Authors: Ingunn Saur Modahl, Andreas Brekke and Hanne Lerche
Transcription
Authors: Ingunn Saur Modahl, Andreas Brekke and Hanne Lerche
Authors: Ingunn Saur Modahl, Andreas Brekke and Hanne Lerche Raadal OR.17.09 og Andreas Brekke ISBN: 978-82-7520-610-5 / 82-7520-610-3 Navn Navn Report no.: OR.17.09 ISBN no.: 978-82-7520-610-5 Type of report: ISBN no.: 82-7520-610-3 Commissioned report ISSN no.: 0803-6659 Report title: Authors: Ingunn Saur Modahl, Andreas Brekke and Hanne Lerche Raadal Project no: 1223 Project title: Life cycle assessment phase II, environmental impact assessment of the products from Borregaard Commissioner: Commissioners reference: Borregaard Industries Limited, Norway Tuva Barnholt Keywords: Availability: LCA Greenhouse gas account Wood conversion Bio refinery Number of pages incl. appendixes: 69 Open Approved: Date: 14th of April, 2009 Project leader (Sign) © Copying with reference allowed Research leader (Sign) CONTENTS 1 2 INTRODUCTION .........................................................................................................................................1 1.1 BACKGROUND ....................................................................................................................................1 1.2 METHODOLOGY..................................................................................................................................2 1.3 GENERAL LIMITATIONS OF LCA .........................................................................................................4 1.4 MANAGEMENT OF THE PROJECT .........................................................................................................4 GOAL, SYSTEM BOUNDARIES AND DATA .......................................................................................... 6 2.1 GOAL OF THE ANALYSIS .....................................................................................................................6 2.2 FUNCTIONAL UNIT .............................................................................................................................. 6 2.3 SYSTEM DESCRIPTION AND SYSTEM BOUNDARIES ..............................................................................6 2.4 DATASET AND CONDITIONS ................................................................................................................8 2.4.1 About the datasets ...................................................................................................................8 2.4.2 Collection of specific data for raw materials and chemicals ...................................................9 2.4.3 Modelling of the infrastructure at Borregaard ...................................................................... 10 2.4.4 Choice of electricity model ................................................................................................... 12 2.4.5 Transport to customer ........................................................................................................... 12 2.4.6 Changes compared to phase 1 of the project......................................................................... 13 3 2.5 ALLOCATION .................................................................................................................................... 14 2.6 QUALITY CONTROL .......................................................................................................................... 16 RESULTS ................................................................................................................................................... 17 3.1 GLOBAL WARMING POTENTIAL (GWP) ........................................................................................... 17 3.2 ACIDIFICATION POTENTIAL .............................................................................................................. 20 3.3 EUTROPHICATION POTENTIAL........................................................................................................... 24 3.4 PHOTOCHEMICAL OZONE CREATION POTENTIAL (POCP) ................................................................... 27 3.5 OZONE DEPLETION POTENTIAL (ODP) ............................................................................................. 32 3.6 CUMULATIVE ENERGY DEMAND (CED) ........................................................................................... 35 3.7 WASTE ............................................................................................................................................. 38 3.8 OTHER ENVIRONMENTAL IMPACT CATEGORIES ................................................................................ 41 4 SUMMARY AND CONCLUSIONS .......................................................................................................... 42 5 REFERENCES ............................................................................................................................................ 47 i Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Appendix 1 Appendix 2 Appendix 3 Appendix 4 Appendix 5 Appendix 6 Aggregated results Data for emissions and water consumption Borregaard Masses and treatment of waste from Borregaard How to read the LCA network figure? LCA – what, why and how? Environmental impact categories and potential effects ii Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 1 INTRODUCTION 1.1 BACKGROUND 1 LCA = Life Cycle Assessment. Wikipedia: http://en.wikipedia.org/wiki/Life_cycle_assessment . Introduction to LCA is presented in appendixes. 2 EPD = Environmental Product Declaration. Standardised (ISO 14025) method for presentation of LCA results. www.environdec.com 1 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 1.2 METHODOLOGY - 3 International organisation for Standardisation; http://www.iso.org/iso/iso_catalogue.htm ISO 14044: Environmental management -- Life cycle assessment -- Requirements and guidelines ISO 14048: Environmental management -- Life cycle assessment -- Data documentation format 2 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Table 1 Impact assessment methods used in this study4 Environmental impact category Impact assessment method Unit Comment Global warming potential (GWP) CML 2 baseline 2000 v.2.04 and IPPC 2001 5 GWP 100a , V1.04 kg CO2-eqv. Corrected for new data for methane in 2005 (IPCC). Assuming steady state in biogenic systems (not considering uptake of CO2 in biological systems, nor counting biogenic CO 2 when burning biological matter). Acidification potential CML 2 baseline 2000, V2.04. kg SO2-eqv. Eutrophication potential CML 2 baseline 2000, V2.04. kg PO4 -eqv. Photochemical ozone creation potential (POCP): CML 2 baseline 2000, V2.04. kg C2H4-eqv (ethene/ ethyleneeqv.) Ozone depletion potential Human and eco toxicity CML 2 baseline 2000, V2.04. CML 2 baseline 2000, V2.04. Resource consumption in the form of area consumption Resource use in the form of material consumption Resource consumption in the form of cumulative energy demand, several categories (CED) Waste (several categories) CML 2001 (all impact categories), V2.04. - kg CFC-11eqv. kg 1.4dichlorobenz ene-eqv. 2 ma -3 Ostfold Research has included emission factors for some groups of emissions (VOC, NMVOC, alkenes, aromatics and esters). The calculations are made according to the LCA-guide from the University of Leiden (Universiteit Leiden, 2005). The last update is from 26/4-05. Not included in this analysis. Not included in this analysis. kg Not included in this analysis. CML 1992 V2.05 and Cumulative Energy Demand V1.05 by Ecoinvent MJ LHV Developed by Ostfold Research, based on own experience, EPD-guidelines and Norwegian regulations in addition to the given methods here. EDIP/UMIP 97 V2.03 (waste). kg waste Developed by Ostfold Research, based on own experience, EPD-guidelines and Norwegian regulations in addition to the given methods here. 4 An explanation of the environmental impact categories and potential effects is found in Appendix 6. Characterisation factors are found at the homepage of University of Leiden: http://www.leidenuniv.nl/interfac/cml/ssp/projects/lca2/lca2.html Here you can find the CML-IA database, which can be downloaded free of charge (Universiteit Leiden, 2007). 5 The global warming potential is based on a time horizon of 100 years. Gases have different lifetimes in the atmosphere, and hence models have been developed for different time horizons. A time horizon of 100 years is most commonly used. 3 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 1.3 GENERAL LIMITATIONS OF LCA 6 - - - 1.4 MANAGEMENT OF THE PROJECT 6 See explanation of the different environmental impact categories in appendix. 4 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 5 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 2 GOAL, SYSTEM BOUNDARIES AND DATA 2.1 GOAL OF THE ANALYSIS 2.2 FUNCTIONAL UNIT The functional unit is 1 tonne product for cellulose, lignin and vanillin and 1 m3 product for ethanol8 2.3 SYSTEM DESCRIPTION AND SYSTEM BOUNDARIES 7 8 The product is called ’Ethanol (99%)’, the actual ethanol content is 99,9%. The analysis is performed on a ’dry basis’, meaning that the analysis is done per tonne dry matter (DM) of the products. For ethanol this means that the environmental impacts are distributed only on the amount of ethanol in the product (water contents are 0,1% and 4%). 6 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg ’ ’ 7 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Raw materials The factories at Borregaard Sarpsborg Products Ethanol 96% Ethanol 99% Production and transport of raw materials and energy carriers Cellulose Lignin (liquid) Lignin (powder) Vanillin 2.4 DATASET AND CONDITIONS 2.4.1 About the datasets 8 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 2.4.2 Collection of specific data for raw materials and chemicals 9 SimaPro is developed and supplied by Pré in the Netherlands. http://www.pre.nl/simapro/ 9 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 2.4.3 Modelling of the infrastructure at Borregaard 10 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 11 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 2.4.4 Choice of electricity model 2.4.5 Transport to customer 12 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Table 2 DM content in the Borregaard products Wet basis Product Content of dry matter Dry basis Water content kg DM/kg product kg w ater/kg product Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Table 3 Product Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin 0.930 0.960 0.999 0.510 0.950 0.999 Content of dry matter Water content Transport correction factor kg DM/kg DM kg w ater/kg DM kg product/kg DM 1.000 1.000 1.000 1.000 1.000 1.000 0.075 0.042 0.001 0.961 0.053 0.001 1.075 1.042 1.001 1.961 1.053 1.001 0.070 0.040 0.001 0.490 0.050 0.001 Corrected transport distance and distribution on means of transportation Transport distance km 100 100 100 100 100 100 Corrected transport distance km 107.5 104.2 100.1 196.1 105.3 100.1 Ship 55 % 10 % 10 % 80 % 65 % 50 % Distribution Lorry 40 % 5% 5% 15 % 35 % 50 % Rail 5% 85 % 85 % 5% 0% 0% 2.4.6 Changes compared to phase 1 of the project 13 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 2.5 ALLOCATION 14 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Table 4 Applied heat values and densities Biological dry matter Ethanol Heat value (LHV) 6.8 GJ/fm3 17 GJ/tonnes 4.7 MWh/tonnes 29.7 MJ/kg Density 3 0.4 tonnes/fm 0.789 kg/l Reference/comment SSB (2006) Calculated Calculated Wikipedia (2008a) 15 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 2.6 QUALITY CONTROL 16 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3 RESULTS 3.1 GLOBAL WARMING POTENTIAL (GWP) Global Warming potential (GWP) 1600 1400 1200 kg CO2-eqv. 1000 800 600 400 200 0 1 tonne 1 m3 1 m3 1 tonne 1 tonne 1 tonne Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin 9 4 4 8 8 10 Other internal processes at Borregaard + various 37 4 32 20 55 58 Combustion of oil at Borregaard 501 129 321 298 531 479 Combustion of waste at Borregaard 102 27 66 37 65 98 6 5 5 6 6 6 Production and transport of timber, wood chips and chemicals 199 77 77 106 192 283 Production and transport of energy carriers 366 95 191 237 377 420 Transport of product to customer (100 km) Borregaard's own infrastructure 17 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 18 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 19 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3.2 ACIDIFICATION POTENTIAL Acidification potential 14 12 10 kg SO2-eqv. 8 6 4 2 0 1 tonne 1 m3 1 m3 1 tonne 1 tonne 1 tonne Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Transport of product to customer (100 km) 0.1 0.0 0.0 0.1 0.1 0.1 Other internal processes at Borregaard + various 1.6 0.3 0.6 0.8 1.0 1.3 Combustion of oil at Borregaard 3.1 0.8 2.0 1.1 3.0 2.9 Combustion of waste at Borregaard 0.7 0.2 0.4 0.2 0.4 0.6 Borregaard's own infrastructure 0.0 0.0 0.0 0.0 0.0 0.0 Production and transport of timber, wood chips and chemicals 4.4 2.1 2.6 4.1 4.3 5.2 Production and transport of energy carriers 1.5 0.4 0.8 0.8 1.7 1.6 20 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 21 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 22 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 23 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3.3 EUTROPHICATION POTENTIAL Eutrophication potential 3.5 3.0 2.5 kg PO4-3-eqv. 2.0 1.5 1.0 0.5 0.0 1 tonne 1 m3 1 m3 1 tonne 1 tonne 1 tonne Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Cellulose Ethanol (96%) Transport of product to customer (100 km) 0.01 0.00 0.00 0.01 0.01 0.01 Other internal processes at Borregaard + various 2.86 0.79 1.06 1.37 2.25 1.99 Combustion of oil at Borregaard 0.10 0.03 0.07 0.09 0.10 0.10 Combustion of waste at Borregaard 0.10 0.03 0.06 0.04 0.06 0.09 Borregaard's own infrastructure 0.00 0.00 0.00 0.00 0.00 0.00 Production and transport of timber, wood chips and chemicals 0.05 0.06 0.08 0.06 0.17 0.13 Production and transport of energy carriers 0.14 0.04 0.08 0.08 0.16 0.15 24 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 25 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 26 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3.4 PHOTOCHEMICAL OZONE CREATION POTENTIAL (POCP) Photochemical ozone creation potential (POCP) 0.9 0.8 0.7 kg C 2H4-eqv. 0.6 0.5 0.4 0.3 0.2 0.1 0.0 1 tonne 1 m3 1 m3 1 tonne 1 tonne 1 tonne Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Transport of product to customer (100 km) 0.01 0.00 0.00 0.01 0.01 0.01 Other internal processes at Borregaard + various 0.08 0.02 0.03 0.03 0.06 0.05 Combustion of oil at Borregaard 0.15 0.04 0.10 0.07 0.15 0.14 Combustion of waste at Borregaard 0.06 0.01 0.04 0.02 0.04 0.05 Borregaard's own infrastructure 0.00 0.00 0.00 0.00 0.00 0.00 Production and transport of timber, wood chips and chemicals 0.25 0.12 0.15 0.22 0.26 0.34 Production and transport of energy carriers 0.16 0.04 0.09 0.08 0.18 0.17 27 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 28 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 29 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 30 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 31 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3.5 OZONE DEPLETION POTENTIAL (ODP) Ozone depletion potential (ODP) 1.2E-04 1.0E-04 kg CFC-11-eqv. 8.0E-05 6.0E-05 4.0E-05 2.0E-05 0.0E+00 Transport of product to customer (100 km) 1 tonne 1 m3 1 m3 1 tonne 1 tonne Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) 1 tonne Vanillin 1.4E-06 3.3E-07 3.2E-07 1.1E-06 1.2E-06 1.6E-06 Other internal processes at Borregaard + various 6.7E-06 9.6E-07 1.5E-06 1.8E-06 4.8E-06 2.4E-06 Combustion of oil at Borregaard 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 0.0E+00 Combustion of waste at Borregaard 1.3E-06 3.4E-07 8.5E-07 4.7E-07 8.4E-07 1.3E-06 Borregaard's own infrastructure 2.7E-07 2.2E-07 2.2E-07 2.7E-07 2.7E-07 2.7E-07 Production and transport of timber, wood chips and chemicals 1.3E-05 6.8E-06 8.6E-06 1.1E-05 2.2E-05 2.5E-05 Production and transport of energy carriers 6.7E-05 1.7E-05 4.0E-05 3.0E-05 7.9E-05 6.8E-05 32 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 33 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 34 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3.6 CUMULATIVE ENERGY DEMAND (CED) Cumulative energy demand (CED ) 40,000 35,000 30,000 MJ LHV 25,000 20,000 15,000 10,000 5,000 - 1 tonne 1 m3 1 m3 1 tonne 1 tonne 1 tonne Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Energy from waste and other energy sources 5,753 1,479 3,627 2,154 4,388 5,549 Renewable energy 7,385 1,844 3,994 3,841 5,970 7,734 Nyclear power 6,531 1,588 3,036 4,006 6,150 7,786 Fossil energy 13,325 3,806 7,426 8,214 14,973 15,422 35 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin 36 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Energy from waste and other energy sources Renewable energy Nyclear power Fossil energy Energy from waste and other energy sources Renewable energy Nyclear power Fossil energy Energy from waste and other energy sources Renewable energy Nyclear power Fossil energy Energy from waste and other energy sources Renewable energy Nyclear power 18,000 Fossil energy Energy from waste and other energy sources Renewable energy Nyclear power Fossil energy Energy from waste and other energy sources Renewable energy Nyclear power Fossil energy MJ LHV Cumulative energy demand (CED) 20,000 Transport of product to customer (100 km) Borregaard's own infrastructure 16,000 Cradle-to-gate at Borregaard, excl. Borregaard's infrastructure 14,000 12,000 10,000 8,000 6,000 4,000 2,000 0 Energy type Fossil energy Nuclear power Renewable energy Waste and other Energy category Coal Oil Fossil gas Peat Sulphur Nuclear power Biomass/biogas Hydropower Wind Solar Geothermal heat Wave Tide Energy waste/recovered Undefined MJ LHV per tonne cellulose 3151 7640 2188 345 0 6531 3042 4164 0 179 0 0 0 5752 0 Most important are of use Production of electricity to Borregaard. Combustion of oil at Borregaard. Production of electricity to Borregaard. Production of electricity to Borregaard. Production of electricity to Borregaard. Combustion of (bio combustion) and alvamix (alva combustion) at Borregaard. Production of electricity to Borregaard. Production to electricity used for production of sodium hydroxide and salt that Borregaard purchases. Combustion of waste oil and municipal waste at Borregaard. - 37 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 3.7 WASTE Waste Solid and non-radioactive 90 80 70 kg waste 60 50 40 30 20 10 - 1 tonne 1 m3 1 m3 1 tonne 1 tonne 1 tonne Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Other waste 0.6 0.2 0.4 0.4 0.6 0.6 Hazardous waste 1.0 0.4 0.6 0.6 1.2 0.9 Waste to landfill 37.8 12.8 17.5 19.4 40.3 63.0 Waste to incineration (without energy recovery) 0.0 0.0 0.0 0.0 0.0 0.0 Waste to energy recovery 2.1 0.8 0.9 1.4 1.4 1.7 16.2 12.6 12.6 16.1 16.1 16.5 Waste to material recycling 38 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 39 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin 40 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Other waste Hazardous waste Waste to landfill Waste to incineration (without energy recovery) Waste to energy recovery Waste to material recycling Other waste Hazardous waste Waste to landfill Waste to incineration (without energy recovery) Waste to energy recovery Waste to material recycling Other waste Hazardous waste Waste to landfill Waste to incineration (without energy recovery) Waste to energy recovery Waste to material recycling Other waste Hazardous waste Waste to landfill Waste to incineration (without energy recovery) 60 Waste to energy recovery Waste to material recycling Other waste Hazardous waste Waste to landfill Waste to incineration (without energy recovery) Waste to energy recovery Waste to material recycling Other waste Hazardous waste Waste to landfill Waste to incineration (without energy recovery) Waste to energy recovery Waste to material recycling kg waste Waste (solid and non-radioactive) 70 Transport of product to customer (100 km) Borregaard's own infrastructure Cradle-to-gate at Borregaard, excl. Borregaard's infrastructure 50 40 30 20 10 0 3.8 Other environmental impact categories 41 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 4 SUMMARY AND CONCLUSIONS Table 6 Environmental burdens from cradle to gate1) for Borregaard’s products Environmental impact category Global warming potential (GWP) Acidification potential Cellulose 3) Unit 1 tonne 3) Ethanol (96 %) 3 1m 3) Ethanol (99 %) 3 1m 3) 3) Lignin (liquid) 1 tonne Lignin (powder) 1 tonne 3) Vanillin 1 tonne kg CO2-eqv. 1,211 335 691 704 1,227 1,343 kg SO2-eqv. 11.3 3.8 6.5 7.1 10.4 11.7 10 LCA = Life Cycle Assessment. See also: http://en.wikipedia.org/wiki/Life_cycle_assessment 11 International organisation for Standardisation; http://www.iso.org/iso/iso_catalogue.htm ISO 14044: Environmental management -- Life cycle assessment -- Requirements and guidelines ISO 14048: Environmental management -- Life cycle assessment -- Data documentation format 12 EPD = Environmental Product Declaration. Standardised (ISO 14025) method for presentation of LCA-results. See also: http://www-epd-norge.no/ (in Norwegian) and http://www.environdec.com/pageld.asp (in English). 13 PCR = Product Category Rules. Common and harmonised calculation rules to ensure that similar procedures are used when creating EPDs. Groups of products usually differ in their inherent environmental performance requiring specific rules to the product group, so-called Product Category Rules (PCR) to be prepared. 42 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Eutrophication potential Photochemical ozone creation potential (POCP) Ozone depletion potential Cumulative energy demand (CED) 2) Waste -3 kg PO4 -eqv. 3.26 0.95 1.35 1.64 2.75 2.47 kg C2H4-eqv. 0.70 0.24 0.41 0.42 0.69 0.76 kg CFC-11-eqv. MJ LHV kg waste 8.9E -5 2.6E -5 5.2E -5 4.3E -5 1.1E -4 9.7E -5 33,000 8,700 18,100 18,200 31,500 36,500 57.8 26.8 31.9 37.8 59.6 82.8 1) Transport to customer is not included in this table. 2) Solid and non-radioactive. 3) On dry basis. For ethanol, this means that the burdens are not allocated the water content of the product. 43 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Waste Global warming potential 4.50 4.00 3.50 3.00 2.50 2.00 1.50 1.00 0.50 0.00 Acidification potential Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Cumulative energy demand Eutrophication potential Lignin (powder) Vanillin Ozone depletion potential Photochemical ozone creation potential 44 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg The life cycle phases' relative burden Production and transport of energy carriers Production and transport of timber, wood chips and chemicals Borregaard's own infrastructure Combustion of waste at Borregaard Combustion of oil at Borregaard Other internal processes at Borregaard + various Global warming potential Transport of product to customer (100 km) Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Acidification potential Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Eutrophication potential Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Ozone depletion potential Photochemical ozone creation potential Vanillin Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin Cellulose Ethanol (96%) Ethanol (99%) Lignin (liquid) Lignin (powder) Vanillin 0% 10 % 20 % 30 % 40 % 50 % 60 % 70 % 80 % 90 % Figure 20 45 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 100 % 46 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 5 REFERENCES Barnholt, T. (2008): Telephone correspondence (June 2008) and e-mail (25/6-08) with Tuva Barnholt, tuva.barnholt@borregaard.com. Brekke, A., Modahl, I.S. og Raadal, H.L.: Klima- og energiregnskap for etanol fra Borregaard. (Norwegian report, Greenhouse gas and energy account for ethanol from Borregaard), OR 17.08, Ostfold Research (Østfoldforskning AS), September 2008. Brekke, A., Modahl, I.S. and Raadal, H.L.: Konkurrentanalyser for cellulose, etanol, lignin og vanillin fra Borregaard. (Norwegian report: Competitor analysis for cellulose, ethanol, lignin and vanillin from Borregaard.) Confidential. Ostfold Research (Østfoldforskning AS) OR 11.09, March 2009 Ecoinvent 1.3/2.0 database; http://www.pre.nl/ecoinvent/default.htm?gclid=CO322re7qpICFQSU1AodYRRKQQ http://www.ecoinvent.ch/ Environdec (2008): PCR for ‘Chemical products, 2000:5’. See also: http://www.environdec.com/pageId.asp (main page) and http://www.environdec.com/pageID.asp?id=131&menu=3,7,0&pcrId=14 (’Chemical products’). ETH-ESU 96 database (2007): Data for 1 kg of mineral wool from the ETH-ESU 96 database found in Simapro software; Processes/Material/construction/Mineral wool ETH U. Frischknecht, R., Althaus, H.-J., Bauer, C., Doka, G., Heck, T., Jungbluth, N., Kellenberg, D. and Nemecek, T. (2007): The Environmental Relevance of Capital Goods in Life Cycle Assessments of Products and Services. The International Journal of Life Cycle Assessment, 12 LCA Special (1) 7-17 (2007). See abstract at: http://www.scientificjournals.com/sj/lca_special/abstract/ArtikelId/8934 IPCC: http://www.ipcc.ch/ ISO, International organisation for Standardisation; http://www.iso.org/iso/iso_catalogue.htm Kristiansen, T. (2008): E-mail correspondence (20-23/6-08) with Tore Kristiansen, tore.kristiansen@borregaard.com Modahl, I.S. and Raadal, H.L. (2008): Klimaregnskap for produkt frå Borregaard. Fase 1: Cellulose, etanol, lignin og vanillin. (Norwegian report: Greenhouse gas account for products from Borregaard. Phase 1: Cellulose, ethanol, lignin and vanillin.) Ostfold Research (Østfoldforskning AS) OR 06.08 (confidential). Modahl, I.S., Raadal, H.L. and Nyland, C.A. (2008): Life Cycle Assessment of Electricity, including Carbon Capture and Storage - A study of a Gas Power Plant with Post-Combustion CO2 Capture at Tjeldbergodden. Report from Ostfold Research (Østfoldforskning) AR 03.08. 47 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Nordisk Miljømerking (2008): Svanemerking av drivstoff. Forslag til versjon 1.0. (Swan label (Nordic eco label) on fuels. Draft to version 1.0) http://www.ecolabel.no/data/f/0/08/55/3_2401_0/Forslag.pdf PRé, The Netherlands; http://www.pre.nl/simapro/ Rojahn, T. (2008): Telephone and e-mail correspondence with Trond Rojahn 6/6-08 and following e-mail correspondence 1/9-12/9 2008, trond.rojahn@borregaard.com SFT 96:16 (1996): Utslipp ved håndtering av kommunalt avfall. Authors: Jonas Sandgran, Aage Heie and Terje Sverud (Det Norske Veritas). (Norwegian report: Emission from handling of municipal solid waste.) Publisher: SFT (Norwegian Pollution Control Authority). TA-no 1366/1996. ISBN 82-7655-008-8. SimaPro, software tool for life cycle assessment; http://www.pre.nl/simapro/ SSB (2006): Naturressurser og miljø 2006. (Norwegian report: Nature resources and the environment) ISBN 82-537-7115-0 (printed), http://www.ssb.no/emner/01/sa_nrm/nrm2008/ Universiteit Leiden (2007): CML-IA - CML's impact assessment methods and characterisation factors. http://www.leidenuniv.nl/interfac/cml/ssp/databases/cmlia/index.html Universiteit Leiden (2005): Emission factors and national emissions found in ’LCA guide’, part 2B, page 14-15, home page http://www.leidenuniv.nl/interfac/cml/ssp/projects/lca2/lca2.html, This is summarised in a file at Ostfold Research under i:TeamAlle/LCAgruppa/SimaPro/STØ-metoder/Karakterisering POCP samlekategorier.doc (last updated 26/4-2005). Veolia (2008): ‘Grønt ansvar’-report ’Rapport på vareadressenivå for fraksjon’ (pdf-file) (Norwegian report: Green responsibility, detailed data for each waste fraction) with explanations sent by Margrethe Mangen, phone: + 47 9915 7670, 23/10-08. Wergeland, P (2008): Meeting with Per Wergeland (Borregaard) at Ostfold Research (Østfoldforskning AS) 19/6-08, and following telephone correspondence. Contact information: per.wergeland@borregaard.com, Phone. + 47 905 40 877. Wikipedia (2008a): http://en.wikipedia.org/wiki/Ethanol Wikipedia (2008b): http://en.wikipedia.org/wiki/Methane 48 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg APPENDIX 1: AGGREGATED RESULTS This appendix shows aggregated results for all the environmental impact categories that are included in the method of Ostfold Research (Østfoldforskning Method LCA/EPD 2008 September v.3.00) Unit global warming (GWP100) ozone layer depletion (ODP) photochemical oxidation acidification eutrophication Ledig 1 Ledig 2 Energy coal (no feedstock) Energy oil (no feedstock) kg CO2 eq Vanillin, inkl. infrastruktur og fellesavfall – Borregaard Impact category Lignin (pulver), inkl. infrastruktur og fellesavfall Borregaard Comparing processes Østfoldforskning Method LCA/EPD 2008 September - B V3.00 / West Europe, 1995 Characterization Never Non Lignin (flytande), inkl. infrastruktur og fellesavfall Borregaard Title: Method: Indicator: Skip categories: Relative mode: Etanol (99%), inkl. infrastruktur og fellesavfallpå Borregaard 11:00:47 Etanol (96%), inkl. infrastruktur og fellesavfall – Borregaard Project Impact Date: 11.03.2009 Time: assessment Borregaard klimaregnskap Cellulose, inkl. infrastruktur og fellesavfall - Borregaard SimaPro 7.1 1210,9 335,5 690,9 703,6 1226,6 1342,8 kg CFC-11 eq 8,86E-05 2,55E-05 5,16E-05 4,30E-05 1,07E-04 9,68E-05 kg C2H4 kg SO2 eq kg PO4--- eq MJ LHV 0,704 11,261 3,258 0 0 3142,66 0,236 3,794 0,945 0 0 759,76 0,412 6,489 1,349 0 0 1426,69 0,419 7,087 1,639 0 0 1834,25 0,690 10,355 2,747 0 0 3096,91 0,758 11,698 2,470 0 0 4113,92 MJ LHV 7517,71 2292,14 4709,28 3664,30 8931,51 7884,60 49 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Energy fossile gas (no feedst) Energy peat (no feedstock) Energy sulfur (no feedstock) Energy nuclear (no feedstock) Energy biomass (no feedstock) Energy hydropower (pond) Energy hp (river = tom) Energy wind Energy solar Energy geothermal Energy vawe (tom) Energy tide (tom) Ledig 3 Ledig 4 Energy waste/recovered (no fs) Energy undefined Spent nuclear fuel (no fs) ...of which uranium (no fs) Waste to material recycling Waste to energy recovery Waste to incineration (no ER) Waste to landfill Waste, electronics Waste, hazardous Ledig 5 Waste, slags/ashes Waste, bulk Waste, water Waste, radioact, LLW, conditio Waste, radioact, HLW, conditio Ledig 6 CO2 emissions (fossile) Ledig 11 Ledig 12 Ledig 13 CH4 emissions N2O emissions NOx emissions SOx emissions VOC emissions CO emissions Dioxin emissions to air PAH emissions to air MJ LHV 2176,62 622,13 1080,48 2376,16 2503,39 2886,41 MJ LHV 345,10 83,45 162,42 220,67 317,87 376,28 MJ LHV 0,01 0,00 0,00 0,00 0,02 0,02 MJ LHV 6521,63 1572,61 3020,99 3997,03 6142,84 7776,90 MJ LHV 3041,50 785,37 1950,14 1085,41 1936,56 2908,32 MJ LHV 4162,62 1012,89 1958,55 2643,27 3864,59 4616,26 MJ LHV MJ LHV MJ LHV MJ LHV MJ LHV MJ LHV MJ LHV MJ LHV MJ LHV 0,00 178,80 0,19 0 0 0 0 0 5752,38 0,00 42,95 0,04 0 0 0 0 0 1479,45 0,00 83,22 0,07 0 0 0 0 0 3627,12 0,00 110,89 0,07 0 0 0 0 0 2154,15 0,00 167,11 0,20 0 0 0 0 0 4387,89 0,00 206,90 0,37 0 0 0 0 0 5548,60 MJ LHV kg kg 0,17 0,01165 0,01165 0,04 0,00281 0,00281 0,08 0,00540 0,00540 0,11 0,00714 0,00714 0,15 0,01097 0,01097 0,18 0,01389 0,01389 kg 16,18 12,61 12,63 16,08 16,12 16,55 kg 2,10 0,78 0,87 1,44 1,41 1,65 kg 0,00 0,00 0,00 0,00 0,00 0,00 kg kg kg kg kg kg m3 36,91 0,00 0,30 0 0,73 0,64 11,09 2,34E-05 12,33 16,99 18,66 39,51 61,95 0,00 0,00 0,00 0,00 0,00 0,18 0,21 0,26 0,30 0,31 0 0 0 0 0 0,18 0,37 0,29 0,90 0,63 0,22 0,35 0,42 0,58 0,62 2,68 5,22 7,09 10,21 12,09 5,64E-06 1,08E-05 1,43E-05 2,20E-05 2,79E-05 m3 5,98E-06 1,44E-06 2,77E-06 3,66E-06 5,63E-06 7,13E-06 kg kg kg kg kg kg kg kg kg kg kg kg 0 1156,82 0 0 0 1,64 0,05 3,45 7,92 0,40 0,86 5,95E-09 0,000118 0 0 0 0 0 321,21 663,06 671,82 1172,35 1276,42 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0,43 0,81 1,04 1,72 2,03 0,01 0,03 0,02 0,04 0,06 1,10 2,09 2,13 3,17 3,62 2,70 4,53 5,00 7,26 8,20 0,14 0,25 0,21 0,44 0,42 0,29 0,50 0,46 0,88 1,10 1,54E-09 3,76E-09 2,21E-09 3,93E-09 5,78E-09 0,000033 0,000067 0,000054 0,000099 0,000135 50 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Cr, Cd, Hg and Pb to air Ledig 15 Ledig 16 Ledig 17 COD N-tot P-tot Ledig 18 Ledig 19 Dioxin emissions to water PAH emissions to water VOC emissions to water Cr, Cd, Hg and Pb to water Ledig 20 Ledig 21 Water res.: turbine water Water res.: river flow (tom) Water res.: cooling water Water res.: process water Water res.: other types Water res.: unspecidfied Ledig 22 Ledig 23 Land use Ledig 24 Ledig 25 Ledig 26 All resources (wa/air/energy) Ledig 27 Ledig 28 Ledig 29 Ledig 30 All res.: coal feedstock All res.: oil feedstock All res.: fossile gas feedstock All res.: peat feedstock (tom) All res.: sulfur feedstock All res.: uranium fstock (tom) All res.: biomass feedstock Ledig 31 Ledig 32 Ledig 33 All res.: recycled paper All res.: recycled other fiber Ledig 34 All res.: recycled steel- kg kg kg 0,001853 0 0 0 100,581 0,654 0,095 0 0 2,91E-08 0,000739 0,001091 0,001060 0,001812 0,002407 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 32,900 42,030 55,497 86,238 76,318 0,082 0,157 0,151 0,386 0,330 0,012 0,023 0,021 0,080 0,046 0 0 0 0 0 0 0 0 0 0 7,50E-09 1,86E-08 1,04E-08 1,85E-08 2,78E-08 kg kg kg 5,82E-05 0,0035 2,0630 1,71E-05 3,62E-05 2,62E-05 6,95E-05 6,02E-05 0,0010 0,0022 0,0016 0,0042 0,0037 0,1867 0,4495 0,3855 1,3696 5,0706 kg kg 0 0 837694 0 0 0 253391 0 0 0 383358 0 0 0 393877 0 kg kg 17949 119278 3746 30144 7245 44609 8858 42405 22711 118669 26160 220798 kg kg kg 6188 1508 0 0 0 0 0 0 1290 1525 327 0 0 0 0 0 0 837 2911 604 0 0 0 0 0 0 910 3737 548 0 0 0 0 0 0 1088 6231 2128 0 0 0 0 0 0 1325 8159 2792 0 0 0 0 0 0 1126 kg kg kg 0 0 0 0 0,16767 0,01738 0,00039 0 0 0 0 0,04054 0,00420 0,00010 0 0 0 0 0,07891 0,00818 0,00019 0 0 0 0 0,10721 0,01111 0,00025 0 0 0 0 0,15443 0,01601 0,00036 0 0 0 0 0,18281 0,01895 0,00043 kg 0 0 0 0 0 0 kg kg 0 0 0 0 0 0 0 0 0 0 0 0 kg 969 707 746 917 1009 597 kg kg 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 kg 0 0 0 0 0 0 0 0 0 0 0 0 kg kg kg m2 0 0 0 0 966172 1558106 0 0 51 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg iron All res.: recycled aluminium All res.: recycled copper All res.: recycled zinc (tom) All res.: recycled other metal Ledig 35 All res.: recycled glass All res.: recycled plastics All res.: recycled others Ledig 37 All res.: chrom All res.: nickel All res.: iron All res.: aluminium All res.: copper All res.: zinc All res.: silicone All res.: manganese All res.: magnesium Ledig 43 Ledig 44 All res.: calcium/limestone All res.: minerals, sand, rock Ledig 44,5 Ledig 45 ledig 46 Ledig 47 Miljøkostnader Norge_utenGWP -----Nytt for BorregaardPCR: All res: coal feedstock All res: oil feedstock All res: fossile gas feedstock All res: peat feedstock (tom) All res: sulfur feedstock All res: uranium fstock (tom) All res: biomass feedstock kg 0 0 0 0 0 0 kg kg 0 0 0 0 0 0 0 0 0 0 0 0 kg 0 0 0 0 0 0 kg 0 0 0 8,73E-06 0 0,308 0,649 8,169 0,311 0,127 0,039 0 0,0143 3,7E-06 0 0 88,8 kg 275,2 73,7 108,4 113,3 kr 0 0 0 0 416067 0 0 0 0 37727 0 0 0 0 90333 0 0 0 0 78005 0 0 0 0 0 0 MJ MJ MJ 4,43 0,71 0,02 1,07 0,17 0,00 2,08 0,34 0,01 2,83 0,46 0,01 4,08 0,66 0,01 4,83 0,78 0,02 MJ 0 0 0 0 0 0 MJ MJ 0 0 0 0 0 0 0 0 0 0 0 0 MJ 14833 10819 11420 14028 15443 9141 kg kg kg kg kg kg kg kg kg kg kg kg - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2,11E-06 4,11E-06 5,58E-06 8,04E-06 9,52E-06 0 0 0 0 0 0,141 0,160 0,193 0,284 0,359 0,339 0,386 0,467 0,673 0,919 2,629 3,940 4,143 8,733 12,676 0,069 0,116 0,132 0,692 0,410 0,022 0,039 0,040 0,142 0,273 0,008 0,013 0,013 0,044 0,082 0 0 0 0 0 0,0045 0,0068 0,0072 0,0157 0,0222 8,3E-07 1,4E-06 1,7E-06 4,0E-06 6,7E-06 0 0 0 0 0 0 0 0 0 0 65,9 75,1 86,6 112,6 85,1 242,1 487,5 0 0 0 0 0 0 0 0 277015 1024265 52 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg APPENDIX 2: DATA FOR EMISSIONS AND WATER CONSUMPTION AT BORREGAARD Data supplied from Lena Ulvan, Borregaard. (in Norwegian) Utslipp fra Borregaard 2007 Årsverdiar basert på oversendte døgn- og timesverdiar frå Borregaard Utslipp til vann KOF Fabrikk tonn/år Opsund/Renseriet Kokeri Blekeri Etanol Lignin (tørr) Lignin (flytende) Spraytørka (tørr) Spraytørka (flytende) Vanillin Farma Kloralkali Biorenseanlegg, 30% til fellesbelastning Biorenseanlegg, 70% til bleikeriet Biokjel Barkkjel Fyrhus/oljekjeler Sum 73 6 059 12 107 3 468 2 390 19,3 41,8 761 1 040 826 BOF S-TS tonn/år tonn/år 16 2 001 1 570 259 147 1,2 2,6 47 85 23 - 73 219 840 543 4,4 197 460 256 27 039 4 153 2 336 Fiber Utslipp merket blått er fra forbrenning Biokjel - utslipp til luft HF HCl Cd+Tl Hg Andre metaller Dioksiner TOC CO AOX Cu Toluen AUORG Hg Na-salter som Na Tot P Tot N SO2 prosess Utslipp til luft SO2 Støv NOX totalt kg/år kg/år tonn/år tonn/år kg/år tonn/år kg/år kg/år tonn/år tonn/år tonn/år tonn/år 81 200 81 200 - 1 445 1 445 0,60 1 6 205 - 0 0 0 0 0 0 0 0 149 0 6 205 0 0 0 0 0 149 As, Cd, Cu og Cr mg/Nm3 mg/Nm3 mg/Nm3 mg/Nm3 mg/Nm3 ng/Nm3 mg/Nm3 mg/Nm3 0 0 0 0 0 0 0 0 0 0 0 0 0 14 673 14 673 110 730 767 4 344 1 752 13 651 438 4 015 3 041 14 447 25 117 6 80 104 1 453 183 1 351 6 826 4 271 30 036 9 965 70 084 20 659 147 132 0 9,6 54,3 22,8 0,9 0,0 0,0 0,0 0 0 0 44,4 103,6 0,0 0,0 0,0 236 0 9,6 54,3 22,8 0,9 0,9 42,9 42,9 0 0 0 44,4 103,6 5,3 11,7 297,0 636 0,0 0,0 0,0 0,0 14,0 0,0 38,5 0,0 0,0 0,0 0,0 0,0 0,0 7,0 2,6 18,4 81 0 0 0 0 0 0 25 25 0 0 0 0 0 138 43 161 391 Vannforbruk CO2 tonn/år tonn/år 0 4 003 4 003 20 393 20 393 1 44 885 94 544 188 223 211 596 3 484 463 13 090 230 3 165 146 3 548 852 117 791 4 647 591 8 958 793 6 644 918 23 570 54 998 380 665 54 748 960 000 45 343 361 Omrekningsfaktorar 365 døgn/år 24 timer/døgn 145 000 tonn cellulose/år 30 % av biorenseanlegg skal belastast felles 70 % av biorenseanlegg skal belastast bleikeriet 53 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Utslipp fra Borregaard 2007 Utslipp til vann Fabrikk Opsund/Renseriet KOF BOF S-TS AOX Cu t/d t/d t/d kg/TAD kg/d Toluen AUORG tonn/år t/d Na-salter Tot P som Na kg/år tonn/d kg/d Hg SO2 prosess kg/d kg/h Tot N Utslipp til luft Vannforbruk SO2 Støv NOX CO2 totalt kg/h kg/h kg/h tonn/år tonn/år 0,2 0,04 0,2 0,3 2 Kokeri 16,6 5,5 0,6 2,1 12 1,1 1,1 3484463 Blekeri 33,2 4,3 2,3 4,8 37 6,2 6,2 13090230 Etanol 9,5 0,7 1,2 11 2,6 2,6 Lignin (tørr) 6,5 0,4 1,5 8,3 40 0,1 0,1 Lignin (flytende) 0,1 0,0 0,0 0,1 0 0,1 Spraytørka (tørr) 0,1 0,01 0,0 0 4,9 Spraytørka (flytende) 2,1 0,1 0,3 4 4,9 Vanillin 2,8 0,2 0,5 4 Farma 2,3 0,1 0,0 19 0,6 17 149 Kloralkali 4,0 Biorenseanlegg Biokjel 211596 0,7 274 16,9 Fyrhus/oljekjeler Utslipp merket blått er fra forbrenning Biokjel - utslipp til luft HF HCl Cd+Tl Hg Andre metaller Dioksiner TOC CO mg/Nm3 mg/Nm3 mg/Nm3 mg/Nm3 mg/Nm3 ng/Nm3 mg/Nm3 mg/Nm3 6,4 Fiber 0,6 kg/Tonn produsert masse = cellulose 17 149 4,0 20393 117791 3 20393 0,6 40 57 403 0 8958793 40 11 0 3 1 39,0 3548852 4003 0,6 1,8 74 4,4 4003 4647591 Barkkjel Sum 3165146 1,6 27 16,9 6644918 78568 0,6 0,8 16 1,3 0,3 5 44885 380665 33,9 2,1 18 94544 960000 73 9,2 45 188223 45343361 54748 As, Cd, Cu og Cr 0,026 0,01 0,0007 0,001 0,004 6E-05 2,8 21,5 54 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg APPENDIX 3: MASSES AND TREATMENT OF WASTE FROM BORREGAARD 55 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Ekstern behandling Opprinneleg rekkefølge 171 172 173 212 213 214 215 216 217 121 122 123 124 125 126 127 223 238 191 155 104 182 101 164 234 142 230 55 254 178 96 187 111 160 52 147 201 228 174 165 105 106 224 156 166 84 148 53 107 167 231 255 143 225 151 239 112 192 229 235 56 188 57 161 202 168 108 183 144 97 193 179 236 157 113 175 194 58 54 226 98 169 256 145 158 176 162 195 240 180 203 Vareadresse Varetekst, %kg, kg, kr, ant kg, fakturert kg Adresse A2060 - rene masser - blandet 1% 6 100 60 100 1 184 100 0 Bioforbrenning (bark) A2080 - gips 5% 54 200 0 54 200 Bioforbrenning (bark) A4020 - aske fra fyringsanlegg, ren 95% 1 123 1 123 800 800 0 Bioforbrenning (bark) 1 184 100 Bioforbrenning (bark) 27501 Cell 3 Blekeri A101 - avfall 71% 45 907 2 188 64 717 245188 907 Bleikeriet (Cellulosefabrikken) 27501 Cell 3 Blekeri A2030 - grus 12% 7 850 0 7 850 Bleikeriet (Cellulosefabrikken) 27501 Cell 3 Blekeri B3020 - treverk - blandet 9% 5 900 0 5 900 Bleikeriet (Cellulosefabrikken) 27501 Cell 3 Blekeri P00403- Grp. B folie farget > 10% energi 1% 450 450 0 Bleikeriet (Cellulosefabrikken) 27501 Cell 3 Blekeri R102 - blandet kontorpapir 2% 1 055 0 1 055 Bleikeriet (Cellulosefabrikken) 27501 Cell 3 Blekeri R302 - bølgepapp 5% 3 555 0 3 555 Bleikeriet (Cellulosefabrikken) 64 717 Bleikeriet (Cellulosefabrikken) 22900 Etanolfabrikken A101 - avfall 1% 26 721 3 938 1 958 983263 721 938 Etanolfabrikken 22900 Etanolfabrikken A2030 - grus 2% 31 250 0 31 250 Etanolfabrikken 22900 Etanolfabrikken A2080 - gips 96% 1 881 490 0 1 881 490 Etanolfabrikken 22900 Etanolfabrikken B3020 - treverk - blandet 1% 17 500 0 17 500 Etanolfabrikken 22900 Etanolfabrikken P00403- Grp. B folie farget > 10% energi 0% 485 485 0 Etanolfabrikken 22900 Etanolfabrikken R102 - blandet kontorpapir 0% 245 0 245 Etanolfabrikken 22900 Etanolfabrikken R302 - bølgepapp 0% 1 292 0 1 292 Etanolfabrikken 1 958 983 Etanolfabrikken 30100 Melløs Kontor A101 - avfall 0% 585 0 129 785 0 585 Felles 35000 Hovedgården A101 - avfall 10% 1 070 0 1 070 Felles 27200 Forskningsbygg Syd A101 - avfall 26% 7 338 0 28 764 113 9167 338 Felles 26101 C-port A101 - avfall 3% 435 0 13 965 0 435 Felles 16500 Sentralverksted A101 - avfall 37% 26 612 0 72 820 0 26 612 Felles 26900 Stjernebygg A101 - avfall 45% 5 699 0 12 770 0 5 699 Felles 15300 Helseavdelingen A101 - avfall 45% 735 0 1 650 0 735 Felles 26500 Storkontrollrom A101 - avfall 46% 19 227 0 41 575 0 19 227 Felles 30103 Melløs Lagerhus A101 - avfall 6% 6 823 2 563 110 113 2 563 6 823 Felles 25500 Tappestasjon A101 - avfall 60% 14 796 1 313 24 803 114313 796 Felles 30102 Melløs Spiselokale A101 - avfall 65% 5 360 0 8 273 0 5 360 Felles 15100 Bilavdelingen A101 - avfall 66% 67 482 83 000 102 906 67292 482152 Felles 80001 Utleiegarderobe/Attf A101 - avfall 66% 8 084 0 12 252 0 8 084 Felles 26800 HMS-avdelingen A101 - avfall 69% 3 326 0 4 791 0 3 326 Felles 15200 Kantina A101 - avfall 71% 12 958 0 18 266 0 12 958 Felles 27000 B-port A101 - avfall 73% 1 200 0 1 200 Felles 20000 Sentrallager A101 - avfall 8% 850 0 10 461 0 850 Felles 26400 Kontor 5 A101 - avfall 81% 7 542 3 688 9 308 3 688 7 542 Felles 14800 Vannverket A101 - avfall 82% 5 480 438 6 660 438 5 480 Felles 25501 Poval A101 - avfall 88% 24 104 12 625 27 54424 12104 625 Felles 27201 Forskningsbygg PilotA101 - avfall 91% 7 922 0 8 691 0 7 922 Felles 30101 Melløs Kjemikai A101 - avfall 92% 6 323 0 6 873 0 6 323 Felles 26600 Renseanlegget A101 - avfall 94% 7 218 1 125 7 716 1 125 7 218 Felles 26500 Storkontrollrom A2030 - grus 26% 10 750 0 10 750 Felles 16500 Sentralverksted A2035 - stein ren 5% 3 800 0 3 800 Felles 16500 Sentralverksted A2060 - rene masser - blandet 23% 16 400 16 400 0 Felles 30100 Melløs Kontor A2060 - rene masser - blandet 59% 76 450 76 450 0 Felles 26101 C-port A2080 - gips 94% 13 150 0 13 150 Felles 26500 Storkontrollrom B2010 - ren flis 4% 1 500 0 1 500 Felles 15100 Bilavdelingen B3020 - treverk - blandet 100% 6 700 0 66700 7000 Felles 25501 Poval B3020 - treverk - blandet 11% 3 050 0 3 050 Felles 14800 Vannverket B3020 - treverk - blandet 17% 1 150 0 1 150 Felles 16500 Sentralverksted B3020 - treverk - blandet 22% 15 800 015 800 Felles 26500 Storkontrollrom B3020 - treverk - blandet 22% 9 350 0 9 350 Felles 30102 Melløs Spiselokale B3020 - treverk - blandet 26% 2 150 0 2 150 Felles 80001 Utleiegarderobe/Attf B3020 - treverk - blandet 31% 3 750 0 3 750 Felles 25500 Tappestasjon B3020 - treverk - blandet 38% 9 450 0 9 450 Felles 30100 Melløs Kontor B3020 - treverk - blandet 40% 52 500 052 500 Felles 26100 Spraytørka B3020 - treverk - blandet 53% 38 700 038 700 Felles 35000 Hovedgården B3020 - treverk - blandet 76% 8 360 0 108930 3600 Felles 20000 Sentrallager B3020 - treverk - blandet 78% 8 200 0 8 200 Felles 27200 Forskningsbygg Syd B3020 - treverk - blandet 8% 2 350 0 2 350 Felles 30101 Melløs Kjemikai B3020 - treverk - blandet 8% 550 0 550 Felles 30103 Melløs Lagerhus B3020 - treverk - blandet 92% 101 350101 0 350 Felles 15100 Bilavdelingen D010F - personbildekk på felg 0% 30 200 30 Felles 27000 B-port Grp. B folie farget > 10% energi 2% 30 0 1 640 30 0 Felles 15100 Bilavdelingen P00403- Grp. B folie farget > 10% energi 0%10 10 0 Felles 26400 Kontor 5 P00403- Grp. B folie farget > 10% energi 0%10 10 0 Felles 27201 Forskningsbygg PilotP00403- Grp. B folie farget > 10% energi 0%10 10 0 Felles 26500 Storkontrollrom P00403- Grp. B folie farget > 10% energi 0% 103 103 0 Felles 16500 Sentralverksted P00403- Grp. B folie farget > 10% energi 0% 197 197 0 Felles 26900 Stjernebygg P00403- Grp. B folie farget > 10% energi 0%60 60 0 Felles 25500 Tappestasjon P00403- Grp. B folie farget > 10% energi 1% 127 127 0 Felles 15200 Kantina P00403- Grp. B folie farget > 10% energi 1% 132 132 0 Felles 27200 Forskningsbygg Syd P00403- Grp. B folie farget > 10% energi 1% 326 326 0 Felles 26800 HMS-avdelingen P00403- Grp. B folie farget > 10% energi 1%45 45 0 Felles 30103 Melløs Lagerhus P00403- Grp. B folie farget > 10% energi 1% 740 740 0 Felles 26101 C-port P00403- Grp. B folie farget > 10% energi 2% 230 230 0 Felles 20000 Sentrallager P00403- Grp. B folie farget > 10% energi 2% 233 233 0 Felles 26600 Renseanlegget P00403- Grp. B folie farget > 10% energi 3% 208 208 0 Felles 27200 Forskningsbygg Syd P09001- Flasker/kanner/brett (blandet) 1%150 150 0 Felles 15100 Bilavdelingen R102 - blandet kontorpapir 0% 175 0 175 Felles 14800 Vannverket R102 - blandet kontorpapir 0% 30 0 30 Felles 30100 Melløs Kontor R102 - blandet kontorpapir 0% 50 0 50 Felles 15200 Kantina R102 - blandet kontorpapir 0% 60 0 60 Felles 26500 Storkontrollrom R102 - blandet kontorpapir 0% 90 0 90 Felles Utleiegarderobe/Attf R102 - blandet kontorpapir 1% 100 0 12 252 1000 Felles 25500 Tappestasjon R102 - blandet kontorpapir 1% 140 0 140 Felles 26101 C-port R102 - blandet kontorpapir 1% 140 0 140 Felles 26600 Renseanlegget R102 - blandet kontorpapir 1% 50 0 50 Felles 26400 Kontor 5 R102 - blandet kontorpapir 12% 1 105 0 1 105 Felles 27200 Forskningsbygg Syd R102 - blandet kontorpapir 12% 3 495 0 3 495 Felles 35000 Hovedgården R102 - blandet kontorpapir 13% 1 450 0 1 450 Felles 26800 HMS-avdelingen R102 - blandet kontorpapir 15% 710 0 710 Felles 27201 Forskningsbygg PilotR102 - blandet kontorpapir 2% 210 0 210 Felles Intern avfallsbehandling Materialgjenvinning Energiutnytting Deponi Farleg avfall Anna (inkl. forbrenning utan energiutnytting) kg/år kg/år kg/år kg/år kg/år Barkforbrenning Barkforbrenning Barkforbrenning Materialgjenvinning internt Energiutnytting internt Deponi internt 6 100 - 45 907 - - - 6 100 - 54 200 1 123 800 1 178 000 7 850 5 900 450 1 055 3 555 5 060 45 907 26 721 - - - 7 850 5 900 - 31 250 1 881 490 17 500 485 245 1 292 2 022 26 721 585 1 070 7 338 435 26 612 5 699 735 19 227 6 823 14 796 5 360 67 482 8 084 3 326 12 958 1 200 850 7 542 5 480 24 104 7 922 6 323 7 218 - - - 31 250 17 500 1 881 490 10 750 3 800 16 400 76 450 13 150 1 500 6 700 3 050 1 150 15 800 9 350 2 150 3 750 9 450 52 500 38 700 8 360 8 200 2 350 550 101 350 30 30 10 10 10 103 197 60 127 132 326 45 740 230 233 208 150 175 30 50 60 90 100 140 140 50 1 105 3 495 1 450 710 210 56 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 189 184 109 102 232 114 185 159 59 227 241 237 190 146 149 170 110 6 99 181 233 177 115 257 103 204 163 196 186 60 61 85 86 197 62 63 64 65 198 87 66 67 68 69 70 88 71 89 72 73 74 75 90 91 76 77 78 92 79 93 80 94 199 81 82 200 95 100 83 48 49 50 51 1 7 12 26 22 13 14 8 2 27 23 15 9 3 28 16 4 10 24 17 29 5 18 11 27000 B-port R102 - blandet kontorpapir 24% 390 0 390 Felles 26900 Stjernebygg R102 - blandet kontorpapir 36% 4 595 0 4 595 Felles 16500 Sentralverksted R102 - blandet kontorpapir 4% 2 995 0 2 995 Felles 15300 Helseavdelingen R102 - blandet kontorpapir 52% 860 0 860 Felles 30102 Melløs Spiselokale R102 - blandet kontorpapir 7% 600 0 600 Felles 20000 Sentrallager R102 - blandet kontorpapir 8% 880 0 880 Felles 26900 Stjernebygg R102M - sams kontorpapir 9% 1 211 0 1 211 Felles 26101 C-port R302 - bølgepapp 0% 10 0 10 Felles 15100 Bilavdelingen R302 - bølgepapp 0% 150 0 150 Felles 30100 Melløs Kontor R302 - bølgepapp 0% 200 0 200 Felles 35000 Hovedgården R302 - bølgepapp 0% 50 0 50 Felles 30103 Melløs Lagerhus R302 - bølgepapp 1% 1 200 0 1 200 Felles 27000 B-port R302 - bølgepapp 1% 20 0 20 Felles 25500 Tappestasjon R302 - bølgepapp 1% 290 0 290 Felles 25501 Poval R302 - bølgepapp 1% 390 0 390 Felles 26500 Storkontrollrom R302 - bølgepapp 1% 555 0 555 Felles 16500 Sentralverksted R302 - bølgepapp 10% 7 016 0 7 016 Felles 10400 IT-avdelingen R302 - bølgepapp 100% 180 0 180 0 180 Felles 15200 Kantina R302 - bølgepapp 11% 1 936 0 1 936 Felles 26800 HMS-avdelingen R302 - bølgepapp 15% 710 0 710 Felles 30102 Melløs Spiselokale R302 - bølgepapp 2% 163 0 163 Felles 26600 Renseanlegget R302 - bølgepapp 3% 240 0 240 Felles 20000 Sentrallager R302 - bølgepapp 3% 298 0 298 Felles Utleiegarderobe/Attf R302 - bølgepapp 3% 318 0 318 Felles 15300 Helseavdelingen R302 - bølgepapp 3% 55 0 1 650 0 55 Felles 27201 Forskningsbygg PilotR302 - bølgepapp 6% 549 0 549 Felles 26400 Kontor 5 R302 - bølgepapp 7% 651 0 651 Felles 27200 Forskningsbygg Syd R302 - bølgepapp 8% 2 235 0 2 235 Felles 26900 Stjernebygg R302 - bølgepapp 9% 1 205 0 1 205 Felles 15100 Bilavdelingen S7011A- 7011 ref.olje, flytende - småkolli 1% 625625 2 500 Felles 15100 Bilavdelingen S7011B- 7011 ref.olje, flytende - fat 10% 1010 746 746 -804 Felles 15101 Miljøstasjon S7012A- 7012 ikke ref.olje, flytende - småkolli 159 2% 159 795 Felles 15101 Miljøstasjon S7012B- 7012 ikke ref.olje, flytende - fat113% 1781 178 3 534 8 775 127 Felles 958 27200 Forskningsbygg Syd S7012B- 7012 ikke ref.olje, flytende - fat1139% 24211 242 33 726 Felles 15100 Bilavdelingen S7012B- 7012 ikke ref.olje, flytende - fat77% 603 7 603 22 809 Felles 15100 Bilavdelingen S7012C- 7012 ikke ref.olje, flytende - IBC34% 9693 969 11 907 Felles 15100 Bilavdelingen S7021B- 7021 olje-/fettavf., fast - fat 0% 131 131917 Felles 15100 Bilavdelingen S7022A- 7022 oljeforur.masse, fast - småkolli 6621% 662 6 620 Felles 27200 Forskningsbygg Syd S7022B- 7022 oljeforur.masse, fast - fat 2%700 700 5 950 Felles 15101 Miljøstasjon S7022B- 7022 oljeforur.masse, fast - fat 22% 1 9091 909 15 853 Felles 15100 Bilavdelingen S7022B- 7022 oljeforur.masse, fast - fat 3% 3 047 3 047 25 900 Felles 15100 Bilavdelingen S7022C- 7022 oljeforur.masse, fast - IBC 0% 399 399 3 392 Felles 15100 Bilavdelingen S7023D- 7023 bl.drivstoff - småkolli 0% 27 243 27 Felles 15100 Bilavdelingen S7024B- 7024 oljefilter - fat 0% 236 826 102 236906 292 152 Felles 15100 Bilavdelingen S7041A- 7041 org.løsem m/halogen, flyt.-småkolli 456 0% 456 11 400Felles 15101 Miljøstasjon S7041A- 7041 org.løsem m/halogen, flyt.-småkolli 198 2% 198 4 950 Felles 15100 Bilavdelingen S7042A- 7042 org.løsem u/halogen, flyt.-småkolli 394 0% 394 3 940 Felles 15101 Miljøstasjon S7042A- 7042 org.løsem u/halogen, flyt.-småkolli 202 2% 202 2 020 Felles 15100 Bilavdelingen S7042B- 7042 org.løsem u/halogen, flytende 617- fat 1% 617 3 702 Felles 15100 Bilavdelingen S7042C- 7042 org.løsem u/halogen, flytende 722- IBC 1% 722 4 332 Felles 15100 Bilavdelingen S7042L- 7042 frostvæske - fat 0% 200 1 200 200 Felles 15100 Bilavdelingen S7051A- 7051 maling, småkolli 0% 211 1 583 211 Felles 15101 Miljøstasjon S7051A- 7051 maling, småkolli 1% 51 383 51 Felles 15101 Miljøstasjon S7055A- 7055 spraybokser - småkolli 0% 3 453 Felles 15100 Bilavdelingen S7055A- 7055 spraybokser - småkolli 0% 5454 810 Felles 15100 Bilavdelingen S7081J- 7081 KOF-avfall 0% 184 7 360 184 Felles 15100 Bilavdelingen S7091A- 7091 uorganiske salter, fast - småkolli 1 679 2% 1 679 33 580 Felles 15101 Miljøstasjon S7091A- 7091 uorganiske salter, fast - småkolli 3 621 41% 3 621 72 420Felles 15100 Bilavdelingen S7092B- 7092 blybatterier, >200kg 1% 796796 -279 Felles 15101 Miljøstasjon S7092B- 7092 blybatterier, >200kg 10% 891 891 -312 Felles 15100 Bilavdelingen S7093A- 7093 småbatterier - småkolli 0% 77772 695 Felles 15101 Miljøstasjon S7133A- 7133 rengj.midl., fast - småkolli 3% 258 258 3 870 Felles 27200 Forskningsbygg Syd S7152A- 7152 org.avf, fast - småkolli 1% 358 35828 640 Felles 15100 Bilavdelingen S7152C- 7152 org.avf, fast - IBC 2% 1 7441 26 744160 Felles 15100 Bilavdelingen S7152J- 7152 lab.kjemikalier, usorterte-småkolli 477 0% 477 38 160 Felles 27200 Forskningsbygg Syd S7152J- 7152 lab.kjemikalier, usorterte-småkolli 570 2% 570 45 600 Felles 15101 Miljøstasjon S7152J- 7152 lab.kjemikalier, usorterte-småkolli 305 3% 305 24 400 Felles 15200 Kantina V150K - matavfall 17% 3 180 0 3 180 Felles 15100 Bilavdelingen X1501 - Rull m 10 stk plastsekker - 240l (blank) 3 0% 3 0 Felles 726 911 Felles 13900 Fyrhus A101 - avfall 88% 12 745 875 14 480 875 12 745 Fyrhus 13900 Fyrhus B3020 - treverk - blandet 8% 1 200 0 1 200 Fyrhus 13900 Fyrhus R102 - blandet kontorpapir 1% 155 0 155 Fyrhus 13900 Fyrhus R302 - bølgepapp 3% 380 380 Fyrhus 14 480 Fyrhus 10200 Pharma Lager A101 - avfall 31% 2 034 0 6 538 0 2 064 Ikkje med 10500 Kraftstasjon A101 - avfall 37% 5 714 0 15 532 0 5 714 Ikkje med 12000 BFC 04-05 A101 - avfall 53% 31 034 813 59 008 5131 238 034 Ikkje med 12002 BFC 01-02 A101 - avfall 83% 2 835 0 3 398 0 2 835 Ikkje med 12001 BFC 07 A101 - avfall 84% 4 394 0 5 202 0 4 394 Ikkje med 12000 BFC 04-05 A4020 - aske fra fyringsanlegg, ren 12% 77 050 050 0 Ikkje med 12000 BFC 04-05 B3020 - treverk - blandet 23% 13 600 013 600 Ikkje med 10500 Kraftstasjon B3020 - treverk - blandet 49% 7 650 0 7 650 Ikkje med 10200 Pharma Lager B3020 - treverk - blandet 50% 3 250 0 3 250 Ikkje med 12002 BFC 01-02 P00403- Grp. B folie farget > 10% energi 0%15 15 0 Ikkje med 12001 BFC 07 P00403- Grp. B folie farget > 10% energi 1%30 30 0 Ikkje med 12000 BFC 04-05 P00403- Grp. B folie farget > 10% energi 1% 640 640 0 Ikkje med 10500 Kraftstasjon P00403- Grp. B folie farget > 10% energi 1%97 97 0 Ikkje med 10200 Pharma Lager P00403- Grp. B folie farget > 10% energi 13% 827827 0 Ikkje med 12002 BFC 01-02 R102 - blandet kontorpapir 1% 30 0 30 Ikkje med 12000 BFC 04-05 R102 - blandet kontorpapir 1% 360 0 360 Ikkje med 10200 Pharma Lager R102 - blandet kontorpapir 1% 70 0 70 Ikkje med 10500 Kraftstasjon R102 - blandet kontorpapir 5% 710 0 710 Ikkje med 12001 BFC 07 R102 - blandet kontorpapir 6% 290 0 290 Ikkje med 12000 BFC 04-05 R102M - sams kontorpapir 1% 695 0 695 Ikkje med 12002 BFC 01-02 R302 - bølgepapp 15% 518 0 518 Ikkje med 10200 Pharma Lager R302 - bølgepapp 5% 357 0 357 Ikkje med 12000 BFC 04-05 R302 - bølgepapp 7% 3 940 0 59 008 51 238 3 940 Ikkje med 10500 Kraftstasjon R302 - bølgepapp 9% 1 361 0 1 361 Ikkje med 390 4 595 2 995 860 600 880 1 211 10 150 200 50 1 200 20 290 390 555 7 016 180 1 936 710 163 240 298 318 55 549 651 2 235 1 205 625 10 746 159 1 178 11 242 7 603 3 969 131 662 700 1 909 3 047 399 27 236 456 198 394 202 617 722 200 211 51 3 54 184 1 679 3 621 796 891 77 258 358 1 744 477 570 305 3 180 3 40 221 244 499 12 745 - 56 731 - 107 400 264 910 13 150 1 200 155 380 535 12 745 2 064 5 714 31 034 2 835 4 394 - - - - 1 200 - 7 050 13 600 7 650 3 250 15 30 640 97 827 30 360 70 710 290 695 518 357 3 940 1 361 57 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg 25 19 20 21 12001 BFC 07 12000 BFC 04-05 12000 BFC 04-05 12000 BFC 04-05 116 117 118 119 120 20800 Klorfabrikken 20800 Klorfabrikken 20800 Klorfabrikken 20800 Klorfabrikken 20800 Klorfabrikken 40 30 31 41 32 42 43 33 44 34 35 45 36 37 38 46 47 39 12501 Syrehus 12500 Kokeriet 12500 Kokeriet 12501 Syrehus 12500 Kokeriet 12501 Syrehus 12501 Syrehus 12500 Kokeriet 12501 Syrehus 12500 Kokeriet 12500 Kokeriet 12501 Syrehus 12500 Kokeriet 12500 Kokeriet 12500 Kokeriet 12501 Syrehus 12501 Syrehus 12500 Kokeriet 150 152 153 154 128 129 130 131 132 26100 Spraytørka 26100 Spraytørka 26100 Spraytørka 26100 Spraytørka 23300 Ligningfabrikken 23300 Ligningfabrikken 23300 Ligningfabrikken 23300 Ligningfabrikken 23300 Ligningfabrikken 250 242 246 247 251 243 248 252 244 249 253 245 205 218 206 207 219 208 220 221 209 210 222 211 138 133 141 134 139 135 136 140 137 R302 - bølgepapp 9% 488 0 488 Ikkje med S7135E- 7135 basisk org.avf., flytende-småkolli 1 303 2% 1 303 19 545 Ikkje med S7152A- 7152 org.avf, fast - småkolli 1% 314 31425 120 Ikkje med S7152J- 7152 lab.kjemikalier, usorterte-småkolli 72 0% 72 5 760 Ikkje med 89 708 Ikkje med A101 - avfall 67% 13 385 1 188 20 034 113188 385 Kloralkalifabrikken B3020 - treverk - blandet 23% 4 510 0 4 510 Kloralkalifabrikken P00403- Grp. B folie farget > 10% energi 2% 417 417 0 Kloralkalifabrikken R102 - blandet kontorpapir 2% 420 0 420 Kloralkalifabrikken R302 - bølgepapp 6% 1 302 0 20 034 1 188 1 302 Kloralkalifabrikken 20 034 Kloralkalifabrikken A101 - avfall 1% 10 752 688 1 514 223 688 10 752 Kokeriet A101 - avfall 40% 52 044 11 188 129 822 5211 044 188 Kokeriet A2030 - grus 14% 18 100 0 18 100 Kokeriet A2030 - grus 91% 1 377 500 0 1 377 500 Kokeriet A2035 - stein ren 6% 8 100 0 8 100 Kokeriet A2035 - stein ren 6% 89 450 0 89 450 Kokeriet A2060 - rene masser - blandet 0% 3 900 30 900 Kokeriet A2060 - rene masser - blandet 5% 7 050 70 050 Kokeriet A2080 - gips 2% 30 950 0 30 950 Kokeriet A2154 - støvavfall 8% 9 750 0 9 750 Kokeriet B2010 - ren flis 14% 17 650 0 129 822 11 17188 650 Kokeriet B3020 - treverk - blandet 0% 1 450 0 1 450 Kokeriet B3020 - treverk - blandet 12% 15 400 015 400 Kokeriet P00403- Grp. B folie farget > 10% energi 0% 217 217 0 Kokeriet R102 - blandet kontorpapir 0% 200 0 200 Kokeriet R102 - blandet kontorpapir 0% 80 0 80 Kokeriet R302 - bølgepapp 0% 141 0 141 Kokeriet R302 - bølgepapp 1% 1 311 0 1 311 Kokeriet 1 644 045 Kokeriet A101 - avfall 39% 28 103 1 250 72 739 128250 103 Ligninfabrikken (pulver og flytande) P00403- Grp. B folie farget > 10% energi 34% 221 3 221Ligninfabrikken 0 (pulver og flytande) R102 - blandet kontorpapir 0% 335 0 335 Ligninfabrikken (pulver og flytande) R302 - bølgepapp 3% 2 380 0 72 739 1 250 2 380 Ligninfabrikken (pulver og flytande) A101 - avfall 72% 20 196 5 125 27 867 520125 196 Ligninfabrikken (pulver og flytande) B3020 - treverk - blandet 12% 3 400 0 3 400 Ligninfabrikken (pulver og flytande) P00403- Grp. B folie farget > 10% energi 16% 781 1 781Ligninfabrikken 0 (pulver og flytande) R102 - blandet kontorpapir 5% 1 355 0 1 355 Ligninfabrikken (pulver og flytande) R302 - bølgepapp 4% 1 135 0 1 135 Ligninfabrikken (pulver og flytande) 61 906 Ligninfabrikken (pulver og flytande) Fordeler etter produsert 43 % 63 143 Prodmengde Ligninfabrikken (pulver) tonn/år mengde 57 % 83 599 Prodmengde Ligninfabrikken (flytande) tonn/år 40400 Opsund Målekontoret A101 - avfall 58% 2 120 0 3 629 0 2 120 Renseriet 40100 Opsund Verksted A101 - avfall 81% 1 876 0 2 303 0 1 876 Renseriet 40200 Opsundrenseriet A101 - avfall 89% 5 520 1 000 6 232 1 000 5 520 Renseriet 40200 Opsundrenseriet P00403- Grp. B folie farget > 10% energi 0%10 10 0 Renseriet 40400 Opsund Målekontoret P00403- Grp. B folie farget > 10% energi 0%10 10 0 Renseriet 40100 Opsund Verksted P00403- Grp. B folie farget > 10% energi 1%30 30 0 Renseriet 40200 Opsundrenseriet R102 - blandet kontorpapir 1% 60 0 60 Renseriet 40400 Opsund Målekontoret R102 - blandet kontorpapir 30% 1 090 0 1 090 Renseriet 40100 Opsund Verksted R102 - blandet kontorpapir 8% 180 0 180 Renseriet 40200 Opsundrenseriet R302 - bølgepapp 10% 642 0 642 Renseriet 40400 Opsund Målekontoret R302 - bølgepapp 11% 409 0 409 Renseriet 40100 Opsund Verksted R302 - bølgepapp 9% 217 0 217 Renseriet 12 164 Renseriet 27500 Cell Tørkemaskin A101 - avfall 19% 31 865 2 688 167 45731 2 688 865 Tørke (Cellulosefabrikken) 27502 Cell 3 Lager A101 - avfall 56% 9 069 7 688 16 142 7 688 9 069 Tørke (Cellulosefabrikken) 27500 Cell Tørkemaskin A2080 - gips 6% 9 800 0 9 800 Tørke (Cellulosefabrikken) 27500 Cell Tørkemaskin B3020 - treverk - blandet 10% 17 050 017 050 Tørke (Cellulosefabrikken) 27502 Cell 3 Lager B3020 - treverk - blandet 40% 6 450 0 6 450 Tørke (Cellulosefabrikken) 27500 Cell Tørkemaskin P00403- Grp. B folie farget > 10% energi 0% 702 702 0 Tørke (Cellulosefabrikken) 27502 Cell 3 Lager P00403- Grp. B folie farget > 10% energi 2% 323 323 0 Tørke (Cellulosefabrikken) 27502 Cell 3 Lager R102 - blandet kontorpapir 0% 70 0 70 Tørke (Cellulosefabrikken) 27500 Cell Tørkemaskin R102 - blandet kontorpapir 1% 1 440 0 1 440 Tørke (Cellulosefabrikken) 27500 Cell Tørkemaskin R107 - cellulose 52% 86 550 0 86 550 Tørke (Cellulosefabrikken) 27502 Cell 3 Lager R302 - bølgepapp 1% 230 0 16 142 7 688 230 Tørke (Cellulosefabrikken) 27500 Cell Tørkemaskin R302 - bølgepapp 12% 20 050 0 20 050 Tørke (Cellulosefabrikken) 183 599 Tørke (Cellulosefabrikken) 23801 Vanillin Bunn A101 - avfall 45% 7 033 0 15 478 0 7 033 Vanillinfabrikken 23800 Vanillin Topp A101 - avfall 60% 12 408 0 20 724 0 12 408 Vanillinfabrikken 23801 Vanillin Bunn B3020 - treverk - blandet 100% 4 550 0 44550 5500 Vanillinfabrikken 23800 Vanillin Topp P00403- Grp. B folie farget > 10% energi 318% 7773 777 0 Vanillinfabrikken 23801 Vanillin Bunn P00403- Grp. B folie farget > 10% energi 18% 171 1 171 0 Vanillinfabrikken 23800 Vanillin Topp R102 - blandet kontorpapir 6% 1 145 0 1 145 Vanillinfabrikken 23800 Vanillin Topp R302 - bølgepapp 16% 3 392 0 3 392 Vanillinfabrikken 23801 Vanillin Bunn R302 - bølgepapp 47% 7 274 0 7 274 Vanillinfabrikken 23800 Vanillin Topp Topp X1501 - Rull m 10 stk plastsekker - 240l2(blank) 0% 2 0Vanillinfabrikken 20 724 0 40 752 Vanillinfabrikken Sum totalt 6 001 399 Sum i Veoilia-rapport 6 001 369 Avvik 0,0005 % 488 10 428 46 041 13 385 1 303 314 72 1 689 - - - 24 500 7 050 4 510 417 420 1 302 2 139 13 385 10 752 52 044 - - - - 4 510 - 18 100 1 377 500 8 100 89 450 3 900 7 050 30 950 9 750 17 650 1 450 15 400 217 200 80 141 1 311 1 949 62 796 28 103 - - - 1 504 100 34 500 40 700 3 221 335 2 380 20 196 3 400 1 781 1 355 1 135 10 207 4 392 5 815 10 10 30 60 1 090 180 642 409 217 2 648 48 299 - - - - 3 400 - 20 783 27 516 2 120 1 876 5 520 - - - - 1 463 1 937 - 9 516 31 865 9 069 - - - - - - 9 800 17 050 6 450 702 323 70 1 440 86 550 230 20 050 22 815 127 484 7 033 12 408 - - - - 23 500 9 800 4 550 3 777 1 171 1 145 3 392 7 274 2 16 761 114 785 19 441 656 834 0 58 420 0 1 656 700 4 550 384 470 3 130 190 Sum ekstern behandling 830 039 14 % Ikkje tatt med pga Pharma, BFC, kraftstasjon 58 158 Med i analysen, til ekstern behandling 771 881 13 % 58 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg APPENDIX 4: HOW TO READ THE LCA NETWORK FIGURE The figure underneath is an illustration and has nothing to do with Borregaard. The figure shows the global warming potential for production of 1 kg of mineral wool (ETH-ESU 96 database, 2007). The figures use the Norwegian decimal system. The total global warming potential for producing 1 kg mineral wool is 1,59 kg CO2 -eqv. The raw material contribution is 0,6639 kg CO2 -eqv. (see below). The rest is due to emissions in the production process itself. The width of the arrows illustrate the environmental burden connected to each process/material. The raw materials for producing mineral wool are: coal cokes, electricity, phenol and cement. The global warming potential connected to the raw material input for mineral wool are: 0,082 + 0,197 + 0,0699 + 0,315 = 0,6639 kg CO2 -eqv. Amount of coal (from underground mine) The global warming potential connected to this amount of coal (CO2 -eqv. ) How to read the LCA network figure. The figure show the global warming potential for production of 1 kg mineral wool (ETH-ESU 96 database, 2007). 59 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg APPENDIX 5: LCA – WHAT, WHY AND HOW? Author: Cecilia Askham Nyland, Østfoldforskning What is a Life Cycle Assessment (LCA) ? "A process that evaluates the environmental burdens associated with a product system or activity." This is done by identifying and describing the energy and material uses and releases into the environment. An LCA includes the entire life cycle of the product, from raw material extraction, through materials processing, use and disposal at the end of the product's life (from "cradle to grave"). All transportation steps involved are also considered. LCA assesses the environmental impacts of the system in the areas of ecological systems, human health and resource depletion. It does not address economic or social effects. Why Life Cycle Assessments? Life cycle assessments give a more holistic approach to environmental aspects of products. They can help the producer understand much more about what environmental problems are associated with a product. The producer can also see where in the product life cycle the main environmental burdens arise. This is very useful information when deciding where to target resources for environmental improvements, so that the resources will be used most effectively. 60 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg There are many more uses for LCA, including analysing the results of future changes in production, or raw materials suppliers etc. A short summary of the main applications is given below: Knowledge development What are the most important environmental problems and where in the life cycle do these arise? What happens to our environmental profile if we make changes in our production process? Decision support Where are the most effective areas for us to target resources (personnel, technology, education) to improve our performance? What sort of product/marketing profile do we want? Which materials and suppliers should we use? Information exchange/ communication Information for employees (internal stakeholders), education as well as key environmental data (EPIs) and environmental product information (EPDs). Communication of the effects of a company's environmental improvement efforts to authorities, neighbours, finiancial institutions and external stakeholders (EPIs) The phases of an LCA According to the ISO 14040 standard, life cycle assessments shall include: 1. 2. 3. 4. Goal and scope Inventory analysis Impact assessment Interpretation of results Goal and Scope 61 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg The goal of an LCA study should state the intended application, the reasons for carrying out the study and the intended audience, i.e. to whom the results of the study are intended to be communicated. When defining the scope of an LCA study, the following items should be considered, clearly described and justified: - The functions of the product system, or, in the case of comparative studies, the systems The functional unit The product system to be studied The product system boundaries Allocation procedures The types of impacts and the methodology of impact assessment and subsequent interpretation to be used Data requirements Assumptions Limitations The initial data quality requirements The type of critical review, if any The type and format of the report required for the study Functional Unit The functional unit represents a product's performance according to a specific user's requirements. This unit should reflect the product's function and life span. Here is an example of a functional unit for cement and concrete: 1 km road, maintained and used over a 50 year lifetime It is important that 'used' is included, as it is nescessary to include other important aspects in the life cycle of the road. These are things like lighting, noise muffling, road markings etc. 62 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg In an LCA, all mass and energy flows are normalised according to the functional unit. Therefore all results are usually presented for the functional unit chosen. System Boundaries System boundaries must be defined, so that we can collect the right inventory data. When one sets system boundaries one defines to what level of detail the product system will be studied and which releases to the environment will be evaluated. It is important that decisions to omit life cycle stages, processes or data are clearly stated and justified. Available inventory data can also set limitations to data gathering (for example when only industry average data is available rather than site specific). Again these limitations must be clearly stated and taken into consideration when conclusions are drawn from the LCA study. In order to help define system boundaries a product tree (or a product network) is drawn. This product tree should include all life cycle stages and unit processes involved, including transportation. The functional unit is the basis for which the product tree is drawn. When defining the system boundaries one must be practical, otherwise the level of detail can be enormous. A common approach is to define cut-off criteria, for example that all components that contribute less than 1% of the total mass flow for the product system are not included. Other important system boundaries that should be clearly stated are geographical boundaries (e.g. is the study of a local, national, or international nature) and time (e.g. what is the reference year for which the data is collected). The intended application of the study, the assumptions made, cut-off criteria, data and cost constraints and the intended audience all affect the system boundaries. This makes it important that these aspects are documented clearly. 63 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Allocation procedures Allocation is the partitioning of the input or output flows of a unit process to the product system under study. Allocation is needed when a unit process in a product’s life cycle has more than one product or raw material, which is part of another life cycle. This means that it is not correct to allocate all environmental burdens from the unit process to just one of the products. There are several possible methods that can be used for allocation. The two methods that are most commonly used are mass allocation and economic allocation, but others such as volume and energy-based allocations can be used where appropriate. Mass allocation Mass allocation is based on the mass flows through the unit process and is illustrated in the diagram above. The percentage (X) of a given flow (M), contributing to a given product (P), through a given unit (U) has been calculated. This same percentage (X) is then used as the percentage of the environmental burdens (B) arising from the unit which are allocated to the product (P). Thus, if a product uses 37% of the mass flow, it's also assigned 37% of the environmental burdens. Economic allocation Economic allocation is based on the sales price of the products produced and is illustrated in the diagram above. Products P, Q and R are produced from the unit process (U). Their sales prices are p, q and r respectively. Product P is therefore allocated the fraction p/(p+q+r) of the environmental burdens (B) arising from the process unit. Thus, if the sales price of product Q is 40% of the total sales price, it's assigned 40% of the environmental burdens. 64 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Assumptions It is important for the interpretation and use of the results from an LCA that all assumptions are clearly documented. The assumptions and system boundaries used affect the applicability of the results. The assumptions used can be tested to see whether changing these assumptions within reasonable intervals can change the conclusions of the study. This is known as a sensitivity analysis and enables the LCA practitioner to gain an understanding of the robustness of the conclusions from the particular study. Limitations There are also only a certain number of environmental burdens examined in an LCA study. This means that although LCA is described as a holistic approach it is also limited to the particular environmental burdens described in the scope definition for the study. LCA assesses the environmental impacts of the system in the areas of ecological systems, human health and resource depletion. It does not address economic, or social effects. Inventory Analysis Inventory analysis is the step where all material and energy flows in and out of the product life cycle are quantified. It involves data collection and calculation procedures to quantify the relevant inputs and outputs of a product system. Thus inventory analysis aims to quantify all energy and raw material requirements, emissions to air, discharges to water, solid waste and other releases for each process step of a product system. 65 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg All inputs and outputs to the product system are related to a functional unit, which is the basis for the calculations performed. For example we don't make an inventory of what emissions and resource use are associated with a tonne of concrete, but for the amount of concrete required for the maintenance and use of a 1 km stretch of road over a 50 year lifetime. When the inventory analysis is complete you have the life cycle inventory (LCI) data. Impact Assessment Different environmental problems occur as a result of the fact that we extract and process raw materials to produce different products. Different emissions contribute to different environmental problems (environmental impacts) in different ways. The impact assessment part of an LCA is where the potential impacts of a life cycle are assessed. The results of the inventory analysis (LCI) are used as the basis for this. The impact assessment is formally described as including the three phases shown in the figure to the left. 66 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Classification - "Which emissions contribute to which impact categories?" In the classification step, the different emissions and energy demands are assigned to different impact categories based on the expected kind of impacts on the environment. The main purpose of the activity is to describe which potential environmental effects the inputs and outputs may cause. Characterisation - "How much do they contribute?" In the characterisation step, the potential contributions from the different inputs and outputs are connected to the different impact categories, and the contributions to the same impact category are added up. Different emissions contribute differently to a given impact category, e.g. methane (CH4) contributes 21 times more to global warming potential than carbon dioxide (CO2). Weighting - " Which impacts are most important?" The weighting phase is an optional phase (ISO 14043, 1999) where the results for each impact category are weighted into an overall quantitative statement of the potential environmental impact for the product system. Interpretation 67 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg In this phase of an LCA one analyses results, reaches conclusions, explains limitations and makes recommendations. It is important that one considers carefully the goal and scope of the study during this phase. Interpretation of the results of an LCA must be done according to the Goal and Scope of the study in order to be of value in decision-making. A good example of this is if data gaps in the inventory phase are shown to be important for the outcome of the study, one recommendation would be to repeat the LCA calculations and fill in the most important data gaps. 68 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg APPENDIX 6: ENVIRONMENTAL IMPACT CATEGORIES AND POTENTIAL EFFECTS The table underneath gives examples of emissions and potential health and environmental effects for each impact category (not all of these are included in this study). Characterisation factors are found at the homepage of University of Leiden: http://www.leidenuniv.nl/interfac/cml/ssp/projects/lca2/lca2.html Here you can find the CML-IA database, which can be downloaded free of charge (Universiteit Leiden, 2007). Impact categories Emissions (examples) Potential effects Global warming potential CO2, N2O, CH4, CF4, C2F6 (GWP) Increased temperature in lower atmosphere, climate changes, raised sea level etc. Acidification potential SO2, HCl, NOx, NH3 Fish death, forest damage, corrosion damage, damage to buildings. Release of heavy metals with impacts on animals, vegetation and health. Eutrophication potential NH3, COD, NOx, PO43(phosphate) Local fouling impacts with increased growth of algae. Reduced biological activity. Photochemical ozone creation potential (POCP) Photochemical oxidants like VOC, Irritation of mucous membranes, CO, NOx and CH4 function. Damage to vegetation. Ozone depletion potential (ODP) CFC’s and HCFC’s (like tetrachloromethane and 1,1,1trichlororethane) Changes in plant growth and in molecular DNA. Skin cancer. Human toxicity and ecotoxicity Heavy metals, aromats (like benzen, toluen and phenol), halogenated aromats (i.e.dioxins) and PAH’s Toxic effects for human beings and eco-systems. Area consumption, energy consumption (cumulative energy demand, CED) and material consumption. No direct ecological effects, but can show the consumption of scarce resources and gives an indication of resource efficiency. Hazardous waste, radioactive waste etc. No direct ecological effects, but gives an indication of resource efficiency. Resource depletion potential Waste affecting lung 69 Ostfold Research OR 17.09 Life cycle assessment of cellulose, ethanol, lignin and vanillin from Borregaard, Sarpsborg Østfoldforskning AS (Ostfold Research) Gamle Beddingvei 2b 1671 Kråkerøy Norway Phone: + 47 69 35 11 00 Telefax: + 47 69 34 24 94 E-mail: firmapost@ostfoldforskning.no www.ostfoldforskning.no www.ostfoldresearch.com Reports may be obtained by contacting us or by downloading them from our website: www.ostfoldresearch.com