CSACS Bulletin du CRMAA

CSACS Bulletin du CRMAA
Centre de recherche sur les matériaux auto-assemblés
Centre for self-assembled chemical structures
Avril 2015 April
1)
Table des matières:

CA: horaire p.1

Séminaire: Rowan p.2

Séminaire: Reynolds p.3

Prix Lash Miller:
Rosei p.4

Stages d'été
2015: Résultats
p.4

Prix du CRMAA
du meilleur article p.5

Publications p.5
Table of contents:

AM: schedule
p.1

Seminar: Rowan
p.2

Seminar: Reynolds p.3

Lash Miller
Award: Rosei,
p.4

2015 undergraduate scholarships: results
p.4

CSACS best paper award p5

Publications p.5
Volume 65
13e Conférence Annuelle du CRMAA
13th Annual CSACS Conference
Horaire / Schedule:
9:00-9:30
9:30-9:40
9:40-10:30
10:30-11:20
11:20-12:00
12:00-14:30
14:30-15:20
15:20-16:10
16:10-16:50
16:50-19:00
Inscription, déjeuner & installation des affiches
Registration, breakfast & poster setup
Discours d'ouverture / Opening remarks
Zhenan Bao, Stanford
Supramolecular Chemistry in Electronic Materials
Jean-François Lutz, Institut Charles Sadron
Unnatural Information-containing Macromolecules
Ma thèse en 180 secondes / My Thesis in 180 seconds
Lunch et session d'affichage / Lunch & poster session
Benoît Marsan, UQAM/CQMF
Nanosized semiconducting materials for photovoltaic cells
Joachim Spatz, Heidelberg/Max Planck
Bio-Molecular and Cellular Assemblies at Interfaces
Présentation du meilleur article et discours de clôture
Best CSACS paper presentation & closing remarks
Cocktail dînatoire et session d’affichage
Cocktail reception and poster session
Inscription requise: Date limite pour soumettre un résumé: 19 avril.
Registration required: Abstract submission deadline: April 19.
CSACS Bulletin du CRMAA
2)
Page 2
Séminaire/Seminar: Stuart Rowan
Visit: McGill (April 7)/ UdeM (Avril 8)
Titre: Les polymères structurellement dynamiques en tant que matériaux
sensibles aux stimuli
Title: Structurally Dynamic Polymers as Stimuli-Responsive Materials
Résumé/Abstract:
Dr. Stuart J. Rowan
Mettalo-Polymers
Biomaterials
The dynamic bond can be defined as any class of bond that selectively undergoes reversible breaking and reformation, usually under equilibrium conditions. The incorporation of dynamic bonds (which can be either covalent or non
-covalent) allows access to structurally dynamic polymers.1 Such polymers can
exhibit macroscopic responses upon exposure to an environmental stimulus, on
account of a rearrangement of the polymeric architecture. In such systems the
nature of the dynamic bond not only dictates which stimulus the material will
be responsive to but also plays a role in the response itself. Thus such a design
concept represents a molecular level approach to the development of new stimuli-responsive materials. We have been interested in the potential of such systems to access new material platforms and have developed a range of new mechanically stable, supramolecular structurally dynamic polymer films that
change their properties in response to a given stimulus, such as temperature,
light or specific chemicals. Such supramolecular materials have been targeted
toward applications that include healable plastics,2,3,4 responsive liquid crystalline polymers,5 chemical sensors,6 thermally responsive hydrogels,7 shape
memory materials8 and mechanically dynamic biomedical implants.9,10 In this
presentation we will focus on two classes of stimuli-responsive materials (1)
photo-healable/shape-memory materials and (2) mechanically dynamic cortical
implants.
References:
1. Wojtecki, R.J.; Meador, M.A.; Rowan S.J. “Utilizing the Dynamic Bond to Access Macroscopically-Responsive
Structurally-Dynamic Polymers” Nature Materials 2011, 10, 14-27. 2. Burnworth, M.; Tang, L.; Kumpfer, J.R.,
Duncan, A. J., Beyer, F.L.; Fiore, G.L.; Rowan S.J.; Weder, C. “Optically Healable Supramolecular Polymers” Nature 2011, 472, 334-337. 3. Fox, J.; Wie, J.J.; Greenland, B.W.; Burattini, S.; Hayes, W.; Colquhoun, H.M.; Mackay,
M.E.; Rowan S.J. “High-Strength, Healable, Supramolecular Polymer Nanocomposites” J. Am. Chem. Soc. 2012,
134, 5362-5368. 4 Michal, B.T.; Jaye, C.A. Spencer, E.J.; Rowan, S.J. “Inherently Photo-Healable and Thermal
Shape-Memory Polydisulfide Networks” ACS Macro Lett. 2013, 2, 694-699. 5. McKenzie, B.M.; Wojtecki, R.J.;
Burke, K.A.; Zhang, C.; Jákli, A.; Mather, P.T. Rowan, S.J. “Metallo-Responsive Liquid Crystalline Monomers and
Polymers” Chem. Mater. 2011, 23, 3525-3533. 6. Kumpfer, J.R.; Jin, J.; Rowan, S.J. “Stimuli-responsive europium
-containing metallo-supramolecular polymers” J. Mater. Chem. 2010, 20, 145-151. 7. Buerkle, L.E.; von Recum,
H.A.; Rowan S.J. “Toward Potential New Supramolecular Tissue Engineering Scaffolds Based on Guanosine Derivatives” Chem. Sci. 2012, 3, 564-572. 8. Kumpfer, J.R.; Rowan, S.J. “Thermo-, Photo- and Chemo-Responsive
Shape-Memory Properties from Photo-Crosslinked Metallo-Supramolecular Polymers” J. Am. Chem. Soc. 2011,
133, 12866-12874.9 Capadona, J.R.; Shanmuganathan, K.; Tyler D.J.; Rowan S.J.; Weder, C. “Stimuli-Responsive
Polymer Nanocomposites Inspired by the Sea Cucumber Dermis” Science 2008, 319, 1370-1374. 10 Capadona J.R.;
Tyler, D.J.; Zorman C.A.; Rowan, S.J.; Weder, C. Mechanically Adaptive Nanocomposites for Neural Interfacing
MRS Bulletin 2012, 37, 581-589.
CSACS Bulletin du CRMAA
3)
Page 3
Séminaire/Seminar: John Reynolds
Visit: McGill (April 28)/ UdeM (Avril 29)
Titre: La couleur dans les polymères conjugués : électrochromisme et photovoltaïque
Title: Color in Conjugated Polymers: Electrochromism and Photovoltaics
Dr. John R. Reynolds
Résumé/Abstract:
Conjugated molecules, oligomers and polymers with intimately interacting
donor-acceptor moieties provide light harvesting and electronic energy levels that can be tuned to optimize their utility in electrochromic, along with
both bulk heterojunction and dye sensitized solar cell applications. In this
presentation, we will explore the combination and interaction of a breadth
of electron rich and electron poor species that ultimately allow us to prepare
polymer films with band gaps that range from 4 eV in the UV to near 0.5 eV
in the infrared. The flexible synthetic chemistry of dioxythiophene-based
polymers has allowed us to complete the color palette (yellow, orange, red,
purple/magenta/, blue, cyan, green, and black) of vibrantly colored to highly
transmissive switching, spray- and blade-coat processed electrochromes of
any color, with donor-acceptor interactions especially enabling materials
that are black, green and cyan in color. Donor-Acceptor-Donor (DAD) triads
with internally fused DA cores provide a means of examining multi-colored
chromophores for charge injection to metal oxide electrodes. DA polymers
synthesized using a broad selection of co-monomers, provides donor polymers, which, in conjunction with PCBM, yield solar cells with power conversion efficiencies of 7-8%, while providing color control. Combination of
multi-layer solution processing allows the construction of solar powered
electrochromic windows.
Pour plus de details visitez
For more details visit us at
www.csacs.mcgill.ca
CSACS Bulletin du CRMAA
4)
William Lash Miller
(1866-1940)
Quand il est mort, on a
décrit Miller comme le
plus grand chimiste
que le Canada ait formé; chose certaine, il
était le plus coloré [...]
When he died, Miller
was described as the
greatest chemist Canada had produced; he
was certainly the most
colourful […]
Page 4
Prix Lash Miller Award: Federico Rosei
Attribué à tous les deux ans par l'Electrochemical Society (Canada)
Le professeur Federico Rosei du Centre Énergie Matériaux Télécommunications de l'INRS est le lauréat du prix Lash Miller 2015 de la Section
canadienne de l'Electrochemical Society. Félicitations au professeur Rosei
qui est une fois de plus honoré pour son excellence et sa multidisciplinarité.
Source: Université INRS
Award from the Electrochemical Society
Professor Rosei will deliver an award lecture on electronic and photonic devices at one of the two Electrochemical Society Canada Section
meetings. Congratulations to Professor Rosei, who has distinguished himself once again for his excellence and multidisciplinarity.
Source: Université INRS
5) Résultats: Stages d'été pour les étudiants du baccalauréat
Results: Summer undergraduate research scholarships
Tableau non officiel des récipiendaires / Unofficial table of the awardees
Nom/Name
Codirecteurs/Cosupervisors
Briony Lago (McMaster)
Cosa/Blum
Conjugated polyelectrolyte lipid interactions explored at the single molecule
level
Tiffany Jeen (Saskatchewan)
Initié en 2005, le programme prend en
charge de 5 à 8 étudiants de premier cycle
d'été (~ 4000 $ par
élève) qui travailleront
sur des projets de recherche communs
entre les membres du
CRMAA.
Initiated in 2005, the
program supports 5 to
8 undergraduate summer students (~ $4K
per student) who will
work on joint research
projects between
CSACS members.
Skene/Giasson
Stimuli responsive brushes prepared by controlled polymerization on transparent surfaces
Farhad Khan (McGill)
Sleiman/Barrett
The investigation of polycationic polymer coated DNA nanoparticles for
gene silencing
Lya Fontaine (INSA Toulouse)
Dory/Zhao
Synthesis and study of new photochromic compounds as optical modulators
Farah Hadji (UdeM)
Bazuin/Pellerin
Photocontrol of block copolymer self-assembly in dip-coated films
Xue Bin (Concordia)
Cuccia/Hanan
Exploring Conglomerate Crystal Sponges
Jung Young Jung (McGill)
Reven/Lennox
Polymer Functionalized Anisotropic Nanoparticles
Nos/Our Finalist(e)s
6)
Perepichka, Angew.
Chem. Int. Ed.
Lennox, Perepichka, ACS Nano
Friščić, Angew. Chem.
Int. Ed.
Prix du CRMAA du meilleur article
CSACS Best Paper Award
Pour la compétition de cette année, le comité Éducation et colloques a
accepté de transmettre quatre découvertes au Comité consultatif international (CCI), toutes provenant de revues scientifiques très reconnues. Parmi ces
quatre finalistes, le CCI va ensuite sélectionner l’article gagnant. Le prix sera
décerné lors de la réunion annuelle du CRMAA en mai.
For this year’s competition, the Educational and Colloquia committee
have agree to forward four discoveries to the International Advisory Committee (IAC), all from highly ranked scientific journals. Among the four finalists, an IAC jury will select the winning paper. The prize will be awarded
at the CSACS annual meeting in May.
7)
Cosa, Chem. Sci.
Page 5
CSACS Bulletin du CRMAA
Publications
La Page Couverture Sleiman/Cosa
on Cover Page
Amani Hariri, Graham Hamblin,
Yasser Gidi, Hanadi Sleiman & Gonzalo Cosa. Stepwise growth of surfacegrafted DNA nanotubes visualized at
the single-molecule level, Nature
Chemistry (2015).
Jean-François Masson
Label-free technologies for biomolecular
interaction monitoring, DrugTargetRev,
Avril 2015 April.
La parution de bulletins réguliers à tous les
membres joue un rôle
essentiel dans les communications internes –
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Centre de recherche
sur les matériaux autoassemblés (CRMAA)
souligne les activités
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vous souhaitez recevoir
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Regular newsletters to all members
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CSACS Bulletin du CRMAA
7)
Page 6
Publications con’t
Georgios Rizis , Theo van de
Ven and Adi Eisenberg.
Homopolymers as StructureDriving Agents in Semicrystalline Block Copolymer Micelles, ACS Nano, Article
ASAP.
Junxue An, Xiaoyan Liu, Per
Linse, Andra Dėdinaitė,
Françoise Winnik and Per
Claesson. Tethered Poly(2isopropyl-2-oxazoline)
Chains: Temperature Effects
on Layer Structure and Interactions Probed by AFM Experiments and Modeling, Langmuir, 2015, 31
(10), pp 3039–3048.
D. Prochowicz, K.
Sokołowski, I.
Justyniak, A. Kornowicz, D. FairenJimenez, T.
Friščić and J.
Lewiński. A mechanochemical strategy for IRMOF assembly based on predesigned oxo-zinc precursors, Chem. Commun., 2015,51, 4032-4035.
csacs.chemistry@mcgill.ca
Al Mamun, Geraldine Bazuin
and Robert Prud’homme.
Morphologies of Various Polycaprolactone/Polymer Blends
in Ultrathin Films, Macromolecules, 48 (5), pp 1412–1417.
CSACS/CRMAA
McGill University
801 Sherbooke St. West
Montreal, Quebec, Canada
H3A 0B8
Phone: 514-983-6288
Fax: 514-398-3797
E-mail: csacs.chemistry@mcgill.ca
http://www.csacs.mcgill.ca
Julia Schneider, Hayden Black, HuaPing Lin and Dmitrii Perepichka. Polymorphism in New Thienothiophene–
Thiazolothiazole Organic Semiconductors, ChemPhysChem.