LORANN OILS, INC. 0535 - Almond Flavor , Artificial
Transcription
LORANN OILS, INC. 0535 - Almond Flavor , Artificial
LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 0535 - Almond Flavor , Artificial Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 05/14/2015 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 0535 - Almond Flavor , Artificial Product form : Mixture 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Food industry: component Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flam. Liq. 4 H227 Aquatic Acute 2 H401 Full text of H-phrases: see section 16 2.2. Label elements GHS-US labeling Signal word (GHS-US) : Warning Hazard statements (GHS-US) : Combustible liquid Toxic to aquatic life Precautionary statements (GHS-US) : Keep away from heat source and sparks . No smoking near container. Avoid release to the environment Wear eye protection and protective gloves. In case of fire: Use ABC-powder to extinguish Store in a well-ventilated place. Keep cool Dispose of contents/container to an approved waste disposal plant 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture 05/14/2015 0535 - Almond Flavor , Artificial 1/7 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Name % Classification (GHS-US) Proprietary Flavor Ingredient - P226 39.6 - 47.7 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Aquatic Acute 2, H401 *The specific chemical identities of the ingredients in this mixture, as well as, exact concentrations of any hazardous ingredients stated above, are considered trade secrets. This information is withheld in accordance with the provisions of 1910.1200 of the Code of Federal Regulations. Full text of H-phrases: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest. First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. : Not expected to present a significant hazard under anticipated conditions of normal use. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Combustible liquid. Explosion hazard : May form flammable/explosive vapor-air mixture. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures 6.1.1. For non-emergency personnel Emergency procedures 6.1.2. : Remove ignition sources. Use special care to avoid static electric charges. No open flames. No smoking. : Evacuate unnecessary personnel. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up 05/14/2015 : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 0535 – Almond Flavor , Artificial 2/7 LORANN OILS, INC. 6.4. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Additional hazards when processed : Handle empty containers with care because residual vapors are flammable. Keep away from heat source and sparks . No smoking near container. Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. No open flames. No smoking. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. Keep in fireproof place. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Heat sources. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 0535 - Almond Flavor , Artificial ACGIH Not applicable OSHA Not applicable Proprietary Flavor Ingredient - P226 ACGIH Not applicable OSHA Not applicable 8.2. Exposure controls Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear eye protection and protective gloves. protective gloves. Eye protection : Chemical goggles or safety glasses. Respiratory protection : Wear appropriate mask. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Refer to specification sheet Odor : characteristic Odor threshold : No data available pH : No data available Relative evaporation rate (butyl acetate=1) : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : 156 °F Auto-ignition temperature : No data available 05/14/2015 0535 – Almond Flavor , Artificial 3/7 LORANN OILS, INC. Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapor pressure : No data available Relative vapor density at 20 °C : No data available Relative density : No data available Specific gravity / density : 0.988 Solubility : Soluble in oil. Water: NO Log Pow : No data available Log Kow : No data available Viscosity, dynamic Office (800)862-8620 Fax (517)882-0507 No data available Explosive properties : No data available Oxidizing properties : No data available Explosive limits : No data available 9.2. 4518 Aurelius Road Lansing, MI 48910 Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Combustible liquid. May form flammable/explosive vapor-air mixture. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. Open flame. Overheating. Heat. Sparks. 10.5. Incompatible materials Strong acids. Strong bases. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. May release flammable gases. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Proprietary Flavor Ingredient - P226 LD50 oral rat 1300 mg/kg (Rat) LD50 dermal rat > 1250 mg/kg (Rat) LD50 dermal rabbit 5000 mg/kg (Rabbit) ATE US (oral) 1300.000 mg/kg body weight ATE US (dermal) 5000.000 mg/kg body weight Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified 05/14/2015 0535 – Almond Flavor , Artificial 4/7 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Toxic to aquatic life. Proprietary Flavor Ingredient - P226 LC50 fish 1 1.1 mg/l (96 h; Lepomis macrochirus) EC50 Daphnia 1 50 mg/l (24 h; Daphnia magna) EC50 other aquatic organisms 1 534 mg/l (5 h; Bacteria; Activated sludge) LC50 fish 2 11.2 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) Threshold limit other aquatic organisms 1 132 mg/l (Pseudomonas putida) Threshold limit algae 1 100 mg/l (336 h; Chlorella sp.; Inhibitory) Threshold limit algae 2 34 mg/l (Scenedesmus quadricauda) 12.2. Persistence and degradability 0535 - Almond Flavor , Artificial Persistence and degradability Not established. Proprietary Flavor Ingredient - P226 Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biochemical oxygen demand (BOD) 1.62 g O₂/g substance Chemical oxygen demand (COD) 1.98 g O₂/g substance ThOD 2.42 g O₂/g substance BOD (% of ThOD) 0.67 % ThOD 12.3. Bioaccumulative potential 0535 - Almond Flavor , Artificial Bioaccumulative potential Not established. Proprietary Flavor Ingredient - P226 BCF other aquatic organisms 1 4.2 - 7.8 (Estimated value) Log Pow 1.48 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil Proprietary Flavor Ingredient - P226 Surface tension 12.5. 0.040 N/m (20 °C) Other adverse effects Effect on ozone layer : Effect on the global warming : No known ecological damage caused by this product. Other information : Avoid release to the environment. 05/14/2015 0535 – Almond Flavor , Artificial 5/7 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to an approved waste disposal plant. Additional information : Handle empty containers with care because residual vapors are flammable. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations Proprietary Flavor Ingredient - 167 Listed on the United States TSCA (Toxic Substances Control Act) inventory Proprietary Flavor Ingredient - P226 Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified 15.2.2. National regulations \ \ 15.3. US State regulations Proprietary Flavor Ingredient - P226 U.S. - New Jersey - Right to Know Hazardous Substance List 05/14/2015 0535 – Almond Flavor , Artificial 6/7 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 16: Other information Other information Full text ------------------------------- of H-phrases: Acute Tox. 4 (Oral) Aquatic Acute 2 Flam. Liq. 4 H227 H302 H401 05/14/2015 : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Acute toxicity (oral) Category 4 Hazardous to the aquatic environment - Acute Hazard Category 2 Flammable liquids Category 4 Combustible liquid Harmful if swallowed Toxic to aquatic life 0535 – Almond Flavor , Artificial 7/7 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 1310 – Blue Color Powder Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 06/30/2015 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product form 1.2. : 1310 – Blue Color Powder : Mixture Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Food industry: component Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2: Hazards identification This mixture has not been tested as a whole. 2.1. Classification of the substance or mixture The product is not classified as dangerous according to OSHA Hazard Communication Standard (29 CFR 1910.1200) 2.2. Label elements The product is not classified as dangerous according to OSHA Hazard Communication Standard (29 CFR 1910.1200) 2.3. Symbols None Code: USH003 Description: May form combustible dust concentrations in the air. 2.4. Unknown acute toxicity (GHS-US) None SECTION 3: Composition/information on ingredients 3.1. Substance FD&C Blue 1# Aluminum Lake CAS# 0068921-42-6 Dextrose CAS# 921-60-8 3.2. Mixture Hazardous components within the meaning of 29 CFR 1910.1200 and related classification: None SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. : Move to fresh air. If symptoms persist, call a physician. : Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. : Do not induce vomiting, seek medical advice. : Not available Indication of any immediate medical attention and special treatment needed Not available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media 06/30/2015 : Water, CO2, foam, chemical powders, according to the materials involved in the fire. In case of fire, use foam, dry chemical, CO2 : None in particular 1310 - Blue Color Powder 1/6 LORANN OILS, INC. 5.2. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Special hazards arising from the substance or mixture Do not inhale explosion and combustible gases. Burning produces heavy smoke. Hazardous combustion products: Not available Explosive properties: Not available Oxidizing properties: Not available 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Collect contaminated fire extinguisher water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. : Use suitable breathing apparatus SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions This must not be discharged into drains 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Suitable material for taking up : dry and inert absorbing material (e.g. vermiculite, sand, earth). Wash with plenty of water. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Storage Incompatible materials 7.3. : Avoid contact with skin and eyes or inhalation. Conditions for safe storage, including any incompatibilities : Ambient temperature. Store in cool, dry place. : None in particular Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters No data available. Appropriate engineering controls: Not available. 8.2. Exposure controls Skin protection : No special precaution must be adopted for normal use. Hand protection Eye/face protection Respiratory protection : Not needed for normal use. : Not needed for normal use. Use according to good working practices. : Control worker exposure to below detectable levels. However, if an effective ventilation system is not in use, use a NIOSH-approved respirator for organic vapors and/or dusts. Where appropriate, use closed systems to transfer and process this material. If appropriate, isolate mixing rooms and other areas where this material is used or openly handles. : Maintain these areas under negative air pressure relative to the rest of the plant. Use local exhaust as required to capture all airborne vapors and dust. Other information SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Powder Color : Blue Odor : Not available Odor threshold : Not available pH : Not available Melting point : Not available Freezing point : Not available Boiling point : Not available 06/30/2015 1310 – Blue Color Powder 2/6 LORANN OILS, INC. Flash point : Not available Evaporation rate : Not available Upper, lower flammability or exposure limits : Not available Vapor density : Not available Vapor pressure : Not available Density : Not available Water solubility : Not available Lipid solubility Partition coefficient (n-octanol/water) : Not available : Not available Auto-ignition temperature : Not available Decomposition temperature : Not available Viscosity : Not available Explosive properties : Not available Oxidizing properties : Not available Flammability (Solid, Gas) : Not available 9.2. Other information Substance group relevant properties Miscibility Fat Solubility Conductivity : : : : 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Not available Not available Not available Not available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Data not available 10.3. Possibility of hazardous reactions Burning produces carbon monoxide and/or carbon dioxide 10.4. Conditions to avoid Stable under normal conditions of temperature and pressure 10.5. Incompatible materials Avoid strong oxidizing agents, peroxides, acids, alkali metals 10.6. Hazardous decomposition products Burning produces carbon monoxide/and or carbon dioxide SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the product Substance(s) listed on the IARC Monographs Substance(s) listed as OSHA carcinogen(s) Substance(s) listed as NIOSH carcinogen(s) Substance(s) listed on the NTP report on carcinogens : : : : : No data available None None None None SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. 12.2. Persistence and degradability Not available 12.3. Mobility in soil Not available 06/30/2015 1310 – Blue Color Powder 3/6 LORANN OILS, INC. 12.4. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Other adverse effects Not available SECTION 13: Disposal considerations 13.1. Waste treatment methods Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local and state environmental agency for specific rules). SECTION 14: Transport information UN number ADR-UN number : N/A DOT-UN number : N/A IATA-UN number : N/A IMDG-UN number : N/A UN proper shipping name ADR-shipping name : N/A DOT proper shipping name : N/A IATA-Technical name : N/A IMDG-Technical name : N/A Transport hazard class (es) ADR-Class : N/a DOT hazard class : N/A IATA-Class : N/A IMDG-Class : N/A Packaging group ADR-Packing group : N/A Exempted for ADR : N/A IATA-Packaging group : N/A IMDG-Packing group : N/A Environmental hazards Marine pollutant : No Environmental Pollutant : Not available Transport in bulk according to Annex II of Marpol73/78 and the IBC Code Not available Special precautions Department of Transportation (DOT) DOT_Special Provision(s) : N/A DOT Label(s) : N/A Dot Symbol : N/A Dot Cargo Aircraft : N/A Dot Passenger Aircraft : N/A DOT/TDG Bulk : N/A DOT Non-Bulk : N/A Road and Rail (ADR-RID) : ADR-Label : N/A ADR- Upper number : N/A ADR-Tunnel Restriction Code : N/A AIR (IATA) IATA-Passenger Aircraft : N/A IATA-Cargo Aircraft : N/A IATA-Label : N/A IATA_Sub Risk : N/A IATA-Special Provisioning : N/A Sea (IMDG) IMDG_Stowage Code : N/A IMDG-Stowage Note : N/A IMDG-Sub Risk : N/A IMDG-Special Provisioning : N/A IMDG-Page : N/A IMDG-Label : N/A IMDG-EMS : N/A IMDG-MFAG : N/A 06/30/2015 1310 – Blue Color Powder 4/6 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 15: Regulatory information 15.1. US Federal regulations USA-Federal regulations: TSCA-Toxic Substances Control Act TSCA-inventory: All the components are listed on the TSCA inventory TSCA listed substances: No substances listed SARA-Superfund Amendments and Reauthorization Act Section 302-Extremely Hazardous substances: No substances listed Section 304-Hazardous substances: No substances listed Section 313-Toxic chemical list: No substances listed CERLA-Comprehensive Environmental Response, Compensation, and Liability Act: Substance(s) listed under CERLA: No substances listed CAA-Clean Air Act CAA listed substances: No substances listed CWA-Clean Water Act CWA listed substances: No substances listed USA-State specific regulations: California Proposition 65 Substance(s) listed under California Proposition 65: No substances listed. Massachusetts Right to Know Substance(s) listed under Massachusetts Right to know: No substances listed Pennsylvania Right to Know Substance(s) listed under Pennsylvania Right to know: No substances listed New Jersey Right to Know Substance(s) listed under New Jersey Right to know: No substances listed SECTION 16: Other information Other information : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Legend to abbreviations and acronyms used in the safety data sheet: AGR: European Agreement concerning the International Carriage of Dangerous Goods by Road RID: Regulation Concerning the International Transport of Dangerous Goods by rail. IMDG: International; Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulation by the “International Air Transport Association” (ICAO) ICAOL International Civil Aviation Organization ICAO-TI: Technical Instructions by the “International Civil Aviation Organization” GHS: Globally Harmonized Systems of Classification and Labeling of Chemicals CLP: Classification, labelling, packaging EINECS: European Inventory of existing Commercial Chemical Substances CAS: Chemical Abstracts service (division of the American Chemical Society) GefStoffVO: Ordinance on Hazardous Substances, Germany LC50: Lethal concentration, for 50 percent of test population LD50: Lethal dose, for 50 percent of test population DNEL: Derived No Effect Level PNEC: Predicted No effect Concentration TLV: Threshold Limiting value 06/30/2015 1310 – Blue Color Powder 5/6 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 TWATLV: Threshold Limiting Value for the time weighted Average 8 hour day. (ACGIH Standard) STEL: Short Term Exposure Limit STOT: Specific Target Organ Toxicity WGK: German water Hazard Class KSt: Explosion coefficient 06/30/2015 1310 – Blue Color Powder 6/6 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 6040 – Citric Acid Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 07/27/2015 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 6040 – Citric Acid CAS number : 77-92-9 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Food industry: component Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2 : Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Eye irritation, Category 2 2.2. Label elements GHS label elements: The substance is classifed and labeled according to the Globally Harmonized System (GHS). Hazard pictograms : Signal word : Hazard statement Precautionary statement : H319 Causes serious eye irritation : P264 Wash skin thoroughly after handling P280 Wear protective gloves / eye protection / face protection P305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337/313 If eye irritation persists: Get medical advice/attention Warning SECTION 3: Composition/information on ingredients : Substances : 100% Citric acid anhydrous CAS number : 77-92-9 SECTION 4: First aid measures 4.1. Description of first aid measures General advice : Get medical advice/attention if you feel unwell. Show this safety data sheet to the doctor in attendance. First-aid measures after inhalation : If breathed in, move person into fresh air. First-aid measures after skin contact : Immediately flush skin with large amounts of water. First-aid measures after eye contact : Remove contact lenses. Rinse immediately with plenty of water, also under the eyelids. 07/27/2015 6040 - Citric Acid 1/5 LORANN OILS, INC. First-aid measures after ingestion 4.2. Office (800)862-8620 Fax (517)882-0507 : Drink plenty of water. If swallowed, DO NOT induce vomiting. Most Important Symptoms and Effects, both Acute and Delayed Symptoms 4.3. 4518 Aurelius Road Lansing, MI 48910 : No information available Indication of any Immediate Medical Attention and Special Treatment Needed Treatment : No information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. : Water spray, dry powder, foam, carbon dioxide (CO2) Special hazards arising from the chemical Do not use a solid water stream as it may scatter and spread fire. Hazardous decomposition proudcts formed under fire conditions. Exposure to decomposition products may be a hazard to health. 5.3. Advice for firefighters Wear self contained breathing apparatus for fire fighting if necessary. Use personal protective equipment. Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. In the event of fire and/or explosion do not breathe fumes. SECTION 6: Accidental release measures 6.1. Personal Precautions, Protective Equipment and Emergency Procedure Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation, especially in confined areas. 6.2. Environmental precautions Prevent further leakage or spillage if safe to do so. No special environmental precautions required. 6.3. Methods and materials for containment and cleaning up Use mechanical handling equipment. Keep in suitable, closed containers for disposal. Clean contaminated surface thoroughly. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid creating dust. Do not breathe dust. Avoid contact with skin and eyes. Dust explosion class : St1 Normal measures for preventive fire protection. 7.2. Conditions for safe storage, including any incompatibilities Storage : Keep in an area equipped with acid resistant flooring. Keep container tightly closed in a dry and well-ventilated place. Do not store at temperatures above 86°F. Incompatible with strong bases and oxidizing agents. No decomposition if stored and applied as directed. SECTION 8: Exposure controls/personal protection Occupational exposure limits : Contains no substances with occupational exposure limit values. Eye/Face protection : Safety goggles Skin protection : Choose body protection according to the amount and concentration of the dangerous substances at the work place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. Do not breathe dust. Avoid contact with skin, eyes and clothing. Respiratory protection : In the case of dust or aerosol formation use respirator with an approved filter. Half mask with a particle filter P2(EN 143). Hand protection : Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Appropriate Engineering Controls : Provide adequate ventilation Environmental exposure controls : Prevent further leakage or spillage if safe to do so. No special environmental precautions required. 07/27/2015 6040 - Citric Acid 2/5 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Crystalline Color : White Odor : Odorless pH : 1,8 at 5% 25°C Evaporation rate : N/A Melting point/range : Ca. 153°C Boiling point : N/A Flash point : N/A Auto-ignition temperature : N/A Vapor pressure : N/A Density : 1,665 g/cm³ at 20°C Flammability : Does not ignite Water solubility : Ca. 800 g/l at 20°C Viscosity : N/A Decompression temperature : N/A 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No decomposition if stored and applied as directed. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions None known. 10.4. Conditions to avoid Avoid dust formation 10.5. Incompatible materials Strong bases, oxidizing agents 10.6. Hazardous decomposition products Build-up of dangerous/toxic fumes possible in cases of fire/high temperature SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute dermal toxicity LD50 Dermal > 2000 mg/kg (Species: Rat) Acute toxicity (other routes of administration) LD50 725 mg/kg (Application route: i.p. Species: rat) LD50 940 mg/kg (Application Route: i.p. Species mouse) Skin corrosion/irritation : May cause skin irritation in susceptible persons. Serious eye damage/irritation : Irritating to eyes Respiratory or skin sensitization : Does not cause skin sensitization Germ cell mutagenicity : In vivo tests did not show mutagenic effects Carcinogenicity : Not classified Reproductive toxicity : No toxicity to reproduction Specific target organ toxicity (single exposure) : Not classified 07/27/2015 6040 - Citric Acid 3/5 LORANN OILS, INC. Specific target organ toxicity (repeated exposure) 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 : Not classified SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Very toxic to aquatic life with long lasting effects. Citric acid anhydrous LC50 fish 440 mg/l (48 h; Leuciscus idus [Golden orfe] static test) Method: OECD Test Guideline 203 EC50 Daphnia 1.535 mg/l (24 h; Daphnia magna [Water flea] static test) Toxicity to Algae 425 mg/l (168 h; Scenedesmus quadricauda [Green algea] static test) Toxicity to bacteria >10000 mg/l (16 h; Pseudomonas putida) 12.2. Persistence and degradability Citric acid anhydrous Biodegradability 97% (28d) Method: OECD Test Guideline 301B. Readily biodegradable. 100% (19d) Method: OECD Test Guideline 301E. Readily biodegradable. Citric acid anhydrous Biochemical Oxygen Demand (BOD) 526 mg/g Chemical Oxygen Demand (COD) 728 mg/g 12.3. Bioaccumulative potential Citric acid anhydrous Bioaccumulative potential The product is miscible in water and readily biodegradable in both water and soil. Accumulation is not expected. 12.4. Mobility in soil 12.5. Results of PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating nor toxic (PBT). SECTION 13: Disposal considerations 13.1. Waste treatment methods Where possible recycling is preferred to disposal or incineration. Can be landfilled or incinerated, when in compliance with local regulations. Waste codes should be assigned by the user based on the application for which the product was used. According to the European Waste Catalogue, Waste Codes are not product specific, but application specific. Empty containers should be taken to an approved waste handling site for recycling or disposal. Dispose of as unused product. SECTION 14: Transport information ADR: Not dangerous goods. DOT: Not a hazardous material. TDG: Not dangerous goods. IATA: Not dangerous goods. IMDG: Not dangerous goods. RID: Not dangerous goods. SECTION 15 : Regulatory information Major Accident Hazard Legislation : 96/82/EC Update: 2003 Directive 96/82/EC does not apply Notification status CERCLA: Not considered hazardous SARA Title III: Not considered hazardous WHMIS: Class E TSCA: On TSCA Inventory EINECS: On the inventory, or in compliance with the inventory AICS: On the inventory, or in compliance with the inventory 07/27/2015 6040 - Citric Acid 4/5 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 DSL: All components of this product are on the Canadian DSL list ENCS: On the inventory, or in compliance with the inventory KECI: On the inventory, or in compliance with the inventory PICCS: On the inventory, or in compliance with the inventory IECSC: On the inventory, or in compliance with the inventory NZIoC: On the inventory, or in compliance with the inventory SECTION 16: Other information Other information 07/27/2015 : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. 6040 - Citric Acid 5/5 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 1320 - Green Color Powder Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 06/30/2015 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name Product form 1.2. : 1320 - Green Color Powder : Mixture Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Food industry: component Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2: Hazards identification This mixture has not been tested as a whole. 2.1. Classification of the substance or mixture The product is not classified as dangerous according to OSHA Hazard Communication Standard (29 CFR 1910.1200) 2.2. Label elements The product is not classified as dangerous according to OSHA Hazard Communication Standard (29 CFR 1910.1200) 2.3. Symbols None Code: USH003 Description: May form combustible dust concentrations in the air. 2.4. Unknown acute toxicity (GHS-US) None SECTION 3: Composition/information on ingredients 3.1. Substance FD&C Blue 1# Aluminum Lake CAS# 0068921-42-6 FD&C Yellow #5 ALuminum Lake CAS# 12225-21-7 Dextrose CAS# 921-60-8 3.2. Mixture Hazardous components within the meaning of 29 CFR 1910.1200 and related classification: None SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries 4.3. : Move to fresh air. If symptoms persist, call a physician. : Wash off immediately with plenty of water. Get medical attention if irritation develops and persists. : Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. : Do not induce vomiting, seek medical advice. : Not available Indication of any immediate medical attention and special treatment needed Not available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 06/30/2015 : Water, CO2, foam, chemical powders, according to the materials involved in the fire. In case of fire, use foam, dry chemical, CO2 1320 – Green Color Powder 1/6 LORANN OILS, INC. Unsuitable extinguishing media 5.2. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 : None in particular Special hazards arising from the substance or mixture Do not inhale explosion and combustible gases. Burning produces heavy smoke. Hazardous combustion products: Not available Explosive properties: Not available Oxidizing properties: Not available 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Collect contaminated fire extinguisher water separately. This must not be discharged into drains. Move undamaged containers from immediate hazard area if it can be done safely. : Use suitable breathing apparatus SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Wear personal protection equipment. Remove persons to safety. See protective measures under point 7 and 8. 6.2. Environmental precautions This must not be discharged into drains 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Suitable material for taking up : dry and inert absorbing material (e.g. vermiculite, sand, earth). Wash with plenty of water. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Storage Incompatible materials 7.3. : Avoid contact with skin and eyes or inhalation. Conditions for safe storage, including any incompatibilities : Ambient temperature. Store in cool, dry place. : None in particular Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters No data available. Appropriate engineering controls: Not available. 8.2. Exposure controls Skin protection : No special precaution must be adopted for normal use. Hand protection Eye/face protection Respiratory protection : Not needed for normal use. : Not needed for normal use. Use according to good working practices. : Control worker exposure to below detectable levels. However, if an effective ventilation system is not in use, use a NIOSH-approved respirator for organic vapors and/or dusts. Where appropriate, use closed systems to transfer and process this material. If appropriate, isolate mixing rooms and other areas where this material is used or openly handles. : Maintain these areas under negative air pressure relative to the rest of the plant. Use local exhaust as required to capture all airborne vapors and dust. Other information SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Powder Color : Green Odor : Not available Odor threshold : Not available pH : Not available Melting point : Not available Freezing point : Not available 06/30/2015 1320 – Green Color Powder 2/6 LORANN OILS, INC. Boiling point : Not available Flash point : Not available Evaporation rate : Not available Upper, lower flammability or exposure limits : Not available Vapor density : Not available Vapor pressure : Not available Density : Not available Water solubility : Not available Lipid solubility Partition coefficient (n-octanol/water) : Not available : Not available Auto-ignition temperature : Not available Decomposition temperature : Not available Viscosity : Not available Explosive properties : Not available Oxidizing properties : Not available Flammability (Solid, Gas) : Not available 9.2. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Other information Substance group relevant properties Miscibility Fat Solubility Conductivity : : : : Not available Not available Not available Not available SECTION 10: Stability and reactivity 10.1. Reactivity Stable under normal conditions 10.2. Chemical stability Data not available 10.3. Possibility of hazardous reactions Burning produces carbon monoxide and/or carbon dioxide 10.4. Conditions to avoid Stable under normal conditions of temperature and pressure 10.5. Incompatible materials Avoid strong oxidizing agents, peroxides, acids, alkali metals 10.6. Hazardous decomposition products Burning produces carbon monoxide/and or carbon dioxide SECTION 11: Toxicological information 11.1. Information on toxicological effects Toxicological information of the product Substance(s) listed on the IARC Monographs Substance(s) listed as OSHA carcinogen(s) Substance(s) listed as NIOSH carcinogen(s) Substance(s) listed on the NTP report on carcinogens : : : : : No data available None None None None SECTION 12: Ecological information 12.1. Toxicity Adopt good working practices, so that the product is not released into the environment. 12.2. Persistence and degradability Not available 12.3. Mobility in soil Not available 06/30/2015 1320 – Green Color Powder 3/6 LORANN OILS, INC. 12.4. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Other adverse effects Not available SECTION 13: Disposal considerations 13.1. Waste treatment methods Any disposal practice must be in compliance with local, state, and federal laws and regulations (contact local and state environmental agency for specific rules). SECTION 14: Transport information UN number ADR-UN number : N/A DOT-UN number : N/A IATA-UN number : N/A IMDG-UN number : N/A UN proper shipping name ADR-shipping name : N/A DOT proper shipping name : N/A IATA-Technical name : N/A IMDG-Technical name : N/A Transport hazard class (es) ADR-Class : N/a DOT hazard class : N/A IATA-Class : N/A IMDG-Class : N/A Packaging group ADR-Packing group : N/A Exempted for ADR : N/A IATA-Packaging group : N/A IMDG-Packing group : N/A Environmental hazards Marine pollutant : No Environmental Pollutant : Not available Transport in bulk according to Annex II of Marpol73/78 and the IBC Code Not available Special precautions Department of Transportation (DOT) DOT_Special Provision(s) : N/A DOT Label(s) : N/A Dot Symbol : N/A Dot Cargo Aircraft : N/A Dot Passenger Aircraft : N/A DOT/TDG Bulk : N/A DOT Non-Bulk : N/A Road and Rail (ADR-RID) : ADR-Label : N/A ADR- Upper number : N/A ADR-Tunnel Restriction Code : N/A AIR (IATA) IATA-Passenger Aircraft : N/A IATA-Cargo Aircraft : N/A IATA-Label : N/A IATA_Sub Risk : N/A IATA-Special Provisioning : N/A Sea (IMDG) IMDG_Stowage Code : N/A IMDG-Stowage Note : N/A IMDG-Sub Risk : N/A IMDG-Special Provisioning : N/A IMDG-Page : N/A IMDG-Label : N/A IMDG-EMS : N/A IMDG-MFAG : N/A 06/30/2015 1320 – Green Color Powder 4/6 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 15: Regulatory information 15.1. US Federal regulations USA-Federal regulations: TSCA-Toxic Substances Control Act TSCA-inventory: All the components are listed on the TSCA inventory TSCA listed substances: No substances listed SARA-Superfund Amendments and Reauthorization Act Section 302-Extremely Hazardous substances: No substances listed Section 304-Hazardous substances: No substances listed Section 313-Toxic chemical list: No substances listed CERLA-Comprehensive Environmental Response, Compensation, and Liability Act: Substance(s) listed under CERLA: No substances listed CAA-Clean Air Act CAA listed substances: No substances listed CWA-Clean Water Act CWA listed substances: No substances listed USA-State specific regulations: California Proposition 65 Substance(s) listed under California Proposition 65: No substances listed. Massachusetts Right to Know Substance(s) listed under Massachusetts Right to know: No substances listed Pennsylvania Right to Know Substance(s) listed under Pennsylvania Right to know: No substances listed New Jersey Right to Know Substance(s) listed under New Jersey Right to know: No substances listed SECTION 16: Other information Other information : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. Legend to abbreviations and acronyms used in the safety data sheet: AGR: European Agreement concerning the International Carriage of Dangerous Goods by Road RID: Regulation Concerning the International Transport of Dangerous Goods by rail. IMDG: International; Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulation by the “International Air Transport Association” (ICAO) ICAOL International Civil Aviation Organization ICAO-TI: Technical Instructions by the “International Civil Aviation Organization” GHS: Globally Harmonized Systems of Classification and Labeling of Chemicals CLP: Classification, labelling, packaging EINECS: European Inventory of existing Commercial Chemical Substances CAS: Chemical Abstracts service (division of the American Chemical Society) GefStoffVO: Ordinance on Hazardous Substances, Germany LC50: Lethal concentration, for 50 percent of test population LD50: Lethal dose, for 50 percent of test population DNEL: Derived No Effect Level PNEC: Predicted No effect Concentration TLV: Threshold Limiting value 06/30/2015 1320 – Green Color Powder 5/6 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 TWATLV: Threshold Limiting Value for the time weighted Average 8 hour day. (ACGIH Standard) STEL: Short Term Exposure Limit STOT: Specific Target Organ Toxicity WGK: German water Hazard Class KSt: Explosion coefficient 06/30/2015 1320 – Green Color Powder 6/6 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 2270 – Lavender Oil, Natural Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 06/17/2015 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 2270 – Lavender Oil, Natural CAS Number : 8008-28-0 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Food industry: component Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Aspiration hazard 1 H304 May be fatal if swallowed and enters airways Eye damage/ irritation 2A H319 Causes serious eye irritation Environmental hazard acute aquatic 3 H402 Harmful to aquatic life Flammable liquid 4 H227 Combustible liquid Skin corrosion/irritation 2 H315 Causes skin irritation Skin Sensitization 1B H317 May cause an allergic skin reaction 2.2. Label elements GHS label elements: The substance is classifed and labeled according to the Globally Harmonized System (GHS). GHS08 Hazard pictograms : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H304 H319 H402 H227 H315 H317 Precautionary statements (GHS-US) : P102 Keep out of reach of children P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed P241 Use explosion-proof electrical equipment P261 Avoid breathing vapours P264 Wash hands thoroughly after handling 06/17/2015 GHS07 May be fatal if swallowed and enters airway Causes serious eye irritation Harmful to aquatic life Combustible liquid Causes skin irritation May cause an allergic skin reaction 2270 – Lavender Oil, Natural 1/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 3: Composition/information on ingredients : Chemical Characterization: Substances CAS No. Description: 8008-28-0 Lavandula stoechas Oil SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove from exposure and move to fresh air immediately. Get medical assistance if cough or other symptoms appear. First-aid measures after skin contact : Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. First-aid measures after eye contact : Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. First-aid measures after ingestion : Do not induce vomiting. Get medical aid if irritation of symptoms occurs. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. : CO2, dry powder or foam type extinguishers Special hazards arising from the substance or mixture No further relevant information available. 5.3. Advice for firefighters Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SECTION 6: Accidental release measures PROCEDURE : Remove any source of flame or sparks. If in a confined area NIOSH approved respiratory protection may be required. Remove individuals from the area if they do not have respiratory/dust protection. Spray material with water to prevent dusting and remove to an approved disposal container. Follow Federal, State and Local procedures for cleaning up of powder. Dispose of in accordance with current laws and regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. : Handle according to good safety procedures, avoiding unnecessary exposure by wearingappropriate proective gear for the situation. Conditions for safe storage, including any incompatibilities Storage : Store in full closed containers in a cool dry area away from heat, light and sources of ignition. SECTION 8: Exposure controls/personal protection Respiratory protection : Respiratory protection is normally not required in well ventilated areas. However, approved respiratory protection may be required when the material is rated toxic by inhalation or if the material is to be used in a confined area. Eye protection : May cause irritation Skin protection : May cause irritation SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state 06/17/2015 : Liquid 2270 – Lavender Oil, Natural 2/4 LORANN OILS, INC. Color : Colorless to pale yellow Odor : Characteristic fresh, sweet, herbaceous – floral odor pH : N/A Relative evaporation rate (butyl acetate=1) : N/A Melting point : N/A Boiling point : N/A Flash point : 156 °F Auto-ignition temperature : N/A Vapor pressure at 20 °C : N/A Refractive index : 1.458 Specific gravity : 0.886 Solubility : Insoluble Viscosity, dynamic : N/A Auto-ignition temperature : N/A 9.2. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability 10.3. Possibility of hazardous reactions 10.4. Conditions to avoid Strong oxidizing agents, strong reducing agents 10.5. Incompatible materials No further relevant information available. 10.6. Hazardous decomposition products Carbon monoxide, carbon dioxide SECTION 11: Toxicological information LD50 (ORAL) : N/A LD50 (DERMAL) : N/A LC50 : N/A MUTAGENICITY : N/A CARCINOGENICITY : N/A REPRODUCTIVE TOXICITY : N/A SECTION 12: Ecological information 12.1. Toxicity Aquatic toxicity : No data available Persistence and degradability : Not available 12.2. Behavior in environmental systems Bioaccumulative potential 06/17/2015 : Not available 2270 – Lavender Oil, Natural 3/4 LORANN OILS, INC. 12.3. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 Additional Ecological Information Results of PBT and vPvB assessment PBT: Not determined. vPvB: Not determined. Other adverse effects: Do not allow the material to enter streams, sewers or other waterways. SECTION 13: Disposal considerations 13.1. Waste treatment methods Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State and Local Regulations. SECTION 14: Transport information DOT: Not regulated UN/NA ID#: N/A TARIFF#: 3301.29.5118 HAZARD CLASS: N/A PACKAGING GROUP: N/A IMO: N/A IATA: N/A SECTION 15: Regulatory information GHS label elements: The substance is classified and labelled according to the Globally Harmonized System (GHS). Hazard pictograms: GHS08 GHS07 Signal word: Danger Risk Phrases: Irritating to skin Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment Harmful: may cause lung damage if swallowed Safety Phrases: Avoid contact with skin and eyes Wear suitable gloves and eye/face protection SECTION 16: Other information Other information 06/17/2015 : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. 2270 – Lavender Oil, Natural 4/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 0060 – Orange Oil, Natural Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 09/18/2015 Version: 2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 0060 - Orange Oil, Natural CAS Number : 8008-57-9 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Food industry: component Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Flammable liquid 3 H226 Flammable liquid and vapor. Aspiration hazard 1 H304 May be fatal if swallowed and enters airways. Skin irritation 2 H315 Causes skin irritation. Skin sensitization 1 H317 May cause an allergic skin reaction. Environmental hazard A2 H401 Toxic to aquatic life Environmental hazard C2 H411 Toxic to aquatic life with long-lasting effects 2.2. Label elements GHS label elements: The substance is classifed and labeled according to the Globally Harmonized System (GHS). Hazard pictograms : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H226 Flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H401 Toxic to aquatic life H411 Toxic to aquatic life with long-lasting effects Precautionary statements (GHS-US) 09/18/2015 : P261 Avoid breathing dust/fume/gas/mist/vapors/spray P273 Avoid release to the environment P280 Wear protective gloves / protective clothing/eye protection / face protection. P331 Do NOT induce vomiting. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. 0060 Orange Oil , Natural 1/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 3: Composition/information on ingredients : Chemical Characterization: Substances CAS No. Description: 8028-48-6 Citrus aurantium dulcis oil 100% Classificiation: AH1, EHA2, EHC2, FL3, SCI2, SS1 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove from exposure and move to fresh air immediately. Get medical assistance if cough or other symptoms appear. First-aid measures after skin contact : Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated cltohing and shoes. First-aid measures after eye contact : Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. First-aid measures after ingestion : Do not induce vomiting. Get medical aid if irritation of symptoms occurs. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. : CO2, dry powder, or foam type extinguishers Special hazards arising from the substance or mixture No further relevant information available. 5.3. Advice for firefighters Special fire fighting procedures : Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes. SECTION 6: Accidental release measures Procedure : Remove any source of flame or sparks. If in a confined area NIOSH approved respiratory protection may be required. Remove individuals from the area if they do not have respirtory/dust protection. Spray material with water to prevent dusting and remove to an approved disposal continer. Follow Federal, State and local procedures for cleaning up of powder. Dispose of in accordance with current laws and regualtions. SECTION 7: Handling and storage 7.1. Precautions for safe handling Handle according to good safety procedures, avoiding unnecessary exposure by wearing appropriate protective gear for the situation. 7.2. Conditions for safe storage, including any incompatibilities Store in full closed containers in a cool dry area away from heat, light and sources of ignition. SECTION 8: Exposure controls/personal protection Eyes : Moderate to severe irritation Skin : May cause irritation Respiratory : Respiratory protection is normally not required in well ventilated areas. However, approved respiratory protection may be required when the material is rated toxic by inhalation or if the material is to be used in a confined area. OSHA permissible exposure limit (PEL) : N/F OSHA threshold limit value (TLV) : N/F SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state 09/18/2015 : Liquid 0060 Orange Oil , Natural 2/4 LORANN OILS, INC. Color : Coloreless, yellow-orange to orange liquid Odor : Characteristic fresh, sweet orange odor Refractive index : 1.473 pH : Not available Specific gravity : .8427 Melting point : Undetermined Freezing point : No data available Boiling point : 348°F Flash point : 109 °F Auto-ignition temperature : Not determined Decomposition temperature : Not determined Flammability (solid, gas) : Not applicable Vapor pressure : Not determined Vapor pressure(mmHg@ 20 °c) : <2MM Relative density : Not determined Density @ 20°C (68°F): : Not determined Solubility : Insoluble Viscosity, dynamic : Not determined 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 10: Stability and reactivity 10.1. Reactivity 10.2. Chemical stability Y 10.3. Substances to be avoided Strong oxidizing agents, strong reducing agents 10.4. Hazardous decomposition products Carbon monoxide, carbon dioxide SECTION 11: Toxicological information 11.1. Information on toxicological effects LD50(oral) : N/A LD50(dermal) : N/A Mutagenicity : N/A Carcinogenicity : N/A Reproductive toxicity : N/A SECTION 12: Ecological information Acute aquatic toxicity : N/A Persistence and degradability : N/A Dioconcentration factore : N/A Mobility in soil : N/A Results of PbT and VPvB : N/A SECTION 13: Disposal considerations Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State, and local storage SECTION 14: Transport information Tariff # : 3301.12.90 UN/NA ID# : UN2319 DOT : Terpene hydroca 09/18/2015 0060 Orange Oil , Natural 3/4 LORANN OILS, INC. Hazard class : 3 Packing group : III 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture GHS label elements: The substance is classified and labelled according to the Globally Harmonized System (GHS). Hazard pictograms: Signal word: Danger Risk Phrases: R10 Flammable R38 Irritating to skin R43 May cause sensitisation by skin contact R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment R65 Harmful: may cause lung damage if swallowed Safety phrases: S24 Avoid contact with skin S37 Wear suitable gloves S61 Avoid release to the environment. Refer to special instructions/safety data sheets S62 If swallowed, do not induce vomiting; seek medical advice immediately and show this container or label. SECTION 16: Other information Other information 09/18/2015 : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. 0060 Orange Oil , Natural 4/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 2440 – Shea Butter Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 05/20/2016 Version: 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : 2440 – Shea Butter CAS number : 91080-23-8 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. : Raw material for cosmetic and pharmaceutical products Details of the supplier of the safety data sheet LorAnn Oils, Inc. 4518 Aurelius Road Lansing, MI 48910 Telephone: 1.800.862.8620 1.4. Emergency telephone number Emergency number : CHEMTREC: Within USA and Canada: 1.800.424.9300 Outside USA and Canada: +1 703 527 3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) n° 1272/2008 (CLP): Not classified Classification according to Directive 67/548/EEC or 1999/45/EC: Not classified Adverse physicochemical, human health and environmental effects: Not applicable 2.2. Label elements Labeling according to Regulation (EC) n° 1272/2008 (CLP) : No labeling applicable 2.3. Other hazards Inhalation : not dangerous Skin contact : not dangerous Ingestion : not dangerous Eye contact : not dangerous In case of leakage, non-skidding shoes are required to prevent falls and sliding. SECTION 3: Composition/information on ingredients : Chemical composition: glycerol trimester and fatty acids INCI Name and EINECS number: Butyrospermum Parkii (Shea Butter) l 293-515-7 SECTION 4: First aid measures 4.1. Description of first aid measures A medical examination is not necessary. First-aid measures after inhalation : Inhalation is not a pertinent exposure route for the product due to this physical aspect and/or its composition. First-aid measures after skin contact : Liberally bathe affected body parts with water and soap. First-aid measures after eye contact : Rinse out carefully with plenty of water with the eyelid held wide open. First-aid measures after ingestion : If the person is conscious, rinse mouth with water. Do not induce vomiting without medical advice. 4.2. Most important symptoms and effects, both acute and delayed No data / information available 4.3. Indication of any immediate medical attention and special treatment needed No data / information available 05/20/2016 2440 – Shea Butter 1/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide, foam, dry chemical powder Unsuitable extinguishing media : Water 5.2. Special protective equipment Use a protecting clothing and self-contained breathing equipment. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures No special precautions required. 6.2. Environmental precautions Avoid discharge into drinking water supplies, waste water or soil. 6.3. Methods and material for containment and cleaning up Small spills and residues may be absorbed with material such as cloth or sawdust, washed away with water and cleaned with sodic products. Larger spillage may be pumped. SECTION 7: Handling and storage 7.1. Precautions for safe handling No special precautions necessary. Use food contact hose pipes. 7.2. Conditions for safe storage, including any incompatibilities Keep in a cool place. Store in the original full closed drum or container to prevent over oxidation. 7.3. Special use(s) None SECTION 8: Exposure controls/personal protection No special protecting equipment required. 8.1. Exposure limits Not applicable 8.2. Exposure controls Not applicable SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Color : Max 2.0 red, Max 20.0 yellow Odor : Solid butter pH : Not applicable Boiling point : Undetermined Auto-ignition temperature : >300°C Vapor pressure : Undetermined Vapor density : Undetermined Density @20°C (g/mL) : Undetermined Solubility : Slightly soluble in ethanol (96%), miscible with light petroleum Viscosity : Undetermined 9.2. Other information No additional information available 05/20/2016 2440 – Shea Butter 2/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 10: Stability and reactivity 10.1. Reactivity Stability: stable under normal conditions 10.2. Chemical stability The product is stable 10.3. Possibility of hazardous reactions No data / information available 10.4. Conditions to avoid Heating at more than 60°C (cosmetic use), light and the oxygen of the ambient air : degradation adn oxidation of the substance. Heating at more than 50°C in the plastic bucket Heathing in the original carton or in the original plastic bage 10.5. Incompatible materials No data / information available 10.6. Hazardous decomposition products No data / information available SECTION 11: Toxicological information Non toxic product : pharmaceutical and cosmetic use Acute toxicity: No acute toxicity is to be feared regarding the product/ Chronic toxicity: No potential chronic health effect needs to be considered. Information on the likely routes of exposure: Ingestion : No known acute effect in normal conditions of use Dermal : No known effect Inhalation : No known acute effect in normal conditions of use Eye contact : No known effect Dermal Irritation : No known effect SECTION 12: Ecological information Toxicity : No study has been carried out for the moment. No ecological problems are to be expected when the product is handled and used with due care and attention. Degradability : Completely biodegradable but rich in DBO Bioaccumulation potential : No data / information available Mobility : No data / information available Results of PBT and vPvB assessment : No data / information available Various harmful effects : No data / information available SECTION 13: Disposal considerations Waste treatment methods : Absorb the oil with material such as cloth, paper or sawdust and throw it in an appropriate waste bin. Disposal in nature : Forbidden Elimination of the product residues : Throw in an appropriate waste bin. Dirty packaging : Observe local regulations. SECTION 14: Transport information Not dangerous product Classification: not classified in ADR (road, directive 94/55/CE), RID (rail, directive 96/49/CE), IMDG (sea), ICAO/IATA (air). Transportation in drums or food tanks. SECTION 15: Regulatory information Regulation (EC) No. 1272/2008 (CLP): product no classified as hazardous, no labelling applicable. Water endangering class: not water endangering. 05/20/2016 2440 – Shea Butter 3/4 LORANN OILS, INC. 4518 Aurelius Road Office (800)862-8620 Lansing, MI 48910 Fax (517)882-0507 SECTION 16: Other information Other information 05/20/2016 : DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable. 2440 – Shea Butter 4/4