Remedial Action Plan

Transcription

Remedial Action Plan- 2015 Addendum
Former Fansteel/V.R. Wesson Property
801 S. Market Street
Waukegan, Illinois 60085
South Lakefront Development
April 6, 2015
Revised September 25, 2015
Prepared for:
The City of Waukegan
100 N. Martin Luther King Jr. Ave.
Waukegan, IL 60085
Prepared by:
28835 N Herky Dr. Unit 120
Lake Bluff, IL. 60044
www.deiganassociates.com
Table of Contents
1.
BACKGROUND AND PURPOSE….…………………………………....................................4
2.
PURPOSE AND OBJECTIVE…….………..…………………...……………….……………5
3.
PROPOSED REMEDIATION OBJECTIVES….............………………………………..…..5
4.
REMEDIAL ACTION PLAN TASKS…….………………………………………...........…...8
5.
4.1
TASKS COMPLETED IN 2008-2009………………………………………………….……..…9
4.2
TASKS PROPOSED IN 2015 RAP ADDENDUM.…………………………………………...11
4.2.1
AREA 1 CONTAMINATED SOIL
REMOVAL AND DISPOSAL………………………....................................................11
4.2.2
AREA 1 CONFIRMATION SAMPLING…....…………………………….………....11
4.2.3
PLACEMENT AND CONFIRMATION SAMPLING
OF THE ENGINEERED BARRIER IN AREA 1……………………….…….……..11
4.2.4
ADDITIONAL SOURCE AREA CONFIRMATION
SAMPLING AND ANALYSIS………………………………….…………..................12
4.2.5
CONFIRMATION SAMPLING AND ANALYSIS OF
THE 2008 – 2009 CONSTRUCTED ENGINEERED BARRIER…………...……....13
4.2.6
VAPOR INTRUSION PATHWAY EVALUATION..……………………………......13
4.2.7
GROUNDWATER MONITORING EVALUATION………………………………..14
4.2.8
INSTITUTIONAL CONTROLS………………………………………………………15
REMEDIAL ACTION COMPLETION REPORT………………………………………….16
Figures
Figure 1:
Figure 2:
Figure 3:
Figure 4:
Figure 5:
Figure 6:
Figure 7A:
Figure 7B:
Figure 8:
Site Location Map
Site Topography Map
2008 – 2009 Source Area Soil Excavation Map
2008 – 2009 Source Area Confirmation Sample Map
Area 1 Soil Removal & Off-Site Disposal Area
2015 Proposed Monitoring Wells Map
2015 Source Area Confirmation Sample Map
Soil Testing Plan for Engineered Barrier
2015 Proposed Soil Gas Sample Map/Vapor Intrusion Pathway Evaluation
Tables
Table 1:
Table 2:
Table 3:
Table 4:
Table 5:
Table 6:
Table 7:
Table 8:
Former Fansteel SRP Submittals to IEPA
Groundwater Remediation Objectives
Soil Remediation Objectives
Remedial Action Technologies
2008 – 2009 Completed Source Area Confirmation Sampling
Proposed 2015 Area 1 Confirmation Sampling & Analysis Plan
Proposed 2015 Soil Source Area Confirmation Sampling & Analysis Plan
Proposed 2015 Perimeter Groundwater Sampling & Analysis Plan
Appendices:
A.
B.
C.
Photographic Summary of 2008-2009 Remedial Action Plan Work
Waukegan Groundwater Use Restriction Ordinance
Imported Barrier Soil Pre-Screening Laboratory Analysis
1.0
BACKGROUND AND PURPOSE
The Former Fansteel/V.R. Wesson property is approximately 11 acres in size and is bisected by
the City of Waukegan’s Market Street right of way. The property address is 801 S. Market Street
in Waukegan, Lake County, Illinois 60085. The property is currently vacant.
On February 7, 2008 the Illinois EPA approved the Remedial Action Plan dated January 15,
2008. Since then a substantial amount of remedial work has been completed before becoming
inactive within the Site Remediation Program. The purpose of this Remedial Action Plan 2015
Addendum is to update the site to reflect current conditions after a portion of the remedial work
was completed in 2008 through 2009. Below is a table of all the previous work submitted to
IEPA before this site became inactive.
Table 1: Former Fansteel Site SRP Submittals to IEPA
Document
Document Date
Enroll in SRP
Site Investigation Work Plan
Site Investigation Report
Supplemental Work Plan and Response to
IEPA Comments
Remedial Objective Report
2nd Supplemental Work Plan and Response to
IEPA Draft Comment
2nd Supplemental Sampling & Analysis
(Revised) Site Investigation Work Plan
Site Investigation Report Addendum
Remedial Action Plan
Remedial Action Plan, Revision 1
IEPA Approval Date
July 19, 2004
--
November 16, 2004
February 25, 2005
*March 8, 2007
*November 5, 2007
June 20, 2005
*March 8, 2007
October 21, 2005
*November 5, 2007
January 16, 2006
*March 8, 2007
January 26, 2007
March 8, 2007
September 6, 2007
September 18, 2007
January 15, 2008
November 5, 2007
November 5, 2007
February 7, 2008
*IEPA approval received after additional information was submitted
Remedial activities commenced shortly after the February 7, 2008 IEPA approval letter
regarding the Remedial Action Plan, Revision 1 in 2008 and continued through 2009 for the site.
During that time the eight designated contaminant source areas were excavated and placed onsite
at Area 1 (see Figure 5) for eventual offsite disposal at a licensed Subtitle D Landfill.
Approximately 10,000 tons were excavated from the source areas, disposal of material was not
completed at that time. Confirmation sampling was completed in six source areas, shown in
Figure 4. Excavated source areas were backfilled with Pre-Screened Borrow (See Data in
Appendix C) soil, a three foot engineered barrier was placed atop the entire site except in Area 1,
confirmation sampling is proposed in 2015 to confirm that soil meets Tier I Residential
Standards.
Work halted in 2009 due to the real estate market collapse, which depleted the investor’s funds
to complete the remedial activities. The City of Waukegan purchased the site in December of
4
2014 and plans to continue to transform this land into usable space as part of the City’s
Redevelopment Master Plan. The City is now leading completion of remaining incomplete
remedial work to obtain a No Further Remediation Letter for the 11 acre site.
2.0
PURPOSE AND OBJECTIVES
The purpose of this RAP 2015 Addendum document and prior SRP RAP submittals is to further
meet the requirements for a Remedial Action Plan (RAP) as defined in 35 IAC Part 740.450 and
update the Remedial Action Plan from 2008. The overall objective of the 2008 RAP Revision 1
that was approved by IEPA on February 7, 2008 was to reduce concentrations of constituents of
concern (COCs) in soil and groundwater to acceptable levels that could remain under an
engineered barrier without migration to Lake Michigan surface water. The objective of the
Remedial Action Plan 2015 Addendum is to demonstrate that the source area concentrations
were reduced to meet the 2008 objectives underneath the 2008 placed engineered barrier.
Another objective in this Addendum is to update the site based on current conditions from work
that has been completed since the approval of the Remedial Action Plan dated January 15, 2008.
The Illinois EPA approved the January 15, 2008 Remedial Action Plan on February 7, 2008;
thereafter, portions of the 2008 Remedial Action Plan were executed. To meet requirements of
USEPA RLF grant, the RAP 2015 Addendum will be reviewed by IEPA and also have a public
comment period. The goal for the Former Fansteel site is to obtain a NFR Letter so that this
property can be transformed into key Lakefront Development Property as part of Waukegan’s
Master Plan for the area. USEPA RLF Grant Funds combined with Waukegan funds are required
to achieve the NFR goal.
3.0
PRELIMINARY REMEDIAL OBJECTIVES
The IEPA approved Initial and Supplemental Site Investigation Reports and the ROR have
determined:
•
Institutional controls will be required to prohibit the use of groundwater on and down
gradient of the property as a means of eliminating the groundwater exposure pathway.
Residual compounds present in site soil have the potential to migrate to groundwater.
Measured groundwater concentrations for lead, iron, and manganese also provide a
basis for restricting groundwater uses at and near the site. The City of Waukegan
provides its municipal water supply from treated Lake Michigan water, and would
serve this property. Appendix B provides the Groundwater Use Restriction Ordinance
for this site.
•
Residual compounds of trichloroethene, arsenic, cyanide, mercury, and lead present
in soil, based on modeling in the ROR (21 October 2005), have the potential to
migrate to the Lake Michigan surface water pathway. The use of engineered barriers
and excavation of contaminated soil for off-site disposal address this site condition, as
presented in the approved 2008 RAP work and proposed 2015 RAP Addendum.
Groundwater sampling to be completed as part of the proposed 2015 RAP Addendum
will be performed to assure that contaminant levels in groundwater have been reduced
to meet the modeling to Lake Michigan surface water quality standards.
Remedial Action Plan-2015 Addendum
5
•
Certain residual compounds of antimony, arsenic, chromium, copper, lead, PCBs,
trichloroethene,
benzo(a)anthracene,
benzo(a)pyrene,
benzo(b)fluoranthene,
benzo(k)fluoranthene, chrysene, dibenzo(ah)anthracene, and indeno(1,2,3-cd)pyrene
in soil exceed ingestion and/or inhalation exposure objectives for residential and open
space development. The use of engineered barriers in the 2008 through 2009 RAP
work addressed this site condition. The proposed 2015 RAP Addendum work will
further address the conditions by excavating and disposing of Area 1 soil at an off-site
licensed Subtitle D Landfill. Area 1 includes the soil placed on top of REC 1-SS1 in
addition to REC 1-SS 1.
•
Construction worker health and safety planning will be required to protect workers
during soil handling and subsurface construction below the engineered barrier during
future development work. Constituents that pose a threat include antimony, arsenic,
chromium, copper, lead, benzo(a)pyrene, benzo(a)anthracene, benzo(b)fluoranthene,
dibenzo(ah)anthracene, naphthalene, PCBs, and trichloroethene.
Exclusion of the groundwater exposure route has been proposed for this site using
institutional controls; therefore, the maximum detected groundwater concentrations (or Class
I groundwater standard, if higher) were proposed as the groundwater remediation objectives.
Table 2 summarizes the proposed groundwater remediation objectives for the constituents
detected in groundwater can be found below:
Table 2: Proposed Groundwater Remediation Objectives
Groundwater Contaminants
Trichloroethene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Chrysene
Dibenzo(a,h)anthrancene
Indeno(1,2,3-cd)pyrene
Bis(2-ethylhexyl)phthalate
Aluminum
Arsenic
Beryllium
Cadmium
Chromium
Iron
Lead
Manganese
Nickel
Mercury
Vanadium
Zinc
Proposed Groundwater Remediation Objective
0.023 mg/L
0.0041 mg/L
0.0025 mg/L
0.0013 mg/L
0.0060 mg/L
0.0010 mg/L
0.0004 mg/L
0.24 mg/L
35 mg/L
0.11 mg/L
0.0067 mg/L
0.0059 mg/L
0.16 mg/L
240 mg/L
0.25 mg/L
5.5 mg/L
0.24 mg/L
0.0023 mg/L
0.079 mg/L
0.13 mg/L
6
In the 2008 Remedial Action Plan, Proposed soil remediation objectives for the constituents
detected at the site include:
Table 3: Preliminary Soil Remediation Objectives
Soil Contaminants
Aldrin
Lindane
Proposed Soil Remediation Objective
Lowest Tier 1 SRO – 0.04 mg/kg- ING
Tier 2 SRO – 0.37 mg/kg – MGW
PCBsa
Lowest Tier 1 SRO* - 1 mg/kg – ING
≤ 1 ppm: Residential yards, parks, railroad
embankment
>1 – ≤ 10 ppm: Open space green areas and parkway
with an engineered barrier of 0-3 ft clean, compacted
soil
>10 – ≤ 25 ppm: Engineered barrier of asphalt,
concrete, and/or building
Tier 1 background* - 1.84 mg/kg
Lowest Tier 1 SRO* - 0.6 mg/kg - MGW
Lowest Tier 1 SRO* – 88 mg/kg - ING
Tier 2 SRO – 154 mg/kg - MGW
Tier 2 SRO* – 231 mg/kg - MGW
Tier 2 SRO – 0.7 mg/kg - MGW
Tier 2 SRO* - 0.7 mg/kg - MGW
Tier 2 SRO – 44 mg/kg – MGW
Lowest Tier 1 SRO* - 5 mg/kg – MGW
Lowest Tier 1 SRO* - 13 mg/kg - ING
Tier 2 SRO* - 2205 mg/kg - MGW
Lowest Tier 1 SRO* - 5.2 mg/kg - MGW
Lowest Tier 1 SRO* - 24 mg/kg - MGW
Lowest Tier 1 SRO* - 40 mg/kg – MGW
Lowest Tier 1 SRO* - 2900 mg/kg - ING
Lowest Tier 1 SRO* - 107 mg/kg - MGW
Lowest Tier 1 SRO* – 8 mg/kg - MGW
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Dibenzo(a,h)anthracene
Indeno(1,2,3-cd)pyrene
Carbazole
Chrysene
Methylene chloride
Naphthalene
Phenanthrene
Tetrachloroethene
Trichloroethene
1,1,2-Trichloroethane
Vinyl chloride
Antimony
Arsenic
Barium
Cadmium
Chromium
Cyanide
Copper
Lead
Mercury
Selenium
7
Notes and Acronyms:
* Indicates proposed SRO for each constituent is exceeded prior to excavation and soil disposal.
ING = based on ingestion exposure route;
MGW = based on migration to groundwater exposure route.
a)Tier 3 SROs were proposed in 2008 for PCBs following the applicability requirements and
methodologies for the development of PCB remediation objectives in 40 CFR 761. The
proposed PCB SROs are:
≤1 ppm: Residential yards, parks, open space (unrestricted)
>1 – ≤10 ppm: Open space green areas and parkway with an engineered barrier of 3 ft.
clean, compacted soil
>10 – ≤25 ppm: Engineered barrier of asphalt, concrete, and/or building
> 25 ppm: Off-site disposal
4.0
REMEDIAL ACTION PLAN TASKS
The IEPA approved the January 15, 2008 Revised Remedial Action Plan that summarized the
remedial action technologies that would be implemented to facilitate the planned
redevelopment as part of Waukegan’s Master Plan. The remedy selected to address the
contamination was to excavate higher concentrated source areas, place in Soil Management
Zones (SMZs) during future development and/or to dispose off-site at a Licensed Subtitle D
Landfill and the placement of a 3 foot engineered barrier of clean soil that meets residential
remedial objectives atop the entire site. Table 4 summarizes the remedial action technologies
presented in the 2008 Revised RAP that were approved by IEPA in a letter dated February 7,
2008.
Table 4: Remedial Action Technologies
Remedial Technology
Engineered Barrier of 3
feet of clean soil
Engineered Barrier of
Asphalt or Concrete
Engineered Barrier of
Building Foundation (with
Vapor Barrier)
Soil Management Zone w/
Engineered Barrier during
Future Development
Applicable Areas
Exposure Route
Addressed
Open space green areas and Soil ingestion; Soil
parkways
Migration to Groundwater
Sidewalks, Roads, Alleys,
Soil Ingestion; Soil
Parking Lots
Inhalation; Soil Migration
to Groundwater; Soil
Migration to Surface
Water
Residential Buildings,
Commercial Buildings,
Inhalation;
Parking Structures
Soil Migration to
Groundwater;
Soil Migration to Surface
Water
Parking Lots, Roads,
Alleys, Multi-Tenant Condo Inhalation;
Buildings, Parking
Soil Migration to
8
Structures, New Railroad
Embankment
Soil Excavation and
Placement in Soil
Management Zones and/or
Off-Site Licensed Landfill
Disposal
4.1
Designated Areas depicted
in Figure 3 and Figure 5
Groundwater;
Water
Inhalation;
Soil Migration to
Groundwater;
Water
TASKS COMPLETED IN 2008-2009
The remedy selected to address the contamination was the excavation and placement in Area
1 and/or Off-Site Licensed Landfill Disposal of higher concentration source area
contaminated soil, in combination with the use of engineered barriers. During the 2008 –
2009 RAP excavation work, contaminated source areas were excavated and placed in Area 1
shown in Figure 5, Area 1 includes the soil placed on top of REC 1-SS1 as well as REC 1SS 1. All excavated source material was placed in Area 1 and will be removed to a licensed
landfill during 2015-2016.
Eight of the nine contaminated sources areas have been excavated in accordance with the
2008 IEPA approved RAP and placed at Area 1 for disposal shown in Figure 5.
Approximately 10,000 tons of excavated source material has been placed at Area 1 onsite, for
planned 2015 offsite disposal at a licensed Subtitle D landfill. After the eight source areas
were excavated and placed on-site at Area 1 during the 2008 – 2009 RAP work, confirmation
sampling was completed. Table 5 summarizes the 2008 – 2009 confirmation sampling that
was completed at source areas. Figure 4 illustrates source area confirmation sampling
completed in 2008 through 2009 after the February 7, 2008 approval letter from IEPA of the
Revised Remedial Action Report Dated January 15, 2008. Confirmation sampling was
completed at six source areas and partial confirmation sampling was completed at one source
area.
Table 5: 2008 – 2009 Completed Source Area Confirmation Sampling
Source Area
REC7 – SS2
REC1 – SS3
Soil Boring ID
Depth (ft. bgs)
NSW
ESW
SSW
WSW
BOT N
BOT S
NSW
ESW
SSW
WSW
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Laboratory Parameters:
Testing Completed
VOCs, PCBs, PAHs, TPH as
gasoline and diesel, total metals,
and pH
9
REC1 – SS4
REC8 – SS1
REC1 – SS7
REC1 – SS8
REC1- SS14
BOT E
BOT W
NSW
ESW
SSW
WSW
BOT N
BOT S
NSW
ESW
SSW
WSW
BOT N
BOT S
NSW
ESW
SSW
WSW
BOT N
BOT S
NSW
ESW
SSW
WSW
BOT E
BOT W
ESW
0.5
0.5
1.25
1.25
1.25
1.25
2.5
2.5
3.5
3.5
3.5
3.5
7
7
3
3
3
3
6
6
1.5
1.5
1.5
1.5
3
3
1.5
The objective of the source area soil removal and confirmation sampling was to demonstrate
reduction in soil contaminant levels to meet Proposed Remedial Objectives prior to
placement of the engineered barrier. After the source areas were excavated and placed at
Area 1 on-site, the voids were backfilled with imported clean fill material.
A minimum of a 3-foot clean soil cover was approved in the 2008 RAP, to be placed in areas
with PCB > 1 mg/kg ≤ 10 mg/kg and in areas with PAHs and/or arsenic above Tier 1
ingestion SRO. During the 2008 through 2009 approved RAP work, a 3 foot engineered
barrier was placed atop the entire site, except in Area 1.
When referring to on-site cleanup and disposal of PCB remediation waste, a cap means a
uniform placement of concrete, asphalt, or similar material of minimum thickness spread
over the area where remediation waste was removed or left in place in order to prevent or
minimize human exposure, infiltration of water, and erosion (40 CFR 761.61(a) (7). The cap
was designed and constructed in accordance to 40 CFR 264.310(a), ensuring that it complies
with the permeability, sieve, liquid limit, and plasticity index parameters in 40 CFR
761.75(b)(1)(ii) through (b)(1)(v).
10
Work that is being proposed as part of the 2015 RAP addendum include sampling imported
fill/engineered barrier material as discussed in Section 4.2.3 and 4.2.5.
4.2
TASKS PROPOSED IN 2015 RAP ADDENDUM
4.2.1
AREA 1 CONTAMINATED SOIL REMOVAL AND DISPOSAL
The 2008 RAP remedial technologies proposed the use of disposal off-site at a licensed
Subtitle D Landfill. Approximately 10,000 tons of contaminated soil has been placed at Area
1 onsite during 2008 through 2009 for offsite disposal in a licensed Subtitle D landfill (see
Figure 5). To facilitate the 2015 remedial activities that stem from the approved 2008 RAP,
a soil sample will be collected from Area 1 of excavated contaminated material to be
analyzed for Waste Profile approval for disposal at Advanced Disposal Zion Landfill
Facility. Upon Landfill Waste Profile approval the approximated 10,000 tons contaminated
soil located in Area 1 will be disposed of at Advanced Disposal Zion Landfill in Zion,
Illinois during 2015-2016.
4.2.2
POST-EXCAVATION AREA 1 CONFIRMATION SAMPLING
Once the soil located at Area 1 has been disposed of at Zion Landfill Facility, confirmation
sampling will be performed to ensure soil meets the 2008 Proposed Soil Remedial
Objectives. A total of 6 side wall and 2 bottom floor soil samples will be collected from the
first 0.5 feet of soil in Area 1. All samples will be analyzed for APP A PART 740 TCL and
TPH as gasoline and diesel.
Table 6: Proposed 2015 Area 1 Confirmation Sampling & Analysis Plan
Source Area
Soil Sample ID
Sample Depth
Testing To Be Completed
Area 1
Stockpile
Post Removal
Sampling
NSW 1
NSW 2
ESW
SSW 1
SSW 2
WSW
BOT E
BOT W
0.5
0.5
0.5
0.5
0.5
0.5
1
1
APP A PART 740 TCL
and TPH as gasoline and
diesel.
Sampling protocols and laboratory methods will follow IEPA and USEPA-approved
methods. Illinois EPA practical quantitation limits (PQLs) established under the Illinois Site
Remediation Program and TACO regulations will be used by the laboratory. Laboratory
analysis will be conducted by an Illinois EPA-accredited laboratory, Test America
Laboratory, of University Park, Illinois.
4.2.3
PLACEMENT AND CONFIRMATION SAMPLING OF THE
11
ENGINEERED BARRIER IN AREA 1
The excavated Area 1 will be backfilled with pre-screened clean material that meets Tier 1
Residential Standards completed using the IEPA approved composite sampling method as
discussed in detail below. After Area 1 is disposed off-site at a licensed landfill and the void
is backfilled with clean soil. A 3 foot engineered barrier comprised of clean soil, will be
placed atop the former Area 1.
Imported fill material for use as a clean fill/engineered barrier in Area 1, will be evaluated
after placement. All loads brought to the site will be visibly screened by an environmental
professional before placement. Evaluation of clean soil will be completed in accordance with
Comment 2 of the IEPA Approval Letter of the 2008 RAP dated February 7, 2008. The
imported clean material will be tested from 1 composite sample collected from 4 sections of
2015 placed engineered barrier in Area 1. The composite sample will be analyzed for
Appendix A-Target Compound List in 35IAC PART 740. The VOC sample will be collected
from a grab sample rather than a composite sample.
4.2.4
ADDITIONAL SOURCE AREA CONFIRMATION
SAMPLING AND ANALYSIS
As demonstrated in Figure 4, source area confirmation sampling was not completed in two
areas that had been excavated and placed at Area 1 on-site during the 2008 through 2009
Remedial Action work. Confirmation sampling will be completed at the three locations
shown Figure 7A. Confirmation samples will be collected from the center of each sidewall
and one at the bottom of both REC 1-SS1 and REC1 – SS15 excavated areas to document the
level of residual contamination (if any). Confirmation samples will be collected from six (6)
sidewall and two at the bottom of REC 1-SS14 (see Figure 7A for sample locations). The
eighteen (18) confirmation samples will be analyzed for Appendix A-Target Compound List
in 35IAC Part 740, TPH as gasoline and diesel.
Confirmation samples will be collected from eighteen soil borings that will be advanced at
REC 1-SS15, REC 1-SS14, and at REC 1-SS1. The drilling activities for the completion of
the soil borings will be conducted using a direct-push GeoProbe® rig. The soil sampling
procedures will be performed in accordance with IEPA protocols. The soil borings will be
advanced to depths ranging from 0.5 to 6 feet below ground surface (bgs). Sidewall and
bottom samples will be located under the cap by re-establishing the site 100’ grid system and
measuring the rectangle.
Each sample depth has been determined from the findings in the 2007 Site Investigation and
approved in the 2008 RAP. The confirmation sample depths for REC1-SS14 and REC1-SS15
were selected prior to the placement of the 3 foot engineered barrier. The 2015 confirmation
sample depths will be the 2008 sample depth plus 3 feet (which accounts for the 2008-2009
placed engineered barrier). A minimum of one soil sample will be collected from each of the
soil borings completed at the Site. The soil samples will be analyzed for the following: TCL
in Appendix A of 35 IAC PART 740 plus TPH as gasoline and diesel, total metals, and pH.
Table 7 summarizes the confirmation sample quantities, depths and analytical plan for each
sample.
12
Table 7: Proposed 2015 Soil Source Area Confirmation Sampling & Analysis Plan
Depth below
Laboratory
Engineered
Parameters:
Source Area
Sampling Procedures
Barrier Layer
Testing
(ft. bgs)
Completed
NSW
0.5*
ESW
0.5*
REC1 – SS1
Four (4) Sidewall Samples
SSW
0.5*
One (1) Bottom Floor Samples
WSW
0.5*
BOT
1*
NSW 1
4.5
ESW 1
4.5
TCL in App A
ESW 2
4.5
of 35IAC PART
SSW 1
4.5
Six (6) Sidewall Samples
740 and TPH as
REC1 – SS14
Two (2) Bottom Floor Samples
WSW 1
4.5
gasoline and
WSW 2
4.5
diesel.
BOT E
6
BOT W
6
NSW
4.5
ESW
4.5
Four (4) Sidewall Samples
REC1 – SS15
SSW
4.5
One (1) Bottom Floor Samples
WSW
4.5
BOT
6
*REC1-SS1 confirmation sampling will be completed prior to the placement of the 3 foot
engineered barrier.
Soil
Boring
ID
4.2.5 CONFIRMATION SAMPLING AND ANALYSIS OF THE 2008
THROUGH 2009 CONSTRUCTED ENGINEERED BARRIER
The clean soil engineered barrier that was placed atop the entire site was pre-screened with
lab analysis as shown in Appendix C in 2008 through 2009. It will further be tested to ensure
it meets Tier 1 residential standards. The clean fill testing will include collecting two (2)
composite sample per acre of the Site at random depths (See Figure 7B). Four (4) discrete
surface samples will be collected from each acre of the engineered barrier to make one
composite. Imported material samples will be analyzed for TCL in Appendix A of 35IAC
PART 740. The VOC sample will be collected from a grab sample rather than a composite
sample as per IEPA comment 2 in the approval letter dated February 7, 2008.
4.2.6
VAPOR INTRUSION PATHWAY EVALUATION
To demonstrate compliance with soil gas remediation objectives for the indoor inhalation
exposure route, three soil gas samples will be collected from REC1–SS4, REC1–SS7, and
REC1–SS14. Sample locations were selected based on 2008 through 2009 confirmation
sampling completed. The proposed locations of the samples are depicted on Figure 8. The
13
soil gas samples will be collected at least 6 feet below the ground surface (bgs), but above the
saturated zone (estimated to be 7.7 feet bgs after the placement of 3 ft. engineered barrier).
The sampling will not take place within 48 hours of a rainfall event of ½ inch or greater. A
direct push method will be used to advance a heavy-gauge decontaminated steel probe, with
an expendable tip, to the desired depth. Once the desired depth is reached, a 1/8 to 1/4 inch
diameter run of either Teflon® or nylon tubing will be connected to the expendable point
holder. Following this, the rods will be pulled up 3-6 inches to create a cavity from which the
sample is collected. The rods would then be sealed at the surface using bentonite, clay or a
water dam. A system leak test will be performed using helium (or another tracer gas) to
determine that there are no leaks around the sampling train. The sampling train will be
purged a minimum 3 volumes prior to sample collection. The samples are to be collected in
either a Tedlar bag or Summa Canister at a flow rate no greater than 200 ml/min. The
samples will be sent to a NELAP certified laboratory, Test America Labs, Inc., under chainof-custody procedures for TO-15 analysis.
4.2.7
GROUNDWATER MONITORING EVALUATION
In the approved 2008 Revised RAP, a re-evaluation of the potential for groundwater
Contaminants of Concern (COCs) to migrate off site and for residual soil COCs to leach to
groundwater was to be completed after the RAP is implemented. To evaluate reduction in
groundwater contaminant concentrations, groundwater samples will be collected from six (6)
perimeter wells, five (5) will be installed on the eastern (down gradient) edge of the property
and one well installed on the western edge of the property (up gradient) that will be
constructed in 2015 as part of the Remedial Action Plan 2015 Addendum. One well cluster
(Deep 40ft, Shallow 20ft.) will be placed in the center of the east side of the site. Consecutive
quarterly groundwater sampling for a minimum of one year will be performed to assure that
contaminant levels in groundwater have been reduced to meet the Lake Michigan surface
water quality standards. All groundwater samples will be analyzed for VOCs, PAHs, total
and dissolved metals as per comment 3 of the IEPA approval letter dated February 7, 2008.
This re-evaluation will be presented in the 2015 Remedial Action Completion Report
(RACR).
Perimeter well construction and groundwater sampling methods will follow IEPA protocol.
Four monitoring wells will be constructed using hollow stem auger drilling techniques and
completed as 2-inch diameter PVC monitoring wells with a 10 foot slotted screen. All
monitoring wells will be completed at 20 feet below ground surface (bgs). One deeper well
will be constructed to 40 ft. Each well will have locking steel protectors for security
purposes.
Based on known geologic conditions at the property from observations noted in the previous
Site Investigation work completed in November 2004 and January 2005, it is anticipated that
well depths will extend to 20 feet below surface. The depth chosen is based on previous
geologic cross-sections which indicated groundwater can be found as deep as 12.1 feet
(before the 3 ft. engineered barrier was placed in 2008). Depth in 2015 would be 15.1 as the
3 foot engineered barrier was placed atop the entire site. Depth is below the shallow pooling
of water is found around 4.7 feet bgs (before the 3 ft. engineered barrier was placed in 2008).
14
Depth of shallow pooling is now, in 2015, 7.7 feet bgs. One deeper well to 40 ft. will be
nested on the east in the center of the site.
Wells will be developed and purged prior to groundwater sampling using dedicated bailers or
a peristaltic pump per IEPA protocol. Monitoring wells were purged a minimum of 3 well
volumes or until dry and allowed to recover prior to sample collection. Field readings will be
collected for pH and specific conductivity to evaluate adequate development and stabilization
of the wells. After each well has recovered to at least 90% of its static water level,
groundwater samples will be obtained using low-flow peristaltic pump or designated bailers,
thereby minimizing contaminant volatilization during sampling. Groundwater samples will
be placed directly into laboratory provided pre-preserved containers and then stored in a
cooler on ice. Table 8 summarizes the groundwater sampling and analytical plan. Figure 6
shows the proposed well locations.
Table 8: Proposed 2015 Perimeter
Groundwater Sampling & Analysis Plan
Well ID
Depth (ft. bgs)
Testing Completed
MW-11
MW-12
MW-13A
MW-13B
MW-14
20
20
20
40
20
VOCs/PAHs/Total and Dissolved Metals
Sampling protocols and laboratory methods will follow IEPA and USEPA-approved
methods. Illinois EPA practical quantitation limits (PQLs) established under the Illinois Site
Remediation Program and TACO regulations will be used by the laboratory. Laboratory
analysis will be conducted by an Illinois EPA-accredited laboratory, Test America
Laboratory, of University Park, Illinois.
Institutional controls (IC) prohibiting the use of groundwater will be used to exclude the
groundwater exposure route and soil migration to groundwater exposure route on and
adjoining the site. This IC will be in the form of a City of Waukegan Ordinance and will
serve to eliminate the groundwater pathway. Appendix B includes documentation of the City
of Waukegan groundwater use restriction ordinance adopted.
4.2.8
INSTITUTIONAL CONTROLS
In the approved Revised RAP dated January 15, 2008 institutional controls were approved to
exclude exposure pathways.
Groundwater Use Restriction Ordinance
The prohibition of installation of potable wells on-site would be an acceptable institutional
control that will be applied as a deed restriction in the NFR letter. Institutional controls will
15
be required to prohibit the use of groundwater on and down gradient of the property as a
means of eliminating the groundwater exposure pathway. The City of Waukegan provides its
municipal water supply from treated Lake Michigan water and would serve this property
upon redevelopment.
Land Use Restriction and Engineered Barrier
The future end use and planned redevelopment of the property is for residential development
consistent with the City of Waukegan’s Master Plan as amended in 2003 by the adoption of
the Lakefront & Downtown Master Plan. The remediation objectives for the site were
established using the residential land use values in TACO. Therefore, institutional controls
except an Engineered Barrier control are not anticipated to be required to limit the property
use.
A deed restriction is required under the PCB regulations (40 CFR 761.61(a) (8)) for low
occupancy and high occupancy areas where a cap is installed. A deed restriction is essentially
a permanent notice executed in accordance with state law and recorded on the deed or some
other instrument normally examined during a title search, which indicates contained
contamination remains at the site. The deed restriction must be recorded within 60 days of
completion of the cleanup activity. Information that will be recorded on the deed restriction
includes:



That the land has been used for PCB remediation waste disposal and is restricted to
use as a low occupancy area or high occupancy area with a cap, as defined in 40 CFR
761.3.
Of the existence of the cap and the requirement to maintain the cap.
The applicable cleanup levels left at the site, under the cap.
A certification, signed by the owner, that he/she has recorded the notation specified in 40
CFR 761.61 (a)(8)(i)(A) will be submitted to the EPA Regional Administrator.
Construction Worker Protection
Construction worker health and safety planning will be required to protect workers during
soil handling and subsurface construction for areas where residual contaminants will remain
below engineered barriers during future construction as part of Waukegan’s Master Place.
5.0
REMEDIAL ACTION COMPLETION REPORT
Following the completion of the Remedial Action including past (2008 – 2009) and proposed
(2015-2016) remedial work, a Remedial Action Completion Report (RACR) will be prepared
and submitted to the IEPA after completion and will include past and future data. The RACR
will include:


Documentation of off-site disposal for soil located at Area 1 to an IEPA-licensed facility
Location and description of engineered barrier(s) and source areas
16




Confirmation sampling of Area 1 and source area excavation (2008 and 2015)
Engineered barrier confirmation sampling
Groundwater monitoring sampling for four consecutive quarters
Soil-gas sampling
Recordkeeping is also required to document the various aspects of the PCB cleanup (40 CFR
761.61 (a) (9). The records that need to be documented include the following as listed in 40 CFR
761.125(c) (5):








Identification of the source of the spill, e.g., type of equipment
Estimated or actual date and time of the spill occurrence
The date and time cleanup was completed or terminated
A brief description of the spill location and the nature of the materials contaminated
Pre-cleanup sampling data used to establish the spill boundaries if required because of
insufficient visible traces and a brief description of the sampling methodology used to
establish the spill boundaries
Approximate depth of soil excavation and the amount of soil removed
Post-cleanup verification sampling data and, if not otherwise apparent from the
documentation, a brief description of the sampling methodology and
analytical technique used
While not required for compliance with the PCB spill cleanup policy, information on the
estimated cost of cleanup
These records will be included in the Remedial Action Completion Report and will be
maintained for a period of 5 years.
17
N
0
200'
400'
S28 T45N R12E
9/16/15
SITE LOCATION MAP
PLANS PREPARED FOR
1
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
GD
GD
SB
595
585
610
590
60
60605 0
0
620
615
630
580
625
5
625
605
625
610
600
620
635
GD
600
5
59
615620
595
595
605
625
620
595
610
600
620
615
0
63
580
605
635
625
GD
58590
5
610
620
635
625
630
590
595
595
600
0
585
63
0
64
64
SITE TOPOGRAPHY MAP
PLANS PREPARED FOR
CITY OF WAUKEGAN
SB
580
640
590
635
585
WAUKEGAN, ILLINOIS
610
620
5
590
595
0
63
595
64
0
635
60
640
63
605
5
605
640
640
615
630
2
635
5
64
645
3/26/15
5
645
63
63
635
64
0
625
64
0
610
635
635
585
615
640
650
605
63 0
615
640
610
635
0
60
590
0
595
59
5
595
0
200'
595
400'
N
0
150'
300'
REC1-SS1 (0.5')
Pb,PCB,PAH
REC7-SS2 (0.5')
As, Pb
REC1-SS3 (0.5')
As, PAH, Pb
REC1-SS4 (2.5')
PAH, PCB, Cu
Pb, As, Cr
REC8-SS1 (7')
As, Cr, Pb, PCB, PAH
REC1-SS7 (6')
Sb, As, Cr, Pb, PAH
REC1-SS8 (3')
As, Cu, Pb, PAH
LEGEND
REC1-SS14 (3')
As, TCE
Test Pit 1 (2')
TCE
REC1-SS1
REC1-SS15 (3')
TCE, PCB, PAH
REC1-SS3
2008/2009 RECOGNIZED
ENVIRONMENTAL CONDITION
(REC)
2008/2009 REC AND COMPLETED
EXCAVATION AREAS
PROPERTY BOUNDARY
SAMPLING GRIDLINES
9/16/15
PLANS PREPARED FOR
28835 N. Herky Drive, Unit 120
3
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
Website: www.deiganassociates.com
GD
SB
N
0
150'
300'
REC1-SS1 (0.5')
REC7-SS2 (0.5')
SSW
Benzo(a)pyrene - 0.14 mg/kg
REC1-SS3 (0.5')
ESW
BOT-S
Results in Lab Report
500-20440-1
SSW
Benzo(a)anthracene - 1.4 mg/kg
Benzo(b)fluoreanthene - 1.1 mg/kg
500-20440-1
REC1-SS4 (2.5')
NSW
Benzo(b)fluoranthene - 1.5 mg/kg
Dibenz(a,h)anthracene - 0.47 mg/kg
BOT-S
Dibenz(a,h,)anthracene - 0.10 mg/kg
BOT-N
Indeno(1,2,3-cd)pyrene - 3.6 mg/kg
Polychlorinated biphenyls, Total - 1.1 mg/kg
REC8-SS1 (7')
Results in Lab Report 500-20440-1
REC1-SS7 (6')
WSW
Trichloroethene - 0.061 mg/kg
SSW
Manganese -1700 mg/kg
ESW
Cadmium - 7.4 mg/kg
Results in Lab Report 500-20245
REC1-SS8 (3')
NSW
BOT-E
Benzo(g,h,i)perylene - 1.1 mg/kg
500-20280-1
REC1-SS14 (3')
ESW
Tetrachloroethene - 0.31 mg/kg
Trichloroethene - 0.83 mg/kg
Arsenic - 150 mg/kg
Iron - 190,000 mg/kg
Lead - 210 mg/kg
Selenium - 16 mg/kg
LEGEND
Results in Lab Report 500-20245
ENVIRONMENTAL CONDITION
(REC)
REC1-SS15 (3')
2008/2009 REC AND COMPLETED
EXCAVATION AREAS
2008/2009 COMPLETED
CONFIRMATION SAMPLES
PROPERTY BOUNDARY
SAMPLING GRIDLINES
9/16/15
PLANS PREPARED FOR
4
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
GD
SB
N
0
150'
AREA 1
LEGEND
AREA 1 - SOIL REMOVAL AND
OFF-SITE DISPOSAL AREA
PROPERTY BOUNDARY
SAMPLING GRIDLINES
9/16/15
SOIL REMOVAL AND OFF-SITE DISPOSAL AREA
PLANS PREPARED FOR
5
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
GD
SB
300'
N
0
150'
300'
REC1-SS1 (0.5')
Pb,PCB,PAH
MW-11
(20 FT.)
MW-12
(20 FT.)
REC7-SS2 (0.5')
As, Pb
REC1-SS3 (0.5')
As, PAH, Pb
REC1-SS4 (2.5')
PAH, PCB, Cu
Pb, As, Cr
REC8-SS1 (7')
As, Cr, Pb, PCB, PAH
MW-13S (20 FT.)
MW-13D (40 FT.)
REC1-SS7 (6')
Sb, As, Cr, Pb, PAH
REC1-SS8 (3')
As, Cu, Pb, PAH
MW-14
(20 FT.)
REC1-SS14 (3')
As, TCE
Test Pit 1 (2')
TCE
MW-15
(20 FT.)
REC1-SS15 (3')
TCE, PCB, PAH
LEGEND
2015 PROPOSED MONITORING
MW-11
WELLS (DEPTH)
(20 FT.)
REC1-SS1
ENVIRONMENTAL CONDITIONS
GROUNDWATER FLOW DIRECTION
PROPERTY BOUNDARY
SAMPLING GRIDLINES
9/15/15
PLANS PREPARED FOR
6
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
GD
SB
N
0
150'
300'
AREA 1
LEGEND
2008/2009 COMPLETED EXCAVATION
ZONES
2015 PROPOSED AREA 1 EXCAVATION
ZONE
AREA 1 - SOIL REMOVAL AND
OFF-SITE DISPOSAL AREA
2015 PROPOSED CONFIRMATION
SAMPLING
PROPERTY BOUNDARY
SAMPLING GRIDLINES
9/15/15
PLANS PREPARED FOR
7A
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
GD
SB
N
0
150'
300'
CS-1 (0')
CS-2 (1')
CS-3 (2')
CS-4 (0')
CS-5 (2')
CS-6 (1')
CS-8 (0')
CS-7 (2')
CS-9 (1')
CS-10 (2')
CS-12 (0')
CS-11 (2')
CS-13 (1')
CS-14 (2')
CS-15 (2')
CS-16 (0')
CS-17 (1')
CS-18 (2')
CS-19 (0')
CS-20 (2')
CS-21 (1')
1 ac
(TYP)
CS-22 (0')
LEGEND
CS-1 (0')
9/16/15
PLANS PREPARED FOR
7B
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
GD
SB
2015 PROPOSED ENGINEERED
BARRIER CONFIRMATION SAMPLING
(SAMPLE DEPTH)
1 ACRE SECTION
PROPERTY BOUNDARY
SAMPLING GRIDLINES
N
0
150'
300'
REC1-SS4
SG-1
REC1-SS7
SG-2
REC1-SS14
SG-3
LEGEND
2015 PROPOSED SOIL GAS SAMPLES
SG-1
2008/2009 COMPLETED EXCAVATION ZONES
PROPERTY BOUNDARY
SAMPLING GRIDLINES
9/16/15
2015 PROPOSED SOIL GAS SAMPLE MAP
PLANS PREPARED FOR
8
CITY OF WAUKEGAN
WAUKEGAN, ILLINOIS
Tel (847) 578-5000
GD
Lake Bluff, IL
60044
GD
SB
Appendix A – Photographic Summary of 2008-2009 Remedial
Action Plan Work
Sustainable Environmental Solutions
Photo 1
Remaining concrete foundations/debris was removed
from the site in 2009.
Photo 2
Site Preparations in 2009 included vegetation and
woody debris removal.
Photo 3
The approved RAP included excavation of contaminated
soil “source areas” prior to placement of the engineered
barrier soil layer.
Photo 4
Excavation of source area soils and transfer to Area 1–
Soil Removal & Off-Site Disposal Area.
Former Fansteel/Waukegan– South Lakefront
Photo Summary of Remedial Action Work Completed in 2009
Page 1 of 2
Photo 5
Loading the source area soil to be relocated to Area 1.
Photo 6
Environmental technician soil sampling of post-excavation
soil source areas to confirm contaminant reduction prior to
backfill/grading and engineered barrier.
Photo 7
Area 1 was utilized to consolidate source area soils in a
similarly con-taminated zone in 2009. Area 1 is
proposed to be removed and hauled to a Licensed
Subtitle D Landfill in 2015-2016.
Photo 8
After the contaminated soil at the source areas were
removed and relocated to Area 1, a 3 to 4 ft. engineering
barrier clean soil layer was placed in compacted lifts and
capped the property.
Former Fansteel/Waukegan– South Lakefront
Photo Summary of Remedial Action Work Completed in 2009
Page 2 of 2
Appendix B – Waukegan Groundwater Use Restricted Ordinance
Water Street
N
Market
Street
South Street
City of Waukegan
South Lakefront
Groundwater Use
Restriction Ordinance Area
(East-West: Lake Michigan to 400
ft. West of Market St.)
(North -South: Water St. to 10th St.)
10 th Street
Appendix C – Imported Barrier Soil Pre-Screening
Laboratory Analysis
ANALYTICAL REPORT
Job Number: 500-13742-1
SDG Number: 500-13742-1
Job Description: North Chicago
For:
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Attention: Gary Deigan
_____________________________________________
Richard C Wright
Project Manager II
richard.wright@testamericainc.com
09/16/2008
These test results meet all the requirements of NELAC for accredited parameters.
The Lab Certification ID# is 100201.
All questions regarding this test report should be directed to the TestAmerica Project Manager whose signature appears
on this report. All pages of this report are integral parts of the analytical data. Therefore, this report should be
reproduced only in its entirety.
Reporting limits are adjusted for sample size used, dilutions and moisture content if applicable.
TestAmerica Laboratories, Inc.
TestAmerica Chicago 2417 Bond Street, University Park, IL 60466
Tel (708) 534-5200 Fax (708) 534-5211 www.testamericainc.com
Page 1 of 51
09/16/2008
Job Narrative
500-J13742-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
GC/MS VOA
No analytical or quality issues were noted.
GC/MS Semi VOA
Method(s) 8270C: The laboratory control standard (LCS) for preparation batch 46612 exceeded control limits for
N-Nitrosodiphenylamine. This analyte was biased high in the LCS and was not detected in the associated samples; therefore, the data
have been reported.
Method(s) 8270C: Internal standard (ISTD) response for the following QC sample was outside of acceptance limits: <LCS 500-46612>.
The sample was not re-analyzed. All the associated analytes were within control limits. No further action was taken.
No other analytical or quality issues were noted.
GC Semi VOA
Method(s) 8081A: The ending continuing calibration verification (CCV) for batch 500-46497 did not meet control limits. Samples matrix is
suspected to have contributed to this failure.
Method(s) 8081A: The following samples were diluted due to the abundance of non-target analytes: PLOTE BF-01 (500-13742-1), PLOTE
BF-02 (500-13742-2). Elevated reporting limits (RLs) are provided.
Metals
Method(s) 6010B: The serial dilution performed for the following sample, 500-13742-1, was outside control limits:
Co,Cr,Fe,K-,Mg,Mn,Ni,Pb, and Zn
Method(s) 6010B: The matrix duplicate %RPD for sample 500-13742-1 was outside the control limits for As,Cr, and Zn.
Method(s) 6010B: The matrix spike / matrix spike duplicate (MS/MSD) recoveries for batch 46517 sample 500-13742-1 were outside
control limits for K-,Na, and Sb. The MS was also out for Cu, and the MSD was also out for Pb. The associated laboratory control
standard (LCS) met acceptance criteria.
General Chemistry
Organic Prep
Page 2 of 51
09/16/2008
EXECUTIVE SUMMARY - Detections
Client: Deigan & Associates
Lab Sample ID
Analyte
500-13742-1
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Client Sample ID
Result / Qualifier
Reporting
Limit
Units
Method
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
SU
%
%
8260B
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
9045C
PercentMoisture
PercentMoisture
PLOTE BF-01
Carbon disulfide
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Benzo[b]fluoranthene
Benzo[g,h,i]perylene
Benzo[k]fluoranthene
Chrysene
Fluoranthene
Indeno[1,2,3-cd]pyrene
Phenanthrene
Pyrene
Aluminum
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Sodium
Thallium
Vanadium
Zinc
pH
Percent Moisture
Percent Solids
0.0028
0.0091
0.028
0.024
0.027
0.031
0.017
0.033
0.061
0.016
0.045
0.048
2700
4.5
12
0.15
0.44
97000
5.1
4.6
15
13000
12
46000
570
12
1100
0.34
1200
0.74
11
29
8.89
0.96
99
J
J
J
J
J
J
J
J
B
J
B
V
V
BV
BV
BV
V
V
V
J
B
J
BV
0.0049
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
17
0.86
0.86
0.34
0.17
86
0.86
0.43
0.86
8.6
0.43
8.6
0.86
0.86
43
0.86
86
0.86
0.43
1.7
0.200
0.10
0.10
TestAmerica Chicago
Page 3 of 51
09/16/2008
EXECUTIVE SUMMARY - Detections
Lab Sample ID
Analyte
500-13742-2
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Client Sample ID
Result / Qualifier
Reporting
Limit
Units
Method
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
SU
%
%
8260B
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8081A
8082
8082
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
6010B
7471A
9045C
PercentMoisture
PercentMoisture
PLOTE BF-02
Carbon disulfide
Acenaphthene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Chrysene
Fluoranthene
Fluorene
2-Methylnaphthalene
Phenanthrene
Pyrene
4,4'-DDE
PCB-1260
Polychlorinated biphenyls, Total
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Sodium
Thallium
Vanadium
Zinc
Mercury
pH
Percent Moisture
Percent Solids
0.0027
0.0076
0.012
0.048
0.052
0.078
0.053
0.031
0.079
0.16
0.0098
0.037
0.024
0.10
0.12
0.0011
0.0063
0.0063
6700
0.67
79
38
0.35
0.56
85000
12
11
39
26000
24
34000
460
26
2000
0.60
1500
0.35
19
70
0.013
8.50
1.3
99
J
J
J
J
J
J
J
J
J
B
JB
J
B
B
B
B
J
B
J
B
J
0.0048
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.032
0.16
0.032
0.032
0.0034
0.017
0.017
20
2.0
0.98
0.98
0.39
0.20
98
0.98
0.49
0.98
9.8
0.49
9.8
0.98
0.98
49
0.98
98
0.98
0.49
2.0
0.017
0.200
0.10
0.10
TestAmerica Chicago
Page 4 of 51
09/16/2008
METHOD SUMMARY
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Description
Lab Location Method
Preparation Method
Volatile Organic Compounds by GC/MS
Closed System Purge & Trap/Field Preservation
TAL CHI
TAL CHI
SW846 8260B
SW846 5035
Semivolatile Compounds by Gas Chromatography/Mass
Spectrometry (GC/MS)
Automated Soxhlet Extraction
TAL CHI
SW846 8270C
Organochlorine Pesticides by Gas Chromatography
TAL CHI
TAL CHI
SW846 8081A
Polychlorinated Biphenyls (PCBs) by Gas Chromatography
TAL CHI
TAL CHI
SW846 8082
Inductively Coupled Plasma - Atomic Emission Spectrometry
Preparation, Metals
TAL CHI
TAL CHI
SW846 6010B
Mercury in Solid or Semisolid Waste (Manual Cold Vapor
Technique)
Mercury in Solid or Semi-Solid Waste (Manual Cold
TAL CHI
SW846 7471A
Titrimetric and Manual Spectrophotometric Determinative
Methods for Cyanide
Cyanide Distillation
TAL CHI
Soil and Waste pH
TAL CHI
Matrix: Solid
TAL CHI
SW846 3541
SW846 3541
SW846 3541
SW846 3050B
TAL CHI
SW846 7471A
SW846 9014
TAL CHI
SW846 9010B
SW846 9045C
Lab References:
TAL CHI = TestAmerica Chicago
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Chicago
Page 5 of 51
09/16/2008
SAMPLE SUMMARY
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID
Client Sample ID
Client Matrix
500-13742-1
500-13742-2
PLOTE BF-01
PLOTE BF-02
Solid
Solid
Date/Time
Sampled
Date/Time
Received
09/02/2008 1030
09/02/2008 1030
09/03/2008 1030
09/03/2008 1030
TestAmerica Chicago
Page 6 of 51
09/16/2008
SAMPLE RESULTS
TestAmerica Chicago
Page 7 of 51
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Client Sample ID: PLOTE BF-01
Lab Sample ID:
500-13742-1
Analyte
Result/Qualifier
Method: 8260B
Prep Method: 5035
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
1,1-Dichloroethene
Acetone
Carbon disulfide
Methylene Chloride
trans-1,2-Dichloroethene
Methyl tert-butyl ether
1,1-Dichloroethane
cis-1,2-Dichloroethene
Methyl Ethyl Ketone
Chloroform
Carbon tetrachloride
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropene
methyl isobutyl ketone
Toluene
trans-1,3-Dichloropropene
Tetrachloroethene
2-Hexanone
Dibromochloromethane
Chlorobenzene
Ethylbenzene
Xylenes, Total
Styrene
Bromoform
1,1,2,2-Tetrachloroethane
1,3-Dichloropropene, Total
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
0.0028
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0049
<0.0099
<0.0049
<0.0049
<0.0049
<0.0049
Surrogate
1,2-Dichloroethane-d4 (Surr)
105
J
Unit
MDL
09/02/2008 1030
09/03/2008 1030
Solid
99
RL
Date Analyzed:
09/06/2008 1758
Date Prepared:
09/02/2008 1030
mg/Kg
0.0016
0.0049
mg/Kg
0.0014
0.0049
mg/Kg
0.0022
0.0049
mg/Kg
0.0012
0.0049
mg/Kg
0.00087
0.0049
mg/Kg
0.0019
0.0049
mg/Kg
0.00093
0.0049
mg/Kg
0.00077
0.0049
mg/Kg
0.00099
0.0049
mg/Kg
0.0013
0.0049
mg/Kg
0.00095
0.0049
mg/Kg
0.00095
0.0049
mg/Kg
0.0018
0.0049
mg/Kg
0.00097
0.0049
mg/Kg
0.00088
0.0049
mg/Kg
0.00093
0.0049
mg/Kg
0.00084
0.0049
mg/Kg
0.0011
0.0049
mg/Kg
0.00095
0.0049
mg/Kg
0.00093
0.0049
mg/Kg
0.00077
0.0049
mg/Kg
0.00079
0.0049
mg/Kg
0.0015
0.0049
mg/Kg
0.00087
0.0049
mg/Kg
0.00095
0.0049
mg/Kg
0.0018
0.0049
mg/Kg
0.00079
0.0049
mg/Kg
0.0012
0.0049
mg/Kg
0.00082
0.0049
mg/Kg
0.00067
0.0049
mg/Kg
0.00070
0.0049
mg/Kg
0.0015
0.0099
mg/Kg
0.00074
0.0049
mg/Kg
0.00099
0.0049
mg/Kg
0.0012
0.0049
mg/Kg
0.00095
0.0049
%
Page 8 of 51
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Acceptance Limits
75 - 140
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-1
Analyte
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene (Surr)
Dibromofluoromethane
Method: 8270C
Prep Method: 3541
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Bis(2-chloroethoxy)methane
Bis(2-chloroethyl)ether
Bis(2-ethylhexyl) phthalate
4-Bromophenyl phenyl ether
Butyl benzyl phthalate
Carbazole
4-Chloroaniline
4-Chloro-3-methylphenol
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenyl phenyl ether
Chrysene
Dibenz(a,h)anthracene
Dibenzofuran
3,3'-Dichlorobenzidine
2,4-Dichlorophenol
Diethyl phthalate
2,4-Dimethylphenol
Dimethyl phthalate
Di-n-butyl phthalate
4,6-Dinitro-2-methylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Fluoranthene
Result/Qualifier
Unit
MDL
09/02/2008 1030
09/03/2008 1030
Solid
99
RL
Acceptance Limits
75 - 130
75 - 120
75 - 140
91
94
98
%
%
%
<0.032
<0.032
0.0091
0.028
0.024
0.027
0.031
0.017
<0.16
<0.16
<0.16
<0.16
<0.16
<0.16
<0.64
<0.32
<0.16
<0.16
<0.16
0.033
<0.032
<0.16
<0.16
<0.32
<0.16
<0.32
<0.16
<0.16
<0.32
<0.64
<0.16
<0.16
<0.16
0.061
Date Analyzed:
09/12/2008 1759
Date Prepared:
09/05/2008 0605
mg/Kg
0.0040
0.032
mg/Kg
0.0034
0.032
mg/Kg
0.0037
0.032
mg/Kg
0.0040
0.032
mg/Kg
0.0030
0.032
mg/Kg
0.0070
0.032
mg/Kg
0.0055
0.032
mg/Kg
0.0068
0.032
mg/Kg
0.020
0.16
mg/Kg
0.021
0.16
mg/Kg
0.027
0.16
mg/Kg
0.013
0.16
mg/Kg
0.014
0.16
mg/Kg
0.012
0.16
mg/Kg
0.12
0.64
mg/Kg
0.078
0.32
mg/Kg
0.015
0.16
mg/Kg
0.028
0.16
mg/Kg
0.013
0.16
mg/Kg
0.0050
0.032
mg/Kg
0.0039
0.032
mg/Kg
0.012
0.16
mg/Kg
0.047
0.16
mg/Kg
0.034
0.32
mg/Kg
0.016
0.16
mg/Kg
0.059
0.32
mg/Kg
0.012
0.16
mg/Kg
0.013
0.16
mg/Kg
0.039
0.32
mg/Kg
0.17
0.64
mg/Kg
0.017
0.16
mg/Kg
0.017
0.16
mg/Kg
0.014
0.16
mg/Kg
0.0041
0.032
J
J
J
J
J
J
Page 9 of 51
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-1
Analyte
Result/Qualifier
09/02/2008 1030
09/03/2008 1030
Solid
99
Unit
MDL
RL
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
0.0034
0.0046
0.019
0.11
0.017
0.0041
0.013
0.018
0.032
0.030
0.0033
0.017
0.063
0.068
0.0059
0.039
0.056
0.022
0.0095
0.017
0.12
0.0028
0.028
0.0037
0.045
0.032
0.032
0.064
0.16
0.64
0.16
0.032
0.16
0.16
0.16
0.16
0.032
0.16
0.32
0.32
0.032
0.32
0.64
0.16
0.16
0.16
0.64
0.032
0.16
0.032
0.32
0.32
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Isophorone
2-Methylnaphthalene
2-Methylphenol
3 & 4 Methylphenol
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodi-n-propylamine
N-Nitrosodiphenylamine
2,2'-oxybis[1-chloropropane]
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
2,4,5-Trichlorophenol
<0.032
<0.064
<0.16
<0.64
<0.16
0.016
<0.16
<0.16
<0.16
<0.16
<0.032
<0.16
<0.32
<0.32
<0.032
<0.32
<0.64
<0.16
<0.16
<0.16
<0.64
0.045
<0.16
0.048
<0.32
<0.32
Surrogate
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
2,4,6-Tribromophenol
85
74
77
71
88
102
%
%
%
%
%
%
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
Date Analyzed:
09/10/2008 1830
Date Prepared:
09/04/2008 0653
mg/Kg
0.0011
0.0034
mg/Kg
0.0019
0.0034
mg/Kg
0.0015
0.0034
mg/Kg
0.00060
0.0034
mg/Kg
0.00046
0.0034
Method: 8081A
Prep Method: 3541
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
J
*
Page 10 of 51
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Acceptance Limits
33 - 114
25 - 111
21 - 116
31 - 110
48 - 146
32 - 138
2.0
2.0
2.0
2.0
2.0
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-1
Analyte
Result/Qualifier
09/02/2008 1030
09/03/2008 1030
Solid
99
Unit
MDL
RL
0.0011
0.00072
0.0014
0.00066
0.00066
0.0012
0.00070
0.0011
0.00032
0.00060
0.00099
0.00060
0.0013
0.00093
0.0011
0.0060
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.017
0.0034
0.0034
0.0034
0.0034
0.034
Aldrin
Heptachlor epoxide
Endosulfan I
Dieldrin
4,4'-DDE
Endrin
Endosulfan II
4,4'-DDD
Endosulfan sulfate
4,4'-DDT
Methoxychlor
Endrin ketone
Endrin aldehyde
alpha-Chlordane
gamma-Chlordane
Toxaphene
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.017
<0.0034
<0.0034
<0.0034
<0.0034
<0.034
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
Surrogate
DCB Decachlorobiphenyl
Tetrachloro-m-xylene
58
52
%
%
Method: 8082
Prep Method: 3541
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
Date Analyzed:
09/10/2008 1357
Date Prepared:
09/04/2008 0653
mg/Kg
0.0072
0.017
mg/Kg
0.0092
0.017
mg/Kg
0.0062
0.017
mg/Kg
0.010
0.017
mg/Kg
0.0088
0.017
mg/Kg
0.0060
0.017
mg/Kg
0.0062
0.017
mg/Kg
0.0060
0.017
Surrogate
66
72
%
%
2700
<1.7
4.5
12
0.15
Date Analyzed:
09/04/2008 2142
Date Prepared:
09/04/2008 0921
mg/Kg
1.5
17
mg/Kg
0.25
1.7
mg/Kg
0.25
0.86
mg/Kg
0.028
0.86
mg/Kg
0.0086
0.34
Method: 6010B
Prep Method: 3050B
Aluminum
Antimony
Arsenic
Barium
Beryllium
B
J
Page 11 of 51
Dilution
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
Acceptance Limits
42 - 142
30 - 127
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Acceptance Limits
32 - 127
44 - 140
1.0
1.0
1.0
1.0
1.0
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-1
Analyte
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Result/Qualifier
0.44
5.1
4.6
15
13000
12
46000
570
12
1100
0.34
<0.43
1200
0.74
11
29
09/02/2008 1030
09/03/2008 1030
Solid
99
Unit
MDL
RL
BV
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
0.028
0.075
0.063
0.39
1.7
0.095
1.0
0.027
0.053
5.2
0.33
0.086
18
0.28
0.073
0.15
0.17
0.86
0.43
0.86
8.6
0.43
8.6
0.86
0.86
43
0.86
0.43
86
0.86
0.43
1.7
B
Date Analyzed:
Date Prepared:
mg/Kg
7.3
V
V
BV
BV
BV
V
V
V
J
B
J
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
09/10/2008 2330
09/04/2008 0921
86
10
<0.017
Date Analyzed:
09/04/2008 1509
Date Prepared:
09/04/2008 1030
mg/Kg
0.0069
0.017
1.0
Method: 9014
Prep Method: 9010B
Cyanide, Total
<0.40
Date Analyzed:
09/12/2008 1311
Date Prepared:
09/11/2008 0835
mg/Kg
0.10
0.40
1.0
Method: 9045C
pH
8.89
SU
Date Analyzed:
09/05/2008 1144
0.200
0.200
1.0
Method: PercentMoisture
Percent Moisture
0.96
%
Date Analyzed:
09/05/2008 0025
0.10
0.10
1.0
Method: 6010B
Prep Method: 3050B
Calcium
Method: 7471A
Prep Method: 7471A
Mercury
97000
Page 12 of 51
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-2
Analyte
Result/Qualifier
Method: 8260B
Prep Method: 5035
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
1,1-Dichloroethene
Acetone
Carbon disulfide
Methylene Chloride
1,1-Dichloroethane
Methyl Ethyl Ketone
Chloroform
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
Xylenes, Total
Styrene
Bromoform
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
0.0027
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0048
<0.0097
<0.0048
<0.0048
<0.0048
<0.0048
Surrogate
109
J
Unit
MDL
09/02/2008 1030
09/03/2008 1030
Solid
99
RL
Date Analyzed:
09/06/2008 1824
Date Prepared:
09/02/2008 1030
mg/Kg
0.0016
0.0048
mg/Kg
0.0014
0.0048
mg/Kg
0.0021
0.0048
mg/Kg
0.0012
0.0048
mg/Kg
0.00085
0.0048
mg/Kg
0.0018
0.0048
mg/Kg
0.00091
0.0048
mg/Kg
0.00076
0.0048
mg/Kg
0.00097
0.0048
mg/Kg
0.0013
0.0048
mg/Kg
0.00093
0.0048
mg/Kg
0.00093
0.0048
mg/Kg
0.0017
0.0048
mg/Kg
0.00095
0.0048
mg/Kg
0.00086
0.0048
mg/Kg
0.00091
0.0048
mg/Kg
0.00082
0.0048
mg/Kg
0.0011
0.0048
mg/Kg
0.00093
0.0048
mg/Kg
0.00091
0.0048
mg/Kg
0.00076
0.0048
mg/Kg
0.00078
0.0048
mg/Kg
0.0015
0.0048
mg/Kg
0.00085
0.0048
mg/Kg
0.00093
0.0048
mg/Kg
0.0017
0.0048
mg/Kg
0.00078
0.0048
mg/Kg
0.0012
0.0048
mg/Kg
0.00080
0.0048
mg/Kg
0.00066
0.0048
mg/Kg
0.00069
0.0048
mg/Kg
0.0015
0.0097
mg/Kg
0.00073
0.0048
mg/Kg
0.00097
0.0048
mg/Kg
0.0012
0.0048
mg/Kg
0.00093
0.0048
%
Page 13 of 51
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Acceptance Limits
75 - 140
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-2
Analyte
Surrogate
Toluene-d8 (Surr)
Method: 8270C
Prep Method: 3541
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Carbazole
4-Chloroaniline
2-Chloronaphthalene
2-Chlorophenol
Chrysene
Dibenzofuran
2,4-Dichlorophenol
Diethyl phthalate
2,4-Dimethylphenol
Dimethyl phthalate
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Result/Qualifier
Unit
MDL
09/02/2008 1030
09/03/2008 1030
Solid
99
RL
Acceptance Limits
75 - 130
75 - 120
75 - 140
93
95
101
%
%
%
0.0076
<0.032
0.012
0.048
0.052
0.078
0.053
0.031
<0.16
<0.16
<0.16
<0.16
<0.16
<0.16
<0.65
<0.32
<0.16
<0.16
<0.16
0.079
<0.032
<0.16
<0.16
<0.32
<0.16
<0.32
<0.16
<0.16
<0.32
<0.65
<0.16
<0.16
<0.16
0.16
Date Analyzed:
09/12/2008 1821
Date Prepared:
09/05/2008 0605
mg/Kg
0.0041
0.032
mg/Kg
0.0034
0.032
mg/Kg
0.0038
0.032
mg/Kg
0.0041
0.032
mg/Kg
0.0030
0.032
mg/Kg
0.0071
0.032
mg/Kg
0.0055
0.032
mg/Kg
0.0069
0.032
mg/Kg
0.020
0.16
mg/Kg
0.021
0.16
mg/Kg
0.027
0.16
mg/Kg
0.013
0.16
mg/Kg
0.014
0.16
mg/Kg
0.012
0.16
mg/Kg
0.12
0.65
mg/Kg
0.079
0.32
mg/Kg
0.015
0.16
mg/Kg
0.028
0.16
mg/Kg
0.013
0.16
mg/Kg
0.0050
0.032
mg/Kg
0.0040
0.032
mg/Kg
0.012
0.16
mg/Kg
0.047
0.16
mg/Kg
0.034
0.32
mg/Kg
0.016
0.16
mg/Kg
0.059
0.32
mg/Kg
0.012
0.16
mg/Kg
0.013
0.16
mg/Kg
0.039
0.32
mg/Kg
0.18
0.65
mg/Kg
0.017
0.16
mg/Kg
0.017
0.16
mg/Kg
0.015
0.16
mg/Kg
0.0042
0.032
J
J
J
Page 14 of 51
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-2
Analyte
Result/Qualifier
Unit
MDL
RL
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
0.0034
0.0047
0.019
0.11
0.017
0.0042
0.013
0.018
0.032
0.030
0.0033
0.018
0.063
0.069
0.0059
0.039
0.056
0.022
0.0096
0.017
0.12
0.0028
0.028
0.0038
0.045
0.032
0.032
0.065
0.16
0.65
0.16
0.032
0.16
0.16
0.16
0.16
0.032
0.16
0.32
0.32
0.032
0.32
0.65
0.16
0.16
0.16
0.65
0.032
0.16
0.032
0.32
0.32
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Isophorone
2-Methylnaphthalene
2-Methylphenol
3 & 4 Methylphenol
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
0.0098
<0.065
<0.16
<0.65
<0.16
0.037
<0.16
0.024
<0.16
<0.16
<0.032
<0.16
<0.32
<0.32
<0.032
<0.32
<0.65
<0.16
<0.16
<0.16
<0.65
0.10
<0.16
0.12
<0.32
<0.32
Surrogate
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
83
72
78
79
91
100
%
%
%
%
%
%
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
Date Analyzed:
09/10/2008 1945
Date Prepared:
09/04/2008 0653
mg/Kg
0.0011
0.0034
mg/Kg
0.0018
0.0034
mg/Kg
0.0015
0.0034
mg/Kg
0.00060
0.0034
mg/Kg
0.00046
0.0034
Method: 8081A
Prep Method: 3541
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
J
09/02/2008 1030
09/03/2008 1030
Solid
99
J
*
Page 15 of 51
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Acceptance Limits
33 - 114
25 - 111
21 - 116
31 - 110
48 - 146
32 - 138
2.0
2.0
2.0
2.0
2.0
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-2
Analyte
Result/Qualifier
09/02/2008 1030
09/03/2008 1030
Solid
99
Unit
MDL
RL
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
0.0011
0.00072
0.0014
0.00066
0.00066
0.0012
0.00070
0.0011
0.00032
0.00060
0.00097
0.00060
0.0013
0.00091
0.0011
0.0060
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.0034
0.016
0.0034
0.0034
0.0034
0.0034
0.033
Aldrin
Heptachlor epoxide
Endosulfan I
Dieldrin
4,4'-DDE
Endrin
Endosulfan II
4,4'-DDD
Endosulfan sulfate
4,4'-DDT
Methoxychlor
Endrin ketone
Endrin aldehyde
alpha-Chlordane
gamma-Chlordane
Toxaphene
<0.0034
<0.0034
<0.0034
<0.0034
0.0011
<0.0034
<0.0034
<0.0034
<0.0034
<0.0034
<0.016
<0.0034
<0.0034
<0.0034
<0.0034
<0.033
Surrogate
60
66
%
%
Method: 8082
Prep Method: 3541
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
0.0063
0.0063
Date Analyzed:
09/10/2008 1439
Date Prepared:
09/04/2008 0653
mg/Kg
0.0072
0.017
mg/Kg
0.0090
0.017
mg/Kg
0.0062
0.017
mg/Kg
0.0099
0.017
mg/Kg
0.0086
0.017
mg/Kg
0.0060
0.017
mg/Kg
0.0062
0.017
mg/Kg
0.0060
0.017
Surrogate
73
70
%
%
6700
0.67
79
38
0.35
Date Analyzed:
09/04/2008 2217
Date Prepared:
09/04/2008 0921
mg/Kg
1.8
20
mg/Kg
0.29
2.0
mg/Kg
0.29
0.98
mg/Kg
0.031
0.98
mg/Kg
0.0098
0.39
Method: 6010B
Prep Method: 3050B
Aluminum
Antimony
Arsenic
Barium
Beryllium
J
J
J
B
JB
J
Page 16 of 51
Dilution
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
2.0
Acceptance Limits
42 - 142
30 - 127
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
Acceptance Limits
32 - 127
44 - 140
1.0
1.0
1.0
1.0
1.0
09/16/2008
Gary Deigan
Deigan & Associates
100 S. Genesee St.
Waukegan, IL 60085
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Date Sampled:
Date Received:
Client Matrix:
Percent Solids:
Lab Sample ID:
500-13742-2
Analyte
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Method: 6010B
Prep Method: 3050B
Calcium
Method: 7471A
Prep Method: 7471A
Mercury
Result/Qualifier
0.56
12
11
39
26000
24
34000
460
26
2000
0.60
<0.49
1500
0.35
19
70
85000
0.013
09/02/2008 1030
09/03/2008 1030
Solid
99
Unit
MDL
RL
B
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
mg/Kg
0.032
0.086
0.072
0.44
2.0
0.11
1.2
0.031
0.061
6.0
0.37
0.098
20
0.32
0.084
0.18
0.20
0.98
0.49
0.98
9.8
0.49
9.8
0.98
0.98
49
0.98
0.49
98
0.98
0.49
2.0
B
B
B
J
B
J
Dilution
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
B
Date Analyzed:
Date Prepared:
mg/Kg
8.4
09/11/2008 0005
09/04/2008 0921
98
10
J
Date Analyzed:
09/04/2008 1515
Date Prepared:
09/04/2008 1030
mg/Kg
0.0068
0.017
1.0
1.0
Method: 9014
Prep Method: 9010B
Cyanide, Total
<0.41
Date Analyzed:
09/12/2008 1312
Date Prepared:
09/11/2008 0835
mg/Kg
0.10
0.41
Method: 9045C
pH
8.50
SU
Date Analyzed:
09/05/2008 1146
0.200
0.200
1.0
Method: PercentMoisture
Percent Moisture
1.3
%
Date Analyzed:
09/05/2008 0025
0.10
0.10
1.0
Page 17 of 51
09/16/2008
DATA REPORTING QUALIFIERS
Lab Section
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Qualifier
Description
J
Result is less than the RL but greater than or equal to the MDL
and the concentration is an approximate value.
*
LCS or LCSD exceeds the control limits
J
J
B
Compound was found in the blank and sample.
F
Duplicate RPD exceeds the control limit
F
MS or MSD exceeds the control limits
4
MS, MSD: The analyte present in the original sample is 4 times
greater than the matrix spike concentration; therefore, control
limits are not applicable.
J
V
Serial Dilution exceeds the control limits
GC/MS VOA
GC/MS Semi VOA
GC Semi VOA
Metals
TestAmerica Chicago
Page 18 of 51
09/16/2008
QUALITY CONTROL RESULTS
TestAmerica Chicago
Page 19 of 51
09/16/2008
Quality Control Results
Job Number: 500-13742-1
Sdg Number: 500-13742-1
QC Association Summary
Lab Sample ID
Client Sample ID
Report
Basis Client Matrix
Method
Prep Batch
GC/MS VOA
Prep Batch: 500-46485
500-13742-1
500-13742-2
PLOTE BF-01
PLOTE BF-02
T
T
Solid
Solid
5035
5035
Analysis Batch:500-46728
LCS 500-46728/19
MB 500-46728/17
500-13742-1
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
PLOTE BF-02
T
T
T
T
Solid
Solid
Solid
Solid
8260B
8260B
8260B
8260B
LCS 500-46612/2-A
MB 500-46612/1-A
500-13742-1
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
PLOTE BF-02
T
T
T
T
Solid
Solid
Solid
Solid
3541
3541
3541
3541
LCS 500-46612/2-A
MB 500-46612/1-A
Lab Control Spike
Method Blank
T
T
Solid
Solid
8270C
8270C
500-46612
500-46612
500-13742-1
500-13742-2
PLOTE BF-01
PLOTE BF-02
T
T
Solid
Solid
8270C
8270C
500-46612
500-46612
500-46485
500-46485
Report Basis
T = Total
GC/MS Semi VOA
Report Basis
T = Total
TestAmerica Chicago
Page 20 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID
Client Sample ID
Report
Basis Client Matrix
Method
Prep Batch
GC Semi VOA
LCS 500-46497/2-A
LCS 500-46497/3-A
MB 500-46497/1-A
500-13742-1
500-13742-1MS
500-13742-1MSD
500-13742-2
Lab Control Spike
Lab Control Spike
Method Blank
PLOTE BF-01
Matrix Spike
Matrix Spike Duplicate
PLOTE BF-02
T
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
Solid
3541
3541
3541
3541
3541
3541
3541
LCS 500-46497/3-A
MB 500-46497/1-A
500-13742-1
500-13742-1MS
500-13742-1MSD
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
8082
8082
8082
8082
8082
8082
500-46497
500-46497
500-46497
500-46497
500-46497
500-46497
LCS 500-46497/2-A
MB 500-46497/1-A
500-13742-1
500-13742-1MS
500-13742-1MSD
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
8081A
8081A
8081A
8081A
8081A
8081A
500-46497
500-46497
500-46497
500-46497
500-46497
500-46497
Report Basis
T = Total
TestAmerica Chicago
Page 21 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID
Client Sample ID
Report
Basis Client Matrix
Method
Prep Batch
Metals
LCS 500-46517/2-A
MB 500-46517/1-A
500-13742-1
500-13742-1DU
500-13742-1MS
500-13742-1MSD
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
Duplicate
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
Solid
3050B
3050B
3050B
3050B
3050B
3050B
3050B
LCS 500-46539/2-A
MB 500-46539/1-A
500-13742-1
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
PLOTE BF-02
T
T
T
T
Solid
Solid
Solid
Solid
7471A
7471A
7471A
7471A
LCS 500-46539/2-A
MB 500-46539/1-A
500-13742-1
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
PLOTE BF-02
T
T
T
T
Solid
Solid
Solid
Solid
7471A
7471A
7471A
7471A
500-46539
500-46539
500-46539
500-46539
LCS 500-46517/2-A
MB 500-46517/1-A
500-13742-1
500-13742-1DU
500-13742-1MS
500-13742-1MSD
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
Duplicate
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
Solid
6010B
6010B
6010B
6010B
6010B
6010B
6010B
500-46517
500-46517
500-46517
500-46517
500-46517
500-46517
500-46517
LCS 500-46517/2-A
MB 500-46517/1-A
500-13742-1
500-13742-1DU
500-13742-1MS
500-13742-1MSD
500-13742-2
Lab Control Spike
Method Blank
PLOTE BF-01
Duplicate
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
Solid
6010B
6010B
6010B
6010B
6010B
6010B
6010B
500-46517
500-46517
500-46517
500-46517
500-46517
500-46517
500-46517
Report Basis
T = Total
TestAmerica Chicago
Page 22 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID
Client Sample ID
Report
Basis Client Matrix
Method
Prep Batch
General Chemistry
500-13742-1
500-13742-2
PLOTE BF-01
PLOTE BF-02
T
T
Solid
Solid
9045C
9045C
500-13742-1
500-13742-2
PLOTE BF-01
PLOTE BF-02
T
T
Solid
Solid
PercentMoisture
PercentMoisture
HLCS 500-47118/27-A
LCS 500-47118/2-A
LLCS 500-47118/28-A
MB 500-47118/1-A
500-13742-1
500-13742-1MS
500-13742-1MSD
500-13742-2
High Level Control Sample
Lab Control Spike
Low Level Control Sample
Method Blank
PLOTE BF-01
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
Solid
Solid
9010B
9010B
9010B
9010B
9010B
9010B
9010B
9010B
HLCS 500-47118/27-A
LCS 500-47118/2-A
LLCS 500-47118/28-A
MB 500-47118/1-A
500-13742-1
500-13742-1MS
500-13742-1MSD
500-13742-2
High Level Control Sample
Lab Control Spike
Low Level Control Sample
Method Blank
PLOTE BF-01
Matrix Spike
PLOTE BF-02
T
T
T
T
T
T
T
T
Solid
Solid
Solid
Solid
Solid
Solid
Solid
Solid
9014
9014
9014
9014
9014
9014
9014
9014
500-47118
500-47118
500-47118
500-47118
500-47118
500-47118
500-47118
500-47118
Report Basis
T = Total
TestAmerica Chicago
Page 23 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Solid
12DCE
%Rec
TOL
%Rec
BFB
%Rec
PLOTE BF-01
105
91
94
98
PLOTE BF-02
109
93
95
101
MB 500-46728/17
96
91
94
90
LCS 500-46728/19
91
91
91
92
Lab Sample ID
Client Sample ID
500-13742-1
500-13742-2
Surrogate
12DCE = 1,2-Dichloroethane-d4 (Surr)
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene (Surr)
DBFM = Dibromofluoromethane
DBFM
%Rec
Acceptance Limits
75-140
75-130
75-120
75-140
TestAmerica Chicago
Page 24 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)
FBP
%Rec
2FP
%Rec
NBZ
%Rec
PHL
%Rec
TPH
%Rec
TBP
%Rec
PLOTE BF-01
85
74
77
71
88
102
PLOTE BF-02
83
72
78
79
91
100
MB 500-46612/1-A
91
90
95
95
98
84
LCS 500-46612/2-A
83
84
88
90
102
74
Lab Sample ID
Client Sample ID
500-13742-1
500-13742-2
Surrogate
FBP = 2-Fluorobiphenyl
2FP = 2-Fluorophenol
NBZ = Nitrobenzene-d5
PHL = Phenol-d5
TPH = Terphenyl-d14
TBP = 2,4,6-Tribromophenol
Acceptance Limits
33-114
25-111
21-116
31-110
48-146
32-138
TestAmerica Chicago
Page 25 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
8081A Organochlorine Pesticides by Gas Chromatography
DCB1
%Rec
TCX1
%Rec
PLOTE BF-01
58
52
PLOTE BF-02
60
66
68
41
Lab Sample ID
Client Sample ID
500-13742-1
500-13742-2
MB 500-46497/1-A
LCS 500-46497/2-A
75
50
500-13742-1 MS
PLOTE BF-01 MS
62
58
500-13742-1 MSD
PLOTE BF-01 MSD
66
66
Surrogate
DCB = DCB Decachlorobiphenyl
TCX = Tetrachloro-m-xylene
Acceptance Limits
42-142
30-127
TestAmerica Chicago
Page 26 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
8082 Polychlorinated Biphenyls (PCBs) by Gas Chromatography
TCX1
%Rec
DCB1
%Rec
PLOTE BF-01
66
72
PLOTE BF-02
73
70
48
89
Lab Sample ID
Client Sample ID
500-13742-1
500-13742-2
MB 500-46497/1-A
LCS 500-46497/3-A
69
85
500-13742-1 MS
PLOTE BF-01 MS
78
83
500-13742-1 MSD
PLOTE BF-01 MSD
81
79
Surrogate
TCX = Tetrachloro-m-xylene
DCB = DCB Decachlorobiphenyl
Acceptance Limits
32-127
44-140
TestAmerica Chicago
Page 27 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Method Blank - Batch: 500-46728
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46728/17
Solid
1.0
09/06/2008 0931
N/A
Method: 8260B
Preparation: N/A
Analysis Batch: 500-46728
Prep Batch: N/A
Units: mg/Kg
Analyte
Result
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
1,1-Dichloroethene
Acetone
Carbon disulfide
Methylene Chloride
1,1-Dichloroethane
Methyl Ethyl Ketone
Chloroform
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
Xylenes, Total
Styrene
Bromoform
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.0050
<0.010
<0.0050
<0.0050
<0.0050
<0.0050
Surrogate
Toluene-d8 (Surr)
Instrument ID: Agilent 6890N GC - 5975N MS
Lab File ID:
18M0906.D
Initial Weight/Volume: 5 g
Final Weight/Volume: 5 mL
Qual
MDL
RL
0.0016
0.0014
0.0022
0.0012
0.00088
0.0019
0.00094
0.00078
0.0010
0.0013
0.00096
0.00096
0.0018
0.00098
0.00089
0.00094
0.00085
0.0011
0.00096
0.00094
0.00078
0.00080
0.0015
0.00088
0.00096
0.0018
0.00080
0.0012
0.00083
0.00068
0.00071
0.0015
0.00075
0.0010
0.0012
0.00096
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.0050
0.010
0.0050
0.0050
0.0050
0.0050
% Rec
Acceptance Limits
96
91
94
75 - 140
75 - 130
75 - 120
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Chicago
Page 28 of 51
09/16/2008
Surrogate
Job Number: 500-13742-1
Sdg Number: 500-13742-1
% Rec
Acceptance Limits
90
75 - 140
TestAmerica Chicago
Page 29 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Control Spike - Batch: 500-46728
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46728/19
Solid
1.0
09/06/2008 0957
N/A
Method: 8260B
Preparation: N/A
Prep Batch: N/A
Units: mg/Kg
Lab File ID:
18S0906.D
Analyte
Spike Amount
Result
% Rec.
Limit
Chloromethane
Vinyl chloride
Bromomethane
Chloroethane
1,1-Dichloroethene
Acetone
Carbon disulfide
Methylene Chloride
1,1-Dichloroethane
Methyl Ethyl Ketone
Chloroform
Benzene
1,2-Dichloroethane
Trichloroethene
1,2-Dichloropropane
Toluene
Tetrachloroethene
2-Hexanone
Chlorobenzene
Ethylbenzene
Xylenes, Total
Styrene
Bromoform
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.0538
0.0500
0.0500
0.0486
0.0500
0.0500
0.0500
0.0500
0.0500
0.0500
0.150
0.0500
0.0500
0.0500
0.0435
0.0522
0.0455
0.0461
0.0399
0.0531
0.0364
0.0454
0.0432
0.0476
0.0436
0.0457
0.0469
0.0437
0.0430
0.0420
0.0431
0.0468
0.0438
0.0475
0.0438
0.0409
0.0429
0.0426
0.0353
0.0439
0.0436
0.0444
0.0402
0.0424
0.0438
0.133
0.0438
0.0353
0.0457
87
104
91
92
80
106
73
91
86
95
87
91
94
87
86
84
86
94
88
95
88
76
86
85
73
88
87
89
80
85
88
89
88
71
91
36 - 143
49 - 133
51 - 154
42 - 155
58 - 127
24 - 147
33 - 140
66 - 124
70 - 120
66 - 122
70 - 120
79 - 120
50 - 120
76 - 120
70 - 120
63 - 120
76 - 120
74 - 120
74 - 120
75 - 120
80 - 120
69 - 120
65 - 126
78 - 120
70 - 120
77 - 120
70 - 120
58 - 120
72 - 120
76 - 120
78 - 120
77 - 120
82 - 120
57 - 120
73 - 120
Surrogate
Toluene-d8 (Surr)
% Rec
Acceptance Limits
91
91
91
92
75 - 140
75 - 130
75 - 120
75 - 140
Qual
TestAmerica Chicago
Page 30 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
TestAmerica Chicago
Page 31 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46612/1-A
Solid
1.0
09/09/2008 1325
09/05/2008 0605
Method: 8270C
Preparation: 3541
Units: mg/Kg
Analyte
Result
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Carbazole
4-Chloroaniline
2-Chloronaphthalene
2-Chlorophenol
Chrysene
Dibenzofuran
2,4-Dichlorophenol
Diethyl phthalate
2,4-Dimethylphenol
Dimethyl phthalate
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Isophorone
<0.033
<0.033
<0.033
<0.033
<0.033
<0.033
<0.033
<0.033
<0.17
<0.17
<0.17
<0.17
<0.17
<0.17
<0.67
<0.33
<0.17
<0.17
<0.17
<0.033
<0.033
<0.17
<0.17
<0.33
<0.17
<0.33
<0.17
<0.17
<0.33
<0.67
<0.17
<0.17
<0.17
<0.033
<0.033
<0.067
<0.17
<0.67
<0.17
<0.033
<0.17
Lab File ID:
46612M.D
Initial Weight/Volume: 15.0000 g
Final Weight/Volume: 0.5 mL
Injection Volume:
1.0 uL
Qual
MDL
RL
0.0042
0.0035
0.0039
0.0042
0.0031
0.0073
0.0057
0.0071
0.021
0.022
0.028
0.013
0.015
0.013
0.13
0.081
0.015
0.029
0.014
0.0052
0.0041
0.012
0.049
0.036
0.017
0.061
0.013
0.013
0.040
0.18
0.018
0.018
0.015
0.0043
0.0035
0.0048
0.019
0.11
0.018
0.0043
0.014
0.033
0.033
0.033
0.033
0.033
0.033
0.033
0.033
0.17
0.17
0.17
0.17
0.17
0.17
0.67
0.33
0.17
0.17
0.17
0.033
0.033
0.17
0.17
0.33
0.17
0.33
0.17
0.17
0.33
0.67
0.17
0.17
0.17
0.033
0.033
0.067
0.17
0.67
0.17
0.033
0.17
TestAmerica Chicago
Page 32 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46612/1-A
Solid
1.0
09/09/2008 1325
09/05/2008 0605
Method: 8270C
Preparation: 3541
Units: mg/Kg
Analyte
Result
2-Methylnaphthalene
2-Methylphenol
3 & 4 Methylphenol
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
<0.17
<0.17
<0.17
<0.033
<0.17
<0.33
<0.33
<0.033
<0.33
<0.67
<0.17
<0.17
<0.17
<0.67
<0.033
<0.17
<0.033
<0.33
<0.33
Surrogate
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
Lab File ID:
46612M.D
Injection Volume:
1.0 uL
Qual
MDL
RL
0.019
0.033
0.031
0.0034
0.018
0.065
0.071
0.0061
0.040
0.058
0.023
0.0099
0.017
0.12
0.0029
0.029
0.0039
0.047
0.034
0.17
0.17
0.17
0.033
0.17
0.33
0.33
0.033
0.33
0.67
0.17
0.17
0.17
0.67
0.033
0.17
0.033
0.33
0.33
% Rec
Acceptance Limits
91
90
95
95
98
84
33 - 114
25 - 111
21 - 116
31 - 110
48 - 146
32 - 138
TestAmerica Chicago
Page 33 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46612/2-A
Solid
1.0
09/09/2008 1600
09/05/2008 0605
Method: 8270C
Preparation: 3541
Units: mg/Kg
Lab File ID:
46612BS.D
Injection Volume:
1.0 uL
Analyte
Spike Amount
Result
% Rec.
Limit
Acenaphthene
Acenaphthylene
Anthracene
Benzo[a]anthracene
Benzo[a]pyrene
Carbazole
4-Chloroaniline
2-Chloronaphthalene
2-Chlorophenol
Chrysene
Dibenzofuran
2,4-Dichlorophenol
Diethyl phthalate
2,4-Dimethylphenol
Dimethyl phthalate
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachloroethane
Isophorone
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.29
1.28
1.36
1.53
1.49
1.54
1.44
1.56
1.37
1.41
1.59
1.45
1.65
1.43
0.941
1.45
1.34
1.43
1.43
1.57
1.42
1.31
0.998
1.36
1.44
1.36
1.40
1.57
0.757
0.222
1.45
1.45
1.82
1.48
1.34
1.43
1.29
0.561
1.26
1.41
1.21
77
77
82
92
90
92
86
94
82
84
96
87
99
86
56
87
80
86
86
94
85
79
60
82
87
82
84
94
45
13
87
87
109
89
80
86
77
34
75
85
73
60 - 110
61 - 110
62 - 110
60 - 117
61 - 111
56 - 118
61 - 113
51 - 114
62 - 110
51 - 110
57 - 120
64 - 112
59 - 117
63 - 110
27 - 110
60 - 110
44 - 116
61 - 110
63 - 110
56 - 117
37 - 124
63 - 110
33 - 110
63 - 110
64 - 110
53 - 110
64 - 110
64 - 112
20 - 112
10 - 121
66 - 117
67 - 112
56 - 116
62 - 110
63 - 110
61 - 118
54 - 116
20 - 110
53 - 110
58 - 110
52 - 110
Qual
J
J
TestAmerica Chicago
Page 34 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46612/2-A
Solid
1.0
09/09/2008 1600
09/05/2008 0605
Method: 8270C
Preparation: 3541
Units: mg/Kg
Lab File ID:
46612BS.D
Injection Volume:
1.0 uL
Analyte
Spike Amount
Result
% Rec.
Limit
2-Methylnaphthalene
2-Methylphenol
3 & 4 Methylphenol
Naphthalene
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.67
1.27
1.35
1.53
1.25
1.61
1.03
1.38
1.27
1.39
1.18
1.41
1.84
1.29
0.624
1.47
1.46
1.53
1.31
1.42
76
81
92
75
96
62
83
76
83
71
84
111
77
37
88
87
92
78
85
34 - 122
58 - 110
57 - 110
57 - 110
58 - 111
39 - 112
49 - 119
57 - 110
60 - 110
30 - 130
54 - 110
63 - 110
38 - 110
26 - 114
63 - 110
50 - 110
56 - 121
63 - 116
62 - 117
Surrogate
2-Fluorobiphenyl
2-Fluorophenol
Nitrobenzene-d5
Phenol-d5
Terphenyl-d14
% Rec
Acceptance Limits
83
84
88
90
102
74
33 - 114
25 - 111
21 - 116
31 - 110
48 - 146
32 - 138
Qual
*
J
TestAmerica Chicago
Page 35 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46497/1-A
Solid
1.0
09/10/2008 1559
09/04/2008 0653
Method: 8081A
Preparation: 3541
Units: mg/Kg
Analyte
Result
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Aldrin
Heptachlor epoxide
Endosulfan I
Dieldrin
4,4'-DDE
Endrin
Endosulfan II
4,4'-DDD
Endosulfan sulfate
4,4'-DDT
Methoxychlor
Endrin ketone
Endrin aldehyde
alpha-Chlordane
gamma-Chlordane
Toxaphene
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0017
<0.0083
<0.0017
<0.0017
<0.0017
<0.0017
<0.017
Surrogate
Instrument ID: HP 6890 GC
Lab File ID:
09060816_201.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
Qual
MDL
RL
0.00057
0.00092
0.00074
0.00030
0.00023
0.00057
0.00036
0.00071
0.00033
0.00033
0.00062
0.00035
0.00053
0.00016
0.00030
0.00049
0.00030
0.00063
0.00046
0.00054
0.0030
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0017
0.0083
0.0017
0.0017
0.0017
0.0017
0.017
% Rec
Acceptance Limits
68
41
42 - 142
30 - 127
TestAmerica Chicago
Page 36 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46497/2-A
Solid
1.0
09/10/2008 1624
09/04/2008 0653
Method: 8081A
Preparation: 3541
Units: mg/Kg
Lab File ID:
09060816_202.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
Analyte
Spike Amount
Result
% Rec.
Limit
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Aldrin
Heptachlor epoxide
Endosulfan I
Dieldrin
4,4'-DDE
Endrin
Endosulfan II
4,4'-DDD
Endosulfan sulfate
4,4'-DDT
Methoxychlor
Endrin ketone
Endrin aldehyde
alpha-Chlordane
gamma-Chlordane
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.0133
0.00722
0.00924
0.0103
0.00890
0.00883
0.00795
0.00944
0.00542
0.00963
0.00952
0.0104
0.00669
0.00997
0.00996
0.0104
0.0107
0.00978
0.00912
0.00921
0.00940
54
69
77
67
66
60
71
41
72
71
78
50
75
75
78
81
73
68
69
70
36 - 115
55 - 117
51 - 126
42 - 117
39 - 117
40 - 114
43 - 123
20 - 110
55 - 122
56 - 123
50 - 131
31 - 110
59 - 126
62 - 122
59 - 138
54 - 135
58 - 128
51 - 125
54 - 120
53 - 119
Surrogate
% Rec
Acceptance Limits
75
50
42 - 142
30 - 127
Qual
TestAmerica Chicago
Page 37 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 500-46497
Method: 8081A
Preparation: 3541
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
2.0
09/10/2008 1855
09/04/2008 0653
Lab File ID:
09060816_208.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
2.0
09/10/2008 1920
09/04/2008 0653
Lab File ID:
09060816_209.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
Analyte
MS
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Heptachlor
Aldrin
Heptachlor epoxide
Endosulfan I
Dieldrin
4,4'-DDE
Endrin
Endosulfan II
4,4'-DDD
Endosulfan sulfate
4,4'-DDT
Methoxychlor
Endrin ketone
Endrin aldehyde
alpha-Chlordane
gamma-Chlordane
57
58
61
58
67
60
63
35
63
65
68
42
63
64
70
62
60
62
58
59
% Rec.
MSD
63
60
64
64
71
62
65
35
64
64
70
43
64
67
73
65
63
66
59
61
Limit
RPD
RPD Limit
36 - 115
55 - 117
51 - 126
42 - 117
39 - 117
40 - 114
43 - 123
20 - 110
55 - 122
56 - 123
50 - 131
31 - 110
59 - 126
62 - 122
59 - 138
54 - 135
58 - 128
51 - 125
54 - 120
53 - 119
13
6
7
12
8
5
6
4
4
1
4
5
3
7
5
7
6
8
4
5
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Surrogate
MS % Rec
MSD % Rec
62
58
66
66
MS Qual MSD Qual
J
J
Acceptance Limits
42 - 142
30 - 127
TestAmerica Chicago
Page 38 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46497/1-A
Solid
1.0
09/10/2008 1219
09/04/2008 0653
Method: 8082
Preparation: 3541
Units: mg/Kg
Analyte
Result
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
<0.017
Surrogate
Instrument ID: Agilent 6890A Series Plus GC
Lab File ID:
09090847_073.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
Qual
LCS 500-46497/3-A
Solid
1.0
09/10/2008 1233
09/04/2008 0653
RL
0.0072
0.0091
0.0062
0.010
0.0087
0.0060
0.0062
0.0060
0.017
0.017
0.017
0.017
0.017
0.017
0.017
0.017
% Rec
Acceptance Limits
48
89
32 - 127
44 - 140
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MDL
Method: 8082
Preparation: 3541
Units: mg/Kg
Lab File ID:
09090847_074.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
Analyte
Spike Amount
Result
% Rec.
Limit
PCB-1016
PCB-1260
0.167
0.167
0.121
0.136
73
81
50 - 113
61 - 120
Surrogate
% Rec
Acceptance Limits
69
85
32 - 127
44 - 140
Qual
TestAmerica Chicago
Page 39 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Matrix Spike/
Method: 8082
Preparation: 3541
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/10/2008 1411
09/04/2008 0653
Instrument ID: Agilent 6890A Series Plus
Lab File ID:
09090847_081.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/10/2008 1425
09/04/2008 0653
Lab File ID:
09090847_082.d
Injection Volume:
1.0 uL
Column ID:
PRIMARY
Analyte
MS
PCB-1016
PCB-1260
78
82
% Rec.
MSD
76
79
Limit
RPD
RPD Limit
50 - 113
61 - 120
3
3
30
30
Surrogate
MS % Rec
MSD % Rec
78
83
81
79
MS Qual MSD Qual
Acceptance Limits
32 - 127
44 - 140
TestAmerica Chicago
Page 40 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46517/1-A
Solid
1.0
09/04/2008 2023
09/04/2008 0921
Method: 6010B
Preparation: 3050B
Units: mg/Kg
Instrument ID: TJA ICAP 61E Trace Analyzer
Lab File ID:
P40904B
Analyte
Result
Qual
MDL
RL
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
6.1
0.82
<1.0
<1.0
<0.40
<0.20
<1.0
<0.50
<1.0
3.9
0.39
1.5
<1.0
<1.0
<50
<1.0
<0.50
84
<1.0
<0.50
0.52
J
J
1.8
0.29
0.29
0.032
0.010
0.033
0.087
0.073
0.45
2.0
0.11
1.2
0.031
0.062
6.1
0.38
0.10
20
0.33
0.085
0.18
20
2.0
1.0
1.0
0.40
0.20
1.0
0.50
1.0
10
0.50
10
1.0
1.0
50
1.0
0.50
100
1.0
0.50
2.0
J
J
J
J
J
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46517/1-A
Solid
1.0
09/10/2008 2316
09/04/2008 0921
Method: 6010B
Preparation: 3050B
Lab File ID:
P40910B
Units: mg/Kg
Analyte
Result
Qual
MDL
RL
Calcium
5.6
J
0.85
10
TestAmerica Chicago
Page 41 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46517/2-A
Solid
1.0
09/04/2008 2030
09/04/2008 0921
Method: 6010B
Preparation: 3050B
Units: mg/Kg
Lab File ID:
P40904B
Analyte
Spike Amount
Result
% Rec.
Limit
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
200
50.0
10.0
200
5.00
5.00
20.0
50.0
25.0
100
10.0
1000
50.0
50.0
1000
10.0
5.00
1000
10.0
50.0
50.0
189
44.0
8.47
187
4.73
4.84
19.8
48.0
24.4
98.0
9.79
923
49.6
47.3
964
8.20
4.72
976
8.64
48.7
48.7
95
88
85
94
95
97
99
96
97
98
98
92
99
95
96
82
94
98
86
97
97
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
80 - 120
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46517/2-A
Solid
1.0
09/10/2008 2323
09/04/2008 0921
Qual
Method: 6010B
Preparation: 3050B
Lab File ID:
P40910B
Units: mg/Kg
Analyte
Spike Amount
Result
% Rec.
Limit
Calcium
1000
990
99
80 - 120
Qual
TestAmerica Chicago
Page 42 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Matrix Spike/
Method: 6010B
Preparation: 3050B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/04/2008 2203
09/04/2008 0921
Instrument ID: TJA ICAP 61E Trace
Lab File ID:
P40904B
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/04/2008 2210
09/04/2008 0921
Lab File ID:
P40904B
% Rec.
MSD
Analyte
MS
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
1330
60
114
96
90
91
108
90
138
658
108
-128
-48
92
244
75
102
138
78
105
105
1080
62
90
95
88
90
103
86
110
-2030
67
530
-8
85
243
76
101
127
80
102
91
Limit
RPD
RPD Limit
MS Qual MSD Qual
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
75 - 125
10
1
17
2
3
2
5
5
16
22
20
14
4
7
1
0
2
5
1
4
10
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
4
F
F
4
4
F
4
4
4
F
4
4
F
F
F
F
TestAmerica Chicago
Page 43 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Matrix Spike/
Method: 6010B
Preparation: 3050B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
10
09/10/2008 2351
09/04/2008 0921
Instrument ID: TJA ICAP 61E Trace
Lab File ID:
P40910B
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
10
09/10/2008 2358
09/04/2008 0921
Lab File ID:
P40910B
Analyte
MS
Calcium
-274
% Rec.
MSD
508
Limit
RPD
RPD Limit
MS Qual MSD Qual
75 - 125
8
20
4
4
TestAmerica Chicago
Page 44 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Duplicate - Batch: 500-46517
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/04/2008 2156
09/04/2008 0921
Method: 6010B
Preparation: 3050B
Units: mg/Kg
Lab File ID:
P40904B
Analyte
Sample Result/Qual
Result
RPD
Limit
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
2700
<1.7
4.5
12
0.15
0.44
5.1
4.6
15
13000
12
46000
570
12
1100
0.34
<0.43
1200
0.74
11
29
3120
0.344
7.01
12.8
0.172
0.396
6.83
5.30
17.3
12300
11.1
43300
521
12.7
1210
0.339
<0.44
1390
0.446
12.7
36.3
14
NC
43
9
12
10
28
14
15
6
9
5
10
5
6
0
NC
13
50
15
23
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
20
J
J
J
Duplicate - Batch: 500-46517
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
10
09/10/2008 2344
09/04/2008 0921
Qual
J
F
J
F
J
J
F
Method: 6010B
Preparation: 3050B
Lab File ID:
P40910B
Units: mg/Kg
Analyte
Sample Result/Qual
Result
RPD
Limit
Calcium
97000
101000
4
20
Qual
TestAmerica Chicago
Page 45 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-46539/1-A
Solid
1.0
09/04/2008 1431
09/04/2008 1030
Method: 7471A
Preparation: 7471A
Units: mg/Kg
Analyte
Result
Mercury
<0.017
Instrument ID: Leeman Labs PS200 Mercury
Lab File ID:
N/A
Qual
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-46539/2-A
Solid
1.0
09/04/2008 1433
09/04/2008 1030
MDL
RL
0.0067
0.017
Method: 7471A
Preparation: 7471A
Units: mg/Kg
Instrument ID: Leeman Labs PS200 Mercury
Lab File ID:
N/A
Analyte
Spike Amount
Result
% Rec.
Limit
Mercury
0.167
0.169
101
80 - 120
Qual
TestAmerica Chicago
Page 46 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 500-47118/1-A
Solid
1.0
09/12/2008 1310
09/11/2008 0835
Method: 9014
Preparation: 9010B
Units: mg/Kg
Analyte
Result
Cyanide, Total
<0.010
Instrument ID: No Equipment Assigned
Lab File ID:
N/A
Initial Weight/Volume: 50 mL
Qual
MDL
RL
0.0025
0.010
TestAmerica Chicago
Page 47 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 500-47118/2-A
Solid
1.0
09/12/2008 1310
09/11/2008 0835
Method: 9014
Preparation: 9010B
Units: mg/Kg
Lab File ID:
N/A
Analyte
Spike Amount
Result
% Rec.
Limit
Cyanide, Total
0.100
0.105
105
80 - 120
High Level Control Sample - Batch: 500-47118
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
HLCS 500-47118/27-A
Solid
1.0
09/12/2008 1311
09/11/2008 0835
Method: 9014
Preparation: 9010B
N/A
Lab File ID:
Units: mg/Kg
Analyte
Spike Amount
Result
% Rec.
Limit
Cyanide, Total
0.400
0.398
100
80 - 120
Low Level Control Sample - Batch: 500-47118
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LLCS 500-47118/28-A
Solid
1.0
09/12/2008 1311
09/11/2008 0835
Qual
Qual
Method: 9014
Preparation: 9010B
Lab File ID:
N/A
Units: mg/Kg
Analyte
Spike Amount
Result
% Rec.
Limit
Cyanide, Total
0.0400
0.0449
112
75 - 125
Qual
TestAmerica Chicago
Page 48 of 51
09/16/2008
Job Number: 500-13742-1
Sdg Number: 500-13742-1
Matrix Spike/
Method: 9014
Preparation: 9010B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/12/2008 1311
09/11/2008 0835
Lab File ID:
N/A
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
500-13742-1
Solid
1.0
09/12/2008 1312
09/11/2008 0835
Lab File ID:
N/A
Analyte
MS
Cyanide, Total
106
% Rec.
MSD
109
Limit
RPD
RPD Limit
75 - 125
4
20
MS Qual MSD Qual
TestAmerica Chicago
Page 49 of 51
09/16/2008
Page 50 of 51
09/16/2008
Login Sample Receipt Check List
Job Number: 500-13742-1
SDG Number: 500-13742-1
Login Number: 13742
Creator: Lunt, Jeff T
List Number: 1
List Source: TestAmerica Chicago
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
True
TestAmerica Chicago
Comment
True
True
True
True
True
True
True
True
True
4.6
True
True
True
True
True
True
True
True
True
True
True
Page 51 of 51
09/16/2008

Remedial Action Plan

Transcription

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