Introduction Initiators

Transcription

1
Introduction
Initiators
Initiators
Initiators for high polymers
for High Polymers
3
Initiators
Initiators for High Polymers
All information concerning these products
and/or all suggestions for handling and use
contained herein are offered in good faith
Akzo Nobel,
Contents
based in the Netherlands, is a multicultural organization serving
4
and believed to be reliable. Akzo Nobel
Polymer Chemicals, however, makes no
Introduction
warranty as to accuracy and/or sufficiency
of such information and/or suggestions, as
customers throughout the world with human and animal healthcare
- Initiators for High Polymers
- Safety, Research & Development
to the product’s merchantability or fitness
for any particular purpose, or that any
products, coatings, and chemicals. We employ around 61,500
6
suggested use will not infringe any patent.
Nothing contained herein shall be
people and conduct our activities in 13 business units, with
- Half-life
construed as granting or extending any
license under any patent. Buyer must
operating subsidiaries in more than 80 countries.
- Storage temperatures
- SADT: Self-Accelerating
determine for himself, by preliminary tests
or otherwise, the suitability of these
Storage & Safety
www.akzonobel.com
Decomposition Temperature
product for his purposes. The information
- Tem: Emergency temperature
contained herein supersedes all previously
- Tc: Control temperature
issued bulletins on the subject matter
- UN Numbers
covered. The user may forward, distribute,
8
and/or photocopy this document only if
unaltered and complete, including all of its
Akzo Nobel’s Polymer Chemicals business unit, headquartered
- Standard packaging
headers and footers, and should refrain
from any unauthorized use. You may not
Packaging
in Chicago, USA, manufactures organic peroxides, metal alkyls,
- Liquid initiators
- Solid initiators
copy this document to a website.
organometallic specialties, polymer additives, and antifouling
- Additional information
© 2006 Akzo Nobel Polymer Chemicals
and suspending agents for the polymer production and
10 Product data
processing industries. Some of these products find various
28 Product survey
other applications as well. We also serve the semiconductor
30 Half-life chart
industry with high purity metalorganics.
Contact us
www.akzonobel-polymerchemicals.com
Code: 2161 BTB Communication
Issue: June 2006
4
5
Introduction
Organic peroxides are also important materials
Safety, Research & Development
in pharmaceutical and fine chemical synthesis
We have a long history in the organic peroxides arena, starting with
or as active pharmaceutical ingredient.
Thorough understanding and knowledge of free radical chemistry and
dibenzoyl peroxide for the bleaching of flour in the early 1920’s.
We are able to supply a comprehensive range
peroxide production technology is at the basis of the development
of initiators to meet all requirements with
This Akzo Nobel invention was the beginning of the production and
respect to area of application, polymerization
of new, more efficient and safer products serving customer needs.
temperature, rate of radical formation and
application of organic peroxides worldwide. Since then, many new
storage facilities.
With almost a century of experience we are your reliable and
organic peroxides have been added to our product line, with the
Listed are the highest concentrations of
innovative partner for the supply of organic peroxides.
formulations for each phlegmatizer.
growth of plastics in everyday life.
We invite you to visit us at www.akzonobel-
The Continuous Initiator Dosing (CID) venture,
polymerchemicals.com for complete product
which is a process improvement technology
listings. Formulations with phlegmatizers or
for the manufacture of PVC, is a good
concentrations other than those indicated as
example of our efforts in the field of R&D.
well as unique custom blends of various
peroxides can be made available with due
Technical support and product development
observance of safety characteristics and the
are mainly provided from laboratories in
Today, we are the world’s largest producer
appropriate environmental and transportation
Deventer - the Netherlands, Pasadena - Tx
of initiators for free radical polymerization
regulations. Please consult your Akzo Nobel
USA, Los Reyes - Mexico and Tianjin - China.
of various monomers. The main area of
account manager for your specific need.
The first is the site of the company’s
fundamental initiator R&D. In each continent
application is the manufacture of high
polymers such as acrylics, low density
We operate organic peroxide manufacturing
we have a team of Technical Development
polyethylene (LDPE), polyvinyl chloride (PVC),
sites and distribution centers all around the
Managers who are the liaison between the
controlled-rheology polypropylene (CR-PP)
world including joint ventures Ankorit -
market and R&D and facilitate the technology
and styrenics. The largest part of our
Russia, Kayaku Akzo Corporation - Japan,
transfer to and from our customers.
initiators program consists of organic
and in China Tianjin Akzo Nobel Peroxides,
peroxides (O-O initiators) which can be
Keum Jung Akzo Nobel Peroxides and Akzo
Our success in safely handling organic
divided into classes such as peroxyesters,
Nobel Crosslinking Peroxides.
peroxides is due to our long-term
peroxy(di)carbonates, diacyl peroxides,
commitment to safety.
dialkyl peroxides, peroxyketals and
All production sites are certified with ISO
hydroperoxides. In addition we supply azo
9001 and ISO 14001 in order to ensure the
The Safety Research laboratory in Deventer
(N-N) initiators and carbon (C-C) initiators.
highest product quality and strictest
participates in R&D by the development of
compliance with environmental regulations.
safe products and processes. Investigations
are performed with the objective to assure a
Akzo Nobel is a Responsible Care® company
high level of safety in manufacturing, handling
and transport of our products.
6
7
Storage & Safety
Half-life
Storage temperatures
UN Numbers
The most important characteristic of a polymerization initiator is its rate of decomposition
The Ts max. is the recommended maximum
All products accepted for transport are assigned to generic entry numbers according
expressed by its half-life (t1/2). For this reason, the initiators in this product catalog are
storage temperature at which the product is
to classification principles as described in the recommendations by the United Nations
arranged in descending order of activity, based on the 1.0 hour half-life temperature.
stable and quality loss will be minimal.
Committee of Experts on the Transport of Dangerous Goods. An explanation of all
The half-life is the time required to reduce the original initiator content at a given temperature
A minimum storage temperature (Ts min.) is
relevant UN numbers is given in table 1.
by 50%. With the exception of hydroperoxides, the half-life is determined by differential
given if phase separation, crystallization or
scanning calorimetry-thermal activity monitoring (DSC-TAM) of a dilute solution of the
solidification of the product is known to
initiator in monochlorobenzene. Kinetic data of the decomposition of hydroperoxides in
occur below the temperature indicated. For
monochlorobenzene are determined titrimetrically.
safety reasons it is also recommended to
store the product above the Ts min.
The tables in this catalog list the temperatures at which the half-lives are 0.1 hour,
indicated.
Classification of Initiators ( table 1)
UN No
Classification
type B; liquid
SADT: Self-Accelerating Decomposition
3111
type B; liquid, temperature controlled
Temperature
3103
type C; liquid
The half-life can be calculated from the
The SADT is the lowest temperature at
3104
type C; solid
Arrhenius equation
which self-accelerating decomposition may
3113
type C; liquid, temperature controlled
occur with a substance in the packaging as
3114
type C; solid, temperature controlled
used in transport. Transportation
3105
type D; liquid
temperatures are derived from the SADT
3106
type D; solid
according to the recommendations by the
3115
type D; liquid, temperature controlled
United Nations Committee of Experts on
3116
type D; solid, temperature controlled
the Transport of Dangerous Goods.
3107
type E; liquid
3117
type E; liquid, temperature controlled
Tem: Emergency temperature
3118
type E; solid, temperature controlled
The Tem is derived from the SADT and is the
3109
type F; liquid
temperature at which emergency
3110
type F; solid
3119
type F; liquid, temperature controlled
None
Non-dangerous good
kd = A · e
-Ea/RT
and t / = ln2/kd
1
2
where
kd = rate constant for the initiator
dissociation in s-1
= Arrhenius frequency factor in s-1
The Arrhenius frequency factor (A) and
A
activation energy (Ea) are given in the
tables.
Ea = Activation energy for the initiator
dissociation in J/mole
R
The residual concentration of the initiator
can be calculated by means of the equation
T
= 8.3142 J/mole·K
= temperature in K
t1/2 = half-life in s
procedures must be implemented.
Tc: Control temperature
Self-reactive substances
The Tc is also derived from the SADT and is
3226
type D; solid
the maximum temperature at which the
3236
type D; solid, temperature controlled
[I0] = original initiator concentration
product can be safely transported. The Tc
3234
type C; solid, temperature controlled
The initiators in this product catalog are
[I] = initiator concentration at time t
is not required if the SADT exceeds 50°C.
arranged in descending order of activity,
t
[I] = [I0] · e
-kd·t
based on 1.0 hour half-life temperature.
where
= time measured from the start of
decomposition in s
Both the Tem and Tc are related to safety
and do not apply to product quality.
To maintain product quality the
recommended storage temperatures
(Ts) have to be observed.
Maximum
Hazard rating
container size
Very High
25 kg (55 lb)
High
50 kg (110 lb)
Medium
50 kg (110 lb)
Low
400 kg (880 lb)
Very Low
IBC’s / Tanks
No
Unrestricted
Medium
50 kg (110 lb)
High
50 kg (110 lb)
Organic peroxides
3101
1.0 hour and 10 hours.
Akzo Nobel
8
9
Packaging
Standard packaging
Peroxide formulations can be directly
We offer a variety of packaging options for
pumped into storage tanks by a leak-free
both liquid and solid initiators. The maximum
dry-break connection. All unloading facilities
package size for each initiator is regulated
are present on the trailer.
by the United Nations, based on the hazard
classification of the initiator as shown in
Continuous investment in refrigerated trucks,
table 1 on page 7.
bulk tankers and dedicated reefers
(refrigerated containers) specifically designed
Liquid initiators ( table 2)
Package
Volume
Net Weight
Comments
Bottle
1 gallon
7-8 lb
packaged as 4 polyethylene bottles per non-returnable carton
HDPE can
20-30 liter (5.3-8 gallon)
15-25 kg (6.8-11.3 lb)
returnable, single component, polyethylene container (Nourytainer®)
15 gallon
100 lb
returnable polyethylene drum
55 gallon
300-410 lb
polyethylene or steel drum
200 liter
150 kg
steel drum
Drum
Liquid initiators
to safely transport our products is a
Liquid initiators from Akzo Nobel are
demonstration of our commitment to security
220 liter
165-190 kg
returnable polyethylene drum
available in packages shown in table 2.
of supply. We also have multiple storage
330 gallon
2000 lb
reusable stainless steel container
Package sizes expressed in gallons are only
locations for all initiators to shorten lead
1000 liter
800-1000 kg
composite container
available in North America.
times.
1250 liter
850-1100 kg
reusable stainless steel container
Akzo Nobel was the first organic peroxide
Solid initiators
varies with product
for transport of bulk shipments of dilute type F organic peroxides
producer to introduce intermediate bulk
Standard packages for our solid initiators are
containers (IBC). We have available a
shown in table 3.
Solid initiators ( table 3)
steel container for diluted organic peroxides
Most solid initiators are packaged in
Package
Net Weight
Comments
and peroxide emulsions. In Europe we also
polyethylene bags inside non-returnable
have available a 1000 liter composite
corrugated boxes. The number of bags per
Carton
varies with product
polyethylene bags inside non-returnable cardboard box
container for organic peroxide suspensions.
box varies, depending on the weight of
Crate
varies with inner package
polyethylene bags inside returnable plastic crate
These IBC’s offer a balance of economy and
initiator per bag.
Drum
20-25 kg (45-55 lb)
fiber drum
IBC
Tank Truck
7000 gallon
20 m3
reusable 1250 liter or 330 gallon stainless
safety for the transportation, storage and
handling of organic peroxides. They offer
For the availability of our products in IBC’s,
several advantages over smaller packages,
bulk or non-standard packages, consult your
such as: reduced worker exposure to organic
Akzo Nobel account manager.
peroxide vapors, elimination of packaging
waste and reduced handling or organic
Additional information
peroxides and packaging.
Material Safety Data Sheets (MSDS) and
Product Data Sheets (PDS) are available at
The specially designed stainless steel IBC has
obtained approvals for the transport of
organic peroxides by road and by sea. The
spring-loaded clamping device, used as an
On request we also provide specific
emergency vent, is an Akzo Nobel invention
publications on the application and the safe
and has been patented. The Akzo Nobel
handling and storage of our products.
development of a cooled trailer with IBC’s
connected to a manifold eliminates the
in-house handling and transport of IBC’s.
Nourytainer, Trigonox, Perkadox and Laurox are registered
trademarks of Akzo Nobel Chemicals BV or affiliates in
one or more territories.
10
11
Product data
Product name
General data
Chemical name [CAS number]
Diisobutyryl peroxide [3437-84-1]
TRIGONOX® 187-C30
TRIGONOX 187-W26
CH 3
O
O
C
CH
Active
(%)
oxygen (%)
Physical form
Kinetic data
Ts max.
TS min.
(°C)
(°C)
0.1 h
9.18
2.76 solution in OMS
2.39 emulsion in water and methanol
57
-20
-20
Safety data
T (°C) for t1/2
1.0 h
39
10 h
23
Standard package type
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
3.37E+14
See also pages 8 - 9
109.06
-25
0
0
-10
-10
-20
-20
3115 HDPE can
3119 steel IBC
10
5
0
-5
-10
-15
3115 HDPE can
3119 steel IBC
10
0
-10
3115 HDPE can
15
15
15
5
5
5
-5
-5
-5
3115 HDPE can
3119 HDPE can
3119 steel IBC
10
0
-10
3115 HDPE can
20
10
0
3115 HDPE can
CH 3
CH 3
Cumyl peroxyneodecanoate [26748-47-0]
R
Assay
weight
30
26
CH 3
TRIGONOX 99-C75
TRIGONOX 99-W50
Molecular
O
C
CH
Storage data
174.2
O
*
Not listed on TSCA
** Not listed on EINECS/ELINCS
OMS = Odorless mineral spirits
Listed are the highest concentrations of formulations for each phlegmatizer.
Please contact us for your specific need.
R1
O
C
C
306.4
CH 3
O
O
5.22
75
50
75
-20
-20
56
38
3.12E+14
114.59
-25
C
R2
CH 3
R + R1 + R2 = C8H19
Di(3-methoxybutyl) peroxydicarbonate [52238-68-3] *
294.3
TRIGONOX 181
5.44
50
O
CH 3
CH
CH 2
O
CH 2
C
O
O
C
O
CH 2
CH 2
CH
O
CH 3
CH 3
R
O
C
C
CH 3
O
43
9.09E+18
143.29
-20
CH 3
O
R1
-10
57
O
1,1,3,3-Tetramethylbutyl peroxyneodecanoate [51240-95-0]
TRIGONOX 423-C70
TRIGONOX 423-W50
2.72 solution in toluene
72
O
R2
C
300.5
CH 3
CH 2
CH 3
C
5.32
70
50
76
-15
-15
57
40
3.98E+14
115.79
-20
CH 3
CH 3
R + R1 + R2 = C8H19
Cumyl peroxyneoheptanoate [130097-36-8] **
TRIGONOX 197-C75
R
R1
O
C
C
264.4
75
CH 3
O
O
6.05
79
59
42
1.77E+14
114.27
-20
C
R2
CH 3
R + R1 + R2 = C5H13
tert-Amyl peroxyneodecanoate [68299-16-1]
TRIGONOX 123-C75
R
R1
O
C
C
R2
R + R1 + R2 = C8H19
258.4
CH 3
O
O
C
CH 3
6.19
75
C 2H 5
81
-15
-25
61
43
1.47E+14
114.38
12
13
Product data
Product name
General data
Storage data
Molecular
Assay
Active
weight
(%)
oxygen (%)
Physical form
Kinetic data
Ts max.
TS min.
(°C)
(°C)
0.1 h
Mixture of peroxydicarbonates [78350-78-4; 19910-65-7; 105-64-6]
80
TRIGONOX ADC
98
O
TRIGONOX ADC-NS60
R
O
O
C
O
O
60
C
O
R1
7.06 solution in diethylene glycol
bis(allyl carbonate)
Safety data
T (°C) for t1/2
1.0 h
62
10 h
45
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
7.69E+15
125.61
-20
-30
0
-10
-20
3111 HDPE can
-20
-30
0
-10
-20
3115 HDPE can
0
0
0
0
-10
-10
-10
-10
-20
-20
-20
-20
3113
3115
3113
3115
5
-5
-15
3115 HDPE can
40
40
40
40
35
35
35
35
30
30
30
30
3114
3114
3114
3119
carton
carton
carton
HDPE can / plastic IBC
0
5
5
0
5
0
5
-10
-5
-5
-10
-5
-10
-5
-20
-15
-15
-20
-15
-20
-15
3113
3115
3119
3119
3118
3113
3115
HDPE can
HDPE can
HDPE can
steel IBC
carton
HDPE can
HDPE can
15
20
20
20
15
5
10
10
10
5
-5
0
0
0
-5
3115
3115
3119
3119
3119
HDPE can
HDPE can
steel IBC
HDPE can
steel IBC
R, R1 : isopropyl or sec-butyl
Di-sec-butyl peroxydicarbonate [19910-65-7]
TRIGONOX SBP
TRIGONOX SBP-C60
TRIGONOX SBPS
TRIGONOX SBPS-C60
O
C2 H5
O
CH
234.2
O
C
O
O
C
O
CH 3
CH
C2 H5
CH 3
Diisopropyl peroxydicarbonate [105-64-6]
PERKADOX®
IPP-NS27
O
CH 3
O
CH
206.2
O
O
C
O
CH
CH 3
O
C
O
C
O
O
O
398.5
C
O
C
CH 3
CH 3
Di(2-ethylhexyl) peroxydicarbonate [16111-62-9]
TRIGONOX EHP
TRIGONOX EHP-C75
TRIGONOX EHP-W60
O
(CH 2 ) 3
TRIGONOX EHP-W40S
TRIGONOX EHPS
TRIGONOX EHPS-C75
CH
CH 2
O
C
346.5
O
O
O
C
O
CH 2
C 2H 5
CH
(CH 2 ) 3
R
R1
O
-15
47
3.19E+15
123.85
64
47
3.35E+15
HDPE can
HDPE can
HDPE can
HDPE can
124.01
-15
C
C
R2
R + R1 + R2 = C8H19
O
O
C
CH 3
CH 3
82
powder
powder
wet powder or cake
suspension in water
20
20
20
20
83
4.53 liquid
40
98
75
1.85 frozen flakes
4.53 liquid
-20
-15
-15
-20
-15
-20
-15
6.22
4.91
1.96
3.27
-10
-10
-10
-10
7.44E+15
126.39
64
47
1.83E+15
122.45
-25
84
liquid
solution in OMS
solution in OMS
emulsion in water and methanol
48
-25
-25
-25
6.55
95
75
30
50
64
0
4.62
98
75
60
244.4
CH 3
3.83
3.83
3.01
1.61
CH 3
C 2H 5
tert-Butyl peroxyneodecanoate [26748-41-4]
TRIGONOX 23
TRIGONOX 23-C75
TRIGONOX 23-C30
TRIGONOX 23-W50
82
63
-30
4.01
95.5
95.5
75
40
CH 3
CH 3
CH 3
-20
-20
-20
-20
CH 3
CH 3
CH 3
82
liquid
solution in OMS
liquid
solution in OMS
CH 3
Di(4-tert-butylcyclohexyl) peroxydicarbonate [15520-11-3]
PERKADOX 16
PERKADOX 16S
PERKADOX 16-W75
PERKADOX 16-W40
6.69
4.10
6.69
4.10
7.76
27
O
C
6.83
98
60
98
60
-30
-25
-25
64
46
1.52E+14
115.47
14
15
Product data
Product name
General data
Dicetyl peroxydicarbonate [26322-14-5]
PERKADOX 24-FL
PERKADOX 24L
PERKADOX 24-W33
O
CH 3
O
(CH 2 ) 15
O
O
O
(CH 2 ) 13
O
(CH 2 ) 15
C
O
O
O
(CH 2 ) 13
C
CH 3
C
O
CH 3
230.3
CH 3
R
R1
O
C
C
2.65 flakes
2.55 powder
0.92 suspension in water
84
20
20
15
1.0 h
65
10 h
48
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
3.02E+15
124.30
0
40
40
40
35
35
35
30
30
30
3116 carton
3116 carton
none HDPE can / plastic IBC
2.98 flakes
1.24 suspension in water
84
15
15
0
-15
-25
65
48
2.82E+15
35
35
30
25
25
20
20
20
15
3116 carton
3119 HDPE can
3119 plastic IBC
20
10
0
3115 HDPE can
20
10
0
3115 HDPE can
25
15
10
3113 HDPE can
20
25
15
10
15
10
0
10
5
3113 HDPE can
3119 steel IBC
3119 Bulk
20
25
10
25
10
15
5
15
0
10
0
10
3115
3119
3119
3119
124.10
86
66
48
2.47E+14
117.50
CH 3
202.3
O
C
7.91
75
CH 3
O
0.1 h
CH 3
tert-Butyl peroxyneoheptanoate [26748-38-9]
TRIGONOX 257-C75
(°C)
6.95
75
C
CH 2
TS min.
(°C)
CH 3
CH 3
C
O
Ts max.
3.11
96
40
C
Physical form
Safety data
T (°C) for t1/2
2.80
514.8
O
CH 3 O
CH 3
oxygen (%)
Kinetic data
CH 3
1,1,3,3-Tetramethylbutyl peroxypivalate [22288-41-1] *
TRIGONOX 425-C75
Active
(%)
94.5
91
33
C
O
CH 3
Assay
weight
570.9
Dimyristyl peroxydicarbonate [53220-22-7]
PERKADOX 26
PERKADOX 26-W40
Storage data
Molecular
O
C
*
Not listed on TSCA
87
67
49
2.09E+14
117.56
-10
CH 3
CH 3
R2
R + R1 + R2 = C5H13
tert-Amyl peroxypivalate [29240-17-3]
TRIGONOX 125-C75
CH 3 O
C
CH 3
C
188.3
75
CH 3
O
C
O
CH 3
CH 2
174.2
C
C
O
C
O
CH 3
TRIGONOX 36-W50
C
CH 3
-15
-20
0
0
-10
0
0
-20
4.12E+15
127.76
CH
CH 2
94
75
57
7.09E+14
123.59
CH 3
O
CH 3
CH 2
-5
-5
55
CH 3
Di(3,5,5-trimethylhexanoyl) peroxide [3851-87-4]
CH 3
-30
9.18
75
25
CH 3
CH 3
TRIGONOX 36-C75
TRIGONOX 36-C37.5
-10
72
CH 3
CH 3 O
CH 3
91
CH 3
tert-Butyl peroxypivalate [927-07-1]
TRIGONOX 25-C75
TRIGONOX 25-C25
8.50
C
O
O
O
C
314.5
CH 3
CH 2
CH
CH 3
CH 2
C
CH 3
5.09
75
37.5
96
CH 3
50
77
59
2.84E+15
128.34
HDPE can
steel IBC
Bulk
HDPE can / IBC
16
17
Product data
Product name
General data
Dilauroyl peroxide [105-74-8]
LAUROX®
LAUROX S
LAUROX W-40
LAUROX W-25
Molecular
Assay
Active
weight
(%)
oxygen (%)
O
O
C
(CH 2 ) 10
CH 3
Didecanoyl peroxide [762-12-9]
342.5
PERKADOX SE-10
CH 3
O
O
C
(CH 2 ) 8
CH 3
C
N
N
C
CN
N
N
C
CN
CH 2
CH
C
CH 3
O
O
C 2H 5
C
CH 2
C
CH 2
CH 3
25
98
granules
25
104
7.43
O
O
C
O
CH 3
C
O
CH
(CH 2 ) 3
123.37
80
63
3.64E+15
3106
3106
3109
none
carton
carton
HDPE can / IBC
HDPE can / IBC
130.48
40
35
30
3114 carton
82
64
2.89E+15
50
45
40
3234 carton / fiber drum
45
40
35
3236 carton / fiber drum
35
25
20
3113 HDPE can
30
20
15
3115 HDPE can
35
35
25
25
20
20
3115 HDPE can
3115 HDPE can
130.23
84
66
1.38E+15
128.93
CH 2
CH 3
O
CH
C 2H 5
C
C
15
-20
5
-20
5
10
-20
86
68
2.19E+15
130.88
272.4
5.87
O
5.29 liquid
109
88
69
1.62E+14
123.80
CH 3
CH 3
230.3
C
CH 3
6.95
95
75
CH 3
O
6.69 liquid
105
CH 3
tert-Amyl peroxy-2-ethylhexanoate [686-31-7]
TRIGONOX 121
TRIGONOX 121-C75
(CH 2 ) 3
3.92E+14
CH 3
C
O
C 2H 5
CH 3
No.
C 2H 5
CH 3
90
CH
UN
(°C)
O
CH 3
1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate [22288-43-3]
(CH 2 ) 3
Tc
(°C)
0
0
101
solid
430.6
TRIGONOX 421
CH 3
Tem
(°C)
10
98
90
(CH 2 ) 3
SADT
CN
TRIGONOX 141
CH 3
61
Ea
(kJ/mole)
50
50
50
50
100
4.60 flakes
79
A
(1/s)
CH 3
2,5-Dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane [13052-09-0]
O
30
30
20
20
192.3
CH 3
C
CH 2
99
flakes
powder
suspension in water
suspension in water
10 h
CN
CH 3
CH 3
3.97
3.97
1.61
1.00
1.0 h
CH 3
2,2’-Azodi(2-methylbutyronitrile) [13472-08-7]
PERKADOX AMBN-GR
0.1 h
164.2
CH 3
CH 3
(°C)
CH 3
2,2’-Azodi(isobutyronitrile) [78-67-1]
PERKADOX AIBN
TS min.
(°C)
O
C
(CH 2 ) 8
Ts max.
Safety data
T (°C) for t1/2
4.67
98.5
O
Physical form
Kinetic data
4.01
99
99
40
25
O
C
(CH 2 ) 10
Storage data
398.6
O
CH 3
CH 2
CH 3
6.60 liquid
111
91
73
1.77E+15
132.11
18
19
Product data
Product name
General data
Dibenzoyl peroxide [94-36-0]
PERKADOX L-W75
PERKADOX L-W40
PERKADOX L-DFG
PERKADOX API
O
O
O
C
O
CH 3
C
CH 3
O
C
O
4.95
2.64
4.95
4.95
C
CH 3
O
C
O
N
10
10
10
-30
-30
15
-30
118
Tem
Tc
UN
(°C)
(°C)
(°C)
No.
6.94E+13
91
72
1.54E+14
122.35
3104
3109
3104
3104
carton
HDPE can
carton
carton
124.90
93
75
2.45E+15
35
35
25
25
25
20
20
20
15
3113 HDPE can
3113 HDPE can
3119 Bulk
35
25
20
3113 HDPE can
30
20
15
3115 HDPE can
134.00
98
79
2.07E+15
135.16
10
224.3
123
302.5
1.10E+16
142.19
35
O
O
CH 3
C
10.58
95
90
75
CH 3
O
85
80
3226 fiber drum
60
60
60
3101 HDPE can
3103 HDPE can
3103 HDPE can
55
3103 HDPE can
N
CH 3
O
powder
103
NC
1,1-Di(tert-butylperoxy)-3,3,5-trimethylcyclohexane [6731-36-8]
CH 3
10.05 liquid
9.52 solution in dibutyl phthalate
128
25
25
25
105
85
7.59E+13
127.52
-10
CH 3
CH 3
CH 3
CH 3
1,1-Di(tert-amylperoxy)cyclohexane [15667-10-4]
CH 3
CH 3
SADT
80
60
80
80
113
8.16 liquid
98
C
Ea
(kJ/mole)
0
113
7.17 liquid
71
A
(1/s)
CH 3
CN
C 2H 5
40
30
40
40
91
10 h
CH 3
PERKADOX ACCN
TRIGONOX 122-C80
wet powder
suspension in water
micronized powder
micronized powder
9.99
50
1,1’-Azodi(hexahydrobenzonitrile) [2094-98-6]
C
113
1.0 h
CH 3
160.2
O
CH 3
0.1 h
CH 3
CH 3
TRIGONOX 29
TRIGONOX 29-B90
TRIGONOX 29-C75
(°C)
8.50
96
tert-Butyl peroxyisobutyrate [109-13-7]
CH
TS min.
(°C)
7.40
188.3
C 2H 5
CH 3
Ts max.
Safety data
T (°C) for t1/2
CH 3
O
CH
Physical form
Kinetic data
6.61
97
70
30
CH 3
tert-Butyl peroxydiethylacetate [2550-33-6]
TRIGONOX 27
TRIGONOX 41-C50
oxygen (%)
216.3
C 2H 5
C 2H 5
Active
(%)
C
C
CH
(CH 2 ) 3
Assay
weight
75
40
75
75
O
CH 3
Molecular
O
tert-Butyl peroxy-2-ethylhexanoate [3006-82-4]
TRIGONOX 21S
TRIGONOX 21-C70
TRIGONOX 21-C30
Storage data
242.2
O
C
288.4
CH 3
O
O
O
O
C
CH 3
11.09
80
C 2H 5
126
30
106
87
3.29E+15
139.46
20
21
Product data
Product name
General data
1,1-Di(tert-butylperoxy)cyclohexane [3006-86-8]
TRIGONOX 22-B50
TRIGONOX 22-E50
TRIGONOX 22-C80
CH 3
C
CH 3
O
O
Assay
Active
weight
(%)
oxygen (%)
260.4
C
O
CH 3
Storage data
Molecular
CH 3
tert-Amylperoxy 2-ethylhexyl carbonate [70833-40-8]
260.4
O
CH
O
CH 2
C
O
O
0.1 h
6.14 solution in dibutyl phthalate
6.14 solution in mineral oil
134
1.0 h
113
10 h
94
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
3.47E+15
142.40
25
25
25
70
70
60
3105 HDPE can
3105 HDPE can
3103 HDPE can
5.78 liquid
134
113
95
2.22E+16
55
3105 HDPE can
60
3107 HDPE can
55
55
45
3105 HDPE can
3109 steel IBC
3119 Bulk
148.41
20
C
CH 2
CH 3
CH 3
tert-Amyl peroxyacetate [690-83-5]
146.2
O
O
C
O
10.94
60
CH 3
C
CH 3
(°C)
CH 3
C 2H 5
TRIGONOX 133-CK60
TS min.
(°C)
6.14
94
(CH 2 ) 3
Ts max.
Safety data
T (°C) for t1/2
CH 3
TRIGONOX 131
CH 3
Physical form
Kinetic data
12.29
50
50
80
CH 3
O
134
114
96
6.59E+16
152.16
30
C 2H 5
CH 3
tert-Butyl peroxy-3,5,5-trimethylhexanoate [13122-18-4]
TRIGONOX 42S
TRIGONOX 42-C30
O
CH 3
CH 3
C
CH 2
CH
CH 3
CH 2
C
230.3
CH 3
O
C
O
CH 3
CH 3
CH 3
C
O
C
CH 3
234.3
O
O
C
C 2H 5
176.2
tert-Butylperoxy 2-ethylhexyl carbonate [34443-12-4]
O
C 2H 5
140.78
116
98
9.30E+16
40
35
154.08
30
30
C
CH 3
O
O
C
CH 3
CH 3
137
25
6.49
95
O
136
9.08
246.3
TRIGONOX 117
CH 2
1.94E+15
70
80
3103 HDPE can
3103 HDPE can
70
3103 HDPE can
55
3105 HDPE can
CH 3
75
CH
94
CH 3
tert-Butylperoxy isopropyl carbonate [2372-21-6]
(CH 2 ) 3
114
-20
-20
13.66
50
50
CH 3
TRIGONOX BPIC-C75
CH 3
135
25
25
CH 3
CH 3
O
6.74 liquid
CH 3
2,2-Di(tert-butylperoxy)butane [2167-23-9]
TRIGONOX D-C50
TRIGONOX D-E50
6.95
97
30
6.17 liquid
137
20
117
98
2.49E+16
150.15
-20
117
98
4.07E+16
151.72
22
23
Product data
Product name
General data
tert-Amyl peroxybenzoate [4511-39-1]
TRIGONOX 127
Molecular
Assay
Active
weight
(%)
oxygen (%)
O
C
Physical form
Kinetic data
Ts max.
TS min.
(°C)
(°C)
7.22 liquid
Safety data
T (°C) for t1/2
0.1 h
7.68
94
CH 3
O
Storage data
208.3
O
C
139
1.0 h
118
10 h
99
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
8.38E+15
147.02
20
60
3103 HDPE can
C 2H 5
CH 3
tert-Butyl peroxyacetate [107-71-1]
TRIGONOX F-C50
132.2
O
TRIGONOX F-CE30
CH 3
C
CH 3
O
O
C
12.11
139
50
10
30
3.63 solution in isoparaffins
10
119
100
1.57E+16
149.36
-15
70
40
3103 HDPE can
35
30
3109 Bulk
CH 3
CH 3
Butyl 4,4-di(tert-butylperoxy)valerate [995-33-5]
334.5
TRIGONOX 17
9.57
95
CH 3
CH 3
C
CH 3
O
C
O
CH 3
143
121
102
1.91E+15
143.51
30
60
3103 HDPE can
60
60
3103 HDPE can
3105 HDPE can
80
3107 HDPE can
75
3110 HDPE can
CH 3
O
C
O
CH 3
CH 3
(CH 2 ) 2
(CH 2 ) 3
O
C
9.09 liquid
CH 3
O
tert-Butyl peroxybenzoate [614-45-9]
TRIGONOX C
TRIGONOX C-C75
194.2
O
CH 3
C
O
O
C
8.24
98
75
8.07 liquid
142
25
25
122
103
2.23E+16
151.59
10
0
CH 3
CH 3
Di-tert-amyl peroxide [10508-09-5]
TRIGONOX 201
CH 3
CH 3
CH 2
C
174.3
O
CH 3
C
CH 3
128
108
4.02E+15
148.35
30
CH 3
270.4
CH 3
C
CH 2
8.72 liquid
150
CH 3
Dicumyl peroxide [80-43-3]
PERKADOX BC-FF
95
CH 3
O
9.18
CH 3
O
O
C
CH 3
5.92
99
5.86 crystals
154
30
132
112
9.24E+15
152.67
24
25
Product data
Product name
General data
Di(tert-butylperoxyisopropyl)benzene [25155-25-3]
PERKADOX 14
PERKADOX 14S-FL
CH 3
CH 3
C
O
CH 3
O
C
O
CH 3
CH 2
290.4
0.1 h
156
8.51 solid
9.08 flakes
1.0 h
134
10 h
114
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
7.65E+15
152.69
30
15
O
O
CH 3
C
CH 3
O
208.3
CH 3
80
80
3106 HDPE drum
3106 carton
286.4
CH 3
CH 3
C
CH 3
C
O
O
CH 3
C
80
80
70
70
70
60
3105
3106
3108
none
3109
3109
80
3107 HDPE can
80
3103 HDPE can
80
80
80
65
3107
3109
3109
3109
O
O
C
CH 3
10
30
10
40
40
40
-30
-30
40
40
0
0
136
115
1.17E+15
HDPE can / HDPE drum
carton
carton
carton
HDPE drum
steel IBC
146.98
164
141
120
1.90E+15
150.67
10.83 liquid
164
141
121
4.20E+15
153.46
HDPE can / steel drum
steel IBC
steel IBC
Bulk
CH 3
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane [24748-23-0]
CH 3
CH 2
C
O
CH 3
O
C
C
O
O
CH 3
CH 2
264.3
18.16
41
10
O
O
CH 3
40
10.94
99
50
30
CH 3
CH 3
CH 2
155.49
CH 3
146.2
CH 3
TRIGONOX 301
TRIGONOX 301-25PP
1.68E+16
CH 3
Di-tert-butyl peroxide [110-05-4]
C
115
CH 3
C
C
CH 3
CH 3
7.30 liquid
159
11.17
85
O
134
10
10
CH 3
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3 [1068-27-5]
O
40
30
30
30
40
CH 3
TRIGONOX 145-E85
CH 3
156
liquid
on silica, powder
on polypropylene, beads
on polypropylene, powder
solution in mineral oil
7.68
95
C
O
10.14
5.51
2.20
0.83
3.31
CH 3
CH 3
C
11.02
92
50
20
7.5
30
CH 3
C
CH 2
CH 3
CH 3
(°C)
CH 3
CH 3
CH 3
TRIGONOX T
TRIGONOX B
TRIGONOX B-C50
TRIGONOX B-C30
TS min.
(°C)
CH 3
tert-Butyl cumyl peroxide [3457-61-2]
C
Ts max.
CH 3
CH 3
CH 3
Physical form
Safety data
T (°C) for t1/2
9.45
90
96
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane [78-63-7]
C
oxygen (%)
338.5
C
O
CH 3
CH 3
Active
(%)
Kinetic data
C
O
CH 3
TRIGONOX 101
TRIGONOX 101-50D-PD
TRIGONOX 101-20PP
TRIGONOX 101-7.5PP-PD
TRIGONOX 101-E30
Assay
weight
CH 3
O
Storage data
Molecular
CH 3
C
CH 3
CH 3
7.45 solution in isoparaffins
1.82 on polypropylene, beads
170
146
125
1.02E+15
150.23
110
90
3105 HDPE can
3110 carton
26
27
Product data
Product name
General data
Isopropylcumyl hydroperoxide [26762-93-6]
TRIGONOX M-55
C
Storage data
Molecular
Assay
Active
weight
(%)
oxygen (%)
194.3
O
Physical form
Kinetic data
Ts max.
TS min.
(°C)
(°C)
0.1 h
183
4.53 solution in diisopropylbenzene
30
-25
20
0
40
-30
40
35
0
0
1.0 h
154
Contains 12.5% Di-tert-butyl peroxide (DTBP), total act. O 15.57%
Safety data
T (°C) for t1/2
8.24
55
CH 3
CH 3
*
10 h
129
A
Ea
SADT
Tem
Tc
UN
(1/s)
(kJ/mole)
(°C)
(°C)
(°C)
No.
2.25E+12
131.44
70
3109 HDPE can
60
3105 HDPE can
70
3109 HDPE can / steel drum
90
80
55
3103 HDPE can
3109 HDPE can / HDPE drum
3109 steel IBC
80
3107 HDPE can / HDPE drum
OH
CH
CH 3
CH 3
1,1,3,3-Tetramethylbutyl hydroperoxide [5809-08-5]
TRIGONOX TMBH-L
CH 3
CH 3
C
146.2
CH 3
C
CH 2
CH 3
10.94
90
O
180
9.85 liquid
159
140
1.90E+18
181.99
OH
CH 3
Cumyl hydroperoxide [80-15-9]
TRIGONOX K-90
152.2
CH 3
C
10.51
90
O
195
9.46 solution in aromatic
solvent mixture
166
140
1.15E+12
132.56
OH
CH 3
tert-Butyl hydroperoxide [75-91-2]
TRIGONOX A-80
TRIGONOX A-W70
90.1
CH 3
C
CH 3
17.75
80
70
O
207
14.20* solution in water and DTBP *
12.43 solution in water
185
164
3.18E+17
186.01
OH
CH 3
tert-Amyl hydroperoxide [3425-61-4]
TRIGONOX TAHP-W85
104.1
85
CH 3
C 2H 5
C
15.36
O
228
13.06 solution in water
190
153
30
OH
CH 3
2,3-Dimethyl-2,3-diphenylbutane [1889-67-4]
PERKADOX 30
CH 3 CH 3
C
C
CH 3 CH 3
238.4
284
95
flakes
30
259
237
7.34E+18
230.19
carton / fiber drum
28
29
Product survey
All products are listed below by type of initiator and in alphabetical order with their main areas of application.
Product name
Acrylics
LDPE
CR-PP
PVC
Styrenics
Page
Azo initiators
PERKADOX AIBN
PERKADOX AMBN-GR
PERKADOX ACCN
Product name
Acrylics
LDPE
✓
✓
✓
✓
✓
✓
16
PERKADOX 14
16
PERKADOX 14S-FL
18
PERKADOX BC-FF
✓
PERKADOX 30
✓
✓
✓
✓
✓
26
TRIGONOX 101-20PP
TRIGONOX 101-7.5PP-PD
Cyclic peroxides
TRIGONOX 101-E30
TRIGONOX 301
24
TRIGONOX 145-E85
24
TRIGONOX 201
✓
✓
TRIGONOX 301-25PP
✓
✓
✓
TRIGONOX B
Diacyl peroxides
TRIGONOX B-C30
LAUROX
16
TRIGONOX B-C50
16
TRIGONOX T
LAUROX W-25
PERKADOX L-W75
PERKADOX L-W40
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
PERKADOX API
✓
TRIGONOX 187-C30
TRIGONOX 187-W26
TRIGONOX 36-C37.5
TRIGONOX 36-C75
TRIGONOX 36-W50
✓
✓
✓
Page
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
Product name
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
24
PERKADOX 16
24
PERKADOX 16S
22
PERKADOX 16-W40
24
PERKADOX 16-W75
24
PERKADOX 24-FL
24
PERKADOX 24L
24
PERKADOX 24-W33
24
PERKADOX 26
24
PERKADOX 26-W40
22
PERKADOX IPP-NS27
24
TRIGONOX 181
24
24
24
TRIGONOX EHP
LDPE
14
TRIGONOX 423-C70
14
TRIGONOX 423-W50
14
TRIGONOX 425-C75
14
TRIGONOX 42-C30
12
TRIGONOX 42S
10
TRIGONOX 99-C75
TRIGONOX ADC
12
TRIGONOX 99-W50
TRIGONOX ADC-NS60
12
TRIGONOX C
12
TRIGONOX C-C75
12
TRIGONOX F-CE30
12
TRIGONOX F-C50
TRIGONOX EHP-W40S
18
TRIGONOX K-90
26
TRIGONOX EHP-W60
18
TRIGONOX M-55
26
TRIGONOX SBP
16
TRIGONOX TAHP-W85
26
TRIGONOX SBP-C60
10
TRIGONOX TMBH-L
26
TRIGONOX SBPS
✓
✓
✓
14
TRIGONOX 131
TRIGONOX BPIC-C75
✓
✓
✓
✓
✓
✓
✓
✓
✓
TRIGONOX SBPS-C60
10
✓
TRIGONOX 421
26
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
14
18
✓
✓
TRIGONOX 41-C50
26
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
20
Peroxyesters
20
TRIGONOX 121
20
TRIGONOX 121-C75
12
Peroxyketals
12
TRIGONOX 17
12
TRIGONOX 122-C80
12
TRIGONOX 22-B50
12
TRIGONOX 22-C80
12
TRIGONOX 22-E50
TRIGONOX 29-B90
✓
✓
TRIGONOX 123-C75
TRIGONOX 125-C75
TRIGONOX 127
TRIGONOX 133-CK60
TRIGONOX 141
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
TRIGONOX 21-C30
TRIGONOX 21-C70
TRIGONOX 21S
TRIGONOX 23
TRIGONOX 23-C30
TRIGONOX 23-C75
TRIGONOX 23-W50
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
16
TRIGONOX 29-C75
16
TRIGONOX D-C50
10
TRIGONOX D-E50
14
22
20
✓
✓
TRIGONOX 197-C75
16
10
18
✓
✓
✓
18
18
12
12
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
LDPE
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
CR-PP
PVC
Styrenics
✓
Page
14
14
✓
14
✓
✓
✓
✓
✓
18
18
16
10
10
14
20
✓
✓
✓
20
10
10
✓
✓
22
22
22
✓
22
12
TRIGONOX 29
✓
✓
✓
Acrylics
TRIGONOX 257-C75
TRIGONOX 27
TRIGONOX A-W70
✓
✓
✓
✓
✓
✓
Product name
12
TRIGONOX A-80
TRIGONOX 117
Page
12
18
14
Styrenics
TRIGONOX 25-C75
TRIGONOX EHPS-C75
Peroxycarbonates
PVC
TRIGONOX 25-C25
TRIGONOX EHPS
14
CR-PP
12
Hydroperoxides
16
Acrylics
12
TRIGONOX EHP-C75
16
✓
✓
PERKADOX L-DFG
PERKADOX SE-10
Styrenics
Peroxydicarbonates
TRIGONOX 101-50D-PD
C-C initiator
LAUROX W-40
PVC
Dialkyl peroxides
TRIGONOX 101
LAUROX S
CR-PP
12
12
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
22
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
18
20
20
20
18
18
18
20
20
30
31
Half-life chart
15
14
13
12
11
10
9
6
5
1
2
3 4
8
7
22
16
17 18 19 20 21
25
23 24
32
31
27
26 28 29
30
35
34 37
33
36
40
39
38
49
48
42 44
41 43
55
54
51
45
46 47
50
52
56
53
58
57
10
1
0.1
20
30
40
50
60
70
80
90
100
110
120
130
140
150
160
170
180
190
200 210 220 230 240 250 260 270 280 290 300
product name
chemical name
1
TRIGONOX 187
Diisobutyryl peroxide
2
TRIGONOX 99
Cumyl peroxyneodecanoate
3
TRIGONOX 423
1,1,3,3-Tetramethylbutyl peroxyneodecanoate
4
TRIGONOX 197
Cumyl peroxyneoheptanoate
5
TRIGONOX 181
Di(3-methoxybutyl) peroxydicarbonate
6
TRIGONOX 123
tert-Amyl peroxyneodecanoate
7
TRIGONOX ADC
Mixture of peroxydicarbonates
8
TRIGONOX 23
tert-Butyl peroxyneodecanoate
9
TRIGONOX SBP
Di-sec-butyl peroxydicarbonate
10
PERKADOX IPP
Diisopropyl peroxydicarbonate
11
TRIGONOX EHP
Di(2-ethylhexyl) peroxydicarbonate
12
PERKADOX 16
Di(4-tert-butylcyclohexyl) peroxydicarbonate
13
PERKADOX 24
Dicetyl peroxydicarbonate
14
PERKADOX 26
Dimyristyl peroxydicarbonate
15
TRIGONOX 425
1,1,3,3-Tetramethylbutyl peroxypivalate
16
TRIGONOX 257
tert-Butyl peroxyneoheptanoate
17
TRIGONOX 125
tert-Amyl peroxypivalate
18
TRIGONOX 25
tert-Butyl peroxypivalate
19
TRIGONOX 36
Di(3,5,5-trimethylhexanoyl) peroxide
20
LAUROX
Dilauroyl peroxide
21
PERKADOX SE-10
Didecanoyl peroxide
22
PERKADOX AIBN
2,2'-Azodi(isobutyronitrile)
23
PERKADOX AMBN
2,2'-Azodi(2-methylbutyronitrile)
24
TRIGONOX 141
2,5-Dimethyl-2,5-di(2-ethylhexanoylperoxy)hexane
25
TRIGONOX 421
1,1,3,3-Tetramethylbutyl peroxy-2-ethylhexanoate
26
PERKADOX L
Dibenzoyl peroxide
27
TRIGONOX 21
tert-Butyl peroxy-2-ethylhexanoate
28
TRIGONOX 121
tert-Amyl peroxy-2-ethylhexanoate
29
TRIGONOX 27
tert-Butyl peroxydiethylacetate
30
TRIGONOX 41
tert-Butyl peroxyisobutyrate
31
PERKADOX ACCN
1,1'-Azodi(hexahydrobenzonitrile)
32
TRIGONOX 29
1,1-Di(tert-butylperoxy)-3,3,5-trimethylcyclohexane
33
TRIGONOX 122
1,1-Di(tert-amylperoxy)cyclohexane
34
TRIGONOX 22
1,1-Di(tert-butylperoxy)cyclohexane
35
TRIGONOX 42
tert-Butyl peroxy-3,5,5-trimethylhexanoate
36
TRIGONOX 131
tert-Amylperoxy 2-ethylhexyl carbonate
37
TRIGONOX 133
tert-Amyl peroxyacetate
38
TRIGONOX D
2,2-Di(tert-butylperoxy)butane
39
TRIGONOX BPIC
tert-Butylperoxy isopropyl carbonate
40
TRIGONOX 117
tert-Butylperoxy 2-ethylhexyl carbonate
41
TRIGONOX 127
tert-Amyl peroxybenzoate
42
TRIGONOX F
tert-Butyl peroxyacetate
43
TRIGONOX 17
Butyl 4,4-di(tert-butylperoxy)valerate
44
TRIGONOX C
tert-Butyl peroxybenzoate
45
TRIGONOX 201
Di-tert-amyl peroxide
46
PERKADOX BC
Dicumyl peroxide
47
PERKADOX 14
Di(tert-butylperoxyisopropyl)benzene
48
TRIGONOX 101
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexane
49
TRIGONOX T
tert-Butyl cumyl peroxide
50
TRIGONOX 145
2,5-Dimethyl-2,5-di(tert-butylperoxy)hexyne-3
51
TRIGONOX B
Di-tert-butyl peroxide
52
TRIGONOX 301
3,6,9-Triethyl-3,6,9-trimethyl-1,4,7-triperoxonane
53
TRIGONOX M
Isopropylcumyl hydroperoxide
54
TRIGONOX TMBH
1,1,3,3-Tetramethylbutyl hydoperoxide
55
TRIGONOX K
Cumyl hydroperoxide
56
TRIGONOX TTAHP
tert-Amyl hydroperoxide
57
TRIGONOX A
tert-Butyl hydroperoxide
58
PERKADOX 30
2,3-Dimethyl-2,3-diphenylbutane
For product inquiry and ordering information, please contact your
Akzo Nobel sales manager or regional Akzo Nobel sales office.
AMERICAS
ASIA PACIFIC
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