0 9 | 2 015 09 | 2015
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0 9 | 2 015 09 | 2015
09 | 2015 Contents Seating Comfort Alfmeier bonds lordosis valves with DELO adhesive In Six Seconds to +180 °C New metal adhesive for electric motors 4 8 14 16 Adhesive-friendly Design Laser Pretreatment Tips & tricks for engineers Bonding stainless steel 2 | DELO-News Editorial Light-weight Design Bonding replaces welding and riveting 10 Dear readers, Maybe you’ve already noticed? We’ve given our customer magazine DELO-News a makeover. Decluttered, with a lot of white space, modern fonts, and attractive images – we think it makes reading a lot more enjoyable! As for the content, the feedback we received from readers (and our thanks to everyone who took part in our survey) told us that there was the desire for a wide range of formats. You want information about our new products as well as case studies for solved applications, forecasts for trends in adhesive technology, and practical tips about bonding. We have also completely revamped our reference book on bonding technology BOND it. In the 5th expanded and revised edition of this book, discover all there is to know about the theoretical background to adhesive technology, its application, and our products. If you have not yet encountered BOND it or only have an old edition, please get in touch with your contact person at DELO or email us at contact@delo.de. Happy reading! Sabine Herold, Managing Partner 18 Bonding PEEK Imprint Evonik Industries and DELO join high-performance materials DELO Industrial Adhesives, DELO-Allee 1, 86949 Windach, Germany Phone +49 8193 9900-0, marcom@DELO.de, www.delo.de DELO-News | 3 Cover Story Comfort Seats in Good Shape Thanks to Adhesives 4 | DELO-News Cover Story Seat comfort is becoming of increasing concern to motorists. While massage seats are still the reserve of the premium segment, lumbar supports are now breaking through into the mass market. Alfmeier, a leading provider of the lordosis valves for these, relies on DELO’s adhesives for reliable products and rapid manufacturing. ordosis valves play an important role for seat comfort. These little helpers have primarily become known as pneumatic actuators for lumbar supports. Initially reserved for the premium segment, they are now increasingly found on the mass market. Another trend is that they are becoming smaller and lighter, which means that they can be installed as valve islands without taking up too much valuable space. They are also becoming more multifunctional and are no longer used just for backrest supports, but also for backrest width adjustment and seat massage functions. In a current top-of-the-range model, for an additional 2,000 euros, it is even possible to get 14 temperaturecontrolled air cushions that mold exactly to the contour of your body. L From Treuchtlingen in Germany out into the World Alfmeier Präzision AG is headquartered in Treuchtlingen, Germany, and is one of the most important providers of lordosis valves on the market. Several hundred thousand units roll off its production lines every year. The owner-operated family business also supplies the automotive, medical technology, and electronics industries with actuators, pumps, and molded plastic parts. From its development, production, and distribution sites in Germany, the Czech Republic, China, Korea, the USA, and Mexico, its two thousand employees serve European, American, and Asian OEMs. Every Second Counts The seal between the electrical connection and the housing bushing is crucial for the reliable functioning of Alfmeier’s valves – after all, the operating pressure can be 1 – 1.5 bar, or even 2.5 bar in some cases. In order to seal these contacts, Alfmeier uses an encapsulation technique with adhesives. Other processes, such as insert molding, are out of the question, because it’s not just reliability that is important to Alfmeier – speed is of the essence here too. The focus here is on simple adhesive dispensing and rapid curing. This is the only way in which the company DELO-News | 5 Cover Story Alfmeier lordosis valves ensure good seat comfort Light- / humidity-curing DELO-DUALBOND adhesive is used to reliably seal off the pins 6 | DELO-News Cover Story can achieve the short cycle times required to implement actual series production processes that include an in-line functional check of the seal. Alfmeier selected DELO as its project partner. The midsized company, with its portfolio of high-end adhesives, was brought on board at an early stage, bringing with it great expertise in bonding processes for large unit volumes. The project involved the setting up, testing, and validation of all the production processes, as well as the special modification of the adhesives to the requirements of lordosis valves. “Bonding is an efficient, but sometimes complex joining method. So it’s important not just to sell products, but to thoroughly test them beforehand and discuss and plan all production aspects with the customer on an equal footing,” says Christian Walther, Head of Sales for Germany at DELO. Efficient in Series Production After a few preliminary tests with numerous products, the final decision was between a onecomponent adhesive and a two-component adhesive. Due to the considerably quicker curing and simpler handling, it was the one-component, dual-curing adhesive that was selected, which also enabled an in-line tightness test. Since then, Alfmeier has also installed a dual-curing adhesive, a product with two curing mechanisms. All areas of the adhesive that are accessible to light are cured with LED lamps, which means that the valves can continue to be handled immediately. In shadowed areas, where the light cannot penetrate, the adhesive is cured by contact with It is important to discuss and plan production aspects with the customer.” humidity, which ensures good reliability. Alfmeier is relying on DELO’s products for the LED lamps too. These are not only tailored to the adhesive, but also offer a high level of intensity and exceptionally uniform light distribution. The valves are produced on a 6-meter-long linear facility, a quarter of which is dedicated to the bonding process. First, the valves are automatically fed in, then the adhesive is dispensed from a pressure tank. Thanks to the aforementioned light-curing process, the pin cast is cured in about 10 seconds, so the total cycle time for dispensing, curing, and quality control is just a few seconds. Alfmeier is therefore well equipped for production growth – which is sure to come, given the boom in comfort seats. Process video: https://youtu.be/6KjxfwepiYU DELO-News | 7 Product In Six Seconds to +180 °C Withstands High Temperatures, Allows Quick and Simple Curing DELO has developed a new adhesive for metal bonding used in high-temperature applications requiring quick and simple production processes. The DELO-ML DB154 adhesive retains its strength at temperatures up to +180 °C. esigned for use in electric motors, DELO-ML DB154 can easily bond buried magnets, rotor packages as well as shafts to hubs. This new adhesive offers exceptional temperature stability and heat resistance, achieving more than twice the shear strength values of other methacrylates in the same temperature range. Many other adhesives on the market experience a strong power drop at temperatures above +150 °C. DELO-ML DB154 retains its strength when it comes in frequent contact with high temperature, corrosive fluids, such as gear oil, motor oil and gasoline. D Cured by exposure to UV or visible light, the adhesive reaches initial strength within six seconds, reliably fixing the components and allowing the process to promptly continue. This provides an even initial fillet strength for more reliable bonding. Full strength of this adhesive is achieved when no oxygen is present in the curing process. Unlike one- or two-component epoxy resins, lightcuring methacrylates, such as DELO-ML DB154, require shorter periods of time for curing. This enables a faster production process and helps reduce the carbon footprint made during production, since no energy is used for heat curing. It also eliminates the mechanical fixing of the components prior to heat curing, saving additional process time. This medium-viscous product adheres to steel and aluminum as well as to magnets made of rare earth often consisting of an iron-neodymium mixture. If an activator is used, metals can also be joined to a component made of plastic. Fast and resistant to elevated temperatures: DELO-ML DB154 for e-motors 8 | DELO-News Product First Liquid, Then Sealing Sealants Cure in Seconds DELO now offers liquid FIPG sealants that protect housing covers from dust, air and water. This new static liquid sealant can be light-cured within seconds, making it superior to conventional liquid sealants that need minutes, if not longer, to cure. esigned to seal electronic and household devices like telephone housings and loudspeaker assemblies as well as automotive components like oil pans, electrical controls, engine covers, pumps, gear parts and door handles, DELO’s FIPG sealants offer immediate final strength, enabling continuous production and no downtime. D Ideal for large production volumes, these light-curing liquid sealants allow for short cycle times and easy automation. Sealants are more advantageous than conventional gaskets in the creation of complex component geometries because they require less process steps, while providing quick machine set-up time and little to no waste. In-line checks are also possible, as potential leaks are detected with the help of fluorescent light. As it is not necessary to keep a huge number of seals on stock, storage costs can be cut down. These run-resistant, high-viscous, silicone-free and PWIS-free sealants (paint wetting impairment substances) can be applied onto housing parts in any desired height. The sealants’ good elasticity offers reliable sealing after joining components. Its low compression set allows the seals to spring back after being compressed. DELO-News | 9 Product ONSERT®: The Best of Both Worlds Joining of Composite Materials [Part 2] In the last edition, we described the challenge of joining composite materials. In this issue, we introduce to you a joining technology that combines screws and adhesive and is suited to a range of applications. 10 | DELO-News Product Process advantages Böllhoff and DELO Combine Bonding and Screwing or joining composite materials to other materials, DELO has developed a new method together with the assembly specialist Böllhoff that uses stud welding as its basis. To prevent complex drilling of holes, screwing or riveting, threaded bolts are bonded to fiber composite materials instead of being welded. The combination of bolt and base is called ONSERT®. What makes this technique so special is its speed and effective energy balance. The process is as follows: First, a one-component adhesive is applied to the thread base and then joined to the composite material. The thickness of the adhesive layer is adjusted by spacers and can range from 0.1 to 0.2 mm. The thread base is made of an amorphous plastic, creating a light-permeable bonding area. This ensures the technique’s short cycle times. The adhesive is then cured within about 4 seconds using an LED lamp. This process can be fully automated as the bonded connection can be loaded immediately, equipping the plastic component with a stable thread directly afterwards. Once these steps have been completed, the thread can be screwed into other materials (not the base) and removed again if necessary. Depending on the mechanical properties required and the ambient conditions of use, F Perfect for automotive and aerospace applications, and even white goods: ONSERT® ONSERT® Low mechanical stressing of the components High reproducibility Fast process No heat input Design freedom thanks to later joining various plastics, such as polycarbonate, polyamide or polyether sulfone, are used as material for the transparent ONSERT® base. The only precondition is that the plastics are amorphous. This will allow enough blue light with a wavelength of 400 nanometers to be transmitted for curing. Multiple Application Possibilities from Retainers to Dampers This new technique is suitable for a wide range of applications, especially those where components must be fixed but not structurally joined. For example, hundreds of thousands of aircraft pins are installed in airplanes every year. With this method, cover plates and insulating materials can be fixed just like floor panels to adhere fire protection components. In recent years, vehicle construction has begun to increase its focus on CFRP, especially for B- and C-pillars. For example, the cable harness in vehicles could be fixed to the bolt and bonded to these pillars. Further urther applications include securing of clips, sensor retainers ers or attachment components. In addition, this method can be d considered as a beneficial alternative to welding ive as it increases production flexibility, lity, since the ONSERT® bonding areas are easy to change even after a design gn is completed. Video: ONSERT®s in BMW i8 series production https://youtu.be/VuLkVnoDm-A DELO-News | 11 Product Used in the BMW i3 An example from series production that demonstrates the wide range of applications is not just theory. The process has proved its worth in fastening cables, trims, and other components for the two new electric BMWs, the i3 and i8. Flexible geometry: In addition to threaded bolts of various sizes, ONSERT® can also be used for plug-in connectors. Impressive Mechanical Properties In order to check if this new joining method is suitable for these types of applications, the technique’s manufacturers bonded many materials to ONSERT®s, and subjected these joints to a broad variety of tests common in the automotive and aviation industries, including the 85 / 85 test, where the components are stored at a temperature of +85 °C and an air humidity of 85 %, and the VDA climate test. The CFRP components were sand-blasted for pretreatment. The lacquered aluminum and polypropylene were cleaned with ethanol. The magnesium components remained untreated. The tests demonstrated that the ONSERT® bases achieved high pull-off strength and shear strength values, as well as withstand the demanding test conditions. In addition to these two tests, the stability of the ONSERT®s was tested after salt spray exposure for 1,000 hours and storage in Skydrol (hydraulic liquid used in aviation) for four weeks. Even under these harsh environmental influences, the bond strength did not drop significantly after the 1,000 hour salt spray and not at all after four weeks of Skydrol. Pull-off-strength [N] Reference 7 d 85/85 10 d VDA 2,500 2,000 1,500 1,000 500 0 CFRP 12 | DELO-News Lacquered aluminum Bare magnesium PP Watch the video! https://www.youtube.com/ user/DELOadhesives/ Tips & Tricks Structural bonding has many advantages over conventional joining technologies. It evenly distributes tensions, and balances tolerances of the parts while simultaneously bonding and sealing components. To take full advantage of their potential, adhesives should be considered early on in the design phase. Achieving a perfect component design increases the performance of a bond, accelerates the production process and saves money. ew materials and designs often require the use of adhesives. Current material trends that foster adhesive bonding are composite materials like carbon fiber reinforced polymers (CFRP), glass fiber reinforced plastic (GFRP) and various multi-material designs. Welding, screwing and riveting are still good joining methods. However, they don’t always create a reliable and durable connection. For example, they are dependable for steel-to-steel or aluminum-toaluminum joining, but less reliable for polymers and multi-metal mixes like steel to aluminum. A typical mistake, made time and time again, is intending to bond a component, which has already been screwed or welded, without adapting its geometry accordingly. This can cause problems in many areas, including adhesive dispensing, joining of materials and bond strength. Despite the advancements in bonding technology to increase adhesion success, this science still remains on the back burner of many engineering studies. Typical mistakes made by engineers not familiar with bonding techniques, in N 14 | DELO-News the trial and error phase, can be easily avoided with some upfront education. The right bond makes all the difference When choosing between an adhesive or a joint with a screw or weld, the one main difference to remember between these joining techniques is that the forces applied from an adhesive effect the entire bonded laminar area, not just isolated (punctual or linear) areas, as is the case when locking with a screw or a weld. That’s why it is important to note that you cannot interchange screwing and welding with adhesive on the same project. It won’t work. It won’t produce the strength needed to hold the bond. Take for instance two metal sheets measuring 1 ft. long by 1 ft. wide that need to be joined. Only a small area of the metal sheets need to be overlapped when welding or screwing them together. Whereas, an area this small is not sufficient for bonding. To achieve a strong bond, the components would need to be designed to overlap a larger area. The larger bonding surface results in a stronger bond with tension spread more evenly throughout the components. (Figure 1) Fig. 1: Enlargement of the bonding area Tips & Tricks Enlarging the bonding area depends a great deal on the forces that arise in the actual application. Often, eccentric force transmission is to be expected. As this force does not act on one axis, it rotates to get balanced on the next axis, causing a torque that results in peel stress. Should this occur, an alternate to an overlap joint, is tongue and groove. Similar to the dovetail design long used in woodworking, tongue and groove joins and locks two components together, making it more difficult for them to bend or come apart. (Figure 2) Fig. 2: Tongue and groove joint – important remedy of peel stress As noted previously, when a structure originally constructed to be welded will then be bonded, the design should be modified. Although the adhesive will deliver proper tensile and compression strength values, the occurrence of a slight peel stress will lead to instability in the structure (Figure 3) To overcome the design challenge in this example, designers can use a larger cylindrical base along with a preengineered borehole in the baseplate. This will create a round tongue and groove joint. Fig. 3: If a welded joint is replaced by bonding, the design should be adapted And even though the magic word for structural bonding seems to be “tongue and groove”, there are several other design possibilities. Find out what they are in the second half of this article in the next edition of DELO-News. For more information or application-oriented training, please contact the DELO Academy at academy@delo.de. DELO-News | 15 Technology New Surface Pretreatment Method Stainless Steel Can Now Be Bonded in an Eco-friendly Manner Using Lasers Stainless steel bonding made easy with lasers t is well known that bonding stainless steel is very difficult, and that permanent, reliable bonds are only possible with pretreatment. Consequently, wet-chemical or tribochemical methods such as the DELO-SACO process (sandblast coating) have mostly been used until now. However, recent tests have shown that components subjected to an intensive laser pretreatment achieve tensile shear strength values almost as high as DELO-SACO-treated components. I For this reason, lasers will become more important despite the current high investment costs, as they also enable in-line processes in production and selective treatments. This requires no additional use of consumables, which are still subject to labeling requirements in conventional wet-chemical pretreatment methods. /D\HURIGLUW Tensile shear strength [MPa] 25 20 15 10 Degreased Degreased, SACO Laser 5 0 No aging 16 | DELO-News Simulated aging (500 h, +85 °C, 85 % r. h.) Technology ([WUDFWLRQ 0DWHULD DO YDSRUS Y SODVPD /D DVHUEHDP $G $GDS GDS SWLRQOD\H S \H HU H Advantages Cleaning and pretreating are performed in one work step Bond strength comparable with conventional pretreatment High process reliability with automated process Selective pretreatment Low running costs Safe for users and the environment, as no harmful substances are required DELO-News | 17 Technology PEEK Bonding Withstands Strict Environmental Conditions Bonded VESTAKEEP® PEEK L4000G from Evonik Industries withstands strict operating environmental conditions when DELOMONOPOX epoxies are used. This is the result of joint tests of Evonik and DELO. onding high-temperature resistant, high-performance thermoplastics such as PEEK (polyetheretherketone) has been challenging for plastic manufacturers. In general, PEEK possesses very low surface energy which leads to poor wettability characteristics. As a result, the surface is extremely resilient to chemical reaction and this makes bonding PEEK a very difficult process. However, recent test results have demonstrated that VESTAKEEP® PEEK L4000G can be bonded very well using a heat-curing DELOMONOPOX adhesive which was specifically designed to bond plastics. B High Bond Strength With or Without Pre-plasma Treatment To measure the bond strength of PEEK, the components were exposed to a compression shear test after the components were stored for 14 days at +85 °C with 85 % humidity. When the component surfaces were pre-treated with atmospheric pressure plasma, the compression shear strength value was as high as 40 MPa. In a separate test in which the component surfaces were not pre-treated with plasma, the compression shear strength still attained a value of approximately 20 MPa. Although this result is lower compared to the plasma-treated component test, the customer can benefit from a simplified production process and lower overall manufacturing costs. “The combination of PEEK and our epoxy-based adhesives is a marriage of high-performance materials”, explains Gudrun Weigel, Head of Engineering at DELO. “The excellent bonding quality is demonstrated by the fact that the test object was deformed before the bonding failed during compression shear testing. These results have opened up a whole range of new application areas”. PEEK bonding is likely to benefit the aerospace industry in the design of modular components. In the automotive sector and from the mechanical engineering’s design point of view, the PEEK bonding system offers solutions for sealing challenges. Become an expert with the new BOND it! The 3rd English edition of the Reference Book on Bonding Technology is now available. The BOND it provides everything worth knowing about adhesives in one handbook. The new BOND it will answer all of your questions about adhesive-friendly design, pretreatment, production processes, and many more. What is new? 256 pages filled with expertise One newly designed chapter “Applications in specific areas” Glossary, info boxes and tips from experts http://www.delo.de/ en/bond-it/