHODS (WATER WELL JOURNAL JULY, 1979) - METHOD ADVANTAGES DISADVANTAGES Oxidizing filters (potasium permanganate) "greensand" filters Can remove up to 6 mglL of sulphide Sulphur clogs filter Chlorination Quick and effective Well contamination from the leakage or spillage of petroleum products is an extremely difficult and expensive problem to rectify because of the following characteristics of petroleum products: 1. They are relatively stable and will not readily decompose in the subsurface. 2. They are capable of travelling long distances with ground water, both Extra equipment needed. Potentially corrosive water produced. Chlorine residual taste. - Ozonation Quick and effective Aeration No chemicals required Prolonged contact times. second tank required for repressurizing water. Space required for aeration units. Must be protected from freezing. Activated carbon filtration GASOLINE AND OIL Removes mild taste and odor problems caused by H,S Hiah initial cost Useful only in concentrations less than 1 mglL as a liquid and in solution. 3. They will adhere to soil particles and be released only slowly by the flushing action of infiltrating precipitation. 4. They will release explosive vapors which for example are a concern when handling contaminated materials. Small quantities of a petroleum product in water will affect its taste and odor and render it unfit for use. The best solution to this problem is one of prevention. Where a leak or spill occurs or should a petroleum-like taste or odor be detected in a water supply, it should be reported immediately to the local Ministry of the Environment Regional Office. Depending on the local hydrogeology, the volume involved and the hydrocarbon concentrations, clean-up procedures can be very elaborate and costly. They may involve the excavation and removal of the contaminated soils to an approved landfill site or they may simply involve adding an activated carbon filter to the water distribution system. In many instances, maintaining aerobic conditions by frequent intermittent aerations down the well has been found useful for accelerating decontamination from hydrocarbon products. GAS (METHANE) Many water wells, particularly in southwestern Ontario, yield water containing some natural gas. Natural gas escaping into an enclosed well pit or pumphouse has been known to cause explosions and fires. A well containing natural gas should be sealed at the top and fitted with an air vent that dispels the gas into the atmosphere. The vent should be at least 2.5 metres above ground level. . Sometimes, if a strong flow of natural gas is encountered, it is necessary for well contractors to leave the well site for a short period during which time the gas is allowed to flow to the atmosphere unrestricted. Signs warning of the presence of explosive gas should be posted at the site. The presence of natural gases in a well should be recorded by the well contractor on the Water Well Record. Natural gas may also cause well pumps to lose their prime. A gas separator diverting gas away from the pump intake will protect the pump and improve its operation (Figure 20). In addition, because all the gases may not be released immediately in the well, it may be necessary to vent the pressure tank, hot water tank or water treatment devices to the atmosphere to prevent a buildup of gases within the distribution system. Unreleased methane gas may impede oxidative water treatment processes i.e., the fouling of iron and manganese filtration units. The use of aeration and activated carbon filters will remove any gas which may enter the distribution system. Considerable care should be taken whenever work is done on a well that produces gas because of the possibility of an explosion. SUBMERSIBLE PUMP Gas in Shroud Figure 20. Gas Separators TURBIDITY In some new wells the water is turbid or cloudy. This results from a fine suspension of clay, silt or organic matter in the well water. The particles should eventually settle to the bottom of the well. Pumping the well will develop it further and the problem should disappear. Where turbidity persists, it may be necessary to add a filter to remove the fine particles. Filters Sand and diatomite filters are commonly used to remove finegrained particles in water. A diatomite filter consists of a filter cake of diatomaceous earth. Water is forced through the filter removing all turbidity. The filter should be backwashed regularly to maintain its effectiveness. Other filters which are used include, carbon cloth, porous stone, and paper. These filters come in cartridges which can be added to the water lines. The cartridge is replaced periodically. Most water conditioning companies carry a variety of filters and are a good source of information on turbidity related problems. APPENDIX "El' - TESTING & INSPECTION CONCRETE ASPHALT GEOTECHNICAL SPECIALISTS STEEL I I I I I I LC-., SOILS PILING SLOPES -I'ONIIEX CONSULTING ENGINEERS SUBSOIL INVESTIGATION ESTATE RESIDENTIAL LOTS LAFRENIERE ESTATES L'ORIGNAL, ONTARIO u I I I I I ' PREPARED FOR L ' ORIGNAL REALTY COMPANY PROJECT NO. : 0-561 7-S APRIL 2, 1981 1 124 CUMMINGS AVENUE, OTTAWA, ONTARIO K l J 7R8 TELEPHONE 746-1 122 . TABLE OF CONTENTS I I I I I I PAGE SUMMARY 1 1. S I T E AND PROJECT DESCRIPTION 3 2. F I E L D WORK AND SUBSOIL 3 3. RECOMMENDATIONS 4 APPENDIX It? I I I I I I I - APPENDIX ' A ' - Table I APPENDIX ' B ' - The E n v i r o n m e n t a l P r o t e c t i o n Act, 1971 S I T E PLAN Summary o f T e s t P i t D a t a DWG. 1 Page 1 SUMMARY The proposed r e s i d e n t i a l development i s low l y i n g a t t h e south boundary, then r i s e s g e n t l y t o a h i g h p o i n t j u s t n o r t h o f Jacquot Street, f o l l o w e d by a g e n t l e downward slope towards t h e northern boundary. Groundwater f l o w and surface water drainage i s t o t h e Ottawa River from t h e h i g h p o i n t north. Drainage of the south s i d e o f t h e p r o p e r t y i s i n a south w e s t e r l y d i r e c t i o n t o a water course'adjoining t h e r e a r o f t h e lots. The water course u l t i m a t e l y empties i n t o t h e Ottawa River. The s u b s o i l i s predominantly t o p s o i l o v e r l y i n g s i l t t i l l . A sand l a y e r was encountered between t h e topsoi 1 and s i 1t t i 1 1 i n t h e c e n t r a l higher p o r t i o n o f t h e s i t e . S i m i l a r l y , an intermediate c l a y l a y e r was found i n t h e southeast corner. Shallow bedrock was encountered i n the southern p o r t i o n and i n the northeast area. The permanent water t a b l e could n o t be e s t a b l i s h e d because o f Spring thaw c o n d i t i o n s a t t h e time of undertaking t h e f i e l d work. A normal t i l e f i e l d i n s t a l l a t i o n i s envisaged f o r most o f the s u b d i v i s i o n l o t s . The recommended p e r c o l a t i o n r a t e f o r t h e s i l t t i 1 1 i s t = 40 minutes, w h i l e t h e recommended r a t e f o r c l a y s u b s o i l s i s t = 60 minutes. Raised t i l e beds i n areas of shallow bedrock should be constructed o f well-graded f i n e t o medium sand. r a t c f o r imported sand i s t = 15 minutes. The recommended p e r c o l a t i o n Page 2 The above p o i n t s a r e described i n d e t a i l i n t h e f o l l o w i n g report. Page 3 I 1. SITE AND PROJECT DESCRIPTION 7 I I I I I t i s understood t h a t r e s i d e n t i a l l o t s w i t h an area exceeding one h a l f hectacre a r e t o be developed i n t h e area known as L a f r e n i e r e Estates i n t h e Town o f L ' O r i g n a l , Ontario. South of Lecours Street, t h e l o t s a r e wooded b u t t h e l a n d i s low l y i n g and wet. However, n o r t h o f Lecours S t r e e t t h e l a n d r i s e s g e n t l y t o a h i g h p o i n t on t h e east-west l e g o f Jacquot S t r e e t then drops o f f g e n t l y towards F r o n t S t r e e t . The groundwater f l o w and surface water drainage w i l l be n o r t h towards t h e Ottawa River, n o r t h of the p o i n t of h i g h l a n d and t h e f l o w w i l l be i n a south w e s t e r l y d i r e c t i o n t o a water course a d j o i n i n g t h e r e a r o f t h e l o t s south o f Lecours S t r e e t . U l t i m a t e l y , the water course empties i n t o t h e Ottawa River. A s u b s o i l i n v e s t i g a t i o n was undertaken t o e s t a b l i s h t h e I I I I s u b s o i l c o n d i t i o n s r e l a t i n g t o t i l e f i e l d disposal systems f o r domestic sewage e f f l u e n t . 2. FIELD MORK AND SUBSOIL The f i e l d work, which consisted of 15 backhoe t e s t p i t s t o depths i n excess o f 2000 mm o r t o refusal on bedrock, was c a r r i e d o u t on March 26, 1981. General ly, t h e 1and i s 1OW l y i n g and wet south o f Lecours Street, as a r e s u l t o f Spring r u n - o f f . Elsewhere, t h e l a n d r i s e s t o a h i g h p o i n t n o r t h o f Jacquot S t r e e t , then slopes g e n t l y downward towards F r o n t S t r e e t . Page 4 0-561 7-S The s u b s o i l i n t h e proposed s u b d i v i s i o n area i s , t y p i c a l l y , 250 mm o f t o p s o i l o v e r l y i n g very dense s i l t t i l l . The exception occurs i n the c e n t r a l p o r t i o n o f t h e s u b d i v i s i o n where a f i n e t o medium sand l a y e r o f about 500 nun i n thickness was found between t h e t o p s o i l and s i l t t i l l s t r a t a . S i m i l a r l y , a 1000 mm l a y e r o f c l a y was encountered betsween t h e above mentioned s t r a t a i n t h e southeast corner o f t h e s i t e . Shallow bedrock occurs a t t h e s o u t h end o f t h e s i t e along Lecours S t r e e t (TP #1, 2, 4), and s i m i l a r l y i n t h e n o r t h e a s t corner i n t h e v i c i n i t y o f t h e L a l i b e r t e and Davidson S t r e e t i n t e r s e c t i o n (TP #7, 9, 10). The s u b s o i l encountered a t each t e s t p i t l o c a t i o n i s described i n d e t a i l i n the Summary o f Test P i t Data, Table I,Appendix 'A'. l o c a t i o n s a r e g i v e n on t h e S i t e Plan, Dwg. 1. Test The 1ong term water t a b l e c o u l d n o t be e s t a b l i s h e d due t o the Spring thaw c o n d i t i o n a t t h e time t h e f i e l d work was c a r r i e d out. However, a s i m i l a r study c a r r i e d o u t on t h e adjacent p r o p e r t y i n d i c a t e d a water t a b l e about 1370 m below grade near t h e end of May (Fondex Report 0-5372-S, May 24, 1979). 3. RECOMMENDATIONS Based on t h e t e s t p i t data, i t i s expected t h a t f o r t h e most p a r t , a normal t i l e f i e l d disposal system can be i n s t a l l e d . Where t h e s u b s o i l c o n s i s t s o f t o p s o i l o v e r l y i n g sand o r s i lt ti 11 w i t h bedrock a t a depth o f 0-561 7-S Page 5 1500 mm o r more below grade, t h e r e w i l l be no need t o impopt sand fill f o r t h e leaching bed. The p e r c o l a t i o n r a t e recommended f o r determining t h e t i l e f i e l d requirements f o r t h e above mentioned c o n d i t i o n s i s t = 40 minutes. Where bedrock was encountered a t a shallow depth (TP # I , 2, 4, 7, 9, lo), i t w i l l be necessary t o p r o v i d e a r a i s e d leaching bed t o comply w i t h t h e requirements of t h e Environmental P r o t e c t i o n Act, 1971. Among o t h e r things, Clause 21 o f t h e Act s t a t e s t h a t a r a i s e d t i l e bed i s r e q u i r e d where bedrock, water t a b l e o r impervious s o i l i s encountered w i t h i n 1500 mm o f the e x i s t i n g grade anywhere i n t h e t i l e bed area. For t h i s information, and o t h e r design data you may require, t h e Act has been reproduced and i s included i n Appendix ' B ' of t h i s r e p o r t . The sand imported f o r t h e r a i s e d t i l e bed should be w e l l d r a i n i n g s o i l i s n o t acceptable. A coarse f r e e - and 10 -5 cm/sec. graded, w i t h a p e r m e a b i l i t y o f between For design purposes, a r a i s e d t i l e bed may be designed using a p e r c o l a t i o n r a t e t - 15 minutes. For t h e low l y i n g l o t s i n the area of Lecours Street, some l o t s w i l l r e q u i r e a r a i s e d t i l e bed due t o t h e presence of bedrock a t a r e l a t i v e l y shallow depth. I n areas where shallow bedrock was n o t encountered and adequate surface drainage w i l l be a v a i l a b l e , i t w i l l be p o s s i b l e t o provide a normal t i l e f i e l d installation. However, i n t h e c l a y s o i l s , i t i s reconmended t h a t a p e r c o l a t i o n r a t e t = 60 minutes be used t o estimate t h e t i l e f i e l d requirements . -. . .. ;,b C l i e n t (4) % ., .3 .- r - . *>,.,- . 1 3 .1 ,-. < ,,' - r-: ., r L J ' I. , ., APPENDIX ' A ' TABLE I SUMMARY OF TEST P I T DATA Page 1 APPENDIX ' A ' SUMMARY OF TEST PIT DATA TABLE I LAFRENIERE ESTATES L'ORIGNAL, ONTARIO TEST PIT NO. LOCATION 1. l o t s 23/ 0 - 400 400-1 200 DESCRIPTION COMMENTS Topsoil w/l i n test p i t @ 1050 m depth a f t e r - S i 1t T i 11 very dense, grey, frequent limestone 2 hrs. cobbles, sandy, very moi s t/wet. 1200 Lots 21/ O - Bedrock backhoe. 200 200-600 - refusal t o Topsoil - S i l t T i 11 very dense, brown, frequent gravel Test p i t dry upon completion. sizes, sandy, moist. 600-900 Bedrock - weathered 1imes tone, refusa 1 t o backhoe. Lots 26/ 27 0 - 300 300-1375 Topsoil Surface water - S i l t y Clay very s t i f f , red/grey, f r i a b l e , very moist. 1375-2100 S i l t Till - very dense, grey, frequent gravel and cobbles, sandy and 2100 cohesive, wet. End of t e s t p i t refusal. - no entering t e s t p i t . Area i s low l y i n g w i t h pockets o f surface water. . 0-561 7-S TEST PIT NO. LOCATION 4. L o t s 20/ 21 - Page 2 DESCRIPTION 0 - 225 225-1050 Topsoil COMMENTS - very S i l t y Clay brown, f r i a b l e , moist. 1050-1600 Silt Till - very stiff, very dense, brown, clayey , frequent gravel sizes, wet. 5. L o t s 181 19 1600 Bedrock backhoe. - Topsoil 0 300 300-600 Sand - - entering t e s t p i t . Area i s low l y i n g w i t h pockets of surface water. refusal t o No f r e e water loose, brown, f i n e t o medium, moist. 600-2100 Surface water - S i l t Ti11 very dense, grey, frequent g r a v e l from t i l l stratum b u t some seepage a t sandltill contact. sizes, frequent cobbles and boulders by 1200 mm depth, s l i g h t l y cohesive moist. End of t e s t p i t - no refusal. 2100 6. L o t s 17/ 18 0 - 300 300-900 Topsoil Sand - No f r e e water loose, dark brown, f i n e t o medium, moist. 900-2100 Silt Till - very dense, grey, frequent g r a v e l and cobbles, s l i g h t l y cohesive, m o i s t . from ti 11 s t r a t u m b u t some seepage a t sandltill contact. Page 3 TEST PIT NO. LOCATION DEPTH' DESCRIPTION COMMENTS Topsoil Silt Till Water e n t e r i n g (mm> 7. Lots 61 - 0 400 400-700 - very dense, brown, occasional g r a v e l and cobbles, s l i g h t l y p i t at till/rock contact. , cohesive, wet. 700 8. L o t s 361 37 0 - 225 900 Bedrock backhoe. - refusal t o Surface i s boulder 225 Topsoil - loose, brown, f i n e Sand t o medium, moist. - 900 - 1950 S i l t T i l l - very dense, grey, frequent g r a v e l strewn. Water e n t e r i n g p i t from ti s t r a t u m a t 1450 mm depth. cobbl es and occasional boulders, very moist. 1950 End o f T e s t P i t - no refusal. 9. L o t s 415 0 - 150 Surface i s boulder Topsoil - 150-500 Sand 500-1200 S i 1t T i 11 very dense, grey, frequent g r a v e l and cobbles, v e r y moist. 1200 Bedrock compact, brown, backhoe. - - refusal t o strewn. Water e n t e r i n g t e s t p i t a1 t i l l / r o c k contact. 0-561 7-S Page 4 TEST PIT NO. LOCATION 10. L o t s 39/ 40 DEPTH 0 0 - 250 250-600 DESCRIPTION COMMENTS Topsoil Surface i s boulder S i l t T i 11 - very dense, grey, boul dery , moist. 600 11. L o t s 2/3 Bedrock backhoe. - 0 300 300-1800 - Topsoi 1 Silt Till strewn. Test p i t d r y upon compl e t i o n . refusal t o - very dense, grey, frequent cobbles b y 900 mm depth, sandy Surface i s boulder strewn. Test p i t d r y upon completion. and s l i g h t l y cohesive, moist. 1800 End of t e s t p i t - no refusal. 12. L o t s 1/2 0 - 225 225-2100 Topsoil Silt Till Surface water - v e r y dense grey, cohesive, bouldery by 900 mm depth. 13. Lots8/9 - entering t e s t p i t . No free water from t i l l stratum. no 2100 End of t e s t p i t refusal. 0-150 150-600 Topsoil Sand loose, brown, f i n e Ground surface i s h i g h w i t h areas o f t o medium, m o i s t . l o c a l i z e d pondi ng o r surface water. 600-1925 - S i l t T i 11 - very dense, grey, frequent gravel, cobbles and boul ders , moist, becoming wet by 1200 mm depth. 1925 End of t e s t p i t - no refusal. Page 5 TEST PIT NO. 14. LOCATION Lots 14/ 15 DESCRIPTION COMMENTS 0 0 - 200 Topsoi 1 Ground surface i s 200-750 Sand DEPTH - compact, brown, boul der strewn . f i n e t o medium, moist. Water e n t e r i n g p i t - from t i l l stratum. Silt Till very dense, grey, frequent g r a v e l and cobbles, s l i g h t l y cohesive, wet. End o f t e s t p i t - no refusal. 15. Lots 13/ 14 0 - 300 300-750 Topsoi 1 Sand - Water e n t e r i n g compact, brown, s i l t y , fine, moist. Silt Till - very dense, grey, frequent gravel and cobbles, wet. End of t e s t p i t refusal. - no p i t from s a n d / t i l l contact. DRAW I NG APPENDIX ' 0 ' The Environmental P r o t e c t i o n Act, 1971