Fiber Jamming and Fiber Matrix Separation during Compression
Transcription
Fiber Jamming and Fiber Matrix Separation during Compression
Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. www.kunststofftech.com © 2006 Carl Hanser Verlag, München Wissenschaftlicher Arbeitskreis der UniversitätsProfessoren der Kunststofftechnik Zeitschrift Kunststofftechnik Journal of Plastics Technology archivierte, rezensierte Internetzeitschrift des Wissenschaftlichen Arbeitskreises Kunststofftechnik (WAK) archival, reviewed online Journal of the Scientific Alliance of Polymer Technology www.kunststofftech.com; www.plasticseng.com eingereicht/handed in: 29.05.2006 angenommen/accepted: 19.06.2006 Alejandro Londoño-Hurtado, Prof. Tim Osswald Department of Mechanical Engineering, University of Wisconsin, Madison Fiber Jamming and Fiber Matrix Separation during Compression Molding Fiber jamming is perhaps the least understood defect in molding of polymer composites. This paper presents a description of the problem, introduces a mechanistic model and a dimensional analysis developed to predict fiber distribution in ribbed sections. Autor/author Alejandro Londoño-Hurtado, Prof. Tim Osswald Department of Mechanical Engineering, University of Wisconsin-Madison 1513 University Avenue Madison, WI 53706 E-Mail-Adresse: osswald@engr.wisc.edu londonohurta@wisc.edu Verlag/Publisher: Carl-Hanser-Verlag Jürgen Harth Ltg. Online-Services & E-Commerce, Fachbuchanzeigen und Elektronische Lizenzen Kolbergerstrasse 22 D-81679 Muenchen Tel.: 089/99 830 - 300 Fax: 089/99 830 - 156 E-mail: harth@hanser.de Herausgeber/Editor: Europa/Europe Prof. em. Dr.-Ing. Dr. h.c. G. W. Ehrenstein, verantwortlich Lehrstuhl für Kunststofftechnik Universität Erlangen-Nürnberg Am Weichselgarten 9 D-91058 Erlangen Deutschland Phone: +49/(0)9131/85-29700 Fax.: +49/(0)9131/85-29709 E-Mail-Adresse: ehrenstein@lkt.uni-erlangen.de Amerika/The Americas Prof. Dr. Tim A. Osswald, responsible Polymer Engineering Center, Director University of Wisconsin-Madison 1513 University Avenue Madison, WI 53706 USA Phone: +1/608 263 9538 Fax.: +1/608 265 2316 E-Mail-Adresse: osswald@engr.wisc.edu Beirat/Editorial Board: Professoren des Wissenschaftlichen Arbeitsk reises Kunststofftechnik/ Professors of the Scientific Alliance of Polymer Technology Carl Hanser Verlag Zeitschrift Kunststofftechnik/Journal of Plastics Technology 2 (2006) 4 Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. www.kunststofftech.com © 2006 Carl Hanser Verlag, München FIBER JAMMING AND FIBER MATRIX SEPARATION DURING COMPRESSION MOLDING Alejandro Londoño-Hurtado, Prof. Tim Osswald . University of Wisconsin, Madison. Fiber jamming is perhaps the least understood defect in molding of polymer composites. This paper presents a description of the problem, introduces a mechanistic model and a dimensional analysis developed to predict fiber distribution in ribbed sections. In diesem artikel wird ein mechanitisches Model der Faser/Matrix-Entmischung entwickelt und eine Ähnlichkeitsanalyse fur geripte SMC und GMT Bauteilen presentiert. Faser/Matrix-Entmischung ist vielleicht einer der am wenigsten verstandenem phenomenen in der Faserverbuntwerkstoffe-Verarbeitung. 1 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Fiber Jamming Compression molding of sheet molding compounds (SMC) and glass mat reinforced thermoplastics (GMT) are common processes used to produce lightweight inexpensive fiber reinforced parts, especially for the automotive industry. During the manufacturing process, the material is squeezed and forced to flow until the charge covers the whole mold cavity. This causes material to flow around sharp corners and into areas that are difficult to access by the molding compound, such as ribs and bosses. As the material is forced to flow, the resin matrix is often squeezed out of the bed of fibers. This leads to fiber density distributions throughout a part; Figure 1. depicts this behavior. These variations affect the mechanical properties of the finished part as well as their surface finish. Variations in fiber density within a part will lead to surface waviness and defects in the finished product. Fiber-matrix separation is perhaps the least understood and understudied effect in fiber reinforced materials molding processes. Figure 1: Uneven fiber distribution in a compression molded part Mechanistic mathematical models that simulate fiber flow have been used for more than four decades. The work of Batchelor [1] and his slender body theory can be highlighted as one of the precursors in the study of suspended particles in fluids. Jeffery [2,3] and Tucker [4,5] provided the foundations for many of the current models . In recent years, Brady et. al. [6-8] have also made important contributions in this area, having significant influence in later works. Phan-Thien et. al. [9] incorporated long range hydrodynamic interactions into Jeffery's model. Schmidt et. al. [10] have done work for flexible fibers at low concentrations. Simulations at high fiber concentrations are a matter of interest for polymer processing. The work presented in this paper is part of an effort to characterize the processing of fiber reinforced composites. 1 CHARACTERIZATION OF FIBER SUSPENSIONS Fiber suspensions are classified according to the amount of concentration of fibers in the matrix. A fiber suspension is said to be dilute if less than one fiber on average is found in a spherical volume of diameter equal to the fiber length, nL3 ≤ 1 , where n is the number of fibers per unit volume. A semi-dilute regime is Journal of Plastics Technology 2 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Fiber Jamming characterized by 1 < nL3 < r p and nL2 << 1 . Here L is the fiber length and r p is the aspect ratio of a fiber of diameter D. rp = L D (1) In the semi-concentrated regime, fibers are significantly disturbed by other fibers during rotation and they can no longer rotate smoothly without crossing through the excluded volume of another fiber [11]. A suspension is said to be concentrated when nL3 > r p . In this case, fibers are assumed to be interacting with each other and the effect of mechanical contacts becomes dominant. The presence of mechanical contacts can significantly increase the stress in a suspension by changing fiber orientation as well as by transmitting stress through contacting fibers. For small aspect ratios, mechanical contacts are the main mechanism causing orientational dispersion. Far field hydrodynamics starts playing a decisive role for higher aspect ratios. As the fiber concentration is increased, it is likely that contact and hydrodynamic forces will have a joint effect. At very high concentrations, a state where each fiber has several mechanical contacts, mechanical contacts will prevail over far field hydrodynamic interactions [12,13]. The number of fibers, any given fiber may interact with as it rotates, is called the crowding factor N crowd [14] N crowd = 2φcrit r p 2 3 (2) Where φcrit is known as the critical concentration and is defined as one fiber, on average, in the spherical volume with a diameter equal to the fiber length. Above this concentration, fibers are not able to rotate without contacting other fibers. The formation of fiber networks is determined by the combination of processing parameters and material properties, which will be covered in the next section. 2 FIBER NETWORK FORMATION When a fiber suspension is driven by a flow, the fibers are subjected to viscous and dynamic forces that cause them to bend. When the flow comes to rest, the fibers try to regain their original unstrained shape. Depending on the concentration, a fraction of the fibers will come in contact with other fibers and they will come to rest in strained positions where forces will be transmitted from fiber to fiber. When a fiber is locked into a network in a strained configuration, it must possess at least three contact points with other fibers [15]. These contact points must be located on alternate sides of the fiber. At low concentrations, there will Journal of Plastics Technology 3 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Fiber Jamming be some fibers that do not become entangled in this manner. Fiber network formation and fiber jamming is governed by processing and physical parameters. For a specific process, the effect of a certain parameter may vary in magnitude or not have any effect at all, as is the case of magnetic effects in compression molding. The following parameters have been identified to play a role in fiber network formation [16]: Colloidal forces: These forces are caused by the chemical characteristics of the fibers and the suspending fluid; they are usually not taken into account when modeling fiber motion in glass fiber composites. Surface tension effects: These are due to entrained gas within a fiber suspension. Bubbles of gas may appear in fiber suspensions due to mixing or other processing factors. Bubbles stay in particle interstices and create an effective attractive force between particles due to free surface effects. Mechanical surface linkages: Its origin is in contacts involving irregularly shaped fibers with surface protrusions. Also, small fibrous entities (fibrils) of the fiber may extend out from the fiber surface. In this case, the fibrils of contacting fiber surfaces may become mechanically entangled. Elastic fiber interlocking: This is found when fibers form an elastic network. Flowing fiber suspensions may experience sufficient viscous forces to cause fibers to elastically deform from an equilibrium configuration. As the fibers attempt to relax, they can become locked in elastically strained configurations due to contacts with other fibers. The fiber surfaces experience friction forces that are proportional to the normal force between fibers, and the normal force is a function of the fiber flexibility Flocculation: Occurs when a dispersion of fibers is dilute enough and fibers tend to aggregate in groups or flocs. This process is known as flocculation and only occurs if fibers interact. Experimental studies [14] have shown that although N crowd is directly related to flocculation, a high value of N crowd doesn't necessarily imply that flocculation will take place [12]. Other parameters like r p and the viscosity of the matrix, are also involved. For example, when the fluid's viscosity is increased, the value of the crowding factor at which flocculation occurs is also increased. 3 MECHANISTIC ANALYSIS OF FIBER SUSPENSIONS In order to study the fiber interactions occurring in the compression molding process, a mechanistic mathematical model was used to predict the configuration. These kind of models use the classical equations of motion, combined with the momentum equations for fluid flow, to study the movement of Journal of Plastics Technology 4 © 2006 Carl Hanser Verlag, München Fiber Jamming the fibers in a suspension at any time from the start of the flow until it has ceased. The following section describes the methodology used to model fiber suspensions subject to a shearing flow. 3.1 SIMULATION METHOD The simulation used in this work, models fiber suspensions as linked cylinders with hemispherical end caps, connected by ball and socket joints as shown in Fig 2. In the case of polymer processing, some assumptions and simplifications are made without altering the accuracy of the results. As a first simplification, fiber extensibility is neglected, since fiber length remains virtually unchanged in polymer processing processes. Far field hydrodynamic interactions can be neglected for high fiber concentrations since frictional forces dominate the flow. Finally, the fibers are assumed as neutrally buoyant with no other external fields applied. The equations of motion for a fiber include the reaction forces between the hinges and contact forces between fibers: Nc i Fi hyd + X i +1 − X i + ∑ FIKcon = 0 (3) k Where Fi hyd are the hydrodynamic drag forces, X i are the joint forces in the hinges and FIKcon are the contact forces. The equation of momentum is, Nc i Ti hyd + Yi +1 − Yi + Lp i × [X i +1 + X i ] + ∑ Gik × Fikcon = 0 (4) k www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Figure 2: Schematic diagram of a model fiber. Journal of Plastics Technology 5 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Fiber Jamming Where Ti hyd is the hydrodynamic torque, Yi the joint torque and the third and fourth terms are the torques exerted by the joint forces and the contact forces, respectively. The term Gik is the distance from the segment center to the point of application of the contact force. The hydrodynamic drag force, Fi hyd , and torque, Ti hyd , are approximated with the expressions for an isolated prolate spheroid with an equivalent ratio re , . Fi hyd = 6πη o LAi .(U i∞ − r i ) (5) Ti hyd = 8πηo L3 (Ci .(Ω ∞ − ωi ) + H i : E ∞ ) (6) Where η o is the viscosity of the fluid, L is the length of the fiber, U ∞ is the fluid . velocity and r is the velocity of the center of mass of the segment. The terms Ω ∞ and ω i are the ambient and segment angular velocities, respectively. The vorticity of the fluid is E ∞ . Tensors Ai , C i and, H i are the resistance drag tensors. The restoring torques Yi are used to model different fiber flexibilities. Fibers can bend and twist since they are composed by spheroids connected by hinges. If these torques were not included in the equations of momentum, the fibers would immediately bend at the joints with the start of the flow. Different magnitudes of fiber flexibility can be modeled by changing the amount of these torques. The expression for the bending and twisting torque is given by, ( Yi = −k b (θ i − θ ieq )eib + 0.67(γ i − γ ieq )eit ) (7) Where θ ieq and γ ieq are the bending and twisting equilibrium angles. When a fiber is not deformed, θ ieq = θ i and γ ieq = γ i , and the resulting torque is zero. The constant k b is the bending constant of the fiber. A high k b means the fiber is rigid while a low k b means the fiber is flexible. For a known initial position of the fibers, it is possible to integrate in time to a new particle configuration at a time t+dt and the system can be updated. Figure 3. shows simulation results for an initially randomly oriented fiber network subjected to shear flow. The unit cell used, employed a periodicity condition, where the fiber leaving one side of the wall enters through the opposite side. The sequence of graphs in the figure demonstrates that the fibers tend to align along the plane of shear. This model works perfectly with dilute and semi-dilute fiber suspensions. However, when the fiber concentration is augmented ,i.e., the suspension is concentrated, it becomes harder to track fiber to fiber contacts and the fibers are so packed that the simulation model can no longer correctly describe the flow. Furthermore, there exists the possibility of the fibers overlapping if the time step is too big. The simulation is then limited to very small time steps. Journal of Plastics Technology 6 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Fiber Jamming Simulations where the fiber concentration by volume is more than 1 % become impractical. The neglection of the hydrodynamic effects in concentrated suspensions is based in the idea that the fluid between fibers does not cause a hydrodynamic effect [17,18]. The hydrodynamic force is based on the ideal situation where a fiber of a given geometry is immersed in a free flowing fluid. This might be true for dilute and semi dilute suspensions, where the fiber interactions are minimum. However, in the case of a concentrated suspension, this is not the case since fibers are constantly in contact with each other, and the interaction with the flow is far from the ideal case. It has been suggested that for the case of concentrated suspensions, the force of friction, the normal force and a lubrication force are orders of magnitude greater than the hydrodynamic force. The lubrication force replaces the hydrodynamic force since, in reality, there is only a thin film of fluid that lubricates the movement between fibers [19,20]. The following section presents a dimensional analysis created to evaluate the relevance of each of the competing forces in the processing of fiber reinforced composites. Figure 3: Fiber matrix simulation for a fiber concentration of 1%. 4 DIMENSIONAL ANALYSIS FOR COMPRESSION MOLDING OF A RIBBED SECTION Fundamental dimensional analysis was conducted on mechanistic models of fiber suspensions to study the influence of processing variables on the final quality of the part. Figure 4. shows a schematic of the compression molding of a ribbed part. An upper platen is lowered with a force F which exerts a pressure p Journal of Plastics Technology 7 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Fiber Jamming . on the charge. The charge is squeezed at a closing speed h until the mold is completely filled with a final flange thickness h. Figure 4: Schematic of compression molding of a ribbed part. The fibers have a length L, area moment of inertia I, Young's modulus E and diameter D. The fiber bed has a permeability K which is expressed in terms of D'Arcy's Law. Bakharev and Tucker [21] used this law to describe flow through a porous medium. The flow of the resin through the fiber bed is modeled as one dimensional flow of a Non-Newtonian fluid through a porous material, ⎛ K ⎞⎛ − dp ⎞ ⎟⎟ V = ⎜⎜ ⎟⎟⎜⎜ ⎝ η ⎠⎝ dy ⎠ (8) K = 0.00025D 2φ −2.4 (9) where V is the velocity of the resin, η the viscosity of the resin, D the fiber diameter and φ the volume fraction of fibers. With a mold cover charge of . about 50% , the velocity V can be assumed to be equal to the closing speed h of the compression molding machine. The relevant parameters for the dimensional analysis are summarized as follows: . Process variables: closing speed h , pressure p, mold closing force F, average fiber distance δ o . Geometric variables: fiber length L, fiber diameter D, flange thickness h, fiber's area moment of inertia I. Journal of Plastics Technology 8 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Fiber Jamming Physical or material properties: matrix viscosity η , permeability K and Young's modulus of the fiber E. It should be noted that the volume fraction, φ , is already a dimensionless number. From the dimensional analysis, the following Π -groups are obtained: Π1 = Π2 = Π3 = L I (10) 1/ 4 D (11) I 1/ 4 h I (12) 1/ 4 . Π4 = Π5 = ηh (13) EI 1 / 4 K (14) I 1/ 2 Π6 = F EI 1 / 2 (15) Π7 = p E (16) The Π -groups can be rearranged to obtain the following dimensionless numbers: . Π 4 Π1 Π 3 η h h 3L2 ℵ1 = = Π5 KEI 2 3 (17) . ℵ2 = Π 4 Π 3 = 3 η h h3 EI Π1 L2 ℵ3 = = Π5 K (18) 2 ℵ4 = L4D 2 3 4δ o h 3 (19) (20) Each of these numbers have a physical significance. They can be expressed in terms of D'Arcy's forces FD hydrodynamic forces FH and fiber bending forces FB . Journal of Plastics Technology 9 Fiber Jamming The dimensionless number ℵ1 is the ratio between D'Arcy's and fiber bending forces, ℵ1 = D' Arcy ' s Forces Fiber Bending Forces (21) A value of ℵ1 less than one, is an indicator of fiber bending forces being greater than D'Arcy's forces, leading to significant fiber matrix separation or fiber jamming. When ℵ1 > 1 , the force needed to bend the fibers is lower than the force needed to make the matrix flow through the fiber bed. In this case, fibers will also be dragged into the rib, diminishing the effects of fiber matrix separation. The higher the values of ℵ1 , the less the chance of fiber matrix separation. Figure 5. shows the behavior of ℵ1 for different fiber concentrations and different fiber diameters. The graph shows that for a given fiber concentration, lower fiber diameters have higher ℵ1 . In other words, fibers with lower diameter require less bending force to flow into the rib and decrease the chance of fiber matrix separation. © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Figure 5: ℵ1 Vs. φ for different fiber diameters. Journal of Plastics Technology 10 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Fiber Jamming Figure 6. shows the variation of ℵ1 with fiber concentrations for different resin matrix viscosities. The higher the viscosity of a charge, the more difficult it is for the charge to flow through the fiber bed. This explains why, for a given fiber concentration, higher viscosities have higher values of ℵ1 . Figure 7. shows the influence of the closing speed in the final part distribution on fiber matrix separation. A higher closing speed increases the D'Arcy forces, dragging the fibers into the ribbed section, and therefore reducing fiber matrix separation effects. The dimensionless number ℵ2 is the ratio between hydrodynamic forces and fiber bending forces. The dimensionless number ℵ3 is the ratio between D'Arcy's forces and hydrodynamic forces, ℵ2 = ℵ3 = Hydrodynamic Forces Fiber Bending Forces D' Arcy ' s Forces Hydrodynamic Forces (22) (23) A high value of ℵ2 is indicative of hydrodynamic forces prevailing over bending forces. This is usually not the case in compression molding, since the fiber bending forces are orders of magnitude higher than the hydrodynamic forces. Figure 8. shows the the behavior of ℵ 3 versus fiber concentration for different fiber diameters. It can be observed that D'Arcy's forces are orders of magnitude higher than hydrodynamic forces. Only for very low fiber concentrations, hydrodynamic forces play an important role. For a given fiber concentration, a smaller radius means a lower hydrodynamic force and therefore higher ℵ 3 . The dimensionless number ℵ4 is the ratio between lubrication forces and hydrodynamic forces. ℵ4 = Lubrication Forces Hydrodynamic Forces (24) Figure 9. shows the dimensionless number for different average fiber separations. At low fiber concentrations, the hydrodynamic forces dominate the lubrication forces. As the fiber concentration increases, the lubrication forces start playing the dominant role, to the point that hydrodynamic forces can be neglected. These results are in accordance with the observations made in experimental results [18,19] and raise the possibility of simplifying the simulation algorithm. The suspension inter-fiber friction can be expressed in terms of known forces. Typical Coulombic friction is given by Ff = µFN Journal of Plastics Technology (25) 11 Figure 6: ℵ1 Vs. φ for different resin viscosities. Figure 7: ℵ1 Vs. φ for different mold closing velocities. Fiber Jamming © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Journal of Plastics Technology 12 Fiber Jamming Where Ff and µ are the force and the coefficient of friction, respectively. The force FN is the normal force between contacting fibers. This normal force can be assumed equal to the isotropic pressure applied to the charge times the projected surface area of the fiber Af . FN = PAf (26) Where Af = DL (27) Expressing the pressure in terms of D'Arcy's forces and finding the ratio with respect to hydrodynamic forces, a final dimensionless number is obtained. Friction Forces L2 ℵ5 = =µ = µℵ3 Hydrodynamic Forces K (28) This result suggests that D'Arcy's and lubrication forces have the same behavior when compared to hydrodynamic forces. In other words, Figure 8. is equivalent to plotting ℵ5 versus fiber diameter without the dampening introduced by the coefficient of friction µ . It is then concluded that friction forces dominate over hydrodynamic forces at high fiber concentrations. © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Figure 8: ℵ3 Vs. φ for different fiber diameters. Journal of Plastics Technology 13 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Figure 9: Fiber Jamming ℵ4 Vs. φ for different fiber separations. 5 CONCLUSIONS The dimensional analysis presented in this paper is aimed at verifying that hydrodynamic forces may be neglected and at maintaining the physical connection of an industrial process with a complex mathematical simulation. With the help of dimensional analysis it is possible to refine the computer simulations and optimize computational time otherwise spent in unrealistic processes. Dimensional analysis supports and validates simulation results that otherwise might lose touch with reality. By conducting a simple dimensional analysis, it was found that at high fiber concentrations, the effect of the hydrodynamic forces can be neglected and replaced by a lubrication effect. This result is in accordance with the behavior found in experiments. The importance of this result should not be overlooked since for concentrated fiber suspensions, most of the problems encountered in the simulations are caused by increasing fiber to fiber contact and tracking the hydrodynamics of the flow. The lubrication simplification could lead to successful simulations of highly concentrated fiber suspensions. Journal of Plastics Technology 14 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Fiber Jamming 6 REFERENCES [1] G. K Batchelor. Slender-body theory for particles of arbitrary cross-section in stokes flow. Journal of Fluid Mechanics, 44 part 3:419.440, 1970. [2] G.B. Jeffery. Proc. Roy. Soc., 111:110, 1926. [3] G.B. Jeffery. The motion of ellipsoidal particles immersed in a viscous fluid. Proc. Roy. Soc., A102:161, 1922. [4] F.P. Folgar and C. L. Tucker. Orientation behavior of fibers in concentrated suspensions. Reinf. Plast. Comp., 3:98, 1984. [5] T.A. Osswald and C. L. Tucker. Compression mold filling simulation for nonplanar parts. International Polymer Processing, 5(2):79.87, 1990. [6] G. Bossis and J.F. Brady. Dynamic simulation of sheared suspensions. l. general method. Journal of Chemical Physics, 80:5141.5154, 1984. [7] Ivan L Claeys and John F. Brady. Suspensions of prolate spheroids in stokes flow. part 2. statistically homogeneus dispersions. J. Fluid Mech., 251:443.477, 1992. [8] Ivan L Claeys and John F. Brady. Suspensions of prolate spheroids in stokes flow. part 3. hydrodynamic transport properties of crystalline dispersions. J. Fluid Mech., 251:479.500, 1992. [9] X.J. Fan, N. PhanThien, and R. Zheng. A direct simulation of fibre suspensions. J. Non-Newtonian Fluid Mech., 74:113.135, 1998. Journal of Plastics Technology 15 © 2006 Carl Hanser Verlag, München www.kunststofftech.com Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño-Hurtado, Tim Osswald Fiber Jamming [10] Christian F. Schmidt, L.H. Switzer, and D.J. Klingenberg. Simulations of fiber flocculation:effects of fiber properties and interfiber friction. J. Rheology,44:781.809, 2000. [11] B. Herzhaft and E. Guazzelli. Experimental study of the sedimentation for dilute and semi-dilute suspensions of fibres. Journal of Fluid Mechanics,384:133.158, 1999. [12] L. Switzer. Simulating Systems of Flexible Fibers. Ph.D. thesis, University of WisconsinMadison, 2002. [13] R.R. Sundararajakumar and D.L Koch. Structure and properties of sheared fiber suspensions with mechanical contacts. Journal of Non-Newtonian Fluid Mechanics, 73:205.239, 1997. [14] R.J. Kerekes and C.J. Schell. Characterization of fibre flocculation regimes by a crowding factor. Journal of Pulp and Paper Science, 18:32.38, 1992. [15] D. Wahren. Fiber network structures in papermaking operations. In Paper Science and technology ,the Cutting edge, 1979. [16] R.J. Kerekes, R. M. Soszynski, and P. a. Tam Doo. The flocculation of pulp fibres. In Transactions of the eighth fundamental research symposium held at Oxford, 1985. [17] A. Moghaddam and Staffan Toll. Fibre suspension rheology: effect of concentration, aspect ratio and fibre size. Rheologica Acta, 45:315.320, 2006. [18] J. E. Manson K. A. Ericsson, S. Toll. The two-way interaction between anisotropic flow and fiber orientation in squeeze flow. J. Rheol., 41(3):491. 511, 1997. [19] Colin Servais, Andre Luciani, Jan Fiber-fiber interaction in concentrated suspensions: Dispersed fiber bundles. J. Journal of Plastics Technology 16 Nicht zur Verwendung in Intranet- und Internet-Angeboten sowie elektronischen Verteilern. Alejandro Londoño Hurtado, Tim Osswald Fiber Jamming Anders, and J. E. Manson. Rheol,43(4):991.1003, 1999. [20] Colin Servais, Andre Luciani, JanAnders, and J.E. Manson Squeeze flow of concentrated long fibre suspensions: experiments and model. J. Non-Newtonian Fluid Mech., 104:165184, 2002. [21] A.S. Bakharev and C. L. Tucker. Predicting the effect if preforming on rtm mold filling. In Society of Plastic Engineers Inc., Technical Papers Volume XLII,1996. Keywords: Fiber jamming , fiber matrix separation, computer simulations, dimensional analysis. Contact: Prof. Tim Osswald (osswald@engr.wisc.edu) Alejandro Londoño-Hurtado (londonohurta@wisc.edu) Department of Mechanical Engineering, University of Wisconsin, Madison. © 2006 Carl Hanser Verlag, München www.kunststofftech.com 1513 University Avenue, 317 Mechanical Engineering Building. Journal of Plastics Technology 17