RFP-1801-049-005-GS_Solicitation
Transcription
RFP-1801-049-005-GS_Solicitation
Please return this form by 5/11/15 PROPOSAL INTENT NOTIFICATION TO: SUBCONTRACTS DEPARTMENT CDM FEDERAL PROGRAMS CORPORATION 3201 Jermantown Road, Suite 400 Fairfax, VA 22030 DATE: ______________ EMAIL to: meroldkz@cdmsmith.com RE: SOLICITATION NUMBER: SITE NAME: RFP-1801-049-005-GS KLAU/BUENA VISTA MINES SUPERFUND STE SAN LUIS OBISPO COUNTY, CALIFORNIA FROM: Company’s Name: Address: _______________________________ _______________________________ _______________________________ Contact: _______________________________ Telephone: ______________ Fax: ___________ Email: ________________________________ Indicate Business Size: (check all that apply) ___ Large ___ Small ___ Woman Owned ___ Disadvantaged ___ Veteran Owned ___ Service Disabled Veteran ___HUBZone The above named company (mark one): [ ] Intends [ ] Does Not Intend to submit a proposal for the above referenced solicitation. *** REQUEST FOR PROPOSAL FOR BATHYMETRIC SURVEYING SERVICES FOR THE KLAU/BUENA VISTA MINES SITE SAN LUIS OBISPO COUNTY, CA SOLICITATION NO. RFP 1801-049-005-GS MAY 2015 CDM FEDERAL PROGRAMS CORPORATION 3201 Jermantown Road, Suite 400 Fairfax, VA 22030 TABLE OF CONTENTS Part Page 1. PROPOSAL REQUIREMENTS ................................................................................ RFP-1 2. RESERVED ......................................................................................................................... 3. STATEMENT OF WORK/SPECIFICATIONS ...................................................... SOW-1 • Figure 1 • Figure 2 4. HEALTH AND SAFETY PLAN ............................................................................... HSP-1 5. PRICE SHEET (To be Submitted upon request of Subcontract Administrator) ........ RFP-1 6. REPRESENTATIONS AND CERTIFICATIONS 7. SAMPLE STANDARD SERVICE ORDER AND TERMS AND CONDITIONS • SUPPLEMENTAL TERMS AND CONDITIONS 8. SERVICE CONTRACT ACT - WAGE DETERMINATIONS PART 1 PROPOSAL REQUIREMENTS 1. This project is being conducted by CDM Federal Programs Corporation (CDM Smith) (the Contractor) on behalf of U. S. Environmental Protection Agency (EPA) under the GSA Prime Contract No. GS-10F-0227J. The Contractor is soliciting services for a Subcontractor to perform bathymetric surveying services at the Klau/Buena Vista Mines Superfund Site in San Luis Obispo County, California. A CDM Smith Project Manager will be assigned to this project. A Subcontract Agreement will be made between CDM Federal Programs Corporation and the selected Subcontractor. 2. This is a "Brooks Act" procurement. Subcontractor shall be registered and active in the System for Award Management (SAM) at www.sam.gov prior to receiving payment from CDM Smith for services/materials/supplies, etc. Firms not willing to register in SAM should not respond to this solicitation. In accordance with Federal Acquisition Regulations (FAR) 52.204-10 Reporting Executive Compensation and First-Tier Subcontract Awards (July 2010), all awards greater than $25,000.00 will be entered into www.fsrs.gov by CDM Smith. 3. This procurement is NOT reserved for small businesses. The North American Industrial Classification System (NAICS) code is 541370, with a size standard of $15M. NAICS size standards may be accessed via the internet at www.sba.gov/size/. 4. It is the responsibility of the responding firm to read and become completely familiar with all information in this Request for Proposal (RFP) and failure to become familiar with the RFP and the desired services will be at the offeror's own risk. Additionally, the Offeror must be familiar with the procedures, terms, conditions and requirements associated with performing the services described in this RFP. Offerors are responsible for checking the CDM Smith solicitations posting page at http://cdmsmith.com/Shared-Items/Solicitations.aspx for amendments issued prior to proposal submittal. 5. The subcontract document CDM Smith intends to use for this project will be based on the Sample Service Order Terms and Conditions in Part 7 of this RFP. The Statement of Work/Specification included in this RFP will be incorporated into the subcontract. Offerors are not required to complete any information in Part 7 at this time. 6. Firms that do not have the capability to meet the required specifications should not submit a technical proposal. Please notify Kathy Merold, Sr. Subcontracts Administrator, by returning the enclosed Intent Form if a technical proposal will or will not be submitted. A brief explanation as to why the firm is declining to submit a technical proposal should be submitted if the firm wishes to remain on CDM Smith’s Offerors list. 7. Reserved. RFP-1 8. A representative of the Contractor will be present during all site related activities. Activities included in the Statement of Work/Specifications shall commence within 10 calendar days of a Notice to Proceed issued by the Contractor or as directed by the Contractor for weather delays. 9. It is anticipated that the Subcontractor will begin activities in June 2015 and complete the work described herein in accordance with the schedule provided in the Statement of Work/Specifications (Part 3). 10. The Subcontractor must meet the health and safety requirements as described in the Health and Safety Plan included as Part 4. The Subcontractor shall perform the surveying services in modified Level-D personal protection at the site. 11. Proposals shall be submitted electronically (contained in 1 email, 2 separate pdf files) in the order specified below: A. B. Administrative Proposal (pdf File 1) (1) Completed and executed Representations and Certifications (Part 6). (2) Generic Certificates(s) of Insurance (Proof of Insurance) for the specific types and values indicated in Attachment E of the Standard Service Order Terms and Conditions including Professional Liability Insurance and Vessel Liability Insurance. Technical Proposal (pdf File 2) (1) Subcontractors who have had experience in performing similar bathymetric surveying services and who have the capacity of providing the required services within the stated timeframe specified in the Statement of Work/Specifications and without the use of lower-tier subcontractor(s) should detail this in their technical submittal. Provide three (3) recent (within 2 years), client references for which the Subcontractor has performed work similar to the work described in the RFP. Client reference list must include the project name, a summary of the scope of work, date work performed and the client name, address, contact name and telephone number. (2) Resume(s) of key personnel who will be responsible for the work specified in the Statement of Work/Specifications, including the Quality Assurance Manager. (3) Outline of procedures for complying with the Work/Specifications. This information must include: (a) Statement The firm's ability to meet or exceed the schedule requirements. RFP-2 of (b) (c) (d) C. (4) Copies of current State of California license(s) for key personnel. (5) Copies of license for Professional Land Surveyor in the State of California. (6) Written evidence that the Subcontractor’s health and safety plan is in full compliance with Part 4 as stipulated in this solicitation. (7) Number of Personnel that will be on site during surveying activities. Price Proposal (To be submitted upon request of Subcontract Administrator) (1) 12a. Technical approach to complete and Statement of Work and list of equipment to be used. Example of the survey log format and standard symbols to be used. Offeror’s QA Management Plan or description of QA procedures Completed Price Sheets and Conflict of Interest Statement (Part 5) including pricing detail (position, rate, hours, materials, etc.). Altering the price sheet may cause a proposal to be rejected. EVALUATION CRITERIA: Selection of a Subcontractor will be based on technical qualifications. Technical evaluation criteria will include: • Demonstrated understanding of the Statement of Work/Specification as shown by the technical approach proposed (25%). • Demonstrated availability, competence, and professional qualifications of experienced surveyors, draftsman and other technical personnel (25%). • Demonstrated relevant past performance on contracts or subcontracts in terms of cost control, quality of work and compliance with performance schedule (25%). • Demonstrated capacity to accomplish the work in the required timeframe (20%). • Demonstrated understanding of required levels of quality control and documentation to ensure compliance with this SOW (5%) 12b. Consideration for equal technical scores will be given in accordance with what is in the best interest of CDM Smith. CDM Smith reserves the right to make an award without discussions in accordance with FAR 15.306 (a) (3). 12c. Cost Services: The cost to provide the required services will be negotiated between the selected Subcontractor and CDM Smith (Contractor). A cost proposal will be requested from the firm selected as the most qualified (based on technical merit) and will serve as the starting point for negotiations with that firm. RFP-3 If an agreement cannot be reached with this firm, the firm will be notified by the Subcontract Administrator. CDM Smith will then follow the same procedure with the firm ranked second technically until an agreement can be reached with a qualified firm. The cost proposal must include all costs for completing the services described herein, including, but not limited to: equipment, materials, supplies, all labor (including overtime) insurance, taxes, licensing and permit fees, per diem, overhead, profit, and conformance with health and safety protocols other Federal, State, and local requirements, as well as regulations and requirements of the owners of the surrounding public and/or private properties. The cost proposal shall be submitted on the Price Sheets provided in Part 5. 13. Offerors shall submit responses to this Solicitation, RFP-1801-049-005-GS, via email in the format specified in Item 11 above no later than 4:00 p.m. (Virginia prevailing time) on May 13, 2015. Offerors shall submit responses to meroldkz@cdmsmith.com with a mandatory copy to thompsondr@cdmsmith.com. Submissions must be received in the CDM Smith email system no later than the due date and time indicated herein. 14 No alternate proposals will be considered in response to this solicitation. 15. All questions pertaining to this solicitation must be addressed in writing, and shall be sent via email to Kathy Merold at meroldkz@cdmsmith.com with a mandatory copy to thompsondr@cdmsmith.com for receipt by 2:00 p.m. (Virginia prevailing time) on May 7, 2014. Verbal explanations or instructions given before the award of RFP will not be binding. Any information given to a prospective proposer concerning the RFP will be furnished promptly to all other prospective offerors as an amendment to the RFP, if that information is necessary for submittal or if the lack thereof would be prejudicial to other prospective offerors. 16. Amendments. If this RFP is amended, then all the terms and conditions which are not modified remain unchanged. For amendments go to http://cdmsmith.com/SharedItems/Solicitations.aspx and locate the solicitation. Offerors shall acknowledge receipt of any amendments to this RFP in the cover letter of the Technical Proposal. CDM Smith must receive the acknowledgment by the time specified for receipt of proposals. 17. All proposals must remain valid for one hundred twenty (120) days after the actual date the responses are due. 18. Late submissions, modifications, and withdrawals of proposals shall be determined by CDM Smith in accordance with FAR 52.215-1. However, CDM Smith will not accept facsimile submissions, notifications or withdrawals of proposals. Written notice or telegram (including mailgram) can be issued to withdraw a proposal providing such notice is received by CDM Smith at any time before the exact time set for receipt of proposals. RFP-4 19. CDM Smith reserves the right to reject all proposals and award the subcontract on what it determines to be in the best interest of the CDM Smith and the Client. 20. This RFP does not commit CDM Smith to pay for any costs incurred in the preparation and submission of technical and/or price proposals or for any other costs that may be incurred prior to the award of a subcontract agreement. 21. Exceptions to the terms, conditions and requirements of this RFP, including but not limited to the terms and conditions of the sample Service Order Terms and Conditions may cause a proposal to be rejected. Any exceptions must be clearly addressed in the cover letter of the proposal submittal. RFP-5 PART 3 STATEMENT OF WORK STATEMENT OF WORK Statement of Work/Specifications for Bathymetric Survey 3.1 Scope of Work A. This statement of work (SOW) is intended to give a general description of the work required, but not cover all variations which may occur during the actual work, for conducting a bathymetric survey in a small private reservoir at the Klau/ Buena Vista Mines Superfund Site (Site). CDM Federal Programs Corporation (CDM Smith, herein after referred to as Contractor) is under contract with the United States Environmental Protection Agency (EPA) to conduct a bathymetric survey at the Site. This SOW is intended to cover the successful completion of the work specified, whether every detail is specifically mentioned or not. All work shall be performed in accordance with the terms of this SOW. B. The Site is located in the Santa Lucia Mountain Range of the California Coast Mountain Range (Figure 1). The Site is drained by tributaries to Las Tablas Creek which flow roughly south to north and is within the headwaters of the Nacimiento River, a major tributary of the Salinas River, which drains the east side of the Santa Lucia Mountains in the Coast Range of Central California. The Las Tablas Creek watershed is approximately 12 miles from the Pacific Ocean near Cambria, California, and approximately 13.5 miles from the Salinas River near Paso Robles. Mineral extraction for mercury began at the Site in the late 1860s and continued until 1970. Mercury production at the Site involved roasting cinnabar-containing ore to recover mercury. The ore was heated in retorts or furnaces to vaporize the mercury from the ore. The vapor was then cooled and resulting elemental liquid mercury was collected in iron flasks. Byproducts of mercury production include mine tailings, low grade ore and waste rock. In addition, mercury production activities resulted in the release of mercury to the air which was subsequently deposited on the ground surface in the vicinity of the production areas. During mining operations, waste rock, tailings and mercury extraction wastes were dumped in drainage channels situated downstream from the mines. Weathering from heavy rains caused deep erosion channels to develop throughout the Site, thereby releasing additional sediment into the North Fork of Las Tablas Creek and the Klau Branch of the South Fork of Las Tablas Creek. Las Tablas Creek has carried sediment from the mining influenced areas to Las Tablas Creek Ranch Reservoir. Las Tablas Creek Ranch Reservoir, a private reservoir, is located within the lower reaches of Las Tablas Creek upstream of Lake Nacimiento (Figure 2). Las Tablas Creek Ranch Reservoir was formed by construction of an earthen dam in 1958 and is the body of water being surveyed. C. The work to be performed under this section includes the furnishing of all labor, materials, equipment, and other facilities and incidentals necessary to conduct a bathymetric survey at the Site. Generally, the survey will include the following tasks: Task 1: Mobilization/Demobilization – Mobilization includes the movement of all equipment, personnel, and material to the Site for the completion of the survey. Demobilization includes the removal of all equipment, personnel, and material from the Site at the completion of onsite activities. Task 2: Bathymetric Survey – The Subcontractor will perform a single beam bathymetric survey of Las Tablas Creek Ranch Reservoir. The survey area, shown on Figure 2, will include the area where Las Tablas Creek flows into Las Tablas Creek Ranch Reservoir and the reservoir up to the earthen dam. A ground SOW-1 control point was established by Sea Engineering Inc. during a bathymetric survey in summer 2014 and marked with a PK nail. The purpose of the summer 2015 bathymetric survey is to evaluate changes to the reservoir sediment bed geometry over the course of a year. Task 3: Reporting – The Subcontractor will produce a report describing the results of the bathymetric survey. D. The summer 2014 control point was established using a static position dataset recorded for more than 8 hours, for comparison to the first static position dataset. The first static position dataset was collected over approximately 30 minutes on the previous day. Both datasets were submitted to the Online Positioning User’s System (OPUS) for rapid static processing, yielding the three‐dimensional coordinate location of the temporary survey control point. Subsequently, six individual raw positioning files were recorded and submitted to OPUS. Coordinate solutions of each differed by less than 0.2‐feet from the average values of all the solutions. Representative coordinate solutions from each day are shown in Table 1. The GPS Base Station coordinates used for the project control point are shown highlighted in gray at the bottom of the table. Table 1 – OPUS Coordinate Solutions from Establishment of Temporary Survey Control Date 5/11/2014 5/12/2014 GPS BASE Project Coordinates E. Base Station Coordinate Solutions Orthometric Latitude (N) Longitude (W) Height (NAVD88) 35 41 4.86437 120 56 25.90013 839.45’ 35 41 4.86438 120 56 25.89992 839.46’ 35 41 4.86435 120 56 25.89999 839.45’ The survey shall be completed in May or June 2015. SOW-2 3.2 Requirements 3.2.1 Mobilization/Demobilization A. The Subcontractor’s mobilization/demobilization to the Site will include, but is not limited to, transportation of the boat and associated equipment, equipment for conducting the bathymetric survey, sub-meter global positioning satellite (GPS) system, water, crew, and per diem. B. The boat must be cleaned to prevent zebra mussels and other aquatic organisms from being unintentionally introduced into the reservoir. Facilities for cleaning the boat are not present at the Site. C. Time for daily health and safety tailgate meetings. D. Tying into the temporary ground control point established in summer 2014 (Figure 2). E. Site clean-up including removal of Subcontractor-generated debris and trash. F. The Subcontractor will be responsible for preserving, protecting, and preventing damage to all public and private property. The Subcontractor shall minimize impacts to wetland areas. G. Removal of Subcontractor equipment and other non-hazardous waste materials, including personal protective equipment (PPE), various packaging materials, plastic sheeting, and general refuse which will be disposed of at the Subcontractor’s off-site disposal containers. H. All other costs not specifically included in other bid items. Mobilization will also include all charges incidental to the Subcontractor's cost for safety training, PPE, life jackets and working over the water. The Subcontractor will be responsible for securing their equipment and all materials while at the Site. The Contractor will not be responsible for any of the Subcontractor's material or equipment that may be vandalized, stolen or otherwise rendered unsuitable for use on this project. A small storage container will be available for the Subcontractor to store a few small items. 3.2.2 Bathymetric Surveys A. The Subcontractor will perform a single beam bathymetric survey along the water body using an Odom Echoscan shallow water acoustic bathymetric survey system or equivalent, a Trimble R8 RTK GPS or equivalent, and a Trimble TSC2 data collector with Trimble survey controller or equivalent. Data will be processed using Hypack Max software or equivalent B. The Subcontractor’s vessel shall be equipped with a differential global positioning system (DGPS) and shall allow access to shallow water along the shore and in the upstream portion of the reservoir such that the bathymetric survey area is maximized. C. The bathymetric survey will be performed in a manner consistent with the United States Army Corps of Engineers (USACE) Class 1 survey methods and accuracies. D. The maximum interval between survey lines shall be 25 feet and sounding precision will be six (6) inches with sounding intervals every five to ten feet. SOW-3 E. Survey work conducted by the Subcontractor must be performed during weather and reservoir conditions adequate for quality survey results. An approved daily log must be kept to record the personnel, craft, conditions, activities, and equipment used during each day of work. A 10-hour work day is assumed for all activities. F. Bathymetric survey vessels will conform to the U.S. Coast Guard requirements for passenger-carrying vessels of its size. The vessel will have adequate seating space for each survey crewmember. An operator possessing a valid U.S. Coast Guard license to pilot passenger-carrying vessels shall be present on the vessel during all sounding operations. G. Bathymetric survey procedures (positioning modes; GPS calibration, accuracy requirements; depth measurements calibration; and data reduction, adjustment, processing, and plotting, etc.) shall conform to industry standards similar to those in the Hydrographic Survey Manual, Corps of Engineers Manual (EM 1110-2-1003, 01 January 2002) and other recognized technical manuals. H. Each sounding for depth will be accomplished by a fully integrated and automated hydrographic data acquisition system utilizing a single-beam echo sounder that 1) is capable of speed of sound correction adjustments and has a frequency operating capability of 200 kilohertz (kHz) +/-20 with a manufacturer’s stated accuracy of 0.03 meters (0.1 foot) or less, and 2) has motion sensor capability with a manufacturer’s stated compensation accuracy of +/-0.05 degrees or less for vessel pitch and roll and the greater of 5 centimeters (cm) or 5 percent for heave. I. Bar checks and calibration will be performed at the intervals specified in EM 1110-2-1003 for Class 1 surveys. A velocity meter/sound profiler may be substituted for a bar and will be performed in accordance with Manual specifications. Calibrations and checks will be taken at 3-meter intervals or less to the maximum working depth at the Site and shown on the depth record (fathometer rolls and/or in field notes). J. Navigation line spacing interval for data collected shall be determined onsite for optimum beam coverage and overlap in order to meet the accuracy and resolution required to ensure that no gap in coverage exists. Cross-line checks shall be run for all Class 1 surveys. Procedures and tolerances will conform to criteria prescribed in EM 1110-2-1003. K. Survey files will be edited to eliminate extraneous data and display an accurate representation of the area of interest. Data with a quality index of less than 3 and depths below or above known parameters will be eliminated. The thinning interval will not exceed 10 feet. 3.3 Submittals and Deliverables for the Bathymetric Survey A. The Subcontractor will provide coordinate data files, processed to a comma-delineated ASCII format to the Contractor. Data sequence shall be Point ID, Northing, Easting, Elevation, and Description of every sounding. B. The Subcontractor shall prepare the drawings using AutoCAD® 2013 or compatible version of AutoCAD® so that the Contractor can work with the files after the Subcontractor has prepared the drawings. AutoCAD® drawings shall be prepared in accordance with the national computer aided drafting (CAD) standards, which can be obtained at http://www.nibs.org. C. The draft and final drawings shall be submitted on a labeled CD-ROM. At the discretion of the Contractor, drawings may be zipped for convenience of delivery and the drawings sent via email. Only the default text font shall be used. D. Drawings shall include the following: SOW-4 a. b. c. d. e. f. g. h. i. Survey date; Project name; North arrow; Bar scale; Coordinate grid tics; 1-foot Contour lines; Shorelines and structures; Contract number; and Survey firm. 3.4 Quality Assurance/Quality Control Requirements A. The Subcontractor shall be licensed by the California Board of Professional Engineers, Land Surveyors, and Geologist. B. The Subcontractor shall have all applicable certifications and shall employ only qualified personnel for the execution of this work. All work shall be performed under the direct supervision of an experienced analyst. The Contractor reserves the right to have the Subcontractor remove and replace Subcontractor and/or lower-tier Subcontractor personnel deemed in view of the Contractor to be unqualified for this particular project. Such removal and replacement of personnel will be totally at the Subcontractor's expense. C. The Contractor may make any investigations deemed necessary to determine the ability of the Subcontractor to perform the work; and the Subcontractor shall furnish to the Contractor any information requested for this purpose. D. The Subcontractor selected for performing this work shall have performed work similar to that described in this Statement of Work/Specifications. E. The Subcontractor shall be available for a conference call with the Contractor’s Project Manager and Technical Leader to: 1. 2. 3. 4. 5. 6. 7. Confirm survey schedule. Identify the Contractor and Subcontractor contacts for technical issues/surveying issues/administrative issues etc. Become knowledgeable of the Contractor’s expectations on invoices. Confirm and clarify SOW requirements – turnaround times, deliverables, and reporting requirements etc. Review communication requirements – identify communication triggers (equipment breakdown, quality Issues/ analytical problems, etc.). Verify Contractor’s client requirements. Review health and safety requirements for working at the Site. Coordinate Site access prior to mobilization, including launching the boat in Las Tablas Creek Ranch Reservoir, a privately owned reservoir. F. The Subcontractor shall maintain documentation of all tasks required in this SOW. G. The Subcontractor shall ensure internal QC over its activities and work products, as well as implement corrective action if non-conformances occur. H. The Subcontractor shall maintain equipment according to manufacturer specifications. I. The Subcontractor shall provide calibration records for equipment, if applicable. J. The Subcontractor shall agree to an onsite audit of field procedures by the Contractor if requested. SOW-5 K. The Subcontractor shall perform an internal quality review of work products prior to submittal to the Contractor. L. The Subcontractor shall notify the Contractor of quality problems and corrective action taken. M. The Subcontractor shall review health and safety requirements with the Contractor’s Project Manager prior to working at the Site. N. The Subcontractor shall coordinate Site access with the Contractor’s Project Manager prior to mobilization, including launching the boat in Las Tablas Creek Ranch Reservoir. 3.5 Health and Safety The Subcontractor shall perform all work tasks in accordance with the Contractor’s Site health and safety plan (SHASP). The SHASP is included in Section 4 for the Subcontractor to review. If the Subcontractor chooses to follow their own SHASP, then they will submit a copy to the Contractor for review prior to working at the Site. 3.6 Notification A. The Subcontractor shall commence activities within 10 calendar days of Notice to Proceed from the Contractor. The fieldwork is anticipated to occur in May or June 2015. B. The Subcontractor shall notify the Contractor’s Contracting Officer and Project Manager in writing at least 24 hours in advance of any anticipated delays in the agreed upon schedule. 3.7 Reporting Requirements A. The required deliverable format is a pdf and native files which will include Microsoft Word, Excel, geographic information systems (GIS) and AutoCAD® 2013 or compatible file types. B. Within 30 days of completion of the survey the report should be submitted via e-mail to the following: 1. Contractor Project Manager, To Be Provided Upon Award 2. C. Technical Lead, To Be Provided Upon Award The report should be submitted to the Contractor’s project manager, via email. 3.8 Warranties and Representation The Subcontractor shall be responsible for the professional quality of the work including: 1. The work, accuracy, and completeness of the survey. 2. The Subcontractor has in effect QA procedures that shall ensure the quality of services that are performed. 3. The Subcontractor possesses and shall maintain all licenses and certifications that are required for the work. The Subcontractor shall present evidence thereof upon request by the Contractor or the EPA and shall notify the Contractor immediately by telephone, and confirm in writing within 1 business day, after any decertification or revocation on any license, or notice thereof. 3.9 Measurement and Payment SOW-6 Item 1 - Bathymetric Survey and Final Report. This item shall be paid on a lump sum/firm fixed price basis and shall include all costs associated with performing the bathymetric survey services in accordance with the Statement of Work. 3.10 Permits The Subcontractor is responsible for obtaining any and all permits required to perform the work outlined in this scope of work. 3.11 Schedule The Contractor anticipates that the survey will be conducted in May or June 2015. The Contractor reserves the right to revise the schedule at no additional Subcontractor cost. The Subcontractor will be promptly notified of any changes to the schedule. SOW-7 C:\KBV\Work Plan Figure 1_Location Map.mxd 9/27/2013 [10:42 AM] Project Location HORRIEAM, CDM Smith Lake Nacimiento OU3 OU2 OU1 O Project Extent 4 Note: Background map courtesy of ESRI ®. OU - Operable Unit 0 4 Miles Technical Work Plan Klau and Buena Vista Mines Superfund Site San Luis Obispo County, California FIGURE 1 Site Location Map T:\100169-KBV\GIS\MXD\2014\BathymBaseMap_meanWindSpeed.mxd 10/13/2014 [10:23 AM] HUSEKE, CDM Smith y X - approximate location of summer 2014 temporary ground control point 100 0 100 200 Feet Bathymetric Contours (1 ft interval) 792 ft 803 ft O Notes: 1. Bathymetric Contours: Sea Engineering, May 2014 2. Background Hillshade: Quantum Spatial 3. Background Aerial Source: Esri, DigitalGlobe, GeoEye, i-cubed, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community Klau/Buena Vista Mines Superfund Site San Luis Obispo County, California 2 FIGURE 1.3-1 2013-2014 Wet Season Mean Wind Speed and Direction for Las Tablas, California PART 4 HEALTH AND SAFETY OUTLINE PART 4 - HEALTH AND SAFETY HAZARDOUS WASTE SITES/OPERATIONS 4.1 INTRODUCTION A. The following material outlines, generally, the relationship that CDM Smith maintains with Subcontractors in health and safety related matters. It attempts to define the responsibilities that each has as they relate to work associated with hazardous waste sites. 4.2 RESERVED 4.2.1 RESERVED 4.2.2 RESERVED 4.2.3 WORK ON HAZARDOUS WASTE SITES OR HAZARDOUS WASTE OPERATIONS A. The following protocols are intended to address OSHA 29 CFR 1910.120 regulations. B. The work to be carried out under these protocols is on or adjacent to a hazardous waste site or operation. Hazardous materials are or may be present in the air, on the surface or subsurface. These materials may require the use of protective clothing and respiratory protective equipment to minimize chemical exposure. The Subcontractor and his employees shall implement and maintain all appropriate procedures as they apply to Subcontractor's work prior to, during and after performance of the work. Subcontractor is responsible for ascertaining the level of protection for each task and assuring that its employees and its subcontractor employees are properly equipped. Subcontractor personnel must have the training and medical approvals required by the 29 CFR 1910.120 regulation. The Subcontractor and his employees shall implement and maintain all appropriate procedures at least as strict as these as they apply to Subcontractor's work prior to, during and after performance of the work, unless exempted as in 4.2.4, below. C. Subcontractor personnel must have the medical and training approvals required by the OSHA Hazardous Waste Operations standard and described in Sections 4.3 and 4.4 of this protocol. Subcontractor must certify that the personnel meet these guidelines. D. All personnel either in or adjacent to the work zone shall wear the appropriate protective equipment. 4.3 HEALTH AND SAFETY PLANS - WORK ON HAZARDOUS WASTE SITES OR HAZARDOUS WASTE OPERATIONS 4.3.1 SUBCONTRACTOR HEALTH AND SAFETY PLANS A. The Subcontractor shall develop and implement their own Health and Safety Plan (HASP). If CDM Smith is required to develop a site HASP, a copy will be supplied to the Subcontractor. HSP-1 Part 4 Rev Sept 2009 This HASP may be used as a guide to outline the minimum requirements of the Subcontractor's HASP, but CDM Smith does not represent or warrant that it's HASP is an adequate or complete guide for the Subcontractor's work and the Subcontractor remains fully responsible for the adequacy and completeness of its own HASP. If the Subcontractor's work is essentially the same as that described in the HASP, the Subcontractor may elect, with the concurrence of the CDM Smith Health and Safety Manager, to utilize the provisions of the CDM Smith HASP in its entirety. When this is permitted, all Subcontractor employees involved with the work will be required to read and understand the contents of the HASP and sign the signature form contained in the HASP. Prior to work on hazardous sites, the Subcontractor shall provide CDM Smith with a fully completed and executed signature form, which acknowledge that the worker has read and understood the HASP. The Subcontractor is fully responsible for the implementation and maintenance of the requirements of the HASP. B. Subcontractor's HASP shall be consistent with the following requirements: 1. OSHA Safety and Health Standards 29 CFR 1910 (General Industry), U.S. Department of Labor, Occupational Safety and Health Administration. Hereafter, referred as "29 CFR 1910" 2. OSHA 29 CFR 1910.120 Hazardous Waste Operations and Emergency Response, U.S. Department of Labor, Occupational Safety and Health Administration 3. OSHA Safety and Health Standards 29 CFR 1926 (Construction Industry), U.S. Department of Labor, Occupational Safety and Health Administration 4. Standard Operating Safety Guidelines, EPA Office of Emergency and Remedial Response Publication 9285.1-03. Hereafter referred to as "EPA Guidelines" 5. Occupational Safety and Health Guidance Manual for Hazardous Waste Site Activities, U.S. Department of Health and Human Services, Public Health Service, Centers for Disease Control, National Institute for Occupational Safety and Health. 6. Client Health and Safety Requirements. 4.3.2 ADOPTION OF HEALTH AND SAFETY PLAN A. If the Subcontractor adopts CDM Smith’s Plan, the Subcontractor shall acknowledge this with the signature of a designated representative on a letter accepting the plan. The letter will be provided prior to commencing work activities. (CDM Smith does not warrant that the CDM Smith Plan will be sufficient for Subcontractor's work. Subcontractor must make an independent determination of the applicability of the CDM Smith Plan to the Subcontractor's work and must comply with all applicable statutes, regulations and codes.) B. If the Subcontractor adopts the CDM Smith Plan, this plan becomes the responsibility of the Subcontractor to implement as it pertains to Subcontractor's work. The Subcontractor assumes all liabilities from such adoption and implementation. C. If a Subcontractor develops a health and safety plan, Subcontractor shall provide it to CDM HSP-2 Part 4 Rev Sept 2009 Smith for review within five (5) days after award of this Subcontract, or at least five (5) days prior to commencement of operations at the job site, whichever occurs last. Subcontractor shall certify in writing its intention to adopt the CDM Smith Plan prior to commencement of operating at the job site. D. The Subcontractor assumes all liabilities associated with the implementation of the Plan. 4.3.3 CONTENTS OF SUBCONTRACTOR HASP A. The Subcontractor's HASP shall include, but not necessarily be limited to, the following components, as appropriate: 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. Characterization and Analysis Safe Work Practices Engineering Safeguards Medical Surveillance Environmental and Personal Monitoring Personal Protective Equipment Training Standard Operating Procedures Control and Decontamination Emergency and Contingency Planning Logs and Reports Hazard Communication Program Material Handling Sanitation Excavation 4.3.4 MODIFICATIONS TO HEALTH AND SAFETY PLANS A. Should the Subcontractor seek relief from, or substitution for, any portion or provision of the Subcontractor's HASP, such relief or substitution shall be requested of CDM Smith in writing. The requested modification will not be implemented until authorized by CDM Smith unless necessary to prevent imminent danger to life, property or the environment. B. Subcontractor shall quickly notify CDM Smith, both verbally and in writing, of any unforeseen hazard, safety related factor, or condition they observe during the work at the site. In the interim, Subcontractor shall take prompt action to establish and maintain safe working conditions and to safeguard employees, the public, and the environment in accordance with the HASP. Should CDM Smith modify any portion or provision of CDM Smith’s Plan, CDM Smith will notify the Subcontractor in writing of such modifications. C. 4.3.5 ENFORCEABILITY A. If the Subcontractor does not fulfill these requirements the Subcontract may be suspended and/or terminated in accordance with the applicable default termination clause in the subcontract. In the event of suspension and/or termination, the Subcontractor will not be deemed eligible for standby time or other compensation for down time during such periods. Failure to comply with these HSP-3 Part 4 Rev Sept 2009 requirements, when failure impacts the performance schedule of the prime contract, may subject the Subcontractor to claims for incidental or consequential damages. B. Any disregard for the provisions of these Health and Safety requirements shall be deemed just and sufficient cause for termination of this subcontract. 4.4 MEDICAL SURVEILLANCE 4.4.1 PHYSICIAN'S CERTIFICATION A. The Subcontractor shall utilize the services of a physician to provide medical surveillance as required by OSHA regulations. The physician's certification of each Subcontractor staff member involved in performance of work under this subcontract shall be on file in Subcontractor's office and available upon request by CDM Smith prior to the Subcontractor commencing work. The certificate must bear the name of the employee and the signature of the physician. The physician must certify that each individual is medically qualified to use respiratory protective devices for the assigned work and is fit to perform the assigned work. 4.4.2 MEDICAL SURVEILLANCE PROTOCOL A. Medical surveillance protocol for the Subcontractor's employees is the responsibility of the Subcontractor's physician. However, certification shall be provided that such medical surveillance meets the requirements of OSHA Standards 29 CFR 1910.120 for all personnel. 4.4.3 FREQUENCY OF EXAMINATION A. Medical examinations must be provided in the following conditions: 1. 2. 3. 4. More than a year has passed since the employee's last examination. The employee is returning to work from a lost time or other short term disability/situation or has reason to suspect that an acute exposure to a toxic or hazardous material has occurred. The examining physician requests it. The employee leaves the company or transfers to a position which would not require potential exposure to hazardous waste. 4.5 TRAINING 4.5.1 BASIC HEALTH AND SAFETY TRAINING A. The Subcontractor shall submit a statement indicating that personnel to be within the work zone understand they are working on a hazardous waste site/operation and are trained and qualified in compliance with 29 CFR 1910.120. In addition, all subcontractor personnel will be adequately trained for the work to which they are assigned. B. Subcontractor's personnel must have completed the training requirements specified in the OSHA regulations. HSP-4 Part 4 Rev Sept 2009 4.5.2 SITE SPECIFIC TRAINING A. A site-specific training session for Subcontractor personnel scheduled to work on site will be conducted by the Subcontractor prior to any work on site. 4.6 EQUIPMENT 4.6.1 PROVISION OF SAFETY EQUIPMENT A. Subcontractor shall supply all protective clothing and equipment necessary for their personnel and maintained in accordance with the manufacturer's specifications. All equipment shall be Mine Safety and Health Administration (MSHA)/NIOSH approved, if applicable. 4.6.2 ONSITE EQUIPMENT USE A. Subcontractor's personnel shall not enter an area to perform a task for which a respirator might be required unless they are in compliance with 29 CFR 1910.134, Respiratory Protection. All onsite personnel shall wear a hard-hat where required by the client, OSHA, state or local regulations. B. All prescription eyeglasses worn on site shall be safety glasses. Subcontractor shall provide prescription lens inserts for employees who need to wear full face respirators. Contact lenses are prohibited inside respirators. C. All personnel protective equipment worn on site will be decontaminated and/or properly disposed of at the end of the work day. D. All safety clothing, including work clothing and safety boots, which have entered the work zone shall be properly decontaminated and/or disposed of. 4.7 PERSONAL HYGIENE A. Subcontractor personnel shall observe the following contamination control rules while on site. B. Eating, drinking, smoking, chewing gum or tobacco, and other practices that increase the probability of hand-to-mouth transfer and ingestion of material is prohibited in any area designated as a contaminated area. C. Hands and face shall be thoroughly washed upon leaving the work area and before eating, drinking, smoking, etc. D. Whenever decontamination procedures for protective clothing are in effect, the entire body shall be thoroughly washed as soon as possible after the protective clothing is removed. E. No facial hair which interferes with a satisfactory fit of a respirator mask-to-face-seal is allowed on personnel required to wear respiratory protective equipment. F. The use of prescription drugs is prohibited unless documentation from the prescribing physician HSP-5 Part 4 Rev Sept 2009 stating that the drugs will not interfere with the employee's ability to work is provided. G. Alcoholic beverages are prohibited and employees appearing to be under the influence of alcohol or illegal drugs will not be allowed site access, or will be removed from the site. 4.8 SITE HEALTH AND SAFETY CONTROL 4.8.1 SITE HEALTH AND SAFETY COORDINATOR (SHSC) A. CDM Smith’s Site Health and Safety Coordinator (SHSC) is responsible to ensure that the CDM Smith HASP is implemented and followed by CDM Smith employees. The SHSC may also provide periodic observation of the Subcontractor activities for compliance with the Subcontractor's HASP. The periodic observation by SHSC shall not relieve the Subcontractor of its sole responsibility to comply with all applicable statutes, regulations and codes and it is the Subcontractor not the SHSC who is solely responsible for the compliance of its employees. 4.8.2 AIR MONITORING A. Air monitoring for pollutants of concern may be performed by CDM Smith or others, unless specifically assigned to the Subcontractor. Photoionization detectors (PIDs), organic vapor analyzers (OVAs), and additional appropriate equipment may be used to measure and assess chemical exposure. Results will be provided to the Subcontractor. 4.8.3 ACCIDENT REPORTING A. The Subcontractor will inform the CDM Smith SHSC, CDM Smith Health and Safety Manager or the CDM Smith Project Manager as soon as possible, of any accidents, injuries, illnesses, or environmental releases associated with this Subcontract. HSP-6 Part 4 Rev Sept 2009 Contract No.: GS‐10F‐0227‐J Order No.: EP‐G139‐00181 Health and Safety Plan Sediment Erosion and Deposition Assessment (SEDA) and Contaminant Loading Evaluation, Klau and Buena Vista Mines Superfund Site, San Luis Obispo County, California CDM Federal Programs Corporation 1218 Third Avenue, Suite 1100 Seattle, WA 98101 November 12, 2013 HEALTH AND SAFETY PLAN FORM CDM Smith Health and Safety Program This document is for the exclusive use of CDM Smith and its subcontractors PROJECT NAME Klau Buena Vista Mine Superfund PROJECT# 100169 REGION SITE ADDRESS 780 Klau Mine Rd CLIENT ORGANIZATION Paso Robles, CA 93446 CLIENT CONTACT San Luis Obispo County, CA US EPA Jim Sickles 415 / 972 - 3265 CLIENT CONTACT PHONE # (No) AMENDMENT TO EXISTING APPROVED H&SP? ( ) H&SP AMENDMENT NUMBER? ( ) DATE OF PREVIOUS H&SP APPROVAL OBJECTIVES OF FIELD WORK: (e.g. collect surface soil samples): SITE TYPE: 1. Mobilize to Site 2. Install sampling stations 3. Perform stream survey 4. Perform dry-weather sampling activities 5. Perform wet-weather sampling activites 6. Collect sediment samples in creek 7. Install and monitor sediment traps in reservoir 8. Perform LiDAR and bathometric survey in reservoir 9. SedFlume Erodability study Check as many as applicable Active ( ) Landfill ( ) Unknown ( ) Inactive (X) Uncontrolled ( ) Military ( ) Secure (X) Industrial (X) Other (specify) Mine Unsecure (X) Recovery ( ) Enclosed space ( ) Well Field ( ) All requirements described in the CDM Smith Health and Safety Manual are incorporated in this health and safety plan by reference. Company / Division Current Training / Office & Medical? PERSONNEL AND RESPONSIBILITIES NAMES OF WORK CREW MEMBERS Project or Site Responsibilities Tasks On Site? Andrew Greazel CDM Smith/CED/PDX Yes Work Assignment Manager 1-2-3-4-5-6-7-8-9 Ryan Wood Craig Nochajski CDM Smith/CED/WLC Yes Site Safety Officer (SSO) and alternate Field Team Leader (FTL) CDM Smith/CED/LTC Yes 2nd H&S Coordinator and FTL 1-2-3-4-5-6-7-8-9 1-2-4-5-6-7 Neal Batchelder CDM Smith/CED/LTC Yes Field Staff 1-2-3-4-5-6-7-8-9 Eric Blischke CDM Smith/CED/PDX Yes Technical Leader 1-2-3-4-5-6-7-8-9 NA Yes Subcontractor Sea Engineering, LiDAR, and Bathymetric Subcontractors BACKGROUND REVIEW: Page-1 ( ) Complete 8-9 ( ) Incomplete KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN FORM This document is for the exclusive use CDM Smith Health and Safety Program of CDM Smith and its subcontractors SITE MAP: Show Exclusion, Contamination Reduction, and Support Zones. Indicate Evacuation and Reassembly Points Page-2 KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN FORM This document is for the exclusive use CDM Smith Health and Safety Program HISTORY: of CDM Smith and its subcontractors Summarize conditions that relate to hazard. Include citizen complaints, spills, previous investigations or agency actions, known injuries, etc. From the EPA Superfund website: The Klau/Buena Vista Mine is located in San Luis Obispo County, approximately 12 miles west of Paso Robles, California. The Klau/Buena Vista Mine consists of two abandoned mercury mine sites (Klau and Buena Vista) that are located on adjacent properties on a northwest‐southeast ridge of the Santa Lucia Range in the California coastal mountains. Mercury mining and ore processing operations occurred at the Buena Vista Mine and adjacent Klau Mine between 1868 and 1970. In 1999, the California Central Coast Regional Water Quality Control Board (RWQCB) requested that the EPA Region 9 Emergency Response Office assist in preventing the continued release of mercury‐laden sediments and other contaminants from the site. Substantial site stabilization work was conducted. These actions have reduced the discharge of acid mine drainage (AMD) and discharge into Las Tablas Creek, but uncontained contamination remains on the site. The remedial investigation began in 2007. Phase I sampling for the remedial investigation was completed in November 2007. Soil, sediment, surface water and biota were sampled. Phase II sampling of surface water and biota was completed in April 2008. Concurrent with the remedial investigation activities, EPA Emergency Response staff returned to the site in Summer 2008 to address seepage of acid mine drainage from the Buena Vista Mine Tailings repository, fill in a new sinkhole at the Klau Mine portion of the site, and perform general site maintenance. A data summary of the Phase I and II sampling was released in October 2008 and work was begun on both the human health risk assessment and screening level ecological risk assessment. Additional sampling of a second stormwater event and the installation of groundwater monitoring wells was conducted in mid‐2009. The draft Remedial Investigation Report was submitted in August 2011. The site has been divided into operable units. OU 1 includes the mine site; OU 2 includes Las Tablas Creek between the Klau/Buena Vista Mine and Harcourt Reservoir; OU 3 includes Las Tablas Creek downstream from Harcourt Reservoir and Lake Nacimiento. WASTE TYPES: ( X ) Liquid WASTE CHARACTERISTICS: ( X ) Solid ( X ) Sludge ( ) Gas ( ) Unknown Check as many as applicable. ( ) Corrosive ( ) Flammable ( ) Radioactive ( X ) Toxic ( ) Volatile ( ) Reactive ( ) Inert Gas ( ) Unknown Monitoring stations will be installed directly below the Klau and Buena Vista adits (OU1). The highest concentrations of metals is expected in these work zones. The remaining work will be performed in OU2 which includes the Las Tablas Creek Watershed and Las Tablas Creek Reservoir areas. Much lower concentrations (nonacute) of metals are expected in these work zones. Work will only be performed in OU1 and OU2. Formal work zones will not be established. ( ) Other: HAZARDS OF CONCERN: ( ) Other, specify: WORK ZONES: Check as many as applicable. FACILITY'S PAST AND PRESENT DISPOSAL METHODS AND PRACTICES: ( X ) Heat Stress CDMS Guideline ( X ) Noise ( X ) Cold Stress CDMS Guideline ( X ) Inorganic Chemicals ( ) Explosive/Flammable ( ) Organic Chemicals ( ) Oxygen Deficient ( X ) Motorized Traffic ( ) Radiological ( ) Heavy Machinery (X) Biological ( X ) Slips & Falls ( X ) Other: Ticks, snakes, & wildlife ( X ) Other: Drowning, Moving water in Creek CDMS Guideline CDMS Guideline During active mining, waste rock, tailings and mercury extraction wastes were dumped in drainage channels situated downstream from the mines. This plan incorporates CDM Smith's procedure (in Appendix A) for: Page-3 Traffic and Work Zone Safety Tools and Power Equipment Heat Stress Decontamination at Hazardous Waste Sites Personal Protective Equipment Cold Stress Material Handling Working Near or Over Water KBV Final HASP for SEDA.xlsx Fall Protection 11/6/2013 HEALTH AND SAFETY PLAN FORM CDM Smith Health and Safety Program DESCRIPTION AND FEATURES: This document is for the exclusive use of CDM Smith and its subcontractors Include principal operations and unusual features (containers, buildings, dikes, power lines, hillslopes, rivers, etc.) The site is located in the Coast Range of California, so the terrain is mountainous, with potentially unstable slopes. Operable Unit No. 1 consists of the two adjacent mine sites (making up 317 acres, including five miles of underground workings, a two acre mine pit, and slopes comprised of approximately 300,000 tons of mine tailings, overburden and waste rock). The area around the site is characterized by steep topography, with elevations ranging from 1,050 feet to more than 1,600 feet. During mining operations, mining waste, including waste rock, tailings and mercury extraction wastes were dumped in drainage channels situated downstream from the mines. Operable Unit No. 2 consists of Las Tables creek watershed, which recieves little to no rainfall from May to November, but can recieve 30‐40 inches of rain the rest of the year. Operable Unit No. 3 consists of Lake Nacimiento, which is located downstream of Las Tables creek. It was created by the construction of Nacimiento Dam in 1957. The lake’s irregular shoreline comprises about 165 miles. The reservoir’s maximumcapacity is 377,900 acre feet with a surface elevation of 800 feet. SURROUNDING POPULATION: ( ) Residential HAZARDOUS MATERIAL SUMMARY: CHEMICALS: SOLIDS: Amount/Units: 2mL per sample bottle ( ) Industrial ( ) Commercial ( ) Rural ( ) Urban OTHER: Highlight or bold waste types and estimate amounts by category. SLUDGES: SOLVENTS: OILS: OTHER: Amount/Units: Dissolved in surface water and comingled with sediments Amount/Units: Amount/Units: Amount/Units: Amount/Units: Acids Flyash Paints Ketones Oily Wastes Laboratory Pickling Liquors Mill or Mine Tailings Pigments Aromatics Gasoline Pharmaceutical Caustics Asbestos Metals Sludges Hydrocarbons Diesel Oil Hospital Pesticides Ferrous Smelter POTW Sludge Alcohols Lubricants Radiological Dyes or Inks Non-Ferrous Smelter Distillation Bottoms Halogenated (chloro, bromo) Polynuclear Aromatics Municipal Cyanides Metals Aluminum Esters PCBs Construction Phenols Dioxins Ethers Heating Oil Munitions Other - specify Other - specify Other - specify Halogens Other - specify Page-4 Other - specify Other - specify KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN FORM This document is for the exclusive use of CDM Smith and its subcontractors CDM Smith Health and Safety Program HIGHEST PEL/TLV IDLH Warning KNOWN OBSERVED ppm or mg/m3 ppm or mg/m3 Concentration SYMPTOMS & EFFECTS IONIZATION CONTAMINANTS CONCENTRATION (specify) (specify) (in ppm) OF ACUTE EXPOSURE POTENTIAL Slightly above background 10 µg/m3 5 mg/m3 Dust Nasal ulcers, fever, bronchitis, melanosis, peripheral neuropathy Dust Liquid mercury in OU1 soil 25 µg/m3 10 mg/m3 NA Severe abdominal pain tremors, weakness, GI irritation, fatigue 10.40 Arsenic, inorganic Mercury and compounds (skin) NA = Not Available S = Soil A = Air Page-5 NE = None Established SW = Surface Water GW = Ground Water U = Unknown T = Tailings SL = Sludge W = Waste D = Drums PHOTO Verify your access to an MSDS for each chemical you will use at the site. TK = Tanks L = Lagoons KBV Final HASP for SEDA.xlsx SD = Sediment OFF = Off-Site 11/6/2013 HEALTH AND SAFETY PLAN FORM CDM Smith Health and Safety Program SPECIFIC TASK DESCRIPTIONS 1 Mobilize to Site 2 Install sampling stations 3 Perform stream survey of creek bed and creek bank 4 Perform dry-weather sampling activities 5 Perform wet-weather sampling activities Page-6&7 This document is for the exclusive use of CDM Smith and its subcontractors Disturbing the TASK - SPECIFIC HAZARDS Waste? HAZARD & SCHEDULE Low Hazard Non-intrusive This task includes driving to and from the site. Driving conditions will consist of 4 to 8 hours of driving on highways, and 15 to 20 miles of driving on curvy, mountain roads that are paved and unpaved in possibly wet, rainy conditions. Non-intrusive Installation of sampling stations will consist of carrying, handling, and setting up equipment near the creek. This will involve safely climbing up and down steep creek banks and working in vegitative areas. Work will be performed during the dry season, but flowing water may be present. Slips, trips, and falls. Non-intrusive Stream survey of creek bed will involve taking distance and elevation measurements within the creek and along the creek bank. This will involve safely climbing up and down steep creek banks. Work will be performed during the dry season, wet season, and storm events. Slips, trips, and falls. Medium Hazard Non-intrusive Use of sampling equipment after installation is complete. This will involve safely climbing up and down steep creek banks. Work will be performed during the dry season, but flowing water will be present. Slips, trips, and falls. Lifting heavy sample coolers. Medium Hazard Non-intrusive Use of sampling equipment during high intensity rain events. This will involve safely climbing up and down steep creek banks. Fast moving water in creek presents a drowning hazard and the possiblility of being hit by floating debris. Saturated slopes along creek beds are subject to slope failure. Working surfaces will be slippery. Slips, trips, and falls. Lifting heavy sample coolers. KBV Final HASP for SEDA.xlsx Moderate Hazard Medium Hazard 11/6/2013 HEALTH AND SAFETY PLAN FORM CDM Smith Health and Safety Program SPECIFIC TASK DESCRIPTIONS 6 Collect sediment samples in creek 7 Intall and monitor sediment traps in reservoir 8 Perform bathometric survey in reservoir 9 SedFlume Erodability study SPECIALIZED TRAINING REQUIRED: This document is for the exclusive use of CDM Smith and its subcontractors Disturbing the TASK - SPECIFIC HAZARDS Waste? HAZARD & SCHEDULE Medium Hazard Intrusive Sediment will be collected within the creek. This will involve safely climbing up and down steep creek banks. Work will be performed during the dry season, but flowing water will be present. Drowining; slips, trips, and falls. Lifting heavy sample coolers. Moderate Hazard Intrusive Installation of sediment traps in the reservoir will involve being on a small boat in the reservoir. Working over water and soft sediment present drowning hazards. Exposure to reservoir water during cold conditions could pose a hypothermia risk. The bathometric survey of the reservoir will involve being on a small boat equiped with sounding devices. Working over water and soft sediment present drowning hazards. Moderate Hazard Non-intrusive Intrusive There will be five shallow sediment cores collected from the Las Tablas Creek Reservoir. Lifting and handling sediment cores onto the platform of the boat could lead to muscular strain or the possiblilty of falling overboard. Working over water and soft sediment present drowning hazards. Moderate Hazard SPECIAL MEDICAL SURVEILLANCE REQUIREMENTS: Please reference the attached Material Safety Data Sheets (MSDS) in Appendix B and Activity Hazards Analysis (AHA) worksheets in Appendix C prior to None performing any of the above tasks. OVERALL HAZARD EVALUATION: ( ) High (X) Medium ( ) Low ( ) Unknown (Where tasks have different hazards, evaluate each.) Medium overall hazard rating due to drowning and slip,trip, fall potential. There is a requirement that workers will not enter the creek if rapidly moving water higher than 18" or their knees is present. Poison oak is abundant at the Site and employees will alert each other JUSTIFICATION: when they see poison oak in the work area. The onsite health and safety officer along with the field team lead will assess the site conditions thoroughly prior to any work performed. FIRE/EXPLOSION POTENTIAL: ( ) High ( ) Medium ( X ) Low ( ) Unknown Page-6&7 KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN FORM This document is for the exclusive use CDM Smith Health and Safety Program TASKS: 1 - 2 - 3 - 4 - 5 - 6 - 7 - 8 - 9 - 10 LEVEL: A - B - C - D - Modified ( ) Primary ( ) Contingency BLOCK C Respiratory: ( X ) Not needed ( ) SCBA, Airline: ( ) APR: ( ) Cartridge: ( ) Escape Mask: ( ) Other: Head and Eye: ( ) Not needed ( X ) Safety Glasses: ( ) Face Shield: ( ) Goggles: ( X ) Hard Hat: ( ) Other: Prot. Clothing: ( ) Not needed ( ) Encapsulated Suit: ( ) Splash Suit ( ) Apron: ( ) Tyvek Coverall or ( ) Saranex Coverall ( ) Cloth Coverall: (X) Other: Snake gaiters at all times when walking site Gloves: ( ) Not needed ( ) Undergloves: ( X ) Gloves: Nitrile ( ) Overgloves: Boots: ( ) Not needed ( X ) Steel-Toe ( ) Steel Shank ( ) Rubber ( ) Leather ( X) Wading boots when in water Other: specify below ( X ) Rain Jacket and Pants/waders ( X ) Flotation Device If Over Water ( X ) Tecnu Poison Oak Wash ( X ) Sun Screen Respiratory: ( ) Not needed ( ) SCBA, Airline: ( ) APR: ( ) Cartridge: ( ) Escape Mask: ( ) Other: Prot. Clothing: ( ) Not needed ( ) Encapsulated Suit: ( ) Splash Suit ( ) Apron: ( ) Tyvek Coverall ( ) Saranex Coverall ( ) Cloth Coverall: ( ) Other: Head and Eye: ( ) Not needed ( ) Safety Glasses: ( ) Face Shield: ( ) Goggles: ( ) Hard Hat: ( ) Other: Boots: ( ) Not needed ( ) Steel-Toe ( ) Steel Shank ( ) Rubber ( ) Leather ( ) Overboots: Gloves: ( ) Not needed ( ) Undergloves: ( ) Gloves: ( ) Overgloves: Other: specify below ( ) Tick Spray ( ) Flotation Device If Over Water ( ) Hearing Protection ( ) Sun Screen BLOCK B TASKS: 1 - 2 - 3 - 4 - 5 - 6 - 7 - 8 - 9 - 10 LEVEL: A - B - C - D - Modified ( ) Primary ( ) Contingency TASKS: 1 - 2 - 3 - 4 - 5 - 6 - 7 - 8 - 9 LEVEL: D - Modified (X) Primary ( ) Contingency BLOCK A Specify by task. Indicate type and/or material, as necessary. Group tasks if possible. Use copies of this sheet if needed. BLOCK D TASKS: 1 - 2 - 3 - 4 - 5 - 6 - 7 - 8 - 9 - 10 LEVEL: A - B - C - D - Modified ( ) Primary ( ) Contingency PROTECTIVE EQUIPMENT: of CDM Smith and its subcontractors Respiratory: ( ) Not needed ( ) SCBA, Airline: ( ) APR: ( ) Cartridge: ( ) Escape Mask: ( ) Other: Prot. Clothing: ( ) Not needed ( ) Encapsulated Suit: ( ) Splash Suit ( ) Apron: ( ) Tyvek Coverall or ( ) Saranex Coverall ( ) Cloth Coverall: Head and Eye: ( ) Not needed ( ) Safety Glasses: ( ) Face Shield: ( ) Goggles: ( ) Hard Hat: ( ) Other: ( ) Other: Gloves: ( ) Not needed ( ) Undergloves: ( ) Gloves: ( ) Overgloves: Boots: ( ) Not needed Other: specify below ( ) Steel-Toe ( ) Steel Shank ( ) Tick Spray ( ) Rubber ( ) Leather ( ) Floatation Device ( ) Overboots: Latex ( ) Hearing Protection ( ) Sun Screen Respiratory: ( ) Not needed ( ) SCBA, Airline: ( ) APR: ( ) Cartridge: ( ) Escape Mask: ( ) Other: Head and Eye: ( ) Not needed ( ) Safety Glasses: ( ) Face Shield: ( ) Goggles: ( ) Hard Hat: ( ) Other: Prot. Clothing: ( ) Not needed ( ) Encapsulated Suit: ( ) Splash Suit ( ) Apron: ( ) Tyvek Coverall ( ) Saranex Coverall ( ) Cloth Coverall: ( ) Other: Gloves: ( ) Not needed ( ) Undergloves: ( ) Gloves: ( ) Overgloves: Boots: ( ) Not needed Other: specify below ( ) Steel-Toe ( ) Steel Shank ( ) Tick Spray ( ) Rubber ( ) Leather ( ) Floatation Device ( ) Overboots: ( ) Hearing Protection ( ) Sun Screen This health and safety plan form constitutes hazard analysis per 29 CFR 1910.132 Page-8 KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN FORM CDM Smith Health and Safety Program This document is for the exclusive use of CDM Smith and its subcontractors MONITORING EQUIPMENT: Specify by task. Indicate type as necessary. Attach additional sheets if needed. INSTRUMENT TASK ACTION GUIDELINES Combustible Gas Indicator 0-10% LEL No explosion hazard 1-2-3-4-5-6-7-8 10-25% LEL Potential explosion hazard; notify SHSC >25% LEL Explosion hazard; interrupt task/evacuate 21.0% O2 Radiation Survey Meter 1-2-3-4-5-6-7-8 Photoionization Detector Specify: _____eV Lamp Type ____ 1-2-3-4-5-6-7-8 COMMENTS ( X ) Not Needed Oxygen normal <21.0% O2 Oxygen deficient; notify SHSC <19.5% O2 Interrupt task/evacuate 3 x Background: Notify HSM >2mR/hr: Establish REZ ( X ) Not Needed ( X ) Not Needed Flame Ionization Specify: Detector 1-2-3-4-5-6-7-8 ( X ) Not Needed Type____________ Single Gas Specify: Type____________ Type____________ 1-2-3-4-5-6-7-8 Respirable Dust Monitor Specify: Type____________ Type____________ 1-2-3-4-5-6-7-8 Other Specify: Type____________ Type____________ 1-2-3-4-5-6-7-8 Other Specify: Type____________ Type____________ 1-2-3-4-5-6-7-8 Page-9 ( X ) Not Needed ( X ) Not Needed ( ) Not Needed ( ) Not Needed KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN FORM CDM Smith Health and Safety Program This document is for the exclusive use of CDM Smith and its subcontractors DECONTAMINATION PROCEDURES ATTACH SITE MAP INDICATING EXCLUSION, DECONTAMINATION, & SUPPORT ZONES AS PAGE TWO Personnel Decontamination Summarize below or attach diagram; Sampling Equipment Decontamination Summarize below or attach diagram; Team members will remove their protective clothing in the following order: *Equipment Drop *Hard Hat Removal *Glove Removal *Hand and Face Wash *Shower as soon as possible Decontamination of sampling equipment will include wash by Alconox, tap wash water wash, tap water rinse, and deionized water rinse. ( ) Not Needed NA ( ) Not Needed Containment and Disposal Method Containment and Disposal Method Wash water will not be contained. Decontamination water will not be contained. HAZARDOUS MATERIALS TO BE BROUGHT ONSITE Preservatives Decontamination ( X ) Alconox TM ( ) Hexane (X) Hydrochloric Acid ( ) Zinc Acetate TM ( ) Liquinox (X) Nitric Acid ( ) Ascorbic Acid ( ) Isopropanol ( ) Sulfuric Acid ( ) Acetic Acid ( ) Acetone ( ) Nitric Acid ( ) Sodium Hydroxide ( ) Other: ( ) Methanol ( ) Other: ( ) Mineral Spirits Page-10 Heavy Equipment Decontamination Summarize below or attach diagram; KBV Final HASP for SEDA.xlsx ( X ) Not Needed Containment and Disposal Method NA ( ( ( ( ( Calibration ) 100 ppm isobutylene ( ) Hydrogen Sulfide ) Methane ( ) Carbon Monoxide ) Pentane ( ) pH Standards ) Hyrogen ( ) Conductivity Std ) Propane ( ) Other: 11/6/2013 Page-11 MAP OF HOSPITAL ROUTE MAP OF HOSPITAL ROUTE Driving Directions to Twin Cities Community Hospital Page-12 1. Drive east on Klau Mine Road for 2.1 miles 4. Turn left onto Winery Road and drive for 0.4 miles 2. Slight right onto Adelaida Road and drive for 1.3 miles 3. Turn right onto Vineyard Drive and drive for 9.6 miles 5. Turn right onto Las Tablas Road and drive for 1.8 miles 6. Destination will be on the left: Total Distance = 15.2 miles KBV Final HASP for SEDA.xlsx 11/6/2013 HEALTH AND SAFETY PLAN SIGNATURE FORM All site personnel must sign this form indicating receipt of the H&SP. Keep this original on site. It becomes part of the permanent project files. Send a copy to the Health and Safety Manager (HSM). SITE NAME/NUMBER: Klau Buena Vista Mine Superfund CED DIVISION/LOCATION: CERTIFICATION: I understand, and agree to comply with, the provisions of the above referenced H&SP for work activities on this project. I agree to report any injuries, illnesses or exposure incidents to the site Health and Safety Coordinator (SHSC). I agree to inform the SHSC about any drugs (legal and illegal) that I take within three days of site work. PRINTED NAME Page-13 SIGNATURE KBV Final HASP for SEDA.xlsx DATE 11/6/2013 Appendix A Work Guidelines 01-03-12 Section 9 Personal Protective Equipment (PPE) CDM Smith employees frequently perform tasks that require the use of protective clothing and equipment to shield or isolate them from chemical and physical hazards. The nature and extent of potential chemical and physical hazards are key factor in choosing PPE. Before mobilization, CDM Smith performs a detailed review of the project site. We review site history, types, and quantities of materials handled at the site, operations performed at the project site, and activities we will perform during the course of the project. 9.1 Use of Personal Protective Equipment Employees must use PPE identified in H&S plans, as directed by site managers, where recognizable hazards exist, to meet client requirements and in accordance with the guidelines described in this section. Employees must also inspect PPE assigned to them and have worn out or defective equipment replaced. Personal protective equipment in use shall be inspected daily and maintained in serviceable condition. Items of personal issue shall be cleaned and sanitized as appropriate before any other employee uses them. Defective or damaged equipment shall be taken out of service immediately. 9.1.1 “Baseline” Protection CDM Smith employees are expected to wear the ensemble of personal protective equipment listed below during all field tasks. • • • • • • • Full-length trousers (See Section 9.2.10) Shirt with sleeves and a collar (See Section 9.2.10) Safety glasses with side shields (See Section 9.2.1) Hardhat (See Section 9.2.2) Steel toe and shank footwear (See Section 9.2.3) Protective gloves (if hands will contact rough or contaminated surfaces) (See Section 9.2.4) High-visibility vest (if vehicles or heavy equipment operate on site) (See Section 9.2.5) 9.1.2 Rules and Standards for PPE Use of personal protective equipment is required by OSHA standards contained in 29 CFR 1910 and 29 CFR 1926, and reinforced by EPA regulations in 40 CFR Part 300. Types of protection required by OSHA and the relevant consensus standards are listed in Table 9-2. 9-1 Section 9 Personal Protective Equipment 01-03-12 9.2 Basic Personal Protective Equipment 9.2.1 Eye Protection Employees should wear safety glasses during field activities unless it can be demonstrated that there are no potential hazards to the eye. Such hazards include active construction sites, hazardous waste sites and potential contact between hazardous or foreign substances and the eye. For most dusts and particulates, safety glasses with side shields meeting the requirements of ANSI standard Z87.1-2003 - Occupational and Educational Eye and Face Protective Devices are adequate. For potential splash hazards of liquids, a face shield or splash hood should be used in conjunction with regular safety glasses. In some exposures to mist or heavy dust, goggles may provide the best form of eye protection. If lasers are used, specialized eye protection using specific lenses for the wavelength and energy emitted by a specific laser may be required. Contact Lenses – Based on current information related to the use of contact lenses in the industrial work environment, contact lenses may be used in most situations. Eye protection such as safety glasses, face shields, or goggles appropriate for the hazards present should be used as well. 9.2.2 Hard Hats Employees should wear hard hats meeting the requirements of ANSI Z89.1 (2009) unless the safety manager grants a waiver per Section 9.1.1.[no need for link here] Hard hats should be worn with the brim facing forwards unless there is a specific safety related reason to turn the hat backwards. In such instances the webbing in the hat shall be repositioned in the hat so that the back of the webbing is at the back of the head. 9.2.3 Foot Protection Personnel should wear protective footwear when working on active construction sites, field hazardous waste sites and while performing work activities where there is a danger of foot injuries due to falling or rolling objects, objects piercing the sole, and where employees' feet are exposed to electrical hazards. Safety footwear shall meet the requirements of ASTM standards F2412-05 (Standard Test Methods for Foot Protection) and F2413-05 (Standard Specification for Performance Requirements for Foot Protection) and cover the ankle. Any footwear worn for fieldwork must have a good sturdy tread appropriate for outdoor use and a defined heel. 9.2.4 Hand Protection Various types of gloves are available for protection against cuts, scrapes, bruises, etc. that may occur during the physical handling of material, equipment tools etc. Gloves should have the qualities required for the work conditions as set by ANSI/ISEA 105 American National Standard for Hand Protection Selection Criteria. [would a link to a glove selection table be appropriate here?]CDM Smith issues cotton, leather, nitrile, neoprene, and Kevlar® gloves depending on the work activity and potential hazards. If needed, leather or mesh work gloves can be worn over chemical protective gloves. 9-2 Section 9 Personal Protective Equipment 01-03-12 9.2.5 High-Visibility Clothing High-visibility vests or jackets are required whenever personnel work in or around vehicular traffic. High-visibility clothing should meet the level of visibility required for the work conditions in ANSI / ISEA 107 (2010). Employees should also wear highvisibility clothing on active construction or industrial sites where there is frequent movement of trucks, excavation, or other heavy equipment. See Section 16.22 Traffic and Work Zone Safety. 9.2.6 Protective Clothing Personnel should wear protective clothing in circumstances where there is the potential for hazardous dusts, toxic or contaminated material, mists, or liquids contact the employee’s skin or personal clothing. Protective clothing may include disposable or reusable coveralls, polymer coated coveralls, or splash suits. When there is a significant potential for direct contact of liquids or mists, polymer-coated coveralls or splash suits are indicated. Selection consideration should be given to such factors as size, durability, chemical compatibility, and heat stress potential. Project managers are particularly reminded to consider the correct size of protective garment for very large and small workers. When ANSI/ISEA standard 103, Classification and Performance Requirements for Chemical Protective Clothing, is published, CDM Smith expects to implement its requirements. Chemical Protective Footwear – Chemical protective footwear should be worn when there is the potential for boots to come into direct contact or be splashed with hazardous materials or waste. When direct contact hazards exist, chemical resistant boots may be worn or boot covers may be worn. Chemical Protective Gloves – For those activities where there is a potential for direct contact with hazardous or toxic materials, or contaminated soil or groundwater, employees should wear chemical protective gloves. The selection of glove should be based on the activity and the material of potential contact. A wide variety of gloves are available and consideration should be given to dexterity, durability, and material compatibility. Gloves should have the qualities required for the work conditions as set by ANSI/ISEA 105 American National Standard for Hand Protection Selection Criteria. Flame and Arc – Flash Protective Clothing – Fire resistant clothing used where fires or electrical arcs are a problem shall have a rating of at least HRC Level 2 as set by NFPA Code 2112 Standard on Flame Resistant Garments for Protection of Industrial Personnel against Flash Fire. NOTE: If an arc flash study described in Section 16-4 requires a higher level of protection, wear that level. 9.2.7 Respirators CDM Smith may issue a respirator to individuals who will frequently use respiratory protection. Employees who are expected to work on projects where the use of respiratory protection is anticipated or required must fulfill the training and medical approval requirements for respirators as described in Section 11, Respiratory Protection of this manual. 9-3 Section 9 Personal Protective Equipment 01-03-12 9.2.8 Hearing Protection Employees shall use hearing protection when noise levels exceed the allowable limit. A Hearing Conservation Program (Section 14) shall be implemented if the allowable limits are exceeded. Devices used for hearing protection shall be certified for the purpose per USEPA regulation 40 CFR 211 subpart B Noise Labeling Standards for Hearing Protection Devices. 9.2.9 Specialized Protective Equipment Specialized protective equipment is available for a wide variety of activities and includes: • • • • • • • Fall protection harnesses and lanyards (See Safety Guideline 16.7) Face shields Chaps for work in rough brush Spark resistant tools Shin guards for chain saws Cooling vests (See Safety Guideline 16.13) Personal floatation devices 9.2.10 Personal Work Clothing Employees are expected to supply personal clothing appropriate for their work assignments including long pants, a shirt with sleeves (at least 4” long). NOTE: Some CDM Smith clients insist that employees wear long-sleeve shirts.) Employees are expected to provide basic outerwear appropriate for protection against normal weather conditions in the geographical areas they are normally assigned. The equipment centers do stock clothing for extreme cold or wet weather. (See Safety Guideline 16.14.) These include rain suits, insulated coveralls, cold weather work gloves, hardhat liners, etc. Employees may request this equipment directly from the equipment centers. 9.3 Availability of PPE CDM Smith field equipment centers maintain an inventory of basic PPE including hard hats, safety glasses, hearing protection, harnesses, traffic vests, etc. The specific make and model of equipment is reviewed periodically by the H&S managers to ensure equipment issued to CDM Smith Inc. personnel is of adequate quality. Projects and employees may obtain basic PPE by requesting equipment from the field equipment centers by telephone or through the field equipment center website at http://cdmweb/fieldequipment/ . 9.3.1 PPE Assigned to the Employee CDM Smith typically assigns items such as hardhat, safety glasses, hi-visibility vests etc to individual employees. The employee's Group Leader or Direct Manager, in consultation with the H&S Manager assigned to support the employee's division, shall decide what PPE employees need, based on their expected role, and help to arrange for 9-4 Section 9 Personal Protective Equipment 01-03-12 it. Employees may, with the approval of their manager or group leader, submit a PPE request. PPE required for use on CDM Smith work activities is provided to CDM Smith employees at no expense to the employee. 9.3.2 Project vs. Overhead Expense PPE that is used to support activities for specific projects should be charged to those projects. Typical project specific PPE would include consumables such as gloves, disposable Tyvek® suits, respirator cartridges, etc. Non - disposable PPE, used on a specific project can be obtained from the equipment centers for short or moderate durations on a rental basis. In some cases it may be more cost effective for projects to have the equipment centers purchase the equipment for the project. Non-disposable PPE may include respirators, air-supplied respiratory protective systems, or specialized chemical protective clothing. The specific PPE ensemble for a specific project will be identified in the project specific H&S plan and approved by the service group H&S manager responsible for that project. Employees may request equipment using the Personal Protective Equipment Request form in Appendix A of this section. Individual PPE that is assigned to a specific employee for use on multiple projects should be charged to the employee's division safety equipment overhead number, typically 0000 <DIV> ADMIN.SAFQP. The employee's Group Leader or Direct Manager, with the advice of the relevant health and safety manager, shall decide what PPE may be charged to an overhead account. Reimbursement for Safety Footwear – CDM Smith will reimburse CDM Smith employees for the cost of purchasing safety footwear up to a maximum amount of $150.00. Reimbursement for Prescription Safety Glasses – CDM Smith employees, who require prescription glasses and are expected to work more than 30 days per year in the field or on locations where safety glasses are required, will be reimbursed for the cost of prescription safety glasses meeting the requirements of ANSI Z87.1 up to a maximum of $175.00. Employees who wear prescription glasses and work less often on projects that require the use of safety glasses should be provided eye protection that fits over their glasses. Employees may request reimbursement through the expense account system from their resource manager or group leader. The resource manager or group leader shall make the final determination as to whether or not safety glasses are a reimbursable item as described above. Employees are eligible for this allowance whenever their existing equipment becomes unsafe to use. If, for example, pair of safety glasses breaks the day after CDM Smith pays for them, the employee is eligible to use the allowance again. If the steel-toe shoes are still fully functional 15 years after purchase, the employee is not. 9-5 Section 9 Personal Protective Equipment 01-03-12 9.4 Levels of Protection Each type of protective equipment has been designed specifically to protect against a reasonably anticipated chemical and physical hazard. To standardize PPE ensembles, “levels of protection” have been defined to address those chemical and physical hazards that may be present at hazardous waste sites. The levels of protection are defined accordingly: Level A This level is worn when the highest level of respiratory, skin, and eye protection is anticipated as being required. Level B This level is worn when the highest level of respiratory protection is anticipated as being required, with a lesser level of skin protection being necessary. Level C This level is worn when criteria for air-purifying respirators are determined to be necessary and a lesser level of skin protection needed. Level D, Modified This level is worn when activities do not pose a problem from a respiratory protection point of view but may present a skin problem and where cross contamination via shoes needs to be considered. Level D This level is worn when activities and areas do not present a respiratory or skin hazard. Detailed equipment, use, and limitations associated with each level of protection appear in Table 9-1. 9-6 Table 9-1 Levels of Protection Level A Equipment Recommended: Pressure-demand, full facepiece self-contained breathing apparatus (SCBA) or pressuredemand supplied-air respirator with escape SCBA Full-encapsulating, chemical-resistant suit Inner chemical-resistant gloves Chemical-resistant safety boots/shoes Two-way radio communications Optional: Cooling unit Coveralls Long cotton underwear Hard hat Disposable gloves and boot covers Protection Provided Should be Used When: The highest available level of respiratory, skin, and eye protection The chemical substance is thought to require the highest level of protection for skin, eyes, and the respiratory system based on either: - Measured (or potential for) high concentration of atmospheric vapors, gases, or particulates - Site operations and work functions involving a high potential for splash, immersion, or exposure to unexpected vapors, gases, or particulates of materials that are harmful to skin or capable of being absorbed through intact skin Limiting Criteria Fully encapsulating suit material must be impermeable to the substances involved The use of Level A protection severely limits the practical duration of work effort. Substances with a high degree of hazard to the skin are known or suspected to be present, and skin contact is possible Operations must be conducted in poorly ventilated areas until the absence of conditions requiring Level A protection is determined 9-7 Section 9 Personal Protective Equipment 01-03-12 Level B Equipment Recommended: Pressure-demand, full-facepiece SCBA or pressure-demand supplied air respirator with escape SCBA Chemical-resistant clothing (overalls and longsleeved jacket; hooded, one-piece chemical splash suit; disposable chemical resistant onepiece suit) Inner and outer chemical-resistant gloves Chemical-resistant safety boots/shoes Hard hat Two-way radio communications Optional: Coveralls Disposable boot covers Face shield Long cotton underwear Table 9-1 (Continued) Protection Provided The same level of respiratory protection but less skin protection than Level A It is the minimum level recommended for initial site entries until the hazards have been further identified Should be Used When: Limiting Criteria The type and atmospheric concentrations of substances have been identified and require a high level of respiratory protection, but less skin protection. This involves atmospheres: - With IDLH concentrations of specific substances that do not represent a severe skin hazard or - That do not meet the criteria for use of airpurifying respirators Used only when the vapor of gases present are not suspected of containing high concentrations of chemicals that are harmful to skin or capable of being absorbed through the intact skin Use only when it is highly unlikely that the work being done will generate either high concentrations of vapors, gases, or particulates or splashes of material that will affect exposed skin Atmosphere contains less than 19.5 percent oxygen Presence of incompletely identified vapors or gases is indicated by direct-reading organic vapor detection instrument, but vapors and gases are not suspected of containing high levels of chemicals harmful to skin or capable of being absorbed through the skin 9-8 Section 9 Personal Protective Equipment 01-03-12 Level C Equipment Recommended: Full-facepiece, air-purifying, cartridge-equipped respirator Chemical-resistant clothing (overalls and longsleeved jacket; hooded, one-piece chemical splash suit; disposable chemical-resistant onepiece suit Inner and outer chemical-resistant gloves Chemical-resistant safety boots/shoes Hard hat Two-way radio communications Table 9-1 (Continued) Protection Provided The same level of skin protection as Level B, but a lower level of respiratory protection MODIFIE D Recommended: Chemical-resistant outer gloves Disposable shoe covers Work clothes Safety boots/shoes Safety glasses or chemical splash goggles Hard hat The atmospheric contaminants, liquid splashes, or other direct contact will not adversely affect any exposed skin The types of air contaminants have been identified, concentrations measured, and a cartridge is available that can remove the contaminant All criteria for the use of airpurifying respirators are met Optional: Coveralls Disposal boot covers Face shield Escape mask Long cotton underwear D Should be Used When: No respiratory protection; minimum skin protection Limiting Criteria Effective only against conditions that are fairly well understood. Not effective for conditions that involve: • Unknown chemicals that the filtering element might not remove well • Oxygen-deficient atmospheres • Unpredictable concentrations that might overwhelm the filtering element The atmosphere contains no known hazard Work functions may involve skin contact with hazardous chemicals 9-9 Table 9-2 OSHA & Consensus Standards for Personal Protective Equipment Type of Protection Regulation Reference General 29 CFR 1910.132 41 CFR Part 50-204.7 General Requirements for Personal Protective Equipment Eye and Face 29 CFR 1910.133(a) ANSI standard Z87.1-2003 Occupational and Educational Eye and Face Protective Devices Noise Exposure 29 CFR 1910.95 USEPA 40 CFR 211 subpart B Respiratory 29 CFR 1910.134 ANSI-1 Z88.2 (1992) Standard Practice for Respiratory Protection Hand 29 CFR 1910.132 ANSI/ISEA 105 American National Standard for Hand Protection Head 29 CFR 1910.135 ANSI Z89.1 (2009) Safety Requirements for Industrial Head Protection Foot 29 CFR 1910.136 ASTM F2412-05and F2413-05 Electrical Protective Devices 29 CFR1910.335(a)(2) NFPA 70E: Standard for Electrical Safety in the Workplace Flame – Resistant Garments 29 CFR1910.335(a)(2) NFPA Code 2112 Standard on Flame Resistant Garments Chemical Protective Clothing 29 CFR 1910.132 ANSI/ISEA standard 103, Chemical Protective Clothing (Draft) High-Visibility Safety Apparel 29 CFR 1926.651(d) ANSI / ISEA 107(2010) National Standard for High-Visibility Safety Apparel 1 American National Standards Institute (ANSI), http://www.ansi.org/ 9-10 Appendix A Personal Protective Equipment Request Form Employee ________________________ Division ________ Active in CDM Smith Medical Surveillance Program? Date of last CDM Smith medical exam? Office________ Yes ___ No ___ ______________________ Equipment Requested Item Requested Issued Hard Hat ______ ______ Safety Glasses ______ ______ Hi-Visibility Vest ______ ______ Fall Protection Harness ______ ______ Work Gloves (____ pairs) ______ ______ Glove Liners (____ pairs) ______ ______ Electrical Gloves (____ pairs) ______ ______ Rain suit ______ ______ Cloth Coveralls ______ ______ Fire – Resistant Coveralls ______ ______ Insulated Coveralls ______ ______ Goggles ______ ______ Ear Muffs (____ pairs) ______ ______ Respirator ______ ______ ______ ______ ______________________________ ______ ______ ______________________________ ______ ______ Make______________ Model_____________ Size_______________ Corrective Lens Inserts You must take reasonable measures to safeguard the items issued to you. Should your employment with CDM Smith terminate for any reason you must return equipment issued for your use. Any loss, theft, or damage of the equipment should be reported promptly to the Equipment Center manager. Approved by: _____________________________________ ________ ____________________ Group Leader or Direct Manager/Date Division Charge Number 9-11 Section 16 Work Practices and Guidelines 01-03-12 16.3 Manual Material Handling CDM Smith employees should follow the work practices outlined below when lifting and carrying heavy objects. Test any load they are required to lift and compare its weight, volume, and shape to their lifting abilities. Employees shall not attempt to lift beyond their capacity. Obtain assistance in lifting heavy objects. Back belts or back braces may be used if desired; however, many ergonomists do not believe that these devices create a benefit or provide protection. When two or more persons are involved in a manual lift, one person should provide direction of the lift. When two or more persons are carrying an object, each employee, if possible, should face the direction in which the object is being carried. When two or more persons carry a heavy object that is to be lowered or dropped, there shall be a prearranged signal for releasing the load. The right way to lift is easiest and safest. Crouch or squat with the feet close to the object to be lifted, secure good footing, take a firm grip, bend the knees, keep the back vertical, and lift by bending at the knees and using the leg and thigh muscles. Exercise caution when lifting or pulling in an awkward position. Employees should avoid twisting or excessive bending when lifting or setting down loads. When moving a load horizontally, employees should push the load rather than pull. For tasks that require repetitive lifting, the load should be positioned to limit bending and twisting. The use of lift tables, pallets, and mechanical devices should be considered. When gripping, grasping, or lifting an object such as a pipe or board, the whole hand and all the fingers should be used. Gripping, grasping, and lifting with just the thumb and index finger should be avoided. 16.3-3 Section 16 Work Practices and Guidelines 01-03-12 16.7 Fall Protection CDM Smith employees who visit active construction sites may be exposed to falls. A fall exposure is considered to exist when an employee is within 6 lateral feet of a change in elevation of 6 vertical feet or more. Typical exposures can include: Excavations Roofs Leading edge of a surface (floor) Floor openings All employees should use fall protection 100 percent of the time when exposed to a fall in excess of 6 feet or when required by rules such as those of a client or the owner or operator of a facility. Fall protection may consist of any of the following: Guardrails Safety nets Positioning systems Warning systems Personal fall arrest systems Employees should not use fall arrest equipment until they have been properly trained. Fall protection training can be arranged by contacting your division HSM. Project managers and site managers shall ensure fall protection is available and used as required for all employees for whom they are responsible and that employees receive adequate training in the use of the equipment. The following work practices and guidelines should be considered for protection against falls: Before working or walking on a surface, consider the strength and structural integrity of the surface. Can it support employees and any needed equipment or material safely? Employees shall work on those surfaces only when the surfaces have the requisite strength and structural integrity. When not protected by any other means of fall protection, such as safety nets or scaffold with proper guardrails, employees shall use full body harnesses, lanyards with double-locking snap hooks, and an adequate anchorage (fall arrest equipment). To achieve 100 percent fall protection, employees may need to use a two-lanyard system and/or vertical or horizontal lifelines, retractable lifelines, or other approved positioning devices. Employees shall rig fall arrest equipment so that it minimizes the potential for a fall arrest event or any potential free-fall, lateral swing, or contact with any lower object. Under no circumstances shall fall arrest equipment be rigged so that an employee can free-fall more than 6 feet. 16.7-25 Section 16 Work Practices and Guidelines 01-03-12 Anchorage points for fall arrest equipment shall be capable of supporting 5,000 pounds per employee attached. Anchorage points for fall arrest equipment shall be located above the employee’s body harness attachment point where practical. When vertical lifelines are used, a separate lifeline shall protect each employee. The lifeline shall be properly weighted at the bottom and terminated to preclude a device such as a rope grab from falling off the line. Horizontal lifelines should be limited to two persons at one time between supports and maintain a safety factor (strength/requirement) of at least 2. Before each use, employees shall visually inspect all fall arrest equipment for cuts, cracks, tears or abrasions, undue stretching, overall deterioration, mildew, operational defects, heat damage, or acid or other corrosion. Equipment showing any defect shall be withdrawn from service. All fall arrest equipment subjected to impacts caused by a free-fall or by testing shall be removed from service. CDM Smith personnel shall use full body harnesses for personal fall protection. Fall protection equipment is available from the field equipment centers. Fall arrest equipment should be stored in a cool dry place not subjected to direct sunlight. Fall arrest equipment shall not be used for any other purpose, such as towropes or hoist lines. Proper guardrails shall be installed on open sides of all walkways and runways where the fall distance exceeds 4 feet. Proper guardrails shall be installed on open sided floors where the fall distance exceeds 6 feet. All floor openings or floor holes shall be protected by guardrails or hole covers. If hole covers are used, they shall be strong enough to support the maximum intended load, secured against displacement, and properly labeled. When guardrails are used for fall protection, they shall consist of a top rail, intermediate rail, and toeboard. The top rail shall have a vertical height of 42 inches, the midrail shall be at 21 inches, and the toeboard 4 inches. When wood railings are used, the post shall be of at least 2-inch by 4-inch stock spaced not to exceed 8 feet, the top rail shall be of at least 2-inch by 4-inch stock, and the intermediate rail shall be of at least 1-inch by 6-inch stock. If pipe is used, it shall be at least 1½-inch nominal diameter. If structural steel is used, it shall be of 2-inch by 2-inch by 3/8-inch angles or equivalent. If wire rope is used for railings, it shall have a diameter of at least 2 inches and shall be stretched taut to allow no more than a 3-inch deflection. When operating a scissor-lift work platform, the lift shall have guardrails on all open sides, with the door access chains or rails in place. Employees operating aerial lifts shall wear a body harness and lanyard attached to the aerial lift. Employees shall not attach the lanyard to an independent structure. 16.7-26 Section 16 Work Practices and Guidelines 01-03-12 Employees riding in a crane-suspended work platform shall wear a body harness and lanyard attached to the grab rail of the platform. Employees working on or near wall forms or rebar shall wear a body harness lanyard and/or positioning device when exposed to a fall in excess of 6 feet. Positioning devices shall be rigged to prevent a free-fall greater than 24 inches. Stairs, ladders, or ramps shall be provided for all access ways where there is a change in elevation greater than 19 inches. Manila or synthetic rope shall not be used as guardrails. Employees shall not stand or sit on guardrails. Personal fall arrest systems shall not be attached to guardrail systems. If warning lines are used, they should consist of rope, wire, or chain and be flagged at intervals of 6 feet or less with high-visibility material. The lowest point should be no less and 34 inches from the surface, and the highest point should be no more than 39 inches. The warning line should be placed at least 6 feet from the edge. Safety net systems should be installed as close to the working surface as practical, but in no case more than 25 feet below the working surface and should extend outward at least 8 to 13 feet depending on the vertical fall distance. Safety nets should be drop-tested after initial installation and at 6-month intervals. The maximum size of net mesh should not exceed 36 square inches nor be longer than 6 inches on any side. Mesh opening should be secure to prevent enlargement. Body belts should not be used for personal fall arrest. Full body harnesses are required. 16.7-27 Section 16 Work Practices and Guidelines 01-03-12 16.12 Tools and Power Equipment 16.12.1 Hand Tools CDM Smith employees who have a need to use basic hand tools should use the following work practices: All tools used on CDM Smith projects, regardless of ownership, shall be of an approved type and maintained in good condition. Tools are subject to inspection at any time. The project manager has the authority and responsibility to condemn unserviceable tools, regardless of ownership. Tag defective tools to prevent their use or removal from the job site. Use the proper tool for the job performed. Do not use hammers with metal handles, screwdrivers, knives with metal continuing through the handle, and metallic measuring tapes on or near energized electrical circuits or equipment. Do not throw tools from place to place or from person to person. Tools that must be raised or lowered from one elevation to another shall be placed in tool buckets or firmly attached to hand lines. Do not place tools unsecured on elevated places. Dress, repair, or replace all impact tools such as chisels, punches, drift pins, etc., that become mushroomed or cracked before further use. Use suitable holders or tongs, not the hands, to hold chisels, drills, punches, ground rods, or pipes that are struck by another employee. Do not use shims to make a wrench fit. Do not use wrenches with sprung or damaged jaws. Do not use pipe or other means to extend a wrench handle for added leverage unless the wrench was designed for such use. Use tools only for the purposes for which they have been designed. Store and handle tools with sharp edges so that they will not cause injury or damage. They shall not be carried in pockets. Use eye protection when using or working around impact type tools (e.g., hammer, chisel, ax, hatchet, etc.). Replace wooden handles that are loose, cracked, or splintered. The handle shall not be taped, glued, or lashed with wire. 16.12-40 Section 16 Work Practices and Guidelines 01-03-12 Keep all cutting tools such as saws, wood chisels, knives, or axes in suitable guards or in special compartments. When using such tools as screwdrivers and wrenches, avoid using your wrists in a bent, flexed, extended, or twisted position for long periods of time. Employees should maintain their wrists in a neutral or straight position. Do not leave tools lying around where they may cause a person to trip or stumble. When working on or above open grating, use a canvas or other suitable covering to cover the grating to prevent tools or parts from dropping to a lower level where others are present, or barricade or guard the danger area. Do not depend on the insulation on hand tools to protect users from shock. 16.12.2 Electric Tools CDM Smith employees who have a need to use electric power tools should use the following work practices: The non-current carrying metal parts of portable electric tools such as drills, saws, and grinders shall be effectively grounded when connected to a power source unless the tool is an approved double-insulated type or the tool is connected to the power supply by means of an isolating transformer or other isolated power supply, such as a 24-volt DC system. All power tools shall be examined before use to ensure general serviceability and the presence of all applicable safety devices. The electric cord and components shall be given a thorough examination for cracks, exposed wires, or other defects. Power tools shall be used only within their capability and shall be operated in accordance with the manufacturers’ instructions. The use of eye protection is required when using or working around power tools. Operators should take care to use appropriate hand positions on cutting tools such as saws, drills, or grinders to avoid hand injury. All tools shall be kept in good repair and disconnected from the power source while repairs are being made. Electrical tools shall not be used where there is a hazard of flammable vapors, gases, or dusts until that hazard is firmly under control. GFCI should be used with all electric power tools. All guards and safety interlocks with which the tools were purchased shall be in place and in working order. 16.12-41 Section 16 Work Practices and Guidelines 01-03-12 Any tool that is identified as defective should be tagged “not for use,” and set aside for repair and/or discarded. Do not wear loose or frayed clothing while operating power tools and equipment. Hair should not stick out from hard hats. Do not use electrical cords to transport, suspend, hoist, or lower tools. Do not allow power cords to lie in water. Disconnect rotating tools from the power source before adjusting, servicing, or cleaning them. Follow the lockout procedure described in Section 16.5. Do not modify tools. 16.12.3 Pneumatic Tools CDM Smith employees that use pneumatic power tools should use the following work practices: Compressed air and compressed air tools shall be used with caution. Pneumatic tools shall never be pointed at another person. Pneumatic hose connections should be secured by some positive means to prevent them from becoming accidentally disconnected. Chicago fittings have wire holes to allow such security. Pneumatic power tools shall be secured to the hose by some positive means to prevent the tool from becoming accidentally disconnected. Safety clips or retainers shall be securely installed and maintained on pneumatic impact tools to prevent attachments from being accidentally expelled. Compressed air shall not be used for cleaning purposes except when reduced to less than 30 psi and then only with effective chip guarding and PPE. Compressed air shall not be used to blow dust or dirt from clothing (or skin). The manufacturer’s safe operating pressure for hoses, pipes, valves, filters, and other fittings shall not be exceeded. The use of hoses for hoisting or lowering tools shall not be permitted. All compressed air hoses exceeding 30 psi shall have a safety device at the source of supply or branch line to reduce pressure in case of hose failure or disengagement of a connection. 16.12-42 Section 16 Work Practices and Guidelines 01-03-12 Before making adjustments or changing air tools, the air shall be shut off at the air supply valve ahead of the hose. The hose shall be bled at the tool before breaking the connection. Disconnection at the quick-change connectors is one way to meet this goal. Eye protection is required when using or working around pneumatic tools. Use hearing protection if noise exposure is a concern (i.e., if it is too loud to conduct a normal conversation). Pneumatic tools shall be operated only by persons trained in their use. A pneumatic tool used where it may contact exposed live electrical parts shall have a nonconductive hose and an accumulator to collect moisture. Employees shall not use any part of their bodies to locate or attempt to stop an air leak. All guards and safety interlocks must be in place and functional. 16.12.4 Engine-Powered Tools CDM Smith employees that use engine-powered tools should use the following work practices: Stop the engine and allow it to cool before refueling, servicing, or maintenance. Use care in refueling. Clean up any small spills of fuel or oil immediately. The use of eye protection is required when using or working around enginepowered tools. Use hearing protection if noise exposure is a concern (i.e., if it is too loud to conduct a normal conversation). If possible, disconnect the spark plug before performing an adjustment, maintenance, or service. Use tools in well ventilated areas to eliminate any accumulation of fumes. Do not use tools in a flammable or explosive atmosphere. Equip engines with spark-arresting mufflers. Avoid contact with hot engine components. All guards and safety interlocks should be in place and functional. 16.12-43 Section 16 Work Practices and Guidelines 01-03-12 16.13 Heat Stress CDM Smith employees may be exposed to hazards associated with hot work environments. Factors that contribute to heat exposure include temperature, humidity, PPE radiant heat, sunlight, access to drinking water, exposure duration, and work activity. Individuals vary widely in their susceptibility to heat stress. Factors that may influence individual susceptibility to heat stress include the following: Lack of physical fitness Lack of acclimatization Age Dehydration Obesity Alcohol and drug use Infection Sunburn Diarrhea Chronic disease The following guidelines should be considered when CDM Smith employees or subcontractors perform work: In ambient air temperatures above 80°F That involves heavy physical labor in temperatures above 70°F In chemical-protective clothing above 70°F 16.13.1 Hazards Associated with Heat Stress Heat Stroke – Heat stroke is a serious medical emergency and can lead to death if left untreated. It is an acute and dangerous reaction caused by the failure of heat regulating mechanisms of the body. Persons who are elderly, obese, chronically ill, alcoholic, diabetic, or have circulatory system problems are at greater risk. Symptoms include red, hot, dry skin; nausea; headache; weakness; dizziness; elevated body temperature (BT); rapid respiration and pulse; coma; or loss of consciousness. Treatment for heat stroke: B Heat stroke is a serious medical emergency. Emergency medical services (911) should be contacted if heat stroke is suspected. B Move the victim to a cool place (shade, air conditioned building, vehicle). B Remove heavy clothing. B Cool the victim with ice packs, wet towels, or cloth. B Keep head and shoulders elevated. B Keep victim’s airway open, check breathing and pulse. Heat Exhaustion – A state of exhaustion or weakness caused by loss of fluids through perspiration and inadequate fluid replacement. Severe cases may result in loss of consciousness (fainting). This condition can progress to heat stroke if left untreated. Symptoms include: o Pale, clammy, moist skin; heavy sweating; and extreme weakness. o BT is normal, pulse is weak and rapid, breathing is shallow. 16.13-44 Section 16 Work Practices and Guidelines 01-03-12 o The person may have a headache, nausea, or feel dizzy. Treatment for heat exhaustion: o o o o o o Remove the victim to a cool location (shade, air conditioned building, or vehicle). Allow the victim to lie down and prop their legs up. Cool the victim with wet towels, cloth, or cold packs. If the victim in not nauseous, they should drink water slowly. If the victim loses consciousness, transport to local medical facility. Continue treatment until symptoms are gone. Consult with CDM Smith medical consultant before returning to work. Heat Cramps – Heat cramps are a condition that can progress to heat exhaustion or heat stroke. Symptoms include severe cramping of the arms, legs, and abdomen. Treatment includes: Removing the victim to a cool location; loosen clothing Having the victim slowly drink cool water Resting the cramping muscles Heat Rash – Heat rash is a mild red skin rash in areas where the body is in contact with clothing or protective gear. The area is likely to itch and can be a source of irritation. Treatment includes decreasing the amount of time in protective gear and applying talcum powder to absorb moisture. When possible, wear breathable clothing to prevent a buildup of moisture within the clothing. 16.13.2 Heat Stress Monitoring Since the susceptibility to heat stress hazards can vary greatly from one individual to another, often the best way to monitor for heat stress is through observing employees and individual physiological monitoring. When working in conditions that have the potential to create heat stress, either heart rate (HR) or BT should be monitored in accordance with the suggested frequency given in Table 16-1 below: Table 16-1 Suggested Frequency of Physiological Monitoring for Fit and Acclimatized Workersa a Adjusted Temperatureb Normal Work Ensemblec Impermeable Ensemble 90°F (32.2°C) or above 87.5° to 90°F (30.8° to 32.2°C) 82.5° to 87.5°F (28.1° to 30.8°C) 77.5° to 82.5°F (25.3° to 28.1°C) 72.5° to 77.5°F (22.5° to 25.3°C) After each 45 minutes of work After each 60 minutes of work After each 90 minutes of work After each 120 minutes of work After each 150 minutes of work After each 15 minutes of work After each 30 minutes of work After each 60 minutes of work After each 90 minutes of work After each 120 minutes of work For work levels of 250 kilocalories/hour. Calculate the adjusted air temperature (Ta adj) by using this equation: Ta adj °F = Ta °F + (13 X % sunshine). Measure air temperature (Ta) with a standard mercury-in-glass thermometer, with the bulb shielded from radiant heat. Estimate percent sunshine by judging what percent time the sun is not covered by clouds that are thick enough to produce a shadow (100 percent sunshine - no cloud cover and a sharp, distinct shadow; 0 percent sunshine - no shadows). b 16.13-45 Section 16 Work Practices and Guidelines 01-03-12 c A normal work ensemble consists of cotton coveralls or other cotton clothing with long sleeves and pants. Heart Rate – HR should be measured by the radial pulse for 30 seconds as early as possible in the initial rest period. On an individual basis, if the HR exceeds 110 beats per minute (BPM), that individual should not return to work until their HR drops below 110 BPM and they are fully recovered. If more than one worker has an HR that exceeds 110 BPM, a work rest regimen or other control measures should be implemented to maintain HRs below 110 BPM. Body Temperature – The BT may be measured using a clinical oral thermometer or a clinical ear thermometer. On an individual basis, if the BT exceeds 99.6°F, that individual should not return to work until their BT drops below 99.6°F and they are fully recovered. If more than one worker has a BT in excess of 99.6°F, a work rest regimen or other control measures should be implemented to maintain BTs below 99.6°F. Personnel should monitor themselves and each other for the development of symptoms such as sudden fatigue, nausea, dizziness, irritability, malaise, flu-like symptoms, and lightheadedness. 16.13.3 Heat Stress Controls and Prevention Develop work/rest regimen to maintain physiological parameters within limits described above and prevent development of initial symptoms of heat stress related conditions. If the physiological limits are exceeded or symptoms develop, the work period should be reduced and rest period increased. Rest areas should be cool (in areas such as shade, air conditioned buildings, or vehicles) and away from heat exposure. In extreme heat conditions, employees may wear heat-control clothing such as ice vests or cool suits. Physiological monitoring should still be conducted and work/rest regimens implemented to keep physiological parameters within recommended limits. Mobile showers or hoses can be used to cool down workers in waterproof protective clothing. Shield sources of radiant heat. Provide shaded work areas. Conduct activities in early morning and late evening to avoid the hottest parts of the day. Allow employees to become acclimatized to the heat by performing less strenuous activities for the first few days. Schedule more physically demanding work later. Provide adequate, cool drinking water for consumption during break periods. Avoid consumption of beverages such as coffee, tea, or colas that act as diuretics and dehydrate the body. 16.13-46 Section 16 Work Practices and Guidelines 01-03-12 16.14 Cold Stress Persons working outdoors in low temperatures, especially below freezing, or in wet or snowy weather are potentially subject to cold stress disorders. Factors that contribute to cold stress exposure include temperature, humidity, wind, sunlight, rain, snow, fog, exposure duration, clothing, and work activity. Individual susceptibility to cold stress disorders can vary widely. Individual physical factors that can affect a person’s response to cold work environments include a person’s general fitness and age. The following guidelines should be considered when working in ambient air temperatures below 40°F, especially when other contributing weather conditions such as snow, rain, or wind are present. 16.14.1 Hazards Associated with Cold Stress Hypothermia – Hypothermia results from a cooling of the body’s core temperature and if left unattended can become a serious condition. Hypothermia can result in the loss of physical skills and impair judgment thereby contributing to the potential for other accidents. Severe hypothermia can result in death. Hypothermia can occur at temperatures above freezing as well as below. Symptoms include shivering, teeth chattering, fumbling hands, slurred speech, and loss of coordination. Eventually, the pulse and respiratory rate may slow. The victim may appear blue or lose color in the face. Treatment for hypothermia is to catch symptoms early and move the individual to a warm environment indoors or in a vehicle. If a warm location is not immediately available, the victim should be sheltered from the wind and provided extra clothing such as coats or blankets and observed to determine if their condition is improving. If the victim continues to deteriorate and becomes colder, they should be transported to a medical facility for assistance. Frostbite – Frostbite is a condition in which the fluids around cells of body tissue freeze. The condition can lead to body tissue damage. The most vulnerable parts of the body are the nose, ears, cheeks, fingers, and toes. Symptoms of frostbite include body parts becoming white, firm, cold to the touch, and may feel waxy. The victim will not feel pain in the affected area. Treatment of frostbite requires that the victim be brought to a warm environment and the affected areas be allowed to thaw and warm. If frostbite has progressed beyond small patches of skin and affects whole body parts such as a hand, foot, or ear, the victim should be transported to a medical facility for treatment and observation. 16.14.2 Cold Stress Monitoring Personnel should monitor themselves and each other for signs and symptoms of frostbite and/or hypothermia. If symptoms are observed in an employee or 16.14-47 Section 16 Work Practices and Guidelines 01-03-12 subcontractor, steps should be taken to treat the symptoms by having the individual go to a warm environment either in a nearby structure or vehicle. 16.14.3 Cold Stress Control and Prevention Cold stress can easily be prevented with proper planning and prevention. Some basic controls and preventative measures are listed below: Forecasted conditions. Consider the effect of wind chill (Table 16-2 on next page). Dress in layers and stay dry. Avoid cotton clothing such as socks or T-shirts. Bring extra clothing. Wear hardhat liners and gloves. Wear rain gear in rain and snow. Curtail work if extreme weather conditions such as a blizzard, extreme wind chill (e.g., less than 0°F), torrential cold rains, or wind is expected. For long-term projects in cold environments, consider setting temporary structures with portable heaters. Take warming breaks as needed. Avoid beverages with caffeine, alcohol, or medications that restrict blood flow. Drink warm noncaffeine beverages such as hot chocolate or soups on breaks. 16.14-48 Section 16 Work Practices and Guidelines 01-03-12 Table 16-2 Windchill Index WINDCHILL INDEX Cooling Power of Wind on Exposed Flesh Expressed as an Equivalent Temperature (under calm conditions) Estimated Wind Speed (in mph) Actual Temperature Reading (°F) 50 40 30 20 10 0 -10 -20 -30 -40 -50 -60 Equivalent Chill Temperature (°F) Calm 50 40 30 20 10 0 -10 -20 -30 -40 -50 -60 5 48 37 27 16 6 -5 -15 -26 -36 -47 -57 -68 10 40 28 16 4 -9 -24 -33 -46 -58 -70 -83 -95 15 36 22 9 -5 -18 -32 -45 -58 -72 -85 -99 -112 20 32 18 4 -10 -25 -39 -53 -67 -82 -96 -110 -121 25 30 16 0 -15 -29 -44 -59 -74 -88 -104 -118 -133 30 28 13 -2 -18 -33 -48 -63 -79 -94 -109 -125 -140 35 27 11 -4 -20 -35 -51 -67 -82 -98 -113 -129 -145 40 26 10 -6 -21 -37 -53 -69 -85 -100 -116 -132 -148 Wind speeds greater than 40 mph have little additional effect LITTLE DANGER in < hour with dry skin. Maximum danger of false sense of security. INCREASING DANGER Danger from freezing of exposed flesh within 1 minute. GREAT DANGER Flesh may freeze within 30 seconds. From Fundamentals of Industrial Hygiene, Third Edition. Plog, B.A., Benjamin, G. S., Kerwin, M.A., National Safety Council, 1988. 16.14-49 Section 16 Work Practices and Guidelines 01-03-12 16.16 Working Near or Over Water When working on, over, or near water, basic water safety precautions must be taken. Such areas include riverbanks, channels, dock areas, working from vessels of any kind, aeration basins, or other areas where a danger of drowning may exist. Depending on the circumstances, precautions needed may include any or all of the following: Employees should wear Coast Guard-approved personal floatation devices (PFDs) (either vests or jackets) where a potential danger of drowning exists. PFDs are required when working from any type of boat or floating platform. The PFDs should be inspected before and at the end of each use for wear, torn stitching or straps, inoperable buckles, or other defects. Ring buoys with at least 90 feet of line shall be provided and readily available for emergency rescue operations. Distance between ring buoys shall not exceed 200 feet. At least one lifesaving skiff shall be immediately available at locations where employees are working over or adjacent to water, unless the width of the water body is small enough to allow any potential rescue to occur from the bank (as would be the case with most aeration basins). In some circumstances, these precautions may also be required by OSHA regulations. If you are planning to conduct work where water hazards may be present, be sure to take all appropriate precautions. If you will work in this situation, you should review the full text of the OSHA standard, OSHA Standard for Work Over or Near Water and consult your division HSM or designated HSC. 16.16-51 Section 16 Work Practices and Guidelines 01-03-12 16.21 Decontamination at Hazardous Waste Sites Proper decontamination helps protect employees and prevents the contamination of uncontaminated areas. Decontamination protects all site personnel by minimizing the transfer of harmful materials into clean areas. It helps prevent mixing of incompatible chemicals and protects the community by preventing uncontrolled transportation of contaminants from the site. 16.21.1 Prevention of Contamination To prevent contamination, crew members should: Follow procedures for proper dressing before entry into the exclusion zone. Proper dressing will minimize the potential for contaminants to bypass the PPE and escape decontamination. Protect monitoring and sampling instruments by bagging. Make openings in the bags for sample ports and sensors that must contact site materials, or cover equipment and tools with a strippable coating, which can be removed during decontamination. Encase any source of contaminants on the site with barriers (e.g., plastic sheeting or over packs). Stress work practices that minimize contact with hazardous substances. Use remote sampling, handling, and container-opening techniques. 16.21.2 Decontamination Equipment Selection In selecting decontamination equipment, consider whether the equipment must be decontaminated for reuse or can be easily disposed. Recommended equipment for decontamination includes: Storage tanks or appropriate treatment systems Drains or pumps Long-handled brushes Wash solutions appropriate for the contaminants present Rinse solutions appropriate for the contaminants present Pressurized sprayers for washing and rinsing Curtains, enclosures, or spray booths Long-handled rods and shovels Containers to hold contaminants and contaminated soils Wash and rinse buckets Brooms Containers for the storage and disposal of contaminated material 16.21-64 Section 16 Work Practices and Guidelines 01-03-12 16.21.3 Decontamination Design Decontamination facilities should be located in the CRZ, i.e., the area between the exclusion zone (the contaminated area) and the support zone (the clean area), and described in the site HSP. Site-specific factors that affect the decontamination facility design must be considered. Typical factors include: o o o o o o o o o o The chemical, physical, and toxicological properties of the wastes The pathogenicity of infectious wastes The amount, location, and containment of contaminants The potential for and location of exposure based on assigned worker duties, activities, and functions The potential for wastes to permeate, degrade, or penetrate materials used for personal protective clothing and equipment, vehicles, tools, buildings, and structures The proximity of incompatible wastes The movement of personnel and/or equipment among different zones The emergencies that may arise The methods available for protecting workers during decontamination The impact of the decontamination process and compounds on worker H&S Decontamination Line o Decontamination should be an organized process by which levels of contamination are reduced. o The decontamination process consists of a series of steps performed in a specific sequence. For example, outer, more heavily contaminated items are decontaminated first, followed by the decontamination and removal of inner, less contaminated items. o Each step should be performed at separate stations to prevent cross contamination. o Decontamination stations should allow enough separation to prevent cross contamination and should be arranged in order of decreasing contamination. o Separate decontamination areas should be provided to isolate workers from different contamination zones containing incompatible wastes or decontamination processes. o Entry and exit points should be conspicuously marked. Preferably the entry to the CRZ from the exclusion zone should be separate from the entry to the exclusion zone from the CRZ. o Dress-out stations for entry to the CRZ should be separate from redressing areas for exit from the CRZ. o Personnel who wish to enter clean areas of the decontamination facility, such as locker rooms, must be appropriately decontaminated first. o Examples of decontamination lines and procedures for personnel wearing various levels of protection are provided in Exhibits 16A and B. 16.21-65 Section 16 Work Practices and Guidelines 01-03-12 16.21.4 PPE for Decontamination Workers A rule of thumb is that decontamination workers wear a level of protection one level below the level of protection worn in the exclusion zone. However, consideration should be given to the following when determining the level of protection for a given project. The nature of site contamination Degree of contamination expected on workers leaving the exclusion zone The results of wipe tests and onsite air monitoring Some site-specific cases may require that decontamination personnel wear the same level of PPE as workers in the exclusion zone. Cases include: Workers using a steam jet may need a different type of respiratory protection than other decontamination personnel because of the high moisture content of the steam jets. Cleaning solutions used and wastes removed during decontamination may generate harmful vapors, requiring a different type of respiratory or clothing protection. 16.21.5 Decontamination Methods All personnel, clothing, equipment, and samples leaving the contaminated area of a site should be decontaminated to remove any harmful chemicals, radioactive material, or infectious organisms that may have adhered to them. The extent of decontamination will vary depending on the nature of site activity, site contamination, and other factors. Decontamination methods available include: o Physical removal o Chemical detoxification or disinfections/sterilization o A combination of both physical and chemical methods The selected decontamination method should be reviewed for any safety and health hazards. If the selected method poses a direct health hazard, measures shall be taken to protect both the decontamination personnel and the workers to be decontaminated. Physical Removal o Physical methods using high pressure and/or heat should be used with caution. o Loose contaminants can be removed by using a soap and water rinse with a soft bristle brush to remove dust and vapors that cling to equipment and workers, or that are trapped in small openings, such as clothing or fabric weaving. Adhering contaminants can be removed by: o o o o o Scraping, brushing, and wiping. Solidifying. Freezing (using dry ice or ice water). Adsorption or absorption (e.g., kitty litter or powdered lime). Melting. 16.21-66 Section 16 Work Practices and Guidelines 01-03-12 o Volatile liquid contaminants can be removed from PPE or equipment by evaporation followed by a water rinse. Evaporation may be expedited by the use of steam jets. Chemical Removal o Decontamination using chemicals should only be done if recommended by an industrial hygienist or other qualified professional. o Any chemical used in the decontamination process must be chemically compatible with the equipment or clothing being decontaminated. o Halogenated solvents should only be used for decontamination in extreme cases where other cleaning agents will not remove the contaminant. Chemical removal types include the following: o Surface contaminants can be dissolved in a solvent. o Solidification of liquid or gel contaminants can enhance their physical removal. Typical solidification processes are moisture removal using adsorbents such as grounded clay or powdered lime; and chemical reactions using polymerization chemicals and/or chemical reagents. 16.21.6 Personnel Decontamination Different levels of personnel protection, as discussed in the PPE guidelines, may be used at any given site. The following is a description of the decontamination process for each level of protection. Level D o An area should be designated for the gross removal of dirt and mud from gloves and boot covers. Paper towels and buckets of rinse water can be made available for this purpose. o Typical decontamination steps for Level D operations are provided in Exhibit 16-B. o Soap and water should be used to wash hands and face before leaving the site. o Laundering of personal clothing should be completed as soon as possible once offsite. Level C and B o A decontamination line should be established. o Site-specific procedures should be outlined in the site HSP. The recommended procedure for this layout is listed in Exhibit 16-C. Level A - It is not anticipated CDM Smith will directly participate in Level A operations. If required, site-specific procedures will be developed in coordination with the division HSM. 16.21.7 Sampling and Monitoring Equipment Decontamination Sampling equipment often becomes grossly contaminated. Often trowels or drum thieves (coliwassas) are dedicated to a particular site. These should be left in the exclusion zone and disposed of as contaminated waste at the end of site work. Sampling equipment such as split spoons or other equipment that is used to collect several samples must be cleaned and decontaminated between samples to prevent cross contamination. These items should be cleaned and decontaminated in accordance with the project operations or sampling 16.21-67 Section 16 Work Practices and Guidelines 01-03-12 plan. Dirt and wash solutions from sampling equipment decontamination should be collected and disposed of as investigation-derived waste. Once grossly contaminated, testing and monitoring instrumentation can be difficult to decontaminate without causing damage to the instrument. Care should be taken in the field to prevent gross contamination of field instruments by avoiding direct contact between the instrument and contaminated soils, water, or surfaces. In some cases it may be necessary to place instruments in plastic bags, leaving small openings for sampling ports, detectors, and exhaust ports. The plastic bags can then be removed as the instrument comes out of the exclusion zone. The outside of instruments can be wiped down with paper towels or brushed off with clean soft brushes. 16.21.8 Heavy Equipment Decontamination Drill rigs, trucks, backhoes, and other heavy equipment can be difficult to decontaminate. The method generally used is to wash them with water under pressure and scrub accessible areas with soap and warm water. Hot water and steam systems can be effective but may increase air concentrations of contaminants, exposing decontamination workers. Particular care should be taken where equipment comes into direct contact with contaminated soils such as tires, buckets, or treads. In severe cases, tires may need to be replaced or parts sand blasted clean or disposed of. Equipment should be visually inspected to be sure it is free of any visible signs of contamination. In some cases, wipe tests or other methods may be needed to confirm equipment has been adequately decontaminated before leaving the site. 16.21.9 Decontamination Solutions, Disposable PPE, and Site Wastes Potentially contaminated equipment, disposable PPE, respirator cartridges, disposable sampling equipment, brushes, buckets, waste decontamination solutions, etc. should be secured in drums and labeled. Disposal methods for these materials may depend on client requirements and/or results of site investigation data. The confirmed presence of hazardous materials on the site may require disposal of investigation-derived wastes as hazardous wastes. Care should be taken during work and decontamination activities to minimize waste materials generated. 16.21-68 Section 16 Work Practices and Guidelines 01-03-12 Exhibit 16-B Minimum Measures For Level D Decontamination Station 1 - Equipment Drop Deposit equipment used on plastic drop cloths. Segregation at the drop reduces the probability of cross contamination. During hot weather, a cool down station may be set up in this area. Station 2 - Outer Garment, Boots, and Scrub outer boots, outer gloves, and suit with deconGloves Wash and Rinse tamination solution or detergent/water. Rinse off using copious amounts of water. Station 3 - Hard Hat, Outer Boot, and Glove Removal Remove hard hat, outer boots, and gloves. Station 4 - Boots, Gloves, and Outer Garment Removal Remove boots, suit, and inner gloves and deposit in separate containers lined with plastic. Station 5 - Field Wash Wash hands and face. Exhibit 16-C Minimum Measures For Level B, And C Decontamination Station 1 - Equipment Drop Station 2 - Outer Garment, Hard Hat, Boots, and Gloves Wash and Rinse Station 3 - Tank/Air Canister Change Station 4 - Outer Boots, and Glove Removal Station 5 - SCBA/Respirator Removal Station 6 - Inner Gloves and Outer Garment Removal Station 7 - Field Wash Deposit equipment used on plastic drop cloths. Segregation at the drop reduces the probability of cross contamination. During hot weather, a cool down station may be set up in this area. Scrub outer boots, hard hat, outer gloves, and suit with decontamination solution or detergent/water. Rinse off using copious amounts of water. If a worker leaves the exclusion zone to change an air tank, air canister, or mask, this is the last step in the decontamination procedure. Worker’s air tank is exchanged, new outer gloves and boots donned, and joints tapped. Worker returns to duty. Remove outer boots and gloves. Deposit in container with plastic liner. SCBA backpack and facepiece/respirator is removed (avoid touching face with fingers). SCBA or respirator is deposited on plastic sheets. Remove suit and inner gloves and deposit in separate containers lined with plastic. Shower if highly toxic, skin-corrosive, or skin-absorbable materials are known or suspected to be present. Wash hands and face. 16.21-69 Section 16 Work Practices and Guidelines 01-03-12 16.22 Traffic and Work Zone Safety These guidelines apply whenever CDM Smith employees or subcontractors work in areas exposed to vehicular traffic on public streets or highways. Where vehicular traffic hazards exist because of work at locations near public streets or roads, a system of traffic and work zone controls should be developed to mitigate the hazard. The system should meet the requirements of Part 6 of the Manual of Uniform Traffic Control Devices (MUTCD) published by the Federal Highway Administration, or the applicable state version of the MUTCD. In general, when the MUTCD allows the use of traffic safety direction devices, such as cones, CDM Smith will supplement those direction devices with a physical barrier, such as a truck. All traffic control systems on public roads must be coordinated with local traffic control officials as required by applicable law. Periodically evaluate effectiveness of temporary traffic control setups by walking or riding the job area looking for evidence of poor controls and near misses such as swerving traffic, motorists braking quickly, skid marks, blind spots, etc. Give motorists plenty of advanced warning of upcoming work zones. All employees working within designated work zones or near vehicular traffic should wear high-visibility clothing such as orange, yellow, or yellow-green shirts, jackets, or vests. During wet or inclement weather, similarly colored rainwear should be worn. During night work, between the hours of sunset and sunrise, high-visibility clothing should incorporate reflective striping or fabric and be visible at a distance of 1,000 feet. This clothing should meet ANSI standard #107 for High Visibility Safety Apparel. All employees working near traffic and vehicles must maintain situational awareness at all times. Stay mindful that warning signs and cones inform drivers to take action but that some drivers may not pay attention, and vehicles may still enter the work zone. 16.22-70 Appendix B MSDS MATERIAL SAFETY DATA SHEET ALCONOX® Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe, Japanese Industrial Standard JIS Z 7250:2000, and European Union REACH Regulations SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION ALCONOX® PRODUCT NAME: CHEMICAL FAMILY NAME: PRODUCT USE: U.N. NUMBER: U.N. DANGEROUS GOODS CLASS: SUPPLIER/MANUFACTURER'S NAME: ADDRESS: EMERGENCY PHONE: BUSINESS PHONE: DATE OF PREPARATION: DATE OF LAST REVISION: Detergent. Critical-cleaning detergent for laboratory, healthcare and industrial applications Not Applicable Non-Regulated Material Alconox, Inc. 30 Glenn St., Suite 309, White Plains, NY 10603. USA 800-255-3924 TOLL-FREE in USA/Canada 813-248-0585 International calls 914-948-4040 May 2011 February 2008 SECTION 2 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: This product is a white granular powder with little or no odor. Exposure can be irritating to eyes, respiratory system and skin. It is a non-flammable solid. The Environmental effects of this product have not been investigated. US DOT SYMBOLS CANADA (WHMIS) SYMBOLS EUROPEAN and (GHS) Hazard Symbols Non-Regulated Signal Word: Warning! EU LABELING AND CLASSIFICATION: Classification of the substance or mixture according to Regulation (EC) No1272/2008 Annex 1 EC# 205-633-8 This substance is not classified in the Annex I of Directive 67/548/EEC EC# 268-356-1 This substance is not classified in the Annex I of Directive 67/548/EEC EC# 231-838-7 This substance is not classified in the Annex I of Directive 67/548/EEC EC# 231-767-1 This substance is not classified in the Annex I of Directive 67/548/EEC EC# 207-638-8 Index# 011-005-00-2 EC# 205-788-1 This substance is not classified in the Annex I of Directive 67/548/EEC GHS Hazard Classification(s): Eye Irritant Category 2A Hazard Statement(s): H319: Causes serious eye irritation Precautionary Statement(s): P260: Do not breath dust/fume/gas/mist/vapors/spray P264: Wash hands thoroughly after handling P271: Use only in well ventilated area. P280: Wear protective gloves/protective clothing/eye protection/face protection/ Hazard Symbol(s): [Xi] Irritant May 2011 Page 1 of 7 Rev 1 MATERIAL SAFETY DATA SHEET ALCONOX® Risk Phrases: R20: Harmful by inhalation R36/37/38: Irritating to eyes, respiratory system and skin Safety Phrases: S8: Keep container dry S22: Do not breath dust S24/25: Avoid contact with skin and eyes HEALTH HAZARDS OR RISKS FROM EXPOSURE: ACUTE: Exposure to this product may cause irritation of the eyes, respiratory system and skin. Ingestion may cause gastrointestinal irritation including pain, vomiting or diarrhea. CHRONIC: This product contains an ingredient which may be corrosive. TARGET ORGANS: ACUTE: Eye, respiratory System, Skin CHRONIC: None Known SECTION 3 - COMPOSITION and INFORMATION ON INGREDIENTS HAZARD CLASSIFICATION; RISK PHRASES HAZARDOUS INGREDIENTS: CAS # EINECS # ICSC # WT % Sodium Bicarbonate 144-55-8 205-633-8 1044 33 - 43% HAZARD CLASSIFICATION: None RISK PHRASES: None Sodium (C10 – C16) Alkylbenzene Sulfonate 68081-81-2 268-356-1 Not Listed 10 – 20% HAZARD CLASSIFICATION: None RISK PHRASES: None Sodium Tripolyphosphate 7758-29-4 231-838-7 1469 5 - 15% HAZARD CLASSIFICATION: None RISK PHRASES: None Tetrasodium Pyrophosphate 7722-88-5 231-767-1 1140 5 - 15% HAZARD CLASSIFICATION: None RISK PHRASES: None Sodium Carbonate 497-19-8 207-638-8 1135 1 - 10% HAZARD CLASSIFICATION: [Xi] Irritant RISK PHRASES: R36 Sodium Alcohol Sulfate 151-21-3 205-788-1 0502 1 – 5% HAZARD CLASSIFICATION: None RISK PHRASES: None Balance of other ingredients are non-hazardous or less than 1% in concentration (or 0.1% for carcinogens, reproductive toxins, or respiratory sensitizers). NOTE: ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been classified in accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JIS Z 7250: 2000. SECTION 4 - FIRST-AID MEASURES Contaminated individuals of chemical exposure must be taken for medical attention if any adverse effect occurs. Rescuers should be taken for medical attention, if necessary. Take copy of label and MSDS to health professional with contaminated individual. EYE CONTACT: If product enters the eyes, open eyes while under gentle running water for at least 15 minutes. Seek medical attention if irritation persists. SKIN CONTACT: Wash skin thoroughly after handling. Seek medical attention if irritation develops and persists. Remove contaminated clothing. Launder before re-use. INHALATION: If breathing becomes difficult, remove victim to fresh air. If necessary, use artificial respiration to support vital functions. Seek medical attention if breathing dificulty continues. INGESTION: If product is swallowed, call physician or poison control center for most current information. If professional advice is not available, do not induce vomiting. Never induce vomiting or give diluents (milk or water) to someone who is unconscious, having convulsions, or who cannot swallow. Seek medical advice. Take a copy of the label and/or MSDS with the victim to the health professional. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing skin, or eye problems may be aggravated by prolonged contact. RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure. May 2011 Page 2 of 7 Rev 1 MATERIAL SAFETY DATA SHEET ALCONOX® SECTION 5 - FIRE-FIGHTING MEASURES FLASH POINT: AUTOIGNITION TEMPERATURE: FLAMMABLE LIMITS (in air by volume, %): FIRE EXTINGUISHING MATERIALS: UNUSUAL FIRE AND EXPLOSION HAZARDS: Explosion Sensitivity to Mechanical Impact: Explosion Sensitivity to Static Discharge: SPECIAL FIRE-FIGHTING PROCEDURES: Not Flammable Not Applicable Lower (LEL): NA Upper (UEL): NA As appropriate for surrounding fire. Carbon dioxide, foam, dry chemical, halon, or water spray. This product is non-flammable and has no known explosion hazards. Not Sensitive. Not Sensitive Incipient fire responders should wear eye protection. Structural firefighters must wear Self-Contained Breathing Apparatus and full protective equipment. Isolate materials not yet involved in the fire and protect personnel. Move containers from fire area if this can be done without risk; otherwise, cool with carefully applied water spray. If possible, prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. NFPA RATING SYSTEM HMIS RATING SYSTEM HAZARDOUS MATERIAL IDENTIFICATION SYSTEM Flammability 0 Health 1 0 Reactivity HEALTH HAZARD (BLUE) 1 FLAMMABILITY HAZARD (RED) 0 PHYSICAL HAZARD (YELLOW) 0 PROTECTIVE EQUIPMENT EYES RESPIRATORY HANDS Other See Sect 8 BODY See Sect 8 For Routine Industrial Use and Handling Applications Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard SECTION 6 - ACCIDENTAL RELEASE MEASURES SPILL AND LEAK RESPONSE: Personnel should be trained for spill response operations. SPILLS: Contain spill if safe to do so. Prevent entry into drains, sewers, and other waterways. Sweep, shovel or vacuum spilled material and place in an appropriate container for re-use or disposal. Avoid dust generation if possible. Dispose of in accordance with applicable Federal, State, and local procedures (see Section 13, Disposal Considerations). SECTION 7 - HANDLING and STORAGE WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product. Avoid breathing dusts generated by this product. Use in a well-ventilated location. Remove contaminated clothing immediately. STORAGE AND HANDLING PRACTICES: Containers of this product must be properly labeled. Store containers in a cool, dry location. Keep container tightly closed when not in use. Store away from strong acids or oxidizers. May 2011 Page 3 of 7 Rev 1 MATERIAL SAFETY DATA SHEET ALCONOX® SECTION 8 - EXPOSURE CONTROLS - PERSONAL PROTECTION EXPOSURE LIMITS/GUIDELINES: Chemical Name CAS# ACGIH TWA OSHA TWA SWA Sodium Bicarbonate 144-55-8 10 mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Sodium (C10 – C16) Alkylbenzene Sulfonate 68081-81-2 10 mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Sodium Tripolyphosphate 7758-29-4 10 mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Tetrasodium Pyrophosphate 7722-88-5 5 mg/m³ 5 mg/m³ 5 mg/m³ Sodium Carbonate 497-19-8 10 mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Sodium Alcohol Sulfate 151-21-3 10 mg/m³ Total Dust 15 mg/m³ Total Dust 10 mg/m³ Total Dust Currently, International exposure limits are not established for the components of this product. Please check with competent authority in each country for the most recent limits in place. VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided below. Use local exhaust ventilation to control airborne dust. Ensure eyewash/safety shower stations are available near areas where this product is used. The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, or standards of EU member states (including EN 149 for respiratory PPE, and EN 166 for face/eye protection), and those of Japan. Please reference applicable regulations and standards for relevant details. RESPIRATORY PROTECTION: Based on test data, exposure limits should not be exceeded under normal use conditions when using Alconox Detergent. Maintain airborne contaminant concentrations below guidelines listed above, if applicable. If necessary, use only respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, or EU member states. EYE PROTECTION: Safety glasses. If necessary, refer to U.S. OSHA 29 CFR 1910.133 or appropriate Canadian Standards. HAND PROTECTION: Use chemical resistant gloves to prevent skin contact.. If necessary, refer to U.S. OSHA 29 CFR 1910.138 or appropriate Standards of Canada. BODY PROTECTION: Use body protection appropriate to prevent contact (e.g. lab coat, overalls). If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards, or relevant Japanese Standards. SECTION 9 - PHYSICAL and CHEMICAL PROPERTIES Solid White granular powder with little or no odor. Not Available Not Applicable Not Applicable. Not Available Not Applicable. Not Applicable. Not Applicable. 9.5 (1% aqueous solution) 0.85 – 1.1 >10% w/w Not Available None Detergent PHYSICAL STATE: APPEARANCE & ODOR: ODOR THRESHOLD (PPM): VAPOR PRESSURE (mmHg): VAPOR DENSITY (AIR=1): BY WEIGHT: EVAPORATION RATE (nBuAc = 1): BOILING POINT (C°): FREEZING POINT (C°): pH: SPECIFIC GRAVITY 20°C: (WATER =1) SOLUBILITY IN WATER (%) COEFFICIENT OF WATER/OIL DIST.: VOC: CHEMICAL FAMILY: May 2011 Page 4 of 7 Rev 1 MATERIAL SAFETY DATA SHEET ALCONOX® SECTION 10 - STABILITY and REACTIVITY STABILITY: Product is stable DECOMPOSITION PRODUCTS: When heated to decomposition this product produces Oxides of carbon (COx) MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Strong acids and strong oxidizing agents. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Contact with incompatible materials and dust generation. SECTION 11 - TOXICOLOGICAL INFORMATION TOXICITY DATA: Toxicity data is available for mixture: CAS# 497-19-8 LD50 Oral (Rat) 4090 mg/kg CAS# 497-19-8 LD50 Oral (Mouse) 6600 mg/kg CAS# 497-19-8 LC50 Inhalation 2300 mg/m³ 2H (Rat) CAS# 497-19-8 LC50 Inhalation 1200 mg/m³ 2H (Mouse) CAS# 7758-29-4 LD50 Oral (Rat) 3120 mg/kg CAS# 7758-29-4 LD50 Oral 3100 mg/kg (Mouse) CAS# 7722-88-5 LD50 Oral (Rat) 4000 mg/kg SUSPECTED CANCER AGENT: None of the ingredients are found on the following lists: FEDERAL OSHA Z LIST, NTP, CAL/OSHA, IARC and therefore is not considered to be, nor suspected to be a cancer-causing agent by these agencies. IRRITANCY OF PRODUCT: Contact with this product can be irritating to exposed skin, eyes and respiratory system. SENSITIZATION OF PRODUCT: This product is not considered a sensitizer. REPRODUCTIVE TOXICITY INFORMATION: No information concerning the effects of this product and its components on the human reproductive system. SECTION 12 - ECOLOGICAL INFORMATION ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL STABILITY: No Data available at this time. EFFECT OF MATERIAL ON PLANTS or ANIMALS: No evidence is currently available on this product’s effects on plants or animals. EFFECT OF CHEMICAL ON AQUATIC LIFE: No evidence is currently available on this product’s effects on aquatic life. SECTION 13 - DISPOSAL CONSIDERATIONS PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations, those of Canada, Australia, EU Member States and Japan. SECTION 14 - TRANSPORTATION INFORMATION US DOT; IATA; IMO; ADR: THIS PRODUCT IS NOT HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Non-Regulated Material HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable UN IDENTIFICATION NUMBER: Not Applicable PACKING GROUP: Not Applicable. DOT LABEL(S) REQUIRED: Not Applicable NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (2004): Not Applicable MARINE POLLUTANT: None of the ingredients are classified by the DOT as a Marine Pollutant (as defined by 49 CFR 172.101, Appendix B) U.S. DEPARTMENT OF TRANSPORTATION (DOT) SHIPPING REGULATIONS: This product is not classified as dangerous goods, per U.S. DOT regulations, under 49 CFR 172.101. TRANSPORT CANADA, TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not classified as Dangerous Goods, per regulations of Transport Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA): This product is not classified as Dangerous Goods, by rules of IATA: INTERNATIONAL MARITIME ORGANIZATION (IMO) DESIGNATION: This product is not classified as Dangerous Goods by the International Maritime Organization. EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD (ADR): May 2011 Page 5 of 7 Rev 1 MATERIAL SAFETY DATA SHEET ALCONOX® This product is not classified by the United Nations Economic Commission for Europe to be dangerous goods. SECTION 15 - REGULATORY INFORMATION UNITED STATES REGULATIONS SARA REPORTING REQUIREMENTS: This product is not subject to the reporting requirements of Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows: None TSCA: All components in this product are listed on the US Toxic Substances Control Act (TSCA) inventory of chemicals. SARA 311/312: Acute Health: Yes Chronic Health: No Fire: No Reactivity: No U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may apply, per 40 CFR 370.20. U.S. CERCLA REPORTABLE QUANTITY (RQ): None CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): None of the ingredients are on the California Proposition 65 lists. CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS: All of the components of this product are on the DSL Inventory CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No component of this product is on the CEPA First Priorities Substance Lists. CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This product is categorized as a Controlled Product, Hazard Class D2B as per the Controlled Product Regulations EUROPEAN ECONOMIC COMMUNITY INFORMATION: EU LABELING AND CLASSIFICATION: Classification of the mixture according to Regulation (EC) No1272/2008. See section 2 for details. AUSTRALIAN INFORMATION FOR PRODUCT: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: All components of this product are listed on the AICS. STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Not applicable. JAPANESE INFORMATION FOR PRODUCT: JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY (MITI) STATUS: The components of this product are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances, or Designated Chemical Substances by the Japanese MITI. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Asia-Pac: Australian Inventory of Chemical Substances (AICS): Korean Existing Chemicals List (ECL): Japanese Existing National Inventory of Chemical Substances (ENCS): Philippines Inventory if Chemicals and Chemical Substances (PICCS): Swiss Giftliste List of Toxic Substances: U.S. TSCA: Listed Listed Listed Listed Listed Listed Listed SECTION 16 - OTHER INFORMATION PREPARED BY: Paul Eigbrett May 2011 Global Safety Management, 10006 Cross Creek Blvd. Suite 440, Tampa, FL 33647 Page 6 of 7 Rev 1 MATERIAL SAFETY DATA SHEET ALCONOX® Disclaimer: To the best of Alconox, Inc. knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness is not guaranteed and no warranties of any type either express or implied are provided. The information contained herein relates only to this specific product. ANNEX: IDENTIFIED USES OF ALCONOX® AND DIRECTIONS FOR USE Used to clean: Healthcare instruments, laboratory ware, vacuum equipment, tissue culture ware, personal protective equipment, sampling apparatus, catheters, tubing, pipes, radioactive contaminated articles, optical parts, electronic components, pharmaceutical apparatus, cosmetics manufacturing equipment, metal castings, forgings and stampings, industrial parts, tanks and reactors. Authorized by USDA for use in federally inspected meat and poultry plants. Passes inhibitory residue test for water analysis. FDA certified. Used to remove: Soil, grit, grime, buffing compound, slime, grease, oils, blood, tissue, salts, deposits, particulates, solvents, chemicals, radioisotopes, radioactive contaminations, silicon oils, mold release agents. Surfaces cleaned: Corrosion inhibited formulation recommended for glass, metal, stainless steel, porcelain, ceramic, plastic, rubber and fiberglass. Can be used on soft metals such as copper, aluminum, zinc and magnesium if rinsed promptly. Corrosion testing may be advisable. Cleaning method: Soak, brush, sponge, cloth, ultrasonic, flow through clean-inplace. Will foam—not for spray or machine use. Directions: Make a fresh 1% solution (2 1/2 Tbsp. per gal., 1 1/4 oz. per gal. or 10 grams per liter) in cold, warm, or hot water. If available use warm water. Use cold water for blood stains. For difficult soils, raise water temperature and use more detergent. Clean by soak, circulate, wipe, or ultrasonic method. Not for spray machines, will foam. For nonabrasive scouring, make paste. Use 2% solution to soak frozen stopcocks. To remove silver tarnish, soak in 1% solution in aluminum container. RINSE THOROUGHLY—preferably with running water. For critical cleaning, do final or all rinsing in distilled, deionized, or purified water. For food contact surfaces, rinse with potable water. Used on a wide range of glass, ceramic, plastic, and metal surfaces. Corrosion testing may be advisable. May 2011 Page 7 of 7 Rev 1 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades Material Safety Data Sheet CITGO Petroleum Corporation P. O. Box 4689 Houston, TX 77210 MSDS No. AG2DF Revision Date 12/31/2007 IMPORTANT: This MSDS is prepared in accordance with 29 CFR 1910.1200. Read this MSDS before transporting, handling, storing or disposing of this product and forward this information to employees, customers and users of this product. Emergency Overview Physical State Liquid. Transparent, clear to Color yellow or red. Odor Hazard Rankings HMIS NFPA 2 0 Fire Hazard 2 2 Reactivity 0 0 Health Hazard * * = Chronic Health Hazard Characteristic, kerosene-like. WARNING! Combustible liquid; vapor may cause flash fire. Harmful or fatal if swallowed - can enter lungs and cause damage. Can cause eye, skin or respiratory tract irritation. May be harmful if inhaled or absorbed through the skin. Overexposure can cause central nervous system (CNS) depression and/or other target organ effects. Possible Cancer Hazard (See Section 3) Harmful to aquatic organisms. Protective Equipment Minimum Recommended See Section 8 for Details SECTION 1. PRODUCT IDENTIFICATION Trade Name CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades Technical Contact (832) 486-5940 Product Number Various Medical Emergency (832) 486-4700 CAS Number 68476-34-6 CHEMTREC Emergency (United States Only) (800) 424-9300 Product Family Motor fuels. Synonyms No. 2-D Grade Diesel Fuel Oil (defined by ASTM D-975); Treated or Refined Diesel Fuel No. 2; Diesel No. 2; Diesel Motor Fuel No. 2; Diesel Oil (Medium); Grade 2 Distillate Fuel; Hydrodesulfurized (HDS) Light Catalytically Cracked Distillate; Middle Distillates (Petroleum); HDS Diesel; Hydrodesulfurized Medium Distillate; HDS Middle Distillate; C9-C16 Petroleum Hydrocarbons; Ultra Low Sulfur Diesel. SECTION 2. COMPOSITION This product may be composed, in whole or in part, of any of the following refinery streams: Diesel Fuel No. 2 [CAS No.: 68476-34-6] Hydrodesulfurized Middle Distillate (petroleum) [CAS No.: 64742-80-9] Hydrodesulfurized Light Catalytic Cracked Distillate (Petroleum) [CAS No.: 68333-25-5] Kerosene [CAS No.: 8008-20-6] Hydrodesulfurized Kerosine (Petroleum) [CAS No.: 64742-81-0] This product contains the following chemical components: Component Name(s) MSDS No. AG2DF Revision Date 12/31/2007 CAS Registry No. Continued on Next Page Concentration (%) Page Number: 1 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades Nonane, all isomers Trimethylbenzenes, all isomers Naphthalene Cumene Ethylbenzene Mixture 25551-13-7 91-20-3 98-82-8 100-41-4 1 - 10 0-2 0-2 0-1 0-1 SECTION 3. HAZARDS IDENTIFICATION Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS. Major Route(s) of Entry Skin contact. Inhalation. Signs and Symptoms of Acute Exposure Inhalation Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Breathing this material may cause central nervous system depression with symptoms including nausea, headache, dizziness, fatigue, drowsiness, or unconsciousness. Eye Contact This material can cause eye irritation with tearing, redness, or a stinging or burning feeling. Further, it can cause swelling of the eyes with blurred vision. Effects may become more serious with repeated or prolonged contact. Skin Contact This material can cause skin irritation. Symptoms include redness, itching, and burning of the skin. This material can be absorbed by the skin and produce central nervous system depression (headache, nausea, fatigue and/or other symptoms including unconsciousness). If the skin is damaged, absorption increases. Prolonged and/or repeated contact may cause severe dermatitis and/or more serious skin disorders. Chronic symptoms may include drying, swelling, scaling, blistering, cracking, and/or severe tissue damage. Ingestion If swallowed, this material may irritate the mouth, throat, and esophagus. It can be absorbed into the blood stream through the stomach and intestinal tract. Symptoms may include a burning sensation of the mouth and esophagus, nausea and vomiting. In addition, it can cause central nervous system effects characterized by dizziness, staggering, drowsiness, delirium and/or loss of consciousness. Because of the low viscosity, this material can enter the lungs directly by aspiration during swallowing or subsequent vomiting. Aspiration of a small amount of liquid can cause severe lung damage and/or death. Chronic Health Effects Secondary effects of ingestion and subsequent aspiration into the lungs may cause pneumatocele (lung cavity) formation and chronic lung dysfunction. Summary This product contains petroleum middle distillates similar to those shown to produce skin tumors on laboratory rodents following repeated application. All tumors appeared during the latter portion of the typical 2-year lifespan of the animals. Certain studies have shown that washing the exposed skin of the test animal with soap and water between treatments greatly reduces the potential tumorigenic effects. These data suggest that good personal hygiene is effective in reducing the risk of this potential adverse health effect. This material and/or its components have been associated with developmental toxicity, reproductive toxicity, genotoxicity, immunotoxicity, and/or carcinogenicity. Refer to Section 11 of this MSDS for additional health-related information. Conditions Aggravated Disorders of the following organs or organ systems that may be aggravated by significant exposure to this material or its components include: Skin, Respiratory System, Liver, by Exposure Kidneys, Central Nervous System (CNS) Target Organs May cause damage to the following organs: kidneys, lungs, liver, mucous membranes, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea Carcinogenic Potential MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 2 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades This material may contain ethylbenzene and naphthalene at concentrations above 0.1%. IARC has identified ethylbenzene and naphthalene as possibly carcinogenic to humans (Group 2B) based on laboratory animal studies. The NTP has determined that naphthalene is reasonably anticipated to be a human carcinogen based on sufficient evidence from studies in experimental animals. NTP has determined that exposure to diesel exhaust particulates, a complex mixture of combustion products of diesel fuel, is reasonably anticipated to be a human carcinogen. OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present, the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR 1910.1200). OSHA Physical Hazard Classification OSHA Health Hazard Classification Sensitizer Combustible Toxic Highly Toxic Corrosive Carcinogenic Irritant X Explosive Pyrophoric Flammable Oxidizer Water-reactive Compressed Gas Organic Peroxide Unstable X SECTION 4. FIRST AID MEASURES Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If breathing is difficult, 100 percent humidified oxygen should be administered by a qualified individual. Seek medical attention immediately. Keep the affected individual warm and at rest. Eye Contact Check for and remove contact lenses. Flush eyes with cool, clean, low-pressure water for at least 15 minutes while occasionally lifting and lowering eyelids. Do not use eye ointment unless directed to by a physician. Seek medical attention if excessive tearing, irritation, or pain persists. Skin Contact Remove contaminated shoes and clothing. Flush affected area with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Ingestion Do not induce vomiting. If spontaneous vomiting is about to occur, place victim’s head below knees. If victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention immediately. Notes to Physician INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted ventilation, as required. INGESTION: If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position. MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 3 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades SECTION 5. FIRE FIGHTING MEASURES NFPA Flammability Classification NFPA Class-II combustible liquid. Flash Point Closed cup: AP 52°C (AP 125°F). (Pensky-Martens.) Lower Flammable Limit AP 0.6 % Autoignition Temperature Upper Flammable Limit AP 7.5 % >254°C (>489°F) Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons and oxides of Products sulfur and nitrogen. Special Properties Combustible Liquid! This material releases vapors when heated above ambient temperatures. Vapors can cause a flash fire. Vapors can travel to a source of ignition and flashback. A vapor and air mixture can create an explosion hazard in confined spaces such as sewers. Use only with adequate ventilation. If container is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media SMALL FIRE: Use dry chemicals, carbon dioxide, foam, or inert gas (nitrogen). Carbon dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or inert gas in confined spaces. LARGE FIRE: Use foam, water fog, or water spray. Water fog and spray are effective in cooling containers and adjacent structures. However, water can cause frothing and/or may not extinguish the fire. Water can be used to cool the external walls of vessels to prevent excessive pressure, autoignition or explosion. DO NOT use a solid stream of water directly on the fire as the water may spread the fire to a larger area. Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid with foam. Containers can build pressure if exposed to radiant heat; cool adjacent containers with flooding quantities of water until well after the fire is out. Withdraw immediately from the area if there is a rising sound from a venting safety device or discoloration of vessels, tanks, or pipelines. Be aware that burning liquid will float on water. Notify appropriate authorities of potential fire and explosion hazard if liquid enter sewers or waterways. SECTION 6. ACCIDENTAL RELEASE MEASURES Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS. Combustible Liquid! Release can result in a fire hazard. Evacuate all non-essential personnel from release area. Establish a regulated zone with site control and security. Eliminate all ignition sources. Stop the leak if it can done without risk. A vapor-suppressing foam may be used to reduce vapors. Properly bond or ground all equipment used when handling this material. Avoid skin contact. Do not walk through spilled material. Verify that responders are properly trained and wearing appropriate personnel protective equipment. Dike far ahead of a liquid spills. Do not allow released material to entry waterways, sewers, basements, or confined areas. This material will float on water. Absorb or cover with dry earth, sand or other non-combustible material. Use clean, non-sparking tools to collect absorbed material. Place spent sorbent materials, free liquids and other clean-up debris into proper waste containers for appropriate disposal. Certain releases must be reported to the National Response Center (800/424-8802) and state or regulatory authorities. Comply with all laws and regulations. MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 4 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades SECTION 7. HANDLING AND STORAGE Handling Combustible Liquid! A static electrical charge can accumulate when this material is flowing through pipes, nozzles or filters and when it is agitated. A static spark discharge can ignite accumulated vapors particularly during dry weather conditions. Always bond receiving containers to the fill pipe before and during loading. Always keep nozzle in contact with the container throughout the loading process. Do not fill any portable container in or on a vehicle. Special precautions, such as reduced loading rates and increased monitoring, must be observed during "switch loading" operations (i.e., loading this material in tanks or shipping compartments that previously containing gasoline or similar low flash point products). Fire hazard increases as product temperature approaches its flash point. Keep container closed and drum bungs in place. Remove spillage immediately from walking areas. Do not handle or store near heat, sparks or other potential ignition sources. Do not handle or store with oxidizing agents. Avoid breathing mist or vapor. Never siphon by mouth. Do not taste or swallow. Avoid contact with eyes, skin and clothing. Use gloves constructed of impervious materials and protective clothing if direct contact is anticipated. Provide ventilation to maintain exposure potential below applicable exposure levels. Avoid water contamination. Wash thoroughly after handling. Prevent contact with food or tobacco products. When performing repairs and maintenance on contaminated equipment, keep unnecessary persons from hazard area. Eliminate heat, flame and other potential ignition sources. Drain and purge equipment, as necessary, to remove material residues. Remove contaminated clothing. Wash exposed skin thoroughly with soap and water after handling. Do not use this material as fuel for equipment, such as portable heaters, in enclosed areas. Hazardous combustion products can cause death. Protect the environment from releases of this material. Prevent discharges to surface waters and groundwater. Maintain handling, transfer and storage equipment in proper working order. Misuse of empty containers can be dangerous. Empty containers may contain material residues which can ignite with explosive force. Cutting or welding of empty containers Do not pressurize or can cause fire, explosion, or release of toxic fumes from residues. expose empty containers to open flame, sparks, or heat. Keep container closed and drum bungs in place. All label warnings and precautions must be observed. Return empty drums to a qualified reconditioner. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling, or disposing of empty containers and/or waste residues of this material. Store in a cool, dry, well-ventilated place. Keep containers tightly closed. Do not store this product near heat, flame or other potential ignition sources. Do not store with oxidizers. Do not store this product in unlabeled containers. Do not puncture or incinerate containers. Ground all equipment containing this material. All electrical equipment in areas where this material is stored or handled must meet all applicable requirements of the NFPA's National Electrical Code (NEC). Store and transport in accordance with all applicable laws. Storage SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls Provide ventilation or other engineering controls to keep the airborne concentrations of vapor or mists below the applicable workplace exposure limits indicated below. All electrical equipment should comply with the National Electric Code. An emergency eye wash station and safety shower should be located near the work-station. Personal Protective Equipment Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum requirements for personal protective equipment. For certain operations, additional PPE may be required. MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 5 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Chemical goggles should be worn during transfer operations or when there is a likelihood of misting, splashing, or spraying of this material. A suitable emergency eye wash water and safety shower should be located near the work station. Hand Protection Avoid skin contact. Use heavy duty gloves constructed of chemical resistant materials such as Viton® or heavy nitrile rubber. Wash hands with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities or leaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives as skin cleaners. Avoid skin contact. Wear long-sleeved fire-retardant garments (e.g., Nomex®) while working with flammable and combustible liquids. Additional chemical-resistant protective gear may be required if splashing or spraying conditions exist. This may include an apron, boots and additional facial protection. If product comes in contact with clothing, immediately remove soaked clothing and shower. Promptly remove and discard contaminated leather goods. Body Protection Respiratory Protection Airborne concentration will determine the level of respiratiory protection required. Respiratory protection is normally not required unless the product is heated or misted. For known or anticipated vapor or mist concentrations above the occupational exposure guidelines (see below), use a NIOSH-approved organic vapor respirator equipped with a dust/mist prefilter if adequate protection is provided. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134). General Comments Warning! Use of this material in spaces without adequate ventilation may result in generation of hazardous levels of combustion products and/or inadequate oxygen levels for breathing. Odor is an inadequate warning for hazardous conditions. Occupational Exposure Guidelines Substance Nonane, all isomers Ethylmethylbenzene, all isomers Trimethylbenzenes, all isomers Naphthalene Cumene n-Propylbenzene 1, 2, 4 Trimethylbenzene Ethylbenzene Xylene, all isomers Diesel exhaust particulate MSDS No. AG2DF Revision Date Applicable Workplace Exposure Levels ACGIH (United States). TWA: 200 ppm 8 hour(s). Not available. ACGIH (United States). TWA: 25 ppm 8 hour(s). ACGIH (United States). Skin TWA: 10 ppm 8 hour(s). STEL: 15 ppm 15 minute(s). OSHA (United States). TWA: 10 ppm 8 hour(s). ACGIH (United States). TWA: 50 ppm 8 hour(s). OSHA (United States). Skin TWA: 50 ppm 8 hour(s). Not available. Not available. ACGIH (United States). TWA: 100 ppm 8 hour(s). STEL: 125 ppm 15 minute(s). OSHA (United States). TWA: 100 ppm 8 hour(s). ACGIH (United States). TWA: 100 ppm 8 hour(s). STEL: 150 ppm 15 minute(s). OSHA (United States). TWA: 100 ppm 8 hour(s). Not available. 12/31/2007 Continued on Next Page Page Number: 6 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades Benzene Toluene Middle distillates, petroleum Straight-run middle distillate (petroleum) Distillates, petroleum, light catalytic cracked Kerosene Hydrodesulfurized middle distillate (petroleum) Hydrodesulfurized Kerosine (Petroleum) Distillates, petroleum, hydrodesulfurized light catalytic cracked Diesel Fuel No. 2 ACGIH (United States). Skin TWA: 0.5 ppm 8 hour(s). STEL: 2.5 ppm 15 minute(s). OSHA (United States). Skin Notes: See Table Z-2 for exclusions in 20 CFR 1910.1028 to the PEL. TWA: 1 ppm 8 hour(s). STEL: 5 ppm 15 minute(s). ACGIH (United States). Skin TWA: 20ppm 8 hour(s). OSHA (United States). TWA: 200 ppm 8 hour(s). CEIL: 300 ppm PEAK: 500 ppm Not available. ACGIH (United States, 1998). Skin TWA: 100 mg/m 3 Not available. NIOSH REL (United States). TWA: 100 mg/m 3 8 hour(s). Not available. Not available. Not available. ACGIH TLV (United States). Skin TWA: 100 mg/m 3 8 hour(s). SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL) Physical State Liquid. Color Transparent, clear to yellow or red. Odor Characteristic, kerosene-like. Specific Gravity AP 0.84 (Water = 1) pH Not Applicable. Vapor Density AP 5 (Air = 1) Boiling Range 154º C (309º F) to 371º C (700º F) Melting/Freezing Point Not available. Vapor Pressure <0.3 kPa (<2 mm Hg) (at 20°C) Volatility 840 g/l VOC (w/v) Solubility in Water Very slightly soluble in cold water. (<0.1 % w/w) Viscosity (cSt @ 40°C) AP 3 Flash Point Closed cup: AP 52°C (AP 125°F). (Pensky-Martens.) Additional Properties Density = AP 7.0 lbs/gal. Viscosity (ASTM D2161) = 30 - 40 SUS @ 100º F SECTION 10. STABILITY AND REACTIVITY Hazardous Polymerization Not expected to occur. Chemical Stability Stable. Conditions to Avoid Keep away from all ignition sources and strong oxidizing conditions. Materials Incompatibility Strong acids, alkalies, and oxidizers such as liquid chlorine, other halogens, hydrogen peroxide and oxygen. Hazardous Decomposition Products No additional hazardous decomposition products were identified other than the combustion products identified in Section 5 of this MSDS. MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 7 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades SECTION 11. TOXICOLOGICAL INFORMATION For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this MSDS. Toxicity Data Diesel Fuel, No. 2 ORAL LD50, Acute: 12,000 to 17,500 mg/kg or 9.0 ml/kg [Rat] DERMAL LD50, Acute: >5.0 ml/kg [Rabbit screen level]. DRAIZE EYE, Acute: Mild irritant [Rabbit] DRAIZE DERMAL, Acute: Severe skin irritant [Rabbit]. BUEHLER DERMAL, Acute: Non-sensitizing [Guinea Pig] 14-Day DERMAL, Sub-chronic: 0% and 67% mortality at 4.0 and 8.0 ml/kg [Rabbit] 62-Week DERMAL, Chronic: 0.05 ml/kg 3x/week [Mouse] - Extreme skin irritation. 97-Week DERMAL, Chronic: 243 g/kg applied 3x/week [Mouse] - Extreme skin irritation. Moderate increase in contact-point skin tumors. MUTAGENICITY: Modified Ames Assay: Negative. [Salmonella typhimurium] In-vitro SCE Ovary Assay: Negative. [Chinese Hamster] In-vitro Lymphoma Assay: Negative. [Mouse] In-vivo Dominant Lethal Assay: Negative. [Mouse] In-vivo Bone Marrow Assay: Clastogenic at 2.0 ml/kg and 6.0 ml/kg [Rat] Diesel exhaust particulate: Lung tumor and lymphomas were identified in rats and mice exposed to unflitered diesel fuel exhaust in chronic inhalation studies. Further, epidemiological studies have identified increase incidences of lung cancer in US railroad workers and bladder cancer in bus and truck drivers possibly associated with exposure to diesel engine exhaust. NTP has determined that exposure to diesel exhaust particulates, a complex mixture of combustion products of diesel fuel, is reasonably anticipated to be a human carcinogen. In addition, NIOSH has identified complete diesel exhaust as a potential carcinogen. : Trimethylbenzenes, all isomers Studies of Workers: Levels of total hydrocarbon vapors present in the breathing atmosphere of these workers ranged from 10 to 60 ppm. The TCLo for humans is 10 ppm, with somnolence and respiratory tract irritation noted. Studies in Laboratory Animals: In inhalation studies with rats, four of ten animals died after exposures of 2400 ppm for 24 hours. An oral dose of 5 mL/kg resulted in death in one of ten rats. Minimum lethal intraperitoneal doses were 1.5 to 2.0 mL/kg in rats and 1.13 to 12 mL/kg in guinea pigs. Mesitylene (1, 3, 5 Trimethylbenzene) inhalation at concentrations of 1.5, 3.0, and 6.0 mg/L for six hours was associated with dose-related changes in white blood cell counts in rats. No significant effects on the complete blood count were noted with six hours per day exposure for five weeks, but elevations of alkaline phosphatase and SGOT were observed. Central nervous system depression and ataxia were noted in rats exposed to 5,100 to 9,180 ppm for two hours. Naphthalene: Studies in Humans Overexposed to Naphthalene: Severe jaundice, neurotoxicity (kernicterus) and fatalities have been reported in young children and infants as a result of hemolytic anemia from over-exposure to naphthalene. Persons with Glucose 6-phosphate dehydrogenase (G6PD) deficiency are more prone to the hemolytic effects of naphthalene. Adverse effects on the kidney have also been reported from over-exposure to naphthalene but these effects are believed to be a consequence of hemolytic anemia, and not a direct effect. Studies in Laboratory Animals: Hemolytic anemia has been observed in laboratory animals exposed to naphthalene. Laboratory rodents exposed to naphthalene vapor for 2 years (lifetime studies) developed non-neoplastic and neoplastic tumors and inflammatory lesions of the nasal and respiratory MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 8 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades tract. Cataracts and other adverse effects on the eye have been observed in laboratory animals exposed to high levels of naphthalene. Findings from a large number of bacterial and mammalian cell mutation assays have been negative. A few studies have shown chromosomal effects (elevated levels of Sister Chromatid Exchange or chromosomal aberrations) in vitro. Ethylbenzene: Effects from Acute Exposure: ORAL (LD50), Acute: 3,500 mg/kg [Rat]. DERMAL (LD50), Acute: 17,800 uL/kg [Rabbit]. INTRAPERITONEAL (LD50), Acute: 2,624 mg/kg [Rat]. Effects from Prolonged or Repeated Exposure: Findings from a 2-year inhalation study in rodents conducted by NTP were as follows: Effects were observed only at the highest exposure level (750 ppm). At this level the incidence of renal tumors was elevated in male rats (tubular carcinomas) and female rats (tubular adenomas). Also, the incidence of tumors was elevated in male mice (alveolar and bronchiolar carcinomas) and female mice (hepatocellular carcinomas). IARC has classified ethyl benzene as “possibly carcinogenic to humans” (Group 2B). Studies in laboratory animals indicate some evidence of post-implantation deaths following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate limited evidence of renal malformations, resorptions, and developmental delays following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate some evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland. Middle distillates, petroleum: Long-term repeated (lifetime) skin exposure to similar materials has been reported to result in an increase in skin tumors in laboratory rodents. The relevance of these findings to humans is not clear at this time. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Freshwater Toxicity: Concentration: 2400 ppm cephalus) Assay: TLM Concentration: >127 ppm Assay: LC50 Exposure: 48 hrs. Species: Juven. Am. Shad ( Squalius Exposure: 96 hrs. Species: Bluegill ( Lepomis macrochirus) Saltwater Toxicity Concentration: 10 ppm Exposure: 96 hrs. Species: Menhaden ( Brevoortia patronus) Assay: LC50 Concentration: 10 ppm Exposure: 96 hrs. Species: Grass Shrimp Assay: LC50 Environmental Fate If spilled, this material will normally evaporate. Hydrocarbon components may contribute to atmospheric smog. If released to the subsoils, petroleum middle distillate fuels will strongly adsorb to soils. Groundwater should be considered as an exposure pathway. Liquid and vapor can migrate through the subsurface and preferential pathways (such as utility line backfill) to downgradient receptors. Middle distillates are potentially toxic to freshwater and saltwater ecosystems. Distillate fuels will normally float on water. In stagnant or slow-flowing waterways, a hydrocarbon layer can cover a large surface area. As a result, this oil layer can limit or eliminate natural atmospheric oxygen transport into the water. With time, if not removed, oxygen depletion in the waterway can cause a fish kill or create an anaerobic environment. Also, this coating action can also kill plankton, algae, and water birds. MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 9 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades SECTION 13. DISPOSAL CONSIDERATIONS Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Maximize material recovery for reuse or recycling. Recovered non-usable material may be regulated by US EPA as a hazardous waste due to its ignitibility (D001) and/or its toxic (D018) characteristics. In addition, conditions of use may cause this material to become a hazardous waste, as defined by Federal or State regulations. It is the responsibility of the user to determine if the material is a hazardous waste at the time of disposal. Transportation, treatment, storage, and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR Parts 260 through 271). Contact your regional US EPA office for guidance concerning case specific disposal issues. State and/or local regulations might be even more restrictive. SECTION 14. TRANSPORT INFORMATION The shipping description below may not represent requirements for all modes of transportation, shipping methods or locations outside of the United States. A U.S. Department of Transportation (DOT) regulated material. The following U. S. DOT US DOT Status hazardous materials shipping description applies to bulk packaged material that is transported by highway or rail. Alternate shipping descriptions may be required for product transported by marine vessel, air or other method and for non-bulk packaged material. Proper Shipping Name Diesel Fuel, Combustible liquid, NA1993, PG III Hazard Class Reportable Quantity DOT Class: Combustible liquid with a flash Packing Group point greater than 37.8°C (100°F). UN/NA Number III NA 1993 A Reportable Quantity (RQ) has not been established for this material. Placard(s) Emergency Response Guide No. 128 MARPOL III Status Not a DOT "Marine Pollutant" per 49 CFR 171.8. SECTION 15. REGULATORY INFORMATION TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. SARA 302/304 Emergency Planning and Notification The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified. SARA 311/312 Hazard Identification The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 CFR 370.2. This material would be classified under the following hazard categories: fire, Acute (Immediate) Health Hazard, Chronic (Delayed) Health Hazard MSDS No. AG2DF Revision Date 12/31/2007 Continued on Next Page Page Number: 10 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades This product contains the following components in concentrations above de minimis levels SARA 313 Toxic that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section Chemical Notification and Release Reporting 313 of SARA: Naphthalene [CAS No.: 91-20-3] Concentration: 2% Ethylbenzene [CAS No.: 100-41-4] Concentration: 0.9% CERCLA The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center concerning release of quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product or refinery stream that may be subject to this statute are: Naphthalene [CAS No.: 91-20-3] RQ = 100 lbs. (45.36 kg) Concentration: 2% Cumene [CAS No.: 98-82-8] RQ = 5000 lbs. (2268 kg) Concentration: 0.9% Ethylbenzene [CAS No.: 100-41-4] RQ = 1000 lbs. (453.6 kg) Concentration: 0.9% Xylene, all isomers [CAS No.: 1330-20-7] RQ = 100 lbs. (45.36 kg) Concentration: 0.9% Benzene [CAS No.: 71-43-2] RQ = 10 lbs. (4.536 kg) Concentration: 0.045% Clean Water Act (CWA) This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. California Proposition 65 This material may contain the following components which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Diesel exhaust particulate Naphthalene: <2% Ethylbenzene: <1% Toluene: <0.1% Benzene: <0.1% New Jersey Right-to-Know Label Diesel Fuel Additional Remarks As minimum requirements, CITGO recommends that the following advisory information be displayed on equipment used to dispense diesel fuel. Additional warnings specified by various regulatory authorities may be required: " Diesel Fuel DANGER: Combustible Liquid. Use as a Motor Fuel Only. DO NOT FILL CONTAINERS THAT HAVE PREVIOUSLY CONTAINED GASOLINE OR OTHER FLAMMABLE LIQUIDS. Sparks From static electricity can ignite flammable vapor residues. PLACE CONTAINER ON GROUND. DO NOT FILL ANY PORTABLE CONTAINER IN OR ON A VEHICLE. Containers must be metal or other material approved for storing diesel fuel. Keep nozzle spout in contact with the container during the entire filling operation. NO SMOKING! Do not leave nozzle unattended during filling. HARMFUL OR FATAL IF SWALLOWED.If swallowed, do not induce vomiting. Call Physician Immediately. Keep Out of Reach of Children. Avoid prolonged breathing of vapors. Never siphon by mouth. Do not store in vehicle or living space. Store and use in a well ventilated area. Do not use near heat, spark or flame. Keep container closed." SECTION 16. OTHER INFORMATION Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product. REVISION INFORMATION 5.1 12/31/2007 Version Number Revision Date ABBREVIATIONS AP: Approximately MSDS No. AG2DF EQ: Equal >: Greater Than Revision Date <: Less Than 12/31/2007 NA: Not Applicable ND: No Data Continued on Next Page NE: Not Establishe Page Number: 11 CITGO No. 2 Diesel Fuel, Low Sulfur, All Grades ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association IARC: International Agency for Research on Cancer NTP: National Toxicology Program NIOSH: National Institute of Occupational Safety and Health OSHA: Occupational Safety and Health Administration NPCA: National Paint and Coating Manufacturers Association HMIS: Hazardous Materials Information System NFPA: National Fire Protection Association EPA: US Environmental Protection Agency DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. ***** END OF MSDS ***** CITGO Gasolines, All Grades Unleaded Material Safety Data Sheet CITGO Petroleum Corporation P.O. Box 4689 Houston, TX 77210 MSDS No. UNLEAD Revision Date 10/14/2008 IMPORTANT: This MSDS is prepared in accordance with 29 CFR 1910.1200. Read this MSDS before transporting, handling, storing or disposing of this product and forward this information to employees, customers and users of this product. Emergency Overview Physical State Liquid. Transparent, clear to Color amber or red. Odor Pungent, characteristic gasoline. Hazard Rankings HMIS NFPA 2 1 Fire Hazard 3 3 Reactivity 0 0 Health Hazard * * = Chronic Health Hazard DANGER: Extremely flammable liquid; vapor may cause flash fire or explosion. Vapor may travel considerable distance to source of ignition and flash back. Use Only as a Motor Fuel. Do Not Siphon by Mouth. Harmful or fatal if swallowed - Can enter lungs and cause damage. High concentrations of vapor reduce oxygen available for breathing and may cause suffocation. May be harmful if inhaled or absorbed through the skin. Mist or vapor may irritate the eyes, mucous membranes, and respiratory tract. Liquid contact may cause eye and skin irritation. Overexposures may cause central nervous system (CNS) depression and target organ effects (See Section 3). Harmful or fatal if swallowed - Can enter lung and cause damage. Inhalation overexposure can increase the heart’s susceptibility to arrhythmias (irregular beats). Contains Benzene - Cancer Hazard. Long term exposure to gasoline vapor has caused cancer in laboratory animals. Avoid Spills. Spills may present both a physical and an environmental hazard. Protective Equipment Minimum Recommended See Section 8 for Details SECTION 1. PRODUCT IDENTIFICATION Trade Name CITGO Gasolines, All Grades Unleaded Technical Contact (832) 486-5940 Product Number Various Medical Emergency (832) 486-4700 CAS Number Mixture. CHEMTREC Emergency (United States Only) (800) 424-9300 Product Family Motor fuels. MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 1 CITGO Gasolines, All Grades Unleaded Synonyms Unleaded Gasolines; Conventional Unleaded Gasoline with Ethanol; Unleaded Gasoline with Ethanol; Reformulated Unleaded Gasoline with Ethanol; Motor Gasolines; Petrol; Automobile Motor Fuels; Finished Gasolines; Gasoline, Regular Unleaded; Gasoline, Mid-grade Unleaded; Gasoline, Premium Unleaded; Reformulated Gasolines (RFG); Reformulated Motor Fuels; Oxygenated Motor Spirits; Gasoline, Regular Reformulated; Gasoline, Mid-grade Reformulated; Gasoline, Premium Reformulated; CBOB; RBOB; GTAB; Clean Burning Gasoline (CBG); CARB Gasoline with Ethanol. SECTION 2. COMPOSITION Gasoline is a complex and variable mixture that originates from finished refinery streams. These streams can contain the components listed below that are regulated or are associated with certain potential health effects. The typical concentration of ethanol in gasoline does not exceed 10% (v/v). Concentration (%) Component Name(s) CAS Registry No. Toluene 108-88-3 <25 Pentanes, all isomers Mixture <20 Octanes, all isomers Mixture <20 Xylene, all isomers 1330-20-7 <18 Hexane, other isomers Mixture <15 Heptane, all isomers 142-82-5 <15 Ethanol 64-17-5 <10 n-Hexane 110-54-3 <8 Benzene 71-43-2 <5 Trimethylbenzenes, all isomers 25551-13-7 <5 2,2,4-Trimethylpentane 540-84-1 <5 Cumene 98-82-8 <4 Ethylbenzene 100-41-4 <4 1, 2, 4 Trimethylbenzene 95-63-6 <3 Cyclohexane 110-82-7 <3 Cyclopentane 287-92-3 <2 Naphthalene 91-20-3 <2 Styrene 100-42-5 <1 SECTION 3. HAZARDS IDENTIFICATION Also see Emergency Overview and Hazard Ratings on the top of Page 1 of this MSDS. Major Route(s) of Entry Skin contact. Eye contact. Inhalation. Ingestion. Signs and Symptoms of Acute Exposure Inhalation Breathing high concentrations may be harmful. Mist or vapor can irritate the throat and lungs. Breathing this material may cause central nervous system depression with symptoms including nausea, headache, dizziness, fatigue, drowsiness, or unconsciousness. Breathing high concentrations of this material, for example, in an enclosed space or by intentional abuse, can cause irregular heartbeats which can cause death. Eye Contact This product can cause eye irritation with short-term contact with liquid, mists or vapor. Symptoms include stinging, watering, redness, and swelling. In severe cases, permanent eye damage can result. Skin Contact This material can cause skin irritation. The severity of irritation will depend on the amount of material that is applied to the skin and the speed and thoroughness that it is removed. It is likely that some components of this material are able to pass into the body through the skin and may cause similar effects as from breathing or swallowing it. If the skin is damaged or abraded, absorption increases. Ingestion MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 2 CITGO Gasolines, All Grades Unleaded If swallowed, this material may irritate the mucous membranes of the mouth, throat, and esophagus. It can be readily absorbed by the stomach and intestinal tract. Symptoms include a burning sensation of the mouth and esophagus, nausea, vomiting, dizziness, staggered gait, drowsiness, loss of consciousness and delirium, as well as additional central nervous system (CNS) effects. Due to its light viscosity, there is a danger of aspiration into the lungs during swallowing and subsequent vomiting. Aspiration can result in severe lung damage or death. Cardiovascular effects include shallow rapid pulse with pallor (loss of color in the face) followed by flushing (redness of the face). Also, progressive CNS depression, respiratory insufficiency and ventricular fibrillation leads to death. Chronic Health Effects Intentional misuse by deliberately concentrating and inhaling gasoline can be harmful or fatal. Altered mental state, drowsiness, peripheral motor neuropathy, irreversible brain damage Summary ("Petrol Sniffers Encephalopathy"), delirium, seizures and sudden death are associated with repeated abuse of gasoline or naphtha. Chronic effects of ingestion and subsequent aspiration into the lungs may include pneumatocele (lung cavity) formation and chronic lung dysfunction. Benzene, a component of this product, is associated with blood disorders and may damage bone marrow, causing certain types of anemia. The International Agency for Research on Cancer (IARC) (1987, 2004, 2007) and the U.S. EPA (IRIS 2007) have determined that benzene is a human carcinogen. It is also capable of causing changes in living cells' genetic material (chromosomes) and is considered to be a mutagen. Repeated and prolonged overexposure to n-hexane has been associated with peripheral nerve tissue damage. Adverse effects include numbness, tingling, pain, and loss of muscle control in the extremities, disorientation, impaired vision and reflexes, decline in motor function and paralysis. Prolonged or repeated overexposure to toluene, a component of this product, has been associated with reproductive effects in experimental animals and in long-term chemical abuse situations. Long-term overexposure to toluene has been associated with impaired color vision. Also, long-term overexposure to toluene in occupational environments have been associated with hearing damage. Prolonged or repeated overexposure to xylene, a component of this product, has been associated with hearing damage in laboratory animals. Repeated overexposure may cause injury to bone marrow, blood cells, kidney, and liver. Refer to Section 11 of this MSDS for additional health-related information. Conditions Aggravated Disorders of the following organs or organ systems that may be aggravated by significant exposure to this material or its components include: Skin, Respiratory System, Liver, by Exposure Kidneys, Central Nervous System (CNS), Cardiovascular System, Blood-forming system. Target Organs May cause damage to the following organs: blood, kidneys, lungs, the reproductive system, liver, mucous membranes, heart, peripheral nervous system, cardiovascular system, upper respiratory tract, skin, auditory system, bone marrow, central nervous system (CNS), eye, lens or cornea Carcinogenic Potential This material may contain benzene, ethylbenzene, naphthalene or styrene at concentrations above 0.1%. Benzene is considered to be a known human carcinogen by OSHA, IARC and NTP. IARC has identified ethylbenzene, styrene, naphthalene, gasoline and gasoline engine exhaust as possibly carcinogenic to humans (Group 2B) based on laboratory animal studies. MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 3 CITGO Gasolines, All Grades Unleaded OSHA Hazard Classification is indicated by an "X" in the box adjacent to the hazard title. If no "X" is present, the product does not exhibit the hazard as defined in the OSHA Hazard Communication Standard (29 CFR 1910.1200). OSHA Physical Hazard Classification OSHA Health Hazard Classification Sensitizer Combustible Toxic Highly Toxic Flammable Corrosive Carcinogenic Irritant X X X Compressed Gas Explosive Pyrophoric Oxidizer Water-reactive Organic Peroxide Unstable SECTION 4. FIRST AID MEASURES Take proper precautions to ensure your own health and safety before attempting rescue or providing first aid. For more specific information, refer to Exposure Controls and Personal Protection in Section 8 of this MSDS. Inhalation Immediately move victim to fresh air. If victim is not breathing, immediately begin rescue breathing. If heart has stopped, immediately begin cardiopulmonary resuscitation (CPR). If breathing is difficult, 100 percent humidified oxygen should be administered by a qualified individual. Seek medical attention immediately. If exposed to benzene in an emergency situation, a medical evaluation should be completed at the end of the work-shift in accordance with OSHA requirements. Eye Contact Flush eyes with cool, clean, low-pressure water for at least 15 minutes. Hold eyelids apart to ensure complete irrigation of the eye and eyelid tissue. If easily accomplished, check for and remove contact lenses. If contact lenses cannot be removed, seek immediate medical attention. Do not use eye ointment. Seek medical attention. Skin Contact Remove contaminated shoes and clothing. Flush affected area with large amounts of water. If skin surface is damaged, apply a clean dressing and seek medical attention. Do not use ointments. If skin surface is not damaged, clean affected area thoroughly with mild soap and water. Seek medical attention if tissue appears damaged or if pain or irritation persists. Ingestion Do not induce vomiting. If spontaneous vomiting is about to occur, place victim’s head below knees. If victim is drowsy or unconscious, place on the left side with head down. Never give anything by mouth to a person who is not fully conscious. Do not leave victim unattended. Seek medical attention immediately. Notes to Physician INHALATION: Inhalation overexposure can produce toxic effects. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for upper respiratory tract inflammation, bronchitis, and pneumonitis. Administer supplemental oxygen with assisted ventilation, as required. This material (or a component) sensitizes the heart to the effects of sympathomimetic amines. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in individuals exposed to this material. Administration of sympathomimetic drugs should be avoided. INGESTION: If ingested, this material presents a significant aspiration and chemical pneumonitis hazard. Induction of emesis is not recommended. Consider activated charcoal and/or gastric lavage. If patient is obtunded, protect the airway by cuffed endotracheal intubation or by placement of the body in a Trendelenburg and left lateral decubitus position. SECTION 5. FIRE FIGHTING MEASURES NFPA Flammability Classification NFPA Class-IB flammable liquid. Flash Point Closed cup: -43°C (-45°F). (Tagliabue [ASTM D-56]) Lower Flammable Limit AP 1.4 % MSDS No. UNLEAD Revision Date Upper Flammable Limit AP 7.6 % 10/14/2008 Continued on Next Page Page Number: 4 CITGO Gasolines, All Grades Unleaded Autoignition Temperature AP 280°C (536°F) Hazardous Combustion Carbon dioxide, carbon monoxide, smoke, fumes, unburned hydrocarbons, aldehydes and Products other products of incomplete combustion. Special Properties Flammable Liquid! This material releases vapors at or below ambient temperatures. When mixed with air in certain proportions and exposed to an ignition source, its vapor can cause a flash fire. Use only with adequate ventilation. Vapors are heavier than air and may travel long distances along the ground to an ignition source and flash back. A vapor and air mixture can create an explosion hazard in confined spaces such as sewers. If container is not properly cooled, it can rupture in the heat of a fire. Extinguishing Media SMALL FIRE: Use dry chemicals, carbon dioxide, foam, or inert gas (nitrogen). Carbon dioxide and inert gas can displace oxygen. Use caution when applying carbon dioxide or inert gas in confined spaces. LARGE FIRE: Use foam, water fog, or water spray. Water may be ineffective. Water may not extinguish the fire. Water fog and spray are effective in cooling containers and adjacent structures. However, water can be used to cool the external walls of vessels to prevent excessive pressure, autoignition or explosion. DO NOT use a solid stream of water directly on the fire as the water may spread the fire to a larger area. Protection of Fire Fighters Firefighters must use full bunker gear including NIOSH-approved positive pressure self-contained breathing apparatus to protect against potential hazardous combustion or decomposition products and oxygen deficiencies. Evacuate area and fight the fire from a maximum distance or use unmanned hose holders or monitor nozzles. Cover pooling liquid with foam. Containers can build pressure if exposed to radiant heat; cool adjacent containers with flooding quantities of water until well after the fire is out. Withdraw immediately from the area if there is a rising sound from a venting safety device or discoloration of vessels, tanks, or pipelines. Be aware that burning liquid will float on water. Notify appropriate authorities of potential fire and explosion hazard if liquid enter sewers or waterways. SECTION 6. ACCIDENTAL RELEASE MEASURES Take proper precautions to ensure your own health and safety before attempting spill control or clean-up. For more specific information, refer to the Emergency Overview on Page 1, Exposure Controls and Personal Protection in Section 8 and Disposal Considerations in Section 13 of this MSDS. Flammable Liquid! Release causes an immediate fire or explosion hazard. Evacuate all non-essential personnel from immediate area and establish a "regulated zone" with site control and security. A vapor-suppressing foam may be used to reduce vapors. Eliminate all ignition sources. All equipment used when handling this material must be grounded. Stop the leak if it can done without risk. Do not touch or walk through spilled material. Remove spillage immediately from hard, smooth walking areas. Prevent spilled material from entering waterways, sewers, basements, or confined areas. Absorb or cover with dry earth, sand, or other non-combustible material and transfer to appropriate waste containers. Use clean, non-sparking tools to collect absorbed material. For large spills, secure the area and control access. Prevent spilled material from entering sewers, storm drains, other drainage systems, and natural waterways. Dike far ahead of a liquid spill to ensure complete collection. Water mist or spray may be used to reduce or disperse vapors; but, it may not prevent ignition in closed spaces. This material will float on water and its run-off may create an explosion or fire hazard. Verify that responders are properly HAZWOPER-trained and wearing appropriate respiratory equipment and fire-resistant protective clothing during cleanup operations. In an urban area, cleanup spill as soon as possible; in natural environments, cleanup on advice from specialists. Pick up free liquid for recycle and/or disposal if it can be accomplished safely with explosion-proof equipment. Collect any excess material with absorbant pads, sand, or other inert non-combustible absorbent materials. Place into appropriate waste containers for later disposal. Comply with all applicable local, state and federal laws and regulations. MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 5 CITGO Gasolines, All Grades Unleaded SECTION 7. HANDLING AND STORAGE FLAMMABLE LIQUID AND VAPOR. USE ONLY as a motor fuel. DO NOT siphon by mouth. DO NOT use as a lighter fluid, solvent or cleaning fluid. Prior to handling or refueling, stop all engines and auxillary equipment. Turn off all electronic equipment including cellular telephones. DO NOT leave nozzle unattended during filling or refueling a vehicle. DO NOT re-enter vehicle while refueling. Keep nozzle spout in contact with the container during the entire filling operations. Handling A static electrical charge can accumulate when this material is flowing through pipes, nozzles or filters and when it is agitated. A static spark discharge can ignite accumulated vapors particularly during dry weather conditions. Always bond receiving containers to the fill pipe before and during loading, following NFPA-704 and /or API RP 2003 requirements. Always keep nozzle in contact with the container throughout the loading process. Do not fill any portable container in or on a vehicle. Special precautions, such as reduced loading rates and increased monitoring, must be observed during "switch loading" operations (i.e., loading this material in tanks or shipping compartments that previously contained middle distillates or similar products). A spill or leak can cause an immediate fire or explosion hazard. Keep containers closed and do not handle or store near heat, sparks, or any other potential ignition sources. Avoid contact with oxidizing agents. Do NOT breathe vapor. Use only with adequate ventilation and personal protection. Never siphon by mouth. Avoid contact with eyes, skin, and clothing. Prevent contact with food and tobacco products. Do NOT take internally. When performing repairs and maintenance on contaminated equipment, keep unnecessary persons away from the area. Eliminate all potential ignition sources. Drain and purge equipment, as necessary, to remove material residues. Follow proper entry procedures, including compliance with 29 CFR 1910.146 prior to entering confined spaces such as tanks or pits. Use gloves constructed of impervious materials and protective clothing if direct contact is anticipated. Use appropriate respiratory protection when concentrations exceed any established occupational exposure level (See Section 8) Promptly remove contaminated clothing. Wash exposed skin thoroughly with soap and water after handling. Non-equilibrium conditions may increase the fire hazard associated with this product. A static electrical charge can accumulate when this material is flowing through pipes, nozzles or filters and when it is agitated. A static spark discharge can ignite accumulated vapors particularly during dry weather conditions. Always bond receiving containers to the fill pipe before and during loading. Always confirm that receiving container is properly grounded. Bonding and grounding alone may be inadequate to eliminate fire and explosion hazards associated with electrostatic charges. Carefully review operations that may increase the risks associated with static electricity such as tank and container filling, tank cleaning, sampling, gauging, loading, filtering, mixing, agitation, etc. In addition to bonding and grounding, efforts to mitigate the hazards of an electrostatic discharge may include, but are not limited to, ventilation, inerting and/or reduction of transfer velocities. Dissipation of electrostatic charges may be improved with the use of conductivity additives when used with other mitigation efforts, including bonding and grounding. Always keep nozzle in contact with the container throughout the loading process. Do NOT fill any portable container in or on a vehicle. Do NOT use compressed air for filling, discharging or other handling operations. Product container is NOT designed for elevated pressure. Do NOT pressurize, cut, weld, braze solder, drill, or grind on containers. Do NOT expose product containers to flames, sparks, heat or other potential ignition sources. Empty containers may contain material residues which can ignite with explosive force. Observe label precautions. Protect the environment from releases of this material. Prevent discharges to surface waters and groundwater. Maintain handling, transfer and storage equipment in proper working order. Misuse of empty containers can be dangerous. Empty containers may contain material residues which can ignite with explosive force. Cutting or welding of empty containers MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 6 CITGO Gasolines, All Grades Unleaded can cause fire, explosion, or release of toxic fumes from residues. Do not pressurize or expose empty containers to open flame, sparks, or heat. Keep container closed and drum bungs in place. All label warnings and precautions must be observed. Return empty drums to a qualified reconditioner. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling, or disposing of empty containers and/or waste residues of this material. Keep container tightly closed. Store in a cool, dry, well-ventilated area. Store only in approved containers. Do not store with oxidizing agents. Do not store at elevated temperatures or in direct sunlight. Protect containers against physical damage. Head spaces in tanks and other containers may contain a mixture of air and vapor in the flammable range. Vapor may be ignited by static discharge. Storage area must meet OSHA requirements and applicable fire codes. Additional information regarding the design and control of hazards associated with the handling and storage of flammable and combustible liquids may be found in professional and industrial documents including, but not limited to, the National Fire Protection Association (NFPA) publications NFPA 30 ("Flammable and Combustible Liquid Code"), NFPA 77 ("Recommended Practice on Static Electricity") and the American Petroleum Institute (API) Recommended Practice 2003, (“Protection Against Ignitions Arising Out of Static, Lightning, and Stray Currents"). Storage Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling or disposing of empty containers or waste residues of this product. SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Engineering Controls Provide ventilation or other engineering controls to keep the airborne concentrations of vapor or mists below the applicable workplace exposure limits indicated below. All electrical equipment should comply with the National Electrical Code. An emergency eye wash station and safety shower should be located near the work-station. Personal Protective Equipment Personal protective equipment should be selected based upon the conditions under which this material is used. A hazard assessment of the work area for PPE requirements should be conducted by a qualified professional pursuant to OSHA regulations. The following pictograms represent the minimum requirements for personal protective equipment. For certain operations, additional PPE may be required. Eye Protection Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. Chemical goggles should be worn during transfer operations or when there is a likelihood of misting, splashing, or spraying of this material. A suitable emergency eye wash water and safety shower should be located near the work station. Hand Protection Avoid skin contact. Use gloves (e.g., disposable PVC, neoprene, nitrile, vinyl, or PVC/NBR). Wash hands with plenty of mild soap and water before eating, drinking, smoking, use of toilet facilities or leaving work. DO NOT use this material as a skin cleaner. Avoid skin contact. Wear long-sleeved fire-retardant garments (e.g., Nomex®) while working with flammable and combustible liquids. Additional chemical-resistant protective gear may be required if splashing or spraying conditions exist. This may include an apron, boots and additional facial protection. If product comes in contact with clothing, immediately remove soaked clothing and shower. Promptly remove and discard contaminated leather goods. Body Protection MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 7 CITGO Gasolines, All Grades Unleaded Respiratory Protection For known vapor concentrations above the occupational exposure guidelines (see below), use a NIOSH-approved organic vapor respirator if adequate protection is provided. Protection factors vary depending upon the type of respirator used. Respirators should be used in accordance with OSHA requirements (29 CFR 1910.134). For airborne vapor concentrations that exceed the recommended protection factors for organic vapor respirators, use a full-face, positive-pressure, supplied air respirator. Due to fire and explosion hazards, do not enter atmospheres containing concentrations greater than 10% of the lower flammable limit of this product. General Comments Warning! Use of this material in spaces without adequate ventilation may result in generation of hazardous levels of combustion products and/or inadequate oxygen levels for breathing. Odor is an inadequate warning for hazardous conditions. Occupational Exposure Guidelines Substance Gasoline Applicable Workplace Exposure Levels ACGIH (United States). TWA: 300 ppm 8 hour(s). STEL: 500 ppm 15 minute(s). ACGIH (United States). TWA: 600 ppm 8 hour(s). OSHA (United States). TWA: 1000 ppm 8 hour(s). ACGIH (United States). TWA: 300 ppm 8 hour(s). OSHA (United States). TWA: 500 ppm 8 hour(s). ACGIH (United States). Skin TWA: 20 ppm 8 hour(s). OSHA (United States). TWA: 200 ppm 8 hour(s). CEIL: 300 ppm PEAK: 500 ppm 1 times per shift, 10 minute(s). ACGIH (United States). TWA: 500 ppm 8 hour(s). STEL: 1000 ppm 15 minute(s). ACGIH (United States). TWA: 400 ppm 8 hour(s). STEL: 500 ppm 15 minute(s). OSHA (United States). TWA: 500 ppm 8 hour(s). ACGIH (United States). TWA: 100 ppm 8 hour(s). STEL: 150 ppm 15 minute(s). OSHA (United States). TWA: 100 ppm 8 hour(s). ACGIH (United States). TWA: 1000 ppm 8 hour(s). OSHA (United States). TWA: 1000 ppm 8 hour(s). ACGIH (United States). Skin TWA: 0.5 ppm 8 hour(s). STEL: 2.5 ppm 15 minute(s). OSHA (United States). Skin Notes: See Table Z-2 for exclusions in 20 CFR 1910.1028 to the PEL. TWA: 1 ppm 8 hour(s). STEL: 5 ppm 15 minute(s). ACGIH (United States). Skin TWA: 50 ppm 8 hour(s). OSHA (United States). TWA: 500 ppm 8 hour(s). ACGIH (United States). TWA: 50 ppm 8 hour(s). OSHA (United States). Skin Pentanes, all isomers Octanes, all isomers Toluene Hexane, other isomers Heptane, all isomers Xylene, all isomers Ethanol Benzene n-Hexane Cumene MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 8 CITGO Gasolines, All Grades Unleaded TWA: 50 ppm 8 hour(s). ACGIH (United States). TWA: 25 ppm 8 hour(s). ACGIH (United States). TWA: 100 ppm 8 hour(s). STEL: 125 ppm 15 minute(s). OSHA (United States). TWA: 100 ppm 8 hour(s). ACGIH (United States). TWA: 100 ppm 8 hour(s). OSHA (United States). TWA: 300 ppm 8 hour(s). ACGIH (United States). TWA: 600 ppm 8 hour(s). ACGIH (United States). Skin TWA: 10 ppm 8 hour(s). STEL: 15 ppm 15 minute(s). OSHA (United States). TWA: 10 ppm 8 hour(s). ACGIH (United States). TWA: 20 ppm 8 hour(s). STEL: 40 ppm 15 minute(s). OSHA (United States). TWA: 100 ppm 8 hour(s). STEL: 200 ppm 15 minute(s). PEAK: 600 ppm Trimethylbenzenes, all isomers Ethylbenzene Cyclohexane Cyclopentane Naphthalene Styrene SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES (TYPICAL) Pungent, characteristic gasoline. 3 to 4 (Air = 1) Physical State Liquid. Color Transparent, clear to amber or red. Odor Specific Gravity 0.72 - 0.77 (Water = 1) pH Not applicable Vapor Density Boiling Range 38 to 204°C (100 to 400°F) Melting/Freezing Point Not available. Vapor Pressure 220 to 450 mm Hg at 20°C (68°F ) or 6 to 15 Reid-psia at 37.8°C (100°F). Volatility 720 to 770 g/l VOC (w/v) Solubility in Water Very slightly soluble in cold water. (<0.1 % w/w) Viscosity (cSt @ 40°C) <1 Flash Point Closed cup: -43°C (-45°F). (Tagliabue [ASTM D-56]) Additional Properties Average Density at 60°F = 6.0 to 6.4 lbs./gal. (ASTM D-2161) SECTION 10. STABILITY AND REACTIVITY Hazardous Polymerization Not expected to occur. Chemical Stability Stable. Conditions to Avoid Keep away from heat, flame and other potential ignition sources. Keep away from strong oxidizing conditions and agents. Materials Incompatibility Strong acids, alkalies and oxidizers such as liquid chlorine, other halogens, hydrogen peroxide and oxygen. Hazardous Decomposition Products No additional hazardous decomposition products were identified other than the combustion products identified in Section 5 of this MSDS. MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 9 CITGO Gasolines, All Grades Unleaded SECTION 11. TOXICOLOGICAL INFORMATION For other health-related information, refer to the Emergency Overview on Page 1 and the Hazards Identification in Section 3 of this MSDS. Toxicity Data Gasoline: VAPOR (TELo) Acute: 140 ppm (Human) (8 hours) - Mild eye irritant. VAPOR (TELo) Acute: 500 ppm (Human) (1 hour) - Moderate eye irritant. INHALATION (TCLo) Acute: 900 ppm (Human) (1 hour) - CNS and pulmonary effects. DERMAL (TDLo) Acute: 53 mg/kg (Human) - Skin allergy effects. INHALATION (LC50) Acute: 101,200 ppm (Rat, Mouse, & Guinea Pig) (5 minutes). A major epidemiological study concluded that there was no increased risk of kidney cancer associated with gasoline exposures for petroleum refinery employees or neighboring residents. Another study identified a slight trend in kidney cancers among service station employees following a 30-year latency period. Two-year inhalation toxicity studies with fully vaporized unleaded gasoline (at concentrations of 67, 292 and 2,056 ppm in air) produced kidney damage and kidney tumors in male rats, but not in female rats or mice of either sex. Results from subsequent scientific studies suggest that the kidney damage, and probably the kidney tumor response, is limited to the male rat. The kidney tumors apparently were the result of the formation of alpha-2u-globulin, a protein unique to male rats. This finding is not considered relevant to human exposure. Under conditions of the study, there was no evidence that exposure to unleaded gasoline vapor is associated with developmental toxicity. Experimental studies with laboratory animals did suggest that overexposure to gasoline may adversely effect male reproductive performance. Also, in laboratory studies with rats, the maternal and developmental "no observable adverse effect level" (NOAEL) was determined to be 9,000 ppm (75% of the LEL value). Female mice developed a slightly higher incidence of liver tumors compared to controls at the highest concentration. In a four week inhalation study of Sprague Dawley® rats, gasoline vapor condensate was determined to induce sister chromatid exchanges in peripheral lymphocytes. IARC has listed gasoline as possibly carcinogenic to humans (Group 2B). Pentanes, all isomers: Studies of pentane isomers in laboratory animals indicate exposure to extremely high levels (roughly 10 vol.%) may induce cardiac arrhythmias (irregular heartbeats) which may be serious or fatal. Toluene: Effects from Acute Exposure: Deliberate inhalation of toluene at high concentrations (e.g., glue sniffing and solvent abuse) has been associated with adverse effects on the liver, kidney and nervous system and can cause CNS depression, cardiac arrhythmias and death. Case studies of persons abusing toluene suggest isolated incidences of adverse effects on the fetus including birth defects. Effects from Repeated or Prolonged Exposure: Studies of workers indicate long-term exposure may be related to impaired color vision and hearing. Some studies of workers suggest long-term exposure may be related to neurobehavioral and cognitive changes. Some of these effects have been observed in laboratory animals following repeated exposure to high levels of toluene. Several studies of workers suggest long-term exposure may be related to small increases in spontaneous abortions and changes in some gonadotropic hormones. However, the weight of evidence does not indicate toluene is a reproductive hazard to humans. Studies in laboratory animals indicate some changes in reproductive organs following high levels of exposure, but no significant effects on mating performance or reproduction were observed. Case studies of persons abusing toluene suggest isolated incidences of adverse effects on the fetus including birth defects. Findings in laboratory animals were largely negative. Positive findings include small increases in minor skeletal and visceral malformations and developmental delays following very high levels of maternal exposure. Studies of workers indicate long-term exposure may be related to effects on the liver, kidney and blood, but these appear to be limited to changes in serum enzymes and decreased leukocyte counts. Studies in laboratory MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 10 CITGO Gasolines, All Grades Unleaded animals indicate some evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland following very high levels of exposure. The relevance of these findings to humans is not clear at this time. Heptane, all isomers: n-Heptane was not mutagenic in the Salmonella/microsome (Ames) assay and is not considered to be carcinogenic. Xylene, all isomers: Effects from Acute Exposure: ORAL (LD 50), Acute: 4,300 mg/kg [Rat]. INHALATION (LC 50), Acute: 4,550 ppm for four hours [Rat]. DERMAL (LD 50), Acute: 14,100 uL/kg [Rabbit]. Overexposure to xylene may cause upper respiratory tract irritation, headache, cyanosis, blood serum changes, CNS damage and narcosis. Effects may be increased by the use of alcoholic beverages. Evidence of liver and kidney impairment were reported in workers recovering from a gross over-exposure. Effects from Prolonged or Repeated Exposure: Impaired neurological function was reported in workers exposed to solvents including xylene. Studies in laboratory animals have shown evidence of impaired hearing following high levels of exposure. Studies in laboratory animals suggest some changes in reproductive organs following high levels of exposure but no significant effects on reproduction were observed. Studies in laboratory animals indicate skeletal and visceral malformations, developmental delays, and increased fetal resorptions following extremely high levels of maternal exposure. Adverse effects on the liver, kidney, bone marrow (changes in blood cell parameters) were observed in laboratory animals following high levels of exposure. The relevance of these observations to humans is not clear at this time. Ethanol: Inhalation exposure to ethanol vapor at concentrations above applicable workplace exposure levels is expected to produce eye and mucus membrane irritation. Human exposure at concentrations from 1000 to 5000 ppm produced symptoms of narcosis, stupor and unconsciousness. Subjects exposed to ethanol vapor in concentrations between 500 and 10,000 ppm experienced coughing and smarting of the eyes and nose. At 15,000 ppm there was continuous lacrimation and coughing. While extensive acute and chronic effects can be expected with ethanol consumption, ingestion is not expected to be a significant route of exposure to this product. Benzene: ORAL (LD50): INHALATION (LC50): (VAPOR): Acute: 930 mg/kg [Rat]. 4700 mg/kg [Mouse]. Acute: 10000 ppm 7 hour(s) [Rat]. 9980 ppm 8 hour(s) [Mouse]. Studies of Workers Over-Exposed to Benzene: Studies of workers exposed to benzene show clear evidence that over-exposure can cause cancer of the blood forming organs (acute myelogenous leukemia) and aplastic anemia, an often fatal disease. Studies also suggest over-exposure to benzene may be associated with other types of leukemia and other blood disorders. Some studies of workers exposed to benzene have shown an association with increased rates of chromosome aberrations in circulating lymphocytes. One study of women workers exposed to benzene suggested a weak association with irregular menstruation. However, other studies of workers exposed to benzene have not demonstrated clear evidence of an effect on fertility or reproductive outcome in humans. Benzene can cross the placenta and affect the developing fetus. Cases of aplastic anemia have been reported in the offspring of persons severely over-exposed to benzene. Studies in Laboratory Animals: Studies in laboratory animals indicate that prolonged, repeated exposure to high levels of benzene vapor can cause bone marrow suppression and cancer in multiple organ systems. Studies in laboratory animals show evidence of adverse effects on male reproductive organs following high levels of exposure but no significant effects on reproduction have been observed. Embryotoxicity has been reported in studies of laboratory animals but effects were MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 11 CITGO Gasolines, All Grades Unleaded limited to reduced fetal weight and skeletal variations. n-Hexane: This material contains n-hexane. Long-term or repeated exposure to n-hexane can cause permanent peripheral nerve damage. Initial symptoms are numbness of the fingers and toes. Also, motor weakness can occur in the digits, but may also involve muscles of the arms, thighs and forearms. The onset of these symptoms may be delayed for several months to a year after the beginning of exposure. Co-exposure to methylethyl ketone or methyl isobutyl ketone increases the neurotoxic properties of n-hexane. In laboratory studies, prolonged exposure to elevated concentrations of n-hexane was associated with decreased sperm count and degenerative changes in the testicles of rats. Cumene: Effects from Acute Exposure: Overexposure to cumene may cause upper respiratory tract irritation and severe CNS depression. Effects from Prolonged or Repeated Exposure: Studies in laboratory animals indicate evidence of adverse effects on the kidney and adrenal glands following high level exposure. The relevance of these findings to humans is not clear at this time. : Trimethylbenzenes, all isomers Studies of Workers: Levels of total hydrocarbon vapors present in the breathing atmosphere of these workers ranged from 10 to 60 ppm. The TCLo for humans is 10 ppm, with somnolence and respiratory tract irritation noted. Studies in Laboratory Animals: In inhalation studies with rats, four of ten animals died after exposures of 2400 ppm for 24 hours. An oral dose of 5 mL/kg resulted in death in one of ten rats. Minimum lethal intraperitoneal doses were 1.5 to 2.0 mL/kg in rats and 1.13 to 12 mL/kg in guinea pigs. Mesitylene (1, 3, 5 Trimethylbenzene) inhalation at concentrations of 1.5, 3.0, and 6.0 mg/L for six hours was associated with dose-related changes in white blood cell counts in rats. No significant effects on the complete blood count were noted with six hours per day exposure for five weeks, but elevations of alkaline phosphatase and SGOT were observed. Central nervous system depression and ataxia were noted in rats exposed to 5,100 to 9,180 ppm for two hours. Ethylbenzene: Effects from Acute Exposure: ORAL (LD50), Acute: 3,500 mg/kg [Rat]. DERMAL (LD50), Acute: 17,800 uL/kg [Rabbit]. INTRAPERITONEAL (LD50), Acute: 2,624 mg/kg [Rat]. Effects from Prolonged or Repeated Exposure: Findings from a 2-year inhalation study in rodents conducted by NTP were as follows: Effects were observed only at the highest exposure level (750 ppm). At this level the incidence of renal tumors was elevated in male rats (tubular carcinomas) and female rats (tubular adenomas). Also, the incidence of tumors was elevated in male mice (alveolar and bronchiolar carcinomas) and female mice (hepatocellular carcinomas). IARC has classified ethyl benzene as “possibly carcinogenic to humans” (Group 2B). Studies in laboratory animals indicate some evidence of post-implantation deaths following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate limited evidence of renal malformations, resorptions, and developmental delays following high levels of maternal exposure. The relevance of these findings to humans is not clear at this time. Studies in laboratory animals indicate some evidence of adverse effects on the liver, kidney, thyroid, and pituitary gland. Cyclohexane: ORAL (LD50): Acute: 12705 mg/kg [Rat]. 813 mg/kg [Mouse]. Cyclohexane can cause eye, skin and mucous membrane irritation, CNS depressant and MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 12 CITGO Gasolines, All Grades Unleaded narcosis at elevated concentrations. In experimental animals exposed to lethal concentrations by inhalation or oral route, generalized vascular damage and degenerative changes in the heart, lungs, liver, kidneys and brain were identified. Cyclohexane has been the focus of substantial testing in laboratory animals. Cyclohexane was not found to be genotoxic in several tests including unscheduled DNA synthesis, bacterial and mammalian cell mutation assays, and in vivo chromosomal aberration. An increase in chromosomal aberrations in bone marrow cells of rats exposed to cyclohexane was reported in the 1980’s. However, a careful re-evaluation of slides from this study by the laboratory which conducted the study indicates these findings were in error, and that no significant chromosomal effects were observed in animals exposed to cyclohexane. Findings indicate long-term exposure to cyclohexane does not promote dermal tumorigenesis. Naphthalene: Studies in Humans Overexposed to Naphthalene: Severe jaundice, neurotoxicity (kernicterus) and fatalities have been reported in young children and infants as a result of hemolytic anemia from over-exposure to naphthalene. Persons with Glucose 6-phosphate dehydrogenase (G6PD) deficiency are more prone to the hemolytic effects of naphthalene. Adverse effects on the kidney have also been reported from over-exposure to naphthalene but these effects are believed to be a consequence of hemolytic anemia, and not a direct effect. Studies in Laboratory Animals: Hemolytic anemia has been observed in laboratory animals exposed to naphthalene. Laboratory rodents exposed to naphthalene vapor for 2 years (lifetime studies) developed non-neoplastic and neoplastic tumors and inflammatory lesions of the nasal and respiratory tract. Cataracts and other adverse effects on the eye have been observed in laboratory animals exposed to high levels of naphthalene. Findings from a large number of bacterial and mammalian cell mutation assays have been negative. A few studies have shown chromosomal effects (elevated levels of Sister Chromatid Exchange or chromosomal aberrations) in vitro. Styrene: Neurological injury associated with chronic styrene exposure include distal hypesthesia, decreased nerve conduction velocity, and altered psychomotor performance. These effects did not occur with exposures to airborne concentrations that were less than 100 ppm. Increased deaths from degenerative neurological disorders were found in a comprehensive epidemiological study of Danish reinforced plastics workers. These workers were reported to have a 2.5-fold increased risk for myeloid leukemia with clonal chromosome aberrations. Also, there are several studies that suggest potential reproductive effects in humans and experimental animals from overexposure to styrene. Styrene was not mutagenic in the standard (liquid phase) Ames Salmonella/microsome assay, but was weakly positive when tested in the vapor phase. IARC has listed styrene as possibly carcinogenic to humans (Group 2B). SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Unleaded gasoline is potentially toxic to freshwater and saltwater ecosystems. Various grades of gasoline exhibited range of lethal toxicity (LC 100) from 40 PPM to 100 PPM in ambient stream water with Rainbow Trout ( Salmo irideus). A 24-hour TLm (Median Toxic Limit) was calculated to be 90 PPM with juvenile American Shad ( Squalius cephalus). In Bluegill Sunfish ( Lepomis macrochirus), Grey Mullet (Chelon labrosus) and Gulf Menhaden ( Brevoortia patronus), gasoline exhibited a 96-hour LC 50 of 8 PPM, 2 PPM, and 2 PPM, respectively. Environmental Fate Biodegradability: Readily biodegradable in aerobic conditions. Residual components most recalcitrant to biodegration are branched alkanes. Partition Coefficient (log Kow): 2.13 to 4.85. Photodegration: Gasoline will partition to air, with the atmospheric half-life for constituents ranging from 0.8 days to 16 days. MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 13 CITGO Gasolines, All Grades Unleaded Stability in water: Gasoline is not readily susceptible to hydrolysis under aquatic conditions, and the constituents readily partition to air. SECTION 13. DISPOSAL CONSIDERATIONS Hazard characteristic and regulatory waste stream classification can change with product use. Accordingly, it is the responsibility of the user to determine the proper storage, transportation, treatment and/or disposal methodologies for spent materials and residues at the time of disposition. Maximize material recovery for reuse or recycling. Recovered non-usable material may be regulated by US EPA as a hazardous waste due to its ignitibility (D001) and/or its toxic (D018) characteristics. Conditions of use may cause this material to become a "hazardous waste", as defined by federal or state regulations. It is the responsibility of the user to determine if the material is a RCRA "hazardous waste" at the time of disposal. Transportation, treatment, storage and disposal of waste material must be conducted in accordance with RCRA regulations (see 40 CFR 260 through 40 CFR 271). State and/or local regulations may be more restrictive. Contact your regional US EPA office for guidance concerning case specfic disposal issues. SECTION 14. TRANSPORT INFORMATION The shipping description below may not represent requirements for all modes of transportation, shipping methods or locations outside of the United States. A U.S. Department of Transportation regulated material. US DOT Status Proper Shipping Name Gasoline, 3, UN 1203, PG II Gasohol, 3, NA 1203, PGII (Use only for gasoline blended with less than 20% ethanol) 3 DOT Class: Flammable liquid. II Hazard Class Packing Group UN/NA Number Reportable Quantity UN1203 or NA1203 A Reportable Quantity (RQ) has not been established for this material. Placard(s) Emergency Response Guide No. 128 MARPOL III Status Not a DOT "Marine Pollutant" per 49 CFR 171.8. FLAMMABLE LIQUID 3 SECTION 15. REGULATORY INFORMATION TSCA Inventory This product and/or its components are listed on the Toxic Substances Control Act (TSCA) inventory. SARA 302/304 Emergency Planning and Notification The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to Subparts 302 and 304 to submit emergency planning and notification information based on Threshold Planning Quantities (TPQs) and Reportable Quantities (RQs) for "Extremely Hazardous Substances" listed in 40 CFR 302.4 and 40 CFR 355. No components were identified. SARA 311/312 Hazard Identification The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires facilities subject to this subpart to submit aggregate information on chemicals by "Hazard Category" as defined in 40 CFR 370.2. This material would be classified under the following hazard categories: MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 14 CITGO Gasolines, All Grades Unleaded Fire, Acute (Immediate) Health Hazard, Chronic (Delayed) Health Hazard This product contains the following components in concentrations above de minimis levels SARA 313 Toxic Chemical Notification that are listed as toxic chemicals in 40 CFR Part 372 pursuant to the requirements of Section and Release Reporting 313 of SARA: Toluene [CAS No.: 108-88-3] Concentration: <25% Xylene, all isomers [CAS No.: 1330-20-7] Concentration: <18% n-Hexane [CAS No.: 110-54-3] Concentration: <8% Benzene [CAS No.: 71-43-2] Concentration: <5% Cumene [CAS No.: 98-82-8] Concentration: <4% Ethylbenzene [CAS No.: 100-41-4] Concentration: <4% 1,2,4--Trimethylbenzene [CAS No.: 95-63-6] Concentration: <3% Cyclohexane [CAS No.: 110-82-7] Concentration: <3% Naphthalene [CAS No.: 91-20-3] Concentration: <2% Styrene [CAS No.: 100-42-5] Concentration: <1% CERCLA The Comprehensive Environmental Response, Compensation, and Liability Act of 1980 (CERCLA) requires notification of the National Response Center concerning release of quantities of "hazardous substances" equal to or greater than the reportable quantities (RQ's) listed in 40 CFR 302.4. As defined by CERCLA, the term "hazardous substance" does not include petroleum, including crude oil or any fraction thereof which is not otherwise specifically designated in 40 CFR 302.4. Chemical substances present in this product or refinery stream that may be subject to this statute are: Toluene [CAS No.: 108-88-3] RQ = 1000 lbs. (453.6 kg) Concentration: <25% Xylene, all isomers [CAS No.: 1330-20-7] RQ = 100 lbs. (45.36 kg) Concentration: <18% n-Hexane [CAS No.: 110-54-3] RQ = 5000 lbs. (2268 kg) Concentration: <8% Benzene [CAS No.: 71-43-2] RQ = 10 lbs. (4.536 kg) Concentration: <5% 2,2,4-Trimethylpentane [CAS No.: 540-84-1] RQ = 1000 lbs. (453.6 kg) Concentration: <5% Cumene [CAS No.: 98-82-8] RQ = 5000 lbs. (2268 kg) Concentration: <4% Ethylbenzene [CAS No.: 100-41-4] RQ = 1000 lbs. (453.6 kg) Concentration: <4% Cyclohexane [CAS No.: 110-82-7] RQ = 1000 lbs. (453.6 kg) Concentration: <3% Naphthalene [CAS No.: 91-20-3] RQ = 100 lbs. (45.36 kg) Concentration: <2% Styrene [CAS No.: 100-42-5] RQ = 1000 lbs. (453.6 kg) Concentration: <1% Clean Water Act (CWA) This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. California Proposition 65 This material may contain the following components which are known to the State of California to cause cancer, birth defects or other reproductive harm, and may be subject to the requirements of California Proposition 65 (CA Health & Safety Code Section 25249.5): Gasoline (Wholly Vaporized and Engine Exhaust), Benzene [CAS No. 71-43-3], Toluene [CAS No. 108-88-3], Ethylbenzene [CAS No.100-41-4] and Naphthalene [CAS No.91-20-3] New Jersey Right-to-Know Label Gasoline [NJDEP CAS No. 8006-61-9] Additional Remarks As minimum requirements, CITGO recommends that the following advisory information be displayed on equipment used to dispense gasoline in motor vehicles. Additional warnings specified by various regulatory authorities may be required: "DANGER: Extremely Flammable. Use as a Motor Fuel Only. No Smoking. Stop Engine. Turn Off All Electronic Equipment including Cellular Telephones. Do Not Overfill Tank. Keep Away from Heat and Flames. Do Not leave nozzle unattended during refueling. Static Sparks Can Cause a Fire, especially when filling portable containers. Containers must be metal or other material approved for storing gasoline. PLACE CONTAINER ON GROUND. DO NOT FILL ANY PORTABLE CONTAINER IN OR ON A VEHICLE. Keep nozzle spout in contact with the container during the entire filling operation. Harmful or Fatal if Swallowed. Long Term-Exposure Has Caused Cancer in Laboratory Animals. Avoid prolonged breathing of vapors. Keep face away from nozzle and gas tank. Never siphon by mouth." WHMIS Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). WHMIS Class D-2B: Material causing other toxic effects (TOXIC). MSDS No. UNLEAD Revision Date 10/14/2008 Continued on Next Page Page Number: 15 CITGO Gasolines, All Grades Unleaded SECTION 16. OTHER INFORMATION Refer to the top of Page 1 for the HMIS and NFPA Hazard Ratings for this product. REVISION INFORMATION 9.1 10/14/2008 ABBREVIATIONS Version Number Revision Date AP: Approximately EQ: Equal >: Greater Than NA: Not Applicable ND: No Data NE: Not Established <: Less Than ACGIH: American Conference of Governmental Industrial Hygienists AIHA: American Industrial Hygiene Association IARC: International Agency for Research on Cancer NIOSH: National Institute of Occupational Safety and Health NPCA: National Paint and Coating Manufacturers Association EPA: US Environmental Protection Agency HMIS: Hazardous Materials Information System OSHA: Occupational Safety and Health Administration NTP: National Toxicology Program NFPA: National Fire Protection Association DISCLAIMER OF LIABILITY THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. ***** END OF MSDS ***** Material Safety Data Sheet Hydrochloric acid MSDS Section 1: Chemical Product and Company Identification Product Name: Hydrochloric acid Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 Catalog Codes: SLH1462, SLH3154 CAS#: Mixture. RTECS: MW4025000 US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 TSCA: TSCA 8(b) inventory: Hydrochloric acid Order Online: ScienceLab.com CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 Synonym: Hydrochloric Acid; Muriatic Acid International CHEMTREC, call: 1-703-527-3887 Chemical Name: Not applicable. For non-emergency assistance, call: 1-281-441-4400 Chemical Formula: Not applicable. Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Hydrogen chloride 7647-01-0 20-38 Water 7732-18-5 62-80 Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat]. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightly hazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Potential Chronic Health Effects: Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. MUTAGENIC EFFECTS: Not available. p. 1 TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in one or many human organs. Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Serious Ingestion: Not available. Section 5: Fire and Explosion Data Flammability of the Product: Non-flammable. Auto-Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: of metals Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks. Fire Fighting Media and Instructions: Not applicable. p. 2 Special Remarks on Fire Hazards: Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts with hydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warm hydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid is used, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid produces spontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact with hydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas. Special Remarks on Explosion Hazards: Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction: Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Amino ethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesium carbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithium disilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate, beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodium hydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbon tetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C. Section 6: Accidental Release Measures Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Large Spill: Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 7: Handling and Storage Precautions: Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organic materials, metals, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Section 8: Exposure Controls/Personal Protection Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection: p. 3 Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States] CEIL: 5 from NIOSH CEIL: 7 (mg/m3) from NIOSH TWA: 1 STEL: 5 (ppm) [United Kingdom (UK)] TWA: 2 STEL: 8 (mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits. Section 9: Physical and Chemical Properties Physical state and appearance: Liquid. Odor: Pungent. Irritating (Strong.) Taste: Not available. Molecular Weight: Not applicable. Color: Colorless to light yellow. pH (1% soln/water): Acidic. Boiling Point: 108.58 C @ 760 mm Hg (for 20.22% HCl in water) 83 C @ 760 mm Hg (for 31% HCl in water) 50.5 C (for 37% HCl in water) Melting Point: -62.25°C (-80°F) (20.69% HCl in water) -46.2 C (31.24% HCl in water) -25.4 C (39.17% HCl in water) Critical Temperature: Not available. Specific Gravity: 1.1- 1.19 (Water = 1) 1.10 (20%and 22% HCl solutions) 1.12 (24% HCl solution) 1.15 (29.57% HCl solution) 1.16 (32% HCl solution) 1.19 (37% and 38%HCl solutions) Vapor Pressure: 16 kPa (@ 20°C) average Vapor Density: 1.267 (Air = 1) Volatility: Not available. Odor Threshold: 0.25 to 10 ppm Water/Oil Dist. Coeff.: Not available. Ionicity (in Water): Not available. p. 4 Dispersion Properties: See solubility in water, diethyl ether. Solubility: Soluble in cold water, hot water, diethyl ether. Section 10: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Incompatible materials, water Incompatibility with various substances: Highly reactive with metals. Reactive with oxidizing agents, organic materials, alkalis, water. Corrosivity: Extremely corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive in presence of glass. Special Remarks on Reactivity: Reacts with water especially when water is added to the product. Absorption of gaseous hydrogen chloride on mercuric sulfate becomes violent @ 125 deg. C. Sodium reacts very violently with gaseous hydrogen chloride. Calcium phosphide and hydrochloric acid undergo very energetic reaction. It reacts with oxidizers releasing chlorine gas. Incompatible with, alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides, phosphides, cyanides, carbonates. Reacts with most metals to produce flammable Hydrogen gas. Reacts violently (moderate reaction with heat of evolution) with water especially when water is added to the product. Isolate hydrogen chloride from heat, direct sunlight, alkalies (reacts vigorously), organic materials, and oxidizers (especially nitric acid and chlorates), amines, metals, copper and alloys (e.g. brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence), sulfuric acid(increase in temperature and pressure) Hydrogen chloride gas is emitted when this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acid onto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydes and epoxides to violently polymerize. Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can cause explosion or ignition on contact or Special Remarks on Corrosivity: Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum, silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys. No corrosivity data on zinc, steel. Severe Corrosive effect on brass and bronze Polymerization: Will not occur. Section 11: Toxicological Information Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Toxicity to Animals: Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity of the vapor (LC50): 3124 ppm, 1 hours [Rat]. Chronic Effects on Humans: CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. May cause damage to the following organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, p. 5 eyes, Circulatory System, teeth. Other Toxic Effects on Humans: Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact (corrosive), of inhalation (lung corrosive). Special Remarks on Toxicity to Animals: Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300 ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects (fetoxicity). May affect genetic material. Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severe eye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract. Inhalation of hydrochloric acid fumes produces nose, throat, and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngeal spasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrations can result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation, glottal closure, occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causes irritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage and infection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation, chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement), the cardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys- renal failure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enamel. Chronic Potential Health Effects: dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also Section 12: Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Transport Information p. 6 DOT Classification: Class 8: Corrosive material Identification: : Hydrochloric acid, solution UNNA: 1789 PG: II Special Provisions for Transport: Not available. Section 15: Other Regulatory Information Federal and State Regulations: Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloric acid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTK hazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid Massachusetts RTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list: Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid California Director's List of Hazardous Substances: Hydrochloric acid TSCA 8(b) inventory: Hydrochloric acid TSCA 4(a) proposed test rules: Hydrochloric acid SARA 302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemical notification and release reporting: Hydrochloric acid CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg) Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances. Other Classifications: WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid. DSCL (EEC): R34- Causes burns. R37- Irritating to respiratory system. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 0 Reactivity: 1 Personal Protection: National Fire Protection Association (U.S.A.): p. 7 Health: 3 Flammability: 0 Reactivity: 1 Specific hazard: Protective Equipment: Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. Section 16: Other Information References: -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I. Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library of Chemical Safety Data, Edition II. -Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada. Centre de conformité internatinal Ltée. 1986. Other Special Considerations: Not available. Created: 10/09/2005 05:45 PM Last Updated: 09/14/2009 10:34 AM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages. p. 8 Material Safety Data Sheet Isobutylene Section 1. Chemical product and company identification Product name Supplier : Isobutylene : AIRGAS INC., on behalf of its subsidiaries 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 Product use Synonym : Synthetic/Analytical chemistry. : Propene, 2-methyl-; γ-Butylene; Isobutene; Isobutylene; Isopropylidenemethylene; 1,1Dimethylethylene; 2-Methyl-1-propene; 2-Methylpropene; iso-C4H8; Methylpropene; 2Methylpropene-isobutylene; UN 1055; UN 1075 : 001031 : 11/10/2010. MSDS # Date of Preparation/Revision In case of emergency : 1-866-734-3438 Section 2. Hazards identification Physical state Emergency overview : Gas. [COLORLESS LIQUEFIED COMPRESSED GAS WITH A SWEET GASOLINELIKE ODOR] : WARNING! FLAMMABLE GAS. MAY CAUSE FLASH FIRE. CONTENTS UNDER PRESSURE. Keep away from heat, sparks and flame. Do not puncture or incinerate container. Use only with adequate ventilation. Keep container closed. Contact with rapidly expanding gases can cause frostbite. : Inhalation Routes of entry Potential acute health effects Eyes : Contact with rapidly expanding gas may cause burns or frostbite. Skin : Contact with rapidly expanding gas may cause burns or frostbite. Inhalation : Acts as a simple asphyxiant. Ingestion Potential chronic health effects : Ingestion is not a normal route of exposure for gases Medical conditions aggravated by overexposure : Acute or chronic respiratory conditions may be aggravated by overexposure to this gas. : CARCINOGENIC EFFECTS: A4 (Not classifiable for humans or animals.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. See toxicological information (section 11) Section 3. Composition, Information on Ingredients Name Isobutylene Build 1.1 CAS number 115-11-7 % Volume 100 Exposure limits ACGIH TLV (United States, 2/2010). TWA: 250 ppm 8 hour(s). Page: 1/6 Isobutylene Section 4. First aid measures No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical attention immediately. Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. To avoid the risk of static discharges and gas ignition, soak contaminated clothing thoroughly with water before removing it. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Frostbite Inhalation : Try to warm up the frozen tissues and seek medical attention. : Move exposed person to fresh air. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Ingestion : As this product is a gas, refer to the inhalation section. Section 5. Fire-fighting measures Flammability of the product Auto-ignition temperature Flammable limits Products of combustion : : : : Flammable. 465°C (869°F) Lower: 1.8% Upper: 9.6% Decomposition products may include the following materials: carbon dioxide carbon monoxide Fire hazards in the presence : Extremely flammable in the presence of the following materials or conditions: open flames, sparks and static discharge and oxidizing materials. of various substances Fire-fighting media and : In case of fire, use water spray (fog), foam or dry chemical. instructions In case of fire, allow gas to burn if flow cannot be shut off immediately. Apply water from a safe distance to cool container and protect surrounding area. If involved in fire, shut off flow immediately if it can be done without risk. Contains gas under pressure. Flammable gas. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. equipment for fire-fighters Section 6. Accidental release measures Personal precautions Environmental precautions Methods for cleaning up Build 1.1 : Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable protective equipment (section 8). Shut off gas supply if this can be done safely. Isolate area until gas has dispersed. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. : Immediately contact emergency personnel. Stop leak if without risk. Use spark-proof tools and explosion-proof equipment. Note: see section 1 for emergency contact information and section 13 for waste disposal. Page: 2/6 Isobutylene Section 7. Handling and storage Handling : Use only with adequate ventilation. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. High pressure gas. Do not puncture or incinerate container. Use equipment rated for cylinder pressure. Close valve after each use and when empty. Keep container closed. Keep away from heat, sparks and flame. To avoid fire, eliminate ignition sources. Protect cylinders from physical damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder movement. Storage : Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame). Segregate from oxidizing materials. Cylinders should be stored upright, with valve protection cap in place, and firmly secured to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 °C (125 °F). Section 8. Exposure controls/personal protection Engineering controls Personal protection Eyes Skin Respiratory Hands Personal protection in case of a large spill : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. : Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists or dusts. : Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93 : Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. : Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the product. Product name 2-methylpropene ACGIH TLV (United States, 2/2010). TWA: 250 ppm 8 hour(s). Consult local authorities for acceptable exposure limits. Section 9. Physical and chemical properties Molecular weight Molecular formula Boiling/condensation point Melting/freezing point Critical temperature Vapor pressure Vapor density Specific Volume (ft 3/lb) Gas Density (lb/ft 3) Build 1.1 : : : : : : : : : 56.12 g/mole C4-H8 -6.9°C (19.6°F) -140°C (-220°F) 144.8°C (292.6°F) 24.3 (psig) 1.9 (Air = 1) 6.6845 0.1496 Page: 3/6 Isobutylene Section 10. Stability and reactivity Stability and reactivity Incompatibility with various substances Hazardous decomposition products Hazardous polymerization : The product is stable. : Extremely reactive or incompatible with the following materials: oxidizing materials. : Under normal conditions of storage and use, hazardous decomposition products should not be produced. : Under normal conditions of storage and use, hazardous polymerization will not occur. Section 11. Toxicological information Toxicity data Product/ingredient name 2-methylpropene Chronic effects on humans Other toxic effects on humans Specific effects Carcinogenic effects Mutagenic effects Reproduction toxicity Result Species Dose Exposure LC50 Inhalation Rat 550000 mg/m3 4 hours Vapor : CARCINOGENIC EFFECTS: A4 (Not classifiable for humans or animals.) by ACGIH. : No specific information is available in our database regarding the other toxic effects of this material to humans. : No known significant effects or critical hazards. : No known significant effects or critical hazards. : No known significant effects or critical hazards. Section 12. Ecological information Aquatic ecotoxicity Not available. Products of degradation Environmental fate Environmental hazards Toxicity to the environment : : : : Products of degradation: carbon oxides (CO, CO2) and water. Not available. No known significant effects or critical hazards. Not available. Section 13. Disposal considerations Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally. Section 14. Transport information Regulatory information UN number Proper shipping name Class Packing group DOT Classification UN1055 ISOBUTYLENE 2.1 Not applicable (gas). Label Additional information Limited quantity Yes. Packaging instruction Passenger aircraft Quantity limitation: Forbidden. Cargo aircraft Quantity limitation: 150 kg Special Build 1.1 Page: 4/6 Isobutylene provisions 19, T50 TDG Classification UN1055 ISOBUTYLENE 2.1 Not applicable (gas). Explosive Limit and Limited Quantity Index 0.125 ERAP Index 3000 Passenger Carrying Ship Index Forbidden Passenger Carrying Road or Rail Index Forbidden Special provisions 29 Mexico Classification UN1055 ISOBUTYLENE 2.1 Not applicable (gas). - “Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the product.” Section 15. Regulatory information United States U.S. Federal regulations State regulations Build 1.1 : United States inventory (TSCA 8b): This material is listed or exempted. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: 2-methylpropene SARA 311/312 MSDS distribution - chemical inventory - hazard identification: 2methylpropene: Fire hazard, Sudden release of pressure Clean Water Act (CWA) 307: No products were found. Clean Water Act (CWA) 311: No products were found. Clean Air Act (CAA) 112 accidental release prevention: 2-methylpropene Clean Air Act (CAA) 112 regulated flammable substances: 2-methylpropene Clean Air Act (CAA) 112 regulated toxic substances: No products were found. : Connecticut Carcinogen Reporting: This material is not listed. Connecticut Hazardous Material Survey: This material is not listed. Florida substances: This material is not listed. Illinois Chemical Safety Act: This material is not listed. Illinois Toxic Substances Disclosure to Employee Act: This material is not listed. Louisiana Reporting: This material is not listed. Louisiana Spill: This material is not listed. Massachusetts Spill: This material is not listed. Massachusetts Substances: This material is listed. Michigan Critical Material: This material is not listed. Page: 5/6 Isobutylene Minnesota Hazardous Substances: This material is not listed. New Jersey Hazardous Substances: This material is listed. New Jersey Spill: This material is not listed. New Jersey Toxic Catastrophe Prevention Act: This material is not listed. New York Acutely Hazardous Substances: This material is not listed. New York Toxic Chemical Release Reporting: This material is not listed. Pennsylvania RTK Hazardous Substances: This material is listed. Rhode Island Hazardous Substances: This material is not listed. Canada WHMIS (Canada) : Class A: Compressed gas. Class B-1: Flammable gas. CEPA Toxic substances: This material is not listed. Canadian ARET: This material is not listed. Canadian NPRI: This material is not listed. Alberta Designated Substances: This material is not listed. Ontario Designated Substances: This material is not listed. Quebec Designated Substances: This material is not listed. Section 16. Other information United States Label requirements Canada Label requirements Hazardous Material Information System (U.S.A.) National Fire Protection Association (U.S.A.) : FLAMMABLE GAS. MAY CAUSE FLASH FIRE. CONTENTS UNDER PRESSURE. : Class A: Compressed gas. Class B-1: Flammable gas. : Health 1 Flammability 4 Physical hazards 0 : Flammability 4 Health 1 0 Instability Special Notice to reader To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Build 1.1 Page: 6/6 msds_liquinox_english_osha LIQUINOX MSDS Section 1 : MANUFACTURER INFORMATION Supplier: Same as manufacturer. Manufacturer: Alconox, Inc. 30 Glenn St. Suite 309 White Plains, NY 10603. Manufacturer emergency 800-255-3924. phone number: 813-248-0585 (outside of the United States). Manufacturer: Alconox, Inc. 30 Glenn St. Suite 309 White Plains, NY 10603. Supplier MSDS date: 2005/02/24 D.O.T. Classification: Not regulated. Section 2 : HAZARDOUS INGREDIENTS C.A.S. 2515530-0 CONCENTRATION % 10-30 Ingredient Name T.L.V. LD/50 LC/50 SODIUM DODECYLBENZENESULFONATE NOT AVAILABLE 438 MG/KG RAT ORAL NOT AVAILABLE 1330 MG/KG MOUSE ORAL Section 3 : PHYSICAL / CHEMICAL CHARACTERISTICS Physical state: Liquid. Appearance & odor: Odourless. Pale yellow. Odor threshold (ppm): Not available. Vapour pressure @ 20°C (68°F). (mmHg): 17 Vapour density (air=1): >1 Volatiles (%) By volume: Not available. Evaporation rate < 1. (butyl acetate = 1): MS 01.40.01.03.04.0 Page 1 of 4 msds_liquinox_english_osha Boiling point (°C): 100 (212F) Freezing point (°C): Not available. pH: 8.5 Specific gravity @ 20 °C: (water = 1). 1.083 Solubility in water (%): Complete. Coefficient of water\oil Not available. dist.: VOC: None Section 4 : FIRE AND EXPLOSION HAZARD DATA Flammability: Not flammable. Conditions of Surrounding fire. flammability: Extinguishing media: Carbon dioxide, dry chemical, foam. Water Water fog. Special procedures: Self-contained breathing apparatus required. Firefighters should wear the usual protective gear. Use water spray to cool fire exposed containers. Auto-ignition Not available. temperature: Flash point (°C), None method: Lower flammability Not applicable. limit (% vol): Upper flammability Not applicable. limit (% vol): Not available. Sensitivity to mechanical Not available. impact: Hazardous combustion Oxides of carbon (COx). products: Hydrocarbons. Rate of burning: Not available. Explosive power: Containers may rupture if exposed to heat or fire. Section 5 : REACTIVITY DATA Chemical stability: Product is stable under normal handling and storage conditions. Conditions of instability: Extreme temperatures. Hazardous Will not occur. polymerization: Incompatible Strong acids. substances: Strong oxidizing agents. Hazardous See hazardous combustion products. decomposition products: Section 6 : HEALTH HAZARD DATA MS 01.40.01.03.04.0 Page 2 of 4 msds_liquinox_english_osha Route of entry: Skin contact, eye contact, inhalation and ingestion. Effects of Acute Exposure Eye contact: May cause irritation. Skin contact: Prolonged and repeated contact may cause irritation. Inhalation: May cause headache and nausea. Ingestion: May cause vomiting and diarrhea. May cause gastric distress. Effects of chronic See effects of acute exposure. exposure: LD50 of product, species > 5000 mg/kg rat oral. & route: LC50 of product, species Not available. & route: Exposure limit of Not available. material: Sensitization to product: Not available. Carcinogenic effects: Not listed as a carcinogen. Reproductive effects: Not available. Teratogenicity: Not available. Mutagenicity: Not available. Synergistic materials: Not available. Medical conditions Not available. aggravated by exposure: First Aid Skin contact: Remove contaminated clothing. Wash thoroughly with soap and water. Seek medical attention if irritation persists. Eye contact: Check for and remove contact lenses. Flush eyes with clear, running water for 15 minutes while holding eyelids open: if irritation persists, consult a physician. Inhalation: Remove victim to fresh air. If irritation persists, seek medical attention. Ingestion: Do not induce vomiting, seek medical attention. Dilute with two glasses of water. Never give anything by mouth to an unconscious person. Section 7 : PRECAUTIONS FOR SAFE HANDLING AND USE Leak/Spill: Contain the spill. Prevent entry into drains, sewers, and other waterways. Wear appropriate protective equipment. Small amounts may be flushed to sewer with water. Soak up with an absorbent material. Place in appropriate container for disposal. Notify the appropriate authorities as required. Waste disposal: In accordance with local and federal regulations. Handling procedures and Protect against physical damage. equipment: Avoid breathing vapors/mists. Wear personal protective equipment appropriate to task. MS 01.40.01.03.04.0 Page 3 of 4 msds_liquinox_english_osha Wash thoroughly after handling. Keep out of reach of children. Avoid contact with skin, eyes and clothing. Avoid extreme temperatures. Launder contaminated clothing prior to reuse. Storage requirements: Store away from incompatible materials. Keep containers closed when not in use. Section 8 : CONTROL MEASURES Precautionary Measures Gloves/Type: Wear appropriate gloves. Respiratory/Type: None required under normal use. Eye/Type: Safety glasses recommended. Footwear/Type: Safety shoes per local regulations. Clothing/Type: As required to prevent skin contact. Other/Type: Eye wash facility should be in close proximity. Emergency shower should be in close proximity. Ventilation Local exhaust at points of emission. requirements: MS 01.40.01.03.04.0 Page 4 of 4 Material Safety Data Sheet Nitric acid, 65% MSDS Section 1: Chemical Product and Company Identification Product Name: Nitric acid, 65% Contact Information: Sciencelab.com, Inc. 14025 Smith Rd. Houston, Texas 77396 Catalog Codes: SLN2161 CAS#: Mixture. RTECS: Not applicable. US Sales: 1-800-901-7247 International Sales: 1-281-441-4400 TSCA: TSCA 8(b) inventory: Water; Nitric acid, fuming Order Online: ScienceLab.com CI#: Not applicable. CHEMTREC (24HR Emergency Telephone), call: 1-800-424-9300 Synonym: Nitric Acid, 65% International CHEMTREC, call: 1-703-527-3887 Chemical Name: Not applicable. For non-emergency assistance, call: 1-281-441-4400 Chemical Formula: Not applicable. Section 2: Composition and Information on Ingredients Composition: Name CAS # % by Weight Water 7732-18-5 35 Nitric acid, fuming 7697-37-2 65 Toxicological Data on Ingredients: Nitric acid, fuming: VAPOR (LC50): Acute: 244 ppm 0.5 hours [Rat]. 344 ppm 0.5 hours [Rat]. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightly hazardous in case of inhalation (lung sensitizer). Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath. Prolonged exposure may result in skin burns and ulcerations. Over-exposure by inhalation may cause respiratory irritation. Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available. p. 1 MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to lungs, mucous membranes, upper respiratory tract, skin, eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention immediately. Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention. Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention. Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Serious Ingestion: Not available. Section 5: Fire and Explosion Data Flammability of the Product: Non-flammable. Auto-Ignition Temperature: Not applicable. Flash Points: Not applicable. Flammable Limits: Not applicable. Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: of combustible materials Explosion Hazards in Presence of Various Substances: Explosive in presence of reducing materials, of organic materials, of metals, of alkalis. Non-explosive in presence of open flames and sparks, of shocks. Fire Fighting Media and Instructions: Not applicable. p. 2 Special Remarks on Fire Hazards: Flammable in presence of cellulose or other combustible materials. Phosphine, hydrogen sulfide, selenide all ignite when fuming nitric acid is dripped into gas. (Nitric Acid, fuming) Special Remarks on Explosion Hazards: Reacts exlposively with metallic powders, carbides, cyanides, sulfides, alkalies and turpentine. Can react explosively with many reducing agents. Arsine, phosphine, tetraborane all oxidized explosively in presence of nitric acid. Cesium and rubidium acetylides explode in contact with nitric acid. Explosive reaction with Nitric Acid + Nitrobenzene + water. Detonation with Nitric Acid + 4-Methylcyclohexane. (Nitric acid, fuming) Section 6: Accidental Release Measures Small Spill: Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. If necessary: Neutralize the residue with a dilute solution of sodium carbonate. Large Spill: Corrosive liquid. Oxidizing material. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 7: Handling and Storage Precautions: Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strong polyethylene inner package. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Separate from acids, alkalies, reducing agents and combustibles. See NFPA 43A, Code for the Storage of Liquid and Solid Oxidizers. Do not store above 23°C (73.4°F). Section 8: Exposure Controls/Personal Protection Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection: Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be p. 3 used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: TWA: 2 STEL: 4 (ppm) from ACGIH (TLV) [United States] TWA: 2 STEL: 4 from OSHA (PEL) [United States] Consult local authorities for acceptable exposure limits. Section 9: Physical and Chemical Properties Physical state and appearance: Liquid. Odor: Acrid. Disagreeable and choking. (Strong.) Taste: Not available. Molecular Weight: Not applicable. Color: Colorless to light yellow. pH (1% soln/water): Acidic. Boiling Point: 121°C (249.8°F) Melting Point: -41.6°C (-42.9°F) Critical Temperature: Not available. Specific Gravity: 1.408 (Water = 1) Vapor Pressure: 6 kPa (@ 20°C) Vapor Density: 2.5 (Air = 1) Volatility: Not available. Odor Threshold: 0.29 ppm Water/Oil Dist. Coeff.: Not available. Ionicity (in Water): Not available. Dispersion Properties: See solubility in water, diethyl ether. Solubility: Easily soluble in cold water, hot water. Soluble in diethyl ether. Section 10: Stability and Reactivity Data Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Incompatible materials Incompatibility with various substances: Highly reactive with alkalis. Reactive with reducing agents, combustible materials, organic materials, metals, acids. p. 4 Corrosivity: Extremely corrosive in presence of aluminum, of copper. Non-corrosive in presence of glass, of stainless steel(304), of stainless steel(316), of brass. Special Remarks on Reactivity: A strong oxidizer. Reacts violently with alcohol, organic material, turpene, charcoal. Violent reaction with Nitric acid + Acetone and Sulfuric acid. Nitric Acid will react with water or steam to produce heat and toxic, corrosive and flammable vapors. (Nitric acid, fuming) Special Remarks on Corrosivity: In presence of traces of oxides, it attacks all base metals except aluminum and special chromium steels. It will attack some forms of plastics, rubber, and coatings. No corrosive effect on bronze. No corrosivity data for zinc, and steel Polymerization: Will not occur. Section 11: Toxicological Information Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Toxicity to Animals: LD50: Not available. LC50: Not available. Chronic Effects on Humans: Contains material which may cause damage to the following organs: lungs, mucous membranes, upper respiratory tract, skin, eyes, teeth. Other Toxic Effects on Humans: Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (corrosive), of ingestion, . Special Remarks on Toxicity to Animals: LDL - Lowest Published Lethal Dose [Human] - Route: Oral; Dose: 430 mg/kg (Nitric acid, fuming) Special Remarks on Chronic Effects on Humans: May cause adverse reproductive effects (effects on newborn and fetotoxicity) based on animal data. (Nitric acid, fuming) Special Remarks on other Toxic Effects on Humans: Acute Potential Health Effects: Skin: Severely irritates skin. Causes skin burns and may cause deep and penetrating ulcers of the skin with a characteristic yellow to brownish discoloration. May be fatal if absorbed through skin. Eyes: Severely irritates eyes. Causes eye burns. May cause irreversible eye injury. Ingestion: May be fatal if swallowed. Causes serious gastrointestinal tract irritation or burns with nausea, vomiting, severe abdominal pain, and possible "coffee grounds" appearance of the vomitus . May cause perforation of the digestive tract. Inhalation: May be fatal if inhaled. Vapor is extremely hazardous. Vapor may cause nitrous gas poisoning. Effects may be delayed. May cause irritation of the mucous membranes and respiratory tract with burning pain in the nose and throat, coughing, sneezing, wheezing, shortness of breath and pulmonary edema. Other symptoms may include nausea, and vomiting. Chronic Potential Health Effects: Repeated inhalation may produce changes in pulmonary function and/or chronic bronchitis. It may also affect behavior (headache, dizziness, drowsiness, muscle contaction or spasticity, weakness, loss of coordinaton, mental confusion), and urinary system (kidney faillure, decreased urinary output after several hours of p. 5 Section 12: Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations Waste Disposal: Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 14: Transport Information DOT Classification: Class 8: Corrosive material Identification: : Nitric acid UNNA: 2031 PG: II Special Provisions for Transport: Marine Pollutant Section 15: Other Regulatory Information Federal and State Regulations: New York release reporting list: Nitric acid, fuming Rhode Island RTK hazardous substances: Nitric acid, fuming Pennsylvania RTK: Nitric acid, fuming Florida: Nitric acid, fuming Minnesota: Nitric acid, fuming Massachusetts RTK: Nitric acid, fuming New Jersey: Nitric acid, fuming TSCA 8(b) inventory: Water; Nitric acid, fuming SARA 302/304/311/312 extremely hazardous substances: Nitric acid, fuming SARA 313 toxic chemical notification and release reporting: Nitric acid, fuming 65% CERCLA: Hazardous substances.: Nitric acid, fuming: 1000 lbs. (453.6 kg); Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications: WHMIS (Canada): CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid. DSCL (EEC): R8- Contact with combustible material may cause fire. R35- Causes severe burns. S23- Do not breathe gas/fumes/vapour/spray [***] p. 6 S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36- Wear suitable protective clothing. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). HMIS (U.S.A.): Health Hazard: 3 Fire Hazard: 0 Reactivity: 0 Personal Protection: National Fire Protection Association (U.S.A.): Health: 4 Flammability: 0 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Face shield. Section 16: Other Information References: Not available. Other Special Considerations: Not available. Created: 10/10/2005 10:59 AM Last Updated: 11/06/2008 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages. p. 7 Appendix C AHA’s ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) L Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Equipment Decontamination Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS HAZARDS X Depth Indicator Decon Eye and Skin Contact with Cleaning Solution X Sample Board Decon Eye and Skin Contact with Cleaning Solution X Sediment Equipment Decon Eye and Skin Contact with Cleaning Solution X Back Strain or Sprain Due to Improper Lifting or Twisting X Foot Injury Due to Dropped Equipment ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS Safety glasses in accordance with ANSI Z87.1 and nitrile gloves shall be worn while performing decon tasks. Gloves will be evaluated for their applicability with the expected temperatures and chemicals. Safety Goggles shall be worn if splash hazards are likely. Safety glasses in accordance with ANSI Z87.1 and nitrile gloves shall be worn while performing decon tasks. Gloves will be evaluated for their applicability with the expected temperatures and chemicals. Safety Goggles shall be worn if splash hazards are likely. Safety glasses in accordance with ANSI Z87.1 and nitrile gloves shall be worn while performing decon tasks. Gloves will be evaluated for their applicability with the expected temperatures and chemicals. Safety Goggles shall be worn if splash hazards are likely. Avoid bending at the waist. Use proper lifting techniques (lift with the legs, not with the back), size up the load, use teamwork, never twist or turn when lifting. Steel-toed shoes shall be worn while performing tasks specified in this AHA. RAC L L L L L Add Items EQUIPMENT X Water Level Meter NWW Form 385-1 (Revised) April 2008 TRAINING Equipment manual, one-on-one instruction from experienced CDM Smith personnel, CDM Smith SOP 4-5 for sampling equipment decontamination. INSPECTION Ensure that contaminants and cleaners are removed following decon process. Inspect gloves and other PPE to verify adequate protection to skin and eyes during decon. ACTIVITY HAZARDS ANALYSIS EQUIPMENT X Sampling trowel, hand auger, drive sampler TRAINING Equipment manual, one-on-one instruction from experienced CDM Smith personnel, review safe lifting techniques for heavier sampling equipment, CDM Smith SOP 4-5 for sampling equipment decontamination. INSPECTION Ensure that contaminants and cleansers are removed following decon process. Inspect gloves and other PPE to verify adequate protection to skin and eyes during decon. Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greaze, Craig Nochajski, and Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) L Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Hand and/or power tools usage Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS X Use of hand and/or power tools NWW Form 385-1 (Revised) April 2008 HAZARDS Contusions, abrasions, cuts, and amputations ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Tools shall be inspected prior to use. • Power tools that are equipped with a safety guard will be used with the guard in place. • Defective tools shall be tagged and removed from service. • Electric tools shall be unplugged when changing the attachments or performing maintenance. • Pneumatic tools shall be disconnected and air pressure released before repair or adjustments are made. • Sections of air hoses, which are not equipped with quick release fittings, shall be secured together with a safety chain or tie. RAC L ACTIVITY HAZARDS ANALYSIS JOB STEPS HAZARDS X Use of Hand and/or Power Tools (continued) Electric shock X Use of Hand and/or Power Tools (continued) Burns X Use of Hand and/or Power Tools (continued) Puncture wounds X Use of Hand and/or Power Tools (continued) Flying debris/chips ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Electric tools with missing ground prongs, or cut or frayed cords shall be removed from service. • Electric tools used in highly conductive locations, such as where the employee may contact water, shall be approved for use in those locations. • Power for portable electric tools shall be supplied from a Ground-Fault Circuit Interrupter (GFCI) receptacle, or an extension cord attached to a GFCI. • Electric tools shall not be used in hazardous locations, such as, flammable or explosive atmospheres, unless they are approved for such locations. • Electrically powered tools will either be double insulated or properly grounded. • Fuel powered tools (generators, pumps, steam cleaners, etc.) shall be turned off during refueling. • Smoking is prohibited around fuel containers, fuel storage areas, and while refueling. • Equipment will be allowed to cool prior to refueling • Caution shall be used while working around lumber with exposed nails. To the extent practical, nails are to be removed or hammered over to minimize punctures. • Caution shall be used while working around jackhammers, concrete saw or equivalent tools that may generate flying debris. • Eye protection emphasized, all other Level D PPE required. RAC L L L L Add Items EQUIPMENT X Hand or powered auger X Drills, hand saws and power saws TRAINING Equipment manual, one-on-one instruction from experienced CDM personnel, experienced subcontractors, applicable specific safety training. Equipment manual, one-on-one instruction from experienced CDM personnel, experienced subcontractors, applicable specific safety training. INSPECTION Before each use Before each use Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greazel, Craig Nochajski, and Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) L Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Mobilization to Site Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS X Highway driving for greater than 200 miles X Driving on curvy, mountain roads for 15 to 20 miles X HAZARDS Driving to Site with limited notice. Driving in possibly rainy conditions Driving during the night Blind curves Slick roads Wildlife crossing Backing up Operating a full-size truck possible towing a cargo trailer Large blind spots or small boat trailer Jack-kinifing ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS Be well rested Check road conditions prior to driving Use defensive driving techniques Use prescription eye ware if necessary Use defensive driving techniques Slow down before entering curves Be aware of the dark or forested areas on the road shoulder Check blind spots of vehicle Ensure brake lights and blinker signals are in working order Use spotter for backing up or driving around tight corners RAC L L L Add Items EQUIPMENT X Full-size truck rental with filled with work equipment X Cargo or boat trailer TRAINING Driver's license appropriate for rental truck Review manufacturer manual and consult with rental facility INSPECTION Check all components of the vehicle prior to driving away from rental facility Check brake lights, blinker signal, and locking gates on trailer Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greazel, Craig Nochajski, Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) L Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Sample Bottle Preparation and Preservation Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS X Bottle Preparation HAZARDS Back Injury Due to Improper Lifting Practices X Employee Vision Impaired Due to Carrying Excessive Load X Cuts to the Hand From Box Cutter, Knife or Paper Cut While Opening Sample Bottle Boxes X Employee Cut by Broken Bottle X Sample Preservation Solution Splashed Into Eye NWW Form 385-1 (Revised) April 2008 ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Avoid bending at the waist. Use proper lifting techniques (lift with the legs, not with the back), size up the load, use teamwork, never twist or turn when lifting. • Avoid lifting more than two sampling bottle boxes at one time. • Use dolly to move boxes if necessary to avoid back strain • Avoid carrying more than two sampling bottle boxes at one time. • Use dolly to move boxes if necessary to avoid tripping or falling due to impaired line of sight. • Employee shall remain alert while cutting boxes open with box cutter or knife. • Cuts shall be made away from the body. • Leather palm gloves shall be worn if there is a likelihood of cuts from paper or box cutter/knife used to open bottle boxes. • Avoid contact with broken bottles. Use dust pan and broom to clean up broken glass. • Use leather palm or other cut resistant gloves if necessary to physically handle broken glass. • Use plastic sampling bottles if appropriate. •Safety glasses that meet the ANSI-Z-87.1 standard will be worn by all personnel. • Maintain the portable emergency eyewash station in the event that employees eyes come into contact with sample preservation solution. RAC L L L L L ACTIVITY HAZARDS ANALYSIS JOB STEPS HAZARDS Sample Solution Contacts Employees Skin X Inhalation of Fumes From Preservation Solution Head injury X X X Foot Injury X Eye Injury ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • If preservation solution is splashed onto employee skin, immediately flush the area with water and consult MSDS for additional measures. • Chemical-resistant apron and nitrile gloves shall be worn during preservation activities. • Protective sleeves or gauntlet gloves shall be worn if there is a likelihood of chemical splash to the arms. • Bottles shall be filled at the acid fume exhaust hood to prevent inhalation. • Hard hats will be required for all work. • Steel-toed safety shoes will be worn by all personnel entering the work site. • Safety glasses that meet the ANSI-Z-87.1 standard will be worn. RAC L L L L L Add Items EQUIPMENT X Sample preservatives X Sample containers TRAINING Review MSDS and safe handling procedures for preservatives, one-on-one instruction from experienced CDM Smith personnel, review safe lifting techniques for heavier sampling equipment, CDM Smith SOP 2-1 for Sample Packaging and Shipping. Safe handling techniques for glass containers INSPECTION Before beginning field work Before beginning field work Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greazel, Craig Nochajski, Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) M Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Installation of Sampling Equipment Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS HAZARDS X Accessing Las Tablas Creek Slippery Creek Bank - slips/trips/falls X Installing sampling equipment Slippery Work Surface - slips/trips/falls X Working In Running Water X Back Injury NWW Form 385-1 (Revised) April 2008 ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Remove vegetation that may restrict access to the creek. • Inspect weed whacker prior to use; don additional PPE when using the weed whacker. Additional PPE should include face shield, ear plugs, and leather gloves. • Don leather gloves when using garden shears. • Inspect access route for hand holds; if hand holds are not present, then install a rope along access path for a hand hold or keep three points of contact when entering and exiting the creek. •Only access the creek when a co-worker is present and ready to help. • Ensure that you have good footing before accessing the sampling device • Use caution when working in the stream and avoid walking on mossy rocks. • Inspect stream conditions prior to entering the stream; if the stream stage is to high or the flow looks to turbulent, do not enter. Use stream staff gauge to help assess stream conditions. • Use safety belt with waders to minimize the amount of water which could enter the waders if you fell. • Always wear a personal flotation device before entering the vicinity of the creek. • Lift with your knees. • Get help retrieving the hand augur if it becomes stuck. • Get a buddy to help move equipment and samples to and from the creek. RAC M M M L ACTIVITY HAZARDS ANALYSIS JOB STEPS HAZARDS X Severe Weather X Eye Injury X Foot Injury X Hearing Loss ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Stop collecting samples if severe weather makes sample collection hazards. • Sampling activities stop if there is lightning • Take shelter during severe weather. • Safety glasses in accordance with ANSI Z87.1 will be required during sampling. • Leather steel-toes boots will be required unless the sampler is in the creek and wearing waders. • Hearing protection will be required during slide hammering. X Hand Injury • Gloves will be worn during sampling activities X Decontamination Eye injury •Safety glasses and/or splash shield will be worn. X Working Outdoors Biological • Don snake gaters before leaving paved surfaces • Inspect work areas for poison oak and ivy; if present, alert co-workers. • Be cognizant of wildlife such as turkeys, mountain lions, and bears. RAC L L L L L L L Add Items EQUIPMENT X Automatic Sampler X Weed Whacker X Garden Shears TRAINING Equipment manual, one-on-one instruction from experienced sampler. Equipment manual, one-on-one instruction from field team leader. Equipment manual, one-on-one instruction from field team leader. INSPECTION Look for cracks, damaged equipment, wear and tear. Make sure the equipment is the right size for the planned samples. Inspect pull cord, inspect 'whacker' cord, inspect gas tank for leaks or spills, inspect cord guards. Look for rust spots, broken blade, broken handle. Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greazel, Craig Nochajski, and Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) M Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Stream and Sediment Sampling Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS HAZARDS X Accessing Las Tablas Creek Slippery Creek Bank - slips/trips/falls X Collecting Samples Slippery Work Surface - slips/trips/falls X Working In Running Water X Back Injury X Severe Weather NWW Form 385-1 (Revised) April 2008 ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Remove vegetation that may restrict access to the creek. • Don leather gloves when using garden shears. • Inspect access route for hand holds; if hand holds are not present, then install a rope along access path for a hand hold or keep three points of contact when entering and exiting the creek. • Only access the creek when a co-worker is present and ready to help. • Don snake gaters before leaving paved areas. • Ensure that you have good footing before accessing the sampling device • Use caution when working in the stream and avoid walking on mossy rocks. • Inspect stream conditions prior to entering the stream; if the stream stage is to high or the flow looks to turbulent, do not enter. Use staff gauge to evaluate stream flow. • Use safety belt with waders to minimize the amount of water which could enter the waders if you fell. • Always wear a personal flotation device before entering the vicinity of the creek. • Lift with your knees. • Get a buddy to help move equipment and samples to and from the creek. • Stop collecting samples if severe weather makes sample collection hazards. • Sampling activities stop if there is lightning • Take shelter during severe weather. RAC M M M L L ACTIVITY HAZARDS ANALYSIS JOB STEPS X Eye Injury X Foot Injury X Hearing Loss ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Safety glasses in accordance with ANSI Z87.1 will be required during sampling. • Leather steel-toes boots will be required unless the sampler is in the creek and wearing waders. • Hearing protection will be required during slide hammering. Hand Injury • Gloves will be worn during sampling activities Eye injury •Safety glasses and/or splash shield will be worn. X X X Decontamination Accessing Las Tablas Creek Ranch Reservoir X X HAZARDS Slippery Creek Bank - slips/trips/falls Launching/Loading Boat Deployment/Retrival of Sediment Traps X Deployment/Retrival of Sediment Traps Back injury • Remove vegetation that may restrict access to the creek. • Don leather gloves when using garden shears. • Inspect access route for hand holds; if hand holds are not present, then install a rope along access path for a hand hold or keep three points of contact when entering and exiting the creek. • Only access the creek when a co-worker is present and ready to help. • Don snake gaters before leaving paved areas. • Inspect boat ramp, before launching boat, to look for hazards and to ensure the trailer/truck won't become stuck. • Use a spotter when backing up boat. • Use hand signals, radios, or a spotter to communicate between the boat operator and the person operating the truck. • Refuel outboard motor before launching boat. • Test outboard motor before launching boat. • Inflate back up raft, which will be used incase someone falls out of the boat, prior to launching boat. • Communicate with field partner before leaning over the edge of the boat. • Wear leather gloves when pounding sediment trap into reservoir sediment. • Wear all PPE necessary for accessing Las Tablas Creek Ranch Reservoir. RAC L L L L L L L • Use the buddy system when retrieving sediment traps and measuring sediment within the trap. Add Items EQUIPMENT X Automatic Sampler X Weed Whacker X Garden Shears X Boat NWW Form 385-1 (Revised) April 2008 TRAINING Equipment manual, one-on-one instruction from experienced sampler. Equipment manual, one-on-one instruction from field team leader. Equipment manual, one-on-one instruction from field team leader. One-on-one instruction from experienced boat operator INSPECTION Look for cracks, damaged equipment, wear and tear. Make sure the equipment is the right size for the planned samples. Inspect pull cord, inspect 'whacker' cord, inspect gas tank for leaks or spills, inspect cord guards. Look for rust spots, broken blade, broken handle. Ensure drain plug is in boat, inspect boat for damage, cracks, or missing parts ACTIVITY HAZARDS ANALYSIS Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greazel, Craig Nochajski, Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 ACTIVITY HAZARDS ANALYSIS Overall Risk Assessment Code (RAC) (Use highest code) M Project: Klau Buena Vista Mine Superfund Date: 16 September 2013 Risk Assessment Code Matrix E = Extremely High Risk H = High Risk M = Moderate Risk Frequent L = Low Risk Activity: Surveying Activities at Las Tablas Creek Water Shed Activity Location: Las Tablas Creek Watershed, Paso Robles, CA S e v e r i t y Prepared By: Ryan Wood Probability Likely Occasional Seldom Unlikely Catastrophic E E H H M Critical E H H M L Marginal H M M L L Negligible M L L L L Add Identified Hazards JOB STEPS HAZARDS X Accessing Las Tablas Creek Slippery Creek Bank - slips/trips/falls X Using survey stake Slippery Work Surface - slips/trips/falls X Working In Running Water X Back Injury X Severe Weather NWW Form 385-1 (Revised) April 2008 ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Remove vegetation that may restrict access to the creek. • Inspect weed whacker prior to use; don additional PPE when using the weed whacker. Additional PPE should include face shield, ear plugs, and leather gloves. • Don leather gloves when using garden shears. • Inspect access route for hand holds; if hand holds are not present, then install a rope along access path for a hand hold or keep three points of contact when entering and exiting the creek. • Use a ladder at locations where the creek bank is steep. •Only access the creek when a co-worker is present and ready to help. • Ensure that you have good footing before accessing the sampling device • Use caution when working in the stream and avoid walking on mossy rocks. • Inspect stream conditions prior to entering the stream; if the stream stage is to high or the flow looks to turbulent, do not enter. • Use safety belt with waders to minimize the amount of water which could enter the waders if you fell. • Always wear a personal flotation device before entering the vicinity of the creek or reservoir. • Lift with your knees. • Get help retrieving the hand augur if it becomes stuck. • Get a buddy to help move equipment to and from the creek. • Stop survey if there is severe weather • Survey activities stop if there is lightning • Take shelter during severe weather. RAC M M M L L ACTIVITY HAZARDS ANALYSIS JOB STEPS X Eye Injury X Foot Injury X Hand Injury ACTIONS TO ELIMINATE OR MINIMIZE HAZARDS • Safety glasses in accordance with ANSI Z87.1 will be required during suvey. • Leather steel-toes boots will be required unless the surveyor is in the creek and wearing waders. • Gloves will be worn during survey activities Eye injury • Safety glasses and/or splash shield will be worn. X Decontamination HAZARDS RAC L L L L Add Items EQUIPMENT X Survey Stake X Tape measure X Eye level X Sediment Core Sampler TRAINING Equipment manual, one-on-one instruction from experienced surveyor. Equipment manual, one-on-one instruction from field team leader. Equipment manual, one-on-one instruction from field team leader. Equipment manual, one-on-one instruction from experienced operator INSPECTION Ensure proper measurement markings and sufficient height for eye level Ensure proper measurement markings and sufficient height for eye level Ensure eye level has level and accurate eyesight Inspect sediment core sampler for wear, missing parts, and broken parts. Involved Personnel: The “Designated Competent Person” from CDM Smith for field implementation will be any of the following: Ryan Wood, Andrew Greazel, Craig Nochajski, Ryan Hardenburger. The Health and Safety Officer (SHSO) will be Ryan Wood and Alternate SHSO's may be any of the listed CDM "Designated Competent Persons" for when Ryan Wood is not present at the site. The "Designated Competent Person" from the subcontractor/s will be determined prior to the field work. This AHA was reviewed and approved by Shawn Oliveira, CIH, CSP Director of H&S for CDM Federal Programs Corporation. Acceptance Authority (digital signature): NWW Form 385-1 (Revised) April 2008 Company Name Date PART 5 - PRICE SHEET RFP-1801-049-005-GS KLAU/BUENA VISTA MINES SUPERFUND SITE SAN LUIS OBISPO COUNTY, CALIFORNIA The undersigned declares that the only persons or parties interested in this Request for Proposal (RFP) as principals are as stated; that the Submittal is made without any collusion with other persons, firms, or corporations; that this (RFP) has been carefully examined; that the Offeror is informed fully in regard to all conditions pertaining to the work and the place where it is to be done, and from them, the undersigned makes this bid. The prices bid shall cover all expenses incurred in performing the work required under the Subcontract Documents of which this Price Sheet is a part, including, but not limited to, costs of the following: ∙ Compliance with all health and safety requirements, other Federal, State and local requirements as well as all regulations and requirements of the owners of the surrounding public and/or private properties. ∙ All labor, (including overtime) equipment, materials, supplies, taxes, licensing and permit fees, overhead, and profit All responses shall be valid for 120 days, after the actual date the responses are due. If a Notice of Award, accompanied by at least three undersigned copies of the Subcontract and all other applicable Subcontract Documents, is delivered to the undersigned within 120 days after the actual date the proposals are opened, the undersigned will, within five working days after the date of receipt of such notification, execute and return all copies of the Subcontract and all other applicable Subcontract Documents. This shall include proof of insurance and proof of bonding, if applicable. The undersigned acknowledges receipt of the following amendments: ______________________________________________________________________________ _____________________________________________________________________________ In accordance with the above understanding, the subcontractor proposes to furnish all materials, and perform and complete the Work in its entirety in the manner and under the conditions required, at the prices listed on the following pages of this Price Sheet. All extensions of the unit price shown will be subject to verification by CDM Federal Programs Corporation. In case of variation between the unit price and the extension, the unit price will be considered to be the proposal. RFP-1 Company Name Date PART 5 - PRICE SHEET RFP-1801-049-005-GS KLAU/BUENA VISTA MINES SUPERFUND SITE SAN LUIS OBISPO COUNTY, CALIFORNIA Line Item 1 Description Bathymetric Survey – shall include all costs associated with performing the Statement of Work, including (but not limited to) mobilization/demobilization, bathymetric survey services and reporting costs Unit Est Qty Lump Sum 1 Total $ Total Price $ Include pricing detail (position, rate, hours, materials, etc.) for the item above: RFP-2 Company Name Date PART 5 - PRICE SHEET RFP-1801-049-005-GS KLAU/BUENA VISTA MINES SUPERFUND SITE SAN LUIS OBISPO COUNTY, CALIFORNIA The Total Amount of Proposal is defined as the sum of the Total Price Proposed for each item. The Contractor reserves the right to omit in its entirety any one or more items of this Subcontract without forfeiture of Subcontractor or claims for loss of anticipated profits or any other claims by the Subcontractor on account of such omissions. The names and business addresses of all person and parties interested in the foregoing Proposal as principals are as follows: (Give first and last names in full). Notice of acceptance should be mailed, telegraphed or delivered to the undersigned Offeror at the following address: (Business Address) (City, State and Zip Code) (Name of Offeror) (Email of Offeror) By: (Signature) (Title) I , ______________________ certify that there are no personal or organizational conflicts of interest or perceived conflicts of interest in the performance of this work. Date: (Signature) (Title) Note: If the Offeror is a corporation, indicate State of incorporation under signature, and affix corporate seal; if a partnership, give full names and residential addresses of partners, if different from business address. RFP-3 PART 6 REPRESENTATIONS AND CERTIFICATIONS Confidential Business Information REPRESENTATIONS AND CERTIFICATIONS Various Federal statutes and regulations require certain representations, certifications, and other statements from bidders/offerors in connection with the award of subcontracts. • • • All bidders/offerors shall complete Items 1 through 8 and Item 13. Bidders shall complete Items 9 and 10 if the solicitation is an Invitation for Bid (IFB). Bidders/offerors shall complete Items 11 and 12 if required, as indicated by an "X". The Following Representations Are Required for All Procurements 1. 2. 3. 4. 5. 6. Taxpayer Identification (FAR 52.204-3) Prohibition on Contracting with Inverted Domestic Corporations – Representation (FAR 52.209-2) Small Business Program Representations (FAR 52.219-1) Previous Contracts and Compliance Reports (FAR 52.222-22) Affirmative Action Compliance (FAR 52.222-25) Prohibition on Contracting with Entities Engaging in Certain Activities or Transactions Relating to Iran—Representation and Certifications (FAR 52.225-25) 7. Historically Black College or University and Minority Institution Representation (FAR 52.226-2) 8. Representation of Limited Rights Data and Restricted Computer Software (FAR 52.227-15) The Following Representations Are Required for All Sealed Bidding Procurements 9. Minimum Bid Acceptance Period (FAR 52.214-16) 10. Equal Low Bids (FAR 52.219-2) The Following Representations Are Required Only If Indicated 11. ___ Recovered Material Certification (FAR 52.223-4) – Applies to procurements that specify the use of EPA-designated products containing recovered materials. Does not apply to A&E services. 12. ___ Preparation of Proposals - Construction (FAR 52.236-28) – Applies to construction procurements when subcontracting by negotiation. Required for All Procurements 13. Certification and Agreement 1 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information REPRESENTATIONS AND CERTIFICATIONS Definitions. • The terms "offeror" or “bidder” as used herein include the Subcontractor. • The term "Government” includes CDM Federal Programs Corporation (CDM Smith). • The term "offer" includes bid. • The term “contract” includes subcontract. The Following Representations Are Required for All Procurements 1. TAXPAYER IDENTIFICATION (FAR 52.204-3) (OCT 1998) (Modified) (a) Definitions. "Common parent", as used in this provision, means that corporate entity that owns or controls an affiliated group of corporations that files its Federal income tax returns on a consolidated basis, and of which the offeror is a member. "Taxpayer Identification Number (TIN)", as used in this provision, means the number required by the Internal Revenue Service (IRS) to be used by the offeror in reporting income tax and other returns. The TIN may be either a Social Security Number or an Employer Identification Number. (b) All offerors must submit the information required in paragraphs (d) through (f) of this provision in order to comply with debt collection requirements of 31 U.S.C. 7701(c) and 3325(d), reporting requirements of 26 U.S.C. 6041, 6041A, and 6050M, and implementing regulations issued by the IRS. If the resulting subcontract is subject to the payment reporting requirements described in Federal acquisition regulation (FAR) 4.904, the failure or refusal by the offeror to furnish the information may result in a 31 percent reduction of payments otherwise due under the subcontract. (c) The TIN may be used by the Government to collect and report on any delinquent amounts arising out of the offeror's relationship with the Government (31 U.S.C. 7701(c)(3)). If the resulting requirements described in FAR 4.904, the TIN provided hereunder may be matched with IRS records to verify the accuracy of the offeror's TIN. (d) Taxpayer Identification Number (TIN). [ [ [ [ ] ] ] ] TIN: . TIN has been applied for. TIN is not required because: Offeror is a nonresident alien, foreign corporation, or foreign partnership that does not have income effectively connected with the conduct of a trade or business in the U.S. and does not have an office or place of business or a fiscal paying agent in the U.S. [ ] Offeror is an agency or instrumentality of a foreign government. [ ] Offeror is an agency or instrumentality of the Federal government. [ ] Other. State basis ______________________________________. (e) Type of Organization. [ [ [ [ [ [ [ [ ] ] ] ] ] ] ] ] Sole proprietorship. Partnership. Corporate entity (not tax-exempt) Corporate entity (tax exempt) Government entity (Federal, State, or local) Foreign government International organization per 25 CFR 1.6049-4 Other __________________________________ 1 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information (f) Common Parent. [ ] Offeror is not owned or controlled by a common parent as defined in paragraph (a) of this provision. [ ] Name and TIN of common parent: Name ________________________________________________________ TIN ________________________________________________________ (g) The offeror should supply the Data Universal Numbering System (DUNS) Number applicable to its name and address. If the offeror does not have a DUNS Number, it may obtain one from any Dun and Bradstreet Branch Office. DUNS NO.: _________________________ (End of Provision) 2. PROHIBITION ON CONTRACTING WITH INVERTED DOMESTIC CORPORATIONS – REPRESENTATION (FAR 52.209-2) (MAY 2011) (a) Definitions. Inverted domestic corporation and subsidiary have the meaning given in the clause of this contract entitled Prohibition on Contracting with Inverted Domestic Corporations (52.209-10). (b) Relation to Internal Revenue Code. An inverted domestic corporation as herein defined does not meet the definition of an inverted domestic corporation as defined by the Internal Revenue Code at 26 U.S.C. 7874. (c) Representation. By submission of its offer, the offeror represents that— (1) It is not an inverted domestic corporation; and (2) It is not a subsidiary of an inverted domestic corporation. (End of Provision) 3. SMALL BUSINESS PROGRAM REPRESENTATIONS (FAR 52.219-1) (APR 2012) (a) (1) The North American Industry Classification System (NAICS) code for this acquisition is 541370. (2) The small business size standard is $15M. (3) The small business size standard for a concern which submits an offer in its own name, other than on a construction or service contract, but which proposes to furnish a product which it did not itself manufacture, is 500 employees. (b) Representations. (Indicate business size based on the date your Price Proposal was submitted to CDM Smith or the date CDM Smith notified you the rates proposed were accepted by CDM Smith, whichever date is later) (1) The offeror represents as part of its offer that it [ ] is a small business concern. [ ] is not a small business concern. (2) [Complete only if offeror represented itself as a small business concern in paragraph (b)(1) of this provision.] The offeror represents, for general statistical purposes, that it [ ] is a small disadvantaged business concern as defined in 13 CFR 124.1002. [ ] is not a small disadvantaged business concern as defined in 13 CFR 124.1002. 2 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information (3) [Complete only if the offeror represented itself as a small business concern in paragraph (b)(1) of this provision.] The offeror represents as part of its offer that it [ ] is a women-owned small business concern. [ ] is not a women-owned small business concern. (4) Women-owned small business (WOSB) concern eligible under the WOSB Program. [Complete only if the offeror represented itself as a women-owned small business concern in paragraph (b)(3) of this provision.] The offeror represents as part of its offer that it (i) [ ] is a WOSB concern eligible under the WOSB Program, has provided all the required documents to the WOSB Repository, and no change in circumstances or adverse decisions have been issued that affects its eligibility. [ ] is not a WOSB concern eligible under the WOSB Program. (ii) [ ] is a joint venture that complies with the requirements of 13 CFR part 127, and the representation in paragraph (b)(4)(i) of this provision is accurate for each WOSB concern eligible under the WOSB Program participating in the joint venture. [The offeror shall enter the name or names of the WOSB concern eligible under the WOSB Program and other small businesses that are participating in the joint venture: ___________________________________________________.] Each WOSB concern eligible under the WOSB Program participating in the joint venture shall submit a separate signed copy of the WOSB representation. [ ] is not a joint venture. (5) Economically disadvantaged women-owned small business (EDWOSB) concern. [Complete only if the offeror represented itself as a women-owned small business concern eligible under the WOSB Program in (b)(4) of this provision.] The offeror represents as part of its offer that it (i) [ ] is an EDWOSB concern eligible under the WOSB Program, has provided all the required documents to the WOSB Repository, and no change in circumstances or adverse decisions have been issued that affects its eligibility. [ ] is not an EDWOSB concern eligible under the WOSB Program. (ii) [ ] is a joint venture that complies with the requirements of 13 CFR part 127, and the representation in paragraph (b)(5)(i) of this provision is accurate for each EDWOSB concern participating in the joint venture. [The offeror shall enter the name or names of the EDWOSB concern and other small businesses that are participating in the joint venture: ______________________.] Each EDWOSB concern participating in the joint venture shall submit a separate signed copy of the EDWOSB representation. [ ] is not a joint venture. (6) [Complete only if the offeror represented itself as a small business concern in paragraph (b)(1) of this provision.] The offeror represents as part of its offer that it [ ] is a veteran-owned small business concern. [ ] is not a veteran-owned small business concern. (7) [Complete only if the offeror represented itself as a veteran-owned small business concern in paragraph (b)(4) of this provision.] The offeror represents as part of its offer that it [ ] is a service-disabled veteran-owned small business concern. [ ] is not a service-disabled veteran-owned small business concern. (8) [Complete only if the offeror represented itself as a small business concern in paragraph (b)(1) of this provision]. The offeror represents, as part of its offer, that it 3 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information (i) [ ] is a HUBZone small business concern listed, on the date of this representation, on the List of Qualified HUBZone Small Business Concerns maintained by the Small Business Administration, and no material change in ownership and control, principal office, or HUBZone employee percentage has occurred since it was certified by the Small Business Administration in accordance with 13 CFR part 126; and [ ] is not a HUBZone small business concern. (ii) [ ] is a HUBZone joint venture that complies with the requirements of 13 CFR part 126, and the representation in paragraph (b)(8)(i) of this provision is accurate for each HUBZone small business concern participating in the HUBZone joint venture. [The offeror shall enter the names of the HUBZone small business concerns participating in the HUBZone joint venture: __________________________________________]. Each HUBZone small business concern participating in the HUBZone joint venture shall submit a separate signed copy of the HUBZone representation. [ ] is not a joint venture. (c) Definitions. As used in this provision “Economically disadvantaged women-owned small business (EDWOSB) concern” means a small business concern that is at least 51 percent directly and unconditionally owned by, and the management and daily business operations of which are controlled by, one or more women who are citizens of the United States and who are economically disadvantaged in accordance with 13 CFR part 127. It automatically qualifies as a women-owned small business concern eligible under the WOSB Program. "Service-disabled veteran-owned small business concern" (1) Means a small business concern: (i) Not less than 51 percent of which is owned by one or more service-disabled veterans or, in the case of any publicly owned business, not less than 51 percent of the stock of which is owned by one or more service-disabled veterans, and (ii) The management and daily business operations of which are controlled by one or more service-disabled veterans, or in the case of a service-disabled veteran with permanent and severe disability, the spouse or permanent caregiver of such veteran. (2) Services-disabled veteran means a veteran, as defined in 38 U.S.C. 101(2), with a disability that is service-connected, as defined in 38 U.S.C. 101(16). "Small business concern" means a concern, including its affiliates, that is independently owned and operated, not dominant in the field of operation in which it is bidding on government contracts, and qualified as a small business under the criteria in 13 CFR Part 121 and the size standard in paragraph (a) of this provision. "Veteran-owned small business concern" means a small business concern: (1) Not less than 51 percent of which is owned by one or more veterans (as defined in 38 U.S.C. 101(2)) or, in the case of any publicly owned business, not less than 51 percent of the stock of which is owned by one or more veterans, and (2) The management and daily business operations of which are controlled by one or more veterans. "Women-owned small business concern" means a small business concern: 4 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information (1) That is at least 51 percent owned by one or more women or, in the case of any publicly owned business, at least 51 percent of the stock of which is owned by one or more women, and (2) Whose management and daily business operations are controlled by one or more women. “Women-owned small business (WOSB) concern eligible under the WOSB Program” (in accordance with 13 CFR part 127), means a small business concern that is at least 51 percent directly and unconditionally owned by, and the management and daily business operations of which are controlled by, one or more women who are citizens of the United States. (d) Notice. (1) If this solicitation is for supplies and has been set aside, in whole or in part, for small business concerns, then the clause in the solicitation providing notice of the set-aside contains restrictions on the source of the end items to be furnished. (2) Under 15 U.S.C. 645(d), any person who misrepresents a firm's status as a small, HUBZone small, small disadvantaged, service-disabled veteran-owned small, economically disadvantaged women-owned small, or women-owned small eligible under the WOSB Program business in order to obtain a contract to be awarded under the preference programs established pursuant to section 8, 9, 15, 31, and 36 of the Small Business Act or any other provision of Federal law that specifically references section 8(d) for a definition of program eligibility, shall: (i) be punished by imposition of a fine, imprisonment, or both; (ii) be subject to administrative remedies, including suspension and debarment; and (iii) be ineligible for participation in programs conducted under the authority of the Act. (End of Provision) Alternate I (Apr 2011). As prescribed in 19.309(a)92), add the following (b)(9) to the basic provision: (9) [Complete if offeror represented itself as disadvantaged in paragraph (b)(2) of this provision]. The offeror shall check the category in which its ownership falls: _____ Black American _____ Hispanic American _____ Native American (American Indians, Eskimos, Aleuts, or Native Hawaiians). _____ Asian-Pacific American (persons with origins from Burma, Thailand, Malaysia, Indonesia, Singapore, Brunei, Japan, China, Taiwan, Laos, Cambodia (Kampuchea), Vietnam, Korea, The Philippines, U.S. Trust Territory of the Pacific Islands (Republic of Palau), Republic of the Marshall Islands, Federated States of Micronesia, The Commonwealth of the Northern Mariana Islands, Guam, Samoa, Macao, Hon Kong, Fiji, Tonga, Kiribati, Tuvalu, or Nauru). _____ Subcontinent Asian (Asian-Indian) American (persons with origins from India, Pakistan, Bangladesh, Sri Lanka, Bhutan, the Maldives Islands, or Nepal). _____ Individual/concern, other than one of the preceding. (End of Provision) 4. PREVIOUS CONTRACTS AND COMPLIANCE REPORTS (FAR 52.222-22) (FEB 1999) The offeror represents that it has: (a) [ ] participated [ ] not participated in a previous contract or subcontract subject to the Equal Opportunity clause of this solicitation; (b) [ ] filed [ ] not filed all required compliance reports; and 5 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information (c) representations indicating submission of required compliance reports, signed by proposed subcontractors, will be obtained before subcontract awards. (End of Provision) 5. AFFIRMATIVE ACTION COMPLIANCE (FAR 52.222-25) (APR 1984) (Does not apply to awards for construction) The offeror represents that it: (a) [ ] has developed and has on file, [ ] has not developed and does not have on file, at each establishment, affirmative action programs required by the rules and regulations of the Secretary of Labor (41 CFR 60-1 and 60-2), or (b) [ ] has not previously had contracts subject to the written affirmative action programs requirements of the rules and regulations of the Secretary of Labor. (End of Provision) 6. PROHIBITION ON CONTRACTING WITH ENTITIES ENGAGING IN CERTAIN ACTIVITIES OR TRANSACTIONS RELATING TO IRAN – REPRESENTATION AND CERTIFICATIONS (52.225-25) (DEC 2012) (a) Definitions. As used in this provision— “Person”— (1) Means— (i) A natural person; (ii) A corporation, business association, partnership, society, trust, financial institution, insurer, underwriter, guarantor, and any other business organization, any other nongovernmental entity, organization, or group, and any governmental entity operating as a business enterprise; and (iii) Any successor to any entity described in paragraph (1)(ii) of this definition; and (2) Does not include a government or governmental entity that is not operating as a business enterprise. “Sensitive technology”— (1) Means hardware, software, telecommunications equipment, or any other technology that is to be used specifically— (i) To restrict the free flow of unbiased information in Iran; or (ii) To disrupt, monitor, or otherwise restrict speech of the people of Iran; and (2) Does not include information or informational materials the export of which the President does not have the authority to regulate or prohibit pursuant to section 203(b)(3) of the International Emergency Economic Powers Act (50 U.S.C. 1702(b)(3)). (b) The offeror shall e-mail questions concerning sensitive technology to the Department of State at CISADA106@state.gov. (c) Except as provided in paragraph (d) of this provision or if a waiver has been granted in accordance with 25.703-4, by submission of its offer, the offeror— 6 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information (1) Represents, to the best of its knowledge and belief, that the offeror does not export any sensitive technology to the government of Iran or any entities or individuals owned or controlled by, or acting on behalf or at the direction of, the government of Iran; (2) Certifies that the offeror, or any person owned or controlled by the offeror, does not engage in any activities for which sanctions may be imposed under section 5 of the Iran Sanctions Act. These sanctioned activities are in the areas of development of the petroleum resources of Iran, production of refined petroleum products in Iran, sale and provision of refined petroleum products to Iran, and contributing to Iran's ability to acquire or develop certain weapons or technologies; and (3) Certifies that the offeror, and any person owned or controlled by the offeror, does not knowingly engage in any transaction that exceeds $3,000 with Iran's Revolutionary Guard Corps or any of its officials, agents, or affiliates, the property and interests in property of which are blocked pursuant to the International Emergency Economic Powers Act (50 U.S.C. 1701 et seq.) (see OFAC's Specially http://www.treasury.gov/ Designated Nationals and Blocked Persons List at ofac/downloads/t11sdn.pdf). (d) Exception for trade agreements. The representation requirement of paragraph (c)(1) and the certification requirements of paragraphs (c)(2) and (c)(3) of this provision do not apply if— (1) This solicitation includes a trade agreements notice or certification (e.g., 52.225-4, 52.2256, 52.225-12, 52.225-24, or comparable agency provision); and (2) The offeror has certified that all the offered products to be supplied are designated country end products or designated country construction material. (End of Provision) 7. HISTORICALLY BLACK COLLEGE OR UNIVERSITY AND MINORITY INSTITUTION REPRESENTATION (FAR 52.226-2) (OCT 2008) (a) Definitions. As used in this provision: "Historically black college or university" means an institution determined by the Secretary of Education to meet the requirements of 34 CFR 608.2. For the Department of Defense, the National Aeronautics and Space Administration, and the Coast Guard, the term also includes any nonprofit research institution that was an integral part of such a college/university before November 14, 1986. "Minority institution" means an institution of higher education meeting the requirements of Section 365(3) of the Higher Education Act of 1965 (20 U.S.C. 1067k), including a Hispanic-serving institution of higher education, as defined in Section 502(a) of the Act (20 U.S.C. 1101a). (b) Representation. The offeror represents that it: [ [ [ [ ] is a Historically Black College or University, ] is not a Historically Black College or University; ] is a Minority Institution, ] is not a Minority Institution. (End of Provision) 8. REPRESENTATION OF LIMITED RIGHTS DATA AND RESTRICTED COMPUTER SOFTWARE (FAR 52.227-15) (DEC 2007) (a) This solicitation sets forth the Government’s known delivery requirements for data (as defined in the clause at 52.227-14, Rights in Data—General). Any resulting contract may also provide the Government the option to order additional data under the Additional Data Requirements clause at 52.227-16, if included in the contract. Any data delivered under the resulting contract will be subject to 7 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information the Rights in Data—General clause at 52.227-14 included in this contract. Under the latter clause, a Contractor may withhold from delivery data that qualify as limited rights data or restricted computer software, and deliver form, fit, and function data instead. The latter clause also may be used with its Alternates II and/or III to obtain delivery of limited rights data or restricted computer software, marked with limited rights or restricted rights notices, as appropriate. In addition, use of Alternate V with this latter clause provides the Government the right to inspect such data at the Contractor’s facility. (b) By completing the remainder of this paragraph, the offeror represents that it has reviewed the requirements for the delivery of technical data or computer software and states [offeror check appropriate block] [ ] (1) None of the data proposed for fulfilling the data delivery requirements qualifies as limited rights data or restricted computer software; or [ ] (2) Data proposed for fulfilling the data delivery requirements qualify as limited rights data or restricted computer software and are identified as follows. ________________________________________________________________________________ ________________________________________________________________________________ (c) Any identification of limited rights data or restricted computer software in the offeror’s response is not determinative of the status of the data should a contract be awarded to the offeror. (End of Provision) The Following Representations Are Required for All Sealed Bidding Procurements 9. MINIMUM BID ACCEPTANCE PERIOD (FAR 52.214-16) (APR 1984) (a) "Acceptance period," as used in this provision, means the number of calendar days available to the Government for awarding a contract from the date specified in this solicitation for receipt of bids. (b) This provision supersedes any language pertaining to the acceptance period that may appear elsewhere in this solicitation. (c) The Government requires a minimum acceptance period of 120 calendar days [the Contract Officer shall insert the number of days]. (d) In the space provided immediately below, bidders may specify a longer acceptance period than the Government's minimum requirement. The bidder allows the following acceptance period: _____ calendar days. (e) A bid allowing less than the Government's minimum acceptance period will be rejected. (f) The bidder agrees to execute all that it has undertaken to do, in compliance with its bid, if that bid is accepted in writing within (1) the acceptance period stated in paragraph (c) above or (2) any longer acceptance period stated in paragraph (d) above. (End of Provision) 10. EQUAL LOW BIDS (FAR 52.219-2) (OCT 1995) (a) This provision applies to small business concerns only. (b) The bidder’s status as a labor surplus area (LSA) concern may affect entitlement to award in case of tie bids. If the bidder wishes to be considered for this priority, the bidder must identify, in the following space, the LSA in which the costs to be incurred on account of manufacturing or production (by the bidder or the first-tier subcontractors) amount to more than 50 percent of the subcontract price. 8 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information ________________________________________________________________________________ ________________________________________________________________________________ (c) Failure to identify the LSAs as specified in paragraph (b) of this provision will preclude the bidder from receiving priority consideration. If the bidder is awarded a subcontract as a result of receiving priority consideration under this provision and would not have otherwise received award, the bidder shall perform the subcontract or cause the subcontract to be performed in accordance with the obligations of an LSA concern. (End of Provision) The Following Representations Are Required Only If Indicated On The Cover Page 11. RECOVERED MATERIAL CERTIFICATION (FAR 52.223-4) (MAY 2008) As required by the Resource Conservation and Recovery Act of 1976 (42 U.S.C. 6962(c)(3)(A)(i)), the offeror certifies, by signing this offer, that the percentage of recovered materials content for EPAdesignated items to be delivered or used in the performance of the subcontract will be at least the amount required by the applicable subcontract specifications or other contractual requirements. (End of Provision) 12. PREPARATION OF PROPOSALS - CONSTRUCTION (52.236-28) (OCT 1997) (a) Proposals must be (1) submitted on the forms furnished by the Government or on copies of those forms; and (2) manually signed. The person signing the proposal must initial each erasure or change appearing on any proposal form. (b) The proposal form may require offerors to submit proposed prices for one or more items on various bases, including: (1) (2) (3) (4) Lump sum price, Alternate prices, Units of construction, or Any combination or paragraphs (b)(1) through (b)(3) of this provision. (c) If the solicitation requires submission of a proposal on all items, failure to do so may result in the proposal being rejected without further consideration. If a proposal on all items is not required, offerors should insert the words “no proposal” in the space provided for any item on which no proposal is submitted. (d) Alternate proposals will not be considered unless this solicitation authorizes their submission. (End of Provision) 9 1801.049.005.Part6.docx (Rev Aug 2013) Confidential Business Information Required for All Procurements 13. CERTIFICATION AND AGREEMENT By signing below the offeror certifies that all the above representations and certifications are accurate, current and complete. FIRM: __________________________________________________________________________ ADDRESS: _______________________________________________________________________ SIGNATURE: _____________________________________________________________________ DATE: __________________________________________________________________________ NOTE: The penalty for making false statements in offers is prescribed in 18 U.S.C. 1001. 10 1801.049.005.Part6.docx (Rev Aug 2013) PART 7 SAMPLE SERVICE ORDER AND TERMS AND CONDITIONS and SUPPLEMENTAL CONDITIONS CDM Federal Programs Corporation 3201 Jermantown Road Suite 400 Fairfax, Virginia 22030 (703) 691-6500 / Fax (703) 267-6083 SERVICE ORDER NO. : TRACKING NO.: Page 1 of 1 Government Client: U.S. Environmental Protection Agency Prime Contract No./WA/DO/TO No.: GS-10F-0227J Prime Contractor: CDM Federal Programs Corporation Note: All contact with client MUST be through CDM Federal Programs Corporation unless initiated by client. Service Provider’s Name & Address: [X ] [X ] [X ] [ ] Architect-Engineer Contract Service Contract Act is applicable Wage determination is applicable Waiver of Professional E&O insurance: [ ] Firm Fixed Price (lump sum) [X ] Fixed Unit Price (ID/IQ) [ ]Time & Materials (Not to Exceed $__________ Business Size:_______ *S.O. DATE SUBCONTRACT ADMINISTRATOR PERIOD OF PERFORMANCE PAYMENT TERMS K. Merold ITEM NO. N42 DESCRIPTION OF SERVICES QTY. UNIT UNIT PRICE EXT. PRICE CDM Federal Programs Corporation Service Order Terms and Conditions, Supplemental Conditions, Health and Safety Plan and Service Contract Act Wage Rates are attached and made a part of this Agreement. NOTES: *Order must be signed and returned within 10 days of Service Order date. Accepted by: Service Provider Signature Date CDM Federal Programs Corporation Signature Subject to the Service Order Standard Terms and Conditions dated August 2012 Rev. 2 Rev. 1-8/07 TOTAL: ORIGINAL Date Page 1 SERVICE ORDER FOR PROFESSIONAL SERVICES (UNDER $150,000) STANDARD TERMS AND CONDITIONS ARTICLE 1. DEFINITIONS A. Prime Contract. The agreement, referenced on the first page of this Service Order, between an Agency of the United States Government and its Prime Contractor B. CDM SMITH. CDM Federal Programs Corporation, the Prime Contractor. C. SERVICE PROVIDER. The entity referenced on the first page of this Service Order. D. Lower Tier Subcontract. Agreements at any level below this Service Order to provide some portion of the services specified herein in privity with the SERVICE PROVIDER. E. Professional Services. Services include, but are not limited to, analytical laboratory, ground and aerial surveying, environmental engineering, and consulting. F. Scope of Services. A description of the work to be performed or the services to be provided. ARTICLE 2. SCOPE OF SERVICES A. SERVICE PROVIDER shall perform the services as described on the signature page of this Service Order or in Exhibit A, "Scope of Services", in accordance with the terms and conditions of this Service Order. ARTICLE 3. TERMS OF PAYMENT A. Invoicing. (1) An invoice is a written request for payment for services rendered. In order to be deemed proper, all invoices shall indicate an invoice date, name of the provider, Service Order number, tracking number, number of hours worked if applicable, dates of performance and unit rates specified herein. Copies of delivery tickets, time sheets, or other items as may be reasonably required by CDM SMITH to support quantities delivered or performed shall be submitted with each invoice. Invoices shall be emailed to CDMFED-Invoicing@cdmsmith.com with the Subject line typed exactly as follows – Subcontractor shall insert invoice number in the blank to complete the subject line (invoices with an improper subject line may be returned for correction): Subject: _____/______________/_____/_________/Invoice#____ (2) SERVICE PROVIDER may submit invoices to CDM SMITH for progress payments not more than once each month (small business firms may submit twice each month). Such invoices shall represent the value of the completed Scope of Services, less 10% retainage (if applicable), and will be prepared in a format and supported by documentation as CDM SMITH may reasonably require. Invoices will be reviewed and accepted by CDM SMITH before payment will be processed. (3) SERVICE PROVIDER shall maintain records, including supporting documentation, as is necessary to demonstrate that all costs claimed have been incurred, are allocable to this Service Order, and comply with applicable cost principles in FAR Part 31. Travel costs, if authorized by CDM SMITH, shall be considered reasonable and allowable to the extent that they comply with government per diem rates in effect at the time of travel as prescribed in the Federal Travel Regulations or Joint Travel Regulations as applicable. B. Payment. Payments will be made in accordance with the applicable payment clause incorporated into this Service Order within forty-two (42) calendar days at the unit prices specified herein, for work which is completed and accepted in accordance with the applicable “Inspection” clause. C. Final Payment. Final payment of any balance will be made upon completion of the Scope of Services and receipt and acceptance of all deliverables, documents and data that are required to be furnished under this Service Order. SERVICE PROVIDER shall also complete and submit the Closeout Release located on the last page hereunder. Payment may be withheld, in whole or in part, pending resolution of any disputed claims. ARTICLE 4. OBLIGATION OF SERVICE PROVIDER A. Independent Contractor. SERVICE PROVIDER is an independent contractor and will maintain complete control of and responsibility for its employees, agents, lower tier subcontractors, methods and operations. Nothing contained in this Service Order will create any contractual relationship between the Government and SERVICE PROVIDER. B. Lower Tier Subcontracts. (1) SERVICE PROVIDER must obtain CDM SMITH’s advance written consent for the use of any lower tier subcontractors. SERVICE PROVIDER shall bind all lower tier subcontractors to the applicable provisions of this Service Order. (2) Neither this Service Order nor any lower tier subcontract will create any contractual relationship between any lower tier subcontractor and CDM SMITH; nor does this Service Order create any contractual relationship between SERVICE PROVIDER and any upper tier contractor, including the Government. C. Performance. The standard of care applicable to SERVICE PROVIDER’s services will be the degree of skill and diligence normally employed by providers performing the same or similar services. The SERVICE PROVIDER will reperform any services not meeting this standard without additional compensation. If such deficiencies are not corrected in a timely manner, CDM SMITH may cause the same to be corrected or reperformed and deduct costs, including any costs of reprocurement incurred, from SERVICE PROVIDER’s compensation. D. Insurance. The SERVICE PROVIDER shall maintain throughout the period of performance of this Service Order the insurance coverages as required in Attachment E and will submit certificates certifying such to CDM SMITH prior to commencing work. E. Indemnification. (1) To the fullest extent permitted by law, the SERVICE PROVIDER shall indemnify, hold harmless and defend CDM SMITH and the Government and their consultants, officers, directors and employees from and against any and all claims, damages, demands, suits, actions, judgments, liabilities or costs or expenses of any nature including reasonable attorney’s fees, to the extent caused by or occasioned by any negligent act, error or omission of Subcontractor, its lower tier subcontractors or anyone for whose actions Subcontractor is legally responsible in the performance of services under this Subcontract or arising from SERVICE PROVIDER’s breach of this Subcontract. (2) The SERVICE PROVIDER also agrees to indemnify, hold harmless and defend CDM SMITH from any and all liability, claims, suits, demands, actions, judgments, liabilities or costs or expenses including reasonable attorney’s fees, to the extent arising from: (a) Claims brought by the employees of the SERVICE PROVIDER or SERVICE PROVIDER lower tier subcontractor employees. (b) Any cost or pricing data furnished or required to be furnished by the SERVICE PROVIDER or its lower tier subcontractors which was not complete, accurate or current. (c) A violation by the SERVICE PROVIDER of any applicable law, rule, or regulation. (d) Any penalty or fine incurred by or assessed against CDM SMITH to the extent attributable to the actions of the SERVICE PROVIDER, its employees, agents, suppliers, or lower tier subcontractors. (e) Any failure on the part of SERVICE PROVIDER to follow health or safety procedures applicable to the site and specified by either CDM SMITH or any other entity authorized to specify such procedures or any failure to follow recognized industry standards. (f) Any finding involving SERVICE PROVIDER’s area of responsibility pursuant to the clause relating to price reduction for defective cost or pricing data. (g) Any finding that SERVICE PROVIDER had violated the clause requiring price or fee adjustment for illegal or improper activity (FAR 52.203-10). (h) Any failure on the part of the Subcontractor to comply with the provisions of FAR 52.230-2 Cost Accounting Standards, or FAR 52.230-6 Administration of Cost Accounting Standards, if applicable to this Subcontract. (3) The indemnification stated in Clauses (1) and (2) above shall not be limited in any way by any limitation on the amount or type of damages, compensation or benefits payable by or for, the Subcontractor or any lower tier subcontractor under worker's compensation statutes. The parties waive the protection of applicable worker's compensation acts, to the extent permitted or required by applicable law. PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) (4) Except for SERVICE PROVIDER’s indemnity obligations as stated above, in no event shall either party be responsible or liable for indirect, special, punitive, incidental or consequential damages, or lost profits or revenues, even if the other party has been advised of the possibility of such damages. (5) In the event that it is necessary to enforce the indemnity obligation herein, the losing party in any such enforcement action shall pay the prevailing party's court costs and reasonable attorney's fees. (6) SERVICE PROVIDER acknowledges specific payment of one hundred dollars ($100) incorporated into the Payment made under this Agreement and other valuable consideration the receipt and adequacy which is also acknowledged as legal consideration for SERVICE PROVIDER’s indemnity obligations as may be provided in this Agreement. F. Liens. SERVICE PROVIDER shall promptly pay for all services, labor, material and equipment used or employed in delivering the Scope of Services and shall maintain the materials, equipment, structures, buildings, premises and other subject matter hereof free and clear of mechanics’ or other liens. SERVICE PROVIDER shall provide executed releases of liens from all lower tier subcontractors or material suppliers with each invoice. G. Codes, Laws and Regulations. SERVICE PROVIDER shall comply with all applicable local, state and federal codes, laws, regulations, standards, ordinances and regulations in force during the term of this Service Order. Failure to comply with any applicable code, law, regulation, standard or ordinance shall be cause for immediate default termination of this Service Order. SERVICE PROVIDER is responsible for understanding and assuring compliance, by its employees and lower tier subcontractors, of all codes, laws, regulations, standards or ordinances applicable to the Scope of Services to be performed under the terms of this Service Order. H. Permits, Licenses and Fees. SERVICE PROVIDER shall obtain and pay for all permits and licenses required by law that are associated with SERVICE PROVIDER’s performance of the Scope of Services and will give all necessary notices. I. Publicity. SERVICE PROVIDER shall not disclose the nature of its Scope of Services or engage in any public media disclosure with respect to this Service Order without the prior written consent of CDM SMITH. J. Key Personnel. (1) SERVICE PROVIDER shall provide qualified personnel to perform its Scope of Services. Within five (5) days of execution of this Service Order or receipt of a written authorization to proceed, the SERVICE PROVIDER shall submit a list of key personnel for its work, including a designated Scope of Services manager, and resumes therefore, if requested by CDM SMITH. SERVICE PROVIDER shall not change or reassign any of the designated key personnel without the written approval of CDM SMITH. (2) If, at any time, CDM SMITH finds any SERVICE PROVIDER employee, agent, consultant or representative to be unacceptable, for whatever reason, CDM SMITH may request the SERVICE PROVIDER to replace at no additional cost that employee, agent, consultant or representative with another person who has at least the equivalent level of qualifications. K. Copies of Data. One legible copy each, unless additional copies are requested, of all notes, field notes, drawings, prints and plans prepared under the terms of this Service Order shall be delivered by SERVICE PROVIDER to CDM SMITH upon completion of the Scope of Services. L. Additional Information. SERVICE PROVIDER shall not separately solicit or accept from the Government any assignments, directly or indirectly related to the Scope of Services, during the life of the Service Order without obtaining CDM SMITH’s written approval. However, this paragraph in no way restricts SERVICE PROVIDER’s right to respond to specific requests from the Government. M. Errors and Omissions: Quality Control. SERVICE PROVIDER is solely responsible for the quality of its work or services and agrees to conduct quality control measures and techniques suitable and appropriate for the scope and characteristics of the Scope of Services and disciplines involved in delivery of the Scope of Services. CDM SMITH and others will rely on the quality and accuracy of the work produced and services performed by SERVICE PROVIDER and will not necessarily verify the accuracy or quality of SERVICE PROVIDER’s work produced and services delivered. However, CDM SMITH reserves the right to conduct an inspection of the technical work or take whatever other steps it feels may be necessary or useful to maintain the quality of SERVICE PROVIDER’s performance. In the event that either party should discover errors or omissions in the work or services of the other party, the discovering party shall report to the other party such errors or omissions, actual or suspected, in order that the party providing such Page 2 work or services may take measures which will minimize the consequences of such errors or omissions. N. Suspension of Work. SERVICE PROVIDER shall, upon written notice from CDM SMITH, suspend, delay or interrupt, in whole or in part, delivery of the Scope of Services. In such event, SERVICE PROVIDER shall resume the Scope of Services upon written notice from CDM SMITH and an appropriate extension of time will be mutually agreed upon and added to the Service Order period of performance. O. Hazardous or Toxic Substances. If this Service Order involves hazardous or toxic substances, the following shall apply: (1) SERVICE PROVIDER shall strictly comply with all health, safety and training requirements that are appended to this Service Order, but CDM SMITH is not responsible for SERVICE PROVIDER’s methods or means of carrying out the work or for the health and safety of SERVICE PROVIDER’s employees. (2) If this Service Order shall require any employee of SERVICE PROVIDER or any of its lower tier subcontractors to go onto or immediately adjacent to a hazardous waste site, the appropriate provisions of the CDM SMITH Corporate Health and Safety Manual and all applicable Site Health and Safety Plans are incorporated herein and made a part hereof. Violation of any provisions of these documents shall be cause for immediate default termination of this Service Order. Copies of these documents will be provided upon request. SERVICE PROVIDER is responsible for obtaining copies and assuring compliance by its employees and lower tier subcontractors. P. Completion and Acceptance. After submittal of the final work product, as specified in Articles 3.B. “Payment” and 4.K. “Copies of Data” of this Service Order, and when SERVICE PROVIDER deems the Scope of Services completed, SERVICE PROVIDER shall give CDM SMITH written notice thereof; for example, by submitting a Final Invoice. Within thirty (30) days after receipt of such notice, CDM SMITH will determine if the Scope of Services has been completed to its satisfaction and, if so, will advise SERVICE PROVIDER of its final acceptance thereof. If not, CDM SMITH will notify SERVICE PROVIDER of its lack of completion or failure to perform and SERVICE PROVIDER shall take remedial action as described in Article 4.C. "Performance” of this Service Order and shall repeat the procedure stated herein until the Scope of Services has been satisfactorily completed and accepted by CDM SMITH. Q. Change in Ownership or Financial Condition. (1) If the SERVICE PROVIDER experiences a material change in its ownership or financial condition at any time after the effective date of this Service Order, the SERVICE PROVIDER shall notify CDM SMITH in writing within 30 days after the change occurs or is identified. (2) The SERVICE PROVIDER shall disclose in writing all pertinent management and financial information necessary for CDM SMITH to make a responsible SERVICE PROVIDER determination in accordance with FAR Subpart 9.104-4. The disclosure shall include results from new conflict of interest screens in accordance with the organizational conflict of interest requirements of the Service Order, cost impact statements for current projects, and a request for a novation or successor-in-interest agreement in accordance with FAR Subpart 42.12, if appropriate. (3) Failure to notify CDM SMITH of a material change in ownership or financial condition will be deemed a breach of this Service Order. R. Bankruptcy. In the event the SERVICE PROVIDER enters into proceedings relating to bankruptcy, whether voluntary or involuntary, the SERVICE PROVIDER agrees to furnish, by certified mail or electronic commerce method authorized by the Service Order, written notification of the bankruptcy to the CDM SMITH Contract Officer responsible for administering the Service Order. This notification shall be furnished within five (5) days of the initiation of the proceedings relating to bankruptcy filing. This notification shall include the date on which the bankruptcy petition was filed, the identity of the court in which the bankruptcy petition was filed, and a listing of CDM SMITH Service Order numbers against which final payment has not been made. This obligation remains in effect until final payment under this Service Order. ARTICLE 5. GENERAL LEGAL PROVISIONS A. Proprietary Information. (1) All drawings, specifications, technical data and other information furnished to SERVICE PROVIDER by CDM SMITH or the Government or developed by SERVICE PROVIDER or others in connection with the Scope of Services are, and shall remain, PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) the property of CDM SMITH or the Government, and shall not be copied or otherwise reproduced or used in any way except in connection with the Scope of Services, or disclosed to third parties or used in any manner detrimental to the interests of CDM SMITH or the Government. (2) The following information will not be subject to the confidentiality requirements of the above: (a) Information in the public domain through no action of SERVICE PROVIDER in breach of this Service Order; (b) Information independently developed by SERVICE PROVIDER; or (c) Information acquired by SERVICE PROVIDER from a third party and not delivered to SERVICE PROVIDER in breach of any confidentiality agreements. B. Assignments. This Service Order and the rights and duties hereunder shall not be assigned, subcontracted or transferred by SERVICE PROVIDER, in whole or in part, without CDM SMITH’s prior written consent. C. Waivers. No waiver by either party of any default by the other party in the performance of any provision of this Service Order shall operate as, or be construed as, a waiver of any future default, whether like or different in character. D. Force Majeure. Neither party to this Service Order shall be liable to the other party for delays in performing the Scope of Services, or for the direct or indirect costs resulting from such delays, that may result from labor strikes, riots, war, acts of governmental authorities, extraordinary weather conditions or other natural catastrophes or any other cause beyond the reasonable control or contemplation of either party. Relief for any such conditions shall be limited in the same manner and to the same extent as set forth in the Prime Contract. SERVICE PROVIDER shall give prompt notice of such an event as soon as it becomes aware of a potential for delay or added cost due to such an event. E. Authorization to Proceed. Execution of this Service Order by CDM SMITH shall constitute the authorization for SERVICE PROVIDER to proceed with the Scope of Services, unless otherwise provided for in this Service Order. F. No Third Party Beneficiaries. This Service Order gives no rights or benefits to anyone other than SERVICE PROVIDER and CDM SMITH and has no third party beneficiaries. G. Jurisdiction. The laws of the Commonwealth of Massachusetts shall govern the validity of this Service Order, its interpretation and performance, and any claims related to it unless the Prime Contract states another Jurisdiction in which case the laws of the Jurisdiction that govern the prime contract shall govern. H. Solicitation of Employees. It is hereby mutually agreed that neither party hereto will knowingly solicit the employment of the other party’s employees during the term of this Service Order and for six (6) months thereafter. This clause shall not prevent the hiring of any employee who independently seeks employment with the other party. I. Severability and Survival. If any of the provisions contained in this Service Order are held for any reason to be invalid, illegal or unenforceable in any respect, such invalidity, illegality or unenforceability shall not affect any other provision and this Service Order shall be construed as if such invalid, illegal or unenforceable provision had never been contained herein. The provisions of Articles 4.E. “Indemnification”, 4.P. “Completion and Acceptance” and 6.A. “Federal Acquisition Regulation” shall survive termination of the Service Order. J. Failure to Deliver. If the SERVICE PROVIDER fails to provide any single deliverable, CDM SMITH shall be reimbursed for any costs determined by the CDM SMITH Subcontracts Manager as equitable in accordance with the applicable FAR clause in Article 6.E. In addition to that amount, it will include any other costs incurred by CDM SMITH as a result of the SERVICE PROVIDER’s failure to deliver. K. Scope of Services. CDM SMITH may adjust the Scope of Services by either adding or deleting services to be performed by issuance of a Change Order to the Service Order. If such adjustment increases or decreases the cost or time required for performance of the Scope of Services, corresponding adjustments to the compensation schedule and/or period of performance of the Service Order will be mutually agreed upon in writing. Additional services provided by SERVICE PROVIDER will be entitled to additional compensation or extension to the period of performance only as authorized in writing by CDM SMITH. If an adjusted figure cannot be agreed upon, SERVICE PROVIDER shall proceed with the Scope of Services and any disagreement concerning compensation shall be treated as a dispute. L. Schedules. Both parties hereto agree and stipulate that, with regard to performance of the Scope of Services by the SERVICE PROVIDER, time is of the essence. SERVICE PROVIDER shall be responsible for all Page 3 direct costs and damages which may arise from its failure to complete the services in accordance with the terms of the Service Order or scheduled milestones, completion or delivery dates established by the Government or CDM SMITH and communicated to the SERVICE PROVIDER. M. Disputes and Claims. (1) In case of any disputes between the SERVICE PROVIDER and CDM SMITH that involve the United States Government, SERVICE PROVIDER agrees to be bound to CDM SMITH to the same extent that CDM SMITH is bound to United States Government both by the terms of the Prime Contract and by any and all decisions or determinations made thereunder by the party or board as authorized in the Prime Contract. It is agreed that in the event the Prime Contract contains a provision, hereinafter called "Disputes" clause, whereby claims may be resolved under an administrative procedure or by arbitration, then as to any claims of SERVICE PROVIDER for or on account of acts or omissions of the United States Government or United States Government's Representative which are not disposed of by agreement, CDM SMITH agrees to present to the United States Government, in CDM SMITH's name, all of SERVICE PROVIDER's claims for additional monetary compensation or time extension which have been properly made to CDM SMITH; and to further invoke, on behalf of the SERVICE PROVIDER, those provisions in the Prime Contract for determining disputes. CDM SMITH shall have the option to present such claims on SERVICE PROVIDER's behalf, in advance of and even without SERVICE PROVIDER's written request. SERVICE PROVIDER shall have full responsibility for preparation and presentation of such claims and shall bear all expenses thereof, including attorneys' fees. SERVICE PROVIDER agrees to be bound by the procedure and final determinations as specified in any such Disputes clause, and agrees that it will not take, or will suspend, any other action or actions with respect to any such claims and will pursue no independent litigation with respect thereto, pending final determination under such Disputes clause. SERVICE PROVIDER shall not be entitled to receive any greater amount from CDM SMITH than CDM SMITH is entitled to and actually does receive from the United States Government on account of SERVICE PROVIDER's Work, less any markups or costs incurred by the CDM SMITH and to which CDM SMITH is otherwise entitled, and SERVICE PROVIDER agrees that it will accept such amount, if any, received by CDM SMITH from United States Government as full satisfaction and discharge of all claims for or on account of acts or omissions of the United States Government or United States Government's Representative. (2) SERVICE PROVIDER shall be bound by CDM SMITH's determination, made in good faith, as to apportionment of any amounts received from United States Government for claimants including CDM SMITH and other subcontractors, whose work is affected by any act or omission of the United States Government or United States Government's Representative. (3) In the event of any dispute between the parties arising out of or in connection with the contract or the services or work contemplated herein and not involving the United States Government or the United States Government’s representative, the parties agree to first make a good faith effort to resolve the dispute informally. Negotiations shall take place between the designated principals of each party. If the parties are unable to resolve the dispute through negotiation within 45 days, then either party may give written notice within 10 days thereafter that it elects to proceed with non-binding mediation pursuant to the commercial mediation rules of the American Arbitration Association. In the event that mediation is not invoked by the parties or that the mediation is unsuccessful in resolving the dispute, then either party may submit the controversy to a court of competent jurisdiction located in the Commonwealth of Massachusetts. The foregoing is a condition precedent to the filing of any action other than an action for injunctive relief or if a Statute of Limitations may expire. Each party shall be responsible for its own costs and expenses including attorneys' fees and court costs incurred in the course of such dispute, mediation, or legal proceeding. The fees of the mediator and any filing fees shall be shared equally by the parties. (4) Pending resolution of any such dispute or claim, by settlement or final judgment, the SERVICE PROVIDER’s performance shall continue in accordance with CDM SMITH’s written instructions. N Audit and Retention of Records. (1) SERVICE PROVIDER shall maintain such books, records, documents and other evidence and shall use such accounting procedures and practices as are necessary to reflect properly all costs claimed to have been incurred or anticipated to be incurred in performing this Service Order. An PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) independent Certified Public Accountant (CPA), as designated by CDM SMITH, shall have the right to examine and audit all of the above in the SERVICE PROVIDER’s offices, during normal business hours, upon reasonable notice to the SERVICE PROVIDER. (2) The independent CPA shall also have the right to examine and audit all books, records, documents and other data of SERVICE PROVIDER related to negotiation, pricing or performance of the Service Order in order to evaluate the accuracy, completeness and currency of the cost or pricing data. This right of examination and audit shall extend to all documents necessary to permit adequate evaluation of the cost or pricing data submitted, along with the computations and projections used. (3) If SERVICE PROVIDER produces any cost, funding or performance reports, the independent CPA shall also have the right to examine and audit books, records and other documents and supporting materials for the purpose of evaluating: (a) the effectiveness of SERVICE PROVIDER’s policies and procedures to produce data compatible with the objectives of these reports; and (b) the data reported. (4) SERVICE PROVIDER shall make available at its office, during normal business hours, upon reasonable notice the materials described in the paragraphs above, for examination, audit or reproduction until the expiration of three (3) years from the date of final payment or, in the event of full or partial termination of this Service Order, from the date of final settlement. Records relating to appeals under Article 5.N. “Disputes and Claims” or to litigation or the settlement of claims arising under, or relating to, this Service Order shall be made available until such appeals, litigation or claims are disposed of. (5) It is agreed that the independent CPA conducting such audits will be required to maintain confidentiality of all rate information, including specific labor rates, salaries and indirect rates, as well as accounting systems, financial structure and pricing methodology information which SERVICE PROVIDER claims as confidential business information. (6) The right to audit or inspect indirect costs comprising SERVICE PROVIDER’s overhead, G&A and other indirect rates shall reside only with the Government or the independent CPA, as designated by CDM SMITH. O. Privity of Contract. (1) The contractual relationship for this Service Order is between CDM SMITH and SERVICE PROVIDER. There is no privity of contract between SERVICE PROVIDER and the Government. (2) All communications between SERVICE PROVIDER and Government must be approved in advance by CDM SMITH’s Contract Officer. In no event shall SERVICE PROVIDER provide cost estimates or work products directly to the Government or any other third party. (3) Under no circumstances shall SERVICE PROVIDER act upon directions given by a representative of the Government without the specific written confirmation by the CDM SMITH Contract Officer. All such direction and technical liaison shall take place through CDM SMITH. CDM SMITH will not be liable for costs of work performed by SERVICE PROVIDER outside of these terms. If SERVICE PROVIDER receives such direction from any representative of the Government, SERVICE PROVIDER shall notify the CDM SMITH Contract Officer as soon as possible before taking any action based upon such direction. P. Entire Agreement. This Service Order, including all attachments, represents the entire agreement between the parties and supersedes all prior agreements and understandings. Changes to this Service Order may be effected only by written modification to the Service Order. Q. Liquidated Damages. (Applicable only if box is checked) (1) Unusable or Missing Sample Data Packages. CDM SMITH shall not be obligated to pay for any Sample Data Package that is either lost or missing or not usable because SERVICE PROVIDER has failed to meet one or more requirements of this Service Order. The data may be unusable because, for example, the sample has been lost or broken after delivery to SERVICE PROVIDER, critical analysis information is missing and additional sampling is required, mandated holding times have been missed, critical tests have not been performed, quality control checks show that the specified requirements have not been met, or for any other reason arising from SERVICE PROVIDER's failure to meet the requirements of this Service Order. Samples shall assume to have been lost if the Sample Data Packages have not been received by the appropriate party within fifteen (15) days of the due date set forth herein. SERVICE PROVIDER assumes the risk of loss for all samples immediately after their delivery to SERVICE PROVIDER or its agent. (2) Sample Data Packages Usable for Alternative Purposes or Accepted for Use in a Non-compliant State. SERVICE PROVIDER may receive a partial payment, based upon an equitable adjustment, for its services in producing Sample Data Packages which the CDM SMITH Contract Officer determines have some value to CDM SMITH's client, although not useful for the original purpose of the Service Order. The Page 4 CDM SMITH Contract Officer shall determine such alternative value and notify the SERVICE PROVIDER. SERVICE PROVIDER's acceptance of such alternative payment shall constitute a waiver of any claim for additional payment. (3) Late Delivery. (a) If SERVICE PROVIDER fails to deliver any Sample Data Package within the time specified herein, or any authorized extension thereof, each party recognizes that CDM SMITH will suffer damage to its reputation and relations with its client(s). Each party also recognizes that such damages are difficult to prove in any legal proceeding. Therefore, in lieu of damages for such injury to reputation due to failure to deliver the Sample Data Packages within the contractually specified time, and not as a penalty, and in recognition of the damage to client relations and CDM SMITH's reputation only, the parties agree that, if so designated on the face of this Service Order, fixed and liquidated damages will apply for each calendar day of delay, up to 15 days, in accordance with the schedule outlined thereon. However, in the absence of a daily schedule, after 15 days the sample shall be considered lost or missing and CDM SMITH shall not be obligated to pay for the Sample Data Package. (b) Sample Data Packages received more than 15 days after they are due may, at the sole discretion of the CDM SMITH Contract Officer, be treated as in paragraph (2) above and subject to an equitable payment not to exceed 25% of the sample unit price. (4) Data which was delivered on time, but determined to be defective for any reason and, where it is determined that the defect can be corrected, will be subject only to a one-time 10% liquidated damages assessment if the corrected data is returned during the agreed upon correction period. Such data as is not corrected during the correction period, but still used in its non-compliant form, will be treated as set forth in paragraph (2) above. (5) CDM SMITH retains the right to terminate this Service Order for any noncompliance in accordance with the terms thereof, including any of the noncompliance matters set forth above, in accordance with the applicable clause under Article 6.E. In the event that CDM SMITH elects to terminate the Service Order, the SERVICE PROVIDER shall be liable for the fixed, agreed and liquidated damages in paragraph (3), accruing until all outstanding Sample Data Packages are delivered. Liquidated damages shall be in addition to excess reprocurement costs eligible for reimbursement under the above noted clause in Article 5.K. (6) The SERVICE PROVIDER shall not be charged with any damages (liquidated or otherwise) nor subject to default termination when the delay in delivery or performance arises out of causes beyond the control, or without the fault or negligence of SERVICE PROVIDER as defined in the above noted clause under Article 6.E.(6). (7) In addition to the above provisions, SERVICE PROVIDER remains liable for failure to deliver any single deliverable in accordance with the applicable Inspection clause in Article 6.E. The equitable adjustment made by CDM SMITH will include as a minimum any liquidated damages adjustments assessed in accordance with Paragraphs (1)-(5) of this Article. In addition, it will include any other costs incurred by the CDM SMITH as a consequence of SERVICE PROVIDER's failure to meet the requirements of this Service Order including the costs of any resampling that are required and any other costs associated with the replacement of lost, damaged or destroyed samples. ARTICLE 6. SERVICE ORDER CLAUSES. A. Federal Acquisition Regulation (FAR). This Service Order incorporates herein by reference the most recently dated FAR clauses listed in Paragraph E., below and elsewhere. The text of each clause shall be deemed to be modified with respect to the identification of parties as provided in Paragraphs B. and C., below. These clauses have the same force and effect as if they were stated in full text. Copies of the FAR clauses can be obtained from the Internet site at http://www.acquisition.gov. B. Rules of Construction. Unless one of the exceptions provided in Paragraph C., below, applies, the term “Contract” shall mean “Service Order”; the term “Contractor” shall mean “SERVICE PROVIDER”; the term “Government” shall mean “CDM SMITH”; and the term “Contracting Officer” shall mean “CDM SMITH’s Contract Officer”. C. Exceptions. The following instances are exceptions to the general rules of construction as provided in Paragraph B., above: (1) where it is clear by the context of the provision itself, or the conditions under which it is being applied, that the reference is intended to refer to the Government, its officers, agents or any upper tier contractor specifically; PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) (2) where an explicit provision of this Service Order states a contrary intent; (3) where access to proprietary financial information or other proprietary data is required; or (4) where interpretation, in accordance with the rules stated above, would place SERVICE PROVIDER in a position of violating the equivalent or related provision of the Prime Contract, whereas construction of the terms without modification would not. D. Disputes Clause. Reference in any provision incorporated by reference herein to the “Disputes” clause shall be construed as reference to Article 5.M. "Disputes and Claims” provision contained in this Service Order. No provision herein shall be taken to imply direct access on the part of the SERVICE PROVIDER to the disputes process as defined in the terms of the Prime Contract. E. Page 5 (5) If the Service Order exceeds $25,000 or is expected to exceed $25,000, the following Articles are hereby incorporated by reference: Article Title of Clause FAR Ref. Article 6.25 Reporting Executive Compensation and First-Tier Subcontract Awards (6) If the Service Order exceeds $30,000 or is expected to exceed $30,000, the following Articles are hereby incorporated by reference: Article 6.26 Protecting the Government’s Interest when Subcontracting with Contractors Debarred, Suspended, or Proposed for Debarment FAR Clauses Incorporated by Reference. (1) The following Articles are hereby incorporated by reference into all Service Orders: 52.204-10 52.209-6 Article Title of Clause FAR Ref. (7) If the Service Order exceeds $100,000 or is expected to exceed $100,000, the following Articles are hereby incorporated by reference: Article 6.1 Article 6.2 Article 6.3 Security Requirements System for Award Management Personal Identity Verification of Contractor Personnel Prohibition of Segregated Facilities Equal Opportunity (Paragraph (c) does not apply) Combating Trafficking in Persons Drug-free Workplace (Only applies if award is to an individual.) Notice of Radioactive Materials Energy Efficiency in Energy-Consuming Products (does not apply to A&E services) Privacy Act Notification Privacy Act Restrictions on Certain Foreign Purchases Rights in Data -- General Unenforceability of Unauthorized Obligations Providing Accelerated Payments to Small Business Subcontractors Subcontracts for Commercial Items Government Property Use and Charges 52.204-2 52.204-7 Article 6.27 Equal Opportunity for Veterans Article 6.28 Employment Report for Veterans 52.204-9 52.222-21 52.222-26 (8) If the “Architect-Engineer” (A-E) block on the face of the Service Order is checked, the following Articles are hereby incorporated by reference: 52.222-50 Article 52.223-6 52.223-7 Article 6.29 Payments under Fixed-Price A-E Contracts Article 6.30 Responsibility of A-E Contractor Article 6.31 Requirements for Registration of Designers Article 6.32 Suspension of Work Article 6.33 Changes - Fixed Price, Alternate III Article 6.34 Subcontracts and Outside Associates and Consultants Article 6.35 Termination (Fixed-Price A-E) Article 6.4 Article 6.5 Article 6.6 Article 6.7 Article 6.8 Article 6.9 Article 6.10 Article 6.11 Article 6.12 Article 6.13 Article 6.14 Article 6.15 Article 6.16 Article 6.17 Article 6.18 52.223-15 52.224-1 52.224-2 52.225-13 52.227-14 Title of Clause 52.232-40 52.244-6 52.245-1 52.245-9 FAR Ref. Article 6.19 Post-award Small Business Program Rerepresentation 52.219-28 Article 6.20 Convict Labor 52.222-3 Article 6.21 Employment Eligibility Verification 52.222-54 Article 6.22 Encouraging Contractor Policies to Ban Text Messaging While Driving 52.223-18 (3) If the Service Order exceeds $10,000 or is expected to exceed $10,000, the following Articles are hereby incorporated by reference: Article 6.23 Notification of Employee Rights under the National Labor Relations Act 52.222-40 (4) If the Service Order exceeds $15,000 or is expected to exceed $15,000, the following Articles are hereby incorporated by reference: Article Title of Clause Article 6.24 Equal Opportunity for Workers with Disabilities FAR Ref. 52.232-10 52.236-23 52.236-25 52.242-14 52.243-1 52.244-4 52.249-7 52.232-39 (2) If the Service Order exceeds $3,000 or is expected to exceed $3,000, the following Articles are hereby incorporated by reference: Article Title of Clause 52.222-35 52.222-37 FAR Ref. (9) If the “Firm Fixed Price” or “Fixed Unit Price” block on the face of this Service Order is checked, the following Articles are hereby incorporated by reference: Article Title of Clause FAR Ref. Article 6.36 Article 6.37 Article 6.38 Article 6.39 Article 6.40 Payments Stop-Work Order Changes -- Fixed-Price, Alternates I Inspection of Services -- Fixed-Price Termination for Convenience of the (Government Services) (Short Form) Article 6.41 Default (Fixed-Price Supply & Service) 52.232-1 52.242-15 52.243-1 52.246-4 52.249-1 52.249-8 (10) If the “Time & Materials” (T&M) block on the face of this Service Order is checked, the following Articles are hereby incorporated by reference: Article Title of Clause FAR Ref. Article 6.42 Allowable Cost and Payment Article 6.43 Payments under T&M and Labor-Hour Contracts Article 6.44 Changes -- T&M or Labor Hours (Modify Paragraph (c) from 30 to 20 days) Article 6.45 Inspection -- T&M and Labor-Hour Article 6.46 Termination (Cost Reimbursement) Alternate IV Article 6.47 Excusable Delays 52.216-7 52.232-7 52.243-3 52.246-6 52.249-6 52.249-14 52.222-36 PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) F. 6 List Of Documents, Exhibits And Other Attachments Supplemental Terms and Conditions Service Contract Act - Wage Determinations Attachment A - Statement of Work Attachment B - Payment Schedule/Price Sheet Attachment C - Reports of Work and Deliverables Attachment D - Health and Safety Attachment E - Insurance Requirements Attachment F - Quality Assurance Plan (if applicable) G. Representations and Certifications dated ____________ (Incorporated By Reference) 52.204-19 Incorporation by Reference of Representations and Certifications The SERVICE PROVIDER’S representations and certifications, including those completed electronically via the System for Award Management (SAM), are incorporated by reference into the Service Order. (End of clause) SERVICE ORDER CLOSEOUT RELEASE The undersigned hereby certifies that the work covered by this Service Order has been completed in accordance with the terms of the Service Order and agrees that upon receipt by the undersigned of a check from CDM SMITH in the amount of $_______________ payable to ____________________(SERVICE PROVIDER), and when the check has been properly endorsed and paid by the bank upon which it is drawn, this document shall become effective to release any lien, stop notice, bond right, or other claim the undersigned has on the project at the site identified in the Scope of Services and CDM SMITH to the following extent. This release covers the final payment for all labor, services, equipment or material furnished under the Scope of Services. SERVICE PROVIDER NAME _________________________________________________________________________________________________ SIGNATURE _______________________________________________________________________________________________________________ DATE ____________________________________________________________________________________________________________________ PROFSOTC August 2012 Rev.2 SUPPLEMENTAL TERMS AND CONDITIONS 1801-1807 GSA PRIME CONTRACT NO. GS-10F-0227J GENERAL RULES OF CONSTRUCTION (a) This Subcontract incorporates the Federal Acquisition Regulation (FAR) and General Services Administration Acquisition Manual (GSAM) clauses listed in the following article and elsewhere herein by reference. The text of each clause shall be deemed to be modified with respect to the identification of parties as provided in paragraphs (b) and (c) below. The most recently dated clauses are incorporated by reference with the same force and effect as if they were given in full text. (b) Unless one of the exceptions provided in paragraph (c) below shall apply, the term "Contract" shall mean "Subcontract"; the term "Contractor" shall mean "Subcontractor"; the term "Government" shall mean "CDM Federal"; and the term "Contracting Officer" shall mean the "CDM Federal Contract Officer". (c) The following instances are exceptions to the general rules of construction as provided in paragraph (b): (d) (i) Where it is clear, by the context of the provision itself or the conditions under which it is being applied, that the reference is intended to refer to the Government, its officers or agents, or the prime contractor specifically; (ii) Where an explicit provision of this Subcontract states a contrary intent; (iii) Where access to proprietary financial information or other proprietary data is required; or (iv) Where interpretation in accordance with the rules stated above would place the prime contractor in a position of violating the equivalent or related provisions of the prime contract whereas construction of the terms without modification would not. References in any provision incorporated by reference herein to the "Disputes" clause shall be construed as references to the “Disputes” clause contained in Section G of this Subcontract. No provision herein shall be taken to imply any direct access on the part of the Subcontractor to the disputes process as defined in the terms of the prime contract. 1801.049.005Part7a.doc 1 SECTION A – CLAUSES INCORPORATED BY REFERENCE A.1 FAR CLAUSES NUMBER 52.204-2 52.208-9 52.222-41 52.229-1 A.2 TITLE Security Requirements Contractor Use of Mandatory Sources of Supply or Services Service Contract Act of 1965, as Amended State and Local Taxes GSA CLAUSES NUMBER 552.211-15 552.229-72 552.238-75 552.238-77 TITLE Defense Priorities and Allocations Systems Requirements Federal Excise Tax – DC Government Identification of Energy Efficient Office Equipment and Supplies containing Recovered Materials or other Environmental Attributes Industrial Funding Fee 1801.049.005Part7a.doc 2 Service Order STANDARD TERMS AND CONDITIONS (continued) 7 ATTACHMENT A STATEMENT OF WORK PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) 8 ATTACHMENT B PAYMENT SCHEDULE/PRICE SHEET PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) 9 ATTACHMENT C REPORTS OF WORK AND DELIVERABLES PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) 10 ATTACHMENT D HEALTH AND SAFETY PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) 11 ATTACHMENT E MINIMUM INSURANCE REQUIRED The Subcontractor shall procure and thereafter maintain during the entire period of performance of this Subcontract and to the extent possible, for at least three (3) years thereafter, the following insurance (indicated by X) with a Best rated company or approved substitute. Required Type of Insurance Limits [X] Commercial (General Liability) - $1,000,000 per occurrence - $1,000,000 in the aggregate - Includes Contractual Liability for bodily injury, death or loss or damage to property to third persons, independent contractor, products, completed operations, and personal injury - Includes XCU (explosion, collapse, and underground) hazard coverage and premises operations when site visitation is required - Limits may be less if supplemented by $1,000,000 per occurrence and $1,000,000 per aggregate of Excess Umbrella Insurance - Additional Insured: Required to name CDM Federal Programs Corporation and the U.S. Government as additional Insured [X] Worker's Compensation - Statutory [X] Employer's Liability - $500,000 per occurrence - Limit may be less if supplemented by $1,000,000 per occurrence and $1,000,000 per aggregate of Excess Umbrella Insurance [X] Professional Liability - $1,000,000 per claim - $1,000,000 per aggregate - Covers any claims arising out of negligent acts, errors, or omissions of Subcontractor when performing professional services - If work is expected to exceed $1,000,000 in any given year of the Subcontract, the minimum coverage shall be $3,000,000 per claim and $3,000,000 per aggregate Pollution Liability Insurance - $1,000,000 per occurrence - $1,000,000 per aggregate - Covers claims based on sudden and accidental discharges of hazardous materials - Additional Insured: Required to name CDM Federal Programs Corporation and the U.S. Government as additional Insured Automobile Liability - $1,000,000 combined single limit - Includes Comprehensive, Bodily Injury and Property Damage coverage - Limit may be less if supplemented by $1,000,000 per occurrence and $1,000,000 per aggregate of Excess Umbrella Insurance - Additional Insured: Required to name CDM Federal Programs Corporation and the U.S. Government as additional Insured [ ] [X] [ ] Automobile Liability with MCS-90 Endorsement - $5,000,000 combined single limit for hazardous transport - $750,000 combined single limit for non hazardous transport - Subcontractor or lower tier Transporter shall have all insurance as required by the Department of Transportation [ ] Excess/Umbrella Liability - $1,000,000 per occurrence - $1,000,000 per aggregate - May supplement Commercial (General) Liability, Automobile Liability, and Employers Liability PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) 12 - If subcontract value will exceed $1,000,000, then $2,000,000 per occurrence and $2,000,000 per aggregate is required - If services include transportation of hazardous materials, $5,000,000 per occurrence and $5,000,000 per aggregate is required Additional Insured: Required to name CDM Federal Programs Corporation and the U.S. Government as additional Insured [ ] Aircraft Public and Passenger Liability [X] Vessel Liability - If aircraft are used in the performance of this Subcontract, then insurance in such amounts as CDM Federal Programs Corporation may require or approve - If vessels are used in the performance of this Subcontract, vessel collision liability and protection and indemnity liability insurance in such amounts as CDM Federal Programs Corporation may require or approve. 1. All policies of insurance shall be endorsed so that Subcontractor’s insurance shall be primary and no contribution shall be required by CDM Federal Programs Corporation. For all policies, the Subcontractor and its insurers shall waive their rights of subrogation against CDM Federal Programs Corporation. 2. Should any of the policies be cancelled before the expiration thereof, notice will be delivered in accordance with the policy provisions. Subcontractor shall provide notice to CDM Federal Programs Corporation at any time Subcontractor becomes aware of any cancellation or material change in the above insurance policies. 3. Subcontractor shall provide copies of its insurance certificates prior to execution of this Subcontract and upon renewal of each policy noted above. The insurance certificate(s) shall include a copy of an endorsement agreeing to provide CDM Federal with a notice of a change in limits or scope of any coverage. If Subcontractor fails to make insurance premium payments or cancels its insurance, CDM Federal Programs Corporation must be notified and all work under the Subcontract will be terminated. The Certificate Holder box on the insurance certificate should include the following name and address as checked. [X] [ CDM Federal Programs Corporation 3201 Jermantown Road, Suite 400 Fairfax, VA 22030 ] CDM Federal Programs Corporation 555 17th Street, Suite 1100 Denver, CO 80202 4. Subcontractor shall insert the substance of this attachment in any lower tier subcontracts and consulting agreements under this Subcontract, including this paragraph 4. PROFSOTC August 2012 Rev.2 Service Order STANDARD TERMS AND CONDITIONS (continued) 13 ATTACHMENT F QUALITY ASSURANCE PLAN PROFSOTC August 2012 Rev.2 PART 8 SERVICE CONTRACT ACT WAGE RATES WD 05-2063 (Rev.-15) was first posted on www.wdol.gov on 12/30/2014 ************************************************************************************ REGISTER OF WAGE DETERMINATIONS UNDER | U.S. DEPARTMENT OF LABOR THE SERVICE CONTRACT ACT | EMPLOYMENT STANDARDS ADMINISTRATION By direction of the Secretary of Labor | WAGE AND HOUR DIVISION | WASHINGTON D.C. 20210 | | | | Wage Determination No.: 2005-2063 Diane C. Koplewski Division of | Revision No.: 15 Director Wage Determinations| Date Of Revision: 12/22/2014 _______________________________________|____________________________________________ Note: Executive Order (EO) 13658 establishes an hourly minimum wage of $10.10 for 2015 that applies to all contracts subject to the Service Contract Act for which the solicitation is issued on or after January 1, 2015. If this contract is covered by the EO, the contractor must pay all workers in any classification listed on this wage determination at least $10.10 (or the applicable wage rate listed on this wage determination, if it is higher) for all hours spent performing on the contract. The EO minimum wage rate will be adjusted annually. Additional information on contractor requirements and worker protections under the EO is available at www.dol.gov/whd/govcontracts. ____________________________________________________________________________________ State: California Area: California Counties of San Luis Obispo, Santa Barbara ____________________________________________________________________________________ **Fringe Benefits Required Follow the Occupational Listing** OCCUPATION CODE - TITLE FOOTNOTE RATE 01000 - Administrative Support And Clerical Occupations 01011 - Accounting Clerk I 15.00 01012 - Accounting Clerk II 16.84 01013 - Accounting Clerk III 18.83 01020 - Administrative Assistant 22.82 01040 - Court Reporter 25.67 01051 - Data Entry Operator I 13.11 01052 - Data Entry Operator II 14.34 01060 - Dispatcher, Motor Vehicle 17.32 01070 - Document Preparation Clerk 14.12 01090 - Duplicating Machine Operator 14.12 01111 - General Clerk I 13.48 01112 - General Clerk II 14.97 01113 - General Clerk III 17.05 01120 - Housing Referral Assistant 21.86 01141 - Messenger Courier 11.96 01191 - Order Clerk I 13.24 01192 - Order Clerk II 14.59 01261 - Personnel Assistant (Employment) I 17.00 01262 - Personnel Assistant (Employment) II 19.01 01263 - Personnel Assistant (Employment) III 21.09 01270 - Production Control Clerk 20.40 01280 - Receptionist 13.14 01290 - Rental Clerk 12.32 01300 - Scheduler, Maintenance 16.47 01311 - Secretary I 16.47 01312 - Secretary II 18.42 01313 - Secretary III 21.86 01320 - Service Order Dispatcher 16.55 01410 - Supply Technician 22.82 01420 - Survey Worker 18.03 01531 - Travel Clerk I 13.04 01532 - Travel Clerk II 13.73 01533 - Travel Clerk III 14.57 01611 - Word Processor I 14.75 01612 - Word Processor II 16.56 01613 - Word Processor III 18.52 05000 - Automotive Service Occupations 05005 - Automobile Body Repairer, Fiberglass 23.91 05010 - Automotive Electrician 18.81 05040 - Automotive Glass Installer 18.02 05070 - Automotive Worker 18.02 05110 - Mobile Equipment Servicer 16.41 05130 - Motor Equipment Metal Mechanic 19.58 05160 - Motor Equipment Metal Worker 18.02 05190 - Motor Vehicle Mechanic 18.68 05220 - Motor Vehicle Mechanic Helper 14.21 05250 - Motor Vehicle Upholstery Worker 17.13 05280 - Motor Vehicle Wrecker 18.02 05310 - Painter, Automotive 18.81 05340 - Radiator Repair Specialist 18.02 http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] 05370 - Tire Repairer 05400 - Transmission Repair Specialist 07000 - Food Preparation And Service Occupations 07010 - Baker 07041 - Cook I 07042 - Cook II 07070 - Dishwasher 07130 - Food Service Worker 07210 - Meat Cutter 07260 - Waiter/Waitress 09000 - Furniture Maintenance And Repair Occupations 09010 - Electrostatic Spray Painter 09040 - Furniture Handler 09080 - Furniture Refinisher 09090 - Furniture Refinisher Helper 09110 - Furniture Repairer, Minor 09130 - Upholsterer 11000 - General Services And Support Occupations 11030 - Cleaner, Vehicles 11060 - Elevator Operator 11090 - Gardener 11122 - Housekeeping Aide 11150 - Janitor 11210 - Laborer, Grounds Maintenance 11240 - Maid or Houseman 11260 - Pruner 11270 - Tractor Operator 11330 - Trail Maintenance Worker 11360 - Window Cleaner 12000 - Health Occupations 12010 - Ambulance Driver 12011 - Breath Alcohol Technician 12012 - Certified Occupational Therapist Assistant 12015 - Certified Physical Therapist Assistant 12020 - Dental Assistant 12025 - Dental Hygienist 12030 - EKG Technician 12035 - Electroneurodiagnostic Technologist 12040 - Emergency Medical Technician 12071 - Licensed Practical Nurse I 12072 - Licensed Practical Nurse II 12073 - Licensed Practical Nurse III 12100 - Medical Assistant 12130 - Medical Laboratory Technician 12160 - Medical Record Clerk 12190 - Medical Record Technician 12195 - Medical Transcriptionist 12210 - Nuclear Medicine Technologist 12221 - Nursing Assistant I 12222 - Nursing Assistant II 12223 - Nursing Assistant III 12224 - Nursing Assistant IV 12235 - Optical Dispenser 12236 - Optical Technician 12250 - Pharmacy Technician 12280 - Phlebotomist 12305 - Radiologic Technologist 12311 - Registered Nurse I 12312 - Registered Nurse II 12313 - Registered Nurse II, Specialist 12314 - Registered Nurse III 12315 - Registered Nurse III, Anesthetist 12316 - Registered Nurse IV 12317 - Scheduler (Drug and Alcohol Testing) 13000 - Information And Arts Occupations 13011 - Exhibits Specialist I 13012 - Exhibits Specialist II 13013 - Exhibits Specialist III 13041 - Illustrator I 13042 - Illustrator II 13043 - Illustrator III 13047 - Librarian 13050 - Library Aide/Clerk 13054 - Library Information Technology Systems Administrator 13058 - Library Technician 13061 - Media Specialist I 13062 - Media Specialist II 13063 - Media Specialist III 13071 - Photographer I 13072 - Photographer II http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] 14.15 17.79 13.29 12.50 13.74 9.90 10.06 16.94 10.95 20.21 13.38 20.21 16.32 18.48 20.21 10.47 12.10 14.19 12.10 12.10 11.76 9.57 10.44 13.51 11.76 13.38 17.06 20.27 26.06 26.06 19.46 38.53 24.78 24.78 17.06 19.17 21.45 23.91 14.88 18.24 15.63 17.48 17.34 47.13 11.18 12.57 13.71 15.39 20.26 19.17 18.55 15.39 29.58 26.61 32.54 32.54 39.34 39.34 47.16 24.52 23.35 28.92 35.39 23.35 28.92 35.39 32.03 15.08 28.92 18.79 20.87 23.35 26.03 19.97 22.32 13073 13074 13075 13110 14000 14041 14042 14043 14044 14045 14071 14072 14073 14074 14101 14102 14103 14150 14160 15000 15010 15020 15030 15050 15060 15070 15080 15090 15095 15110 15120 16000 16010 16030 16040 16070 16090 16110 16130 16160 16190 16220 16250 19000 19010 19040 21000 21020 21030 21040 21050 21071 21080 21110 21130 21140 21150 21210 21410 23000 23010 23021 23022 23023 23040 23050 23060 23080 23110 23120 23125 23130 23140 23160 23181 23182 23183 23260 23290 23310 23311 - Photographer III - Photographer IV - Photographer V - Video Teleconference Technician Information Technology Occupations - Computer Operator I - Computer Operator II - Computer Operator III - Computer Operator IV - Computer Operator V - Computer Programmer I (see 1) - Computer Programmer II (see 1) - Computer Programmer III (see 1) - Computer Programmer IV (see 1) - Computer Systems Analyst I (see 1) - Computer Systems Analyst II (see 1) - Computer Systems Analyst III (see 1) - Peripheral Equipment Operator - Personal Computer Support Technician (see 2) Instructional Occupations - Aircrew Training Devices Instructor (Non-Rated) - Aircrew Training Devices Instructor (Rated) - Air Crew Training Devices Instructor (Pilot) - Computer Based Training Specialist / Instructor - Educational Technologist - Flight Instructor (Pilot) - Graphic Artist - Technical Instructor - Technical Instructor/Course Developer - Test Proctor - Tutor Laundry, Dry-Cleaning, Pressing And Related Occupations - Assembler - Counter Attendant - Dry Cleaner - Finisher, Flatwork, Machine - Presser, Hand - Presser, Machine, Drycleaning - Presser, Machine, Shirts - Presser, Machine, Wearing Apparel, Laundry - Sewing Machine Operator - Tailor - Washer, Machine Machine Tool Operation And Repair Occupations - Machine-Tool Operator (Tool Room) - Tool And Die Maker Materials Handling And Packing Occupations - Forklift Operator - Material Coordinator - Material Expediter - Material Handling Laborer - Order Filler - Production Line Worker (Food Processing) - Shipping Packer - Shipping/Receiving Clerk - Store Worker I - Stock Clerk - Tools And Parts Attendant - Warehouse Specialist Mechanics And Maintenance And Repair Occupations - Aerospace Structural Welder - Aircraft Mechanic I - Aircraft Mechanic II - Aircraft Mechanic III - Aircraft Mechanic Helper - Aircraft, Painter - Aircraft Servicer - Aircraft Worker - Appliance Mechanic - Bicycle Repairer - Cable Splicer - Carpenter, Maintenance - Carpet Layer - Electrician, Maintenance - Electronics Technician Maintenance I - Electronics Technician Maintenance II - Electronics Technician Maintenance III - Fabric Worker - Fire Alarm System Mechanic - Fire Extinguisher Repairer - Fuel Distribution System Mechanic http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] 28.46 32.11 34.60 21.49 17.11 19.98 22.28 24.75 27.42 23.62 17.11 24.75 29.02 35.11 42.09 32.85 27.13 42.09 23.48 22.99 28.12 18.56 18.56 9.77 9.77 11.84 9.77 9.77 9.77 9.77 9.77 12.52 13.17 10.37 23.57 27.45 15.97 20.40 20.40 12.25 15.11 15.97 14.99 14.99 11.44 16.26 15.97 15.97 28.20 27.07 28.20 29.22 20.61 26.03 23.80 24.90 20.33 14.15 27.83 27.59 21.88 29.38 22.54 23.57 25.80 21.37 24.48 19.87 29.80 23312 - Fuel Distribution System Operator 23370 - General Maintenance Worker 23380 - Ground Support Equipment Mechanic 23381 - Ground Support Equipment Servicer 23382 - Ground Support Equipment Worker 23391 - Gunsmith I 23392 - Gunsmith II 23393 - Gunsmith III 23410 - Heating, Ventilation And Air-Conditioning Mechanic 23411 - Heating, Ventilation And Air Contditioning Mechanic (Research Facility) 23430 - Heavy Equipment Mechanic 23440 - Heavy Equipment Operator 23460 - Instrument Mechanic 23465 - Laboratory/Shelter Mechanic 23470 - Laborer 23510 - Locksmith 23530 - Machinery Maintenance Mechanic 23550 - Machinist, Maintenance 23580 - Maintenance Trades Helper 23591 - Metrology Technician I 23592 - Metrology Technician II 23593 - Metrology Technician III 23640 - Millwright 23710 - Office Appliance Repairer 23760 - Painter, Maintenance 23790 - Pipefitter, Maintenance 23810 - Plumber, Maintenance 23820 - Pneudraulic Systems Mechanic 23850 - Rigger 23870 - Scale Mechanic 23890 - Sheet-Metal Worker, Maintenance 23910 - Small Engine Mechanic 23931 - Telecommunications Mechanic I 23932 - Telecommunications Mechanic II 23950 - Telephone Lineman 23960 - Welder, Combination, Maintenance 23965 - Well Driller 23970 - Woodcraft Worker 23980 - Woodworker 24000 - Personal Needs Occupations 24570 - Child Care Attendant 24580 - Child Care Center Clerk 24610 - Chore Aide 24620 - Family Readiness And Support Services Coordinator 24630 - Homemaker 25000 - Plant And System Operations Occupations 25010 - Boiler Tender 25040 - Sewage Plant Operator 25070 - Stationary Engineer 25190 - Ventilation Equipment Tender 25210 - Water Treatment Plant Operator 27000 - Protective Service Occupations 27004 - Alarm Monitor 27007 - Baggage Inspector 27008 - Corrections Officer 27010 - Court Security Officer 27030 - Detection Dog Handler 27040 - Detention Officer 27070 - Firefighter 27101 - Guard I 27102 - Guard II 27131 - Police Officer I 27132 - Police Officer II 28000 - Recreation Occupations 28041 - Carnival Equipment Operator 28042 - Carnival Equipment Repairer 28043 - Carnival Equpment Worker 28210 - Gate Attendant/Gate Tender 28310 - Lifeguard 28350 - Park Attendant (Aide) 28510 - Recreation Aide/Health Facility Attendant 28515 - Recreation Specialist 28630 - Sports Official 28690 - Swimming Pool Operator 29000 - Stevedoring/Longshoremen Occupational Services 29010 - Blocker And Bracer 29020 - Hatch Tender 29030 - Line Handler http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] 22.74 19.47 27.07 23.80 24.90 19.87 22.54 24.53 24.51 25.53 22.86 31.14 24.53 23.57 12.25 23.52 25.37 22.87 15.36 24.53 25.55 27.56 24.53 23.39 18.38 24.97 23.98 24.53 24.53 22.54 24.66 21.58 24.14 24.84 27.24 21.15 24.53 24.53 19.77 12.73 16.73 12.02 16.99 18.59 26.75 24.04 26.75 20.37 24.04 15.94 12.48 28.63 28.63 13.96 28.63 23.21 12.48 13.96 32.52 36.13 15.15 15.89 10.35 15.28 12.12 17.09 12.48 19.32 13.62 20.66 22.54 22.54 22.54 29041 - Stevedore I 29042 - Stevedore II 30000 - Technical Occupations 30010 - Air Traffic Control Specialist, Center (HFO) (see 30011 - Air Traffic Control Specialist, Station (HFO) (see 30012 - Air Traffic Control Specialist, Terminal (HFO) (see 30021 - Archeological Technician I 30022 - Archeological Technician II 30023 - Archeological Technician III 30030 - Cartographic Technician 30040 - Civil Engineering Technician 30061 - Drafter/CAD Operator I 30062 - Drafter/CAD Operator II 30063 - Drafter/CAD Operator III 30064 - Drafter/CAD Operator IV 30081 - Engineering Technician I 30082 - Engineering Technician II 30083 - Engineering Technician III 30084 - Engineering Technician IV 30085 - Engineering Technician V 30086 - Engineering Technician VI 30090 - Environmental Technician 30210 - Laboratory Technician 30240 - Mathematical Technician 30361 - Paralegal/Legal Assistant I 30362 - Paralegal/Legal Assistant II 30363 - Paralegal/Legal Assistant III 30364 - Paralegal/Legal Assistant IV 30390 - Photo-Optics Technician 30461 - Technical Writer I 30462 - Technical Writer II 30463 - Technical Writer III 30491 - Unexploded Ordnance (UXO) Technician I 30492 - Unexploded Ordnance (UXO) Technician II 30493 - Unexploded Ordnance (UXO) Technician III 30494 - Unexploded (UXO) Safety Escort 30495 - Unexploded (UXO) Sweep Personnel 30620 - Weather Observer, Combined Upper Air Or (see Surface Programs 30621 - Weather Observer, Senior (see 31000 - Transportation/Mobile Equipment Operation Occupations 31020 - Bus Aide 31030 - Bus Driver 31043 - Driver Courier 31260 - Parking and Lot Attendant 31290 - Shuttle Bus Driver 31310 - Taxi Driver 31361 - Truckdriver, Light 31362 - Truckdriver, Medium 31363 - Truckdriver, Heavy 31364 - Truckdriver, Tractor-Trailer 99000 - Miscellaneous Occupations 99030 - Cashier 99050 - Desk Clerk 99095 - Embalmer 99251 - Laboratory Animal Caretaker I 99252 - Laboratory Animal Caretaker II 99310 - Mortician 99410 - Pest Controller 99510 - Photofinishing Worker 99710 - Recycling Laborer 99711 - Recycling Specialist 99730 - Refuse Collector 99810 - Sales Clerk 99820 - School Crossing Guard 99830 - Survey Party Chief 99831 - Surveying Aide 99832 - Surveying Technician 99840 - Vending Machine Attendant 99841 - Vending Machine Repairer 99842 - Vending Machine Repairer Helper 21.37 23.57 3) 3) 3) 3) 39.85 27.48 30.26 18.29 20.46 25.35 25.86 27.81 18.29 20.46 23.27 28.07 16.50 19.21 21.06 29.71 33.15 40.11 26.67 20.45 25.86 19.60 25.03 30.59 36.99 25.86 24.02 29.38 35.55 25.32 30.64 36.72 25.32 25.32 23.27 3) 25.35 13.62 20.94 13.63 9.61 14.80 12.48 14.80 17.73 17.89 17.89 11.10 11.32 25.32 12.33 13.23 25.32 18.38 14.83 21.38 23.67 19.26 12.55 13.08 28.30 18.63 25.56 18.63 21.51 18.63 ____________________________________________________________________________________ ALL OCCUPATIONS LISTED ABOVE RECEIVE THE FOLLOWING BENEFITS: HEALTH & WELFARE: $4.02 per hour or $160.80 per week or $696.79 per month http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] VACATION: 2 weeks paid vacation after 1 year of service with a contractor or successor; 3 weeks after 5 years, and 4 weeks after 15 years. Length of service includes the whole span of continuous service with the present contractor or successor, wherever employed, and with the predecessor contractors in the performance of similar work at the same Federal facility. (Reg. 29 CFR 4.173) HOLIDAYS: A minimum of eleven paid holidays per year: New Year's Day, Martin Luther King Jr's Birthday, Washington's Birthday, Good Friday, Memorial Day, Independence Day, Labor Day, Columbus Day, Veterans' Day, Thanksgiving Day, and Christmas Day. A contractor may substitute for any of the named holidays another day off with pay in accordance with a plan communicated to the employees involved.) (See 29 CFR 4.174) THE OCCUPATIONS WHICH HAVE NUMBERED FOOTNOTES IN PARENTHESES RECEIVE THE FOLLOWING: 1) COMPUTER EMPLOYEES: Under the SCA at section 8(b), this wage determination does not apply to any employee who individually qualifies as a bona fide executive, administrative, or professional employee as defined in 29 C.F.R. Part 541. Because most Computer System Analysts and Computer Programmers who are compensated at a rate not less than $27.63 (or on a salary or fee basis at a rate not less than $455 per week) an hour would likely qualify as exempt computer professionals, (29 C.F.R. 541. 400) wage rates may not be listed on this wage determination for all occupations within those job families. In addition, because this wage determination may not list a wage rate for some or all occupations within those job families if the survey data indicates that the prevailing wage rate for the occupation equals or exceeds $27.63 per hour conformances may be necessary for certain nonexempt employees. For example, if an individual employee is nonexempt but nevertheless performs duties within the scope of one of the Computer Systems Analyst or Computer Programmer occupations for which this wage determination does not specify an SCA wage rate, then the wage rate for that employee must be conformed in accordance with the conformance procedures described in the conformance note included on this wage determination. Additionally, because job titles vary widely and change quickly in the computer industry, job titles are not determinative of the application of the computer professional exemption. Therefore, the exemption applies only to computer employees who satisfy the compensation requirements and whose primary duty consists of: (1) The application of systems analysis techniques and procedures, including consulting with users, to determine hardware, software or system functional specifications; (2) The design, development, documentation, analysis, creation, testing or modification of computer systems or programs, including prototypes, based on and related to user or system design specifications; (3) The design, documentation, testing, creation or modification of computer programs related to machine operating systems; or (4) A combination of the aforementioned duties, the performance of which requires the same level of skills. (29 C.F.R. 541.400). 2) Does not apply to employees employed in a bona fide executive, administrative, or professional capacity as defined and delineated in 29 CFR 541. (See CFR 4.156) 3) AIR TRAFFIC CONTROLLERS AND WEATHER OBSERVERS - NIGHT PAY & SUNDAY PAY: If you work at night as part of a regular tour of duty, you will earn a night differential and receive an additional 10% of basic pay for any hours worked between 6pm and 6am. If you are a full-time employed (40 hours a week) and Sunday is part of your regularly scheduled workweek, you are paid at your rate of basic pay plus a Sunday premium of 25% of your basic rate for each hour of Sunday work which is not overtime (i.e. occasional work on Sunday outside the normal tour of duty is considered overtime work). HAZARDOUS PAY DIFFERENTIAL: An 8 percent differential is applicable to employees employed in a position that represents a high degree of hazard when working with or in close proximity to ordinance, explosives, and incendiary materials. This includes work such as screening, blending, dying, mixing, and pressing of sensitive ordance, explosives, and pyrotechnic compositions such as lead azide, black powder and photoflash powder. All dry-house activities involving propellants or explosives. Demilitarization, modification, renovation, demolition, and maintenance operations on sensitive ordnance, explosives and incendiary materials. All operations involving regrading and cleaning of artillery ranges. A 4 percent differential is applicable to employees employed in a position that represents a low degree of hazard when working with, or in close proximity to ordance, (or employees possibly adjacent to) explosives and incendiary materials which involves potential injury such as laceration of hands, face, or arms of the employee engaged in the operation, irritation of the skin, minor burns and the like; minimal damage to immediate or adjacent work area or equipment being used. All operations involving, unloading, storage, and hauling of ordance, explosive, and incendiary ordnance material other than small arms ammunition. These differentials http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] are only applicable to work that has been specifically designated by the agency for ordance, explosives, and incendiary material differential pay. ** UNIFORM ALLOWANCE ** If employees are required to wear uniforms in the performance of this contract (either by the terms of the Government contract, by the employer, by the state or local law, etc.), the cost of furnishing such uniforms and maintaining (by laundering or dry cleaning) such uniforms is an expense that may not be borne by an employee where such cost reduces the hourly rate below that required by the wage determination. The Department of Labor will accept payment in accordance with the following standards as compliance: The contractor or subcontractor is required to furnish all employees with an adequate number of uniforms without cost or to reimburse employees for the actual cost of the uniforms. In addition, where uniform cleaning and maintenance is made the responsibility of the employee, all contractors and subcontractors subject to this wage determination shall (in the absence of a bona fide collective bargaining agreement providing for a different amount, or the furnishing of contrary affirmative proof as to the actual cost), reimburse all employees for such cleaning and maintenance at a rate of $3.35 per week (or $.67 cents per day). However, in those instances where the uniforms furnished are made of "wash and wear" materials, may be routinely washed and dried with other personal garments, and do not require any special treatment such as dry cleaning, daily washing, or commercial laundering in order to meet the cleanliness or appearance standards set by the terms of the Government contract, by the contractor, by law, or by the nature of the work, there is no requirement that employees be reimbursed for uniform maintenance costs. The duties of employees under job titles listed are those described in the "Service Contract Act Directory of Occupations", Fifth Edition, April 2006, unless otherwise indicated. Copies of the Directory are available on the Internet. A links to the Directory may be found on the WHD home page at http://www.dol. gov/esa/whd/ or through the Wage Determinations On-Line (WDOL) Web site at http://wdol.gov/. REQUEST FOR AUTHORIZATION OF ADDITIONAL CLASSIFICATION AND WAGE RATE {Standard Form 1444 (SF 1444)} Conformance Process: The contracting officer shall require that any class of service employee which is not listed herein and which is to be employed under the contract (i.e., the work to be performed is not performed by any classification listed in the wage determination), be classified by the contractor so as to provide a reasonable relationship (i.e., appropriate level of skill comparison) between such unlisted classifications and the classifications listed in the wage determination. Such conformed classes of employees shall be paid the monetary wages and furnished the fringe benefits as are determined. Such conforming process shall be initiated by the contractor prior to the performance of contract work by such unlisted class(es) of employees. The conformed classification, wage rate, and/or fringe benefits shall be retroactive to the commencement date of the contract. {See Section 4.6 (C)(vi)} When multiple wage determinations are included in a contract, a separate SF 1444 should be prepared for each wage determination to which a class(es) is to be conformed. The process for preparing a conformance request is as follows: 1) When preparing the bid, the contractor identifies the need for a conformed occupation(s) and computes a proposed rate(s). 2) After contract award, the contractor prepares a written report listing in order proposed classification title(s), a Federal grade equivalency (FGE) for each proposed classification(s), job description(s), and rationale for proposed wage rate(s), including information regarding the agreement or disagreement of the authorized representative of the employees involved, or where there is no authorized representative, the employees themselves. This report should be submitted to the contracting officer no later than 30 days after such unlisted class(es) of employees performs any contract work. 3) The contracting officer reviews the proposed action and promptly submits a report of the action, together with the agency's recommendations and pertinent information including the position of the contractor and the employees, to the Wage and Hour Division, Employment Standards Administration, U.S. Department of Labor, for review. (See section 4.6(b)(2) of Regulations 29 CFR Part 4). 4) Within 30 days of receipt, the Wage and Hour Division approves, modifies, or disapproves the action via transmittal to the agency contracting officer, or notifies the contracting officer that additional time will be required to process the request. 5) The contracting officer transmits the Wage and Hour decision to the contractor. http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM] 6) The contractor informs the affected employees. Information required by the Regulations must be submitted on SF 1444 or bond paper. When preparing a conformance request, the "Service Contract Act Directory of Occupations" (the Directory) should be used to compare job definitions to insure that duties requested are not performed by a classification already listed in the wage determination. Remember, it is not the job title, but the required tasks that determine whether a class is included in an established wage determination. Conformances may not be used to artificially split, combine, or subdivide classifications listed in the wage determination. http://www.wdol.gov/wdol/scafiles/std/05-2063.txt?v=15[4/30/2015 11:15:32 AM]