Novel Heterostructure Metal-Semiconductor-Metal
Transcription
Novel Heterostructure Metal-Semiconductor-Metal
Novel Heterostructure Metal-Semiconductor-Metal (HMSM) Photodetectors with Resonant Cavity for Fiber Optic Communications A Thesis Submitted to the Faculty of Drexel University by Xiying Chen in partial fulfillment for the requirements for the degree of Doctor of Philosophy June 2002 ii Dedications I would like to dedicate this work to my father Lieyi Chen, my mother Lili Shen, and my sister Xueying Chen, for their continuous support, love and belief in me. iii Acknowledgements I would like to thank Dr. Bahram Nabet for his tireless motivation, continuous guidance, and neverending support of my work. I am also extremely grateful to Dr. Richard L. Coren, Dr. Steward D. Personick, and Dr. M. El-Sherif for their support to my education, and Dr. Peter Herczfeld and Dr. Afshin Daryoush for their encouragement to my research. I would also like to thank Dr. Afshin Daryoush and Dr. Warren Rosen for helping design the distributed Bragg reflector (DBR), Dr. Fabio Quaranta for fabricating the devices, Dr. Adriano Cola for assisting to analyze the experimental data and making photocurrent spectral response and current-voltage measurements, Dr. Marc Currie for lending me a hand in waveguide transmission line designs and for making the time response measurement, and Mr. Eric Gallo for editing the whole thesis. Many thanks to Dr. Amro Anwar, Dr. Hujie Chen, Dr. Xueshi Yang, and Dr. Francisco Castro for their valuable discussions, to Mr. Eric Gallo, Ms. Athena Bauerle, and Mr. Hungjen Huang for their helpful arguments, and Mr. Liming Zhou, Mr. Yuankai Zhou, Mr. Qiliang Zhang and Ms. Hongyuan Shi for their friendship and support of my graduate study. iv Table of Contents LIST OF TABLES........................................................................................................... viii LIST OF FIGURES ............................................................................................................ix ABSTRACT.......................................................................................................................xv 1. INTRODUCTION ...................................................................................................1 1.1 The Need for Fiber-Optic Communication Systems ...................................1 1.2 Fiber-Optic Communication Systems..........................................................2 1.3 Optical Photodetectors .................................................................................3 1.3.1 PIN photodiode ................................................................................5 1.3.2 Avalanche photodiods (APDs) ........................................................7 1.3.3 Metal-Semiconductor-Metal (MSM) photodiodes ..........................8 1.4 Photodetectors for Different Transmission Windows..................................9 1.4.1 Transmission characteristic of the optical fiber .............................10 1.4.2 Transmission in the 0.85 µm optical window................................12 1.4.2.1 Si photodiodes..............................................................13 1.4.2.2 GaAs photodiodes........................................................14 1.4.3 Transmission in the 1.3 µm optical window..................................18 1.4.4 Transmission in the 1.55 µm optical window................................18 1.4.4.1 Ge infrared (IR) photodiodes .......................................19 1.4.4.2 In0.53Ga0.47As infrared (IR) photodiodes......................20 1.5 Objective and Scope of the Thesis.............................................................23 1.6 Literature Review.......................................................................................26 2. RESONANT CAVITY ENHANCED DEVICES .................................................34 2.1 Introduction................................................................................................34 2.2 Theoretical Analysis of Planar Mirror Resonators ....................................36 2.3 Formulation of Quantum Efficiency for RCE Photodetectors...................39 2.3.1 Formulation of the quantum efficiency for RCE photodetectors ................................................................................40 2.3.2 Formulation of the reflectivity of the two mirrors .........................43 2.3.3 Numerical calculation of RCE quantum efficiency .......................44 2.3.4 Standing wave effect......................................................................47 2.4 Formulation of Reflection Coefficient of Mirrors .....................................50 2.4.1 Reflection coefficient calculated from transmission line analogue .........................................................................................50 2.4.2 Multiple reflection viewpoint ........................................................53 2.5 Formulation Modified at Oblique Incidence..............................................56 v 3. A CLOSED-FORM EXPRESSION TO ANALYZE ELECTRONIC PROPERTIES IN DELTA-DOPED HETEROSTRUCTURES............................60 3.1 Introduction................................................................................................61 3.2 Closed-form Expression for Delta Doped Modulation Heterostructures .........................................................................................63 3.3 Closed-form Model of Electric Field and Potential...................................68 3.4 Numerical Model Based on Schrödinger and Poisson Equations..............69 3.5 Calculation Scheme for Numerical Model Based on Schrödinger and Poisson Equations ...............................................................................71 3.6 Results and Discussion ..............................................................................73 3.7 Conclusions................................................................................................78 4. III-V MATERIAL BASED DOPED HMSM PHOTODETECTOR DESIGN WITH RESONANT CAVITY FOR OPTICAL COMMUNICATIONS ..........................................................................................79 4.1 Introduction................................................................................................80 4.2 Material Selection ......................................................................................83 4.2.1 III-V material parameters’ calculation...........................................84 4.2.1.1 Ternary (GaAl)As system ............................................85 4.2.1.2 Quaternary (GaIn)(AsP) and (Al,Ga,In)As systems.........................................................................88 4.2.2 Absorption layer.............................................................................89 4.2.2.1 Absorption materials for 800-900 nm optical window.........................................................................89 4.2.2.2 Absorption materials for 1550 nm optical window.........................................................................90 4.2.3 Barrier enhancement layer .............................................................91 4.2.3.1 Barrier enhancement layer for GaAs based photodetectors ..............................................................91 4.2.3.2 Barrier enhancement layer for InP based photodetectors ..............................................................93 4.2.4 Distributed Bragg reflector ............................................................94 4.2.4.1 DBR for GaAs based photodetectors...........................94 4.2.4.2 DBR for InP based photodetectors ..............................95 4.3 Selection of Structure Parameters..............................................................96 4.3.1 The grown RCE heterojunction MSM...........................................96 4.3.1.1 GaAs based photodetector structures...........................97 4.3.1.2 InP based photodetector structures ..............................98 4.3.2 Dispersion relation expression.......................................................99 4.3.2.1 Dispersion relation in ternary (GaAl)As system..........99 4.3.2.2 Dispersion relation of quaternary (GaIn)(AsP), (Al,Ga,In)As system ..................................................101 4.3.3 Reflectivity from the bottom mirror ............................................102 4.3.3.1 Reflectivity from the bottom mirror in GaAs based PD ....................................................................103 4.3.3.2 Reflectivity from the bottom mirror in InP based PD ..............................................................................104 vi 4.3.4 4.4 Quantum efficiency......................................................................106 4.3.4.1 Quantum efficiency in GaAs based PD .....................106 4.3.4.2 Quantum efficiency in InP based PD.........................107 4.3.5 Sheet charge density ....................................................................108 4.3.6 Electric field.................................................................................110 4.3.6.1 Electric field profile in GaAs based PD.....................110 4.3.6.2 Electric field profile in InP based PD ........................112 Conclusions..............................................................................................114 5. PERFORMANCE CHARACTERISTICS OF ALGAAS/GAAS DELTA DOPED HMSM PHOTODETECTOR WITH RESONANT CAVITY FOR SHORT HAUL COMMUNICATIONS .....................................................118 5.1 Wavelength Selectivity, High Sensitivity, and High Speed ....................119 5.1.1 Wavelength selectivity.................................................................120 5.1.2 Sensitivity, light response ............................................................122 5.1.3 High speed (time domain)............................................................124 5.1.4 High speed (frequency domain)...................................................126 5.1.5 Long trace of time response.........................................................128 5.1.6 Capacitance measurement............................................................129 5.2 Improvement of MSM Photodetector using Delta-doped AlGaAs/GaAs Heterostructure ................................................................131 5.2.1 Band bending profile....................................................................131 5.2.2 Current-voltage comparison.........................................................133 5.2.2.1 Experimental data ......................................................133 5.2.2.2 Thermionic emission theory ......................................134 5.2.2.3 Discussions ................................................................138 5.2.2.4 Potential distribution in 2DEG ..................................139 5.2.3 Comparison of current voltage at different temperature..............141 5.2.4 Comparison of capacitance- voltage measurements ....................144 5.2.5 Time response comparison ..........................................................145 5.2.6 Discussion of time response.........................................................147 5.2.6.1 Comparison of temporal response (short trace) .........148 5.2.6.2 Comparison of temporal response (long trace)..........153 5.3 Further Comparison of Undoped and Delta-doped Devices....................156 5.3.1 TEM (transmitted electron microscopy) structure.......................157 5.3.2 Comparison of the reflectivities between two devices ................159 5.3.3 Simulation results of the reflectivity spectrum ............................161 5.3.4 Comparison of the internal quantum efficiency...........................163 5.4 Conclusions..............................................................................................165 6. CONTRIBUTIONS AND FUTURE DIRECTIONS ..........................................167 6.1 General.....................................................................................................167 6.2 Contributions............................................................................................167 6.3 Future Work .............................................................................................170 6.3.1 ISE-TCAD simulation .................................................................170 6.3.2 Dynamic behavior........................................................................172 6.3.3 Electro-Optic measurement of microwave circuits......................174 vii 6.3.4 HEMT design...............................................................................176 LIST OF REFERENCES.................................................................................................184 APPENDIX A: TRANSMISSION LINE DESIGN ........................................................197 A1 Requirements of Geometry of Structure ..................................................197 A2 Formula for Calculation...........................................................................198 A3 Simulation Results ...................................................................................201 VITA ..............................................................................................................................205 viii List of Tables Table 1. 1 Typical characteristics of p-i-n and avalanche photodiodes [5, 6]. .............9 Table 1. 2 Comparison of characteristics of Si and GaAs photodiodes for 0.85 µm [5, 6, 20-26]. ........................................................................................17 Table 1. 3 Progress in trans-Atlantic-transmission (TAT) capacity. ..........................29 Table 4. 1 Lattice constant, gap energy, and electron affinity for a selected number of III-V binary compounds [125] [126]........................................84 Table 4. 2 AlxGa1-xAs material information................................................................87 Table 4. 3 Material parameters of quaternary (GaIn)(AsP) and (Al,Ga,In)As systems.......................................................................................................88 Table 4. 4 Optical and electrical characteristics of GaAs and Si................................89 Table 4. 5 Optical and electrical characteristics of In0.53Ga0.47As and Ge..................90 Table 4. 6 Performance of barrier enhancement layer structure above In0.53Ga0.47As active layer [85, 47, 134-136]. ............................................93 Table 4. 7 Electronic parameters for GaAs, AlAs, and AlxGa1-xAs..........................101 Table 4. 8 Parameters used in the calculation of ε1(ω). ............................................101 Table 5. 1 Measured and theoretical capacitance values. .........................................145 ix List of Figures Figure 1. 1 Conventional fiber optic communication link, showing a fiber optic connecting an optical transmitter and a receiver passing by a repeater, adapted from [2]............................................................................3 Figure 1. 2 Block diagram of an optical receiver, consisting of a photodetector and an amplifier. ..........................................................................................4 Figure 1. 3 Optical receiver equivalent circuit. ..............................................................4 Figure 1. 4 Layer and functional structure of a PIN photodiode....................................6 Figure 1. 5 p-i-n photodiode: (a) front-illuminated PD; (b) fear-illuminated PD; (c) edge-illuminated PD........................................................................6 Figure 1. 6 Functional structure of an APD photodiode. ...............................................7 Figure 1. 7 A top-view for the Metal-Semiconductor-Metal photodetector planar interdigitated structure. .....................................................................8 Figure 1. 8 Attenuation as a function of wavelength[7]...............................................10 Figure 1. 9 Typical dispersion vs. wavelength curve[8]. .............................................11 Figure 1. 10 Absorption coefficients of important semiconductor materials versus wavelength [9]. ...............................................................................12 Figure 1. 11 Schematic cross section of a Si pin photodiode.[10]. ................................13 Figure 1. 12 Cross-section of a Si APD with a so-called pπpπn structure (π standing for low p- doping level).[10]........................................................14 Figure 1. 13 Integration schemes for integrated photoreceivers: (a) pin-HBT; (b) pin-FET on a planar substrate; (c) pin-FET on a recessed substrate [10]..............................................................................................15 Figure 1. 14 Devices for monolithic photoreceiver integration. One should notice the similarity of MSM and FET structures. [10].............................16 Figure 1. 15 Ge photodiode on SiGe/Si [34]..................................................................20 Figure 1. 16 Example of an InGaAs photodiode with back-illumination.[10]...............21 x Figure 1. 17 Fundamental device structure of III-V MESFET and heterostructure HEMT. ..............................................................................23 Figure 2. 1 Two-mirror planar resonator (Fabry-Perot Mirror). ..................................36 Figure 2. 2 Schematic diagram of resonant-cavity-enhanced heterojunction photodetector..............................................................................................40 Figure 2. 3 Wavelength dependence of η for RCE detectors having various top mirror reflectivities for fixed L1=550Å, L2=1175 Å, R2=0.9, and αL2=0.1. .....................................................................................................45 Figure 2. 4 Frequency dependence of η for RCE detectors having various top mirror reflectivities for fixed L1=550Å, L2=1175 Å, R2=0.9, and αL2=0.1. .....................................................................................................46 Figure 2. 5 SWE as a function of wavelength for four different active layer thicknesses: L2a=1175 Å (solid), L2b=2306 Å (dash), L2c=3438 Å (dot), L2d=4569 Å (dash dot) for a cavity with R2=1, ψ2=-π, and the material refractive index will not change with the wavelength. (a) in wavelength spectrum; (b) in frequency spectrum..................................49 Figure 2. 6 Discontinuity between two different transmission lines is analogues to that between two dissimilar media........................................51 Figure 2. 7 Equivalent electric circuit for photodetector shown in Fig. 2.2.................52 Figure 2. 8 Multiple reflection analysis of the RCE photodetector. ............................55 Figure 2. 9 A wave is (a) perpendicularly polarized when its E field is perpendicular to the plane of incidence and (b) parallel polarized when its E field lies in the plane of incidence. ..........................................57 Figure 3. 1 Schematic diagram of conduction band of a modulation doped heterojunction. ...........................................................................................64 Figure 3. 2 Flow chart diagram of computer program. E is electric filed, E1 and E2 are two energy level, n1 and n2 are 2DEG concentration at E1 and E2, respectively, V is static potential. .............................................72 Figure 3. 3 Schematic diagram of delta-doped AlGaAs/GaAs heterostructure. ..........74 Figure 3. 4 Simulation of nso against AlGaAs delta doping concentration at 300K for various spacer layer thickness. ...................................................75 Figure 3. 5 Simulation of nso against AlGaAs delta doping concentration at 300K for various spacer layer thickness. Also shown are numerical results of analytical expressions for nso. ....................................................76 xi Figure 3. 6 Comparison of electric field strength profile by using Eq. (3.13) and modified Shrödinger and Poisson model 300K for various spacer layer thickness. ...............................................................................77 Figure 4. 1 Energy band diagrams showing existence of a conduction-bandedge discontinuity at interface between semiconductors with different values of electron affinity............................................................87 Figure 4. 2 Device structure of GaAs based resonant-cavity-enhanced HMSM photodetector..............................................................................................97 Figure 4. 3 In0.52Al0.48As/In0.53Ga0.47As/InP HMSM RCE-PD schematic diagram. .....................................................................................................98 Figure 4. 4 Reflectivity of bottom mirror vs wavelength for different numbers of quarter wave pairs. N is the number of quarter wave pairs. +: N=10; ×: N=15; •: N=20; ∗: N=30. (GaAs based PD) .............................103 Figure 4. 5 Reflectivity of bottom mirror vs wavelength for different numbers of quarter wave pairs. N is the number of quarter wave pairs. +: N=10; •: N=15; ×: N=20; ∗: N=30. (InP based PD).................................105 Figure 4. 6 Quantum efficiency of entire structure vs wavelength for different thickness of absorption layer (number of quarter wave pairs is fixed as N=20). m represents thickness of GaAs absorption layer. •: m=1; +: m=2; ×: m=3; ∗: m=4. (GaAs based PD) ................................106 Figure 4. 7 Quantum efficiency of entire structure vs wavelength for different thickness of absorption layer (number of quarter wave pairs is fixed as N=15). m represents thickness of InGaAs absorption layer. +: m=1; •: m=2; ×: m=3; ∗: m=4. (InP based PD) ...................................108 Figure 4. 8 Simulation of nso against AlGaAs delta doping concentration at 300K for various thickness of spacer layer. (GaAs based PD)................109 Figure 4. 9 Comparison of electric field strength profile by using closed-form expression and modified Schrödinger and Poisson model 300K for various spacer layer thickness (GaAs based PD).....................................110 Figure 4. 10 Drift velocity in GaAs material [144]......................................................111 Figure 4. 11 The electric field strength profile by using closed-form expression and modified Schrödinger and Poisson model 300K. (InP based PD) ...........................................................................................................113 Figure 4. 12 Drift velocity of electrons and holes in In0.53Ga0.47As [145] ...................114 Figure 4. 13 Top view and schematic cross-section of GaAs based PD. .....................116 xii Figure 4. 14 InP based PD diagram..............................................................................117 Figure 5. 1 Simulation results for quantum efficiency of layered structure as a function of wavelength for two different incident angles........................120 Figure 5. 2 Photocurrent spectral response of resonant-cavity-enhanced HMSM photodetector measured at 10V reverse bias. (Data courtesy of IME-CNR, Lecce, Italy)........................................................121 Figure 5. 3 Photoresponse of resonant-cavity-enhanced HMSM photodetector measured at 20V reverse bias at different incident light power. (Data courtesy of IME-CNR, Lecce, Italy)..............................................124 Figure 5. 4 Schematic of high-speed time response measurements setup..................125 Figure 5. 5 Temporal response of photodetector with 1 µm finger and 4 µm gap with a 0.1 mW incident power at 5V reverse bias. ...........................126 Figure 5. 6 Calculated frequency response from Fig. 5.5. .........................................127 Figure 5. 7 Long trace time response with 1 µm finger and 4 µm gap with a 0.1 mW incident power at 5V reverse bias. .............................................129 Figure 5. 8 C-V curves for four different interdigital structures of delta doped devices. (Data courtesy of IME-CNR, Lecce, Italy)................................130 Figure 5. 9 Schematic diagram of energy band of devices: (a) undoped device; (b) doped device.......................................................................................133 Figure 5. 10 Comparison of I-V of undoped and δ-doped devices. ο: undoped device; •: doped device (Data courtesy of IME-CNR, Lecce, Italy).......134 Figure 5. 11 Potential profile at zero bias of undoped and δ-doped devices. (a): undoped device; (b): doped device. .........................................................135 Figure 5. 12 Potential profile at V=V1+V2 bias of undoped and δ-doped devices. (a): undoped device; (b): doped device....................................................136 Figure 5. 13 Simplified model of 2D electron gas p-type semiconductor junction. ...................................................................................................140 Figure 5. 14 Current-voltage measurement under different temperature for GaAs based devices. empty symbols: undoped device; solid symbols: doped device. (Data courtesy of IME-CNR, Lecce, Italy). ......142 Figure 5. 15 Ln(I) vs 1/kT at 5V, 10V, and 15V for GaAs based. empty symbols: undoped device; solid symbols: doped device. (Data courtesy of IME-CNR, Lecce, Italy)........................................................143 xiii Figure 5. 16 C-V curves GaAs based.photodetectors, empty symbols: undoped device; solid symbols: doped device. (Data courtesy of IME-CNR, Lecce, Italy). ............................................................................................145 Figure 5. 17 Comparison of temporal response of undoped and doped devices under a bias of 5V; insert shows comparison of their calculated frequency response. ο: undoped device; •: doped device........................146 Figure 5. 18 Comparison of temporal response (short trace) at the different bias. Empty symbols: undoped devices; solid symbols: doped devices. □ and ■: W1G2; ○ and ●: W2G2; ∆ and ▲: W1G4; and : W2G4.......................................................................................................149 Figure 5. 19 Comparison of temporal response (long trace) at the different bias. Empty symbols: undoped devices; solid symbols: doped devices. □ and ■: W1G2; ○ and ●: W2G2; ∆ and ▲: W1G4; and : W2G4.......................................................................................................154 Figure 5. 20 TEM picture for DBR layer. (a) undoped device, Al0.9Ga0.1As: (67±1) nm, Al0.24Ga0.76As: (61±1) nm. (b) doped device, Al0.9Ga0.1As: (67±2) nm, Al0.24Ga0.76As: (60±2)nm (Data courtesy of IME-CNR, Lecce, Italy). .....................................................................157 Figure 5. 21 Comparison of contrast line scan profiles (a) undoped device, (b) doped device (Data courtesy of IME-CNR, Lecce, Italy). ......................158 Figure 5. 22 Comparison of reflectivity spectrum between undoped device and doped device. ο: undoped device; •: doped device (Data courtesy of IME-CNR, Lecce, Italy). .....................................................................160 Figure 5. 23 Interfaces for light to be reflected. (a) bottom mirror, (b) top mirror. ......................................................................................................161 Figure 5. 24 Comparison of reflectivity spectrum between undoped device and doped device. (a) undoped device, solid line: experimental data, dashed line: simulation results; (b) doped device, solid line: experimental data, dashed line: simulation results. .................................162 Figure 5. 25 Comparison of simulation results of quantum efficiency between undoped device and doped device. ο: undoped device; •: doped device. (a) incident angle is 0o; (b) incident angle is 50o.........................164 Figure 6. 1 HMSM typical device structure. ..............................................................171 Figure 6. 2 Cross section of simulated device: X is carrier transport direction, Z is growth direction; device is biased at V volts. ...................................173 xiv Figure 6. 3 Electro-optic sampling system schematic [151]. .....................................175 Figure 6. 4 External electro-optic sampling scheme[151]. ........................................176 Figure 6. 5 Series of GaAs based heterostructure RCE devices. ...............................180 Figure 6. 6 Series of InP based heterostructure REC devices. ...................................183 xv Abstract Novel Heterostructure Metal-Semiconductor-Metal (HMSM) Photodetectors with Resonant Cavity for Fiber Optic Communications Xiying Chen Bahram Nabet Monolithically integrated photoreceivers, optoelectronic integrated circuit photoreceivers (OEIC), are important components for fiber optic communications. Two novel delta modulation doped HMSM photodetectors with resonant cavities have been designed with improved performance in terms of responsivity, speed, sensitivity, and wavelength selectivity to fulfill the increasingly more stringent requirements of transmission systems. The major contributions of the author during the Ph.D. period are as follows: 1. A closed-form model was developed to describe the electronic properties of delta modulation doped heterostructures, which has been compared with a modified selfconsistent method of solving Schrödinger and Poisson equations. 2. A GaAs based and an InP based delta modulation doped HMSM photodetectors with a resonant cavity have been designed for short haul and long haul optical communications, respectively. 3. Two different groups of GaAs based devices with various geometries have been fabricated and characterized: one with the delta modulation doped structure, the other without this doping. Delta doped photodetector shows wavelength selectivity at 850 nm, with 9.2 fA/µm2 dark current, 0.08 A/W average photo responsivity, less than 30 fF capacitance, 10.6 ps full width at half maximum, 9 ps rise time, and 18.4 ps fall time. 4. The most important feature of the delta doped GaAs based device is its improvement of the optical and speed response: its dc photocurrent increases by a factor of 1.6 while the dark current reduces by a factor of 7.8 under 4V bias and a 7 GHz expansion of the 3dB bandwidth xvi under 5V bias compared to the undoped device. The mechanism responsible for the reduction of dark current is enhancement of the cathode metal-semiconductor barrier due to the confined electron cloud, as well as band bending in the anode that reduces hole current flow. The increase in responsivity and speed of response is attributed to the vertical electric field and suitable potential profile in the direction of growth. The device designed, analyzed, characterized, and presented here is an excellent candidate for optical detection purpose, especially for fiber optic communications. 1 1. 1.1 Introduction The Need for Fiber-Optic Communication Systems The most important characteristic of a telecommunication system is unquestionably its information-carrying capacity, but there are many other important characteristics such as security and speed. According to the Shannon-Hartley theorem, the information-carrying capacity is limited by C ci = BW × log 2 (1 + SNR ) , (1.1) where Cci is the information-carrying capacity (bits/sec), BW is the link bandwidth (Hz=cycles/sec), and SNR is the signal-to-noise power ratio. The Shannon-Hartley theorem states that information-carrying capacity is proportional to channel bandwidth. Using a rule of the thumb estimation, the bandwidth is approximately 10 percent of the carrier-signal frequency, which means that the frequency of the carrier signal limits channel bandwidth. Optical fiber has emerged as an excellent medium in view of its tremendous bandwidth potential (50 THz), which permits high data transmission, thus satisfies the demands of the emergence of high-speed applications such as video-conferencing and the rapid growth in the number of networked users. Besides the benefits from the information-carrying capacity, optical fiber is difficult to tap, thus providing a higher degree of security than possible with copper wire; immunity to electromagnetic interference reduces bit error rate and eliminates the need for shielding within or outside a building; the low attenuation of glass fiber permits 2 extended cable transmission distances; light as a transmission medium provides the ability to use optical fiber in dangerous environments; as well as light weight and small diameter of fiber permit high capacity through existing conduits. Over the past decades, the growth of optical-fiber technology in undersea, terrestrial long-haul interoffice trunklines and cable television (cable TV) systems has been explosive. At present, single-mode fiber is the preferred transmission medium for long-distance, point-to-point links such as telephone company intercity trunks. Although it is still unclear what role photonics technology will play in short-hop applications such as local area networks (LANs) and telephone subscriber loops [1], visionaries predicted that fiber’s fingers would touch every home, ultimately replacing coaxial cables and twisted-pair copper wires for telephone and cable television communications. 1.2 Fiber-Optic Communication Systems A modern fiber-optic communications system consists of many components whose functions and technical implementation vary. However, regardless of the sophistication of a network, the features of a fiber-optic communication system can be seen in Fig. 1.1, which includes three main constituent parts: the optical transmitter, the fiber optic channel and the receiver. The major part of the optical transmitter is a light source, whose function is to convert an information signal from its electrical form into light. There are two sources for the fiber-optic communications systems, either lightemitting diodes (LEDs) or laser diodes (LDs). The transmission medium is an optical fiber, which guides light from a transmitter to a receiver. The optical fiber is made from a 3 type of glass called silica. The heart of an optical receiver is its photodetector, which is used to convert an optical information signal back into an electrical signal. The photodetector in fiber-optic communications systems is semiconductor photodiode. Two novel photodetector designs will be discussed in detail in this thesis: one is for short haul communication, and the other is aimed for long haul communication. Transmitter Electrical input signal Drive circuit Light source Fiber flylead Connector Optical splice Optical fiber Optical coupler Repeater Optical receiver Electronics Optical transmitter Receiver Optical Amplifier Electrical signal Signal restorer Photodetector Electricl signal out Amplifier Optical signal Figure 1. 1 Conventional fiber optic communication link, showing a fiber optic connecting an optical transmitter and a receiver passing by a repeater, adapted from [2]. 1.3 Optical Photodetectors At the receiving end, an optical receiver converts the modulated optical signal back into electrical form, thus closing the optical path for information traveling along the fiber-optic communications link. An optical receiver consists of a photodetector, an 4 amplifier, and some related matching circuit. A generic photo-receiver with a photodetector is shown as Fig. 1.2 and its equivalent circuit as Fig. 1.3. A photodiode is the heart of a receiver in the same manner as an LED or an LD is the heart of a transmitter. Only miniature semiconductor photodiodes are employed in fiber-optic communications technology to detect an optical signal. Bias voltage Photodiode R Figure 1. 2 amplifier. AMP L Block diagram of an optical receiver, consisting of a photodetector and an Photo-diode (Ideal) Rs RD Ls CD Ra Equivalent photo- diode circuit Figure 1. 3 Output Optical receiver equivalent circuit. Ca AMP 5 1.3.1 PIN photodiode A PIN photodiode (PD) is basically a reverse biased p-n (or p-i-n, with i standing for intrinsic or undoped) semiconductor junction, which is sensitive to incident light through the absorption of photons, and generates a photocurrent imitating this photon flux. The major feature of this photodiode is that it consists of a thick, lightly doped intrinsic layer sandwiched between thin p and n region. The basic structure of a p-i-n PD is shown in Fig. 1.4. There are three major types of p-i-n photodiodes: front-illuminated PD (Fig. 1.5 [a]), end-illuminated PD (Fig. 1.5 [b]), and edge-illuminated PD (Fig. 1.5 [c]). In a front-illuminated PD, light enters the active region through the top contact. To reduce the backreflection of the incident light, the active surface is covered by an antireflective coating. The light passes through the thin p region and generates electronhole pairs in the thick intrinsic layer. In a rear-illuminated PD, light enters the active region through a heavily doped n+ layer, which is transparent to the incident light, due to its energy band gap is larger than the incident photon energy. The other processes are similar to those that take place in the front-illuminated PD. In an edge-illuminated PD, the incident light doesn’t impinge to the junction perpendicularly; the junction is illuminated in parallel. A large interest in exploiting the specific features of edgeilluminated pin photodiodes has developed since the late 1980’s to solve the limited bandwidth-responsivity product, lack of compatibility with semiconductor laser geometry and limited saturation power in the conventional PIN diodes [3, 4]. 6 P + + P N n Figure 1. 4 Layer and functional structure of a PIN photodiode. A p-i-n photodiode is the most commonly employed light detector in today’s fiber-optic communications systems because of its ease of fabrication, high reliability, low noise, low voltage, and relatively high bandwidth. Antireflection coating Metal contact Metal contact Metal contact p Metal contact P p i i n i n+ n Metal contact Metal contact (a) (b) Metal contact n Metal contact Antireflection coating (c) Figure 1. 5 p-i-n photodiode: (a) front-illuminated PD; (b) fear-illuminated PD; (c) edgeilluminated PD. 7 1.3.2 Avalanche photodiods (APDs) The basic diagram of an APD is shown in Fig. 1.6, which indicates there is an avalanche effect in the photodiode. When the reverse bias on a semiconductor diode is set close, but not quite up to Zener breakdown level, there is strong acceleration of free electrons and holes by large electric fields in the depletion region. These highly energized charges and semiconductor atoms can generate secondary electron-hole pairs through a process known as “impact ionization”, which increases the external current by a factor of G defined by G = I I (1.2) p p+ i p n+ Electric field Depletion region Figure 1. 6 Functional structure of an APD photodiode. APD is at least 10 times more sensitive than a p-i-n PD with comparable bandwidth, which implies a 10-times-longer fiber-optic span between a transmitter and a receiver. But this advantage almost vanishes if one recalls that an APD requires relatively high reverse voltage. 8 1.3.3 Metal-Semiconductor-Metal (MSM) photodiodes An MSM (metal-semiconductor-metal) is another type of photodetector used in fiber-optic communications. The basic structure of an MSM photodetector is shown in Fig. 1.7. Photons generate electron-hole pairs whose flow creates current. A set of flat metal contacts is deposited on the surface of a semiconductor, which are called fingers. They are biased alternately so that a relatively high electric field exists between the fingers. Photons strike the semiconductor material between the fingers and create electron-hole pairs, which are separated by the electric field. Metal Semiconductor Metal Figure 1. 7 A top-view for the Metal-Semiconductor-Metal photodetector planar interdigitated structure. Since both electrodes and a photosensitive region are fabricated on the same side of the semiconductor, this structure is called planar. The advantage of this photodetector is that planar structure results in low capacitance, thus high bandwidth, and in ease of 9 fabrication. However, a drawback to an MSM photodetector is its relatively low responsivity, which ranges from 0.4 to 0.7 A/W. Table 1.1 summarizes the typical characteristics of p-i-n and avalanche photodiodes [5, 6] for three semiconductor materials. Table 1. 1 Typical characteristics of p-i-n and avalanche photodiodes [5, 6]. p-i-n p-i-n Si 0.4-1.1 0.4-0.45 75-90 Material Ge 0.8-1.8 0.8-0.87 50-55 InGaAs 1.0-1.7 0.5-0.95 60-70 V APD p-i-n APD p-i-n APD p-i-n APD p-i-n 1-10 0.1-1 0.125-1.4 0.01 50-100 50-200 50-500 50-500 0-0.0015 1.5 6-10 10-40 1-20 1-5 0.0025-40 1.5-3.5 0.1555-53 2.5-4 5-6 - APD APD 200-250 0.02-0.05 20-40 0.7-1.0 20-30 0.5-0.7 Parameter Wavelength Responsivity Quantum Efficiency APD gain Dark Current Symbol λ R η Unit nm A/W % Type M Id nA Bandwidth BW GHz Bit rate BR Gbit/s Reverse voltage V k-factor 1.4 kA Photodetectors for Different Transmission Windows The transmission characteristics of the optical fiber are of utmost importance for optical telecommunication systems. When incident light propagates along the fiber link, the optical signal experiences all types of losses, which demand the use of a repeater. When short optical pulses are used, a pulse broadening effect arising from dispersion must be accounted for. 10 1.4.1 Transmission characteristic of the optical fiber The key optical performance parameters are attenuation and dispersion. Attenuation is the reduction of signal strength or light power over the distance, whose unit is decibels per kilometer (dB/km). Attenuation of an optical signal varies as a function of wavelength (see Fig. 1.8) [7]. Attenuation is very low, as compared to other transmission media (i.e., copper, coaxial cable, etc.), with a typical value of 0.35 dB/km at 1300 nm. Attenuation at 1550 nm is even lower with a typical value of 0.25 dB/km. This gives an optical signal, transmitted through fiber, the ability to travel more than 100 km without regeneration or amplification. Figure 1. 8 Attenuation as a function of wavelength[7]. Dispersion is the time distortion of an optical signal that results from the many discrete wavelength components traveling at different rates and results in pulse broadening, whose unit is picosecond per nanometer per kilometer (ps /nm-km). In digital transmission, dispersion limits the maximum data rate, the maximum distance, or the information-carrying capacity. In analog transmission, dispersion can cause a waveform 11 to become significantly distorted and can result in unacceptable levels of composite second-order distortion (CSO). Fiber dispersion varies with wavelength and is controlled by fiber design (see Fig. 1.9) [8]. The wavelength at which dispersion equals zero is called the zero-dispersion wavelength (λ0). This is the wavelength at which fiber has its maximum information-carrying capacity. For standard fibers, this is in the region of 1310 nm. Figure 1. 9 Typical dispersion vs. wavelength curve[8]. During the evolution of optical transmission, there have been two major basic fiber optic types: single mode and multimode developed. The multimode fibers operate at 0.8 ~ 0.9 µm (short wavelength) and 1.25 ~ 1.35 µm (long wavelength) while single mode fibers are qualified at two primary regions from 1.2 to 1.6 µm and from 1.60 to 1.65 µm. 12 Figure 1. 10 Absorption coefficients of important semiconductor materials versus wavelength [9]. 1.4.2 Transmission in the 0.85 µm optical window Although optical fiber provides its lowest attenuation in the third optical window at 1.55 µm, 0.85 µm is used for some short-haul transmission due to the availability of very low cost components for this wavelength. From the absorption spectrum of semiconductor materials (see Fig. 1.10) [9], excluding In0.53Ga0.47As and 6H-SiC, the other materials are appropriate for the visible and near infrared spectral range, which is the 0.85 µm optical window. But Si and GaAs are cheaper than other semiconductor materials and also their processing is more mature when compared to the other materials. 13 1.4.2.1 Si photodiodes The absorption of Si is one or two orders of magnitude lower than that of the direct semiconductor in this spectral range. For Si detectors, a much thicker absorption layer is needed than for the direct semiconductor. However, silicon is economically the most important semiconductor in integrated circuits in spite of the nonoptimum optical absorption of silicon. Benefiting from the well-established microelectronics technology, pin photodiodes operating at 0.85 µm have been available for a long time, with a planar technology on n-type substrate, as sketched in Fig. 1.11 [10]. To achieve a good responsivity, a specific characteristic of the wafers for the photodiodes operating at 0.85 µm is a thick (20-50 µm) non-intentionally doped epitaxy layer. ARC p+ contact n- n+ Figure 1. 11 Schematic cross section of a Si pin photodiode.[10]. A Si APD photodiode has other advantages over Si pin photodiodes, such as low noise and large gain-bandwidth. To cope with the low absorption coefficient and with the requirement of pure electron injection in the multiplication region, which is necessarily 14 situated close to the surface at the p-n junction, the structure has to be complex. pπpπn structure is the one designed for Si APD (see Fig. 1.12. [10]). To withstand the high avalanche electric field, very good material quality for both the substrate and the epitaxy layer is mandatory. ARC n contact n+ p π p-(π) p+ Figure 1. 12 Cross-section of a Si APD with a so-called pπpπn structure (π standing for low p- doping level).[10]. 1.4.2.2 GaAs photodiodes In optoelectronics, III-V semiconductor materials are typically used when speed and quantum efficiency of a photodetector are necessary. This is due to low electron mobility in Si, a factor of six lower than that of GaAs, and its indirect band gap, providing a low absorption coefficient. In the past decade, manufacturability and reliability of avalanche photodiodes was the main issue. More recently, speed and power handling capability have received much 15 more attention. At the same time, avalanche multiplication has lost part of its importance with the development of optical amplifiers. Also, short-haul communications are attracting research groups’ concentration more and more as computer processor speeds continue to reach the giga-hertz regime, as introduction of video on demand (VoD) influences the demand for transmission capacity, and also as the transmission rate of data continues to expand [11]. Fiber optics is progressing from point-to-point links to optical networks. The trend towards optical computer networking creates a need for the emergence of high-speed optical components. A compact, low-loss, low-cost optical photodetector whose performance reaches multiGigabyte/s levels is rapidly becoming very attractive [12 - 15]. pin HBT pin FET FET pin substrate (a) substrate (b) substrate (c) Figure 1. 13 Integration schemes for integrated photoreceivers: (a) pin-HBT; (b) pin-FET on a planar substrate; (c) pin-FET on a recessed substrate [10]. Optoelectronic integrated circuits (OEICs) are the key technology for advanced optical storage systems and for the enhancement of their speed and data rate. The trend towards monolithic optoelectronic integrated circuits (OEIC) motivates appreciable research activity directed towards the employment of planar photodetectors, which can be easily fabricated and are compatible with the field effect transistor (FET) process. OEIC 16 photoreceivers incorporating pin photodiodes and metal semiconductor field effect transistors (MESFET) pioneered the recessed substrate approach to planarize the wafer and ease the processing. Integration schemes for integrated photoreceivers with pin photodiodes are shown in Fig. 1.13 [10]. Planar metal-semiconductor-metal photodetectors (MSM-PD’s) are good candidates for such OEIC receivers [16, 17] since these devices can be fabricated in a GaAs buffer layer (or semi-insulating undoped substrate) and there is no additional cost to deposit MSM electrodes, they can be deposited at the same time as the gate electrodes. Since the introduction of MSM device in 1979 by Sugeta [18, 19], several experimental investigation were reported for the utilization of MSM in high-speed receivers [20-26]. The devices for monolithic photoreciever integration can be shown in Fig. 1.14 [10]. B n p+ E p n n+ n+ S.I. S.I. Photodiode bipolar transistor S G D n or p S.I. M.S.M. diode C n+ n buffer n-, pS.I. FET Figure 1. 14 Devices for monolithic photoreceiver integration. One should notice the similarity of MSM and FET structures. [10]. 17 For the first generation fiber optic links, GaAs based MSM PDs were used in the 0.85 µm wavelength range. The second and third generation fiber optic links shift from the 0.85 µm window to the 1.3 µm window where minimum dispersion in fibers occurs and the 1.55 µm window where minimum attenuation occurs. For the detection of the 1.3 µm and 1.55 µm lightwaves, GaAs can not be used any more due to its cutoff wavelength and other ternary semiconductor compound materials are utilized to obtain acceptable responsivity. Table 1. 2 6, 20-26]. Comparison of characteristics of Si and GaAs photodiodes for 0.85 µm [5, Parameter Wavelength Responsivity Symbol Unit nm λ R A/W Quantum Efficiency η Dark Current Bandwidth % Id nA BW GHz Bit rate BR Gbit/s Reverse voltage V V Type p-i-n MSM p-i-n MSM p-i-n MSM p-i-n MSM p-i-n MSM p-i-n MSM Si 0.4-1.1 0.4-0.45 Material GaAs 0.6-0.9 0.35-0.45 75-90 100 1-10 < 1nA 0.125-1.4 > 10GHz 0.01 > 2.5 Gbits/s 50-100 18 1.4.3 Transmission in the 1.3 µm optical window For the 1.3 µm optical transmission window, both single mode fiber and multimode fiber are qualified in this wavelength region. For standard single-mode fibers, 1.31 µm has the lowest dispersion. From the absorption spectrum of Fig. 1.10, In0.53Ga0.47As and Ge cover the widest range including the wavelengths 1.3 and 1.55 µm which are used for long distance optical data transmission via optical fibers. Also, chromatic dispersion consists of two kinds of dispersion. Material dispersion refers to the pulse spreading caused by the specific composition of the glass. Waveguide dispersion results from the light traveling in both the core and the inner cladding glasses at the same time but at slightly different speeds. The two types can be balanced to produce a wavelength of zero dispersion anywhere within the 1.31 µm to 1.65 µm operating window. Thus, optical fiber can be manufactured to have the zero dispersion wavelength in the 1.55 µm region, which is also the point where silica-based fibers have inherently minimal attenuation. In0.53Ga0.47As and Ge photodiodes will be discussed in the next section; they are suitable for transmission in the 1.55 µm optical window, since both of them can operate at that wavelength. 1.4.4 Transmission in the 1.55 µm optical window The dispersion-shifted fibers have low dispersion and low attenuation in the 1.55 µm optical window, which are used in long-distance applications at high bit rates. For 19 applications utilizing multiple wavelengths, it is undesirable to have the zero dispersion point within the operating wavelength range and fibers known as nonzero dispersionshifted fiber (NZDSF) are most applicable. NZDSF fibers with large effective areas are used to obtain greater transmission capacity over longer distance than would be possible with standard single-mode fibers. These fibers are able to take advantage of the optical amplifier technology available in the 1.53 to 1.6 µm operating window while mitigating nonlinear effects that can be troublesome at higher power levels. 1.4.4.1 Ge infrared (IR) photodiodes The developments of long haul communications systems have stimulated a great deal of research towards the fabrication of low-cost optical receivers for the infrared photodiodes. The integration of optoelectronic devices on the silicon chips has been demonstrated as one of the applicable approaches. Due to the SiGe process’s compatibility with complementary metal oxide semiconductor (CMOS) technology, and also a lower bandgap of Ge enabling Si-based detectors for 1.3 µm and to a somewhat less advantageous extent for 1.55 µm [27-30], many research groups have concentrated on integrating SiGe photodiodes on silicon [31-32]. The challenge is to solve the lattice mismatch between Si and Ge of about 4%. The most effective way to fabricate highquality SiGe and Ge layers on Si substrates is to implement graded composition buffer layers [33]. The reduction in threading dislocation density has led to a low dark current density of 0.15 mA/cm2 in Ge mesa photodiodes shown in Fig. 1.15 [34]. Still, there is some difficulty in integrating a Ge photodiode on Si substrate. With a layer thickness of the buffer shown in Fig. 1.15, there is a height of 9.2 µm plus 1.5 µm 20 for the top n+ and p+ layers. Metal interconnects from the Ge photodiode to circuits on the Si substrate, therefore, cause significant problems. Also, this structure is contrary to the trend towards planarization. hν n+ Ge 92% Ge 76% Ge Uniform n+ Ge cap layer, 550oC, 30mT Relaxed graded buffer 10% Ge µm-1 750oC, 250 mT Relaxed graded buffer 10% Ge µm-1 750oC, 250 mT 50% Ge CMP Relaxed graded buffer 10% Ge µm-1 750oC, 250 mT (001) Si substrate offcut 6o to in-plane <110> Figure 1. 15 1.4.4.2 Ge photodiode on SiGe/Si [34]. In0.53Ga0.47As infrared (IR) photodiodes While Ge photodiodes were the components of choice for earlier fiber transmission at 1.3 µm, their poor performance at 1.55 µm and the development of an InP-based optoelectronic technology lead In0.53Ga0.47As photodiodes to meet most demands of long haul communications (long wavelength transmission). Also, its high electron mobility (~12,000cm2V-1s-1 at 300K) and high saturation velocity 21 (~2.5x107cm/s) make lattice-matched growth of In0.53Ga0.47As on InP substrate to be of great promise for receivers used in the 1.55µm and 1.3µm fiber bands of importance to high bit rate, long fiber-link communications [35-40]. p+ nn n+ Figure 1. 16 InGaAsP InGaAs InGaAsP InP Example of an InGaAs photodiode with back-illumination.[10]. Conventional InGaAs pin photodiodes have taken the specific features of the InP heterostructure technology as described in the following: the front layer is wide bandgap material, which is transparent to the incident light, thus it improves both responsivity and response time, while at the same time, it decreases the leakage current; semi-insulating substrates allow for the fabrication of low-capacitance bonding pad; InP’s transparent substrate offer the possibility of illumination through the substrate, which is the way to improve the bandwidth without compromising the responsivity since light crosses the active region two times due to the reflection provided by the front metallization (see Fig. 1.16 [10]). Some sophisticated structures have been investigated to overcome the responsivity-bandwidth limitation of the conventional InGaAs pin photodiodes, such as 22 edge-illuminated InGaAs pin photodiode [41], resonant-cavity photodetector [42], and double-heterostructure multimode photodiodes [43]. Recent developments have further improved the performance of edge-illuminated photodiodes in terms of bandwidth or power handling capability: traveling wave photodiodes and uni traveling carrier photodiodes. Due to its low bandgap and direct type transition, InGaAs is not suited as avalanche multiplication material. In fact, the tunneling current is greater than 1 A/cm2 when avalanche occurs. A very sophisticated structure has been developed, called separate absorption and multiplication (SAM) –APDs, in which absorption takes place in the InGaAs region while multiplication occurs in another material. Such APDs are interesting for applications in the 622 Mbit / s- 10Gbit / s range. To extend to bit rates higher than 10 Gbit / s, much more complicated designs have to be implemented. MSM PDs can be easily integrated with high electron mobility transistor (HEMT) based amplifiers and have much lower capacitance per unit area than the best p-i-n diodes. Receivers for operating at a bit rate over 10 Gb/s have been fabricated by using MSM PD with HEMT technology [44,45]. Figure 1.17 shows the device structure of IIIV MESFET and heterostructure HEMT. Several techniques have been used to improve performance of InGaAs MSM photodetectors, such as responsivity enhancement with nanometer fingers [46] or with semi-transparent Schottky contacts [47], speed increasing with He-plasma assisted MBE grown InGaAsP [48], and dark current reduction with coplanar waveguide transmission lines [49]. 23 Gate narrow band gap material wide band gap material SI Substrate 2DEG HEMT Figure 1. 17 1.5 MESFET Fundamental device structure of III-V MESFET and heterostructure HEMT. Objective and Scope of the Thesis The main objective of this dissertation is to design a novel photodetector for the fiber optical communications applications. Since the early 1980s, monolithically integrated photoreceivers have been identified as important components for optical fiber communications due to their compactness, lower cost, increased sensitivity, and flat response in the case of very large bandwidth photoreceiver [50,51]. Planar metal-semiconductor-metal photodetectors (MSM-PD’s) are good candidates for such OEIC receivers since they are easily fabricated, and are compatible with the FET technology [16, 17]. The latter itself is strongly affected by progress in heterojunction-based devices that take advantage of the reduced dimensionality regime of conduction. This has motivated the development of heterojunction based photodetectors that enjoy better conduction while being compatible with HEMT technology [16]. Heterostucture metal-semiconductor-metal photodetectors (HMSM-PD’s) have demonstrated much less dark current than conventional MSM due to 24 both the two-dimensional electron gas (2DEG) and the effect of barrier enhancement due to the wide-gap material [52-54]. Delta modulation doped technology has been employed due to its high channel electron density, reduced trapping effects, and improved threshold voltage as well as high breakdown characteristics [55-59], thus providing the means to make a high speed device. A resonant cavity is another technology used to solve the trade off between high quantum efficiency and high speed while, at the same time, offering narrow spectral bandwidth detection useful in wavelength-division multiplexing (WDM) applications [60]. In this dissertation, design, fabrication, characterization and analysis of two highspeed, resonant-cavity-enhanced (RCE), HMSM photodetectors with a distributed Bragg reflector (DBR) operating at certain wavelength will be reported. As fiber optics is progressing from point to point links to optical networks, the short haul communications in the Gigabit region is receiving increased attention. Multimode fiber operating at 0.85 µm is used primarily in a LAN environment since it has large bandwidth capability and low costs although the attenuation level is higher compared to a single-mode fiber. We have designed a GaAs-based high-speed, resonant-cavity-enhanced, heterostructure metal-semiconductor-metal photodetector with Al0.24Ga0.76As/ Al0.9Ga0.1As distributed Bragg reflector operating around 0.85 µm for the short haul communications. The photocurrent spectrum shows a clear peak at this wavelength with full width at half maximum (FWHM) of around 30 nm. At resonance wavelength, a seven-fold increase can be achieved in quantum efficiency compared to a detector of the same absorption depth. The top reflector is a delta modulation doped Al0.24Ga0.76As that 25 also acts as the barrier enhancement layer thus providing a 9.2 fA/µm2 low dark current values. The breakdown voltage is above 20 V. Time response measurements show rise time, fall time and FWHM of 9 ps, 18.4 ps, and 10.6 ps, respectively, giving a 3-dB bandwidth of about 33-GHz. Photo response shows 0.08 A/W average photo responsivity and capacitance-voltage measurements indicate less than 30 fF capacitance value. Delta doping of the top AlGaAs layer produces a confined electron cloud and an associated electric field. The delta doped device shows a factor of 7.8 reduction in dark current and a factor of 1.6 increase in DC photocurrent with a 4 volts bias, and about 7 GHz expansion of the 3dB bandwidth under 5V bias compared to an undoped device. We propose that the mechanism responsible for the reduction of dark current is enhancement of the cathode metal-semiconductor barrier due to the confined electron cloud, as well as band bending in the anode that reduces hole current flow. The increase in responsivity and speed of response is attributed to the vertical electric field and suitable potential profile in the direction of growth. As stated earlier, the dispersion-shifted fibers have low dispersion and low attenuation in the 1.55 µm optical window, which are used in long-distance applications with high bit rates. A InP-based high-speed, RCE, In0.52Al0.48As/In0.53Ga0.47As HMSM photodetector with InP/In0.527Al0.144Ga0.329As DBR operating around 1.55 µm has been designed for long haul communications. The devices have been made, while the measurements are still in progress. To understand delta modulation-doped heterostructures’ electronic behavior and the underlying device physics, a closed-form model has been developed to describe the electronic properties for delta modulation doped heterostructures, particularly the 2DEG 26 sheet charge density and the electric field distribution in the direction of growth. The model includes the effects of real-space charge transfer and carrier degeneracy. The electron transfer and quasi-equilibrium condition in the growth direction have been used in order to express the 2DEG sheet charge density that is only a function of material parameters and constants. An empirical constant, corresponding to quantized energy states, has been employed to further simplify this description and to arrive at a closed form expression. Results from the analytical expressions are shown to agree well with numerical simulations based on a self-consistent solution of modified Schrödinger and Poisson equations. To overcome the limitation of the time response of the measurement systems, a coplanar stripe transmission line (CPS) and a coplanar waveguide (CPW) transmission line have been designed for the high speed testing. 1.6 Literature Review High sensitivity (large signal to noise ratio, which also means low dark current), high responsivity, and high speed are goals for future photodetectors. Good power handling devices lost part of their importance due to the development of optical amplifiers. Wavelength selectivity and agile photodetectors are expected to become important devices for future work. The knowledge of material physics, bandgap engineering, and integration technology should be involved in designing novel devices for fiber optical communications of the future. 27 Fiber optical communications are experiencing a shift from point-to-point link to optical networks. Data transmission rate and cost play more important roles than attenuation in short haul optical communications. Fast speed and low cost are high priorities to be satisfied when an optical component device is to be designed. The optical transmission window for short haul communications is in the 0.85 µm region based on the above consideration. The adoption of 0.85 µm short wavelength permits the integration of low capacitance MSM photodetector and the conventional electronic circuit onto a single chip [61]. A 1 Gbit/s OEIC receiver for fiber-optic data link application has been reported by using the conventional GaAs MSM photodetector [61]. To further increase time response, a GaAs based fully integrated HMSM optoelectronic receiver with HEMT technology has demonstrated a data transmission rate beyond 20 Gbit/s [62]. AlGaAs/GaAs heterostructure metal-semiconductor-metal photodetectors (HMSM-PD’s) have much less dark current than conventional MSM due to both the two-dimensional electron gas (2DEG) and the effect of barrier enhancement due to the wide-gap material [52-54]. Also, it takes advantages of 2DEG effects and space separation between the ionized donors in AlGaAs materials and the electrons in the GaAs side to remove scattering effects, thus achieving a high speed device. Such high speed and low current photodetectors based on uniformly modulation-doped technology have been demonstrated in our previous work [52-54]. Uniformly modulation-doped field-effect transistors (U-MODFETs) in optoelectronic applications have been limited by the occurrence of persistent photoconductivity, threshold voltage shift, and collapse of voltage characteristics due 28 largely to effects caused by DX centers and surface states [63-65]. Using a delta (δ) doping technique as an alternative choice for selectively doped heterostructure transistors results in the optimization of its electronic properties. Its high channel electron density, reduced trapping effects, and improved threshold voltage as well as high breakdown characteristics [55-59], have been used to design high speed optoelectronic devices. To better understand the underlying operation mechanisms, extensive exploitation of modulation-doped heterostructure in the novel high-speed devices has motivated the development of theoretical expressions that reveal and help understand the underlying device physics [58,59,66-71]. Specifically, a simplified analytical tool has been developed for carrying out most calculations in terms of sheet carrier density (nso) level in uniformly modulation-doped heterostructure, which is a closed form expression [69,72,73]. Also, a description of the electric field profile can be expressed through the application of Gauss’s Law [74]. A closed-form model to describe the electronic properties for delta modulation doped heterostructures has been developed based on the background mentioned in the above, particularly the 2DEG sheet charge density and the electric field distribution in the direction of growth. A common problem with planar as well as vertical, photodetectors is the trade-off between speed and quantum efficiency. A resonant cavity technique offers the possibility to balance such conflict between fast speed and sensitivity [75]. Resonant cavity (RC) technology has been exploited in the design of active optical components as light emitting diodes [76,77] and vertical cavity surface emitting lasers (VCSELs) [78,79]. Recently, it has extended in the design of passive optical components, such as p-i-n 29 heterojunction photodiodes, Schottky barrier internal emission photodiodes, and quantum well infrared photodetectors [80-82]. There are at least three reasons for Al0.24Ga0.76As to be selected as the top layer above GaAs absorption layer: the first is that its lattice constant matches with the substrate material, which prevents imperfections that might result from the bonding process from affecting the quality of the devices; the second is that its Schottky barrier height with metal is 0.8 eV, which is high enough to form a very good Schottky contact; the third is that the conduction band discontinuity is high enough to make a good heterojunction between Al0.24Ga0.76As and GaAs. Based on the above research background, we designed a GaAs-based high-speed, resonant-cavity-enhanced, heterostructure metal-semiconductor-metal photodetector with Al0.24Ga0.76As / Al0.9Ga0.1As distributed Bragg reflector operating around 850 nm. Combination of low dark current, fast response, wavelength selectivity, and compatibility with high electron mobility transistors makes this device especially suitable for short haul communications purposes. Table 1. 3 Year Medium Voice channels Progress in trans-Atlantic-transmission (TAT) capacity. 1956 1963 1970 1976 1988 Coaxial Coaxial Coaxial Coaxial Fiber (1.3 µm) 84 128 720 4000 40,000 1997 Fiber (1.55 µm) 60,000 (5Gbit/s) 2001 Fiber (1.55 µm) ≈120,000 While for long haul communication, fiber optics is on the road to becoming the key technology of information superhighways offering ultrahigh bit rate transmission. Typical point-to-point links are the telephone company intercity trunk. Typically these 30 links operate at data rates between 45 Mbit/s and 565 Mbit/s, but now, 1.6 Gbit/s to 1.7 Gbit/s (USA) and 2.4 Gbit/s to 2.5 Gbit/s (Europe) systems are available in most places. Table 1.3 shows the progress in trans-Atlantic-transmission (TAT) capacity. The dispersion-shifted fibers have low dispersion and low attenuation in the 1.55 µm optical window, which are used in long-distance applications with high bit rates. While Ge photodiodes were the components of choice for the earlier fiber transmission at 1.3 µm, their degraded performance at 1.55 µm and the development of an InP-based optoelectronic technology lead In0.53Ga0.47As photodiodes to dominate the market of the long haul communications (long wavelength transmission). There are several advantages for InGaAs over the other III-V semiconductor materials: its high electron mobility and high saturation velocity promise a high speed device, its lattice-matched growth of In0.53Ga0.47As on InP substrate result in no stress within the entire structure, and also its aborption region from 1.0-1.6 µm makes it suitable for either 1.3 µm or 1.55 µm fiber optical communications. Receivers for operating with bit rate over 10 Gb/s have been fabricated by using MSM PD with HEMT technology [44,45]. Nanometer fingers or semi-transparent Schottky contacts to enhance the responsivity, He-plasma assisted MBE grown InGaAsP to increase the speed, and CPW transmission lines to reduce dark current have been employed to improve the performance of InGaAs HMSM PDs [46-49]. High-speed monolithically integrated InAlAs/InGsAs/InP HMSM/HEMT photoreceivers have been reported [83]. A packaged receiver has been tested at 5 Gbit/s and an open eye pattern has been obtained. Another research group developed a 31 monolithic receiver by using HMSM structure with a pseudomorphic In0.25Ga0.75As channel with delta doping to acquire 13.5 GHz bandwidth [84]. We have developed a novel design including a delta modulation doping structure, HMSM, and RCE for the InGaAs photodetectro used for the long haul communication. However, low Schottky barrier height (~0.2eV) on n- In0.53Ga0.47As causes excessive leakage current [85]. A lattice-matched material In0.52Al0.48As has been used as a barrier enhancement layer on the top of In0.53Ga0.47As to limit the leakage current to an acceptable value, which has been demonstrated by several groups [86-88]. Based on the background mentioned above, an InP-based high-speed, RCE, In0.52Al0.48As/In0.53Ga0.47As HMSM photodetector with InP/In0.527Al0.144Ga0.329As DBR operating around 1.55 µm is proposed in this thesis. Testing of high speed photodetectors presents a challenge in its own right. We have used femtosecond pulses for excitation of detectors and extracted the response using microwave probes. This limits the resolutions of measurement. To overcome the limitation of the time response of the measurement systems, a coplanar stripe transmission line (CPS) and a coplanar waveguide (CPW) transmission line have been designed for the high speed testing. This dissertation is arranged in the following manner. In Chapter 2, a formulation of resonant cavity enhanced photodetectors derived from the theoretical analysis of planar mirror resonator is presented to calculate the quantum efficiency, finesse, and free spectral range of an arbitrary RCE detector structure. A simplified transmission line model is applied to compute reflection coefficients of two mirrors that form resonant cavity of our detector in terms of the parameters of materials and structures. 32 Since a distinguishing feature of our devices developed here is delta-doping technique, whose advantages are demonstrated in chapter 5, a closed-form model has been developed to describe the electronic properties for delta modulation doped heterostructures, particularly the 2DEG sheet charge density and the electric field distribution in the direction of growth in Chapter 3. Two complete designs are presented in Chapter 4. One is a GaAs-based highspeed, RCE, HMSM photodetector with Al0.24Ga0.76As/ Al0.9Ga0.1As DBR operating around 0.85 µm, which will be employed for short haul optical communications. The other is InP-based high-speed, RCE, HMSM photodetector with InP/In0.527Al0.144Ga0.329As DBR operating around 1.55 µm, which will be used for long haul optical communications. In Chapter 5, the experimental results of GaAs-based photodetectors are presented. First, the performance characteristics of GaAs-based high-speed, RCE, HMSM photodetector with Al0.24Ga0.76As/ Al0.9Ga0.1As DBR are listed; then, the effect of delta doping that is employed in the top AlGaAs layer are investigated by comparing current-voltage, current-votage variation with temperature, capacitance-voltage, and temporal response measurements of doped and undoped devices. Finally, further comparison between the delta-doped and undoped device are discussed, which includes structures from transmitted electron microscope (TEM) pictures and the reflectivity for the light incident on the top surface of the devices from the reflectivity spectrum. In Chapter 6, the contributions of this dissertation are reiterated and future work related to these designs is discussed. Commercial software will be used for simulating the static electronic properties of the specific structures; a model based on Ramo’s theory 33 will be employed to describe the dynamic behavior of the photogenerated carriers in those devices; and the mechanism of the electro-optic measurement will be described. 34 2. Resonant Cavity Enhanced Devices Importance for the design and understanding of RCE based devices is the development of an analytical mathematical model describing the behavior of an active absorption (or gain) region inside a Fabry-Perot resonator. Below, the theoretical analysis of a planar mirror resonator is presented first. Then, a formulation of resonant cavity enhanced photodetectors derived from the theoretical analysis of planar mirror resonator allows the calculation of the quantum efficiency, finesse, and free spectral range of an arbitrary RCE detector structure. The dependence of RCE detector properties on the placement of the active layer within the cavity and the angle of incidence of the detected radiation is also considered in the following analysis. A simplified transmission line model is applied to compute reflection coefficients of two mirrors that form resonant cavity of our detector in terms of the parameters of materials and structures. The simulation results and discussions in this chapter help design the resonant cavity part of the devices used for the short haul and long haul communications in Chapter 4, and characterize the optical properties of those optoelectronic devices. 2.1 Introduction High speed and high sensitivity photo-receivers are the key components in high- bit-rate and low cost fiber optic communication systems. For some of the applications that employ wavelength division multiplexing (WDM), it would be advantageous to 35 combine wavelength selectivity with detection. A family of optoelectronic devices emerged over the past twenty years whose performance is improved by placing the active device structure inside a Fabry-Perot resonant micro-cavity. Such resonant cavity enhanced (RCE) devices derive advantages from the wavelength selectivity and the large increase of the resonant optical field resulting from the resonant microcavity. The increased optical field allows photodetctors to be made thinner and therefore faster, while at the same time, increasing the quantum efficiency at the resonant wavelength. Offresonant wavelengths are rejected by the microcavity, thus making it suitable for the low cross-talk WDM applications. The resonant cavity structure alleviates the well-known bandwidth/quantum efficiency tradeoff as well as to provide a narrow spectral response in p-i-n photodiodes [89, 90], elemental semiconductor (Si and Ge) and compound semiconductor APDs [91 - 93], and MSM photodiodes [36, 38]. The enhanced performance of the semiconductor devices resulting from the resonant cavity in the optoelectronic applications has also been demonstrated in numerous active optoelectronic devices: vertical resonant cavity surface emitting lasers (VCSEL’s) decreased the threshold current densities [94], light emitting diodes (LED’s) improved their spectral purity and directivity, as well as optical modulator operated at lower voltages. This chapter provides an overview of RCE passive optoelectronic devices, including theoretical analysis of RCE photodetectors parameters in Section 2.3 and design criteria for RCE photodetectors in Section 2.4. The formula in the first 3 sections are employed in the normal incident case; while in Section 2.5, the oblique incidence are discussed and the formula are modified to be used in this case based on those of the previous sections. 36 2.2 Theoretical Analysis of Planar Mirror Resonators For the purpose of the design and understanding of RCE-based photonic devices, an analytical mathematical model describing the behavior of an active absorption (or gain) region inside a Fabry-Perot resonator has to be developed. Several research groups have contributed to this endeavor [95 - 99]. A resonator is constructed of two parallel, highly reflective, flat mirrors separated by a distance d (Fig 2.1). Mirror 1 Mirror 2 E3 E2 E1=r1r2e-jΨE0 E1 E0 + E r1r2e-jΨ E0 t 1 r1 d r2 t 2 z=0 (a) Figure 2. 1 (b) Two-mirror planar resonator (Fabry-Perot Mirror). Resonator modes are the standing waves. A monochromatic wave of frequency f has a wavefunction, 37 r r E (r , t ) = E (r ) exp( j 2π f t ) (2.1) which represents the transverse component of the electric field. The complex amplitude r E (r ) should satisfy the Helmholtz equation, r r ∇ 2 E (r ) + β 2 E (r ) = 0 (2.2) where β=2π f/up is the wave number and up is the speed of light in the medium. The modes of a resonator are the basic solutions of the Helmholtz equation subject to the r appropriate boundary conditions, which require that E (r ) equals zero at z=0 and z=d plane. This restricts β to the values β m = limited to the discrete values f m = m up 2d mπ , which also means that the frequency f is d . Thus, the adjacent resonance frequencies are separated by a constant frequency difference f m+1 − f m = up 2d . The resonator modes can alternatively be determined by following a wave as it travels back and forth between the two mirrors (Fig. 2.1(a)). The phase difference imparted by a single propagation round trip is Ψ = 2β d = 4π f d 4π d = , up λ (2.3) where λ is the wavelength in the medium. When the mirrors are not perfect, which means that reflectivity is not 1, the phasors are not of equal magnitude. The relation between the two consecutive phasors can be expressed as Ei +1 = r1 r2 e − jΨ Ei (2.4) 38 As shown in Fig. 2.1(b), r1 and r2 are the reflection coefficients of the two mirrors, respectively. If the phasor Ei+1 is related to Ei by a complex factor h = r1r2 e − jΨ . The net result is the superposition of an infinite number of waves E = E0 + E1 + E 2 + .... ∞ ∞ i =0 i =0 = ∑ Ei = ∑ E 0 h i = . E0 E0 = 1 − h 1 − r1 r2 e − jΨ (2.5) Therefore, the wave intensity in the resonator is found to be I= E = = 2 = 2 E0 1 − r1r2 e − jΨ 2 E0 (2.6) 1 − R1 e − jΨ 1 R2 e − jΨ 2 e − jΨ I0 1 + R1 R2 − 2 R1 R2 cos(Ψ +Ψ 1 +Ψ 2 ) where R1 and R2 are the reflectivities of the two mirrors, respectively, and Ψ1 and Ψ2 are phase shifts introduced by the front and the back mirrors. Here I 0 = E0 of the initial wave, and F = can be maximized π( R1 R2 )1 / 2 1 − R1 R2 when 2 is the intensity is the finesse of the resonator. The intensity, I, cos(Ψ + Ψ 1 + Ψ 2 ) equals unity, which requires Ψ + Ψ 1 + Ψ 2 = 2mπ . If F is large, which requires that the mirrors have large reflectivities, then I has sharp peaks centered at the values Ψ + Ψ 1 + Ψ 2 = 2mπ . In the above derivation, we only considered the losses arising from imperfect reflection at the mirrors. There are other sources of resonator loss due to absorption and scattering in the medium between the mirrors. The round trip power attenuation factor associated with these processes is exp(−2α d ) , where α is the absorption coefficient of the 39 material. Then, the complex factor h relating the phasor Ei+1 to Ei should include this effect, which can be rewritten as exp(-αd)r1r2e-jΨ. Thus, Eq. 2.6 is modified to the following I= = 2 E0 1 − e −αd R1 e − jΨ 1 R2 e − jΨ 2 e − jΨ 1 + R1 R2 e − 2 αd (2.7) I0 − 2 R1 R2 e −αd cos(Ψ + Ψ 1 + Ψ 2 ) Also, the finesse F can be expressed as a function of the effective loss coefficient αr F= π exp(−α r d / 2) , 1 − exp(−α r d ) (2.8) where αr can be calculated from the formula αr = α + 1 1 ln( ). 2d R1 R2 (2.9) Based on the above theoretical analysis, a formulation of the quantum efficiency for RCE photodetectors can be derived as follows. 2.3 Formulation of Quantum Efficiency for RCE Photodetectors The content covered in this section is arranged as the following description. A formula of quantum efficiency for the resonant-cavity-enhanced heterojunction photodetector shown as Fig. 2.2 is derived at first. The formulation of the reflectivity of the two mirrors is described in terms of material parameters in the next part. The 40 numerical calculation results are discussed as the next following. The standing wave effect involved in the quantum efficiency will be depicted as the last part. 2.3.1 Formulation of the quantum efficiency for RCE photodetectors incident light Z=0 Ei Barrier Ef enhancement layer Eb absorption layer √R1e-jΨ1 t1 L1 L2 √R2e-jΨ2 DBR reflector Figure 2. 2 Schematic photodetector. diagram of resonant-cavity-enhanced heterojunction A typical RCE photodetector is made of a Fabry-Perot cavity, with a mirror on each end, whose length determines the resonant frequency. In practice, the bottom mirror consists of quarter-wave stacks of two different materials forming a distributed Bragg reflector (DBR). The top mirror can be the interface between the native semiconductor and air due to the large difference in their refractive index. The active layer, where the absorption occurs, is placed between the two mirrors. Here we use a delta-doped heterojunction to achieve better photon reflection as well as other important electronic functionalities. These include decreasing the dark current due to an enhancement of 41 Schottky barrier height, modulating the two dimensional electron gas density in the triangular quantum well at the narrow gap material side, adjusting the electric filed profile distribution in the growth direction, thus controlling the carriers' behavior, and more as will be detailed in Chapter 4 and Chapter 5. Figure 2.2 shows a simplified structure of our RCE photodetector, where L1 is the non-absorbing barrier enhancement layer. Re-circulation of photons from the top of this layer and the bottom DBR, allows a thin absorption layer L2 to be used to minimize the response time without hampering the quantum efficiency. R1 and R2 are the reflectivity of top mirror and bottom mirror respectively, α is the absorption coefficient of the absorption layer, Ψ1 and Ψ2 are phase shifts introduced by top and bottom mirrors due to light penetration into the mirrors, and β1 and β2 are the propagation constants in these two materials. The transmitted component of the incident light wave electrical field (Ein) equals t1Ein. In the cavity, the forward traveling wave is composed of these transmitted waves and the feedback as a result of internal reflections at the mirrors. Thus, the forward traveling wave Ef at z=0 can be obtained through a self-consistent consideration, i.e., Ef is the sum of the transmitted field and the feedback after a round trip in the cavity: E f = t1 Ein + e −αL2 R1 e − jΨ 1 R2 e − jΨ 2 e − jΨ E f = t1 Ein + e −αL2 R1 e − jΨ 1 R2 e − jΨ 2 e − j ( 2β1L1 + 2β2 L2 ) E f = t1 Ein + e ⇒ Ef = −αL2 1− e R1 e −αL2 − jΨ 1 R1 e R2 e t1 − jΨ 1 − jΨ 2 e − j (2 2π 2π L1 + 2 L2 ) λ1 λ2 R 2 e − jΨ 2 e − jΨ Ein Ef (2.10) 42 The backward traveling wave Eb, i.e., electric field at z=L1+L2, can be found from Ef through the detector region: Eb = e −αL2 / 2 R2 e − jΨ 2 e − jΨ / 2 E f (2.11) = e −αL2 / 2 R2 e − jΨ 2 e − j ( β1L1 + β2 L2 ) E f The optical power inside the resonant cavity is given by Ps = Es 2 2η s (s=f or b), (2.12) where ηs is the intrinsic impedance of the detector material, which will be defined in the next section. The light power absorbed in the active layer (Pl) can be obtained from the incident power Pi: Pl = ( Pf + Ps )(1 − e −αL2 ) = (1 − R1 )(1 + R2 e −αL2 )(1 − e −αL2 ) 1 − 2 R1 R2 e −αL2 cos(2( β1 L1 + β 2 L2 ) + Ψ 1 + Ψ 2 ) + R1 R2 e −2αL2 Pi (2.13) One of the desired features for RCE photodetectors is high quantum efficiency. Under the assumption that all the photogenerated carriers contribute to the detector current, quantum efficiency (η) is defined as the ratio of absorbed power to incident optical power. The derivation of the quantum efficiency for the photodetectors is based on the structure shown Fig. 2.2, which can be written as [103]: η = (1 − R1 )(1 − e −αL2 ) ( ) 1 + R2 e −αL2 × − αL − 2αL2 1 − 2 R1 R2 e 2 cos(2( β1 L1 + β 2 L2 ) + Ψ 1 + Ψ 2 ) + R1 R2 e , (2.14) From this formula, quantum efficiency is maximized due to high reflection from the DBR and when the condition cos(2( β1 L1 + β 2 L2 ) + Ψ 1 + Ψ 2 ) = 1 is satisfied. 43 2.3.2 Formulation of the reflectivity of the two mirrors A simplified transmission model is applied to calculate reflection coefficients of two mirrors [100]. The impedance calculated begins at the substrate and ends at the top of the bottom mirror. Every semiconductor layer is considered to be a transmission line segment, whose characteristic impedance is given as [100]: ηi = µ ε − jε " ' , (2.15) where ε´ and ε˝ are the real and imaginary part of the dielectric constant, and µ is the material’s permeability. For non-absorbing layer, ε ' >> ε " , ηi can be written as ηi = µ ε' and also the propagation constant can be simplified for every non-absorbing layer as β = ω µε ' . Here, ω is the operation frequency, which is related to the incident light. An equivalent expression for β is given as: β = 2π (λ0 is the wavelength of the incident λ0 / n light in the vacuum and n is the refractive index for the material). The substrate impedance is first computed by using Eq. (2.15). The equivalent input impedance for every layer with its thickness and characteristic impedance is calculated from [101]: η i = η 0i η i −1 + η 0i tanh(γ i li ) , i=1 to 2N η 0i + η i −1 tan(γ i li ) (2.16) where N is the total number of the contrasting pairs in the quarter mirror stacks, γi = αi 2 + iβ i , αi is the absorption coefficient of ith layer and βi is the propagation 44 constant of the ith layer, until the top of the bottom mirror is reached. The overall reflection coefficient can then be evaluated as [101]: Γ2 = η 2 N − η abs = R2 e − jΨ 2 η 2 N + η abs (2.17) where η2N is the input impedance at the interface between the active layer and the top of the bottom mirror; ηabs is the characteristic impedance of the absorption layer, which can be found using the same method as used for the substrate’s characteristic impedance. The reflection coefficient for the top mirror can be acquired in the same manner. The only difference from Γ2 is to replace η2N with ηair and replace ηabs with ηbarrier. ηair is the characteristic impedance of air and ηbarrier is the characteristic impedance of the barrier enhancement layer. The thickness of the barrier enhancement layer and the absorption layer are limited by satisfying the optimization condition requirement of the quantum efficiency ( cos(2( β1 L1 + β 2 L2 ) + Ψ 1 + Ψ 2 ) = 1 ). 2.3.3 Numerical calculation of RCE quantum efficiency Since the propagation constant β has a wavelength dependence, quantum efficiency, η, is a periodic function of the inverse wavelength while the thickness of the barrier enhancement layer and absorption layer are fixed. This can be seen in Fig. 2.3, which illustrates the calculated wavelength dependency of η. The simulation results are based on the structure shown in Fig. 2.2. The three curves correspond to the cases of R1=0.9, 0.3, and 0.05 while L1 = 550Å, L2 = 1175Å, R2 = 0.9, and αL2 = 0.11 are fixed. The simulation results shown in Fig. 2.3 and Fig. 2.4 do not include the non-linear dispersion effects, which mean that the refractive index of the material does not change 45 within the whole spectrum range. The refractive index of the barrier enhancement layer Al0.24Ga0.76As is value at a λ of 0.83 µm while GaAs’s refractive index at 0.83 µm is that of the absorption layer. 0.6 0.5 Quantum Efficiency αL2=0.11, R2=0.9 FSR 0.4 0.3 0.2 R1=0.05 0.1 R1=0.3 0.0 R1=0.9 0.4 0.6 0.8 1.0 1.2 1.4 Wavelength (µm) Figure 2. 3 Wavelength dependence of η for RCE detectors having various top mirror reflectivities for fixed L1=550Å, L2=1175 Å, R2=0.9, and αL2=0.1. It’s observed that η is enhanced periodically at the resonant wavelengths which occur when 2( β1 L1 + β 2 L2 ) + Ψ 1 + Ψ 2 = 2mπ (m=1, 2…). The spacing of the cavity modes is defined as the free spectral range (FSR), i.e., resonant wavelengths and resonant frequencies, which can be seen in Fig. 2.3 and Fig. 2.4 respectively. 46 0.6 0.5 Quantum Efficiency αL2=0.11, R2=0.9 FSR 0.4 0.3 0.2 R1=0.05 0.1 R1=0.3 0.0 R1=0.9 0.4 0.6 0.8 1.0 1.2 1.4 Wavelength (µm) Figure 2. 4 Frequency dependence of η for RCE detectors having various top mirror reflectivities for fixed L1=550Å, L2=1175 Å, R2=0.9, and αL2=0.1. For the photodetector described as the above structure, the FSR is around 330 nm between the resonant wavelength at 0.83 µm and its adjacent resonant wavelength at the high energy level side, and also the FSR is about 240 THz between two adjacent resonant frequencies in Fig. 2.3 and Fig. 2.4 respectively. For a well-designed photodetector, the active region should be the only place to absorb the incident light. In the above photodetector structure, the band gap of the absorption material is the smallest. Thus, the spacing of the cavity modes at the low energy side to the resonant wavelength at 0.83 µm does not need to be considered, while the resonant wavelength adjacent to 0.83 µm on the other side is around 0.5 µm, which is larger than the band gap of the barrier enhancement layer. Therefore, the absorption in the Al0.24Ga0.76As material is decreased by using the resonant cavity technique if the incident photon energy is smaller than the edge of the bandgap of Al0.24Ga0.76As. 47 2.3.4 Standing wave effect The peak η at the resonant wavelengths can be derived by imposing the resonant condition in Eq. 2.14: ( ) 1 + R e −αL2 2 η = (1 − R1 )(1 − e −αL2 ) × − αL (1 − R1 R2 e 2 ) 2 (2.18) In the limit of the a thin active layer αL2 << 1, (2.18) reduces to (1 + R (1 − αL ) ) 2 2 η ≈ (1 − R1 )αL2 (1 − R1 R2 (1 − αL2 )) 2 (2.19) In the simulation results of the previous section, the spatial distribution of the optical field inside the cavity was neglected. A spatial distribution arises from the standing wave formed by the two counter propagating waves. It follows that η, which was derived from the power absorbed in the active region, is a function of the placement of the active region in the optical field. This is called the standing wave effect (SWE). When detectors with thick active layers which span several periods of the standing wave are considered, the standing wave effect can be neglected. For very thin active layers, which are necessary for strained layer absorbers, the SWE must be considered. The SWE is conveniently included in the formulation of η as an effective absorption coefficient, i.e., α eff = SWE × α , which is either enhanced or decreased by the placement of the active region. The effective absorption coefficient αeff is the normalized integral of the product α and the field intensity across the absorption region. Using a perturbation analysis of Maxwell’s equations, including the loss factors and assuming 48 uniformity along the transverse direction, the effective absorption coefficient can be expressed as [102]: 2 L1 + L2 ∫ α( z ) E ( z , λ) 1 / L2 dz 0 α eff = 2/λ , 2 λ/2 ∫ E ( z , λ) (2.20) dz 0 where λ = λ0 n , E(z, λ) is the total electrical field in the cavity at a given wavelength and the denominator is the average of the standing wave. Taking α to be negligible outside of the active region and constant within, we arrive at L1 + L2 SWE = α eff α 1 / L2 2 ∫ E( z) dz L1 = 2/λ λ/2 ∫ E ( z) (2.21) 2 dz 0 The forward (Ef) and backward (Eb) components of the standing wave are given 2 by Eq. (2.10) and Eq. (2.11). The total electric field E and intensity E are : E = E f (0)e − jβz + Eb ( L1 + L2 )e jβ( z −( L1 + L2 )) (2.22) and 2 2 2 { * } E = E f (0) + Eb ( L1 + L2 ) + 2 Re E f ( z ) Eb ( z ) (2.23) Substituting Eq. (2.10) and Eq. (2.11) into Eq. (2.23) and assuming α=0, which is reasonable for a thin active layer which absorbs a small fraction of total power density: 49 E 2 (1 − R1 ) = 1 − R1 R2 e j ( 2 βL +Ψ 1 +Ψ 2 ) [ 2 (2.24) ] × 1 + R2 + 2 R2 cos[2 β ( L1 + L 2 − z ) + Ψ 2 ] Ein 2 Substituting Eq. (2.24) into Eq. (2.21), we obtain the dependence of the SWE on the cavity parameters [103]: SWE = 1 + 2 R2 βL2 (1 + R2 ) [sin βL2 cos( βL2 + Ψ 2 )] (a) 1.2 1.1 SWE SWE (b) 1.2 1.1 1.0 0.9 0.8 (2.25) 1.0 0.9 0.4 0.6 0.8 1.0 Wavelength (µm) 1.2 1.4 0.8 200 300 400 500 600 700 800 900 1000 Frequency (THz) Figure 2. 5 SWE as a function of wavelength for four different active layer thicknesses: L2a=1175 Å (solid), L2b=2306 Å (dash), L2c=3438 Å (dot), L2d=4569 Å (dash dot) for a cavity with R2=1, ψ2=-π, and the material refractive index will not change with the wavelength. (a) in wavelength spectrum; (b) in frequency spectrum. Figure 2.5 indicates the wavelength dependence of the SWE for various active layer thickness L2. As shown in the figure, for a very thin active layer structure, the SWE is more prominent. Knowledge and control of the phase behavior is particularly important 50 for proper positioning of very thin absorbing layers in high η photodetectors. Also, Fig. 2.5 shows that the SWE becomes more pronounced as the photon energy of the incident light decreases. Since the SWE is larger than one at the low energy side to the resonant wavelength while smaller than one at the other side as shown in Figure 2.5, the absorption coefficient is larger than that without considering the SWE at the long wavelength side the resonant wavelength while smaller than that at the other side when the absorption coefficients are modified by Eq. (2.20). 2.4 Formulation of Reflection Coefficient of Mirrors In this section, formulation of reflectivity of the mirrors will be expressed from the transmission line analogue and the multiple reflection view point, which is the theoretical basis for simulating the experimental data of the reflectivity spectrum of the top mirror in Chapter 5. The transmission line analogue is used for calculating the effective reflection coefficient of the bottom mirror, while the multiple reflection effect has been included in calculating the reflection coefficient from the top mirror since light has been multiply reflected between the two mirrors due to the resonant cavity. 2.4.1 Reflection coefficient calculated from transmission line analogue When a guided wave traveling along a transmission line encounters an impedance discontinuity, such as that shown in Fig. 2.6 (a), at the boundary between two lines with different characteristic impedances, that incident wave is partly reflected back toward the source and partly transmitted across the boundary into the second line. A similar process 51 applies to a uniform plane wave propagating in an unbounded medium when it encounters a boundary. In fact, the situation depicted in Fig. 2.6 (b) is exactly analogous to the transmission line configuration of Fig. 2.6 (a). The boundary conditions governing the relationships between the electric and magnetic fields of the incident, reflected, and transmitted waves in Fig. 2.6 (b) are similar to those for the voltages and currents of the corresponding waves on the transmission line. Transmission line 1 Z01 z=0 Transmission line 2 Incident wave Transmitted Wave Z02 Reflected wave (a) Boundary between transmission line z=0 Incident plane wave Transmitted plane Wave Reflected plane wave Medium 1 η1 Medium 2 η2 (b) Boundary between different media Figure 2. 6 Discontinuity between two different transmission lines is analogues to that between two dissimilar media. The input impedance of an infinitely long line is equal to its characteristic impedance. Hence, at z=0, the voltage reflection coefficient (looking toward the boundary from the voltage point of the first line) is 52 Γ = Z 02 − Z 01 Z 02 + Z 01 (2.26). There is a one-to-one correspondence between the transmission line parameters ~ ~ ~ ~ ( V , I , β , Z 0 ) and the plane wave parameters ( E , H , β ,η ). This correspondence allows us to use the transmission line techniques to solve the plane wave propagation problems. The equivalent electric circuit for the structure shown in Fig. 2.2 can be drawn in the following picture (Fig. 2.7). l1 = λ0/4n1 L2 Absorption layer air L1 Barrier enhancement layer Figure 2. 7 Γ ηL l2 = λ0/4n2 N pairs quarter wave stack Equivalent electric circuit for photodetector shown in Fig. 2.2. The substrate impedance is first computed by using Eq.(2.15), which corresponds to the load impedance ηL in Fig. 2.7. Each semiconductor layer can be seen as a 53 transmission line in accordance to its thickness li and characteristic impedance ηi calculated by using Eq. (2.15). The impedance is transformed for each layer by Eq. (2.16) until the top of the bottom mirror is reached. Once the input impedance (ηin) at the top of the bottom mirror is known, the overall complex reflection coefficient from the bottom mirror can be evaluated as: Γ = η in − η abs η in + η abs (2.27). Reflectivity calculation is straight forward since it is the square of the magnitude of the reflection coefficient. 2.4.2 Multiple reflection viewpoint Since the incident light experiences multiple reflections between the top and bottom mirrors within the resonant cavity shown in Fig. 2.2, from a multiple reflection viewpoint, the overall or total reflection coefficient of a wave incident on this RCE photodetector can be computed using the following derivation. There is an assumption that the partial reflection at the interface between the barrier enhancement layer and the absorption layer can be neglected due to the smaller characteristic difference between these two materials. Figure 2.8 shows the equivalent electric circuit of the RCE photodetector with reflection and transmission coefficients defined as follows: Γ = overall, or total, reflection coefficient of a wave incident on the RCE photodetector. 54 Γ1 = partial reflection coefficient of a wave incident on a load ηair, from the ηbarrier line. Γ1´ = partial reflection coefficient of a wave incident on a load ηbarrier, from the ηair line. Γ2 = partial reflection coefficient of a wave incident on a load η2N, from the ηabs line. τ1 = partial transmission coefficient of a wave from ηbarrier line to ηair line. τ1´ = partial transmission coefficient of a wave from ηair line to ηbarrier line. Here η2N is the input impedance at the top surface of the bottom mirror, which is the equivalent load for a wave incident on this interface. These coefficients can then be expressed as Γ 1' = η barrier − η air η barrier + η air (2.28 a) Γ1 = η air − η barrier = −Γ 1' η air + η barrier (2.28 b) Γ2 = η 2 N − η abs η 2 N + η abs (2.28 c) τ 1' = 1 + Γ 1 ' = τ1 = 1 + Γ 1 = 2η barrier η barrier + η air 2η air η barrier + η air (2.28 d) (2.28 e) Since each round-trip path forward and back through the resonant cavity results in a − 2( β 1 L1 + β 2 L2 ) phase shift and a e −αL2 magnitude decrease, the total reflection coefficient can be expressed as 55 Γ = Γ 1' + τ 1'τ 1Γ 2 e − j 2( β1L1 + β 2 L2 ) e −αL2 + τ 1'τ 1Γ 2 e − j 2( β1L1 + β 2 L2 ) e −αL2 Γ 1e − j 2( β1L1 + β 2 L2 ) e −αL2 Γ 2 + ... ∞ = Γ 1' + τ 1'τ 1 ∑ (Γ 2 e − j 2( β1L1 + β 2 L2 ) e −αL2 ) i (Γ 1 ) i −1 . i =1 ' ' = Γ 1 + τ1 τ1 Γ 2 e − j 2( β1L1 + β 2 L2 ) e −αL2 1 − Γ 2 e − j 2( β1L1 + β 2 L2 ) e −αL2 Γ 1 RCE photodetector τ1 ηbarrier ηair ηabs Barrier enhancement layer air τ1′ Γ′1 η2N Absorption layer L1 L2 Γ1 Γ2 L1+L2 1 Γ′1 Figure 2. 8 τ1’ τ1 Γ1 Γ2 τ1 Γ1 Γ2 Multiple reflection analysis of the RCE photodetector. (2.29) 56 2.5 Formulation modified at Oblique Incidence For normal incidence, the reflection coefficient Γ and transmission coefficient τ of a boundary between two different media are independent of the polarization of the incident wave, because the electric and magnetic fields of a normally incident plane wave are always tangential to the boundary regardless of the wave polarization. This is not the case for oblique incidence at an angle θi ≠ 0o. In addition, the length of the light path within each individual layer is different from the thickness of the layer when the light is not normally incident. In this section, formulae of reflectivities and quantum efficiencies are modified to be used for oblique incidence, which are then employed to simulate the quantum efficiency in order to explain the experimental results contained in Chapter 5. There are two different polarized waves: one with its electric field parallel to the plane of incidence called parallel polarization, and the other with its electric field perpendicular to the plane of incidence called perpendicular polarization. The plane of incidence is defined as the plane containing the normal to the boundary and the direction of propagation of the incident wave. These two polarization configurations are shown in Fig. 2.9. Instead of solving the reflection and transmission problems for the general case of a wave with an arbitrary polarization, it is more convenient in practice to first decompose the indicent wave (Ei, Hi) into a perpendicularly polarized component (Eipe, Hipe) and a parallel polarized component (Eipa, Hipa), and then after determining the reflected waves (Erpe, Hrpe) and (Erpa, Hrpa) due to the two incident components, the reflected waves can 57 be added together to give the total reflected wave corresponding to the original wave. A similar process applies to the transmitted wave. X βr Hper θr Z Y βi Epei Hpet θt θi Medium 1 ( ε1 , µ 1 ) βt Epet Eper Hpe Medium 2 ( ε2 , µ 2 ) i z=0 (a) Perpendicular polarization X βr Epa r Epat Hpar θr θi Medium 1 ( ε1 , µ 1 ) θt Hpa Hpat Y βi Epai βt Z Medium 2 ( ε2 , µ 2 ) i z=0 (b) Parallel polarization Figure 2. 9 A wave is (a) perpendicularly polarized when its E field is perpendicular to the plane of incidence and (b) parallel polarized when its E field lies in the plane of incidence. The phase matching condition is known as β1 sin θ i = β1 sin θ r = β 2 sin θ t , (2.30) 58 where β1 is the wave number in the first medium, β2 is the wave number in the second medium, θi is the incident angle, θr is the reflected angle, and θt is the transmitted angle. The first equality in Eq. (2.30) leads to θ i = θ r (Snell’s law of reflection) (2.31 a) and the second equality leads to sin θ t β1 n1 = = (Snell’s law of refraction) sin θ i β 2 n 2 (2.31 b) The following expressions are for the reflection and transmission coefficients in the perpendicular polarization case: Γ⊥ = τ⊥ = E rpe E ipe E tpe E ipe = = η 2 cos θi − η 1 cos θt η 2 cos θi + η 1 cos θt 2η 2 cos θ i η 2 cos θ i + η 1 cos θ t (2.32 a) (2.32 b) where θi and θt are defined as the above description, and η1 and η2 have the same definition as in the previous sections. The Fresnel reflection coefficients for perpendicular polarization are related by τ ⊥ = 1+ Γ ⊥ (2.33) Equations (2.33) are the expressions for the reflection and transmission coefficients in the parallel polarization case, Γ = τ = E rpa E ipa E tpa E ipa = η 2 cos θt − η 1 cos θi η 2 cos θt + η 1 cos θi (2.34 a) = 2η 2 cos θi , η 2 cos θt + η 1 cos θi (2.34 b) 59 The above expressions can be shown to yield the relation τ = (1 + Γ ) cos θi cos θt (2.35). The thickness of each individual semiconductor layer has to be modified for the oblique incident case, which can be found by using Eq.(2.36) Leff _ j = Lj cos θ j _ t = Lj 1 − (sin θ j _ t ) 2 = Lj 1 − (sin θ i / n j ) 2 , (2.36) where Leff_j is the effective thickness of the jth layer and Lj represents the thickness of the jth layer; while the θj_t is the transmitted angle in the jth layer and nj is the refractive index of the jth layer. When the light is oblique incident on the devices, the partial reflection and transmission coefficients of a wave in the previous sections at each individual boundary are replaced with Γ┴ and τ┴ or Γ║ and τ║ for perpendicularly polarized wave or parallel polarized wave, respectively. Also, the thickness of each individual layer has to be replaced with the effective thickness by using Eq. (2.36). 60 3. A Closed-form Expression to Analyze Electronic Properties in Delta-doped Heterostructures An important feature of the devices developed here is that delta-doping technique will be employed in the top AlGaAs layer to produce a confined electron cloud and an associated transverse electric field, which may result in a reduction of dark current. Also, the vertical electric field along the growth direction gives the contribution to the collection of photo-generated carriers. These advantages of the delta modulation doping will be demonstrated in Chapter 5. A closed-form model is developed in this chapter to describe the electronic properties of delta modulation doped heterostructures, particularly the 2DEG sheet charge density and the electric field distribution in the direction of growth. The model includes the effects of real-space charge transfer and carrier degeneracy. The electron transfer and quasi-equilibrium condition in growth direction have been used in order to express the 2DEG sheet charge density that is only a function of material parameters and constants. An empirical constant, corresponding to quantized energy states, has been employed to further simplify this description and to arrive at a closed form expression. Results from the analytical expressions are shown to agree well with numerical simulations based on a self-consistent solution of modified Schrödinger and Poisson equations. In addition to their use in modeling of current conduction in HEMT devices, we expect that these expressions will serve as versatile tools in the modeling of optical and spectral effects that occur in the AlGaAs/GaAs heterostructures. The simulation results and discussions in this chapter help design the delta modulation doped 61 heterostucture part of the devices used for short haul and long haul communications in Chapter 4 and characterize the electronic properties of those optoelectronics devices. 3.1 Introduction The successful use of uniformly modulation-doped field-effect transistors (U- MODFETs) in the design of high-speed devices in optoelectronic applications has been limited by the occurrence of persistent photoconductivity [63], threshold voltage shift [64], and collapse of voltage characteristics [65] due largely to effects caused by DX centers and surface states. Using a delta (δ) doping technique as an alternative choice for selectively doped heterostructure transistors results in the optimization of its electronic properties. Experiments show that delta modulation doped MODFET’s provide high channel electron density, reduced trapping effects, and improved threshold voltage as well as high breakdown characteristics [55 - 59]. Extensive exploitation of modulationdoped heterostructure in the novel high speed devices has motivated the development of theoretical expressions that reveal and help in understanding the underlying device physics [58, 59, 66 - 71]. Although the advantages of the delta modulation doped devices over the uniformly modulation doped devices have been shown experimentally, much more attention has been paid to the latter structure than the former in detailed theoretical investigations. Specifically, a simplified analytical tool has been used for carrying out most calculations in terms of sheet carrier density (nso) level in uniformly modulationdoped heterostructure, which is a closed form expression [69, 72, 73]. Also, it is possible 62 to use the results given by this expression to produce a description of the electric field profile through the application of Gauss’s Law [74]. Recent experimental results show that strong built-in electric fields produced by modulation-doped heterostructures aid in the collection photo-generated carriers [54]. Photoreflectance (PR) and electroreflectance (ER) studies of modulation-doped heterostructures also show that the electric fields change the electric and optical properties of semiconductor microstructures [104]. The objective of this chapter is to develop a simplified analytical tool for delta modulation-doped heterostructures, which helps in understanding its electronic behavior and the underlying device physics, in the form of a closed-form expression. The model includes the effects of real-space charge transfer and carrier degeneracy. The real-space electron transfer and quasi-equilibrium condition in growth direction are used as two identities to describe 2DEG sheet charge density as only a function of material parameters and constants. An empirical constant corresponding to quantized energy states has been employed in order to simplify the functions and to arrive at a closed form description [73]. We calculate sheet charge density variation with delta doping concentration and electric field profile variation with distance from the interface by using this method. Also, a comparison between sheet charge density and electric field profile for different structures is made by using this simplified analytical tool and a much more complex variational method that is based on simultaneous solution of the Schrödinger and Poisson equations [105]. 63 3.2 Closed-form Expression for Delta Doped Modulation Heterostructures The conduction band diagram of the delta modulation doped heterostructure is shown in Fig.3.1. If no parallel conduction occurs in the AlGaAs layers, then the Fermi level is at or below the bottom of the conduction band in the whole AlGaAs region, i.e., E f ≤ EC for the delta-doped heterostructure. The free electron concentration can be written using Boltzmann statistics as n( z ) = N c exp(qVδ / kT ) (3.1) where Nc is conduction band effective density of states and Vδ is as indicated as in Fig.3.1. The space charge density ρ(z) in AlGaAs delta doped region is given by ρ ( z ) = q[ N d + ( z ) − n( z )] (3.2) where N d + ( z) = Nd 1 + g n exp[( E d + qVδ ) / kT ] (3.3) is the concentration of the ionized donors. Here, Nd is the total donor impurity concentration in the delta doped region, gn is the degeneracy factor of the donor level, Ed is the donor activation energy, k is the Boltzmann constant, and T is the lattice temperature. The difference of energy levels between the conduction band and Fermi level ( qVδ = E f − EC ) in the delta-doped region can be assumed to be constant due to its confinement to a small region, even though a large electric field exists there. 64 EC EGaAs(z) EAlGaAs(z) -qVδ Ef Z Eo δ-doping AlGaAs spacer layer AlGaAs top layer GaAs absorption layer Zs Figure 3. 1 Schematic heterojunction. diagram of conduction band of a modulation doped The amount of electron transfer across the interface is found by ignoring the effect of AlGaAs surface states and equating the electrons depleted from AlGaAs deltadoped region with the electrons accumulated in the triangular potential well of GaAs, hence n so Nd qV = − N c exp( δ kT 1 + g exp( E d + qVδ ) n kT ) Z d (3.4) where nso is sheet charge density in the quantum well and Zd is the thickness of delta doped region. Rearranging this relation produces a quadratic equation in terms of exp(qVδ / kT ) , whose meaningful root is then calculated to yield 65 exp( qVδ )= kT n − so g n' + N c + Zd 2 n so ' n g n + N c − 4 g n' N c so − N d Zd Zd (3.5) ' 2g n N c where g n' = g n exp( E d / kT ) . Using Taylor series expansion and retaining the first two terms, i.e. assuming Vδ << kT / q , this equation can be simplified to qVδ kT = n − so g n' + N c + Zd 2 nso ' n g n + N c − 4 g n' N c so − N d Zd Zd − 1 (3.6) ' 2 gn Nc The assumption leading to Eq. (3.6) implies that the conduction band in AlGaAs at the point of δ-doping is above the Fermi level but by less than a kT. This is a valid assumption since if it is below Ef, (Vδ >0) then there is large parasitic conduction in AlGaAs due to a large number of mobile electrons. On the other hand, if − qVδ = −( E f − EC ) is much greater than kT, it indicates that a small number of dopants are ionized, hence the number of carriers that are transferred to GaAs is small, or mobile charge density in GaAs quantum well is low. So, in fact the assumption of Vδ =0, indicates that about half of the donors are ionized and transferred to GaAs which is a rule of thumb often used by expitaxial growers to relate delta doping concentration to the 2DEG mobile carrier density. Equation (3.6) establishes a relationship between Vδ and nso; a second identity can be drawn from the energy band diagram of Fig.3.1 given that the Fermi level is constant due to equilibrium in Z-direction − qVδ + qE AlGaAs Z s − ∆EC + ( E f − Eo ) = 0 (3.7) 66 where EAlGaAs is the electric field in the spacer region, Zs is the thickness of the spacer layer, ∆EC is the magnitude of the conduction band discontinuity and Eo is the conduction band at the interface in the narrow gap material, taken as a point of reference for energy. The second term in this equation is the potential change in the spacer region. The electric field value in the spacer region can be readily obtained from sheet carrier density level using Gauss’s law and continuity of displacement vector as E AlGaAs = qn so ε AlGaAs , (3.8) where ε AlGaAs is the complex dielectric permittivity of AlGaAs material. The last term in Eq.(3.7) can also be derived in terms of GaAs sheet charge density nso in the form E f − Eo = kT / q × ln( f (n so )) [69, 72], but this exact formulation still requires empirical constants corresponding to the 1st and 2nd quantized states. Instead a linear approximation is often employed which offers great accuracy for depletion type devices, (i.e., large sheet charge density) and lends itself to mathematical manipulating [73] E f − Eo q = bn so + ∆E Fo , q (3.9) Here, b and ∆EFo are fitting parameters that are found by simple optimization methods. In fact, ∆EFo is 0 eV at 300°K and 0.025 eV at 77K and can be ignored. Substituting Eq.(3.6), Eq.(3.8), and Eq.(3.9) in Eq.(3.7) results in a quadratic equation in terms of nso which can be solved to yield nso = where − B + B 2 − 4 AC 2A (3.10) 67 qZ s kT / q A = b + +2 ε AlGaAs 2N c Z d qZ s b + ε AlGaAs , qZ s kT + ∆E Fo − ∆EC kT / q kT / q + B = 2 b + + ε AlGaAs 2 N c Z d q E 2 g n exp d kT kT / q kT / q + 2N c Z d E g n exp d kT , and 2 kT + ∆E Fo − ∆EC C = q kT + ∆E Fo − ∆EC kT / q + q g exp E d n kT Nd − (kT / q ) 2 E g n exp d N c kT Equation (3.10) is in terms of material parameters and constants. The only fitting parameter is the constant b which is obtained by simple optimization methods to be 0.090, 0.095 and 0.100x10-16 Vm2 for, respectively, spacer layer thicknesses of Zs = 50, 70, and 100 Å. An important advantage of having a closed form relation for sheet charge density is that other structure characteristics, such as the electric field in the direction of growth may also be obtained, as discussed next. 68 3.3 Closed-form Model of Electric Field and Potential The electric field strength in the GaAs side of the heterointerface is given by EGaAs ( z = 0) = Eint = qn so ε GaAs (3.11) This value becomes a boundary condition for determining the entire electric field profile inside the GaAs layer. Derivation of the electric field is significantly simplified by the band bending analysis of Si − SiO 2 interfaces, where similar inversion conditions to those in AlGaAs/GaAs heterostructures have produced a model of the potential profile of the form [74]. U GaAs ( z , n so ) = 2kT qEint z ln1 + 2kT q (3.12) From this analytical conduction band model, the electric field profile is obtained directly from Poisson’s equation EGaAs ( z , n s 0 ) = 2kT × Eint ∂U = ∂z 2kT + qEint z (3.13) The electric field profile of Eq.(3.13) is a function of the spatial position Z and of the sheet carrier density in the form of the interface field strength. Usefulness of expressions Eq.(3.10), Eq.(3.12) and Eq.(3.13) is evident in describing the sheet charge density, potential and electric field variation in the direction of growth, their accuracy, however, needs to be established in comparison with other modeling techniques. The choice of numerical simulation techniques is between commercial packages or a solution of Schrödinger and Poisson equations. The latter in its 69 brute force form is very computationally intensive. In what follows we describe a numerical model based on self-consistent solution of a modified Schrödinger and Poisson equations and then compare numerical results with our closed form analytical description. 3.4 Numerical Model Based on Schrödinger and Poisson Equations A more rigorous requirement for modeling heterojunctions is incorporation of quantization effects and solution of the wave function in the quantum well of the narrow bandgap material. The most accurate method is to use a full numerical model that may solve in a self-consistent manner the Schrödinger and Poisson equations [106, 107]. An alternative approach to the full numerical calculation is the use of variational techniques [108], which can then be incorporated into more complicated models. In this section we provide a modified self-consistent solution of Schrödinger and Poisson equations to verify the closed-form analytical description developed above. This method starts by assuming a form for Eigen functions. Then, applying boundary conditions on this wave function and its derivative, as well as its orthonormalization, reduces the number of the unknown coefficients. The program iteratively and self consistently solves the Poisson equation with this form of the wave function in Schrödinger equation to determine the remaining parameters. The potential well created in the AlGaAs/GaAs interface is relatively narrow [106], [109], therefore, it is sufficient only to consider the first two bound states. For the ground and the first excited energy levels, a convenient form of the wave function that 70 captures both spatial confinement and exponential decay characteristics can be written [110], for GaAs side (z>0) as: Ψ 1 ( z ) = C1 X 1 ( X 1 z + C 2 ) exp(− X1z ) 2 Ψ 2 ( z ) = X 2 (C 4 + C5 z + C 6 z 2 ) exp(− (3.14) X2z ) 2 (3.15) And for AlGaAs side (z<0): Ψ 1 ( z ) = C 3 X 3 exp( X3z ) 2 (3.16) Ψ 2 ( z ) = C 7 X 4 exp( X4z ) 2 (3.17) where C1-7 and X1-4 are 11 parameters that depend on the structure and are determined as follows. The wave functions described by Eq.(3.14) – Eq.(3.17) and their derivatives should be continuous at the interface. This, in addition to orthonormality conditions for Ψ1(z) and Ψ2(z) are used to reduce the number of variation parameters from 11 to 4, which only include X1-4. Further constraints are set on the Eigen values and Eigen functions by noting that the lower the total energy of the system is, the more stable it is. This is achieved by minimizing Ei = ∞ ∫ Ψi ( z ) H Ψi ( z )dz (3.18) −∞ where H is the Hamiltonian operator and Ei is the ith energy level with respect to the Fermi level. Electric potential V(z) is obtained from the Poisson equation: 71 ∂ 2V ( z ) ∂z 2 =− q ε GaAs [− N a − 2 + p − n1 ( z )Ψ 1 ( z ) − n2 ( z )Ψ 2 ( z ) 2 ] (3.19) where qE ni ( z ) = N 2 D ln 1 + exp i kT i=1,2 (3.20) and N 2 D = m*kT / πh 2 is the 2D density of states. Poisson equations in other regions are the same as the conventional description without quantum effects. An iterative solution of the Schrödinger equation with this particular form of the wave function, and Poisson equation with the same potential allows a self-consistent description. The calculation program is based on a shooting method described in [105]. As a result the static potential, electric field, and wave functions as well as electron distribution are determined. 3.5 Calculation Scheme for Numerical Model Based on Schrödinger and Poisson Equations Figure 3.2 shows the calculation scheme used for the modified self-consistent solution based on Schrödinger and Poisson equations. The calculation starts at the GaAs buffer side. Since it is under the equilibrium condition, the static potential V and the electric field E are approaching zero. The static potential is fixed at almost zero and the electric field E is the free parameter at the starting point. Then, Runge-Kutta method is used to solve the second order differential equations, which are the normal Poission equations in all the regions except the triangular 72 well, where Schrödinger equations are used to calculate the two dimensional electron densities. Initialization Set initial E at the GaAs buffer layer Calculations into the surface Minimization of <E1> Use updated X1-4 parameters Calculation of n1 Minimization of <E2> Calculation of n2 No Modify shooting E at the GaAs buffer layer <E1>+<E2> converge ? Yes Desired V at the AlGaAs surface ? No Stop Figure 3. 2 Flow chart diagram of computer program. E is electric filed, E1 and E2 are two energy level, n1 and n2 are 2DEG concentration at E1 and E2, respectively, V is static potential. 73 A downhill simplex method in multidimensions [111] is used to minimize the energy level, thus to achieve the four reasonable parameters in the two wave functions. The downhill simplex method is due to Nelder and Mead [112]. The method requires only function evaluations, not derivations. It is not very efficient in terms of the number of function evaluations that it requires. However, the downhill simplex method may frequently be the best method to use if the figure of merit is “get something working quickly” for a problem whose computational burden is small. If the static potential V at the AlGaAs surface is the desired value, the program will stop. Otherwise, the shooting method will find the adjustment of the free parameters at the starting point that zeros the discrepancies at the other AlGaAs surface. 3.6 Results and Discussion The AlGaAs/GaAs heterostructure used in the simulations is illustrated in Fig. 3.3. The structure consists of unintentionally doped (n-type 8x1014 cm-3) top Al0.24Ga0.76As layer, which is used to increase Schottky barrier and to lower the leakage current, a 20Å delta modulation doped n+-Al0.24Ga0.76As layer, and an undoped AlGaAs spacer layer followed by unintentionally doped (p-type 1014 cm-3) GaAs layer. Thus, the delta-doped layer is placed between the unintentionally doped Al0.24Ga0.76As layer and Al0.24Ga0.76As spacer layers. 74 500 Å n-(6~8*1014cm-3) Al0.24Ga0.76As barrier δ-doped layer Zd=20Å 50~100 Å undoped Al0.24Ga0.76As spacer p- 1014cm-3 background doped GaAs Figure 3. 3 Schematic diagram of delta-doped AlGaAs/GaAs heterostructure. Figure 3.4 demonstrates the effect of the approximations performed in order to derive a closed form formula for 2DEG sheet carrier density nso. Two plots are compared for three spacer layer thicknesses; in one Eq.(3.5), which is an exponential function, is iteratively solved with Eq.(3.7) while in the second case it is linearized to yield Eq.(3.6) which then leads to the closed form Eq.(3.10). It is observed that the two techniques yield similar results especially when delta doping concentration is beyond 1013 cm-2 and when spacer layer is thin, i.e., when the 2DEG density is high. However, for smaller values of doping, replacing exp(qVδ / kT ) with 1 + qVδ / kT is not a very good approximation. This indicates that Eq.(3.10) is most valid when the conduction band of the delta doped region is above but in the vicinity of the Fermi level; a condition that is almost always met for depletion type devices. 75 12 -2 Sheet Charge Density (cm) 1.8x10 closed-form expression without using equation (3.6) approximation 12 1.6x10 50 Å 12 1.4x10 70 Å 12 1.2x10 12 100 Å 1.0x10 11 8.0x10 12 4.0x10 12 8.0x10 13 1.2x10 13 1.6x10 13 2.0x10 -2 Delta Doping Concentration (cm ) Figure 3. 4 Simulation of nso against AlGaAs delta doping concentration at 300K for various spacer layer thickness. In order to check the accuracy of the closed-form expression, it is compared in Fig. 3.5 with the numerical model based on modified Schrödinger and Poisson equations for various spacer layer thicknesses. Results of iterative solutions of Eq.(3.5) and Eq.(3.7) are also shown in that figure. It is observed that the closed-form expression provides a description that for a populated triangular well closely matches the much more involved numerical method based on solution of Schrödinger and Poisson equations. It needs to be repeated that the closed form expression requires one fitting parameter that has to be determined for each spacer layer thickness, the values of which for 50, 70 and 100 Å thicknesses were given earlier. 76 12 -2 Sheet Charge Density (cm) 1.8x10 12 1.6x10 modified Schrodinger and Poission model without using equation (3.6) approximation closed-form expression 50 Å 12 1.4x10 70 Å 12 1.2x10 100 Å 12 1.0x10 11 8.0x10 12 4.0x10 12 8.0x10 13 1.2x10 13 1.6x10 13 2.0x10 -2 Delta Doping Concentration (cm ) Figure 3. 5 Simulation of nso against AlGaAs delta doping concentration at 300K for various spacer layer thickness. Also shown are numerical results of analytical expressions for nso. In addition to the sheet charge density distribution, the electric field profile in the narrowband material can also be analytically derived as given in Eq.(3.13). That expression, with the same linearization factor used for Fig.3.5, is plotted in comparison to the field derived from numerical solution of Schrödinger and Poisson equations in Fig.3.6. The volume delta doping concentration is 5x1019 cm-3 and the thickness of the donor plane is 20 Å, which corresponds to an areal doping concentration of 1013 cm-2. It is seen that the electric field strength at the heterointerface is closely modeled by the closed-form expression. Also, away from the interface when the field reaches values that 77 are mainly due to background doping, the analytical and numerical solutions are identical. However, discrepancy exists between analytical and numerical values in the vicinity of the interface and up to about 60 Å toward the substrate. This discrepancy is partly due to ignoring background doping concentration, or bulk charges, when relating the field to the charge by Gauss’s law in Eq.(3.11). Nevertheless, it is seen from this comparison that the analytical expression compares well with much more involved E lectric Field (V /cm ) numerical modeling methods. 2.5x10 5 2.0x10 5 1.5x10 5 modified Schrodinger and Poission model 50 Å closed-form expression 70 Å 100 Å 1.0x10 5 5.0x10 4 0.0 -1 10 0 1 2 3 10 10 10 10 Distance from the interface (Å) 10 4 Figure 3. 6 Comparison of electric field strength profile by using Eq. (3.13) and modified Shrödinger and Poisson model 300K for various spacer layer thickness. 78 3.7 Conclusions The benefits of using delta modulation doped AlGaAs/GaAs heterostructure in the design of devices is mainly derived from the ability to remove the limitation for the uniformly modulation doped heterostructure, such as the occurrence of persistent photoconductivity, threshold voltage shift, and collapse of voltage characteristics, to produce high performance systems. Novel HEMT and other optoelectronic devices use delta doped heterostructures to garner the benefits in sensitivity, speed, and efficiency that arise from the presence of channel confinement and a strong electric field in the absorption layer. For the purpose of studying these effects, a closed-form analytical expression for describing sheet charge density in the delta modulation doped heterostructure has been developed to help the design and analyze the physical mechanism underlying the device behavior. This expression was shown to follow closely the behavior of the numerical simulations based on much more involved methods using a self-consistent solution of Schrödinger and Poisson equations. Versatility of the developed analytical expression was shown by deriving the electric field profile and showing that outside a region of about 50Å it matched closely with numerical simulation results. In addition to their use in modeling of current conduction in HEMT devices, we expect that these expressions would serve as versatile tools in the modeling of optical and spectral effects that occur in the AlGaAs/GaAs heterostructures. 79 4. III-V Material based Doped HMSM Photodetector Design with Resonant Cavity for Optical Communications III-V material based resonant-cavity-enhanced, heterostructure metal- semiconductor-metal photodetector designs are presented in this chapter. One is GaAsbased design for short haul optical communication; the other is InP based design for long haul optical communication. The GaAs based photodetector utilizes a Al0.24Ga0.76As/ Al0.9Ga0.1As distributed Bragg reflector (DBR) operating around 0.85 µm; while the InP based photodetector employs a In0.527Al0.144Ga0.329As/ InP (DBR) operating around 1.55 µm. The simulation results show clear peaks at 0.85 µm with a 30 nm full width at half maximum (FWHM) and 1.55 µm with a 0.1 µm FWHM for GaAs based and InP based photodetectors, respectively. At the resonance wavelength, a several-fold and a 3.5 fold increase can be achieved in quantum efficiency compared to a detector of the same absorption depth in GaAs and InP based designs respectively. The top reflector is a delta modulation doped wide band gap material that also acts as the barrier enhancement layer thus providing very low dark current values. Based on the simulation results and discussions of the optical and electrical properties of the device, an optimization including wavelength selectivity, optical sensitivity, quantum efficiency, and dynamic speed will be considered during the design. Combination of low dark current, fast response, wavelength selectivity, and compatibility with high electron mobility transistors makes these devices especially suitable for optical communications purposes. The characteristic performance of GaAs based devices is discussed in the next chapter. 80 4.1 Introduction Vertical cavity surface emitting lasers (VCSEL) emitting at 850 nm [113] have been a preferred source for high-speed short-haul communication systems. These VCSELs are particularly suitable for local area networks (LAN) using multimode optical fibers (MMF) with typical core diameters of 50 and 62.5 µm. The circular output beam of the VCSELs allows for easy coupling of light into the MMF. It is also desirable to have photodetectors with large active windows compatible with MMF for low cost coupling of light at the receiving end. Furthermore, high sensitivity and high bandwidth are also necessary attributes for photodetectors used in optical communication applications. As VCSELs with modulation rates approaching 10 Gb/s become commercially available [114], compatible high speed performance is required from photodetectors. The two major speed-limiting factors in vertically illuminated photodiodes are the depletion capacitance and the transit time [3]. The capacitance limit can be alleviated either by employing smaller device areas or by increasing the depletion width, thereby decreasing the capacitance per unit area. However, an increased depletion width consequently increases the transit time. Utilization of a thin absorption layer at an optimized position within the depletion region can further improve the transit-time-limited bandwidth of conventional photodiodes. The reduction in quantum efficiency resulting from a thin absorption layer can be compensated for by using resonant cavity enhanced (RCE) detection. In addition to their important application in vertical cavity surface emitting lasers (VCSEL’s), resonant cavities (RC’s) have been exploited in the design of vertical photodetectors, 81 such as p-i-n heterojunction photodiodes, Schottky barrier internal emission photodiodes, and quantum well infrared photodetectors [80 - 82]. Resonant-cavity-enhanced (RCE) photodetectors have attracted attention in the past few years due to their potential in solving the trade off between high quantum efficiency and high speed while, at the same time, offering narrow spectral bandwidth detection useful in wavelength-division multiplexing (WDM) applications [25]. On the other hand, the growing interest in mobile communication by wireless links to the data highway has led to the concept of fiber-fed transceiver cells utilizing microwave photonics. Millimeter-wave fiber-radio systems have attracted special interest [115]. As a high-speed optical receiver for these systems, monolithic receiver optoelectronic integrated circuits (OEICs) are attractive due to their potential for highspeed operation, compactness, and cost reduction. The trend towards monolithic OEIC motivates appreciable research activity directed towards the employment of planar photodetectors, which can be easily fabricated and are compatible with the FET process. Planar metal-semiconductor-metal photodetectors (MSM-PD’s) are good candidates for such OEIC receivers [16, 17]. The FET technology itself is strongly affected by progress in heterojunction-based devices that take advantage of the reduced dimensionality regime of conduction; the high electron mobility transistor (HEMT) being a prime example. This has motivated the development of heterojunction based photodetectors that enjoy better conduction while being compatible with HEMT technology [16]. In particular, we have previously proposed AlGaAs/GaAs heterostructure metal-semiconductor-metal photodetectors (HMSM-PD’s) that show much less dark current than conventional MSM 82 due to both the two dimensional electron gas (2DEG) and the barrier enhancement effect due to the wide-gap material [52 - 54]. A common problem with planar, as well as vertical, photodetectors is the trade-off between speed and quantum efficiency; in order to achieve a fast response from photodetectors, the depleted absorption region needs to be small for reduced path length, but it results in a decreased responsivity due to small absorption depth. Resonant cavity technique offers the possibility to balance such conflict between fast speed and sensitivity [75]. Also, the main drawback of MSM-PD’s is their low responsivity due to the metal showing effect. Resonant-cavity photodetector (RCE-PDs) have been demonstrated to be an attractive design to achieve high quantum efficiency while using a thin absorbing layer [116, 117]. Schottky barrier height and band-edge discontinuities play an important role in the behavior of heterojunction devices by strongly affecting current transport [52, 53, 118, 119]. Several techniques have been proposed to modulate the Schottky barrier height, heterojunction barrier height and band-edge discontinuities including: tuning of the conduction and valence-band barrier heights at an abrupt intrinsic semiconductorsemiconductor heterojunction via incorporation of a doping interface dipole [120]; controlling the effective Schottky barrier height over a wide range using highly doped surface layers [121]; increasing the barrier height due to energy quantization of confined electrons [122]; and increasing Schottky contact through the electron-electron cloud effect in the modulation-doped heterostructures [54]. The last effect is particularly relevant in the present work. The electron cloud that is formed in the narrow gap material of a heterojunction exerts a repulsive force on the 83 electrons that are emitted from the metal to the wide gap material, thus decreasing the dark current. It also influences absorption of the optically generated carriers though a field-induced change in the index of refraction, a change similar to the Franz-Keldysh effect [123]. Two different techniques of uniform doping or delta doping of the wide-gap material have been employed in order to form such an electron cloud in modulation doped field-effect transistors (MODFET). Delta doping is a better candidate than uniformly doping in the modulation doped heterojunction devices due to the optimization of its electronic properties as mentioned in Chapter 3. A transmission line model has been employed to design the resonant cavity and the distributed Bragg reflector (DBR) that forms the bottom mirror, which exposes how the parameters are calculated to optimize the quantum efficiency of the overall structure [101]. Also, a variational method and a newly developed closed-form expression as described in Chapter 3 are used to calculate the electric field profile [105,124] in the device. 4.2 Material Selection The development of heterostructure science and technology is largely influenced by the availability of suitable substrates and the need from industrial applications. Among III-V compounds, the ternary (GaAl)As system lattice-matched to GaAs substrated and quaternary (GaIn)(AsP) and (Al,Ga,In)As systems lattice-matched to InP substrate have been extensively studied, the former for short haul fiber optic communications and the 84 latter for long haul fiber optic communications for reasons enumerated in Chapter 1 and Chapter 2. 4.2.1 III-V material parameters’ calculation The process involved in making a ternary III-V material is much easier and also cheaper than that of a quaternary material. InAs and AlAs are the materials to be considered to make a ternary material with GaAs. AlAs is the best choice due to its larger bandgap (Table 4.1), which can make a new wider bandgap ternary material, thus enhancing the Schottky barrier between metal and GaAs. The quaternary (GaIn)(AsP) and (Al,Ga,In)As systems lattice-matched to InP substrate have been employed for long haul fiber optic communications. The absorption materials, the barrier enhancement layer material, quarter wave stack pair materials are selected based on this quaternary (GaIn)(AsP) and (Al,Ga,In)As systems. Table 4. 1 Lattice constant, gap energy, and electron affinity for a selected number of III-V binary compounds [125] [126]. Compound Lattice Constant (Å) AlP 5.451 AlAs 5.6605 AlSb 6.1355 GaP 5.45117 GaAs 5.65325 GaSb 6.09593 InP 5.86875 InAs 6.0585 InSb 6.47937 Gap (eV) Energy at 300 K 2.45 2.163 1.58 2.261 1.424 0.726 1.351 0.360 0.172 Eχ Eχ Eχ Eχ EΓ EΓ EΓ EΓ EΓ Electron affinity (eV) (3.5) [125] 3.64 4.0 4.05 (4.07) [126] 4.03 (4.06) [126] 4.4 4.54 (4.90) [126] 4.59 (4.59) [126] 85 4.2.1.1 Ternary (GaAl)As system The material must be lattice matched to the GaAs substrate. Assuming a linear dependence of lattice constant a on composition, the lattice-matching condition is a1 (1 − x) + a 2 x = a3 (4.1) where a1 is the lattice constant for GaAs, a2 is that of AlAs, and x is the percentage of Al composition. And a3 is that of new ternary material AlxGa1-xAs. If we again assume a linear relation between the energy gap, the energy gap of the ternary is given by E1 (1 − x) + E 2 x = E3 (4.2) where E1 is the energy gap for GaAs, E2 is the energy gap for AlAs, and the definition of x is Al mole fraction. And E3 is the energy gap for new ternary material AlxGa1-xAs. While GaAs is a direct-gap semiconductor, AlAs is an indirect gap semiconductor. In AlxGa1-xAs the transition from direct to indirect gap occurs at x=0.45 with E g = E (Γ6 ) − E (Γg ) varying as E g = 1.424 + 1.247 x (4.3) in the direct gap region and with E g = E ( X 6 ) − E (Γg ) varying as E g = 1.985 + 1.147( x − 0.45) 2 (4.4) in the indirect gap region. Therefore, a gap discontinuity exists at the AlxGa1-xAs and GaAs interface. There are two different methods to calculate the band gap discontinuity, which can be computed by using the following explanation. 86 One physical quantity commonly used in constructing the energy band diagram at a semiconductor-metal interface is electron affinity χe. For AlxGa1-xAs, the quantity varies with composition as χ e = 4.07 − 1.06 x (4.5) in the direct gap region (x < 0.45), and as χ e = 3.64 − 0.14 x (4.6) in the indirect gap region (0.45 <x <1.0). Figure 4.1 shows conduction band edge EC in GaAs and AlxGa1-xAs relative to vacuum level. A conduction band discontinuity ∆EC can be expected to behave according to the following expression: ∆EC = χ1 − χ 2 = 1.06 x (4.7) where x is less than 0.45. The results on capacitance-voltage C-V and current densityvoltage J-V measurements in heterojunction, however, yield the following empirical relation [127-129]: ∆EC = 0.60∆E g (4.8) Another relevant property is the dielectric constant εAlGaAs which for AlxGa1-xAs is given by ε AlGaAs = (13.1 − 3.0 x)ε 0 (4.9) 87 Vaccum level χ2 χ1 Ec2 ∆Ec Ec1 Figure 4. 1 Energy band diagrams showing existence of a conduction-band-edge discontinuity at interface between semiconductors with different values of electron affinity. Table 4.2 lists parameters of the AlxGa1-xAs ternary materials, which have been calculated by using the above formulae (4.1-4.9). The linear dependence on the composition has been used in most cases Eq.(4.1) and (4.2). The refractive index is the square root of relative dielectric constant. Table 4. 2 Compound GaAs AlAs Al0.24Ga0.76As Al0.2Ga0.8As Al0.15Ga0.85As Al0.9Ga0.1As Al0.35Ga0.65As AlxGa1-xAs material information. Lattice Constant (Å) 5.6533 5.661 5.6551 5.6548 5.6545 5.6602 5.6560 Gap (eV) 1.424 2.168 1.7233 1.6734 1.6111 2.1283 1.8605 Gap (µm) 0.871 0.572 0.720 0.741 0.770 0.583 0.667 ∆EC (eV) Eq 4.8 0.000 0.496 0.200 0.166 0.125 0.470 0.291 Affinity (eV) 4.07 3.5 3.816 3.858 3.911 3.514 3.699 ∆EC (eV) Eq 4.7 0.000 0.570 0.254 0.212 0.159 0.556 0.371 Dielectric constant (0.83 µm) 13.455 9.053 12.127 12.337 12.636 9.419 11.609 λ/(4n) at 0.83 µm (nm) 56.57 68.97 59.59 59.08 58.37 67.61 60.90 88 4.2.1.2 Quaternary (GaIn)(AsP) and (Al,Ga,In)As systems Table 4.3 shows the material parameters of the quaternary (GaIn)(AsP) and (Al,Ga,In)As systems lattice-matched to InP substrate. Table 4. 3 Material parameters of quaternary (GaIn)(AsP) and (Al,Ga,In)As systems. Compound AlAs GaAs InP InAs GaP In0.53Ga0.47As In0.52Al0.48As (In0.53Ga0.47As)0.5 (In0.52Al0.48As)0.5 (In0.53Ga0.47As)0.6 (In0.52Al0.48As)0.4 (In0.53Ga0.47As)0.7 (In0.52Al0.48As)0.3 (In0.53Ga0.47As)0.44 (InP)0.56 Lattice Constant (Å) 5.660 5.653 5.869 6.058 5.451 5.868 5.867 Gap (eV) Barrier (eV) 2.153 1.420 1.350 0.360 2.740 0.752 1.457 0.841 0.401 0.359 -0.235 1.193 0.000 0.423 Dielectric constant (1.55 µm) 8.237 11.364 10.037 12.388 9.322 12.469 10.243 5.868 1.055 0.182 11.156 3.340 116.014 5.868 0.988 0.142 11.395 3.376 114.791 5.868 0.925 0.104 11.693 3.420 113.318 5.868 1.038 0.172 10.659 3.265 118.690 Refractive Index (1.55 µm) 2.870 3.371 3.168 3.520 3.053 3.531 3.200 λ/(4n) at 1.55 µm (nm) 135.016 114.949 122.312 110.095 126.916 109.738 121.075 To calculate the energy band gap of the ternary and quaternary materials, data from Science and Technology has been used as a reference [130]. Based on the information given in this reference, energy band gaps of the ternary materials in the above table have been calculated by using the following formula: E g (In1-x Ga x As) = 0.36 + 0.629 x + 0.436 x 2 (4.10) E g (In1-x Al x As) = 0.37 + 1.91x + 0.74 x 2 (4.11) and respectively; x is the mole fraction of the Ga in InGaAs and the Al in InAlAs ternary materials. 89 The energy band gap of the (In0.53Ga0.47As)1-z(In0.52Al0.48As)z quaternary materials is calculated from E g ((In 0.52 Al 0.48 As) z (In 0.53 Ga 0.47 As)1-z ) = 0.76 + 0.49 z + 0.20 z 2 (4.12), where z is the mole fraction of (In0.52Al0.48As) in (In0.53Ga0.47As)1-z(In0.52Al0.48As)z. Another quaternary material of importance, (In0.53Ga0.47As)z(InP)1-z, latticematches to the InP substrate, and the formula to calculate its energy band gap is E g ((In 0.53 Ga 0.47 As) z (InP)1-z ) = 1.35 - 0.775 z + 0.149 z 2 (4.13) where z is the composition of (In0.53Ga0.47As) in (In0.53Ga0.47As)z(InP)1-z. 4.2.2 Absorption layer 4.2.2.1 Absorption materials for 800-900 nm optical window For fiber optic communication operating in the 800-900 nm optical window, GaAs and Si are the best candidates for the active region material, which can be seen in Fig. 1.10. Table 4.4 summarizes the relevant optical and electrical characteristics of GaAs and Si [131]. Table 4. 4 Optical and electrical characteristics of GaAs and Si. Material Mobility (cm2/(V.s)) Energy band gap (eV) Interface state density (cm-2) Passivation Layer Processing Si 1350 1.12 (indirect) <1010 MOS Mature and low cost GaAs 8600 1.42 (1.35) (direct) >1012 / Not so mature and high cost 90 It can be seen from the above table, as a natural microelectronic material, Si integrated circuit processing is much more mature than that of GaAs. When used for making optoelectronic device, however its importance has been limited by speed, due to low mobility, and quantum efficiency, due to its indirect bandgap. GaAs as another standard integrated circuit processing material plays an important role in fiber optic communication. Therefore, GaAs is used as the active region material in the following design. 4.2.2.2 Absorption materials for 1550 nm optical window For fiber optic communication operating in the 1550 nm optical window, InGaAs and Ge are the best candidates for the active region material, which can be seen in Fig. 1.10. The former is III-V material and the latter is IV material. Table 4. 5 Optical and electrical characteristics of In0.53Ga0.47As and Ge Material Electron Mobility (cm2/(V.s)) Hole Mobility (cm2/(V.s)) Energy band gap (eV) Ge 3900 800 0.664 (indirect) / 0.805 (direct) In0.53Ga0.47As 13800 (LPE) 11200 (MOCVD) 0.75 While Ge photodiodes were the components of choice for the earlier fiber transmission at 1.3 µm, their degraded performance at 1.55 µm and the development of InP-based optoelectronic technology have lead In0.53Ga0.47As photodiodes to be the best choice for meeting most demands of long haul communications (long wavelength 91 transmission). Table 4.5 compares the optical and electrical characteristics of In0.53Ga0.47As and Ge. As can be seen from the table, the electron mobility of In0.53Ga0.47As is almost three times of that of Ge. In the manufacture of optoelectronic devices, Ge’s importance has been limited by low speed due to this low mobility. Also, time-division-multiplexed (TDM) optical transmission systems have been demonstrated at 40 Gb/s [132]. InP-based heterostructures have traditionally been utilized for the fabrication of photodetectors and integrated optoelectronic circuits (OEICs) operating at long wavelengths (1.55 µm) for optical fiber applications due to speed requirement. The In0.53Ga0.47As epi-layer absorbs photons in the regime of 1.0~1.6µm wavelength (Fig. 1.10) and also has a high electron mobility (~12,000cm2V-1S-1 at 300K) and high saturation velocity (~2.5x107cm/s) (Fig. 4.12), which make lattice-matched growth of In0.53Ga0.47As on an InP substrate of great promise for the absorption region in a photodetector and for the active channel in electronic devices used in wavelength 1.55µm and 1.3µm fiber bands in long haul communications [20, 34 - 40]. Therefore, In0.53Ga0.47As was selected as the active region material in the following design. 4.2.3 Barrier enhancement layer 4.2.3.1 Barrier enhancement layer for GaAs based photodetectors The barrier enhancement layer is the top layer of the entire structure. The top mirror is the interface between the barrier enhancement layer and air, which should reduce reflection from air and recirculate photons reflected by the bottom mirror. 92 Heterojunction based photodetectors enjoy better conduction due to a reduced dimensionality region. For this reason, it is advantageous to choose a material that creates a heterojunction with GaAs. There are four requirements for the barrier enhancement layer material. First, it should enhance the Schottky barrier between metal and GaAs; second, the bandgap discontinuity should be large enough to confine a two dimensional electron gas in the triangular well; third, the material must lattice match with GaAs, which removes the stress affecting the quality factor of the device; the last consideration is that the refractive index difference between this layer material and the air has to be reasonable in order to create a good resonant cavity. A 55 nm Al0.24Ga0.76As layer has been used which offers the following electronic properties. First, this layer lattice-matches to the absorption layer, with reduced DXcenter defect levels due to low Al mole fraction, while providing surface stability. Second, it enhances the Schottky barrier between metal and GaAs due to its larger bandgap. Third, this layer is delta-doped to produce a 2DEG that is confined to the vicinity of the heterojunction by the conduction band discontinuity of about 0.3 eV. The last is the most important feature of this device. The confined electronic states of the quantum well at the interface as well as the electron cloud of the 2DEG have been shown to further enhance the barrier height and reduce the dark current, and thus the noise of these detectors [133]. This electron cloud is confined by a vertical electric field that has also been shown to aid in transport of photoelectrons [54]. Finally, modulation doping of this layer makes the growth compatible with HEMT. This top AlGaAs layer is delta doped, rather than uniformly, in order to take advantage of high channel electron 93 density, reduced trapping effects, and improved threshold voltage as well as high breakdown characteristics [55-59]. The lattice mismatch for Al0.24Ga0.76As to the GaAs substrate is 0.032%. 4.2.3.2 Barrier enhancement layer for InP based photodetectors Four requirements for the barrier enhancement layer material should be the same as the described in the previous section. Table 4.6 lists the performance of the barrier enhancement layer structure above the In0.53Ga0.47As active layer based on current background. However, low Schottky barrier height (~0.2eV) on n- In0.53Ga0.47As causes excess leakage current when the contacts are formed directly with the material [85], preventing it from being further developed. Experimental results show that a latticematched material In0.52Al0.48As may serve as a barrier enhancement layer on the top of In0.53Ga0.47As to limit the leakage current to an acceptable value [86 - 88]. There are several research groups concentrating on such Schottky barrier photodiodes [134 - 136]. Table 4. 6 Performance of barrier enhancement layer structure above In0.53Ga0.47As active layer [85, 47, 134-136]. Barrier enhancement layer In0.52Al0.48As InGaP P+-In0.53Ga0.47As P+-InP Dark current < 1 pA/µm2 at 5V, < 25 pA/µm2 at 15V, < 300 pA/µm2 at 30V 1.6pA/µm2 at 10V < 0.1 ~ 1 nA/µm2 at 5V < 0.1 ~ 1 nA/µm2 at 10V Barrier height Al / In0.52Al0.48As: 0.8 eV Au / In0.52Al0.48As: 0.82 eV A 55 nm In0.52Al0.48As has been employed due to the following electronic properties. First, this layer lattice-matches to the absorption layer. Second, it enhances the 94 Schottky barrier between metal and In0.53Ga0.47As to limit the dark current to an acceptable level. Third, this layer is delta-doped to produce a 2DEG that is confined to the vicinity of the heterojunction by a conduction band discontinuity of about 0.42 eV. The lattice mismatch for In0.53Ga0.47As to the InP substrate is less than 0.017%. 4.2.4 Distributed Bragg reflector 4.2.4.1 DBR for GaAs based photodetectors A distributed Bragg reflector is composed of number of pairs of quarter wave stacks, which form the bottom mirror of a Fabry-Perot resonant cavity. From Eq.(2.14), the larger the reflection coefficient of the bottom mirror, R2, is, the larger is the quantum efficiency, which is demonstrated by simulation results in the next section. A large reflectivity of the bottom mirror is a necessary condition for good device performance. Equation (2.17) shows a large difference in characteristic impedance results in a large reflection coefficient, and therefore a large reflectivity. Equations (2.14) to (2.17) are used to compute the reflectivity for the light incident at the top of the bottom mirror. A pair of materials having large refractive contrast is the best choice to form the DBR; having a highly reflective bottom mirror while needing less pairs, decreases costs of the device. There are two further requirements for the materials. First, material with a band gap larger than the energy of the incident light has priority. If this is the case, the DBR material will not absorb the incident light, which means that no carriers are generated below the GaAs absorption region. This situation results in a short light path existing 95 within the structure. Therefore, the performance of the time response of the device is improved. Second, lattice-matched materials help prevent imperfections that might result from bonding process from affecting the quality-factor of the microcavity. Based on the material parameters shown in Table 4.2, Al0.24Ga0.76As and Al0.9Ga0.1As are suitable pairs to construct this DBR- mirror. The lattice mismatch for Al0.24Ga0.76As and Al0.9Ga0.1As to the GaAs substrate is 0.032% and 0.122% respectively. 4.2.4.2 DBR for InP based photodetectors The material for the DBR on the InP substructure must satisfy the same three requirements. First, a pair of materials having large refractive contrast is the best choice to form a DBR, which results in a low cost device to achieve the same functionality. Second, the material with a band gap larger than the energy of the incident light has priority to be selected, which helps decrease the length of the light path, and produce a faster device. Third, material must lattice-match to the substrate preventing imperfections in the bonding process from affecting the quality-factor of the microcavity. Based on the material parameters shown in Table 4.3, In0.527Al0.144Ga0.329As and InP are such suitable pairs. The lattice mismatch for In0.527Al0.144Ga0.329As to the InP substrate is 0.01%. 96 4.3 Selection of Structure Parameters The thickness of the barrier enhancement layer and the absorption layer, in turn, are determined by satisfying the optimization condition of the quantum efficiency cos(2( β1 L1 + β 2 L2 ) + Ψ1 + Ψ2 ) = 1 . For the DBR reflector, the thickness of each individual layer in the stacks is one quarter of the effective wavelength of the incident light, which can be expressed as (λ0/n). Here λ0 is the incident light wavelength in a vacuum and n is the refractive index of the material at the resonant frequency. This section will be arranged as follows: first, the growth technique will be described; then, the dispersion relation used in the theoretical simulation will be discussed; the number of the quarter wave stack pairs will be decided and the thickness of the absorption layer will be determined from the simulation results; finally, from the simulation results and discussion of the electric field profile along growth direction, the thickness of the spacer layer will be selected, thus the thickness of the barrier enhancement layer will be determined based on the resonant requirement cos(2( β1 L1 + β 2 L2 ) + Ψ1 + Ψ2 ) = 1 . 4.3.1 The grown RCE heterojunction MSM The schematic cross-sections of the grown RCE heterojunction MSM of GaAs based and InP based photodetectors are shown in Fig.4.2 and Fig.4.3 respectively. 97 4.3.1.1 GaAs based photodetector structures Figure 4.2 shows the schematic cross-section of GaAs based photodetectors with RCE heterojunction MSM. light 50 nm nid Al0.24Ga0.76As Barrier 5 nm nid Al0.24Ga0.76As Spacer 117.5nm undoped GaAs absorption layer (λ0/4n) undoped Al0.24Ga0.76As (59.6nm) (λ0/4n) undoped Al0.9Ga0.1As (67.6nm) Si δ-doping 5x1012 cm-2 DBR quarter wave stacks 200nm GaAs Buffer GaAs Substrate Device structure of GaAs based resonant-cavity-enhanced HMSM photodetector. Figure 4. 2 The layer structure was grown by solid-source molecular beam epitaxy on a semiinsulating GaAs substrate. Twenty-periods of the Al0.24Ga0.76As/Al0.9Ga0.1As DBR were grown on a 200 nm GaAs buffer layer. The thickness of the top barrier enhancement layer is 50 nm and the spacer layer is 5 nm, which separates the ionized donors and the electrons and removes the scattering effects in the 2DEG, thus increasing transport speed. A Si delta doping layer with sheet density of 5 x 1012cm-2 was grown between the barrier 98 enhancement and spacer layers due to its previously mentioned advantages [55 - 59]. The bottom mirror was designed for high reflectance at a 830 nm center wavelength. The thickness of the quarter-wave pair is one half of the effective wavelength, and therefore the thickness of each layer is one quarter of the effective wavelength (λ0/n). 4.3.1.2 InP based photodetector structures 40 nm n+(1.5*10^18 cm-3) GaAs cap 50 nm n-(6~8*1014cm-3) In0.52Al0.48As barrier 5 nm undoped In0.52Al0.48As spacer Si δ-doping 1013cm-2 385.8 nm undoped In0.53Ga0.47As absorption layer (λ/4n) Undoped InP (122.3nm) 20 periods (λ/4n) In0.527Al0.144Ga0.329As (113.3nm) 25nm InP:Fe Buffer InP Substrate Figure 4. 3 In0.52Al0.48As/In0.53Ga0.47As/InP HMSM RCE-PD schematic diagram. The In0.52Al0.48As/In0.53Ga0.47As/InP HMSM RCE-PD is illustrated in Fig.4.3. The layer structure was also grown by solid-source molecular beam epitaxy on a semiinsulating InP substrate. Fifteen-periods of the In0.53Ga0.47As/InP DBR were grown on a 25 nm InP buffer layer. The thickness of the top barrier enhancement layer is 50 nm and 99 the spacer layer is 5 nm. A Si delta doping layer with sheet density of 1013cm-2 was grown between the barrier enhancement and spacer layers due to its previously mentioned advantages. The bottom mirror was designed for high reflectance at a 1550 nm center wavelength. The thickness of each individual layer in the quarter-wave pair is one quarter of the effective wavelength. The thickness of the active layer has to satisfy the optimization of quantum efficiency. 4.3.2 Dispersion relation expression Material dispersion effects have to be considered in optimization of quantum efficiency. This section describes the disperstion relation expression of the ralted material systems. 4.3.2.1 Dispersion relation in ternary (GaAl)As system The dispersion relation is a result of two factors. One is due to material dispersion properties [125]. The other is that light with a wavelength that does not match the thickness of the DBR is incident on the device. The fundamental optical excitation spectrum of a material can be described in terms of a frequency-dependent complex dielectric constant ε(ω): ε (ω ) = ε 1 (ω ) + iε 2 (ω ) (4.14) The dielectric constant has well-known integral dispersion relations between the real and imaginary parts of the function ε(ω) dependent on the frequency ω [KramersKronig relations] [123]: 100 ε 1 (ω ) = 1 + ε 2 (ω ) = − ∞ 2 ω 'ε 2 (ω ' ) dω ' ∫ ' 2 2 π 0 (ω ) − ω (4.15) ∞ 2 ωε 1 (ω ' ) dω ' ∫ ' 2 2 π 0 (ω ) − ω (4.16) A model of the dielectric constant of semiconductors based on simplified models of the interband transitions will be employed [137]. The lowest-direct gaps in the zincblende type semiconductors occur in the center of the Brillouin zone, where is has fourfold (counting the two spin states) E0 and two-fold E0+∆0 gaps. The real part of ε(ω) in the zinc-blende material below the band edge can, thus, be written as [137] 1 2 ε 1 (ω ) = A0 { f ( χ ) + [ E0 /( E0 + ∆0 )]3 / 2 f ( χ 0 )} + B0 (4.17) f ( χ ) = χ −2 [2 − (1 + χ )1 / 2 − (1 − χ )1 / 2 ] (4.18), χ = hω / E0 (4.19), χ 0 = hω /( E0 + ∆0 ) (4.20). with and The constants A0 and B0 as a function of composition x, as determined by leastsquare fitting Eq.(4.17) with the experimental data, are found to be [125]: A0 ( x) = 6.3 + 19.0 x (4.21) B0 ( x) = 9.4 − 10.2 x (4.22) Table 4.7 [138-140] shows the electric band parameters for GaAs, AlAs, and AlxGa1-xAs, which are used to achieve the dispersion relation expression. 101 Table 4. 7 Electronic parameters for GaAs, AlAs, and AlxGa1-xAs. Parameter Band-gap energy Egα (eV) GaAs 1.424 (EgX) Critical-point energy (eV) 1.425 E0 1.765 E0+∆0 4.3.2.2 AlAs 2.168 (EgX) AlxGa1-xAs 1.424+1.247x (0<x<0.45) 1.900+0.125x+0.143x2 (4.5<x<1) 3.02 3.32 1.425+1.155x+0.37x2 1.765+1.115x+0.37x2 Dispersion relation of quaternary (GaIn)(AsP), (Al,Ga,In)As system The (GaIn)(AsP) quaternary system has generated much interest recently because it can be grown epitaxially on InP without lattice mismatch over a wide range of compositions. The real part of ε(ω) of the material in this system still can be written as Eq.(4.17-4.20) [141]. Table 4.8 shows the parameters used in the calculation of ε1(ω). Table 4. 8 Material InP GaP GaAs InAs Parameters used in the calculation of ε1(ω). E0 1.35 2.74 1.42 0.36 E0+∆ 1.45 2.84 1.76 0.79 A0 8.40 22.25 9.29 4.36 B0 6.60 0.90 7.86 10.52 A0 and B0 are given by the following two equations in (In0.53Ga0.47As)z(InP)1-z: A0 ( z ) = 8.40 − 3.40 z (4.23 a) B0 ( z ) = 6.60 + 3.40 z (4.23 b). and The dielectric constant ε1(ω) of In1-xGaxAszP1-z can then be specified in terms of z alone. The definition of z is the composition of (In0.53Ga0.47As) in (In0.53Ga0.47As)z(InP)1-z. 102 The refractive index dispersion of the (Al,Ga,In)As quaternary systems for various (Al,In)As mole fractions can be calculated as described in the following. The index of dispersion of the (Al,Ga,In)As quaternary for various (Al,In)As mole fractions, z, i.e., (In0.53Ga0.47As)1-z(In0.52Al0.48As)z is known from the previous waveguide measurements [142]. By fitting the data to a first-order Sellmeier equation of the form n( λ ) 2 = A1 + B1 λ 2 λ 2 − C1 2 (4.24), the empirical A1, B1, and C1 coefficients as a function of In0.52Al0.48As mole fraction z can be obtained A1 (z) = 9.689 − 1.012 z (4.25 a), B1 (z) = 1.590 − 0.376 z (4.25 b), C1 ( z ) = 1102.4 − 702.0 z + 330.4 z 2 (4.25 c). and where 0.3 < z <1.0 [143]. A linear interpolation has been employed to calculate the rest of the lattice constants, energy band gaps, and some other electronic and optical parameters of the materials in the same manner as depicted in previous sections. 4.3.3 Reflectivity from the bottom mirror The simulations are based on the simplified resonant-cavity-enhanced heterojunction photodetector shown in Fig.2.2. The materials shown in Fig. 4.2 and Fig. 4.3 are employed to fill each layer in Fig.2.2 for GaAs based and InP based photodetectors correspondingly. 103 Figure 4.4 and Fig. 4.5 show the calculated reflection coefficients of a wave incident on the top of the DBR reflector for GaAs based and InP based photodetectors respectively, which include the materials dispersion effects as mentioned in the above section. 4.3.3.1 Reflectivity from the bottom mirror in GaAs based PD Figure 4.4 shows how the reflection coefficient changes with wavelength. Since the energy band gap of Al0.24Ga0.76As and Al0.9Ga0.1As are both larger than the incident R eflectivities of the bottom m irror photon’s energy considered, the absorption effect is neglected here. 1.0 N=30 N=20 0.8 N=15 N=10 0.6 0.4 0.2 0.0 720 760 800 840 880 920 960 Wavelength (nm) Figure 4. 4 Reflectivity of bottom mirror vs wavelength for different numbers of quarter wave pairs. N is the number of quarter wave pairs. +: N=10; ×: N=15; •: N=20; ∗: N=30. (GaAs based PD) 104 N is the total number of the contrasting pairs in the quarter mirror stacks. The more quarter mirror stacks, the higher the reflectivity of the Bragg mirror. Also, the more quarter mirror stacks, the sharper the curve, which means with high reflectivity of the bottom mirror, a high spectral resolution can be achieved for the corresponding receiver. This kind of feature makes it behave like a filter, which can help it to serve as a wavelength selected receiver in the WDM (wavelength division multiplexing) systems. FWHM (full width at half maximum) of these four curves are approximately 95nm, 82nm, 77nm, and 71nm and also the peak value of the reflectivities of these four different structures are 0.7259, 0.9136, 0.9748 and 0.9980 at 830 nm respectively while N equals to 10, 15, 20 and 30. For N=20, the reflectivity of the bottom mirror almost reaches unity and also the bandwidth at 90% of its peak value is 57 nm, which is only 3 nm different from the ideal case. Thus, 20 quarter wave pairs were selected in the design for the distributed Bragg reflector. 4.3.3.2 Reflectivity from the bottom mirror in InP based PD Figure 4.5 shows the reflection coefficient′s dependence on wavelength. There are two factors that produce such a curve. One is from material dispersion properties. The second is that the thickness of all these layers does not match the wavelength of the incident light when it varies from 1.55µm. Since the energy band gap of In0.527Al0.144Ga0.329As and InP are both larger than the incident photon energy considered, the absorption effect is neglected here. N is the total number of the contrasting pairs in the quarter mirror stack. The more quarter mirror pairs, the higher the reflectivity of the 105 Bragg mirror. Also, the more quarter mirror pairs, the sharper the curve, meaning high reflectivity of the bottom mirror creates a high resolution in the corresponding receiver. This type of feature creates filter-like behavior, which allows it to serve as a wavelength selective receiver in the WDM (wavelength division multiplexing) systems. Except N=10, FWHM (full width at half maximum) of the other three curves is approximately R eflectiv ity of th e b ottom m irro r equal to 0.1µm. 1.0 N=30 0.8 N=20 0.6 N=15 0.4 N=10 0.2 0.0 1.4 1.5 1.6 1.7 wavelength (um) Figure 4. 5 Reflectivity of bottom mirror vs wavelength for different numbers of quarter wave pairs. N is the number of quarter wave pairs. +: N=10; •: N=15; ×: N=20; ∗: N=30. (InP based PD) 106 4.3.4 Quantum efficiency 4.3.4.1 Quantum efficiency in GaAs based PD Figure 4.6 shows how the quantum efficiency of the whole structure is dependent on wavelength for the different thicknesses of the absorption layer. 1.0 m=4 m=3 Quantum Efficiency 0.8 0.6 m=2 m=1 0.4 0.2 0.0 760 800 840 880 920 Wavelength (nm) Figure 4. 6 Quantum efficiency of entire structure vs wavelength for different thickness of absorption layer (number of quarter wave pairs is fixed as N=20). m represents thickness of GaAs absorption layer. •: m=1; +: m=2; ×: m=3; ∗: m=4. (GaAs based PD) In this figure, the number of the quarter wave pairs is fixed at 20. Different m values correspond to different thicknesses of the absorption layer, which represents the thickness of the GaAs layer: 117.5 nm, 230.6 nm, 343.8 nm, and 456.9 nm for an m of 1 to 4 respectively. Their relation is decided by the formula 107 2( β1L1 + β 2L2 ) + Ψ1 + Ψ2 = 2mπ . The thicker the absorption layer is, the larger the peak value is. However, a thick absorption layer will increase transit time of the optically generated carriers. Thus, a tradeoff between response and quantum efficiency has to be considered. This figure also suggests that m only changes the peak value and does not affect the shape of the curves. The peak quantum efficiencies of these four structures are 54.2%, 79.1%, 91.0%, and 96.2% respectively. There is no significant difference between the FWHM of these different curves, which is around 28 nm for each. When m is larger than 3, i.e., the thickness of absorption layer is greater than 340.8 nm, the benefits of increasing the thickness of the absorption layer become significantly reduced. 4.3.4.2 Quantum efficiency in InP based PD Figure 4.7 shows how the quantum efficiency of the whole structure changes with wavelength for different thickness of the absorption layer. The number of the quarter wave pairs is fixed at 15. Different m values correspond to different thicknesses of the absorption layer. Their relation is decided by the formula 2( β1L1 + β 2L2 ) + Ψ1 + Ψ2 = 2mπ . The thicker the absorption layer, the higher the peak value. However, a thick absorption layer creates a lower time response by producing long path for electrons to travel to the triangular well. A tradeoff between fast response and high quantum efficiency has to be considered here. It is shown in this figure that m only changes the peak value and does not affect the shape of the curves. There is no difference between the FWHM of these different curves. When m is larger than 3 (the thickness of the absorption layer is greater than 600nm), the benefits from increasing the thickness of the absorption layer decrease significantly. 108 1.0 m=4 Quantum Efficiency 0.8 m=3 0.6 m=2 0.4 m=1 0.2 0.0 1.4 1.5 1.6 1.7 Wavelength (um) Figure 4. 7 Quantum efficiency of entire structure vs wavelength for different thickness of absorption layer (number of quarter wave pairs is fixed as N=15). m represents thickness of InGaAs absorption layer. +: m=1; •: m=2; ×: m=3; ∗: m=4. (InP based PD) 4.3.5 Sheet charge density In order to understand the tradeoff between the response time and quantum efficiency, the electronic properties, primarily the sheet charge density in the triangular well and the electric field profile have to be examined in this type of structure. A closedform expression developed by our group and a modified self-consistent method has been employed to simulate the devices referred to in this thesis. The number shown in Fig.4.8 represents the thickness of the spacer layer between the delta-doped layer and AlGaAs/GaAs interface. It was observed that for the same doping concentration in the 109 delta doped plane, the thinner the spacer layer, the larger the sheet carrier density in the triangular well on GaAs side. The thickness of the spacer in our device is 5 nm and doping concentration is 5 x 1012 cm-2, which means the sheet carrier density in the well is around 1.4x1012 cm-2 and 1.5x1012 cm-2 from two different simulation methods. 12 Sheet Charge Density (cm-2) 1.8x10 modified Schrodinger and Poission model closed-form expression 12 1.6x10 50 Å 12 1.4x10 70 Å 12 1.2x10 100 Å 12 1.0x10 11 8.0x10 12 4.0x10 12 8.0x10 13 1.2x10 13 1.6x10 13 2.0x10 -2 Delta Doping Concentration (cm ) Figure 4. 8 Simulation of nso against AlGaAs delta doping concentration at 300K for various thickness of spacer layer. (GaAs based PD) 110 4.3.6 Electric field Electric Field (V/cm ) 4.3.6.1 Electric field profile in GaAs based PD 2.0x10 5 1.5x10 5 50 Å modified Schroinger and Poisson model 70 Å closed-form expression 100 Å 1.0x10 5 5.0x10 4 0.0 -1 10 0 1 2 3 10 10 10 10 Distance from the interface (Å) 4 10 Figure 4. 9 Comparison of electric field strength profile by using closed-form expression and modified Schrödinger and Poisson model 300K for various spacer layer thickness (GaAs based PD) Knowing the electric field distribution in the device is the best way to comprehend the transport behavior of the photogenerated carriers. Figure 4.9 shows the electric field profile in the absorption region away from the heterointerface, which is implemented using the closed-form analytical model equation and the modified selfconsistent solution of Schrödinger and Poisson equations. 111 Figure 4. 10 Drift velocity in GaAs material [144]. From Fig. 4.9, the electric field strength at the interface is around 2.0 x 105 V/cm, 1.7 x 105 V/cm, and 1.4 x 105 V/cm while the thickness of the spacer layer is 5 nm, 7 nm and 10 nm respectively for a doping concentration of 5 x 1012 cm-2. This electric field remains relatively constant in the quantum well and drops to about 4.7 x 104 V/cm, 4.4 x 104 V/cm, and 4.1 x 104 V/cm at 100 Å away from the interface for each case, which is the critical value for both electrons and holes to reach saturation velocity [144]. Each curve reaches a constant value of 7 x 103 V/cm at around one thousand Å away from the Al0.24Ga0.76As/GaAs interface. The electrons have reached their saturation velocity while the electric field is larger than 7 x 103 V/cm based on the information from Fig.4.10. This indicates that the whole absorption region experiences a vertical field that is very strong close to the surface, where exponentially larger numbers of optical carriers are produced. 112 4.3.6.2 Electric field profile in InP based PD Figure 4.11 shows the electric field profile in the absorption region away from the heterointerface by using two different theoretical methods. Simulation results are created from the closed-form analytical model equation and the modified self-consistent solution of Schrödinger and Poisson equations. The electric field strength at the heterointerface is closely modeled by the closed-form expression, however, near interface values are slightly lower than expected and also the curve calculated based on the modified selfconsistent solution of Schrödinger and Poisson equations is flatter than the other within 100Å of the interface. The fitting parameter b can be reoptimized for the closed-form expression to achieve a closer electric field strength value near the interface to the modified self-consistent solution of Schrödinger and Poisson equations. The flatter curve for the modified self-consistent solution of Schrödinger and Poisson equations within 100Å is due to the assumption in this simulation that triangular quantum well width is around 100Å. Thus, the electric field strength is a flat line within that region. Nevertheless, it is seen from this comparison that the analytic expression compares well with much more involved modeling methods. E lectric field (V /cm ) 113 4.0x10 5 3.0x10 5 2.0x10 5 1.0x10 5 0.0 -2 10 10 -1 10 0 10 1 10 2 10 3 Distance from the interface (0.1nm) Figure 4. 11 The electric field strength profile by using closed-form expression and modified Schrödinger and Poisson model 300K. (InP based PD) From Fig. 4.11, the electric field strength at the interface is around 3.8x105V/cm, and within the triangular quantum well (100Å), the electric field values are still above 5x104V/cm, which is the critical value for both holes and electrons to reach saturation velocity as shown in Fig. 4.12. According to the simulation data, while the thickness of the absorption layer is beyond 1700Å, which is thicker than the thickness when m=1, the electric field is below 4x103V/cm. Field-dependent drift velocity of electrons decreases rapidly and field-dependent drift velocity of holes is less than 1% of the saturation velocity of electrons when the electric field is below 4x103V/cm. For the photo response spectrum, a long tail is explained as the slow motion of holes. When m=1, the internal quantum efficiency of the peak value is around 40%, which is tolerable in our case. To be 114 conservative, m=2 is our choice, which means that the thickness of the absorption layer is around 385.8 nm. Figure 4. 12 4.4 Drift velocity of electrons and holes in In0.53Ga0.47As [145] Conclusions An AlGaAs/GaAs based RCE, HMSM PD with an Al0.24Ga0.76As/Al0.9Ga0.1As DBR operating around 830 nm and an InAlAs/InGaAs based RCE, HMSM PD with an In0.527Al0.144Ga0.329As/InP DBR operating around 1550 nm was designed. Delta doping is employed in the top wide band gap materials to produce a confined electron cloud and an associated transverse electric field. The effect of doping will be investigated by currentvoltage and temporal response measurements of doped and undoped devices in the following chapter. The design process requires considering the speed, quantum efficiency and sensitivity of the device. These favorable performance characteristics combined with 115 the growth substrate and compatibility of the growth structure with high electron mobility transistors, makes GaAs based and InP based delta doped device excellent candidates for short haul (local area) and long haul high speed telecommunication applications respectively. Based on the analysis in Section 4.3, the top view and the schematic cross-section of GaAs based PD is shown in Fig. 4.13. The layer structure was grown by solid-source molecular beam epitaxy on a semi-insulating GaAs substrate. Twenty-periods of a Al0.24Ga0.76As/Al0.9Ga0.1As DBR were grown on a 200 nm GaAs buffer layer. The thickness of the top barrier enhancement layer is 50 nm and the spacer layer is 5 nm, which separates the ionized donors and the electrons and removes the scattering effects in the 2DEG, thus increasing transport speed. A Si delta doped layer with sheet density of 5x1012cm-2 was grown between the barrier enhancement and spacer layers due its previously mentioned advantages using uniform doping [56 - 60]. The bottom mirror was designed for high reflectance at a 830 nm center wavelength. The thickness of the quarter-wave pair is one half of the effective wavelength (λ0/n). The device area was 40 x 40 µm2 with a typical interdigital pattern using finger width of 1 µm or 2 µm and distance of 2 or 4 µm. 116 40µm finger 40µm gap Metal Semiconductor Metal light 50 nm nid Al0.24Ga0.76As Barrier 5 nm nid Al0.24Ga0.76As Spacer 117.5nm undoped GaAs absorption layer (λ0/4n) undoped Al0.24Ga0.76As (59.6nm) (λ0/4n) undoped Al0.9Ga0.1As (67.6nm) Si δ-doping 5x1012 cm-2 DBR quarter wave stacks 200nm GaAs Buffer GaAs Substrate Figure 4. 13 Top view and schematic cross-section of GaAs based PD. The schematic cross-section of InP based PD is shown in Fig. 4.14. The layer structure was grown by solid-source molecular beam epitaxy on a semi-insulating InP substrate. Fifteen-periods of a In0.527Al0.144Ga0.329As/InP DBR were grown on a 25 nm InP buffer layer. The thickness of the top barrier enhancement layer is 50 nm and the spacer layer is 5 nm. A Si delta doped layer with sheet density of 1013cm-2 was grown 117 between the barrier enhancement and spacer layers. The bottom mirror was designed for high reflectance at a 1550 nm center wavelength. The thickness of the quarter-wave pair is one half of the effective wavelength (λ0/n). The device area was 40 x 40 µm2 with a typical interdigital pattern using finger width of 1 µm or 2 µm and distance of 2 or 4 µm. light Schottky Schottky 50 nm n(6~8*1014cm-3) In0.52Al0.48As barrier Si δ-doping 13 2 5 nm undoped In0.52Al0.48As spacer 385.8.nm undoped In0.53Ga0.47As absorption layer (λ/4n) Undoped InP (122.3nm) (λ/4n) In0.527Al0.144Ga0.329As (113.3nm) 25nm InP:Fe Buffer InP Substrate Figure 4. 14 InP based PD diagram. 15 periods 118 5. Performance Characteristics of AlGaAs/GaAs Delta Doped HMSM Photodetector with Resonant Cavity for Short Haul Communications Design considerations for an AlGaAs/GaAs based resonant-cavity-enhanced (RCE), heterostructure metal-semiconductor-metal (HMSM) photodetector with a Al0.24Ga0.76As/Al0.9Ga0.1As distributed Bragg reflector was presented in Chapter 4. In this chapter, we present the experimental results. In the first section, the photocurrent spectrum is presented, which shows a clear peak around 850 nm with full width at half maximum (FWHM) equal to around 30 nm. The device shows a 0.08 A/W average photoresponsivity with a 9.2 fA/µm2 dark current. Time response measurements using femtosecond pulses show rise time, fall time and FWHM of 10.6 ps, 9 ps, and 18.4 ps, respectively, giving a 3-dB bandwidth of about 33-GHz for this device. Capacitance voltage measurements indicate a very low capacitance value, which is below 30 fF. In the second section, we investigate the effect of delta doping is employed in the top AlGaAs layer. This technique produces a confined electron cloud and an associated transverse electric field. The effect of doping is studied by comparing current-voltage and temporal response measurements of doped and undoped devices. All figures of merit show improvement for doped devices. An important feature of the delta doped device is an improvement in the optical response; its dc photocurrent increases by a factor of 1.6 while the dark current reduces by about a factor of 7.8 under 4V bias, resulting in a factor of 12.5 increase in the dynamic range. Current voltage measurements under different temperatures demonstrate that the doped devices have larger activation energy and a lower capacitance value at low bias range compared with the undoped device. There is 119 about a 7 GHz expansion of the 3dB bandwidth under 5V bias for the delta-doped device. A number of devices with different geometry have been measured to illustrate the aiding field mechanism. In the third section, further comparison between the delta-doped and undoped device are discussed, which includes structures from transmitted electron microscope (TEM) pictures and the reflectivity for the light incident on the top surface of the devices from the reflectivity spectrum. The structures parameters are based on the TEM figure. The simulation results of the reflectivity based on the Chapter 2 analysis have been completed, including the standing wave effect which means that the quantum efficiency is a function of the placement of the active region in the optical field. Based on the wide range of experimental data, the favorable performance characteristics, combined with its substrate and compatibility with high electron mobility transistors, makes the doped device, for receivers used in the 850 nm wavelength fiber band, of importance to short haul communications. 5.1 Wavelength Selectivity, High Sensitivity, and High Speed As shown in Fig.4.13, a twenty period Al0.24Ga0.76As/Al0.9Ga0.1As DBR grown on a 200 nm GaAs buffer layer, a top barrier enhancement layer of 50 nm, a spacer layer of 5 nm, and a Si delta (δ) doped layer with sheet density of 5 x 1012cm-2 grown between the barrier enhancement and spacer layers are the primary components of our device. The device area was 40 x 40 µm2 with a typical interdigital pattern shown in Fig. 1.7 with finger width of 1 µm or 2 µm and distance between fingers of 2 or 4 µm. 120 5.1.1 Wavelength selectivity Q u a ntum E ffic ien cy 0.6 0.5 0.4 0.3 deviate from normal incident 45 o normal incident 0.2 0.1 0.0 750 800 850 900 950 Wavelength (nm) Figure 5. 1 Simulation results for quantum efficiency of layered structure as a function of wavelength for two different incident angles. Figure 5.1 shows the simulation results of the quantum efficiencies as a function of wavelength at two different angles of incidence for our devices. Compared to a device without a resonant cavity, a seven-fold enhancement is achieved in quantum efficiency with a 1 µm-1 absorption coefficient. The peak of quantum efficiency varies with angle of incidence due to a difference in optical path length. The calculated full width at half maximum (FWHM) is around 30 nm. This value can be reduced to less than 10 nm if the 121 reflectance of the top mirror is larger than 0.9, however that would require a much thicker layered structure to compensate for the quantum efficiency. Figure 5.2 shows the experimental photocurrent spectral response of the RCEHMSM photodetector with a 2 µm finger width and a 4 µm gap width. A monochrometer with 0.15 nm resolution was used to select the excitation wavelength from a chopped tungsten light source. The signal was measured by a lock-in amplifier. The spectral response was measured under 10V reverse bias. -12 1.4x10 Photocurrent (a. u.) -12 1.2x10 -12 1.0x10 -13 8.0x10 -13 6.0x10 -13 4.0x10 -13 2.0x10 0.0 700 750 800 850 900 950 1000 Wavelength (nm) Figure 5. 2 Photocurrent spectral response of resonant-cavity-enhanced HMSM photodetector measured at 10V reverse bias. (Data courtesy of IME-CNR, Lecce, Italy) The resonant peak value is around 850 nm due to the angle of incidence of the single mode fiber optic line, in accordance with Fig. 5.1. The FWHM value is seen to be 122 in good agreement with the simulation results of Fig. 5.1. The shape of the photocurrent response, however, is asymmetric. This is due to the fundamental absorption edge of GaAs, which is around 870 nm and limits low energy absorption. Also, Fig. 5.2 is not normalized to photon flux, which would make it more comparable with Fig. 5.1. Finally, the dependence of the absorption coefficient on wavelength is not included in this simulation. A large increase in the photocurrent is observed around 710 nm, due to absorption in Al0.24Ga0.76As layers. 5.1.2 Sensitivity, light response One of the common problems in measuring light intensity is that signals from most photodetectors are non-linear. Figure 5.3 shows the photoresponse of our photodetector with a 2 µm finger width and a 4 µm gap width at 20V reverse bias, at different incident light power. Current of the photodetector is measured at the same distance from the laser. The intensity of the light incident on the photodetector is given in terms of light power. A linear relation is obtained as shown in Fig.5.3. If one linear curve is employed to fit the experimental data, the photoresponse can be written as I Re = Are Pin + Bre (5.1) where Are and Bre are the two fitting parameters, Pin is the incident power, and Ire is the photocurrent at different incident power. Thus, parameter Are is the responsivity and can be extracted from experimental data presented in Fig. 5.1, to be 0.081 A/W with a 0.002 A/W deviation. Parameter Bre is equal to 1.2 x 10-6 A with a 9 x 10-7 A deviation. With a 0.081 A/W responsivity, the corresponding thickness of the active layer without resonant 123 cavity can be calculated to be around 1.2 µm. This calculation is based on the assumption of a 0.25 µm-1 absorption coefficient at 850 nm, according to Fig. 1.10 and a reflectivity of 0.3 from the top layer. While in our device, the thickness of the absorption layer is about 0.12 µm, which is noly one tenth of the thickness of the conventional device. The device shows a nine fold photoresponse increase over the conventional device. While in the simulation results using Eq.(2.14), the resonant caivity only gives around eight-factor increase in the quantum efficiency at the resonant wavelength with a 0.25 µm-1 absorption coefficient. Besides the resonant cavity technique, maybe the other contributions may need to be considered in characterizing the performance of the delta doped HMSM RCE photodetecotrs. Another possibility is that the absorption coefficient is underestimated. Even with the assumption of a 0.5 µm-1 absorption coefficient at 850 nm, the experimental data shows that the device still demonstrates a 4.4 fold photoresponse increase over the conventional device, lower than the 7.5 factor increase in the quantum efficiency obtained from the simulation results. It can be seen in the above figure that the curve may be better fit by using two linear parts. The first is in the lower incident power range, below 0.1 mW. The other is in the comparatively higher incident power, greater than 0.1 mW. Then it can be observed that in the lower incident power range, the photo response is around 0.19 A/W; while in the other range, the photo response is slightly lower, around 75 mA/W. A lower responsivity at an incident power larger than 0.1 mW may be explained by considering that this device gradually reaches the saturation photoresponse under such incident power intensity. 124 Finally, the dark current of the device is also calculated from Fig. 5.3 to be around 15 picoamps at this bias, which normalizes to the very low value of 9.2 femtoamps/ µm2. This is one of the lowest dark currents reported in the literature. -3 1.0x10 20V -4 Photo current (A) 1.0x10 -5 1.0x10 -6 1.0x10 -7 1.0x10 -8 1.0x10 -7 1.0x10 -6 1.0x10 -5 1.0x10 -4 1.0x10 -3 1.0x10 -2 1.0x10 Incident Optical Power (W) Figure 5. 3 Photoresponse of resonant-cavity-enhanced HMSM photodetector measured at 20V reverse bias at different incident light power. (Data courtesy of IME-CNR, Lecce, Italy) 5.1.3 High speed (time domain) The high-speed time response measurement setup is shown in Fig.5.4. A modelocked Ti: Sapphire laser, pumped by an Ar-ion laser, was used to excite picosecond pulses in the device. The laser provided ~ 100fs wide optical pulses with 740 ~ 1000 nm wavelength and 76 MHz repetition rate. The excitation beam was intensity modulated by 125 an attenuator and focused by a microscope objective to a 10-µm-diameter spot on the active region of the device. During the measurements, the device was biased through the bias-tee using a voltage source. The device was measured by a 50 GHz sampling oscilloscope. The time response measurement was done by Dr. Marc Currie at the Naval Research Laboratory in Washington DC. Figure 5. 4 Schematic of high-speed time response measurements setup. Figure 5.5 shows the temporal response of a photodetector with 1 µm fingers and 4 µm spacing between fingers, measured at 5 V bias with a 0.1 mW incident power. As seen in the Fig. 5.5, FWHM of the time response is 10.6 ps, its rise time is 9 ps, and fall time is 18.4 ps. The incident power is 0.1 mW, half of which shines on the photodetector. From the above figure, the magnitude of the peak value is 0.14 V, which results in a 2.8 kV/W peak value normalized to the incident power. 126 1.00 V oltag e (V ) 5V 0.95 0.90 0.85 0 10 20 30 40 50 60 Time (psec) Figure 5. 5 Temporal response of photodetector with 1 µm finger and 4 µm gap with a 0.1 mW incident power at 5V reverse bias. 5.1.4 High speed (frequency domain) If the highest frequency contained in an analog signal V(t) is Fmax = B, the sampling rate FN = 2B = 2Fmax is called the Nyquist rate [146]. A sample remedy that avoids this potentially troublesome situation is to sample the analog signal at a rate higher than the Nyquist rate. The sampling time period in Fig. 5.6 is 0.1 ps, while the entire acquisition time is 51.2 ps. Therefore, the sampling rate is 104 GHz, which is large enough here even if the highest frequency contained in an analog signal V(t) is larger than 1000 GHz. Since the acquisition time is 51.2 ps, some generated carriers whose collection time is beyond that are not counted. Based on Fig. 4.10, if carrier behavior of holes is neglected since the 127 electrons dominate the transport behavior, the acquisition time period is sufficiently long. This can be demonstrated from Fig. 4.9. The electric field curve reaches a constant value of 7 x 103 V/cm at the interface between the GaAs absorption region and the Bragg layers, which indicates that the electrons reach the saturation velocity within the whole absorption region. A Fourier transform is performed on the experimental data in Fig. 5.5 and shown in Fig 5.6. The transformed data reveals a 3 dB (photocurrent) bandwidth of Frequency response 33 GHz. 1 0.9 0.8 0.7 0.6 0.5 5V 0.4 3dB:33GHz 0.3 0.2 0.1 1 10 Frequency (GHz) Figure 5. 6 Calculated frequency response from Fig. 5.5. 128 5.1.5 Long trace of time response To better understand the transport mechanism of the device, carrier behavior of holes must be considered. From the drift velocity changing with the electric field shown in Fig.4.10, it indicates that the drift velocity of the holes reaches 2 x 106 cm/s when the electric field is 1.25 V/µm. For a photodetector with a 1 µm finger and 4 µm spacing between fingers under 5 V bais, the average lateral electric field in the GaAs region is around 1.25 V/µm. The transit time for the photogenerated holes carriers to be collected at the cathode contact traveling from the anode is about 200 ps. The acquisition time should be at least longer than 200 ps to get all the information for the transport behavior of the photogenerated holes. Figure 5.7 shows the long trace temporal response of a photodetector with a 1 µm finger and 4 µm spacing between fingers, measured at 5 V bias with the same incident power as for the short trace time response measurement shown in Fig.5.5. The sampling time period in Fig. 5.7 is 2 ps, while the entire acquisition time is 1024 ps. Therefore, the sampling rate is 500 GHz. Since the acquisition time is 1024 ps, the characteristics of the device depend on the transport behavior of both photogenerated holes and electrons. The insert picture shown in Fig.5.7 is a Fourier transform performed on the experimental data. The transformed data reveals a 3 dB (photocurrent) bandwidth of 1.65 GHz. Therefore, the effect of holes will eventually limit the bit rates during data transmission. Experimental data in Fig 5.7 do not represent the best performance of our device, which are only employed for the comparison with a short trace shown in Fig. 5.5. In Section 5.2.6, we present that the best performance of the device can be achieved by 129 changing the operation condition such as the bias and the input power and optimizing geometry of the device. 1.00 Frequency Response Voltage(V) 5V 0.95 1 0.9 0.8 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.1 1 10 Frequency (GHz) 0.90 0 200 400 600 800 1000 Time (p sec) Figure 5. 7 Long trace time response with 1 µm finger and 4 µm gap with a 0.1 mW incident power at 5V reverse bias. 5.1.6 Capacitance measurement The capacitance measurements have been performed at 1 MHz frequency and 30 mV amplitude of the oscillating voltage with a reverse bias voltage on the devices by using a precision LCR meter. Figure 5.8 shows the capacitance-voltage curves of the delta modulation doped devices with different geometries under dark. The symbols, ■, ●, 130 ▲, and ▼, represent the experimental data of the devices with a 1 µm finger width and a 2 µm gap, a 1 µm finger width and a 4 µm gap, a 2 µm finger width and a 4 µm gap, and Dark Capacitance (F) a 2 µm finger width and a 4 µm gap respectively. 2.6x10 -14 2.4x10 -14 2.2x10 -14 2.0x10 -14 1.8x10 -14 1.6x10 -14 1.4x10 -14 W1G2 W1G4 W2G4 W2G2 0 2 4 6 8 10 12 14 16 Bias (V) Figure 5. 8 C-V curves for four different interdigital structures of delta doped devices. (Data courtesy of IME-CNR, Lecce, Italy). The figure indicates that the capacitance values are independent of the applied voltage for all the devices. Also, the maximum capacitance value in this figure is around 26 fF, which shows a 1.3 ps maximum RC (resistor-capacitor) time constant for those devices with a 50 Ω resistor in the circuit. Compared with the experimental data shown in the above temporal response figures, it demonstrates that the performance of these devices is not limited by an RC time constant. 131 5.2 Improvement of MSM Photodetector using Delta-doped AlGaAs/GaAs Heterostructure A heterostructure metal-semiconductor-metal (HMSM) photodetector combining low dark current, fast response, high sensitivity and wavelength selectivity, due to its resonant-cavity-enhanced (RCE) structure, has been presented in the above section. To further improve the characteristics of such a photodetector, the underlying current conduction mechanisms have to be investigated. Schottky barrier height and band-edge discontinuities play an important role in the behavior of heterojunction devices by strongly affecting current transport [52, 118, 119]. Several techniques have been proposed to modulate Schottky barrier height, heterojunction barrier height and bandedge discontinuities including: tuning of the conduction and valence-band barrier heights at an abrupt intrinsic semiconductor-semiconductor heterojunction via incorporation of a doping interface dipole [120]; controlling the effective Schottky barrier height over a wide range using highly doped surface layers [121]; increasing the barrier height due to energy quantization of confined electrons [122]; and increasing Schottky barrier through the electron-electron cloud effects in the modulation-doped heterostructures [54]. 5.2.1 Band bending profile To further improve the characteristics of such a photodetector, the underlying current conduction mechanisms have to be investigated. Since Schottky barrier height and band-edge discontinuities strongly affect current transport in heterojunction devices, [54, 65, 122] two different groups of devices are employed to characterize its underlying 132 mechanism. Figure 5.9 shows a quasi two-dimensional sketch of the potential profile along the growth direction for the delta-doped (right) and undoped (left) devices under thermal equilibrium. The figure, although only qualitative, shows band bending due to delta doping of AlGaAs; it is noteworthy that current transport is in the lateral direction and the absorption region is shown only up to the non-absorbing Bragg layers. There is no band bending in the undoped devices since the semiconductor material is unintentionally doped, while the band bending profile of the doped device is due to its delta-doped plane. Simulation results based on self-consistent solution of Poisson and Schrödinger equations show that sheet charge density is around 1.4 x 1012 cm-2, Fermi level is below the bottom of the conduction band in the entire AlGaAs region, and the electric field is about 2.1 x 105 V/cm at the heterojunction interface on the GaAs side. This electric field remains relatively constant in the quantum well and drops to about 4.7x 104 V/cm at 100 Å from the interface, reaching a constant value of 7 x 103 V/cm at the interface with the Bragg layers (refer Fig. 4.9). This indicates that the whole absorption region experiences a vertical field that is very strong close to the surface, where exponentially larger numbers of optical carriers are produced. These values are calculated for thermal equilibrium as sketched in Fig. 5.9, application of bias, however, would modify the electric field and electrostatic potential profile due to the effect of the Schottky contact. Nevertheless, in the vicinity of the anode we can expect similar values indicating the aiding effect of the field on photoelectron transport. 133 AlGaAs AlGaAs ∆Ec φn1 GaAs cathode φn1 cathode anode Ec φp2 Ef ∆Ec Ec Ef φp2 GaAs ∆Ev Ev Ev (a) anode VD2 ∆Ev (b) Figure 5. 9 Schematic diagram of energy band of devices: (a) undoped device; (b) doped device. 5.2.2 Current-voltage comparison 5.2.2.1 Experimental data Figure 5.10 compares the I-V curves of the dark current and photocurrent for doped and undoped devices with finger widths of 2 µm and distance between fingers of 4 µm. It is observed that the dark current of the delta-doped device is lower by about a factor of 8 compared to the undoped device. An important feature of the delta doped device is its improvement of the optical response; its dc photocurrent increases by a factor of 1.6 while the dark current reduces by about a factor of 7.8 under 4V bias, resulting in a factor of 12.5 increase in the dynamic range. Responsivity values measured 134 at various light intensities showed an average improvement of a factor of 1.5 while dark current normalizes to a very low value of 9.2 femtoamps/ µm2. -6 1x10 12.6µW -7 1x10 -8 Current (A) 1x10 -9 1x10 -10 1x10 -11 1x10 Dark Current -12 1x10 -13 1x10 0 4 8 12 16 20 Voltage (V) Figure 5. 10 Comparison of I-V of undoped and δ-doped devices. ο: undoped device; •: doped device (Data courtesy of IME-CNR, Lecce, Italy). 5.2.2.2 Thermionic emission theory The reverse current density Jn1 for the cathode contact is given by [147] J n1 = An *T 2 e − βφn1 e β ( ∆φn1 −∆φn 2 ) (1 − e − βV1 ) = J ns e β ( ∆φn1 −∆φn 2 ) (1 − e − βV1 ) (5.2) where An∗ is the effective Richardson constant for electrons, T is the temperature, β = q / kT , ∆φn1 is the image-force-induced lowering of the Schottky barrier height, the 135 quantity ∆φn2 models the barrier enhancement that results from the repulsive effect of the mobile 2DEG on the electrons that are thermionically emitted from the cathode [133], and V1 is the bias value dropped at the cathode. Ec φn1 ∆Ec Ef Ev φp2 ∆Ev (a) Ec φn1 ∆Ec Ef ∆Ev δ-doping cathode Ev φp2 VD2 (b) AlGaAs GaAs absorption layer anode Figure 5. 11 Potential profile at zero bias of undoped and δ-doped devices. (a): undoped device; (b): doped device. Figure 5.11 shows the potential profile for two different devices at zero bias. Equation 5.2 gives the reverse current density Jn1, which is the electron current in the device. The hole current originates from thermionic emission of holes from the anode contact. As shown in Fig. 5.11, the effective barrier for holes at the anode contact is given by (φ p 2 + V D 2 − V2 ) , and V2 is the bias value dropped at the anode, which is forward biased. Those emitted holes which diffuse from x2 to x1 constitute the hole current. 136 ∆Ec Ec φn1 V (a) Ev φn1 V1 ∆Ev φp2 ∆Ec Ec ∆Ev x2 x1 V2 Ev δ-doping φp2 (b) VD2-V2 AlGaAs GaAs absorption layer cathode anode Figure 5. 12 Potential profile at V=V1+V2 bias of undoped and δ-doped devices. (a): undoped device; (b): doped device. In the neutral region (x1 >x > x2) the steady state continuity equation for holes is given by ∂ 2 p p − pn0 − =0 D pτ p ∂x 2 (5.3) where pn0 is the equilibrium hole density, Dp is the diffusion coefficient, and τp is the lifetime. The solution of Eq.(5.3) is simply p − p n 0 = Ae x / Lp + Be − x / Lp (5.4) 137 where Lp is the diffusion constant, which equals D pτ p . The boundary conditions are (1) at x = x1, p = p n0 e ( − qV1 / kT ) , and (2) at x = x2, J p 2 = A p *T 2 e − β ( φ p 2 +VD 2 −V2 ) (5.5) where Ap* is the effective Richardson constant for holes. The arbitrary constants A and B in Eq.(5.4) can be determined from the boundary conditions. The hole current density Jp1 is then given by the gradient at x1 and the condition that Jp1 =0 at thermal equilibrium condition (i.e., V = 0): J p1 = qD p =[ + dp dx x1 qD p p n 0 tanh(( x 2 − x1 ) / L p ) Lp J ps e − βVD 2 cosh[( x 2 − x1 ) / L p ] (1 − e − βV1 ) (5.6). (e βV2 − 1)] where (x2-x1) is the undepeleted region in the GaAs channel. Based on the above derivation, the contributions of electron and hole current to the total current under small bias is [147]: J = J n1 + J p1 = J ns e β ( ∆φn1 −∆φn 2 ) (1 − e − βV1 ) +[ + qD p p n 0 tanh(( x 2 − x1 ) / L p ) Lp J ps e − βVD 2 cosh[( x 2 − x1 ) / L p ] (1 − e − βV1 ) (5.7) (e βV2 − 1)] where J ns = An *T 2 e − βφn1 and J ps = A p *T 2 e − βφ p 2 . φn1, φp2, and VD2 are defined as shown in Fig. 5.9, Fig. 5.11, and Fig. 5.12. The second term in Eq.(5.7) is much smaller than the first for both devices, and can be neglected. Further, for better modeling, scaling 138 terms should be added to either the first or the last term which reflect majority carrier concentration values. The following section is a discussion based on the description in this section about the experimental data of I-V comparison shown in Fig.5.10. 5.2.2.3 Discussions Image-force lowering of the barrier due to band bending and ionized donors in AlGaAs should increase the thermionic emission of the δ-doped device in comparison to the undoped device; however, we observe an opposite effect under low biases in Fig. 5.10. This is due to increase of the barrier by the exerted force of the mobile electron cloud, depicted by ∆φn2, as well as band bending at the anode that adds to the hole barrier, i.e., due to VD2 in Eq.(5.7). With increasing bias, the electron cloud of the triangular well under the cathode side is depleted and the extra barrier for the holes in the anode side becomes smaller due to forward bias, leading to an increase of current. In fact, with increasing bias, the electron cloud under the cathode is further depleted, and the image-force-induced lowering of the Schottky barrier causes more current to flow in the delta doped sample, while in the undoped one, the cathode barrier is not lowered as in the doped device. A potential distribution in 2 DEG based on the conformal mapping technique will be employed to help to illuminate the difference of the dark current between the undoped and doped device in the following section. 139 5.2.2.4 Potential distribution in 2DEG The distribution of the electric potential in a 2DEG system can be derived by using a conformal mapping technique. The x axis is shown in Fig. 5.13 is the plane of a complex argument z = x + iy in the direction perpendicular to the surface of the 2D gas in the plane of the p-type contact boundary. The y axis is in the plane containing the 2D gas as shown in Fig. 5.13. The real part of the gradient of the complex potential dV / dz on the axis is equal to zero because the plane of the p+ contact is an equipotential surface. The imaginary part of the gradient is equal to zero for y > ddep because half-plane of the 2D electron gas is an equipotential surface. Finally, the real part of this function is equal to qn s where εGaAs is the dielectric permittivity of the semiconductor and ns is the 2ε GaAs 2DEG sheet charge density. This function has opposite signs at the two sides of the cut made between the singular points z = id dep and z = −id dep . Hence, the discontinuity of the electric induction vector is equal to qNs and dV / dz is an even function. Therefore, it is sufficient to solve the problem for the y ≥ 0, x > 0 quadrant. The conformal transformation w = ( z d dep ) 2 converts this quadrant into the half-plane Im w > 0. Then the problem reduces to the solution of the Laplace equation for dV / dw whose real part is equal to zero for w > 0 and w < -1 and whose imaginary part is equal to qn s d dep /[4ε GaAs (− w)1 / 2 ] for 0 > w >-1. Using a standard procedure, the gradient of the complex potential is obtained as follows: ( z 2 + d dep 2 )1 / 2 + d dep qn s dV / dz = −i ln 2πε GaAs ( z 2 + d dep 2 )1 / 2 − d dep (5.8) 140 Choosing the potential of the p contact as a reference point and integrating Eq.(5.8) with respect to z, the complex function of the potential can be obtained as: ( z 2 + d dep 2 )1 / 2 + d dep ( z 2 + d dep 2 )1 / 2 + z qn s V = −i + d dep ln [ z ln ] (5.9) 2πε GaAs ( z 2 + d dep 2 )1 / 2 − d dep ( z 2 + d dep 2 )1 / 2 − z w x depletion region p+ drain y 2D electron gas +++++ z Figure 5. 13 R Simplified model of 2D electron gas p-type semiconductor junction. From Eq.(5.9), the potential distribution along the positively charged depletion layer can be achieved (d dep 2 − y 2 )1 / 2 + d dep qn s V ( y) = [ y ln + 2d dep sin −1 ( y / d dep )] 2 2 1/ 2 2πε GaAs d dep − (d dep − y ) Hence, the potential V at y = ddep is given by (5.10) 141 V = qn s d dep (5.11) 2ε GaAs It is noteworthy that for a two 2DEG the relation between bias and depletion region is calculated from V = qn s d dep 2ε GaAs [148], which gives a value of over 10 V, consistent with the above argument. 5.2.3 Comparison of current voltage at different temperature Current-voltage measurements for GaAs based HMSM RCE-PDs have been carried out in the cryostat as a function of the temperature from 360 K to 280 K. Figure 5.14 shows the experimental data of I-V changing with temperature for the undoped device and the doped device respectively. Both types of devices have the same geometry with finger widths of 2 µm and distance between fingers of 4 µm. The empty symbols represent the experimental data of the undoped devices while the solid symbols stand for those of the doped devices. For all temperatures, the behavior is quite similar. The undoped devices show an almost exponential increase at low voltage, followed by a ‘quasi-saturation’. The doped devices indicate lower currents under low bias compared with the undoped devices. The measurement results in Fig. 5.14 agree with what have been observed in Fig. 5.10, which further demonstrate that the aiding field and band bending associated with the delta modulation doped heterostructure improve the performance of GaAs based HMSM RCE photodetectors. C urrent (A ) 142 1x10 -10 1x10 -11 1x10 -12 1x10 -13 1x10 -14 1x10 -15 360 350 340 330 320 310 300 290 280 0 2 4 6 8 10 12 K K K K K K K K K 14 Bias (V) Current (A) (a) 1x10 -10 1x10 -11 1x10 -12 1x10 -13 1x10 -14 1x10 -15 360 K 350 K 340 K 330 K 320 K 310 K 300 K Tamb 0 2 4 6 8 10 12 14 Bias (V) (b) Figure 5. 14 Current-voltage measurement under different temperature for GaAs based devices. empty symbols: undoped device; solid symbols: doped device. (Data courtesy of IME-CNR, Lecce, Italy). Figure 5.15 shows the derivative currents with respect to 1/kT in log scale under 5V, 10V, and 15V bias respectively. Part (a) and (b) in Fig.5.15 are for the experimental 143 data of the undoped and doped devices correspondingly. All curves indicate linear behavior except the points measured under the low temperature in the doped device. With a linear curve to be employed to fit those experimental data, the activation energies have been deduced. The activation energys are 0.50eV, 0.42eV, and 0.34eV for the undoped device and 0.686eV, 0.65eV, and 0.60eV for the doped device under 5V, 10V, and 15V bias respectively. It can be observed that under the same bias, the doped device has larger activation energy compared to the undoped device. With increasing bias, the activation energy decreases in both devices, which also means the dark current increases with increasing bias. -20 -22 Ea=-0.34 eV at 15 V Ea=-0.42 eV at 10 V Ea=-0.50 eV at 5 V -24 ln (current) ln (current) -22 Ea=-0.60 eV at 15 V Ea=-0.65 eV at 10 V Ea=-0.686 eV at 5 V -24 -26 -26 -28 -28 32 34 36 38 -1 1/kT (eV ) (a) 40 42 32 34 36 38 40 42 -1 1/kT (eV ) (b) Figure 5. 15 Ln(I) vs 1/kT at 5V, 10V, and 15V for GaAs based. empty symbols: undoped device; solid symbols: doped device. (Data courtesy of IME-CNR, Lecce, Italy). 144 5.2.4 Comparison of capacitance- voltage measurements The capacitance-voltage curves of samples with different geometries under dark conditions are reported in Fig. 5.16. Part (a) and (b) in Fig.5.16 represents the experimental data of the undoped and doped devices correspondingly. The symbols here have the same meaning as in Fig.5.8. The most obvious difference in the characteristics between these two types of devices is that doped samples show capacitance values independent of the applied voltage, while the undoped samples indicate higher capacitance values at low bias compared to the doped samples having the same geometry. It is observed that the capacitance values of the undoped devices are almost one order of magnitude greater with a low applied voltage than with a high bias. For the undoped devices, the capacitance maitains a constant value up to almost 2V, and then it jumps to a low value at this critical voltage. The behavior of the undoped devices is the same as what was observed in Fig. 5.10. The capacitance of the interdigital structure can be calculated from Eq.(5.12) [145]: C≈ where πε GaAs A (5.12) 2(W + G ) log(2(1 + κ ) /(1 − κ )) εGaAs is the GaAs permittivity, A is the interdigited area, and κ = (1 − tan 4 (πW / 4(W + G )))1 / 2 is a dimensionless quantity. W and G represent the finger width and the distance between the fingers. Table 5.1 lists the measured capacitance compared with the theoretical capacitance. It shows that at high applied voltages, the experimental results agree well with calculated values. 145 -13 2x10 -14 2.6x10 W1G2 W1G4 W2G4 -13 1x10 W1G2 W1G4 W2G4 W2G2 -14 2.4x10 Dark Capacitance (F) Dark Capacitance (F) -14 -14 8x10 -14 4x10 0 0 2.2x10 -14 2.0x10 -14 1.8x10 -14 1.6x10 -14 2 4 6 8 10 12 14 16 1.4x10 0 2 4 6 8 Bias (V) Bias (V) (a) (b) 10 12 14 16 Figure 5. 16 C-V curves GaAs based.photodetectors, empty symbols: undoped device; solid symbols: doped device. (Data courtesy of IME-CNR, Lecce, Italy). Table 5. 1 Geometry W1G2 W1G4 W2G2 W2G4 5.2.5 Measured and theoretical capacitance values. undoped device (fF) 24.4 11.5 14.4 δ doped device (fF) 26 16.5 21.5 16 calculated values (fF) 26.2 12.4 25.2 13.0 Time response comparison An important feature of the δ-doped device is its improvement in the optical response as partially observed in Fig. 5.10. Its dc photocurrent increases by a factor of 1.6 while the dark current reduces by about a factor of 7.8 under 4V bias, resulting in a factor of 12.5 increase in the dynamic range. Responsivity values measured at various light 146 intensities show an average improvement of a factor of 1.5 while dark current normalizes to a very low value of 9.2 femtoamps/ µm2 of device area. 1.00 5V 1 0.90 Frequency Response Voltage (V) 0.95 0.85 0.1 1 10 Frequency (GHz) 0.80 0 10 20 30 40 50 60 Time (psec) Figure 5. 17 Comparison of temporal response of undoped and doped devices under a bias of 5V; insert shows comparison of their calculated frequency response. ο: undoped device; •: doped device. Figure 5.17 shows the temporal response of a photodetector with a 1 µm finger and 4 µm spacing between fingers, measured by a 50 GHz sampling scope at 5 V bias. As seen in the figure, FWHM of the time response is 10.6 ps (11.0 ps), its rise time is 9.0 ps (8.7 ps), and 18.4 ps (19.4 ps) for the doped (undoped) device. Fourier transform of the data is shown in the inset of the figure and has a 3 dB (photocurrent) bandwidth of 33 GHz and 26 GHz for the doped device and the undoped devices, respectively. The figure 147 also shows an increase of peak response, for the same incident light intensity, by almost a factor of 4. A large number of devices were measured, showing consistent improvement in figures of merit for the delta doped device. Time response data verifies that both collection and transport are affected by the delta doping. This is explained by examining the schematic energy band diagram of Fig. 5.9, noting that photo-carriers move lateral to growth layers and the energy band will be modified and tilted from cathode to anode as a result of the applies bias. The potential profile for the delta-doped device is such that the photoelectrons that are absorbed in GaAs have adequate potential energy, due to vertical band bending, to overcome the conduction band discontinuity. The band bending in the cathode side would hinder hole collection, but the reverse-bias of the Schottky cathode would tend to deplete the 2DEG and hence reduce this bending to make it similar to an undoped device. The vertical field also aids transport of photo-electrons by adding to their velocity in the direction of collection, towards the surface and contacts. Holes, on the other hand, are pushed away from the surface causing broadening of the transit time, however, this long tail of response is controlled by the fact that transit distance in GaAs is limited by the Bragg layers. 5.2.6 Discussion of time response The previous three sections discussed that delta doping in the wide band gap material affect both collection and transport behavior of the photogenerated carriers. In this section, more detailed experimental data with different geometry size are presented 148 to clarify the aiding field and band bending effects in helping the collection and transport of the carriers. 5.2.6.1 Comparison of temporal response (short trace) Figure 5.18 shows the comparison of temporal response of photodetectors with a 1~2 µm finger and 2~4 µm spacing between fingers, measured by a 50 GHz sampling scope at 5, 10, and 20 V bias respectively. W1G2, W2G2, W1G4, and W2G4 devices represent a device with 1 µm finger and 2 µm spacing, 2 µm finger and 2 µm spacing, 1 µm finger and 4 µm spacing, and 2 µm finger and 4 µm spacing in the following description respectively. The experimental setup is the same as described in Section 5.1.3. The wavelength of the incident light is tuned at 850 nm, the resonant wavelength. The sampling period is 0.1 ps, while the acquisition time is 51.2 ps for the entire group of data, which is defined as the short trace data. As elucidated in Section 5.1.3, Section 5.1.4, and Section 5.1.5, the behavior of the photogenerated electron carriers dominates the characteristic of transport and collection of carriers. In Fig. 5.18, the incident power is 0.1 mW, half of which shined on the photodetectors. Four groups of devices have been measured at different biases for the analysis. Part (a) and (b) are the comparisons of peak amplitude normalized to the incident power among the photodetectors with different geometries, which can be achieved from the temporal response spectrum directly. In part (a) and (b), horizontal axis indicates the different biases, while vertical axis represents the normalized peak amplitudes. Part (c) and (d) are the comparisons of 3dB bandwidth, which can be 149 achieved by performing a Fourier transform on the experimental data of temporal response. The horizontal axis has the same meaning as in part (a) and (b), but the vertical axis indicates the 3dB bandwidth of the devices. 5 5 4 W2G2 3 2 1 4 8 12 16 4 Peak Amplitude (V/mW) Peak Amplitude (V/mW) W1G2 W1G4 3 W2G4 2 1 0 20 4 8 12 Voltage (V) 16 20 Voltage (V) (a) (b) 50 40 W1G2 W1G4 W2G2 30 3dB (GHz) 3dB (GHz) 40 30 20 20 4 8 12 Voltage (V) (c) 16 20 W2G4 4 8 12 16 20 Voltage (V) (d) Figure 5. 18 Comparison of temporal response (short trace) at the different bias. Empty symbols: undoped devices; solid symbols: doped devices. □ and ■: W1G2; ○ and ●: W2G2; ∆ and ▲: W1G4; and : W2G4. 150 The solid symbols represent the doped devices while the empty symbols indicate the undoped devices. Part (a) and (c) show the data of the devices with a 2 µm spacing between fingers, where □ and ■ stand for the data of the devices with a 1µm finger width, and ○ and ● represent the data of the devices with a 2µm finger width. Part (b) and part (d) show the data of the devices with a 4 µm spacing between fingers, where ∆ and ▲ signify the data of the devices with a 1µm finger width, and and indicate the data of the devices with a 2µm finger width. Part (a) and (b) show that the normalized peak amplitudes of the doped devices are larger than those of the undoped devices with the same geometry and size under the same voltage bias. Part (a) shows that with increasing bias, there is almost a linear increase in the normalized peak amplitude for the doped groups; while in the undoped groups, there is a faster increase from 5 volts to 10 volts than from 10 volts to 20 volts. Also, it has been observed that although W1G2 and W2G2 devices have the same spacing distance between the fingers, the former have larger normalized peak amplitudes than the latter. The advantage of the normalized peak amplitude of the doped devices over the undoped devices can be explained the same as our previous arguments that the band bending and aiding field in the vertical direction help the collection and transport of the photogenerated electrons. There are two reasons explaining the normalized peak amplitude increase with increasing bias. One is that the average drift velocity of photogenerated electrons increases with increasing bias. The other is that more photogenerated holes have been collected within 51.2 ps acquisition time since the drift velocity of the holes increases 151 with increasing bias. In the undoped devices, since a portion of the applied voltage drops over the anode to help the photogenerated electrons overcoming the conduction band discontinuity, two mentioned reasons cause an increase of normalized peak amplitude in the low bias range while the second one dominates after 10 volts bias, which results in a faster increase in the low bias than in the high bias. Although the conduction band discontinuity exists in the doped devices, the band bending in the potential distribution along the growth direction as shown in Fig.5.9 helps to collect the photogenerated electron carriers in the anode contact, which means that no voltage needs to drop on the electrodes to collect the electrons. As indicated in part (a) of Fig.5.18, there is almost a linear increase in the normalized peak amplitude for the doped devices. The W1G2 group has larger normalized peak amplitudes than the W2G2 group due to the larger active region in the former devices. Part (c) of Fig.5.18 shows that the 3dB bandwidth comparison of the W1G2 and the W2G2 groups by performing a Fourier transform on the experimental data of the temporal response. In the W1G2 group, as indicated in Fig.5.18, 3dB bandwidths of the doped device are larger than those of the undoped device at three different applied voltages. It is also observed that in the W1G2 group, with increasing bias, the 3dB bandwidth of the undoped device shows an increase from 5V to 10V while a decrease from 10V to 20V. However, the trend of the 3dB bandwidth changing with bias is completely different in the doped device from the undoped device of the W1G2 group. In the doped device of the W1G2 group, the 3dB bandwidth decreases from 5V to 10V at first, then increases from 10V to 20V. 152 The advantage of the 3dB bandwidth of the doped devices over the undoped devices can be explained by the fact that the aiding field in the vertical direction accelerates the transport behavior of photogenerated electrons. In the undoped device of the W1G2 group, as explained for the normalized peak amplitude changing with bias, some portion of the applied voltage drops on the anode to collect the photogenerated electrons, even when the applied voltage is larger than 5 volts, the average drift velocity of photogenerated electrons should not reach the saturation velocity. With increasing bias between 5V to 10V, the average drift velocity of photogenerated electrons continues to increase, which results in an increase of the 3dB bandwidth. The decrease in the 3dB bandwidth of the undoped device in the W1G2 group with changing a bias from 10V to 20V can be explained by the following. When the bias is larger than 10V, the average drift velocity of the electrons reaches the saturation velocity and more photogenerated holes contribute to the photocurrent within 51.2 ps acquisition time with increasing bias. Therefore, although there is an increase of the normalized peak amplitude of undoped device in the W1G2 group with increasing bias between 10V to 20V, the collection of more holes results in a decrease in the 3dB bandwidth due to the slower transport behavior of these holes compared to electrons as shown in Fig.4.10. While in the doped device of the W1G2 group, since no voltage drops on the anode to collect electrons, the average drift velocity of electrons reaches the saturation velocity at 5V. Thus, the decreasing 3dB bandwidth with increasing bias between 5V to 10V can be explained the same way as a decrease in the undoped device with an applied 153 voltage varying from 10V to 20V. The increase between 10V to 20V is due to the increase of the average drift velocity of holes with increasing bias. As for the 3dB bandwidth of W2G2 group in part (c) of Fig.5.18, it is observed that the undoped device has the same trend in 3dB bandwidth with applied voltage as the undoped device of the W1G2 group; while the doped device has a faster increase in 3dB bandwidth with a bias between 10V to 20V than from 5V to 10V. The possible reason is that the critical bias voltage to alter the trend of 3dB bandwidth changing with applied voltage may be smaller than 5V due to the wide finger effect, which modifies the electric field distribution from that in the devices of the W1G2 group. Thus, the undoped device has a larger 3dB bandwidth than the doped device in W2G2 group at 5V and 10V bias. The explanation for the difference of the peak amplitude in part (b) and 3dB bandwidth in part (d) of Fig.5.18 between the undoped devices and the doped devices follows the above description for the W1G2 and W2G2 groups. There is a 2.5 factor increase in the peak amplitude of the doped device with a 2 µm finger and 4 µm spacing at 20V bias, which agrees with the results in the current voltage measurements shown in Fig.5.10. The highest 3dB bandwidth is 45.2 GHz for a W1G2 doped device at a bias of 5V. 5.2.6.2 Comparison of temporal response (long trace) The only difference for Fig.5.19 from Fig.5.18 is the sampling period and the entire acquisition time. The sampling periode is 2 ps and the acquisition time is 1024 ps. The transport and collection behavior of the photogenerated electrons does not dominate 154 here, while the transport behaviors of both electrons and holes carriers have to be considered in analyzing the characteristic performance of the devices. W2G2 2 1 0 4 W1G2 4 8 12 16 Peak Amplitude (V/mW) Peak Value (V/mW) 3 3 W2G4 2 1 0 20 W1G4 4 8 Voltage (V) (a) 16 20 (b) 8 8 6 W1G4 W1G2 3dB (GHz) 3dB (GHz) 12 Voltage (V) 4 W2G2 4 W2G4 2 0 0 4 8 12 Voltage (V) (c) 16 20 4 8 12 16 20 Voltage (V) (d) Figure 5. 19 Comparison of temporal response (long trace) at the different bias. Empty symbols: undoped devices; solid symbols: doped devices. □ and ■: W1G2; ○ and ●: W2G2; ∆ and ▲: W1G4; and : W2G4. 155 Figure 5.19 is much simpler than Fig.5.18. In part (a) and (b) of Fig.5.19, it is observed that the normalized peak amplitudes of the doped devices are larger than those of the undoped devices with the same geometry and size under the same voltage bias. Also, it shows that with increasing bias, there is an almost linear increase in the normalized peak amplitude for the undoped groups; as for the doped groups, the W1G2 and W2G2 devices have a faster increase from 5 volts to 10 volts than from 10 volts to 20 volts, while the W1G4 and W2G4 devices show saturation in the normalized peak amplitude after 10 volts. The W1G2 and W1G4 devices have larger normalized peaks amplitude than the W2G2 and W2G4 devices in part (a) and (b) correspondingly. In part (c) and (d) of Fig.5.19, it is shown that the 3dB bandwidths of the doped devices are larger than those of the undoped devices. Also, it consistently indicates that the 3dB bandwidths of all devices increase with increasing bias monotonically. The increase of the normalized peak amplitude in the doped devices over the undoped devices follows the same explanation as the aiding field effects in the vertical direction of the doped devices. Since the acquisition time is 1024 ps, a comparative amount of holes contribute to the photocurrent even at a low bias. The transport behavior of holes dominates the changes in temporal response with increasing bias due to their slower behavior compared to the electrons. With increasing bias, the average drift velocity of holes increases. Therefore, there is an increase in the normalized peak amplitude. Since no voltage drops on the anode to collect photogenerated electrons in the doped devices, there is a slower increase from 10V to 20V than from 5V to 10V in the normalized peak amplitude of the W1G2 and W2G2 groups and the normalized peak amplitude of the W1G4 and W2G4 groups reach the saturation status. The larger 156 normalized peak amplitude in the W1G2 and W1G4 groups than in the W2G2 and W2G4 groups is due to the larger active region. As mentioned in the above paragraph, the transport behavior of holes dominates the changes in temporal response for a large acquisition time. The increase of the average drift velocity of the photogenerated holes result in a decrease of average collection time of carriers. In part (c) and (d) of Fig.5.19, 3dB bandwidth increases with increasing bias monotonically consistent in all devices. The highest 3dB bandwidth among long trances is 6.2 GHz for the doped device in the W1G4 group at 20 volts. From discussion in Sections 5.2.6.1 and 5.2.6.2, it is shown that the characteristic performance of the devices can be optimized by choosing suitable geometry and proper operation bias. Also, in the other experimental data of temporal response, we observed that it is obvious that the power of the incident light affects the transport behavior of the photogenerated carriers. More detailed analysis depends on simulation results from ISE commercial software and a description of the dynamic behavior of the photogenerated carriers based on Ramo’s theory to be done in future work. 5.3 Further Comparison of Undoped and Delta-doped Devices We continue our device characterization by investigating the structural difference between the undoped and δ doped devices, which may be responsible for the differences in the optical and electronic properties in the two different types of samples. 157 5.3.1 TEM (transmitted electron microscopy) structure In Fig. 5.20, particularly in its Bragg reflector region, the undoped device is structurally better than the doped device, in terms of presence of defects and interface quality. The doped device shows faults propagating through the layers of the Al0.9Ga0.1As/Al0.24Ga0.76As super lattice. In the undoped sample as shown in Fig. 5.20(a), the thickness of Al0.9Ga0.1As is 67 ± 1 nm and the thickness of Al0.24Ga0.76As is 61 ± 1 nm; while in the doped sample as shown in part (b), the thickness of Al0.9Ga0.1As is 67 ± 2 nm and the thickness of Al0.24Ga0.76As is 60 ± 2 nm. As Ga Al 0.9 s aA 4G Al 0.2 100 nm 100 nm (a) (b) Figure 5. 20 TEM picture for DBR layer. (a) undoped device, Al0.9Ga0.1As: (67±1) nm, Al0.24Ga0.76As: (61±1) nm. (b) doped device, Al0.9Ga0.1As: (67±2) nm, Al0.24Ga0.76As: (60±2)nm (Data courtesy of IME-CNR, Lecce, Italy). The interfaces of the doped samples are much broader than in the undoped device, as shown by the comparison of the contrast line scan profiles obtained from both 158 samples. Figure 5.21 indicates the comparison of the contrast line scan profiles. In particular, it is worth noting that, even in the case of the doped device, the Al0.9Ga0.1As / Al0.24Ga0.76As interface is sharper than the Al0.24Ga0.76As /Al0.9Ga0.1As interface, as clearly evidenced by the linear fit interpolations of the contrast line scan profile. (a) 1 A l 0 . 9 G a A s / A l 0 .2 4 G a A s in t e r fa c e A l0 . 2 4 G a A s / A l 0 . 9 G a A s in t e r fa c e 2 3 (b) 4 5 6 7 8 9 10 Figure 5. 21 Comparison of contrast line scan profiles (a) undoped device, (b) doped device (Data courtesy of IME-CNR, Lecce, Italy). In Fig. 5.21 (b), the odd numbers represent the Al0.9Ga0.1As /Al0.24Ga0.76As interfaces while the even numbers represent the Al0.24Ga0.76As /Al0.9Ga0.1As interfaces. Those interfaces are called interfacial layers. For the simulation in the next section, each 159 interfacial layer has been divided into ten layers. Those ten layers have the same thickness and the Al mole fraction decreases from 0.9 to 0.24 for the Al0.9Ga0.1As /Al0.24Ga0.76As interfaces. While for the Al0.24Ga0.76As /Al0.9Ga0.1As interfaces, Al composition increases from 0.24 to 0.9. The undoped sample has a clear interface, which is indicated in Fig 5.21 (a). There is only one layer used to be interfacial layer, where Al mole fraction is the average of Al0.9Ga0.1As and Al0.24Ga0.76. The thickness of this interfacial layer is 1nm. 5.3.2 Comparison of the reflectivities between two devices Reflectivity measurements have been done by using an integrating sphere. First, a “reference” has been measured, which is a completely reflective surface. Then, the reflected signal was measured, which is the summation of the reflected and diffused signal. Fig. 5.22 shows the comparison of the measured reflectivity spectrum between the doped device and the undoped device. The solid dots represent the reflectivity for the light incident on the doped device while the empty dots represent the reflectivity for the light incident on the undoped device. As shown in Fig. 5.22, the plot shows a broad band in reflectivity. For the doped device, FWHM of the curve is around 60 nm, while for the undoped device, FWHM of the curve is about 64 nm, which is in agreement with the simulation results in Fig. 4.4. The FWHM of the reflectivity is 71 nm for light normally incident on the DBR. Also, the spectrum shows a resonant peak value of 835 nm for the doped device and 849 nm for the undoped device respectively. In the design, a resonant peak value of 830 nm for light normally incident on the device was targeted. 160 Another difference between the simulation results in Fig 4.4 and the experimental data in Fig. 5.22 is that Fig 4.4 shows the reflectivity spectrum for light normally incident on the bottom mirror with a 830 nm resonant peak while Fig. 5.22 indicates the reflectivity spectrum for the light incident on the top surface of the entire growth structure. Fig. 5.23 shows the different interfaces for the light to be reflected, where part (a) is the structure for the light incident on the bottom mirror which is used to simulate the reflectivity spectrum as shown in Fig 4.4 while part (b) is the structure for the light incident on the top layer of the whole growth structure which is used to measure the reflectivity spectrum as shown in Fig. 5.22. 180 R eflectivity (a.u.) 160 140 120 100 80 60 40 700 800 900 1000 Wavelength (nm) Figure 5. 22 Comparison of reflectivity spectrum between undoped device and doped device. ο: undoped device; •: doped device (Data courtesy of IME-CNR, Lecce, Italy). 161 The simulation results for the reflectivity spectrum from the whole growth structure are discussed in the next section. And growth structures for the simulation are employed based on the TEM experimental data. The structural information has been given in the previous section. 30 nm n+(1.5*1018 cm-3) GaAs cap 50 nm n-(6~8*1014cm-3) Al0.24Ga0.76As barrier enhancement layer 5 nm undoped Al0.24Ga0.76As spacer (λ/4n) Undoped Al0.24Ga0.76As (59.6nm) (λ/4n) Al0.9Ga0.1As (67.6nm) 20 periods quarter wave stack 117.5nm undoped GaAs absorption layer (λ/4n) Undoped Al0.24Ga0.76As (59.6nm) (λ/4n) Al0.9Ga0.1As (67.6nm) 25nm GaAs Buffer 25nm GaAs Buffer GaAs Substrate GaAs Substrate (a) Figure 5. 23 5*1012cm-2 Si δdoping 20 periods quarter wave stack (b) Interfaces for light to be reflected. (a) bottom mirror, (b) top mirror. 5.3.3 Simulation results of the reflectivity spectrum There are two factors resulting in the resonant wavelength differences between the simulation and actual data. One is a variation in the actual layer thickness from the value used in simulation. The second is the angle of incidence of light on the device. In 162 the simulation, the incident light was assumed to be exactly normal to the device, while in testing, there was probably a slight variation in this angle. 180 180 160 160 (a) 140 120 Reflectivity Reflectivity 120 100 80 100 80 60 60 40 40 20 (b) 140 700 800 900 1000 20 700 Wavelength(nm) 800 900 1000 Wavelength(nm) Figure 5. 24 Comparison of reflectivity spectrum between undoped device and doped device. (a) undoped device, solid line: experimental data, dashed line: simulation results; (b) doped device, solid line: experimental data, dashed line: simulation results. The simulations of the reflectivity of the entire growth structure have been calculated based on the formula in Section 4.3. In the simulation results shown in Fig. 5.24, the structures employed are based on the description in Section 5.3.1; dispersion effects coming from material have been calculated based on the formula in Section 4.3.2; and absorption coefficients changing with the wavelength have also been included based on Fig. 1.10. The simulation results show that the difference in the thickness of the quarter wave stack layers between the undoped and doped device affects the position of the 163 resonant peak value in the reflectivity spectrum, while the interface quality affects the shape of the curve, especially near the resonant wavelength. We must also account for the magnitude difference of the resonant peaks. The reflectivity in the experimental data is a relative value, which is not normalized. The simulation result however is normalized reflectivity. The figure shows that the normalized reflectivity of the simulation results simply multiply 180. Another possible factor resulting in a difference between the experimental data and simulation results is a change in the optical properties of the material due to the thin layer effect. 5.3.4 Comparison of the internal quantum efficiency Figure 5.25 shows the simulation results of the quantum efficiency. The structures used for the simulation are exactly the same as in the above simulation. Part (a) is for the light perpendicularly incident on the devices, which is the same for the time response measurement as in Fig. 5.17; while in part (b), the incident angle for the simulation is about 50o, which is the same for current-voltage measurement shown in Fig. 5.10. The structures, the dispersion effects coming from the materials, and the absorption coefficients changing with wavelength are the same as those used for the simulation of the reflectivity spectrum in the previous section. The only difference is that there is not a cap layer in the simulation of the quantum efficiency. Incidentally, the cap layer in the growth structure will be used for high electron mobility transistor (HEMT) device design. 164 0.2 Quantumefficiency (a.u.) Quantumefficiency (a.u.) 0.2 0.1 0.1 0.0 650 700 750 800 850 900 950 1000 1050 0.0 650 700 750 800 850 900 950 1000 1050 Wavelength(nm) Wavelength(nm) (a) (b) Figure 5. 25 Comparison of simulation results of quantum efficiency between undoped device and doped device. ο: undoped device; •: doped device. (a) incident angle is 0o; (b) incident angle is 50o. There is an obvious difference between Fig. 5.25 and Fig. 4.6. The quantum efficiency shows asymmetric behavior on both sides of the resonant wavelength. The simulation results in Fig. 4.6 do not include the effects originating from the absorption coefficient’s dependence on wavelength. The absorption coefficient is assumed to be 1 µm-1 within the entire spectrum region, however Fig. 1.10 indicates a large difference within different spectrum regions of the absorption coefficient. Figure 1.10 shows no absorption when the wavelength of the incident light is larger than approximately 900 nm. GaAs has stronger absorption ability in the high energy region, resulting in an asymmetric curve as shown in Fig. 5.25. Since the absorption coefficient at the resonant wavelength is around 0.3 µm-1, smaller than 1 µm-1 used in the simulation of Fig. 4.6, the quantum efficiency is lower in the figure at the resonant wavelength. 165 Figure 5.25 shows that the magnitude of the peak value at the resonant wavelength of the doped device is slightly larger than that of the undoped device in part (a) while about two times larger in part (b). FWHM of the doped device is around 17.0 nm, while in the undoped device it is around 20.2 nm in part (b). For light normally incident on the devices, the FWHM in both devices is 25.6 nm, slightly smaller than that in the selectivity spectrum, which can also be explained when we consider that absorption effects in the wide gap material have not been included in the simulation. For light almost perpendicularly incident on the devices at 850 nm as shown in part (a), the quantum efficiency of the doped devices is 14.3% while in the undoped device, it is 12.2%. Therefore, a four times magnitude difference in the time response measurement in Fig. 5.17 can not be explained only from the difference of the growth structure. When the devices are illuminated at an angle around 50o away from the normal incident at 850 nm, the quantum efficiency of the doped devices is about two times of that of the undoped devices. This result also can not account for the greater than one order of magnitude difference in the current voltage measurement under low bias. The above description further supports our explanation for the increase in responsivity and speed of response. It is attributable to the vertical electric field and potential profile in the direction of growth due to delta modulation doping. 5.4 Conclusions An AlGaAs/GaAs based resonant-cavity-enhanced, heterostructure metal- semiconductor-metal photodetector with a Al0.24Ga0.76As/Al0.9Ga0.1As distributed Bragg 166 reflector operating around 850 nm was fabricated and tested. Delta doping is employed in the top AlGaAs layer to produce a confined electron cloud and an associated transverse electric field. The effect of doping is investigated by current-voltage and temporal response measurements of doped and undoped devices. We observe concurrent improvement in dark current under low biases, in DC photoresponse, and in time and frequency response. We suggest that the mechanism responsible for reduction of dark current is the enhancement of the cathode metal-semiconductor barrier due to the effect of the confined electron cloud, as well as band bending in the wide gap material at the anode that reduces hole current flow. Time response data consistently shows improvement of peak response, fall time and FWHM for the doped device. The increase in responsivity and speed of response is attributed to the vertical electric field and potential profile in the direction of growth due to delta modulation doping. In Section 5.3, the growth structures from TEM pictures have been employed to simulate the internal quantum efficiency, which further demonstrates that the vertical electric field and potential profile in the direction of growth due to delta modulation doping is responsible for the improvements observed. These favorable performance characteristics combined with the substrate and compatibility of the structure with high electron mobility transistors, makes the delta doped device an excellent candidate for short haul (local area) high speed telecommunication applications. 167 6. Contributions and Future Directions 6.1 General First, we conclude by emphasizing the main contributions of this thesis in this chapter. Second, future work that will continue the development and analysis of GaAs and InP based photodetectors is discussed. In theoretical analysis parts, ISE-TCAD commercial simulation tool will be employed to achieve the electric field profile in the devices and Ramo’s theory will be used to depict the dynamic behavior of the devices. For the experimental portion, transmission lines have been designed for high speed measurement to remove the limitations of the test systems. An electro-optical test will be used for the time response test in the future. Besides this work, the growth structure can be designed for HEMT devices. The last part of the future work lists the different device designs for HEMT. 6.2 Contributions In this dissertation we developed a closed-form model to describe the electronic properties of delta modulation doped heterostructures, particularly the 2DEG sheet charge density and the electric field distribution in the direction of growth. The model includes the effects of real-space charge transfer and carrier degeneracy. The electron transfer and quasi-equilibrium condition in the growth direction have been used in order 168 to express the 2DEG sheet charge density as a function of only material parameters and constants. An empirical constant, corresponding to quantized energy states, has been employed to further simplify this description and to arrive at a closed form expression. Results from the analytical expressions are compared with numerical simulations based on a self-consistent solution of modified Schrödinger and Poisson equations. We designed two III-V material based HMSM photodetectors with RCE and delta doping in the wide bandgap material in this dissertation, where HMSM is compatible with monolithic OEIC technology, RCE solves the trade-off between fast speed and high quantum efficiency while, at the same time, offering narrow spectral bandwidth detection useful in wavelength-division multiplexing (WDM) applications, and the delta doping plane in the wide band material modulates the Schottky barrier height to further reduce dark current. The GaAs-based design is for short haul optical communication; while the InP based design is for long haul optical communication. The GaAs based photodetector utilizes a Al0.24Ga0.76As/ Al0.9Ga0.1As distributed Bragg reflector (DBR) operating around 0.85 µm; while the InP based photodetector employs a In0.527Al0.144Ga0.329As/ InP (DBR) operating around 1.55 µm. A transmission line model is employed to design the resonant cavity and the distributed Bragg reflector (DBR) while a closed-form model is used to optimize the electronic properties of delta modulation doped heterostructures, particularly the 2DEG sheet charge density and the electric field distribution in the direction of growth. The simulation results show clear peaks at 0.85 µm with a 30 nm full width at half maximum (FWHM) and 1.55 µm with a 0.1 µm FWHM for GaAs based and InP based photodetectors, respectively. Also, the simulation results show that the GaAs and InP 169 based photodetectors have a seven-fold and a 3.5 fold increase in quantum efficiency at the resonance wavelength compared to a detector of the same absorption depth respectively. Based on the simulation results and discussions of the optical and electrical properties of the device, an optimization including wavelength selectivity, optical sensitivity, quantum efficiency, and dynamic speed are considered in the design. The HMSM RCE GaAs-based photodetectors have been fabricated, characterized and analyzed. The photocurrent spectrum shows a clear peak at this wavelength with full width at half maximum (FWHM) of around 30 nm. Photo response shows 0.08 A/W average photo responsivity, which means the device has a 4.4 fold photoresponse increase over the conventional device with an assumption of 0.5 µm-1 absorption coefficient at 850 nm. The top reflector is a delta modulation doped Al0.24Ga0.76As layer that also acts as the barrier enhancement layer producing a low dark current of 9.2 fA/µm2. The breakdown voltage is above 20 V. Time response measurements show rise time, fall time and FWHM of 9 ps, 18.4 ps, and 10.6 ps, respectively, giving a 3dB bandwidth of about 33-GHz. Capacitance-voltage measurements indicate a less than 30 fF capacitance value. Delta doping of the top AlGaAs layer produces a confined electron cloud and an associated electric field. The delta doped device shows a factor of 7.8 reduction in dark current and a factor of 1.6 increase in DC photocurrent with a 4 volts bias, and about 7 GHz expansion of the 3dB bandwidth under 5V bias compared to an undoped device. We propose that the mechanism responsible for the reduction of dark current is enhancement of the cathode metal-semiconductor barrier due to the confined electron cloud, as well as band bending in the anode that reduces hole current flow. The increase in responsivity 170 and speed of response is attributed to the vertical electric field and potential profile in the direction of growth. 6.3 Future Work 6.3.1 ISE-TCAD simulation In previous work of our group, ISE-TCAD commercial simulation software results show that there is a strong electric field in thin Al0.24Ga0.76As layer. Al0.24Ga0.76As wide gap material does not contribute to the dark current in the typical device structure shown as Fig. 6.1. Moreover, due to its energy gap value, this layer is transparent to radiation of wavelength greater than 710 nm. The underlying GaAs is responsible for the absorption and current flow. In the narrow band gap material GaAs, the vertical component of the electric field depends on the doping of the AlGaAs layer, in the sense that it increases as the doping concentration level increases in AlGaAs. This aiding field pushes the photogenerated electrons toward the AlGaAs/GaAs interface. While falling in the triangular well, the electrons will drift towards the anode due to the applied horizontal field. For the HMSM RCE-PD devices, the current-voltage characteristics under light have been measured for both the undoped and the doped devices. From the comparison of the experimental data, the above description can be employed to explain the different characteristics between these two devices. Therefore, it is necessary to calculate the 171 electric-field profiles in these two different types of devices under different experimental conditions. Light Schottky Schottky n-AlGaAs 500Å AlGaAs spacer 100Å GaAs 5000Å 2DEG GaAs Substrate Figure 6. 1 HMSM typical device structure. The commercial software- ISE-TCAD is a multidimensional, electrothermal, mixed mode device and circuit simulator for one-, two-, and three-dimensional semiconductor devices. This software should be used to construct a two-dimensional electric field profile for modeling the dynamic behavior of the device. 172 6.3.2 Dynamic behavior Interdigital MSM Schottky contact diodes fabricated on GaAs or InP are attractive photodetectors for multigigabit optical communication systems. The most appealing features for the application of MSM photodetectors as the front end of integrated high frequency optoelectronic receivers are their fast response, high sensitivity, and low dark current. The response is determined by carrier transit times and resistorcapacitor (RC) charging times of the external circuit. The response of small area detectors is then dominated by carrier transit times which in principle can be minimized by choosing a small distance between the Schottky contacts. Such a geometry permits rapid carrier collection after photoexcitatoin. To optimize the design of MSM detectors of a required bandwidth, it is necessary to identify the factors limiting their performance and to investigate the variation of their properties. A numerical simulator based on a finite difference numerical method and on Monte Carlo procedure should be employed to describe the dynamic behavior. The following paragraph is a brief description of the principles of the method. When a photon interacts within the semiconductor, it produces a certain number of hole-electron pairs. If an electric field is applied, the photo-produced charges drift toward their respective electrodes. The single carrier motion induces a current signal on the external read-out circuit, which can be evaluated by Ramo’s theorem [149, 150]: r r i (t ) = eν • E w (6.1) where i(t) is the instantaneous current received by the given electrode due to a single carrier motion, e is the electrode charge, v is the carrier velocity, which is a function of the drift field, and Ew is the so-called “weighing field”. The weighing field Ew(x,z) is 173 calculated by grounding all the electrodes with the exception of the investigated anode, which is raised to unit potential. Z X Schottky Schottky Schottky 0 V 0 Figure 6. 2 Cross section of simulated device: X is carrier transport direction, Z is growth direction; device is biased at V volts. A different finite method has been adopted to calculate Ew and the other physical quantities of interest. The model is two-dimensional: the Laplace equation is solved in an x-z section of the detector over a numerical grid with a constant mesh, finite difference iterative method. Figure 6.2 shows a cross section of the simulated device. There is an assumption that the active region of a SI GaAs or SI InGaAs reverse biased detector is almost neutral so the Laplace equation can be used to solve the electrostatic problem. In this way, the potential V(x,z) and the electric field E(x,z) distributions are found. The hole 174 and electron drift velocity is calculated from the electric field using parameterization of the experimental data [144, 145]. This work is presently continuing in our research group. 6.3.3 Electro-Optic measurement of microwave circuits It has been mentioned in Chapter 5 that the measurement systems may have prevented us from drawing conclusions about the intrinsic photoresponse speed. A technique which utilizes short-pulse lasers and electro-optic materials for measuring electrical transients has extremely high temporal resolution, which is less than 300 femtoseconds. A sample structure optimized for electro-optical (EO) sampling measurements has been designed that will be explained below. EO sampling mechanism will be explored. Electro-optic sampling uses the principle of an electric field induced birefringence in crystals such as lithium tantalate. Introduction of the lithium tantalate into an electric field, such as that radiated above a circuit, results in a linear change in the refractive index ellipsoid for a given direction through the crystal. Measurement of the refractive index change is achieved by detecting the polarization rotation induced in an optical beam passing through the crystal. The extent of polarization rotation gives a direct measurement of the electric field strength. Figure 6.3 shows the electro-optic sampling system schematic. A commercial Ti: sapphire laser will be used to excite picosecond pulse in the microbridge and electrooptically measure the signal propagating on the coplanar waveguide (CPW) line or coplanar strip (CPS) line. 175 Figure 6. 3 Electro-optic sampling system schematic [151]. The laser provids ~ 100fs wide optical pulses (76 MHz repetition rate), which are split into two paths. The first (excitation) beam is frequency doubled in a nonlinear crystal, intensity modulated, and focused by a microscope objective to a 10 µm diameter spot on MSM. The second (sampling) beam traveles through a computer-controlled delay line and is focused on a ~10 µm diameter spot at the gap between the center and ground CPS or CPW line, only ~20 µm from MSM where it is generated. The sampling beam is reflected by a dielectric infrared coating on the bottom face of the LiTaO3 crystal and directed to an analyzer. The electric field of the measured pulse, which is parallel to the LiTaO3 optical axis, induces extra birefringence into an intensity change that is detected 176 at the modulation frequency by a lock-in amplifier, resulting in a time-domain mapping of the electric field at the sampling point. Figrue 6.4 is the experimental setup for the Electro-optic measurement. Figure 6. 4 External electro-optic sampling scheme[151]. 6.3.4 HEMT design We designed a new cluster of devices with active area of 40x40 µm2, employing the same planar interdigital structure. Arrays of devices were produced with metal finger width varying between 1-2 microns in steps of 1 micron, and inter-finger spacing varying between 2-4 microns. 177 The design criteria are to investigate other alternative designs that are compatible with the same wafer structure; i.e., still holds compatibility to HEMT and MESFET amplifiers. The fabrications of the following group of new devices are in progress: HMSM (Sh-Sh): Schottky contact on both sides of the barrier enhancement layer. HMSM (Oh-Sh): Ohmic contact on one side of the barrier enhancement layer, and Schottky contact on the other side of the barrier enhancement layer. HMSM (Sl-Sl): Schottky contact on both sides of the 2DEG. HMSM (Oh-Sl): Ohmic contact on one side of the barrier enhancement layer, and Schottky contact on the other side of the 2DEG. HEMT with Ohmic contacts. Figure 6.5 shows the series of GaAs based heterostructure RCE devices, while Fig. 6.6 indicates InP based heterostructure RCE devices. 178 Schottky Schottky 500Å Al0.24Ga0.76As n-(6~8*1014cm-3) barrier enhancement layer Si δ-doping 5 x 1012cm-2 Al0.24Ga0.76As 50Å GaAs 1175Å 2DEG (λ/4n) Undoped Al0.24Ga0.76As (596 Å) 20 periods HMSM (Sh-Sh): Schottky contact on both sides of the barrier enhancement layer. (λ/4n) Al0.9Ga0.1As (676 Å) 25nm GaAs Buffer GaAs Substrate Ohmic Schottky 500Å Al0.24Ga0.76As n-(6~8*1014cm-3) barrier enhancement layer Si δ-doping 5 x 1012cm-2 Al0.24Ga0.76As 50Å GaAs 1175Å 2DEG (λ/4n) Undoped Al0.24Ga0.76As (596 Å) (λ/4n) Al0.9Ga0.1As (676 Å) 25nm GaAs Buffer GaAs Substrate 20 periods HMSM (Oh-Sh): Ohmic contact on one side of the barrier enhancement layer, and Schottky contact on the other side of the barrier enhancement layer 179 500Å Schottky Al 0.24Ga 0.76As layer Schottky Si δ-doping 5 x 10 12cm -2 Al0.24Ga 0.76 As 50Å GaAs 1175Å 2DEG (λ/4n) Undoped Al 0.24Ga 0.76As (596 Å) 20 periods (λ/4n) Al0.9Ga 0.1As (676 Å) 25nm GaAs Buffer HMSM (Sl-Sl): Schottky contact on both sides of the 2DEG. GaAs Substrate Ohmic 500Å Al0.24Ga0.76As n-(6~8*1014cm-3) barrier enhancement layer Schottky Si δ-doping 5 x 1012cm-2 Al0.24Ga0.76As 50Å GaAs 1175Å 2DEG (λ/4n) Undoped Al0.24Ga0.76As (596 Å) (λ/4n) Al0.9Ga0.1As (676 Å) 25nm GaAs Buffer GaAs Substrate 20 periods HMSM (Oh-Sl): Ohmic contact on one side of the barrier enhancement layer, and Schottky contact on the other side of the 2DEG 180 Source Drain Gate Ohmic Ohmic Schottky 500Å Al0.24Ga0.76 As n-(6~8*1014 cm-3) barrier enhancement layer Si δ-doping 5 x 1012cm-2 Al0.24Ga0.76 As 50Å GaAs 1175Å 2DEG (λ/4n) Undoped Al0.24Ga0.76As (596 Å) 20 periods HEMT with Ohmic contacts (λ/4n) Al0.9Ga0.1As (676 Å) 25nm GaAs Buffer GaAs Substrate Figure 6. 5 Series of GaAs based heterostructure RCE devices. 181 Schottky Schottky 500Å In0.52Al0.48As n-(6~8*1014cm-3) barrier enhancement layer Si δ-doping 1 x 1013cm-2 In0.52Al0.48As 50Å In0.53Ga0.47As 3858Å 2DEG (λ/4n) Undoped InP (1223 Å) 15 periods HMSM (Sh-Sh): Schottky contact on both sides of the barrier enhancement layer (λ/4n) In0.527Al0.144Ga0.329As (1133 Å) 25nm InP Buffer InP Substrate Ohmic Schottky 500Å In0.52Al0.48As n-(6~8*1014cm-3) barrier enhancement layer Si δ-doping 1 x 1013cm-2 In0.52Al0.48As 50Å In0.53Ga0.47As 3858Å 2DEG (λ/4n) Undoped InP (1223 Å) (λ/4n) In0.527Al0.144Ga0.329As (1133 Å) 25nm InP Buffer InP Substrate 15 periods HMSM (Oh-Sh): Ohmic contact on one side of the barrier enhancement layer, and Schottky contact on the other side of the barrier enhancement layer 182 500Å In0.52 Al0.48 As Schottky Schottky Si δ-doping 1013cm-2 In0.52 Al0.48 As 50Å In0.53Ga0.47As 3858Å 2DEG 15 periods (λ/4n) Undoped InP (1223 Å) HMSM (Sl-Sl): Schottky contact on both sides of the 2DEG (λ/4n) In0.527 Al 0.144Ga0.329As (1133 Å) 25nm InP Buffer InP Substrate Ohmic 500Å In0.52Al0.48As Schottky In0.52Al0.48 As 50Å In0.53Ga0.47As 3858Å 2DEG (λ/4n) Undoped InP (1223 Å) (λ/4n) In0.527Al0.144Ga0.329As (1133 Å) 25nm InP Buffer InP Substrate Si δ-doping 1013cm-2 15 periods HMSM (Oh-Sl): Ohmic contact on one side of the barrier enhancement layer, and Schottky contact on the other side of the 2DEG 183 Source Ohmic Drain Gate Ohmic Schottky 500Å In0.52 Al0.48 As n-(6~8*1014 cm -3) barrier enhancement layer Si δ-doping 1013cm-2 HEMT with Ohmic contacts In0.52 Al0.48 As 50Å In0.53Ga0.47As 3858Å 2DEG (λ/4n) Undoped InP (1223 Å) 15 periods (λ/4n) In0.527 Al 0.144Ga0.329As (1133 Å) 25nm InP Buffer InP Substrate Figure 6. 6 Series of InP based heterostructure REC devices. 184 LIST OF REFERENCES 1. 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Here, the traveling time, t, is defined as the window size for the reflection free time, thus eliminating from waveforms the artifacts that may be caused by reflections at the end of the transmission line. Parameter t can be expressed by t= 2l Vg (A.1) Here, l is the length of the transmission line and Vg is the group velocity of the microwave signal and Vg is defined by Vg = c ε re (A.2) εre is the effective relative dielectric constant considering quasi-TEM mode. Since the FWHM of all of our devices is less than 13 ps using oscilloscope measurement, the reflection free window is designed around 40 ps. The width of the transmission line must be determined by impedance matching. The characteristic impedance of the coaxial line is 50Ω. If the characteristic impedance of the transmission line is designed to 50Ω, which means it is matched to that of the coaxial line, it will reduce the reflection effect. 198 A2 Formula for Calculation Photodetector l=2.25mm l=2.25mm 45.5µm 2b=96µm 2a=5µm 45.5µm Figure A. 1. signal ground Coplanar stripe transmission line scheme with a 50 µm pitch. The definition of the pitch for CPS is given by pitch = 2 × a + (b − a) (A.3) where 2a is the width of the space between the metal, 2b is the width between the edges of the two metals, which will be seen in Fig. A.1. And the definition of the pitch for CPW is given by pitch = b + c−b 2 (A.4) where 2a is the width of the signal line, 2b and 2c are shown in the CPW schematic (Fig. A.2). 199 ground 500µm Photodetector 58µm l=2.25mm 2c=1200µm 2b=200µm l=2.25mm signal 2a=84µm 58µm 500µm Figure A. 2. ground Coplanar waveguide transmission line scheme with a 350 µm pitch. The equations (A.5-A.8) will be employed to achieve optimized structures for the electro-optic sampling measurement [1]. k' = 1− k2 (A.5) π K (k ) for 0 ≤ k ≤ 0.707 = ' K (k ) ln[2 × (1 + k ' ) /(1 − k ' )] (A.6 a) K (k ) 1 = ln[2 × (1 + k ) /(1 − k )] for 0.707 ≤ k ≤ 1 K ' (k ) π (A.6 b) 200 The formula for calculating the characteristic impedance of CPS are given by Eq. (A.7) k1 = a b (A.7 a) k2 = sinh(πa / 2h) sinh(πb / 2h) (A.7 b) ε re = 1 + Z 0cs = ε r − 1 K (k2 ) K ' (k1 ) 2 K ' (k2 ) K (k1 ) 120π K (k1 ) ε re K ' (k1 ) (A.7 c) (A.7 d) where h is the thickness of the substrate. The equations (A.7) are used in the symmetric CPS with finite dielectric thickness. The formula for calculating the characteristics impedance of CPW are given by k3 = a 1 − b2 / c2 b 1 − a2 / c2 (A.8 a) k4 = sinh(πa / 2h) 1 − sinh 2 (πb / 2h) / sinh 2 (πc / 2h) sinh(πb / 2h) 1 − sinh 2 (πa / 2h) / sinh 2 (πc / 2h) (A.8 b) ε re = 1 + Z 0cp ε r − 1 K ( k 4 ) K ' ( k3 ) 2 K ' ( k 4 ) K ( k3 ) 30π K ' (k 3 ) = ε re K (k 3 ) (A.8 c) (A.8 d) where h is the thickness of the substrate. And Eq. (A.8) is used in the symmetric CPW with finite dielectric thickness and finite width ground planes. 201 140 140 120 120 100 100 80 80 60 60 40 40 20 0.01 0.1 Pitch (µm) Simulation Results Characteristic impedance (Ω) A3 20 0.7 Ratio a/b Figure A. 3. Simulation results for CPS with a pitch of 50 µm. The probe size limits CPS with a pitch 50 or 100 µm, CPW with a pitch of 350 µm. The thickness of the substrate is assumed to 600 µm in the following design. Figure A.3 shows the simulation results if the pitch is equal to 50 µm. From Figure A.3, it can be seen when a/b ratio equals 0.052, Z0cs equals 50 Ω and pitch equals 50 µm. By using the formula (A.7), the values of 2a=5 µm, 2b = 96 µm, and εre = 7.09 are shown in Fig. A.1. Thus, the group velocity is given by Eq. (A.2). Here Vg is equal to 1.13∗108 m/s. If the window size is 40 ps, the length of the transmission line is 202 equal to l = Vg × t 2 = 2.25mm . Figure A.4 shows the simulation results for the pitch of 100 160 160 140 140 120 120 100 100 80 80 60 60 40 40 20 0.01 0.1 Pitch (µm) Characteristic impedance (Ω) µm. 20 0.7 ratio of a/b Figure A. 4. Simulation results for CPS with a pitch of 100 µm. From Figure A.4, it can be seen when a/b ratio equals 0.053, Z0cs equals 51.5 Ω and pitch equals 100 µm. By using the formula (A.7), the values of 2a=10 µm, 2b = 190 µm, and εre = 7.08 are shown in Fig. A.5. Thus, the group velocity is given by Eq.(A.2). Here Vg is equal to 1.13∗108 m/s. If the window size is 40 ps, the length of the transmission line is equal to l = for CPW with a 350 µm pitch. Vg × t 2 = 2.25mm . Figure A.6 shows the simulation results 203 Photodetector l=2.25mm l=2.25mm 90µm 2b=190µm 2a=10 µm 90µm Figure A. 5. Charateristic impedance (Ω) ground Coplanar strip transmission line scheme with a 100 µm pitch. 140 120 100 80 60 40 20 0.01 0.1 0.7 Ratio a/b Figure A. 6. signal Simulation results for CPW with a pitch of 350 µm. 204 From Figure A.6, it can be seen that when a/b ratio equals 0.42, Z0cs equals 50 Ω and pitch equals 350 µm. By using formula (A.8), the values of 2a=84 µm, 2b = 200 µm, and εre = 7.08 are shown in Fig. A.2. Thus, the group velocity is given by Eq. (A.2). Here Vg is equal to 1.13∗108 m/s. If the window size is 40 ps, the length of the transmission line is equal to l = Vg × t 2 = 2.25 × 10− 3 m = 2.25mm . Reference: 1. K. C. Gupta, R. Garg, I. Bahl, and P. Bhartia, “Microstrip Lines and Slotlines,” Artech House, 2nd Edition, 1996. 205 VITA Xiying Chen was born in Tongling, P. R. China in February 1972. She received her Bachelor of Science majoring in applied physics from the department of Physics II of Fudan University in June of 1993 and Master of Science majoring in condensed matter physics from the department of Physics of Fudan University in June of 1996. From 1996 to 1997, she was a process metrology engineer and then became a failure analysis engineer at Huahong microelectronic company in Shanghai of China. She then worked for Huahong – NEC electronic company in Shanghai of China from 1997 to1998 as a product engineer who handled process integration and quality control for a 0.35 µm 8 inch DRAM product line. From September 1998, while a graduate student at Drexel University, she was involved in several research activities, which included InGaAs/InP designs for optoelectronic devices used in long haul communications, AlGaAs/GaAs designs for optoelectronic devices used in short haul communications, theoretical derivation of a closed-form expression to analyze electronic properties in δ-doped heterostructures, optical and electronic buffer in optical communications, AlGaAs/GaAs heterodimensional device designs, and monolithic laser driver for OC768. Her main research interest was to design new optical receivers for optical communications. During her graduate studies at Drexel University, she designed two novel photodetectors, a GaAs based photodetector for short haul communication, and an InP based photodetectors for long haul communication. Her research activities have been published in several prestigious technical journals: J. Applied Physics, Applied Physics Letters, J. Crystal Growth, J. Vaccum Science & Technology B, Surface and Interface Analysis, Acta Physics Sinica, and Chinese J. Semiconductor. She has published fourteen journal papers, nine conference papers, and holds two patents. Currently, she has submitted three journal papers. She was awarded the 2nd best student paper in 2001 and the 1st best student paper in 2002 at IEEE Sarnoff Symposium on Advances in Wired and Wireless Communications, New Jersey. She has received Allen Rothwarf Outstanding Graduate Student Award from Drexel University in 2001. In 1993, she achieved the Honored Graduate by Higher Education Bureau of Shanghai. Ms. Chen is a student member of IEEE.