Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario

MAGMATIC NICKEL-COPPER-PLATINUM GROUP ELEMENT DEPOSITS
O. ROGER ECKSTRAND AND LARRY J. HULBERT
Geological Survey of Canada, 601 Booth Street, Ottawa, Ontario, K1A 0E8
Corresponding author’s email: lhulbert@nrcan.gc.ca
Abstract
Magmatic deposits containing exploitable quantities of nickel, copper, and platinum group elements (PGE) are associated with variable quantities of localized sulphide concentrations in mafic and ultramafic rocks. Ni-Cu deposits, nickel
being the main economic commodity, are associated with high concentrations of sulphides, and the host bodies are classified based on the nature of the confining magmatic environment: (1) meteorite-impact, (2) rift and continental flood
basalt, (3) komatiitic, and (4) other related mafic/ultramafic bodies. Platinum group element deposits are also confined
to mafic/ultramafic bodies, but are associated with low quantities of sulphides. Reef-type or stratiform PGE deposits
form in large, well-layered mafic/ultramafic intrusions, whereas magmatic breccia-type deposits occurs in stock-like or
layered bodies.
The economics and rarity of such deposits with respect to number, grade, tonnage, and mining districts are outlined.
In addition, the geological attributes of the various deposit types and subtypes are documented.
Exploration models based on district and local scales are discussed, as well as recent advances and knowledge gaps
in this field.
Résumé
Les gîtes magmatiques renfermant des quantités exploitables de nickel, de cuivre et d’éléments du groupe du platine
(ÉGP) sont associés à des concentrations localisées de sulfures, en quantités plus ou moins importantes, dans les roches
mafiques et ultramafiques. Les gîtes de Ni-Cu, où le nickel est la principale substance utile, sont associés à de fortes
concentrations de sulfures et les corps hôtes sont classés d’après la nature des milieux magmatiques qui les renferment :
(1) impact météoritique, (2) basaltes de rift et de plateaux continentaux, (3) unités komatiitiques et (4) autres corps mafiques/ultramafiques connexes. Les gîtes d’éléments du groupe du platine sont également restreints aux corps mafiques
et ultramafiques, mais sont associés à de faibles quantités de sulfures. Les gîtes d’ÉGP de type horizon minéralisé ou
minéralisation stratiforme sont formés dans de grandes intrusions mafiques/ultramafiques bien stratifiées, alors que les
gîtes de type brèche magmatique se forment dans des corps s’apparentant à des stocks ou dans des massifs stratifiés.
La valeur et la rareté de ces gîtes sont soulignées en termes de nombres, de teneurs de tonnages et de districts miniers.
Les attributs géologiques des divers types et sous-types de gîtes sont en outre documentés.
Des modèles d’exploration à l’échelle du district et à l’échelle locale sont discutés et les progrès récents dans ce domaine ainsi que les lacunes dans nos connaissances sont soulignés.
Definition
A broad group of deposits containing nickel, copper, and
platinum group elements (PGE) occur as sulphide concentrations associated with a variety of mafic and ultramafic magmatic rocks (Eckstrand et al., 2004; Naldrett, 2004). The magmas originate in the upper mantle and contain small amounts
of nickel, copper, PGE, and variable but minor amounts of
S (the one exception to this source of magma is the Sudbury
Igneous Complex, or SIC, which will be discussed separately). The magmas ascend through the crust and cool as they
encounter cooler crustal rocks. If the original S content of the
magma is sufficient, or if S is added from crustal wall rocks, a
separate sulphide liquid forms as droplets dispersed throughout the magma. Because the partition coefficients of nickel,
copper, and PGE as well as iron favour sulphide liquid over
silicate liquid, these elements preferentially transfer into the
sulphide droplets from the surrounding magma. The sulphide
droplets tend to sink toward the base of the magma because
of their greater density, and form sulphide concentrations. On
further cooling, the sulphide liquid crystallizes to form the ore
deposits that contain these metals.
Among such deposits, two main types are distinguishable.
In the first, Ni-Cu sulphide, Ni and Cu are the main economic
commodities. These occur as sulphide-rich ores that are associated with differentiated mafic and/or ultramafic sills and
stocks, and ultramafic (komatiitic) volcanic flows and sills.
The second type is exploited principally for PGE, which are
associated with sparsely dispersed sulphides in very large to
medium-sized, typically mafic/ultramafic layered intrusions.
In Ni-Cu sulphide deposits (the first type), Ni constitutes the main economic commodity, generally at grades of
about 1 to 3 percent. Copper may be either a coproduct or
by-product, and Co, PGE, and Au are the usual by-products.
However, in some cases, such as Noril’sk-Talnakh, PGE may
constitute highly significant coproducts. Other commodities
recovered in some cases include Ag, S, Se, and Te. These
metals are all associated with the sulphides, which generally
make up more than 10 percent of the ore.
The mafic and ultramafic magmatic bodies that host the
Ni-Cu sulphide ores are diverse in form and composition,
and can be subdivided into the following four subtypes:
1. A meteorite-impact mafic melt sheet that contains basal
sulphide ores (Sudbury, Ontario is the only known example).
2. Rift and continental flood basalt-associated mafic sills
and dyke-like bodies (Noril’sk-Talnakh, Russia; Jinchuan,
Eckstrand, O.R., and Hulbert, L.J., 2007, Magmatic nickel-copper-platinum group element deposits, in Goodfellow, W.D., ed., Mineral Deposits of Canada: A
Synthesis of Major Deposit Types, District Metallogeny, the Evolution of Geological Provinces, and Exploration Methods: Geological Association of Canada,
Mineral Deposits Division, Special Publication No. 5, p. 205-222.
O.R. Eckstrand and L.J. Hulbert
China; Duluth Complex, Minnesota; Muskox, Nunavut;
and Crystal Lake intrusion, Ontario).
3. Komatiitic (magnesium-rich) volcanic flows and related
sill-like intrusions (Thompson, Manitoba; Raglan and
Marbridge, Quebec; Langmuir, Ontario; Kambalda and
Agnew, Australia; Pechenga, Russia; Shangani, Trojan,
and Hunter’s Road, Zimbabwe).
4. Other mafic/ultramafic intrusions (Voisey’s Bay, Labrador;
Lynn Lake, Manitoba; Giant Mascot, British Columbia;
Kotalahti, Finland; Råna, Norway; and Selebi-Phikwe,
Botswana).
The PGE of the second type of deposit include Os, Ir, Ru,
Rh, Pt, and Pd. Platinum and Pd are the most abundant of
these and determine the economic value of these ores, although Rh, Ni, Cu, and Au are commonly recovered as
well.
1. PGE-dominant magmatic sulphide ores are associated
with mafic/ultramafic intrusions. There are two principal
subtypes of deposits:
2. Reef-type or stratiform PGE deposits, which occur in well
layered mafic/ultramafic intrusions (Merensky Reef and
UG-2 chromitite layer of the Bushveld Complex, South
Africa; J-M Reef of the Stillwater Complex, Montana;
Main sulphide zone in the Great Dyke, Zimbabwe).
3. Magmatic breccia type, which occurs in stock-like or layered mafic/ultramafic intrusions (Platreef deposits of the
northern Bushveld Complex, South Africa; Lac des Iles
deposit and Marathon deposit, Ontario).
Mafic/ultramafic rocks host other types of mineralization
as well. These include lateritic nickel deposits, placer Pt deposits, chromite deposits, and titaniferous magnetite deposits.
None of these are discussed further.
Economic Characteristics
Magmatic Ni-Cu sulphide deposits provide most of the
Ni produced in the world and continue to have substantial
reserves. However, lateritic Ni deposits, formed from the
weathering of ultramafic rocks, are also substantial sources of
Ni, and have global reserves greater than those of Ni-Cu sulphide deposits. Lateritic Ni deposits do not occur in Canada,
but will probably in time become the main source of nickel.
Magmatic PGE deposits and Ni-Cu sulphide deposits are
the source of essentially all of the world’s platinum group elements. Placer deposits have also been mined for Pt in many
parts of the world, but are of little significance in Canada and
appear to have little potential elsewhere.
Some Ni-Cu-PGE deposits occur as individual sulphide
bodies associated with magmatic mafic and/or ultramafic
bodies. Others occur as groups of sulphide bodies associated
with one or more related magmatic bodies in areas or belts
up to tens, even hundreds of kilometres long. Such groups
of deposits are known as districts (e.g. Sudbury, Thompson,
Noril’sk-Talnakh, Kambalda, Raglan). In total there are 142
Ni-Cu-PGE deposits and districts in the world for which grade
and ore tonnage data have been reported that contain more
than 100 000 tonnes of resources and/or production, as shown
in Figure 1. These include deposits that are economic or possibly economic. The distribution of these deposits in Canada
is shown in Figure 2. Among the global deposits/districts
FIGURE 1. World map (after Chorlton, 2003) showing magmatic Ni-Cu-PGE sulphide deposits having resources and/or production greater than
100,000 tonnes of ore.
206
Magmatic Nickel-Copper-Platinum Group Element Deposits
Canalask
Wellgreen
Raglan horizon
Ferguson Lake
Nickel Mountain (E and L)
Rankin Inlet
Voisey's Bay
Delta
Rottenstone
Lynn Lake
Nemeiben Lake
Thompson
Manibridge
Namew Lake
Alexo Dumont sill
Bowden
Montcalm
Langmuir
Bucko
gabbro McWatters
Minago
Cat Lake
Gordon Lake
Thierry
Hart
Dumbarton
Maskwa West
Giant Nickel
Expo-Ungava
Lac des Isles
Shebandowan
Great Lakes Nickel
Marathon
Redstone
Texmont
Marbridge
La Force
Lorraine
Lac Kelly
Midrim
St Stephen intrusion
Sothman
Sudbury
Macassa
Kanichee
FIGURE 2. Geological map of Canada (after Wheeler et al., 1996), showing the distribution of magmatic Ni-Cu-PGE sulphide deposits with resources and/or production greater than 100 000 tonnes of ore. Ni-Cu deposits are shown in yellow, with PGE deposits shown in white.
there are 51 Ni-Cu deposits/districts and 5 PGE deposits/districts with greater than 10 million metric tonnes (MT), and
13 Ni-Cu deposits/districts and 2 PGE deposits/districts with
greater than 100 Mt.
Grade and Tonnage Characteristics
Among Ni-Cu deposits, Ni grades are typically between 0.7
and 3 percent, and Cu grades are between 0.2 and 2 percent
(Fig. 3). Ore tonnages of individual deposits range from a few
hundred thousands to a few tens of millions (Fig. 3A). Two
giant Ni-Cu districts stand out above all the rest in the world:
Sudbury, Ontario, and Noril’sk-Talnakh, Russia, with ore tonnages of 1645 and 1903 Mt respectively (Fig. 4). Other major Ni-Cu districts include the Thompson, Voisey’s Bay, and
Raglan districts in Canada, and Jinchuan (China), Kambalda
(Australia), and Pechenga (Russia).
The most important platinum-rich PGE district in the world
is the Bushveld Complex, South Africa (Pt/Pd = 1.35), which
contains two major types of PGE deposits. The next in importance is the Noril’sk-Talnakh district, which is exceptionally Pd-rich (Pd/Pt = 3.5) as a by-product of its Ni-Cu ores.
Stillwater, U.S. is also a significant producer of unusually rich
PGE ores (Pd/Pt = 3.6). Canada’s only primary producing deposit is the Lac des Iles Pd deposit (Pd/Pt = 9.2). The Sudbury
district, because of its size, also produces significant amounts
of PGE, although PGE tenors are comparatively low.
Grades and tonnages of global magmatic Ni-Cu deposits
(Fig. 4) show that Sudbury and Noril’sk-Talnakh are the
only districts that contain in excess of 10 million tons of
contained Ni. The other important districts tend to have Ni
contents of about 1 to 6 million tonnes.
Geological Attributes
Magmatic Ni-Cu-PGE deposits are consistently found in
association with mafic and/or ultramafic magmatic bodies,
but these parent bodies occur in diverse geological settings.
Their ages are predominantly Archean and Paleoproterozoic
(Fig. 3E). In the following account, the two main types, (1)
Ni-Cu and (2) PGE, and the four subtypes of Ni-Cu will be
treated separately. Each account will begin with regional settings and proceed with progressively more detailed characterization of the deposits, including local geological setting,
associated bounding rocks, the magmatic host rocks, and the
ores themselves.
Nickel-Copper Deposits
As noted above, these ores are characterized by an abundance of sulphide. Much of the S in the sulphides was de-
207
(A)
Number of deposits
100
90
80
70
60
50
40
30
20
10
0
5 >400 mT
0
50
100
150
200
250
300
Number of deposits
O.R. Eckstrand and L.J. Hulbert
4.5
4
3.5
3
2.5
2
1.5
1
0.5
0
350
Million tons (10 mT intervals)
30
20
10
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0
Pa
Ni (wt %)
(C)
Number of deposits
80
70
60
50
40
30
20
10
0
0.0 0.5 1.0 1.5 2.0 2.5 3.0
Cu (wt %)
rived by assimilation (e.g., Grinenko, 1985). It is likely that
the high content of S in the magma caused over saturation of
S in the magma, thus producing large quantities of sulphide
liquid. As stated above, Ni, Cu, and PGE partition preferentially into sulphide liquid relative to silicate liquid. On cooling, the liquid sulphide crystallizes over a large temperature
range to eventually form the common mineral assemblage
dominated by pyrrhotite-pentlandite-chalcopyrite.
Meteorite-Impact Subtype
Sudbury is the only known representative of this type
of Ni-Cu deposit. Because meteorite impacts are random
events on the earth’s surface, there is no possible regional
geological control on their distribution, with the exception
that subsequent geological events could obscure or obliterate their traces. In the case of the Sudbury Igneous Complex
(Fig. 5), it is well preserved although strongly deformed by
208
10
15
PGE (g/t)
20
(E)
Number of deposits
40
0
5
Ar
c
pr hea
o
n
M
t
e
es
ro
op
zo
ic
ro
Ne tero
op
zo
ic
ro
te
ro
zo
ic
Pa
le
oz
oi
O
c
rd
ov
ici
an
Si
lu
ria
n
De
vo
ni
an
Pe
rm
ia
n
Tr
ia
ss
i
c
Ju
ra
ss
Cr
i
c
et
ac
eo
us
Te
rti
ar
y
50
0
80
70
60
3.5 504.0
40
30
20
10
0
(B)
le
o
Number of deposits
60
(D)
Age
FIGURE 3. Range and distribution of (A) ore tonnages, (B) Ni grades,
(C) Cu grades, (D) PGE grades, and (E) ages of magmatic Ni-Cu-PGE
sulphide deposits. (Prepared from data in Eckstrand et al., 2004: in some
cases modified.) Because of inconsistency in reported PGE grades, the
values used are as follows: Pt + Pd for Bushveld, Stillwater, Lac des
Iles, and Marathon; PGE for Hartley; and (Pt+Pd+Rh+Au) for Munni
Munni.
later compressional events.
The meteorite impact took place at 1850 Ma, at the boundary between Neoarchean gneisses (about 2711 Ma) to the
north and Paleoproterozoic volcano-sedimentary rocks of the
overlying Huronian Supergroup (about 2450 Ma) to the south
(Pye et al., 1984; Naldrett, 1999). The impact produced a crater some 200 km in diametre, as well as radiating and concentric fracture/breccia zones that penetrated the surrounding
wall rocks for distances of tens of kilometres. The impact
generated a high-temperature melt layer that occupied the
floor of the impact crater. On cooling, the melt differentiated
into a lower norite unit and an overlying granophyre, separated by a thinner gabbro layer. Contacts between these units
are gradational, and finer-scale layering is absent. A discontinuous, more mafic basal unit termed the sublayer contains
most of the Ni-Cu ores and abundant xenolithic clasts (Souch
et al., 1969; Pattison, 1979; Naldrett et al., 1984). The melt
also intruded some of the radiating breccia zones, forming
many kilometres long quartz diorite dykes (offsets) extending outward from the SIC, and these also contain Ni-Cu ores
(Cochrane, 1984).
Subsequent regional overthrusting from the south compressed the southern half of the SIC and produced the presently exposed elongate basin 65 km long and 27 km across
(Shanks and Schwerdtner, 1991). The inward dip of the com-
Magmatic Nickel-Copper-Platinum Group Element Deposits
Ni% vs ore tonnage
Kambalda Voisey s Bay
Thompson Pechanga
Jinchuan
Sudbury
Agnew
Noril sk
Mount
Keith
Raglan
1
10
,0
00
Ni %
(A)
10
,0
Duluth
00
0.1
1,
00
0
Cu %
0,
Jinchuan
10
,0
00
,0
Pechanga
0.1
0,
0
0
00
00
0
100
00
0,
,0
00
10
00
10
10
1,
10
1
0
10
0.1
00
1,
Thompson
0.01
0.01
1000 10000
Ore, million tonnes
PGE g/t vs ore tonnage
(C)
10
,0
00
10
0,
00
1,
0
100
PGE g/t
00
0
1000 10000
100
Sudbury
Raglan
Noril sk
Voisey s Bay
Duluth
1
00
0,
10
00
0
,0
00
10
,0
00
Stillwater
10
1
00
10
Ore, million tonnes
Cu% vs ore tonnage
(B)
10
1000
0,
00
0
1
10
,0
00
0
0.1
10
1,
10
10
0.01
.01
Munni
Hartley
Marathon
0.01
0.1
1
10
100
0,
00
0,
00
0
Lac des
Isles
Bushveld
Ore, million tonnes
1000 10000
FIGURE 4. Grade and tonnage plots of global magmatic Ni-Cu sulphide
deposits. (A) Tonnages vs. Ni grades; (B) Tonnages vs. Cu grades; (C)
Tonnages vs. PGE grades. (Prepared from data in Eckstrand et al., 2004:
in some cases modified.) Inclined contours show quantities of contained
metals in each figure; tonnes for Ni and Cu, and kg for PGE.
plex averages about 30° along the less-deformed north range,
and 45° to 60° along the strongly deformed south range. The
total thickness of the complex is about 2.5 km.
The impacted country rocks contained significant amounts
of S in the form of sulphides. These were incorporated in the
initial super-liquidus melt as dissolved S, but with cooling,
the melt became saturated with respect to S. Sulphide liquid
was thus produced, which extracted Ni, Cu, and PGE from
the silicate melt. Another factor contributing to formation of
sulphide was the reduced solubility of sulphide in the melt
caused by the mixing of mafic and felsic target rocks. The
liquid sulphide, along with abundant fragmental material, segregated into a basal mafic noritic unit (sublayer) and collect-
ed in depressions (embayments) along the base of the melt
sheet. The Murray mine is in such an embayment (Fig. 5;
Souch et al., 1969). Sulphide liquid also accompanied melt
into the offsets. On cooling, the sulphide liquid crystallized
to form Ni-Cu-PGE ores. In some of the embayments, sulphide melt remaining after partial crystallization migrated
downward from the SIC into breccia zones in the footwall
rocks to produce particularly Cu and PGE-rich sulphide ore
veins and masses up to 400 m below the sublayer.
The resulting orebodies associated with the sublayer at
the base of the intrusion form irregular lenticular sulphiderich masses, with the longest dimension plunging steeply as
at the Murray mine on the South Range (Fig. 6A), and the
Strathcona, McCreedy East, and Fraser mines on the North
Range (Fig. 6B; Coats and Snajdr, 1984). Clusters of such
orebodies, similarly oriented, lie in the embayments and persist to great depths as at the Creighton mine. The orebodies in the offsets form discontinuous sulphide-rich sheets or
lenses with steep dips subparallel to the associated quartz
diorite offset. An example is the orebody in the Copper Cliff
mine shown in Figure 6C (Cochrane, 1984).
A different kind of ore zone occurs at the Falconbridge
East mine, where the ore is irregularly strung out as discontinuous sheets along the Main fault, which separates the felsic
norite of the SIC from the Stobie volcanics (Fig. 6D; Owen
and Coats, 1984). The deep Cu-PGE-rich ores in the footwall
below the SIC form sets of subparallel stringers and veins of
massive sulphides (Fig. 6B; Coats and Snajdr, 1984).
The sulphide ores consist of the typical magmatic sulphide minerals. In general order of abundance, they include
pyrrhotite, pentlandite, chalcopyrite, and pyrite. Bornite is
present in copper-rich ores, and South Range ores typically
contain arsenic minerals, including niccolite, maucherite,
gersdorfite, and cobaltite. The platinum group elements
occur as microscopic grains of numerous minerals, the most
abundant of which are michenerite (PdBiTe), moncheite
(PtTe2), and sperrylite (PtAs2).
Sudbury ores have many of the same textural features as
other magmatic Ni-Cu sulphide ores. Massive ores (Fig. 7C)
consist mainly of an annealed mosaic of subequant pyrrhotite grains with shreddy interstitial pentlandite. Breccia ores
(Fig. 7D) contain rock clasts and silicate grains suspended
in a matrix of sulphide (mostly pyrrhotite with patchy grains
of pentlandite; chalcopyrite often penetrates the rock clasts).
A distinctive feature of Sudbury sulphide-rich ores and the
hosting sublayer is the presence of clasts of ultramafic rock,
not exposed elsewhere but likely unmelted residue of one of
the rocks impacted by the meteorite.
Rift and Continental Flood Basalt-Associated Subtype
Ni-Cu deposits of the rift and continental flood basaltassociated subtype are the products of the magmatism that
accompanies intracrustal rifting events. They include the largest deposit, Noril’sk-Talnakh, (12.6 MT of contained Ni),
and several other large deposits, for example, Jinchuan (Chai
and Naldrett, 1992) and Duluth. The features that these deposits tend to have in common are that they are associated
with large magma systems, and that within these systems
the Ni-Cu sulphide ores tend to be associated with conduits
209
O.R. Eckstrand and L.J. Hulbert
N
Milnet
0
km
10
Nickel
Offset
Whistle
North Range
Shaft
Strathcona
Coleman
Longvac
Fecunis
Capreol
Fraser
Fecunis Lake
Levack
Levack West
McCreedy
Boundary
Hardy
Windy
L.
Norduna
Chelmsford
L.
L McKim
.
Murray
Trillabelle
Little StobieGarson
Stobie
Frood
SUDBURY
L.
L.
Collins
Ramsey
Lake
L.
Sultana
Chicago
Clarabelle
Victoria
East Falconbridge
Falconbridge
Copper Cliff North
Copper Cliff South
Creighton
Worthington
Sudbury Igneaous Complex
Proterozoic
LEGEND
Granophyre
Chemsford Formation
Quartz-rich gabbro
Onwatin Formation
Norite
Onaping Formation
Sublayer
Creighton, Murray granites
Quartzite
Greywacke, volcanic rocks
Archean
Granite gneiss and plutons
South Range Shear Zone Fault
Olivine diabase dykes
Ni-Cu-PGE deposits
FIGURE 5. Sudbury Igneous Complex: geological map (assembled from Pattison, 1979; Naldrett et al., 1984; Naldrett, 1989; Shanks and Schwerdtner,
1991).
or feeders to the larger igneous masses (in this last respect,
Duluth is an exception in which the low-grade Ni-Cu sulphides have not yet proven to be economic). Much of the
sulphide has been derived by contamination of the magma
through incorporation of S from adjoining wall rocks. Once
formed, and if in sufficient quantity, the sulphides tend to
settle gravitationally within the moving magma, and collect
in the conduits at points where magma velocity is reduced.
The sulphides have probably experienced progressive enrichment by repeated extraction of additional metals from
successive pulses of magma moving through the conduits
(Maier et al., 2001).
Noril’sk-Talnakh: The Ni-Cu-PGE ores of the Noril’skTalnakh district (Duzhikov et al., 1992; Naldrett and
Lightfoot, 1992) are spatially associated with the huge
Siberian flood basalt magmatic suite. In the Noril’sk-Talnakh
area, the sedimentary strata form a gentle north–south-trending syncline. Intruded into this sequence are elongate, gently
210
dipping sill-like mafic bodies that underlie the 3.5 km thick
lava sequence. These are the units with which the ores are associated (Fig. 8), and that are considered to be feeders to the
overlying volcanic rocks. All the ore-bearing sills lie within 7
km of the NNE trending Karayelakh fault, which is thought
to be part of the conduit system. The sills have thicknesses of
a few tens of metres, lateral extents of a few hundred metres,
and lengths of a few kilometres. They consist of a variety of
layer-like gabbro-dolerite units (Fig. 9; Distler, 1994). The
lowermost unit consists of an olivine-free gabbro-dolerite
contact facies overlain by coarser-grained taxitic olivine gabbro-dolerite, which passes upwards into picritic gabbro-dolerite. Olivine-free gabbro-dolerite and anorthosite units make
up the upper portions of these bodies. The sills are enveloped
by metamorphic aureoles of exceptional thickness (up to 200
metres) and, hence, are considered to have been conduits for
the passage of very large volumes of magma.
Three distinct types of Ni-Cu-PGE ore occur in specific
Magmatic Nickel-Copper-Platinum Group Element Deposits
Surface
(A)
(C)
Footwall
0
Shear
0
200m
200m
N
Norite
Ragged disseminated
sulphide
Interstitial sulphide
in norite
Gabbro-peridotite
inclusion sulphide
Inclusion massive sulphide
LEGEND
Sudbury
breccia
Country
rock
Sulphide
Quartz diorite
LEGEND
(D)
4525 Level
Felsic norite
Mafic norite, sublayer
Footwall breccia
Levack gneiss
Mafic - ultramafic rock
Main Zone
Diabase
85
Ore
Fault
(B)
Strathcona
82 E
Main
40
LEGEND
South Range
Norite
No
.1
Fau HW
lt
0
N
10m
84 E
Fault
70
85
Stobie
Formation
75
Nickel-copper
sulphide
Fault
McCreedy East
Deep Copper zone
0
Fraser Depth
Fraser No. 2 Fault
400m
FIGURE 6. Sudbury ore deposits: geological maps and sections. (A) Murray mine (after Souch et al., 1969); (B) Strathcona, McCreedy East and
Fraser mines (after Coats and Snajdr, 1984); (C) Copper Cliff South mine (after Cochrane, 1984); (D) Falconbridge East mine (after Owen and
Coats, 1984).
associations with the mineralized sills, and contribute to the
total resources of the Noril’sk-Talnakh ore field (Table 1).
1. Massive sulphide ores occur as flat-lying sheets and lenses
at the base of the sills, in some cases protruding downward
into the footwall rocks (Figs. 8, 9). One such massive sulphide orebody attains a thickness of over 50 m and lateral
dimensions of hundreds of metres. Some of the larger orebodies display remarkable sulphide zonation, ranging from
pyrrhotite dominated chalcopyrite-pentlandite assemblages
in the outermost and lower parts, through progressively
more copper-rich zones, to mainly Cu sulphides, chalcopyrite, cubanite, and mooihoekite together with pentlandite
in the central upper parts (Stekhin, 1994). The latter can
TABLE 1. Noril’sk-Talnakh Ore Field—Measured, Indicated, and Inferred Resources (2003)
Ore type
Rich (massive)
Ore (Mt)
88.7
Ni %
3.42
Cu %
5.38
PGE (g/t)
5–100
Cuprous (Cu breccia)
108.4
0.8
2.64
5–50
Disseminated
1706.3
0.51
1.02
2–10
Total
1903.4
0.66
1.31
have up to 25 to 30 percent Cu, 3 to 6 percent Ni, 50 to 60
ppm Pt, and 60 to 200 ppm Pd. This zonation of sulphides
is believed to result from fractionation in situ. The mechanism of early cumulate separation and basal segregation
of a pyrrhotite-like iron sulphide leaves a Cu-PGE-rich
supernatant liquid to crystallize last. These Ni and Cu-rich
massive sulphide ores have been the mainstay of Noril’sk
production for much of the district’s history.
2. Copper breccia ores as semiconformable sheet-like zones
occupy the upper contacts of the sills with the overlying
rocks (stringer-disseminated ores in Fig. 9). The breccia
comprises fragments of both the intrusion and wall rocks
in a matrix of mainly massive sulphide. Sulphide stringers
and disseminations accompany the breccias.
3. Disseminated sulphide ores form lenticular to tabular
layers in picritic gabbro-dolerite units within the sills.
The sulphides generally take the form of centimetre-size
spheres of chalcopyrite, pentlandite, and pyrrhotite dispersed through the host gabbro-dolerite. This was the first
ore type mined at Noril’sk; later it declined in importance
with the discovery of massive sulphide ores. However, it
is presently an important component in mining reserves
again due to the high price of platinum.
211
O.R. Eckstrand and L.J. Hulbert
ic rift zones or rifted arcs. They are generally
composed of strongly folded, basaltic/andesitic
volcanic rocks and related sills, siliciclastic sediments, and granitoid intrusions. They have been
metamorphosed to greenschist and amphibolite
facies, and typically adjoin tonalitic gneiss terranes. Komatiitic rocks form an integral part
of some of these greenstone belts. Examples
are the Kambalda district and the Mt. Keith deposit, respectively, from two greenstone belts
in Western Australia. The second setting is as
Paleoproterozoic komatiitic sills associated with
rifting at cratonic margins. Prime examples are
the Raglan horizon in the Cape Smith-Wkeham
Bay Belt of Ungava, Quebec, and the Thompson
district of the Thompson Nickel Belt, in northern Manitoba. The komatiitic rocks are set in a
sequence of volcano-sedimentary strata unconformably resting on Archean basement and are
D
weakly (Raglan) to intensely (Thompson) folded
and deformed. An additional Paleoproterozoic
C
example is the Pechenga Belt of Ni-Cu sulphide deposits in the Russian Kola Peninsula
(Melezhik et al., 1994).
The liquid-equivalent portions of ultramafic
komatiitic rocks are magnesium-rich (18%–
32% MgO), and therefore the precursor magmas
are very hot and fluid. Because of their primitive (high Mg, Ni) composition, the Ni:Cu ratio
of the associated sulphide ores is high, in many
cases 10:1 or more. The S in the sulphide ores
has been derived in significant proportion by
contamination from sulphidic wall rocks. The
commonly observed close spatial association
of these deposits and their hosts with sulphidic
sedimentary footwall rocks, and the similarity of
S isotopes and other chemical parametres of the
magmatic and sedimentary sulphides strongly
FIGURE 7. Typical magmatic Ni-Cu sulphide ore textures: (A) disseminated sulphides, Thompson; (B) matrix-textured sulphides, Lynn Lake; (C) massive sulphides, Lynn Lake; (D) sulphide
suggests that the S in these deposits was derived
breccia, Lynn Lake. Pyrrhotite=medium gray, pentlandite=light gray, chalcopyrite=yellow, locally from the sediments. This contrasts to
silicate gangue=dark gray to black. Photographs courtesy of L.J. Hulbert.
some degree with deposits like Noril’sk where,
although it is clear that S came from an extraneous
source,
that
source was not likely so near at hand.
Noril’sk-Talnakh ores are exceptionally rich in PGE, to
Two
types
of
Ni-Cu
sulphide ores characterize these dethe degree that the precious metals currently have approxiposits. Sulphide-rich ores comprising massive, breccia, and
mately the same value in the ores as the base metals. Noril’sk
matrix-textured ores (Fig. 7C, 7D, and 7B, respectively)
is the world’s leading producer of Pd, and supplies about 20
consisting of pyrrhotite, pentlandite, and chalcopyrite occur
percent of the world’s Pt, second only to the Bushveld.
at the basal contact of the hosting ultramafic flows and sills.
Komatiitic Volcanic Flow and Sill-Associated Subtype
These deposits are generally small, in the order of a few milKomatiitic Ni-Cu deposits are widely distributed in the
lion tonnes, and the grades are in the 1.5 to 4 percent range.
world, mainly in Neoarchean and Paleoproterozoic terranes
The second type, sulphide-poor disseminated ore (Fig. 7A),
(Lesher, 1989). Major Ni-Cu producing districts and other
forms internal lens-like zones of sparsely dispersed sulphide
prominent deposits are found in Australia, Canada, Brazil,
blebs that consist mainly of pyrrhotite-pentlandite. Deposits
Zimbabwe, Finland, and Karelia (Russia).
of this type also occur in both sills and flows, but the largest
deposits are in sills, with ore tonnages of 10s to 100s of milThe komatiitic subtype of Ni-Cu sulphide deposits occurs
lions, although grades are a modest 0.6 to 0.9 percent Ni. The
for the most part in two different settings. One setting is as
rich sulphide concentrations of the first type appear to result
komatiitic volcanic flows and sills in mostly Neoarchean
from significant contamination by S from host rocks, whereas
greenstone belts. Greenstone belts are typical terranes found
the lower-grade sulphides of the second type may not have
in many Archean cratons, and may represent intra-craton-
B
B
A
212
LEGEND
Permo-Triassic flood basalts
Upper Carboniferous to Upper Permian
terrigenous coal-bearing sediments
Middle to Upper Devonian carbonate
sediments
Middle Devonian sulphate sediments
Lower to Middle Devonian terrigenous
carbonate and sulphate sediments
Silurian carbonate sediments
Ti-augite dolerites
Talnakh group of intrusions
Magmatic Nickel-Copper-Platinum Group Element Deposits
Contact gabbro-dolerites; upper taxitic gabbrodolerites;gabbro-dolerites; non-olivine, olivinebearing, olivine-, and olivine-biotite gabbrodolerites
Picritic, taxitic, and contact gabbro--dolerites
with disseminated Cu-Ni sulphide ores
Massive Cu-Ni ores
Lower Talnakh intrusion
fault
Fault
FIGURE 8. Noril’sk-Talnakh: west-east geological section (after Duzhikov et al., 1992).
Layered series
of intrusive
and host rocks
Geological
column
Intrusive rocks
Volcanogenic &
sedimentary metamorphic
rocks
Sulphide ores
Stringer-disseminated ores,
veins of massive sulphide
Contact gabbro-dolerites,
anorthosites, leukocratic
anorthitic gabbro
Chromite-bearing taxitic
gabbroic rocks
Prismatic granular gabbrodolerites and diorites
Upper gabbro
(layered series)
Rare sulphide dissemination
Quartz-bearing olivine-free
gabbro-dolerites
Olivine-free and olivinebearing gabbro-dolerites
Olivine gabbro-dolerites
Main gabbro
(layered series)
Olivine-biotite gabbro-dolerite
Picritic gabbro-dolerites,
plagio-olivinites
clinopyroxenite, troctolites
Plagiochromitites
T
T
Lower gabbro
(layered series)
T
T
Disseminated ores with
ovoid and interstitial
sulphide aggregates
Taxitic olivine gabbro dolerite
Disseminated ores with
xenomorphic stringer-like
Olivine-free gabbro-dolerites, sulphide aggregates
contact dolerites
producers. The deposits in Western Australia are
much larger and more economically significant.
Kambalda, Western Australia: Ni sulphide
ores of the Kambalda district are typical of the
basal contact deposits associated with ultramafic
flows in greenstone belts (Gresham and LoftusHills, 1981; Gresham, 1986). They occur in
the Kambalda komatiite, which is a package of
ultramafic flows (2710 Ma) that has been folded into an elongate, doubly plunging anticlinal
dome structure about 8 km by 3 km (Fig. 10).
The underlying member of this succession is
the Lunnon basalt, and the overlying units are
a sequence of basalts, slates, and greywackes
(2710–2670 Ma). The core of the dome is intruded by a granitoid stock (2662 Ma), whose
dykes crosscut the komatiitic hosts and ores.
The Kambalda komatiite is made up of a
pile of thinner, more extensive sheet flows and
thicker channel flows (Perring et al., 1994).
The flows that contain ore are channel flows
in the lower part of the pile, and may be up to
15 km long and 100 m thick. These flows are
commonly interspersed with sulphidic interflow
sediment, from which the S that formed the ores
was probably derived (Lesher, 1989).
Most of the orebodies are at the basal contact
of the lowermost channel flows (accounting for
80% of reserves), although some do occur in
overlying flows in the lower part of the flow sequence (Fig. 11). The orebodies typically form
long tabular or lenticular bodies up to 3 km
long and 5 m thick. The ores generally consist
of massive and breccia sulphides (Fig. 7C,D)
at the base, overlain successively by matrixtextured sulphides (Fig. 7B), and disseminated
sulphides (Fig. 7A). The sediment that underlies the flow sequence is generally absent beneath the lowermost ore-bearing channel flow,
due to thermal erosion by the flow. Structural
deformation renders the shape and continuity
of ores more complicated in many instances.
Because of their weaker competency compared
to their wall rocks, sulphide zones are in many
cases strung out along, or cut off by, faults and
shear zones.
Homogeneous and zoned
massive sulphides
Komatiitic Ores in Rifted Cratonic Margin
Setting
Stringer-disseminated ores
There are two major Canadian nickel belts in
rifted
cratonic settings, both being segments of
FIGURE 9. Noril’sk-Talnakh: typical stratigraphic profile of an ore-bearing sill (after Distler,
the Circum-Superior Belt that encircles a large
1994).
part of the northern Superior province. One is
had an external source of S.
the Raglan horizon in the Cape Smith-Wakeham Bay Belt in
the Ungava peninsula of northern Quebec, and the other is
Komatiitic Ores in Greenstone Belt Setting
the Thompson Nickel Belt in northern Manitoba.
Canadian examples of this kind of Ni-Cu deposit are best deRaglan Horizon, Cape Smith-Wakeham Bay Belt: The
veloped in the Abitibi Greenstone Belt. The Alexo, Langmuir,
Raglan horizon is a series of Ni-Cu ore-bearing komatiitic
Redstone, and Texmont mines in the Timmins, Ontario area
sills emplaced along the northern contact of the Povungnituk
and the Marbridge mine in the Val d’Or area have been minor
Group, at the base of the overlying Chukotat Group
Sedimentary &
metamorphic
rocks
213
O.R. Eckstrand and L.J. Hulbert
0
2
Kilometres
Wroth
Juan
Durkin
f ro
y
lt
au
nF
Jua
t
rus
r Th
Otte
McMahon
N
Le
Gellaty Gordon
Gibb
Long
lt
F au
Loreto
Ken
Victor
Fisher
Lunnon
LEGEND
Felsic-intermediate
intrusive rocks
Felsic volcanic and
sedimentary rocks
Hanging wall basalts
Red Hill
Hunt
Ultramafic rocks
Footwall basalt
Sedimentary beds
Projected Nickel ore shoots
or surface occurrences
Fault
Inferred fault
Gold mine
FIGURE 10. Kambalda district: geological map (after Gresham and
Loftus-Hills, 1981).
uted to formation of the ores.
The Ni-Cu sulphide deposits of the Raglan horizon have
much the same development of ore types as the komatiitic
greenstone deposits. The Raglan deposits are basal contact
deposits consisting of massive and breccia sulphides at the
basal contact, overlain in turn by matrix-textured ores and disseminated sulphides. Tectonic deformation has disrupted and
mobilized some of the orebodies. Because of their remoteness
and accompanying higher production costs, only the richer
deposits can profitably be mined.
Thompson Nickel Belt: The Thompson Nickel Belt (TNB)
is a portion of the Paleoproterozoic Circum-Superior Belt
(Fig. 13), the rifted cratonic margin of the Archean Superior
province (Bleeker, 1991). The Ni sulphide ores that characterize the TNB are associated with ultramafic komatiitic sills
(1880 Ma; Hulbert et al., 2005) that intrude a sequence of
Paleoproterozoic sedimentary cover rocks (Ospwagan Group).
The latter consists of conglomerates, greywackes, iron formation, and pelitic and calcareous sediments capped by mafic to
ultramafic volcanics. Most rocks have suffered several periods
of intense deformation, and amphibolite to granulite facies
metamorphism (about 1820 Ma). Paleoproterozoic strata are
tightly infolded with the Archean basement gneisses. Original
relationships are strongly deformed and obscured. The TNB
on the northwest side abuts against the Paleoproterozoic
Churchill province along the relatively late Churchill-Superior
Boundary fault.
The ultramafic sills with which the ore is associated intrude the Pipe Formation of the Ospwagan Group. The Pipe
Formation consists of pelitic schists and iron formations. All
the known deposits in the Moak Lake-Thompson area are associated with sulphide iron formations of the Pipe Formation.
The Pipe 2 and Birchtree ultramafic sills intersect a sulphide
iron formation near the base of the Pipe Formation, whereas
the Thompson ultramafic sill intersects another sulphide iron
formation that is higher in the same pelitic unit.
Intense deformation has produced unusual modifications
of some of the nickel deposits. Some of the deformational
(Fig. 12). Together, these form the southerly leading edge
of the Cape Smith-Wakeham Bay Belt, northern Quebec, a
thin-skinned thrust belt which overrides the Archean craton.
The Povungnituk Group consists of basaltic and rhyolitic
volcanic and clastic sedimentary rocks, the products of continental rifting. The Chukotat Group comprises
massive and pillowed basalts and related mafic/
ultramafic sills.
In addition to the Raglan Horizon of
komatiitic sills along the Chukotat contact, there
is another wide zone of komatiitic differentiated mafic/ultramafic sills in the interior of the
Povungnituk Group. These Paleo-proterozoic
suites of komatiitic magmatic rocks (1918 Ma)
differ from the greenstone type of komatiites in
their lower liquid-equivalent MgO content (up to
only 16%–18%) and consequently Ni:Cu ratios
of the ores are lower, averaging about 3:1. There
are a number of economic Ni-Cu deposits in the
Raglan horizon, and as well there are many NiInterflow sediment
Komatiitic dunite
Aphyric komatiite
Cu occurrences elsewhere in this horizon and in
(predominantly sulphidic)
Massive nickel
the ultramafic units lower in the Povungnituk
Volcaniclastic breccia
Spinifex texture
sulphide ore
Group. The Raglan sills appear to have richer,
Pillow basalt
Massive basalt
Porphyritic komatiite
more abundant sulphide ore, likely because the
clastic sediments they intrude are sulphide-rich, FIGURE 11. Generalized section of komatiitic flows and related nickel deposits (after Lesher,
and have provided much of the S that contrib- 1989).
214
Magmatic Nickel-Copper-Platinum Group Element Deposits
FIGURE 12. Cape Smith Ungava district: geological map (from Canadian Royalties Inc. Web site).
features are due to the weak competency of massive sulphide relative to its wall rocks. The following descriptions
are arranged in order of increasing deformational effects
experienced by the various deposits. The Pipe 2 nickel deposit consists of massive and stringer sulphide concentrations
forming a U shape around the nose of the folded ultramafic
sill, and representing the original basal contact sulphide. The
Manibridge mineralized ultramafic is laced with pegmatitic
dykes that were mobilized out of the surrounding gneisses,
and present problems for mining. The Birchtree mine has one
ore zone that is an extensive sheet-like shear zone of massive and breccia sulphide. The Soab North mine consists of a
partly mineralized ellipsoidal boudin of ultramafic rock with
a nearly complete enclosing sheath of massive and breccia
sulphide. Ore in the Thompson mine, the principal deposit
in the belt, is associated with a highly fragmented ultramafic
sill, now dispersed as a zone of ultramafic boudins of all sizes,
aligned in a horizon within the pelitic schist unit. The ore consists of nickeliferous sulphides (pyrrhotite-pentlandite) as impregnations in the pelitic schist in a conformable zone that is
coextensive with the ultramafic boudins. Massive sulphides
are commonly coarsely recrystallized; pentlandite “eyes” up
to several cm are not unusual.
Other Mafic/Ultramafic Intrusion-Associated Subtypes
The host mafic/ultramafic intrusions associated with these
Ni-Cu sulphide deposit include a variety of types: multiphase
stocks (Lynn Lake, Proterozoic; Råna, Silurian), multiphase
chonoliths (Kotalahti, 1885 Ma), multiphase sills (Kanichee
and Carr Boyd Rocks, Archean), and highly deformed sills
(Selebi-Phikwe, Archean). The styles of mineralization are
also varied, including massive sulphides, breccia sulphides,
stringers and veins, and disseminated sulphides. Voisey’s
Bay is the most important example.
Voisey’s Bay: The Ni-Cu sulphide ores at Voisey’s Bay are
associated with the troctolitic Voisey’s Bay Intrusion, a part
of the anorogenic Nain Plutonic Suite in Labrador. These deposits have similarities to those at Noril’sk in that the role
of a feeder system appears crucial to the accumulation of
sulphides (Li et al., 2001).
The troctolitic intrusions (1290–1340 Ma) straddle the collisional suture (~1850 Ma) between the Archean Nain province gneisses (2843 Ma) to the east and the Paleoproterozoic
Churchill (Rae) province gneisses to the west (Ryan et al.,
1995; Naldrett et al., 1996; Fig. 14). These intrusions constitute a large magmatic system that includes granites, anorthosite, ferro-diorite, and troctolite. The Voisey’s Bay Intrusion
intrudes sulphide-bearing Tasiuyak gneiss of the Churchill
province, which appear to have been the source of much of
the S essential for forming the magmatic sulphides.
The Voisey’s Bay intrusion (Fig. 15) consists of a deep
western subchamber of troctolite-olivine gabbro that is connected by a subvertical mineralized feeder dyke of ferrodiorite, olivine gabbro, and troctolite. This dyke extends and
215
O.R. Eckstrand and L.J. Hulbert
98
Moak
56
Mystery
Birchtree
Thompson
Ospwagan
Lake
Pipe
Setting
Lake
100
55
N
B
Wintering
Lake
T
Hambone
Soab North
Soab South
Setting
98
55
Bowden
Bucko
Manibridge
Ni-Cu deposits
Ni-Cu mines
Serpentinized
ultramafic
Paleoproterozoic
Ospwagan Formation
Minago
William
L.
Lake
Winnipeg
0
10 20 30
Km
FIGURE 13. Thompson Nickel Belt: regional geology (after Hulbert et
al., 2005).
flattens generally eastward for about 3 km to the Eastern
Deeps troctolitic chamber, the largest exposed part of the intrusion. Along this strike length, three main Ni-Cu sulphide
zones constitute integral widened parts of the feeder dyke.
The Reid Brook mineralized zone (Fig. 15B) in the west is a
near-vertical, thickened part of the feeder dyke with a central
mineralized Leopard Troctolite (augite oikocrysts), sheathed
in a mineralized breccia and transected by steep massive
sulphide veins. The Ovoid deposit (Fig. 15C) is the richest
ore zone. It is a flat-lying spoon-shaped lens of massive sulphide enveloped in mineralized Leopard and variable-textured troctolite and breccia, representing a widened part of
the feeder dyke. The Eastern Deeps zone (Fig. 15D) is located where the feeder dyke widens out into the base of the
Eastern Deeps troctolite chamber. At the core of this junction
is a massive sulphide lens that expands and extends into the
Eastern Deeps chamber. The massive sulphide is enclosed in
a complex mineralized sheath of variable textured troctolite,
Leopard troctolite, and breccia, similar to the assemblages
accompanying the Reid Brook and Ovoid mineralized ores.
The feeder system and the Eastern Deeps zone are extensively mineralized in addition to the three zones mentioned
above. However, these ores represent sulphide-enriched locations in the feeder system, where it widened and slowed
the through-going flow of magma. As a result, the suspended
droplets of liquid sulphide settled gravitationally out of the
flowing magma and produced accumulations of ponded li-
quid sulphides that crystallized to form massive Ni-Cu sulphide. Each of the main ore zones includes veins of crosscutting massive sulphide that transect the other rock units,
indicating the later mobility of liquid sulphide.
Sulphide assemblages consist of the usual pyrrhotite-penlandite-chalcopyrite, with additional troilite and magnetite.
Pyrrhotite grain size is exceptionally coarse, up to 20 cm in
the massive sulphide ore, whereas pentlandite forms finer exsolution grains and lamellae. The Ni, Cu, and Co resources for
the Voisey’s Bay deposits are given in Table 2.
Platinum Group Element (PGE) Deposits
Economic Platinum Group Element deposits are extremely
rare. Two districts, Bushveld and Noril’sk-Talnakh, supply
the majority of the world’s PGE, although Noril’sk-Talnakh
has not been considered primarily a PGE deposit (Cawthorn,
1999; Cawthorn et al., 2002). Stillwater (Zientek et al., 2002)
is the only other significant PGE producer of this type. Lac
des Iles (Hinchey and Lavigne, 2005), small by comparison,
is Canada’s only producer of this type of deposit.
An obvious feature of the few economic PGE deposits in
the world is the large size of their host intrusions. An apparent
exception is the smaller Lac des Iles intrusion, but it is just
one of a number of comagmatic plutons in the area, which
together constitute a significant magma system. Mafic magmas have very low contents of PGE. Despite the high R factor of PGE (e.g., the high partition coefficients of PGE), the
sulphide has apparently equilibrated with large proportions of
magma to form economic PGE deposits.
Another feature shared by most known examples is the
small amount of sulphide (less than 3%) with which the PGE
are associated. The sparsely disseminated sulphide is mainly
chalcopyrite, but also includes pentlandite and pyrrhotite. The
PGE minerals occur in very minute quantities that have apparently exsolved from the iron and base metal sulphides during
cooling (Cabri, 2002). They include a host of known as well
as unnamed minerals. Pentlandite is the only common sulphide mineral that contains a significant amount of any PGE,
in this case Pd.
The small amount of sulphide appears due to the fact that
the only S involved is the original mantle S, with little or no
addition from the intruded wall rocks. Because the solubility
of S in mafic magmas is quite low, the amount of sulphide
produced when the magma reaches saturation is very small,
resulting in small, sparsely dispersed sulphides. This is in distinct contrast with Ni-Cu sulphide deposits in which the ore
consists of rich concentrations of sulphide.
Two distinct modes of PGE deposits are (1) the reef type,
and (2) the magmatic breccia type. Of the two, only the reef
type has proved to be a major producer.
TABLE 2. Voisey’s Bay Resources*
Ore type
Ore (Mt)
Ni %
Cu %
Co %
31
2.88
1.69
0.14
Additional, indicated
97
1.29
0.61
0.08
Additional, inferred
14
1
0.7
0.06
142
1.61
0.85
0.09
Ovoid deposit (proven)
Total
*From Inco 2001 Annual Report
216
Magmatic Nickel-Copper-Platinum Group Element Deposits
newly formed sulphide droplets, thus produced
then scavenge PGE from the silicate magma
Mesoproterozoic
and settle to form a sparse sulphide concentraHornblende
tion with a rich PGE content as a thin layer on
quartz monzonite
d
the floor of the overlying magma. An alternative
Hornblende
model proposes PGE carried upward by rising
d
quartz monzonite
drift
fluids (Boudreau and McCallum, 1992).
"Grey"
Bushveld Complex: The Bushveld Complex is
d
F
troctolite
d
Reid Brook a mafic/ultramafic layered intrusion (2060 Ma)
d
that extends over an area of 240 by 350 km in
Intrusion
"Red"
the Kapvaal craton, South Africa (Fig. 16A). It
troctolite
F
F
is noted not only for its large size, but also for
Norite,
d
d
the remarkable lateral extent of the Merensky
anorthosite
F Voisey's Bay
F
Ni - Cu - Co
Reef and the UG-2 chromitite, the two produWestern
F
CHURCHILL
(RAE)
PROVINCE
Deposit
cing PGE layers (Cawthorn et al., 2002). The
Extension
"Ovoid" Lake
Paleoproterozoic
4N
Complex’s total thickness of over 7 km is made
F
0
Churchill
Lake
up of four stratigraphic zones: (1) the Lower
Baseline
F
F
4S
gneiss
F
zone of bronzitites, harzburgites, and dunites;
8S
125
d2
Metadiabase (2)
(2) the Critical zone of chromitite, pyroxenEastern
ite, norite, and anorthosite, which includes the
NAIN PROVINCE
Deeps
drift
Merensky Reef and UG-2 chromitite as well as
Archean
d2
d2
numerous additional chromitites; (3) the Main
Nain
zone of norite and gabbronorite with minor angneiss
orthosite and pyroxenite; and (4) the Upper zone
d
Metadiabase (1)
of anorthosite, leucogabbro, and diorite, notable
Voisey's
d2
for numerous magnetitite layers up to 6 m thick.
Bay
Metagabbro
The whole of the sequence represents a simple
progression of cumulus minerals (Fig. 16B), but
d2
0 1 2 3 Km
actual succession of layered units is complex.
Much of the Critical zone is made up of cyclic
FIGURE 14. Voisey’s Bay district: geological map (after Naldrett, 1997)
units, each consisting of all or part of an upward
sequence of chromitite, pyroxenite, norite, and
anorthosite.
Reef Subtype
The Merensky Reef occurs near the top of the upper part
The reef or stratiform subtype of PGE deposits invariof the Critical zone, and the UG-2 chromitite at varying
ably occurs in large, well-layered mafic/ultramafic intrusions
depths below the Merensky: about 30 m below at Union,
(Naldrett, 1989). The most important examples include the
0 m below at Rustenburg, and 350 m below near Lebowa.
Merensky Reef and UG-2 chromitite reef of the Western and
The Merensky Reef lies at the base of the Merensky cyclic
Eastern Bushveld, the J-M Reef of the Stillwater Complex,
unit, below the basal pyroxenite (Fig. 16C). It generally
and the Main Sulphide zone of the Great Dyke (Prendergast
comprises a thin pegmatoidal feldspathic pyroxenite layer
and Wilson, 1989; Oberthuer, 2002). Other examples include
about 1 m in thickness, bounded above and below by very
the PGE zones in the Penikat (Finland; Alapieti and Lahtinen,
thin chromitite layers, and containing sparsely disseminated
2002), Munni Munni (Australia; Barnes et al., 1992), and the
Cu-Ni sulphides (up to 3%). The UG-2 chromitite occurs at
Rincon del Tigre (Bolivia; Prendergast, 2000) layered intruthe base of the UG-2 cyclic unit. It ranges from 70 to 130 cm
sions. All PGE reefs are typically more or less conformable,
in thickness, and has the same lateral extent as the Merensky
relatively thin layers (from less than one to a few metres)
Reef (see Fig. 16A). Estimated resources contained in the
within the well-layered sequence of the intrusions. No signifitwo reefs and the Platreef (discussed below) are shown in
cant examples are known in Canada.
Table 3 (Cawthorn, 1999).
The genesis of the Merensky and J-M reefs remains controThe PGE grade of the Merensky Reef is surprisingly universial. Because of their great lateral extent (virtually a single
form throughout the lateral extent of the unit, ranging belayer within the whole of each large intrusion) and the thintween 4.9 and 7.3 g/t. This is despite considerable variation
ness of the reefs, it is appealing to call on a magmatic process
along strike in the platinum group mineral assemblages,
operating during the course of formation of the layered intruwhich include alloys, sulphides, tellurides, and arsenides.
sions. The most generally accepted model involves the mixA feature common to sulphide reef-type deposits in laying of the residual magma remaining after partial crystallizaered intrusions is that they tend to occur at, or some distance
tion with a new pulse of magma emplaced above it (Campbell
above, the contact between the lower ultramafic zone and the
et al., 1983). It has been demonstrated experimentally that
upper mafic zone. The Bushveld and Stillwater reefs occur
this mixing mechanism can induce sulphide saturation. The
some distance above the contact, and the Hartley and Munni
NAIN PLUTONIC SUITE
2800E
600E
1200E
1600E
800W
Anaktalik
Bay
217
O.R. Eckstrand and L.J. Hulbert
TABLE 3. Bushveld Complex PGE Resources
Eastern Bushveld
Merensky
UG2
Western Bushveld (N.)
Merensky
UG2
Western Bushveld (S.)
Merensky
UG2
Northern Bushveld
Platreef
Total Bushveld:
Pt g/t
Pd g/t
Mt
3.2
2.4
1.4
2
1320
2035
3.2
2.4
1.4
2
435
675
3.2
2.4
1.4
2
760
1530
1.3
1.4
3060
2.3
1.7
9815
Tonnages and total average grades are calculated from the grade and
total ounces of Pt and Pd estimated by von Gruenewaldt, as cited in
Cawthorn, 1999.
Munni reefs (Barnes et al., 1992) lie immediately below this
contact.
Magmatic Breccia Subtype
The magmatic breccia subtype of PGE mineralization is
characterized by a large zone of sparsely disseminated sulphide in a mafic magmatic host that has a high proportion of
breccia clasts, both cognate and exotic. The most important
example of this subtype is the Platreef district in the Northern
Bushveld Complex, South Africa. Two similar Canadian deposits are in the River Valley intrusion (Tardif, 2000) and the
Marathon deposit in the Coldwell Complex (Barrie et al.,
2002). These deposits all comprise semiconformable zones of
PGE mineralization in a basal breccia unit of a layered mafic/
ultramafic intrusion. The Lac des Iles PGE deposit in Canada
is different from the preceding examples in that the intrusion
is a multiphase stock-like body rather than a layered intrusion.
Nevertheless, the deposit comprises disseminated sulphide
in a mafic magmatic breccia (Fig. 17), and on this basis, is
grouped in this subtype.
Lac des Iles: The Lac des Iles intrusion (2738 Ma) intrudes
a Neoarchean gneissic tonalitic terrane. It is one of a 30 kmdiametre ring of similar intrusions, and on a larger scale,
part of an ENE-trending zone of mafic plutons (Lavigne and
Michaud, 2002; Hinchey and Lavigne, 2005). The intrusion
consists essentially of a gabbronorite elliptical core, enveloped by a border unit of varitextured gabbro. The Roby Ore
zone lies between these two units at the west end of the intrusion and is made up of a combination of varitextured gabbro,
which is matrix to a heterolithic gabbro breccia. The varitextured gabbro contains abundant coarse-grained and pegmatitic patches, and the clasts in the heterolithic breccia are mostly
cognate mafic rock types. A 20 m-wide north-trending dyke-
FIGURE 15. Voisey’s Bay ore deposits: (A) Plan of the Voisey’s Bay intrusion feeder and associated ore zones (after Li et al., 2001). The ores are
projected to surface. (B) Reid Brook zone (after Li and Naldrett, 1999). (C) Ovoid orebody (after Li and Naldrett, 1999). (D) Eastern Deeps (after
Li et al., 2001).
218
Magmatic Nickel-Copper-Platinum Group Element Deposits
26 00'
28 00'
Bushveld Granite Suite
Bushveld Granophyre Suite
Layered rocks of Bushveld
Rooiberg Felsite Group
?
Merensky Reef and UG-2
Platinum mine (major
[active], minor)
City
30 00'
?
BRPM
Impala
Pandora
Rustenberg
Kroondal Lonmin
E&W
km
Pretoria
28 00'
100
Mag.
B
24 00'
PPRust (PlatreefSandsloot)
Lebowa
Messina
Marula
?
Driekop
?
Mooihoek
Onverwacht
Amandelbult
Northam
Union
0
A
PGE
and saussuritized feldspar. The PGE minerals are
mainly braggite, merenskyite, and kotulskite.
The stock-like Lac des Iles PGE deposit may
represent a conduit for mineralized magmatic breccia. If intruded to a higher level in the
crust, such a magmatic breccia could have been
emplaced as the stratiform basal PGE-mineralized breccia unit of a layered intrusion such as
the Platreef, the River Valley intrusion, or the
Marathon deposit.
Exploration Models
Because magmatic Ni-Cu-PGE sulphide deposits are invariably associated with mafic and/or
ultramafic magmatic bodies, such bodies constitute the first-order target for exploration. From
the preceding accounts, it is clear that the different types of deposits are associated with different
suites of mafic and/or ultramafic rocks, each of
which have somewhat different but typical attributes.
LEGEND
District Scale
The Voisey’s Bay discovery has emphasized,
Magnetite
as
is also the case at Noril’sk-Talnakh, the im4.5m
seam
portance of relatively small intrusions as parts of
large magmatic systems. Their role as conduits
for large volumes of magma provides sites for
Merensky Reef
accumulations of settled sulphide out of the passMerensky
ing magma. At Voisey’s Bay, a dyke-like conduit
Reef
that led from one magma chamber to a higher
Pegmatoid
0
Main
one contains the ores. At Noril’sk-Talnakh, sills
chromite
are the conduits that appear to have fed the flood
basalts, and in which the sulphide ores formed.
0.5
Although of different geometries, the conduits
record the passage of differing magmas by ex1.0m
hibiting significant differentiation: well-layered
Vertical scale
at Noril’sk-Talnakh (Fig. 9), distinct dyke facies
C
at Voisey’s Bay (Fig. 15B,C). In the case of the
FIGURE 16. Bushveld Complex: (A) Geological map showing the trace of the Merensky Reef Jinchuan deposits, the exposed ore-laden intruand platinum mines (modified after Campbell et al., 1983); (B) Stratigraphic range of cumulus sion itself may be a feeder to a much larger layminerals over the 4 zones of the complex (after Campbell et al., 1983); (C) Typical local straered magmatic complex, now largely removed by
tigraphy of the Merensky Reef and profile of PGE grade (after Naldrett, 1989).
erosion. If this interpretation is correct, the target
within a large mafic magmatic province would be
like pyroxenite lies between the Roby Ore Zone and the barsmaller differentiated cognate intrusions that may represent
ren gabbronorite to the east, and effectively marks the eastern
magma conduits.
boundary of mineralization.
Komatiitic deposits occur in small to medium-sized sills
The PGE mineralized Roby Ore zone is 950 m long by 8 m
and flows that invariably include ultramafic rocks, either
wide and is distinguished by the presence of up to 3 percent
alone or with mafic differentiates, usually gabbros. Those
irregularly disseminated sulphides. These include chalcopyrin greenstone belts tend to occupy a limited range of straite, pyrrhotite, pentlandite, and pyrite as grains and patches of
tigraphy at the district or regional scale. Thus, they form
submillimetre to a few centimetres size. Sulphide mineralizaclusters of ultramafic lenses along strike of formations as at
tion is coextensive with the varitextured gabbro breccia. PGE
the Langmuir and Redstone mines near Timmins, Ontario,
mineralization is Pd-rich (Pd:Pt = 9:1) and is locally erraticor whole formations as at Kambalda (Fig. 10). Similarly,
ally distributed, but on a mine scale is more or less uniform
the komatiitic deposits in cratonic margin rift settings occur
(Fig. 18). A higher grade zone (about 5 g/t) is localized on
in lenticular ultramafic sills strung out along strike in long
a 400 m-long portion of the western part of the pyroxenite
linear belts as at Thompson (Fig. 13) and Raglan horizon
dyke and a parallel portion of the adjoining varitextured gab(Fig. 12). These groupings of target rocks focus exploration
bro/heterolithic breccia. Within this higher-grade zone, the
at a district scale.
silicates are hydrothermally altered to amphibole, chlorite,
Ultramafic rocks associated with any of the deposit types
Augite
Bronzite
Cr.
Anorthosite
leuconorite
Norite
Pyroxenite,
melanorite
Chromite
seam
Olivine
Bronzite
Olivine
Ultramafic
Plagioclase
Mafic
grade
219
O.R. Eckstrand and L.J. Hulbert
Lac Des Iles
Baker Zone
Roby Pit
Phase 3
Shear
Ore
Roby
Zone
0.5
Diabase
Felsic Intrusives
Leucograbbo/Gabbro
Varitextured Gabbro
Heterolithic Gabbro Breccia
Gabbronorite
Gabbronorite Breccia
Magnetite Gabbronorite
Hornblende Gabbro
Clinopyroxenite
Samples > 2.5 g/T Pd
Samples > 0.7 g/T Pd
Twighlight
Zone
Moore
Zone
0
Creek Zone
1 km
Camp
Lake
Drill Core Sample >1 g/T Pd+Pt
Outline of Ore Zones - 2000
Faults
500m
1000m
FIGURE 17. Lac des Isle: geological map of intrusion (after Lavigne and Michaud, 2002).
W
E
500m
sulphide-rich ores are most likely to be found at
the base of those bodies. Determination of the
base of a given body is, thus, an important part
of exploration targeting. Within the komatiitic
greenstone belt type, the ores are generally located in the lowest flow, which is also generally
the most primitive in the pile of flows. Some
ores may lie at a somewhat higher level.
In areas that have been intensely deformed
and/or faulted, the distribution pattern of sulphide-rich zones may be more complex. For
instance, in the Thompson Nickel Belt, some of
the sulphide ores are extended far beyond the
parent ultramafic bodies.
The exploration of large layered mafic/ultramafic intrusions for PGE deposits should be focused from just below to some distance above
the main ultramafic-mafic contact. This is the
stratigraphic range of most of the PGE-rich
layers in the Bushveld, Stillwater, Great Dyke,
Munni Munni, and Rincon del Tigre deposits.
Because chromite is commonly a mineral associated with PGE deposits (e.g., the UG-2 reef
in the Bushveld Complex), geochemical surveys
should include Cr as well as the obvious suite
consisting of Ni, Cu, Co, Pt, and Pd.
Electromagnetic surveys designed to detect
conductors should be effective in locating the
sulphide-rich (i.e., massive, breccia, and matrix-textured sulphide) deposits. IP methods may
identify disseminated sulphides, but the presence of serpentinization in the ultramafic host
may render the technique ineffective.
Recent Advances
A much better appreciation of the role of
magma dynamics in the concentration and enrichment of magmatic Ni-Cu-PGE sulphide deposits has developed in the last decade or two.
The importance of changes in fluid flow, particuNorth America Palladium Ltd.
larly decreases in the rate of flow of magmas,
FIGURE 18. Lac des Isle: west-east section showing grade distribution (after Lavigne and has become clearer. The location of sulphide
Michaud, 2002).
concentrations in conduits at Talnakh-Noril’sk
and Voisey’s Bay, and near conduits in certain
of the komatiitic deposits, suggests that sulphides accumulate
have, in most terranes (especially greenschist facies metawhere the flow rate of magma was reduced and the entrained
morphism), undergone serpentinization with the accomsulphides were able to settle gravitationally to form rich basal
panying generation of magnetite. Consequently these bodies
concentrations.
typically have a well-defined magnetic response. Low-level
aeromagnetic surveys thus are indispensable at early explorNickel depletion of mafic magmatic rocks in connection
ation stages, especially in poorly exposed areas.
with the existence of Ni sulphide deposits has become better
Large layered intrusions are the prime targets in exploradocumented. It was anticipated that the formation of nickeliftion for PGE deposits, and have been recognized in many
erous liquid sulphide in a magma resulted by extraction of
regions. However, there may still be unidentified bodies in
nickel from the magma, thereby leaving the magma depleted
some poorly exposed or poorly mapped areas. Magnetic and
in nickel. Documentation has supported this theory, and it
gravity surveys could be of use in these areas.
now plays a part in exploration strategy.
Pd
Pdgrade
Grade
0m
> 5.0 g/tone
2.5 to 5.0 g/tonne
0.70 to 2.50 g/tonne
0.35 to 0.70 g/tonne
< 0.35 g/tonne
Outline of Phase 3 Pit
Present Surface
Outline of Pyroxenite Unit
Local Scale
Sulphide-rich Ni-Cu deposits achieve their concentrations
mostly through the settling effects of gravity. Consequently,
in virtually all magmatic bodies (sills, flows, and dykes), the
220
Knowledge Gaps
One of the gaps in our knowledge of Ni-Cu sulphide deposits is knowing the most important factor in triggering sulphide saturation in a given magma. Certain things are clear.
Magmatic Nickel-Copper-Platinum Group Element Deposits
The magma must have a sufficient dissolved content of Ni,
Cu, and PGE. Once a liquid sulphide is formed, it will tend
to equilibrate with the magma, and this means acquiring the
Ni, Cu, and PGE from the magma according to the partition
coefficients for those elements. It also is clear that much of
the S in magmatic Ni-Cu sulphide deposits has been derived
from sulphidic wall rocks, commonly pyritic sediments. Thus,
addition of S to the magma by incorporation of such material
leads to sulphide saturation. However, it is also known that by
increasing the silica content of the magma through incorporation of siliceous wall rock, the solubility of sulphide in the
magma is decreased, thereby producing sulphide saturation.
It remains unclear which of the two mechanisms is the more
critical in producing sulphide saturation. The significance for
exploration is whether it is essential to have wall rock rich in
sulphide as a source of S in order to better evaluate a priori
the nickel potential of a given mafic/ultramafic body. Existing
evidence tends to favor the sulphidic wall rock theory, but
more investigation of the settings of known nickel sulphide
deposits is needed in order to evaluate the importance of the
alternative theory.
In the case of PGE reef type deposits, there is still ongoing controversy over the main mechanism of concentration
of PGE in the thin extensive “reefs” that are hosted in very
large layered mafic/ultramafic intrusions. As noted above, the
magmatic theory emphasizing magma mixing is the more favored, but a “fluids from below” theory has some persuasive
arguments. This controversy will undoubtedly continue; it is
unclear whether there are important exploration ramifications
contingent on this question.
Acknowledgements
The authors are grateful for the helpful reviews of M.
Lesher and M. Duke. Their comments have led to much improvement of this manuscript. The editorial guidance of W.
Goodfellow is also appreciated.
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