ADC - Polytrade GmbH

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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 26.11.2014
*
Version number 4
Revision: 26.11.2014
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
· 1.1 Product identifier
· Trade name: AZODICARBONAMID
· CAS Number:
123-77-3
· EC number:
204-650-8
· Index number:
611-028-00-3
· Registration number 01-2119493056-35-0006
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Chemicals for synthesis
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Polytrade GmbH
Borsigallee 12
D-60388 Frankfurt/M.
Tel. +49 69 94 20 72-33
Fax +49 69 41 03 60
www.polytrade.de
· Informing department:
Tel. +49 69 94 20 72 - 34
d.janssen@polytrade.de
· 1.4 Emergency telephone number:
Tel. +49 69 94 20 72 - 33
Bürozeiten / Office hours 9:00 - 17:00
*
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS08 health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Sensitising
R42: May cause sensitisation by inhalation.
R44: Risk of explosion if heated under confinement.
· Classification system:
The classification is in line with current EC lists. It is expanded, however, by information from
technical literature and by information furnished by supplier companies.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 1)
· Hazard pictograms
GHS08
· Signal word Danger
· Hazard-determining components of labelling:
C,C'-azodi(formamide)
· Hazard statements
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
· Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P285
In case of inadequate ventilation wear respiratory protection.
P261
Avoid breathing dust.
P234
Keep only in original container.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P411
Store at temperatures not exceeding 50°C.
P420
Store away from other materials.
P403+P235 Store in a well-ventilated place. Keep cool.
P501
Dispose of contents/container in accordance with local/regional/national/
international regulations.
· Additional information:
EUH044 Risk of explosion if heated under confinement.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
*
SECTION 3: Composition/information on ingredients
· 3.1 Chemical characterisation: Substances
· CAS No. Designation:
123-77-3 C,C'-azodi(formamide)
· Identification number(s):
· EC number: 204-650-8
· Index number: 611-028-00-3
· SVHC
123-77-3 C,C'-azodi(formamide)
SECTION 4: First aid measures
· 4.1 Description of first aid measures
· General information Instantly remove any clothing soiled by the product.
· After inhalation Supply fresh air; consult doctor in case of symptoms.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 2)
· After skin contact
Instantly wash with water and soap and rinse thoroughly.
In case of permanent aches and pains please go and see the doctor.
· After eye contact
Rinse opened eye for several minutes under running water.
In case of permanent aches and pains please go and see the doctor.
· After swallowing
Rinse out mouth and then drink plenty of water.
In case of persistent symptoms consult doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
*
SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fire with alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Can be released in case of fire:
Nitrogen oxides (NOx)
Carbon monoxide (CO)
Danger of explosion when heated under confinement.
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained breathing apparatus.
· Additional information
Remove fill mass from incendiary zone, if possible.
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
*
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Bring persons out of danger.
Avoid causing dust.
Ensure adequate ventilation
· 6.2 Environmental precautions:
No special measures required.
Do not allow to enter drainage system, surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 8 for information on personal protection equipment.
*
SECTION 7: Handling and storage
· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
(Contd. on page 4)
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Safety data sheet
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Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 3)
Any deposit of dust which cannot be avoided must be removed regularly.
Use appropriate industrial vacuum cleaners or central vacuum systems for dust removal.
· Information about protection against explosions and fires:
Dust can combine with air to form an explosive mixture.
Keep ignition sources away - Do not smoke.
Protect from heat.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Store only in the original container.
Use only containers specifically permitted for this substance/product.
Store in cool location.
· Information about storage in one common storage facility:
Store away from oxidising agents.
· Further information about storage conditions:
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
· Recommended storage temperature: < 50 °C.
· 7.3 Specific end use(s) No further relevant information available.
*
SECTION 8: Exposure controls/personal protection
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace:
123-77-3 C,C'-azodi(formamide)
WEL (Great Britain) Short-term value: 3.0 mg/m³
Long-term value: 1.0 mg/m³
Sen
· DNELs
123-77-3 C,C'-azodi(formamide)
Dermal
DNEL (worker, long-term, systemic) 14.03 mg/kg bw/day (human)
Inhalative DNEL (worker, long-term, systemic) 4.02 mg/m³ (human)
· PNECs
123-77-3 C,C'-azodi(formamide)
PNEC STP
8 mg/L (.)
PNEC aqua (freshwater)
0.011 mg/L (.)
PNEC aqua (intermittent releases) 0.110 mg/L (.)
PNEC aqua (marine water)
0.0011 mg/L (.)
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Do not inhale dust / smoke / mist.
Avoid contact with the eyes and skin.
· Breathing equipment:
Use breathing protection in case of insufficient ventilation.
(Contd. on page 5)
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Safety data sheet
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Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 4)
Filter P3.
· Protection of hands: Protective gloves.
· Material of gloves
Nitrile rubber, NBR
The selection of the suitable gloves does not only depend on the material, but also on further
marks of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
With solid dry substances permeation is not to be expected. Therefore the breakthrough-time
for this protective glove has not been measured.
The exact break through time has to be found out by the manufacturer of the protective gloves
and has to be observed.
· Eye protection: Tightly sealed safety glasses.
· Body protection: Protective work clothing.
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
· Form:
Powder
· Colour:
Orange
· Odour:
Product specific
· Change in condition
· Melting point/Melting range:
· Boiling point/Boiling range:
· Flash point:
195 °C
Not determined
> 200 °C
· Inflammability (solid, gaseous) Substance is inflammable.
· Ignition temperature:
· Decomposition temperature:
>195 °C
· Danger of explosion:
Product is not explosive.
· Density at 20 °C
1.60-1.70 g/cm³
· Solubility in / Miscibility with
· Water at 20 °C:
· Solids content:
· 9.2 Other information
0.05 g/l
> 95 %
No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Thermal decomposition > 195 °C.
· 10.3 Possibility of hazardous reactions
The product is not capable of dust explosion in the form supplied; enrichment with fine dust causes
risk of dust explosion
(Contd. on page 6)
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Safety data sheet
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Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 5)
Reacts with flammable substances
Reacts with oxidizing agents
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: Bases
· 10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
Nitrogen oxides (NOx)
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
123-77-3 C,C'-azodi(formamide)
Oral
LD50 > 5000 mg/kg (rat) (OECD 401)
Dermal
LD50 > 2000 mg/kg (rat) (OECD 402)
Inhalative LC50 > 0.52 mg/l/4h (rat) (OECD 403)
· Primary irritant effect:
· on the skin: No irritant effect.
· on the eye: No irritant effect.
· Sensitisation: Sensitization possible by inhalation.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
123-77-3 C,C'-azodi(formamide)
EC50 (static) 19.7 mg/l/72h (Desmodesmus subspicatus) (EU C.3)
11 mg/l/48h (Daphnia magna) (OECD 202)
NOEC (static) 4.8 mg/l/24h (Daphnia magna) (OECD 202)
≥ 50 mg/l/96h (Pimephales promelas) (OECD 203)
· 12.2 Persistence and degradability Easily biodegradable
· 12.3 Bioaccumulative potential Does not accumulate in organisms
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Assessment by list): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or
sewage system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
GB
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 6)
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
The waste code numbers mentioned are recommendations based on the probable use of the
product.
· European waste catalogue
07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES
07 07 00 wastes from the MFSU of fine chemicals and chemical products not otherwise specified
07 07 08* other still bottoms and reaction residues
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
*
SECTION 14: Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA
UN3242
· 14.2 UN proper shipping name
· ADR
· IMDG, IATA
3242 AZODICARBONAMIDE
AZODICARBONAMIDE
· 14.3 Transport hazard class(es)
· ADR
· Class
4.1 (SR1) Flammable solids, self-reactive
substances and solid desensitised explosives.
4.1
· Label
· IMDG, IATA
· Class
4.1 Flammable solids, self-reactive substances
and solid desensitised explosives.
4.1
· Label
· 14.4 Packing group
· ADR, IMDG, IATA
II
· 14.5 Environmental hazards:
Not applicable.
· 14.6 Special precautions for user
Warning: Flammable solids, self-reactive
substances and solid desensitised explosives.
40
· Kemler Number:
(Contd. on page 8)
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Safety data sheet
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Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 7)
· EMS Number:
F-J,S-G
· 14.7 Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code
Not applicable.
· Transport/Additional information:
· ADR
· Limited quantities (LQ)
· Excepted quantities (EQ)
1 kg
Code: E2
Maximum net quantity per inner packaging:
30 g
Maximum net quantity per outer packaging:
500 g
2
D
· Transport category
· Tunnel restriction code
· IMDG
· Limited quantities (LQ)
· Excepted quantities (EQ)
500 g
Code: E2
Maximum net quantity per inner packaging:
30 g
Maximum net quantity per outer packaging:
500 g
· IATA
· Remarks:
· UN "Model Regulation":
*
Air transportation prohibited.
UN3242, AZODICARBONAMIDE, 4.1, II
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS08
· Signal word Danger
· Hazard-determining components of labelling:
C,C'-azodi(formamide)
· Hazard statements
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
· Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P285
In case of inadequate ventilation wear respiratory protection.
P261
Avoid breathing dust.
P234
Keep only in original container.
(Contd. on page 9)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 26.11.2014
Version number 4
Revision: 26.11.2014
Trade name: AZODICARBONAMID
(Contd. from page 8)
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
P304+P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a
position comfortable for breathing.
P370+P378 In case of fire: Use for extinction: CO2, powder or water spray.
P411
Store at temperatures not exceeding 50°C.
P420
Store away from other materials.
P403+P235 Store in a well-ventilated place. Keep cool.
P501
Dispose of contents/container in accordance with local/regional/national/
international regulations.
· National regulations
· Water hazard class: Water hazard class 1 (Assessment by list): slightly hazardous for water.
· Substances of very high concern (SVHC) according to REACH, Article 57
Substance is not listed.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Department issuing data specification sheet:
This Material Safety Data Sheet has been drawn up in cooperation with:
DEKRA Consulting GmbH, Hanomagstr. 12, D-30449 Hanover, Germany,
tel.: (+49) 511 42079 311, reach@dekra.com.
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations
Concerning the International Transport of Dangerous Goods by Rail)
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organisation
ICAO-TI: Technical Instructions by the "International Civil Aviation Organisation" (ICAO)
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning
the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Resp. Sens. 1: Sensitisation - Respirat., Hazard Category 1
· * Data compared to the previous version altered.
GB